聚钼酸盐（｛Mo_（154）｝和｛Mo_（72）Fe_（30）｝）聚集性质及其与表面活性剂相互作用的研究
|
摘要
无机盐大分子——聚钼酸盐(polyoxomolybdates，简称POMs)最近备受化学家们的关注。对于这类物质的研究，最初可追溯到1793年Scheele有关“蓝水”溶液的研究报告，他认为这种蓝水是溶质为含有Mo(Ⅴ)化合物的天然聚钼酸盐矿泉水。其后的研究表明，这些钼蓝分子有多种结构类型，含有较多的原子，其大小能够达到纳米级范围，被称之为“纳米级无机大分子(nanoscale inorganicmacromolecules)”或者“纳米级聚钼酸盐(nanoscalc polyoxomolybdates)”。这类无机盐大分子具有非常好的水溶性，溶于水后，可以电离出大阴离子和对应的小阳离子；但这并非是这类分子在极性溶剂中的最终存在状态。在经过一段时间后，这些大的阴离子会发生自聚集，进而形成二级有序聚集体。这一特点和胶体与界面化学中两亲分子溶液中形成的“有序聚集体结构”，如囊泡结构等相似。本文从“胶体化学”的角度分析聚钼酸盐与表面活性剂的作用机理，了解POMs与表面活性剂聚集体之间关系；此外，通过研究反离子(阳离子)对无机大阴离子聚集的影响，探索聚钼酸盐无机大分子“第二溶质态”的特性。合成了聚钼酸盐{Mo_(154)}和{Mo_(72)Fe_(30)}，研究了聚钼酸盐({Mo_(154)})与表面活性剂进行复配形成具有准单晶结构无机／有机聚集体，并从反离子对聚钼酸盐大阴离子({Mo_(72)Fe_(30)})聚集性质及对形成聚集体的影响方面进行了研究；且从电化学性质的角度研究了聚钼酸盐({Mo_(154)}和{Mo_(72)Fe_(30)})在形成聚集体前后电化学性质的变化。
第一章介绍了“纳米级聚钼酸盐”的结构与合成(“一级有序结构”)以及最近的相关研究结果，对比两亲分子自聚集体系，提出了“二级有序聚集体”的概念，并对“二级有序聚集体”的形成驱动力、以及一定量的无机盐电解质对“二级有序聚集体”的性质影响等方面进行了归纳总结；介绍了表面活性剂聚集体的形成结构及机理，并将其与聚钼酸盐“二级有序聚集体”的形成机理进行简单比较；最后对表面活性剂与“纳米级无机聚钼酸盐”相互作用形成有机／无机“二级有序聚集体”混合材料的研究结果进行了归纳。这类无机分子具有双重性质——它们既具有单个分子所具有的特性，如确定的结构和均匀的大小，又具有纳米颗粒、复合物和胶体粒子的特性。纳米级无机分子溶液表现出的奇特性质，特别是分子纳米特性和可变的物理化学性质，这在开发新型的纳米器件等方面有潜在的广阔应用前景。
Achim Müller领导的研究组通过破坏阴离子聚合物表面的水合外壳使其结晶纯化，合成了一系列聚钼酸盐簇合物，并确定了其化学结构。这类聚钼酸盐分子结构面纱的揭开为进一步了解这类分子各方面的物理化学性质奠定了基础。第二章合成了两种聚钼酸盐：一种是大的轮状分子的代表：{Mo_(154)}；另外一种是球状或者说Keplerate状分子的代表：{Mo_(72)Fe_(30)}(其中，包括合成Keplerate球状的{Mo_(132)}大分子晶体)，对它们的结构进行了表征，表征结果与文献所给出的结果非常吻合，为后面聚钼酸盐与表面活性剂复配及聚钼酸盐聚集性质等工作的开展奠定了基础。
由于无机纳米簇合物和长链表面活性剂进行混合复配体系在许多方面具有很好的应用潜力，因此与之相关的研究较多。但是，由于无机纳米颗粒具有多分散特性和有机表面活性剂具有长链的柔韧性与易弯曲的特性，导致在较大三维空间范围内制得具有有序结构的有机／无机混合单晶材料比较困难。而单晶材料因本身具备许多奇特性质，在材料科学方面具有非常重要的应用。有研究者通过带相反电荷的阳离子表面活性剂与聚钼酸盐无机大阴离子的相互作用对聚钼酸盐类大阴离子表面进行改性，然后在界面上会形成二维膜，但是关于聚钼酸盐与表面活性剂相互作用的研究中，迄今未发现有关具有单晶结构有机／无机混合材料形成的报道。
第三章中，轮状聚钼酸盐Na_(15)[Mo~Ⅵ_(126)Mo~Ⅴ_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5)[Mo~Ⅵ_(124)Mo~Ⅴ_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5)·ca.400H_2O(简写成{Mo_(154)}，在水溶液中可以电离出大阴离子{Mo_(154)}~(14-)和{Mo_(154)}~(16-)，因此也可以简写成{Mo_(154)}~(15-))与阳离子表面活性剂十四烷基三甲基溴化铵(简写成TTABr)相互作用形成了被表面活性剂包封的复合体。由于单个{Mo_(154)}簇合物分子本身具有相同尺寸和结构的纳米颗粒，因此这些簇合物单体在和阳离子表面活性剂相互作用之后，会发生自聚集，形成尺寸约为70-200 nm左右的六方形堆积复合体，电子衍射图的分析表明：这些六方形堆积结构的复合体具有准单晶性质。这一结果表明：通过调控无机晶体与有机表面活性剂之间的相互作用，以及通过对无机金属盐晶体表面的改性，可以形成具有准单晶性质的有机／无机复合体。此外，这些准单晶性质的复合体还可以进一步溶解在大量TTABr存在的溶液中，从而形成更大尺寸的聚集体。
无机聚钼酸盐大分子或者称为POMs在极性溶液中(水、乙醇或丙酮中)发生电离形成带有负电荷的大阴离子和作为反离子的小阳离子(比如Na~+、NH_4~+和H~+等)，这些大阴离子会发生自聚集形成一种单层、中空的囊泡状聚集体。这种具有超分子结构的中空囊泡状聚集体与溶液中表面活性剂所形成的囊泡及生物脂质体很相似，关于由聚钼酸盐大阴离子形成的囊泡状聚集体平衡尺寸的平衡控制方面的研究结果，也有利于表面活性剂体系比如囊泡，盘状胶束等方面的研究。
第四章研究的内容是在不引入其它杂质离子的情况下，观察不同种类和价态的阳离子对{Mo_(72)Fe_(30)}稀溶液中囊泡状聚集体尺寸的影响。主要通过在{Mo_(72)Fe_(30)}溶液中引入了小的阳离子如Na~+、NH_4~+和H~+，以及小的有机阳离子如(CH_3)_4N~+、(C_2H_5)_4N~+和(C_4H_9)_4N~+等，观察了这些阳离子对大阴离子发生聚集的影响。研究结果表明当加入不同的阳离子时，由{Mo_(72)Fe_(30)}大阴离子形成的超分子聚集体的尺寸发生了变化，研究认为聚集体尺寸的变化主要受两个因素的影响：引入的各种阳离子所带电荷数(价态)以及离子的尺寸(半径)。阳离子所带的电荷数越多(价态越高)，则形成的超分子聚集体的尺寸越大：而反离子(阳离子)的尺寸越大而形成的超分子聚集体的尺寸将有所变小。聚钼酸盐大阴离子在形成超分子聚集体的尺寸是受到上述两个影响因素平衡后的结果，或者也可以说，通过使拓扑缺陷能和自身静电能最小化对最后形成的聚集体尺寸进行调节。动态光散射和透射电镜观测结果也进一步证实了反离子对大阴离子形成的囊泡状聚集体的影响：一个是反离子(阳离子)所带的电荷；另外一个是反离子(阳离子)的尺寸大小。这些结果对进一步理解两亲性分子自聚集体系的聚集行为，提供了一种新的聚集模型，而且在纳米科学与技术的研究方面也有非常重要的意义。
聚钼酸盐类无机大分子形成二级有序自聚集体的驱动力是什么?关于这方面的研究，Lehigh大学有研究者认为，导致聚集体形成的驱动力并非是静电力作用，而且聚集体中“一级有序结构”单体之间的距离较大(1～2 nm)，也不存在化学键的作用，氢键也不是促使聚集体形成的主要因素，这种聚集作用应该是一种特殊驱动力的结果，称之为类电荷吸引力(like-charge attraction)，即“一级有序结构”是纳米聚钼酸盐阴离子共享反离子电荷相互吸引而形成稳定的囊泡聚集体，该理论可以说是介于胶体化学中的DLVO理论(Derjaguin-Landau-Verwey-Overbeek)和单个离子能够在溶液中稳定存在的Debye-Hückel理论之间的新观点。也就是说，这种驱动力是一种物理作用，在聚集前后单体自身性质没有改变。
第五章从电化学性质的角度，通过对比{Mo_(154)}和{Mo_(72)Fe_(30)}溶液在形成囊泡状聚集体前后的循环伏安曲线，发现聚集前后其电化学性质没有发生改变，说明无机聚钼酸盐大分子在形成囊泡状聚集体的过程中没有引起单体分子氧化—还原性质的改变，同时从侧面证明了聚钼酸盐在形成聚集体的过程中应该主要是受一种物理作用驱使。对{Mo_(154)}和{Mo_(72)Fe_(30)}聚钼酸盐溶液电化学性质的简单分析也为这类无机聚钼酸盐的物理化学性质及聚集机理的研究提供了一种新的研究手段。
