系列V-O配聚物的合成、结构及光电性能
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摘要
配位聚合物是金属离子和有机配体通过自组装而形成的无限结构的配位化合物。我们发现,具有某些特定结构的配聚物可能是具有一定半导体特性,甚至是无机半导体一有机半导体的统一性的化合物。因此它们在光、电、磁等领域具有诱人的应用前景,已成为多学科和领域的研究热点。特别是部分配聚物具有很好的光电转换能力,而关于这个方面的报道又是很少,因此配聚物的研制及其光电性能的研究对于寻找新型的光电转换材料有重要的理论和实际意义。
本文采用溶剂热,水热等方法,主要以钒为中心原子合成了5种V-O配合物和2种其它过渡金属配聚物(Cu、Co),全部得到了单晶体,测定了它们的晶体结构,给出了明确的结构解析。它们的分子式如下:
研究了上述7种配合物的红外,紫外-可见光谱,并且重点利用表面光电压光谱技术和场诱导表面光电压光谱技术对7种化合物进行了光电性能测定。结果表明在300-800nm范围内,它们都体现出光-电性能转换的趋势,而且都显示出一定的半导体特征,体现出与L-L跃迁,L-M跃迁和d-d跃迁相呼应的光伏响应,这对研制一种介于无机半导体和有机半导体之间的新型半导体光电材料有一定的启发和引导意义。
Coordination polymer is coordination complexes with extended structure self-assembled through metal ions and organic ligands. We have found that those coordination polymer with special structures may have some semeconductor charactristics,even organic-inorganic consolidate semeconductor property. Hence they were regarded the most promising fuctional materials currently and has been an active area in inorganic and materials chemistry due to its interesting potential application in optics, electronic, magetic and catalytic ect fields. In paticular,some of the coordination polymer possess more photo-electric transform property and less reported. So the preparing of the coordination polymers and studyding their photo-electric property have significient theorial and practical meaning for finding a new style photo-electric materials.
Herein, using hydrothermal, solvothermal syntheses methods, we mainly report five V-O coordiantion complexes and two transitional metal coordiantion complexes based on Cu and Co. Their structures have been determined by X-ray diffraction methods. Their formulas are presented as following:
We have thorough studied the seven polymer we mentioned before on infrared spectrum,ultraviolet- visible spectrum and put emphasis on the photo-electric properties of these complexes using surface photovoltage spectrum and Field -induced surface photovoltage spectrum. The result indicate that between the range of 300-800nm,they all behave some photo-electric behavior and possess the characteristic of orgainc/inorgainc semeconductor property, also shows the transition of L-L,L-M,d-d according to the photo-electric response.It has a well meaning to develop new orgainc/inorgainc semeconductor materials.
本文采用溶剂热,水热等方法,主要以钒为中心原子合成了5种V-O配合物和2种其它过渡金属配聚物(Cu、Co),全部得到了单晶体,测定了它们的晶体结构,给出了明确的结构解析。它们的分子式如下:
研究了上述7种配合物的红外,紫外-可见光谱,并且重点利用表面光电压光谱技术和场诱导表面光电压光谱技术对7种化合物进行了光电性能测定。结果表明在300-800nm范围内,它们都体现出光-电性能转换的趋势,而且都显示出一定的半导体特征,体现出与L-L跃迁,L-M跃迁和d-d跃迁相呼应的光伏响应,这对研制一种介于无机半导体和有机半导体之间的新型半导体光电材料有一定的启发和引导意义。
Coordination polymer is coordination complexes with extended structure self-assembled through metal ions and organic ligands. We have found that those coordination polymer with special structures may have some semeconductor charactristics,even organic-inorganic consolidate semeconductor property. Hence they were regarded the most promising fuctional materials currently and has been an active area in inorganic and materials chemistry due to its interesting potential application in optics, electronic, magetic and catalytic ect fields. In paticular,some of the coordination polymer possess more photo-electric transform property and less reported. So the preparing of the coordination polymers and studyding their photo-electric property have significient theorial and practical meaning for finding a new style photo-electric materials.
Herein, using hydrothermal, solvothermal syntheses methods, we mainly report five V-O coordiantion complexes and two transitional metal coordiantion complexes based on Cu and Co. Their structures have been determined by X-ray diffraction methods. Their formulas are presented as following:
We have thorough studied the seven polymer we mentioned before on infrared spectrum,ultraviolet- visible spectrum and put emphasis on the photo-electric properties of these complexes using surface photovoltage spectrum and Field -induced surface photovoltage spectrum. The result indicate that between the range of 300-800nm,they all behave some photo-electric behavior and possess the characteristic of orgainc/inorgainc semeconductor property, also shows the transition of L-L,L-M,d-d according to the photo-electric response.It has a well meaning to develop new orgainc/inorgainc semeconductor materials.
引文
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