ABS污水处理技术研究
摘要
我国的污水处理工艺技术在20世纪末期已经有了较大发展，接近当代国际水平。但是ABS污水处理问题，仍然没有得到根本解决。目前，国内引进的2万吨/年以上的ABS生产装置共有7家，在ABS污水处理方法上，普遍采用的是絮凝、气浮、生化处理方法，ABS污水排放达标率均很低。本课题通过对国内主要ABS生产装置的工艺、规模、废水排放及处理情况的调查研究，详细分析了ABS废水不能达标排放的主要原因，通过ABS废水组成分析，研究ABS废水污染物组成；通过混凝剂，助凝剂的筛选，研究合适的ABS废水处理化学药剂；通过ABS废水的可生化性研究，筛选ABS废水处理的优势菌种。从而提出了一套切实可行的ABS废水处理方法。
There was great development in the latter stage of the 20th century in the sewage disposal technology of our country, Close to the contemporary world level. But the ABS sewage handles problem, have not still gotten basic settlement. At present,the 20,000th ton that introduce at home /produce have in all the 7th is in ABS sewage disposal method at device annual above ABSs, What adopted is flocculating, angry floating, biochemical treatment methods generally, the ABS sewage discharges the rate up to standard verily low. This subject through producing the technologies of device to domestic main ABSses,, waste water discharge and deal with the investigationses of situation scale, It can'ts analyse ABS waste water up to standard main reasons that discharges in detail form analysing through ABS's waste water, Study the pollutant of ABS's waste water to form ; Through the coagulant, help and congeal the screening of the pharmaceutical, study the suitable ABS waste water treatment chemical drug; At ABS waste water very biochemical qualities study, screen ABS the advantage bacterials of waste water treatment. Thus put forward a set of feasible ABS waste water treatment methods .
There was great development in the latter stage of the 20th century in the sewage disposal technology of our country, Close to the contemporary world level. But the ABS sewage handles problem, have not still gotten basic settlement. At present,the 20,000th ton that introduce at home /produce have in all the 7th is in ABS sewage disposal method at device annual above ABSs, What adopted is flocculating, angry floating, biochemical treatment methods generally, the ABS sewage discharges the rate up to standard verily low. This subject through producing the technologies of device to domestic main ABSses,, waste water discharge and deal with the investigationses of situation scale, It can'ts analyse ABS waste water up to standard main reasons that discharges in detail form analysing through ABS's waste water, Study the pollutant of ABS's waste water to form ; Through the coagulant, help and congeal the screening of the pharmaceutical, study the suitable ABS waste water treatment chemical drug; At ABS waste water very biochemical qualities study, screen ABS the advantage bacterials of waste water treatment. Thus put forward a set of feasible ABS waste water treatment methods .
引文
[1]《大庆石化总厂ABS装置操作规程》，2001
[2]《大庆石化总厂污水处理装置装置操作规程》，2001
[3]《油气田环境保护》，2001，2002，1-4期。
[4]李国鼎主编．石油化工废水治理．中国环境科学出版社，1995
[5]唐受印 戴友芝主编．水处理工程师手册．化学工业出版社，2000
[6]唐受印主编．废水处理工程．化学工业出版社，1998
[7]朱月海编著．投药与混合技术．中国环境科学出版社，1992
[8]郑平主编．环境微生物学．浙江大学出版社，2002
[9]国家环保局《水和废水监测分析方法》编委会．水和废水监测分析方法．中国环境科学出版社,1989
[10]吴文新等．ABS树脂生产现状及发展趋势．辽宁化工，1997,26(2)：64—67
[11]乌锡康主编．有机化废水治理技术．化学工业出版社,1999
[12]王希成．生物化学．清华大学出版社,2001
[13]Bossert,I.et al. Petroleum Microbiology,New York:Macmillan Pubilshing Co., 1991,434～476
[14]Joseph G. L. et al. Microbial degradation of hydrocarbon in the environment. Microbial Reviews, 1990,54,(3):305～315
[15]K.Y.Li.Rate Controlling Modle for Bioremediation of Oil Contaminated Soil [J].Environment Progress,(214);257～261
[16]Khan R.A.Petroleum biodegradation and spill bioremediation [J]. Bull. Envirn. Contam. Toxicol., 1993,(50):378～384
[17]Atlas R.M. Microbial degradation of petroleum hydrocarbons:an environmental perspective [J].Microbial Rev.2001,11(2):30～40