structures (superficially at least, resemble bilayer vesicles formed by surfactants or lipids in solution) with an average, almost monodispersed radius in water of several tens of nanometers, and composed of more than 1000 POMs. The cohesive energy of per bond between {Mo_(72)Fe_(30)} macroanions on the single-layer shells is approximately 6kT which was extracted from analysis based on a charge regulation model. These findings related to the equilibrium controlling for the size of single-layer shells composed of polyoxometalate macroions in dilute solution could certainly be propitious to surfactant systems such as the vesicles, disc-like micelles, etc. In the fourth chapter, small cations (such as Na~+、 K~+、 Ca~(2+)、 Ba~(2+)、 (CH_3)_4N~+、 (C_2H_5)_4N~+ and (G_4H_9)_4N~+) )were introduced to the {Mo_(72)Fe_(30)} aqueous solution. The finally dilute solutions are free-extra-electrolytes, being equal to the solutions obtained from dissolving Na~+-{Mo_(72)Fe_(30)}, K~+-{Mo_(72)Fe_(30)}, (CH_3)_4N~+-{Mo_(72)Fe_(30)}, (C_2H_5)_4N~+-{Mo_(72)Fe_(30)}, (C_4H_9)_4N~+-{Mo_(72)Fe_(30)}, Ca~(2+)-{Mo_(72)Fe_(30)}, and Ba~(2+)-{Mo_(72)Fe_(30)} compounds in water. When the large {Mo_(72)Fe_(30)} anionic clusters and cationic counter-ions form superstructures, the conductivity mainly is contributed from the monomers of {Mo_(72)Fe_(30)} anions and cationic cations in solution. Two factors determine the equilibrium size of shells in our studied systems, the charges and the size of the exchanged cationic counter-ions. The higher charges of cationic counter-ions induce the bigger size of shells, however, large size of cationic counter-ions reduce the size of the shells. The size of the shells is subsequently determined by the balance of the two factors, i.e, by minimizing the energy cost of topological defects and the electrostatic self-energy. For the unique self-assembly process of this polyoxomolybdates, certain questions to be analyzed, for example, the driving forces to overcome the Coulomb repulsion among macroanions and attract them together. Prof. Liu had a particular opinion, the self-assembly of the hydrophilic macroions is not mainly attributed to electrostatic interaction, van der Wals force, or chemical bond interaction (the interanionic distance about 1-2 nm) and also the hydrophobic interaction and the hydrogen bond cannot be dominant; therefore, the self-assembly of the hydrophilic macroions is mainly attributed to the charges on their surfaces. So the like-charge attraction does exist in hydrophilic macroionic solutions, and it determines the association of the polyoxomolybdates. That is to say, the nanoscacle polyoxomolybdate anions ("first organized structures") attract each other by sharing the counterions to form the stable vesicle-like aggregations, which is the novel viewpoint between the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory in colloidal chemistry and the Debye-Huckel theory about the stable ions in solution. With regard to this viewpoint about the driving force, there is still no report on the aggregations of amphiphile surfactants. In the fifth chapter, no changes were not found by contrasting the curves of cyclic voltammograms of the before and after aggregation formation of {Mo_(154)} and {Mo_(72)Fe_(30)} aqueous solution, which indicated that there were no changes of oxidation and reduction in the formation of the aggregation of {Mo_(154)} and {Mo_(72)Fe_(30)}. In another word, these suggested that the vesicle aggregation formation of the polyoxomolybdates is driven by physical forces.
第一章介绍了“纳米级聚钼酸盐”的结构与合成(“一级有序结构”)以及最近的相关研究结果，对比两亲分子自聚集体系，提出了“二级有序聚集体”的概念，并对“二级有序聚集体”的形成驱动力、以及一定量的无机盐电解质对“二级有序聚集体”的性质影响等方面进行了归纳总结；介绍了表面活性剂聚集体的形成结构及机理，并将其与聚钼酸盐“二级有序聚集体”的形成机理进行简单比较；最后对表面活性剂与“纳米级无机聚钼酸盐”相互作用形成有机／无机“二级有序聚集体”混合材料的研究结果进行了归纳。这类无机分子具有双重性质——它们既具有单个分子所具有的特性，如确定的结构和均匀的大小，又具有纳米颗粒、复合物和胶体粒子的特性。纳米级无机分子溶液表现出的奇特性质，特别是分子纳米特性和可变的物理化学性质，这在开发新型的纳米器件等方面有潜在的广阔应用前景。
Achim Müller领导的研究组通过破坏阴离子聚合物表面的水合外壳使其结晶纯化，合成了一系列聚钼酸盐簇合物，并确定了其化学结构。这类聚钼酸盐分子结构面纱的揭开为进一步了解这类分子各方面的物理化学性质奠定了基础。第二章合成了两种聚钼酸盐：一种是大的轮状分子的代表：{Mo_(154)}；另外一种是球状或者说Keplerate状分子的代表：{Mo_(72)Fe_(30)}(其中，包括合成Keplerate球状的{Mo_(132)}大分子晶体)，对它们的结构进行了表征，表征结果与文献所给出的结果非常吻合，为后面聚钼酸盐与表面活性剂复配及聚钼酸盐聚集性质等工作的开展奠定了基础。
由于无机纳米簇合物和长链表面活性剂进行混合复配体系在许多方面具有很好的应用潜力，因此与之相关的研究较多。但是，由于无机纳米颗粒具有多分散特性和有机表面活性剂具有长链的柔韧性与易弯曲的特性，导致在较大三维空间范围内制得具有有序结构的有机／无机混合单晶材料比较困难。而单晶材料因本身具备许多奇特性质，在材料科学方面具有非常重要的应用。有研究者通过带相反电荷的阳离子表面活性剂与聚钼酸盐无机大阴离子的相互作用对聚钼酸盐类大阴离子表面进行改性，然后在界面上会形成二维膜，但是关于聚钼酸盐与表面活性剂相互作用的研究中，迄今未发现有关具有单晶结构有机／无机混合材料形成的报道。
第三章中，轮状聚钼酸盐Na_(15)[Mo~Ⅵ_(126)Mo~Ⅴ_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5)[Mo~Ⅵ_(124)Mo~Ⅴ_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5)·ca.400H_2O(简写成{Mo_(154)}，在水溶液中可以电离出大阴离子{Mo_(154)}~(14-)和{Mo_(154)}~(16-)，因此也可以简写成{Mo_(154)}~(15-))与阳离子表面活性剂十四烷基三甲基溴化铵(简写成TTABr)相互作用形成了被表面活性剂包封的复合体。由于单个{Mo_(154)}簇合物分子本身具有相同尺寸和结构的纳米颗粒，因此这些簇合物单体在和阳离子表面活性剂相互作用之后，会发生自聚集，形成尺寸约为70-200 nm左右的六方形堆积复合体，电子衍射图的分析表明：这些六方形堆积结构的复合体具有准单晶性质。这一结果表明：通过调控无机晶体与有机表面活性剂之间的相互作用，以及通过对无机金属盐晶体表面的改性，可以形成具有准单晶性质的有机／无机复合体。此外，这些准单晶性质的复合体还可以进一步溶解在大量TTABr存在的溶液中，从而形成更大尺寸的聚集体。
无机聚钼酸盐大分子或者称为POMs在极性溶液中(水、乙醇或丙酮中)发生电离形成带有负电荷的大阴离子和作为反离子的小阳离子(比如Na~+、NH_4~+和H~+等)，这些大阴离子会发生自聚集形成一种单层、中空的囊泡状聚集体。这种具有超分子结构的中空囊泡状聚集体与溶液中表面活性剂所形成的囊泡及生物脂质体很相似，关于由聚钼酸盐大阴离子形成的囊泡状聚集体平衡尺寸的平衡控制方面的研究结果，也有利于表面活性剂体系比如囊泡，盘状胶束等方面的研究。
第四章研究的内容是在不引入其它杂质离子的情况下，观察不同种类和价态的阳离子对{Mo_(72)Fe_(30)}稀溶液中囊泡状聚集体尺寸的影响。主要通过在{Mo_(72)Fe_(30)}溶液中引入了小的阳离子如Na~+、NH_4~+和H~+，以及小的有机阳离子如(CH_3)_4N~+、(C_2H_5)_4N~+和(C_4H_9)_4N~+等，观察了这些阳离子对大阴离子发生聚集的影响。研究结果表明当加入不同的阳离子时，由{Mo_(72)Fe_(30)}大阴离子形成的超分子聚集体的尺寸发生了变化，研究认为聚集体尺寸的变化主要受两个因素的影响：引入的各种阳离子所带电荷数(价态)以及离子的尺寸(半径)。阳离子所带的电荷数越多(价态越高)，则形成的超分子聚集体的尺寸越大：而反离子(阳离子)的尺寸越大而形成的超分子聚集体的尺寸将有所变小。聚钼酸盐大阴离子在形成超分子聚集体的尺寸是受到上述两个影响因素平衡后的结果，或者也可以说，通过使拓扑缺陷能和自身静电能最小化对最后形成的聚集体尺寸进行调节。动态光散射和透射电镜观测结果也进一步证实了反离子对大阴离子形成的囊泡状聚集体的影响：一个是反离子(阳离子)所带的电荷；另外一个是反离子(阳离子)的尺寸大小。这些结果对进一步理解两亲性分子自聚集体系的聚集行为，提供了一种新的聚集模型，而且在纳米科学与技术的研究方面也有非常重要的意义。
聚钼酸盐类无机大分子形成二级有序自聚集体的驱动力是什么?关于这方面的研究，Lehigh大学有研究者认为，导致聚集体形成的驱动力并非是静电力作用，而且聚集体中“一级有序结构”单体之间的距离较大(1～2 nm)，也不存在化学键的作用，氢键也不是促使聚集体形成的主要因素，这种聚集作用应该是一种特殊驱动力的结果，称之为类电荷吸引力(like-charge attraction)，即“一级有序结构”是纳米聚钼酸盐阴离子共享反离子电荷相互吸引而形成稳定的囊泡聚集体，该理论可以说是介于胶体化学中的DLVO理论(Derjaguin-Landau-Verwey-Overbeek)和单个离子能够在溶液中稳定存在的Debye-Hückel理论之间的新观点。也就是说，这种驱动力是一种物理作用，在聚集前后单体自身性质没有改变。
第五章从电化学性质的角度，通过对比{Mo_(154)}和{Mo_(72)Fe_(30)}溶液在形成囊泡状聚集体前后的循环伏安曲线，发现聚集前后其电化学性质没有发生改变，说明无机聚钼酸盐大分子在形成囊泡状聚集体的过程中没有引起单体分子氧化—还原性质的改变，同时从侧面证明了聚钼酸盐在形成聚集体的过程中应该主要是受一种物理作用驱使。对{Mo_(154)}和{Mo_(72)Fe_(30)}聚钼酸盐溶液电化学性质的简单分析也为这类无机聚钼酸盐的物理化学性质及聚集机理的研究提供了一种新的研究手段。