[18]张希蘅主编．废水处理工程．冶金工业出版社，1984
[19]田宝珍等．铝铁共聚复合混凝剂的研究及应用(J)．中国给水排水，1999,15(2)：17
[20]李俊梅．聚合氯化铝絮凝效果及在污水处理中的应用(J)．化工环保，1998,18(1)：7～10
[21]余维波．ABS废水处理技术[J]．化工环保,2000,20(6)：64～67
[22]苏红．ABS废水处理方法的研究．吉林化工学院学报,2000,17(2)：45～49
[23]顾夏生等．水处理工程[M]．清华大学出版社，1985
[24]李善仁等．石油化工废水试验研究．重庆环境科学,2002(8)：48～49
[25]谢重阁．环境中石油污染物的分析技术．中国环境科学出版社，1987
[26]郑远羊编译．石油污染生化治理的进展．国外环境科学技术，1993，(3)：46～50
[27]俞辉群，全浩编译．水环境净化及废水处理微生物学．中国建筑工业出版社，1988
[28]陈美荣等．石油化工工业废水处理工艺研究．环境保护科学,2000,(97)：16～18
[29]高建平等．聚丙烯酰胺在水介质中的低温化学降解．化学工业与工程，1999,16(1)：44～48
[30]姜昌亮等．石油工业环境保护[M]．石油工业出版社,2000
[31]武汉大学分析化学教研室．分析化学．人民教育出版社，1990
[32]杨承义．环境监测．天津大学出版社，1993
[33]Fedorak R.M.,Westlaked W.S. Microbial degradation of aromatics and saturates in Prudhoe Bay
crude oil as determined by glass capillary gas chromatography[j].j.of microbial,1981,(27):432～443
[34]Murphy A.P.Studies of oxidation by Fenton reagent[J].Environmental science and technology, 1989,23(2): 167～172
[35]Harruff,Lewis Gect．用活性碳净化．第75界气体加工年会论文[C]，1996．113～143
[36]As sibe catailsis inst.RU 2053838[P].1996,02,10
[37]Demetrios K Kyriacoll.Basic of electro organic synthesis,New York: 1981:85～98
[38]Crank J.Mathematics of Diffusion.2nd London:Oxford university Press, 1979.56～60
[39]Swearengin J V. Method of Purifying arylphenones[P].US5777171.1998
[40]Walz R, BamerB,Heitz W, Monomeric and polymeric azoinitiators[J],Makromol Chem,1977,178:2527～2534
[2]《大庆石化总厂污水处理装置装置操作规程》，2001
[3]《油气田环境保护》，2001，2002，1-4期。
[4]李国鼎主编．石油化工废水治理．中国环境科学出版社，1995
[5]唐受印 戴友芝主编．水处理工程师手册．化学工业出版社，2000
[6]唐受印主编．废水处理工程．化学工业出版社，1998
[7]朱月海编著．投药与混合技术．中国环境科学出版社，1992
[8]郑平主编．环境微生物学．浙江大学出版社，2002
[9]国家环保局《水和废水监测分析方法》编委会．水和废水监测分析方法．中国环境科学出版社,1989
[10]吴文新等．ABS树脂生产现状及发展趋势．辽宁化工，1997,26(2)：64—67
[11]乌锡康主编．有机化废水治理技术．化学工业出版社,1999
[12]王希成．生物化学．清华大学出版社,2001
[13]Bossert,I.et al. Petroleum Microbiology,New York:Macmillan Pubilshing Co., 1991,434～476
[14]Joseph G. L. et al. Microbial degradation of hydrocarbon in the environment. Microbial Reviews, 1990,54,(3):305～315
[15]K.Y.Li.Rate Controlling Modle for Bioremediation of Oil Contaminated Soil [J].Environment Progress,(214);257～261
[16]Khan R.A.Petroleum biodegradation and spill bioremediation [J]. Bull. Envirn. Contam. Toxicol., 1993,(50):378～384
[17]Atlas R.M. Microbial degradation of petroleum hydrocarbons:an environmental perspective [J].Microbial Rev.2001,11(2):30～40
[18]张希蘅主编．废水处理工程．冶金工业出版社，1984
[19]田宝珍等．铝铁共聚复合混凝剂的研究及应用(J)．中国给水排水，1999,15(2)：17
[20]李俊梅．聚合氯化铝絮凝效果及在污水处理中的应用(J)．化工环保，1998,18(1)：7～10
[21]余维波．ABS废水处理技术[J]．化工环保,2000,20(6)：64～67
[22]苏红．ABS废水处理方法的研究．吉林化工学院学报,2000,17(2)：45～49
[23]顾夏生等．水处理工程[M]．清华大学出版社，1985
[24]李善仁等．石油化工废水试验研究．重庆环境科学,2002(8)：48～49
[25]谢重阁．环境中石油污染物的分析技术．中国环境科学出版社，1987
[26]郑远羊编译．石油污染生化治理的进展．国外环境科学技术，1993，(3)：46～50
[27]俞辉群，全浩编译．水环境净化及废水处理微生物学．中国建筑工业出版社，1988
[28]陈美荣等．石油化工工业废水处理工艺研究．环境保护科学,2000,(97)：16～18
[29]高建平等．聚丙烯酰胺在水介质中的低温化学降解．化学工业与工程，1999,16(1)：44～48
[30]姜昌亮等．石油工业环境保护[M]．石油工业出版社,2000
[31]武汉大学分析化学教研室．分析化学．人民教育出版社，1990
[32]杨承义．环境监测．天津大学出版社，1993
[33]Fedorak R.M.,Westlaked W.S. Microbial degradation of aromatics and saturates in Prudhoe Bay
crude oil as determined by glass capillary gas chromatography[j].j.of microbial,1981,(27):432～443
[34]Murphy A.P.Studies of oxidation by Fenton reagent[J].Environmental science and technology, 1989,23(2): 167～172
[35]Harruff,Lewis Gect．用活性碳净化．第75界气体加工年会论文[C]，1996．113～143
[36]As sibe catailsis inst.RU 2053838[P].1996,02,10
[37]Demetrios K Kyriacoll.Basic of electro organic synthesis,New York: 1981:85～98
[38]Crank J.Mathematics of Diffusion.2nd London:Oxford university Press, 1979.56～60
[39]Swearengin J V. Method of Purifying arylphenones[P].US5777171.1998
[40]Walz R, BamerB,Heitz W, Monomeric and polymeric azoinitiators[J],Makromol Chem,1977,178:2527～2534