structures (superficially at least, resemble bilayer vesicles formed by surfactants or lipids in solution) with an average, almost monodispersed radius in water of several tens of nanometers, and composed of more than 1000 POMs. The cohesive energy of per bond between {Mo_(72)Fe_(30)} macroanions on the single-layer shells is approximately 6kT which was extracted from analysis based on a charge regulation model. These findings related to the equilibrium controlling for the size of single-layer shells composed of polyoxometalate macroions in dilute solution could certainly be propitious to surfactant systems such as the vesicles, disc-like micelles, etc. In the fourth chapter, small cations (such as Na~+、 K~+、 Ca~(2+)、 Ba~(2+)、 (CH_3)_4N~+、 (C_2H_5)_4N~+ and (G_4H_9)_4N~+) )were introduced to the {Mo_(72)Fe_(30)} aqueous solution. The finally dilute solutions are free-extra-electrolytes, being equal to the solutions obtained from dissolving Na~+-{Mo_(72)Fe_(30)}, K~+-{Mo_(72)Fe_(30)}, (CH_3)_4N~+-{Mo_(72)Fe_(30)}, (C_2H_5)_4N~+-{Mo_(72)Fe_(30)}, (C_4H_9)_4N~+-{Mo_(72)Fe_(30)}, Ca~(2+)-{Mo_(72)Fe_(30)}, and Ba~(2+)-{Mo_(72)Fe_(30)} compounds in water. When the large {Mo_(72)Fe_(30)} anionic clusters and cationic counter-ions form superstructures, the conductivity mainly is contributed from the monomers of {Mo_(72)Fe_(30)} anions and cationic cations in solution. Two factors determine the equilibrium size of shells in our studied systems, the charges and the size of the exchanged cationic counter-ions. The higher charges of cationic counter-ions induce the bigger size of shells, however, large size of cationic counter-ions reduce the size of the shells. The size of the shells is subsequently determined by the balance of the two factors, i.e, by minimizing the energy cost of topological defects and the electrostatic self-energy. For the unique self-assembly process of this polyoxomolybdates, certain questions to be analyzed, for example, the driving forces to overcome the Coulomb repulsion among macroanions and attract them together. Prof. Liu had a particular opinion, the self-assembly of the hydrophilic macroions is not mainly attributed to electrostatic interaction, van der Wals force, or chemical bond interaction (the interanionic distance about 1-2 nm) and also the hydrophobic interaction and the hydrogen bond cannot be dominant; therefore, the self-assembly of the hydrophilic macroions is mainly attributed to the charges on their surfaces. So the like-charge attraction does exist in hydrophilic macroionic solutions, and it determines the association of the polyoxomolybdates. That is to say, the nanoscacle polyoxomolybdate anions ("first organized structures") attract each other by sharing the counterions to form the stable vesicle-like aggregations, which is the novel viewpoint between the DLVO (Derjaguin-Landau-Verwey-Overbeek) theory in colloidal chemistry and the Debye-Huckel theory about the stable ions in solution. With regard to this viewpoint about the driving force, there is still no report on the aggregations of amphiphile surfactants. In the fifth chapter, no changes were not found by contrasting the curves of cyclic voltammograms of the before and after aggregation formation of {Mo_(154)} and {Mo_(72)Fe_(30)} aqueous solution, which indicated that there were no changes of oxidation and reduction in the formation of the aggregation of {Mo_(154)} and {Mo_(72)Fe_(30)}. In another word, these suggested that the vesicle aggregation formation of the polyoxomolybdates is driven by physical forces.
引文
[1] C. W. Scheele. Samtliche Physische und Chemische Werke [M]. Hermbstadt, D. S. F. Ed. Martin Sandig oHG: Niederwalluf/Wiesbaden, 1971, 1: 185 (reprint: original 1793)
[2] T. Liu; E. Diemann; H. Li; A.W.M. Dress; A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003,426: 59-62.
[3] G. Liu; T. Liu. Strong attraction among the fully hydrophilic {Mo_(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc., 2005,127: 6942-6943.
[4] G. Liu; Y. Cai; T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc, 2004,126: 16690-16691.
[5] G. Liu; M. Cons; T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005,118: 27-29.
[6] G. Liu; T. Liu. Thermodynamic properties of the unique self-assembly of {Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions[J]. Lagmuir, 2005,21:2713-2720.
[7] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters [J]. J. Clust. Sci., 2003, 14(3): 215-226.
[8] A. Muller, E. Diemann. The bis(tertrathiotungstato) nickelate(II) ion, a novel complex with WS_4~(2-) ion as a ligand [J]. Chem. Comm., 1971,65-67.
[9] E. Koniger-Ahlborn, A. Muller. Crystalline compound with isolated W_3S_3~(2-) ion: a thio analog of transition metal isopolyanions [J]. Angew. Chem. Int. Ed. Engl. 1975,14:573-574.
[10] D. Rehder, E. T. K. Haupt, H. B8gge, A. Muller. Countercation Transport Modeled by Porous Spherical Molybdenum Oxide Based Nanocapsules [J], Chem. Asian J., 2006,1: 76-81.??High Negative Charge and Cubane-Like Mo_4S_4-Moiety: On the Significance of Cyanothiomolybdates for the Prebiotic Evolution [J]. Angew. Chem. Int. Ed. Engl., 1982,21: 795-796.
[12] A. Muller, W. Hellmann, H. Bogge, R. Jostes, M. Rdmer, U. Schimanski. [Fe_3W_3S_(14)]~(4-), A Novel Hexanuclear, "Pure" Bimetal-Sulfur Cluster with Fe_3(μ_3-S)_2 Center [J]. Angew. Chem. Int. Ed. Engl. 1982,21: 860-861.
[13] A. Muller, M. Romer, H. B6gge, E. Krickemeyer, D. Bergmann. [Cu_6S_(17)]~(2-), a Novel Binary Discrete Polynuclear CuI Complex with Several Interesting Structural Features: The Arrangement of the Metal Atoms and Co-ordination of Ligands [J]. Chem. Comm., 1984, 348-349.
[14] A. Muller, R. Jostes, W. Eltzner, Chong-Shi Nie, E. Diemann, H. Bogge, M. Zimmermann, M. Dartmann, U. Reinsch-Vogell, Shun Che, S. J. Cyvin, B. N. Cyvin. Synthetic, Spectroscopic, X-ray Structural, and Quantum-Chemical Studies of Cyanothiomolybdates with Mo_2S, Mo2S_2, Mo_3S_4, and Mo_4S_4 Cores: A Remarkable Class of Species Existing with Different Electron Populations and Having the Same Central Units as the Ferredoxins [J]. Inorg. Chem., 1985,24:2872-2884.
[15] A. Muller, K. Schmitz, E. Krickemeyer, M. Penk, H. Bogge. [Pd_2S_(28)]~(4-): A 30-Membered Cage Containing an Entrapped Cation [J]", Angew. Chem. Int. Ed. Engl., 1986,25:453-454.
[16] A. Muller, E. Krickemeyer, H. Bogge. Darstellung und Kristall-Struktur von R[ReS_4], R'[ReS_9], (NH_4)_4[Re_4S_(22)] 2H_2O, R'2[Cl_2Fe(MoS_4)FeCl_2]_x[Cl_2Fe(ReS_4)FeCl_2]_(1-x), R_2‘[(ReS_4)Cu_3I_4] und RR_2’[(ReS_4)Cu_5Br_7] (R = NEt_4; R‘ = PPh_4; x = 0,3; 0,5) [J]. Z. anorg. allg. Chem., 1987,554:61-78.
[17] A. Muller, N. H. Schladerbeck, E. Krickemeyer, H. B6gge,.K. Schmitz, E. Bill, A. X.Trautwein. Darstellung von Metall-Schwefel-Clustern durch einfache Reaktion von Metallsalzen mit H_2S: R_2(NH_4)[Cu_3S_(12)], R_2[Cu_4S_(12)] CH_3CN, R_2[Cu_4S_(1.28)], R_2[Fe_2S_2(S_5)_2], R_2[Fe_4S_4Br_4], R_2[Fe_4S_4Br_2Cl_2],??allg. Chem., 1989, 570: 7-36.
[18] A. Muller, E. Krickemeyer, M. Penk, V. Wittneben, J. Doring. [H_6As_(10)Mo_(24)O_(90)]~(8-), a Heteropolyanion Comprising Two Linked Spherical Fragments, and Reduced Keggin Anions as Its Degradation Products [J]. Angew. Chem. Int. Ed. Engl., 1990,29: 88-90.
[19] A. Muller, E. Krickemeyer. Molybdenum-sulfur clusters [M]. In: Inorganic Synthesis, Vol. 27 (Ed.: A. P. Ginsberg), Wiley, New York (1990).
[20] A. Muller, M. Penk, R. Rohlfing, E. Krickemeyer, J. Doring. Topologically Interesting Cages for Negative Ions with Extremely High "Coordination Number": An Unusual Property of V-0 Clusters [J]. Angew. Chem. Int. Ed. Engl. 1990,29:926-927.
[21] A. Muller, R. Rohlfing, J. Doring, M. Penk. Formation of a Cluster Sheath around a Central Cluster by a "Self-Organization Process": the Mixed Valence Polyoxovanadate [V_(34)O_(82)]~(10-)[J]. Angew. Chem. Int. Ed. Engl., 1991, 30: 588-590.
[22] A. Muller, E. Krickemeyer, V. Wittneben, H. Bogge, M. Lemke. (NH_4)_2 [Re_2S_(16)], a Soluble Metal Sulfide with Interesting Electronic Properties and Unusual Reactivity [J]. Angew. Chem. Int. Ed. Engl., 1991,30:1512-1514.
[23] A. Muller, E. Krickemeyer, M. Penk, R. Rohlfing, A. Armatage, H. Bogge. Template-Controlled Formation of Cluster Shells or a Type of Molecular Recognition: Synthesis of [HV_(22)O_(54)(ClO_4)]~(6-) and [H_2V_(18)O_(44)(N_3)]~(5-) [J]. Angew. Chem. Int. Ed. Engl., 1991, 30: 1674-1677.
[24] A. Muller, K. Hovemeier, R. Rohlfing. A Novel Host/Guest System with a Nanometer Large Cavity for Anions and Cations: [2 NH_4~+, 2Cl~- in V_(14)O_(22)(OH)_4(H_2O)_2 (C_6H_5PO_3)-8]~(6-) [J]. Angew. Chem. Int. Ed. Engl., 1992,31: 1192-1195.
[25] A. Muller, R. Rohlfing, E. Krickemeyer, H. Bogge. Control of the Linkage of Inorganic Fragments of V-O Compounds: From Cluster Shells as Carcerands via Cluster Aggregates to Sold-State Structures [J]. Angew. Chem. Int. Ed. Engl., 1993,32:909-912.
[26] A. Muller, V. P. Fedin, E. Diemann, H. B5gge, E. Krickemeyer, D. S61ter, A. M. Giuliani, R. Barbieri, P. Adler. Reductive Addition at the W_3S_4~(4+) Core by Sn~(2+) or an Unusual Supramolecular System: A Synergetic Reaction Leading to the Host Guest Compound (Me_2NH_2)_6[(SCN)_9W_3S-4SnCl_3]0.5H_2O. Inorg. Chem., 1994,33:2243-2247.
[27] A. Muller, E. Krickemeyer, H. Bogge, H. Ratajczak, A. Armatage. A Building Principle of Amorphous Chalcogenides of Transition Metals: The "Extrusion" of the Electron-Rich Cluster [Re_4S_2(SO_2)_4(CN)_(10)]~(8-) from a-Re_2S_7 [J]. Angew. Chem. Int. Ed. Engl., 1994,33:770-773.
[28] A. Muller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bogge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann. [Mo_(57)Fe_6(NO)_6O_(174)(OH)_3(H_2O)_(24)]~(15-): A Highly Symmetrical Giant Cluster with an Unusual Cavity and the Possibility of Positioning Paramagnetic Centers on Extremely Large Cluster Surfaces [J]. Angew. Chem. Int. Ed. Engl., 1994,33: 849-851.
[29] A. Muller. E. Krickemeyer, S. Dillinger, H. Bogge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing. New Perspectives in Polyoxometalate Chemistry by Isolation of Compounds Containing Very Large Moieties as Transferable Building Blocks: (NMe_4)_5[As_2Mo_8V_4AsO_(40)] 3H_2O, (NH_4)_(21)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] ·65H_2O, (NH_2Me_2)_(18)(NH_4)_6[Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] 14H_2O, and (NH_4)_(12)[Mo_(36)(NO)_4O_(108)(H_2O)(16)] · 33H_2O [J]. Z. anorg. allg. Chem., 1994, 620: 599-619.
[30] A. Muller, E. Krickemeyer, J. Meyer, H. Bogge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke. [Mo_(154)(NO)_(14)O_(420)(OH)(28)(H_2O)_(70)]~((25±5)-) : A Water-Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24 000 [J]. Angew. Chem. Int. Ed. Engl., 1995,34:2122-2124.
[31] A. Mttller, K. Hovemeier, E. Krickemeyer, H. Bogge. Modelling the Remote-Controlled Organization of Particles in a Nanodimensional Cavity: Synthesis and Properties of (Et_3NH)_3(tBuNH_3)_2Na_2[(H_2O)_2, N~(3-) in??V_(14)O_(22)(OH)_4(PhPO_3)_8] ·6H_2O ·2 DMF [J]. Angew. Chem. Int. Ed. Engl., 1995, 34: 779-781.
[32] A. Muller, J. Meyer, E. Krickemeyer, E. Diemann, Molybdenum Blue: A 200 Year Old Mystery Unveiled [J]. Angew. Chem. Int. Ed. Engl., 1996, 35: 1206-1208.
[33] A. Muller, K. U. Johannes, W. Plass, H. Bogge, E. Krahn, K. Schneider. Uber grunes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ahnliche Ni~(II)-Komplexe [J]. Z. anorg. allg. Chem., 1996,622: 1765-1772.
[34] A. Mailer, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer. An Unusual Polyoxomolybdate: Giant Wheels Linked to Chains [J]. Angew. Chem. Int. Ed. Engl., 1997,36:483-486.
[35] A. Muller, R. Sessoli, E. Krickemeyer, H. Bogge, J. Meyer, D. Gatteschi, L. Pardi, J. Westphal, K. Hovemeier, R. Rohlfing, J. Doring, F. Hellweg, C. Beugholt, M. Schmidtmann. Polyoxovanadates: High-Nuclearity Spin Clusters with Interesting Host-Guest Systems and Different Electron Populations. Synthesis, Spin Organization, Magnetochemistry, and Spectroscopic Studies [J]. Inorg. Chem. 1997,36: 5239-5250.
[36] A. Muller, E. Krickemeyer, H. B6gge, M. Schmidtmann, C. Beugholt, P. Kogerler, C. Lu. Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO_3)_(176)(H_2O)_(80)H_(32)] [J]. Angew. Chem. Int. Ed. Engl., 1998,37:1220-1223.
[37] A. Muller, J. Meyer, E. Krickemeyer, C. Beugholt, H. BSgge, F. Peters, M. Schmidtmann, P. KSgerler, M. J. Koop. Unusual Stepwise Assembly and Molecular Growth: [H_(140MO_(37)O_(112)]~(14-) and [H_3Mo_(57)V_6(NO)-6O_(189)(H_2O)_(12)(MoO)_6]~(21-)[J]. Chem. Europ. J., 1998, 4: 1000-1006.
[38] A. Muller, A. Hildebrand, E. Krickemeyer, M. I. Khan, M. Penk, H. Bogge, F. Secheresse. Generating Structural Motifs between Three-Dimensional Solids and Discrete Species Based on the {CuNCS} Unit: (PPh_4)[(ReS_4)Cu_2(NCS)_2］1998,4:1932-1937.
[39] A. Muller, J. Meyer, H. Bogge, A. Stammler, A. Botar. Trinuclear Fragments as Nucleation Centres: New Polyoxoalkoxyvanadates by (Induced) Self-Assembly [J]. Chem. Europ. J., 1998,4: 1388-1397.
[40] A. Muller, M. Koop, H. Bogge, M. Schmidtmann, C. Beugholt. Exchanged ligands on the surface of a giant cluster: [(MoO_3)_(176)(H_2O)_(63)(CH_3OH)_(17)H_n]~(32-n) [J]. Chem. Comm., 1998, 1501-1502.
[41] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[42] A. Miiller, S. Q. N. Shah, H. Bogge, M. Schmidtmann. Molecular growth from a Mo_(176) to a Mo_(248) cluster [J]. Nature, 1999,397: 48-50.
[43] A. Muller, E. Krickemeyer, H. B6gge, M. Schmidtmann, C. Beugholt, S. K. Das, F. Peters. Giant Ring-Shaped Building Blocks Linked to Form a Layered Cluster Network with Nanosized Channels: [Mo~(VI)_(124)Mo~V_(28)O_(429)(μ_3-O)_(28)H_(14)(H_2O)_(66.5)]~(16-) [J]. Chem. Eur. J., 1999, 5: 1496-1502.
[44] A. Muller, V. P. Fedin, C. Kuhlmann, H. B6gge, M. Schmidtmann. A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H_2O)_n in Mo~(VI)_(72)Mo~V_(60)O_(372)(HCO_2)_(30)(H_2O)_(72)]~(42-) [J]. Chem. Comm., 1999,927-928.
[45] A. Muller, S. K. Das, H. Bogge, C. Beugholt, M. Schmidtmann. Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites: Na_(21)[Mo~(VI)_(126)Mo~V_(28)O_(462)H_(14)(H_2O)_(54)(H_2PO_2)_7]_xH_2O (x≈300 [J]. Chem. Comm., 1999,1035-1036.
[46] A. Miiller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized
??Ring-Shaped Anions:400 H_2O and Na_(22)[Mo~(VI)_(118)Mo~V_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. Anorg. Allg. Chem., 1999, 625: 1187-1192.
[47] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl. 1999, 38: 3238-3241.
[48] A. Muller, S. Polarz, S. K. Das, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Hauptfleisch. "Open and Shut" for Guests in Molybdenum-Oxide-Based Giant Spheres, Baskets, and Rings Containing the Pentagon as a Common Structural Element [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3241-3245.
[49] A. Muller, V. P. Fedin, C. Kuhlmann, H.-D. Fenske, G. Baum, H. Bogge, B. Hauptfleisch. "Adding" stable functional complementary, nucleophilic and electrophilic clusters: a synthetic route to [{(SiW_(11)O_(39)) Mo_3S_4(H_2O)_3(μ-OH)}_2]~(10-) and [{(P_2W_(17)O_(61))Mo_3S_4(H_2O)_3(μ-OH)}_2]~(14-) as examples [J]. Chem. Comm., 1999, 1189-1190.
[50] A. Muller, M. Koop, H. Bogge, M. Schmidtmann, F. Peters, P. Kogerler, Chem. Comm. Building blocks as disposition in solution: [{Mo~(VI)O_3(H_2O)}_(10){V~(IV)O(H_2O)}_(20){(Mo~(VI)/Mo~(VI)_5O_(21))(H_2O)_3}_(10)({Mo~(VI)O_2(H_2O) _2)_(5/2))_2 ({NaSO_4}_5)_2]~(20-) a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry [J]. 1999, 1885-1886.
[51] A. Miiller, C. Beugholt, M. Koop, S. K. Das, M. Schmidtmann, H. Bogge. Facile and Optimized Syntheses and Structures of Crystalline Molybdenum Blue Compounds Including one with an Interesting High Degree of Defects: Na_(26)[Mo_(142)O_(432)(H_2O)_(58)H_(14)] ca. 300 H_2O and Na_(16)[(MoO_3)_(176)(H_2O)_(63) (CH_3OH)_(17)H_(16)] ca. 600 H_2O 6 CH_3OH [J]. Z. anorg. allg. Chem., 1999, 625: 1960-1962.
[52] V. Bereau, E. Cadot, H. Bogge, A. Muller, F. Secheresse. Addition of {M_2S_2O_2}~(2+) , M = Mo, W, to A-a-[PW_9O_(34)]~(9-) . Synthesis and Structural Characterizations in the Solid State and in Solution [J]. Inorg. Chem., 1999, 38: 5803-5808.
[53] A. Muller, S. Q. N. Shah, H. Bogge, M. Schmidtmann, P. Kogerler, B. Hauptfleisch, S. Leiding, K. Wittier. 30 Electrons "Trapped" in a Spherical Matrix: A Molybdenum Oxide-Based Nanostructured Keplerate Reduced by 36 Electrons [J]. Angew. Chem. Int. Ed. Engl., 2000, 39: 1614-1616.
[54] A. Muller, E. Krickemeyer, S. K. Das, S. Sarkar, H. Bogge, M. Schmidtmann, P. Kogerler, Sh. Sarkar. Linking Icosahedral, Strong Molecular Magnets {Mo~(VI)Fe~(III)_(30)} to Layers - A Solid-State Reaction at Room Temperature [J]. Angew. Chem. Int. Ed. Engl., 2000,39:1612-1614.
[55] A. Miiller, C. Beugholt, H. Bogge, M. Schmidtmann. Influencing the Size of Giant Rings by Manipulating their Curvatures:Na_6[Mo_(120)O_(366)(H_2O)_(48)H_(12){Pr(H_2O)_5}_6] ca. 200 H_2O with Open Shell Metal Centers at the Cluster Surface [J]. Inorg. Chem., 2000, 39: 3112-3113.
[56] A. Muller, S. K. Das, H. Bogge, M. Schmidtmann, P. Kogerler, A. X. Trautwein, V. Schunemann, E. Krickemeyer, W. Preetz, H. U., Gudel. A New Type of Supramolecular Compound: Molybdenum-Oxide-Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a Two-Dimensional Network [J]. Angew. Chem. Int. Ed., 2000,39: 3413-3417.
[57] A. Muller, C. Kuhlmann, H. Bogge, M. Schmidtmann, M. Baumann, E. Krickemeyer. Mo~V_2O_4~(2+) Directs the Formation and Subsequent Linking of Potential Building Blocks under Different Boundary Conditions: A Related Set of Novel Cyclic Polyoxomolybdates [J]. Eur. J. Inorg. Chem., 2001, 2271-2277.
[58] A. Miiller, S. K. Das, C. Kuhlmann, H. B6gge, M. Schmidtmann, E. Diemann, E. Krickemeyer, J. Hormes, H. Modrow, M. Schindler. On the option of generating novel type surfaces with multiphilic ligands wihtin the??cavity of a giant metal-oxide based wheel type cluster: chemical reactions with well-defined nanoobjects [J]. Chem. Comm. 2001, 655-656.
[59] A. Muller, S. K. Das, H. B8gge, M. Schmidtmann. Generation of cluster capsules (I_h) from decomposition products of a smaller cluster (Keggin - T_d) while surviving ones get encapsulated: species with core-shell topology formed by a fundamental symmetry-driven reaction [J]. A. Botar, Chem. Comm., 2001,657-658.
[60] A. Miiller, R. Maiti, M. Schmidtmann, H. Bogge, S. K. Das, W. Zhang. Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster [J]. Chem. Comm. 2001, 2126-2127.
[61] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, P. Kogerler, C. Rosu, E. Beckmann. "Nanoobjects" by Self-Assembly Concomitant with Modifications under Alterable Boundary Conditions: Incorporation of Paramagnetic Metal Centers (Cu~(2+)) in Ring-Shaped Molybdenum-Oxide Based Clusters [J]. Angew. Chem. Int. Ed., 2001, 40: 4034-4037.
[62] A. Miiller, E. Beckmann, H. B6gge, M. Schmidtmann, A. Dress. Inorganic Chemistry Goes Protein Size: A Mo_(368) Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int. Ed., 2002,41: 1162-1167.
[63] A. Muller, B. Botar, S. K. Das, H. Bogge, M. Schmidtmann, A. Merca. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron, 2004, 23: 2381-2385.
[64] A. Muller, E. Diemann, S. Q. N. Shah, C. Kuhlmann, M. C. Letzel. Soccer-playing metal oxide giant spheres: a first step towards patterning structurally well defined nano-object collectives [J]. Chem. Comm., 2002, 440-441.
[65] A. Muller, S. K. Das, M. Talismanova, H. Bogge, P. K6gerler, M. Schmidtmann, S. Talismanov, M. Luban, E. Krickemeyer. Paramagnetic??Keplerate "Necklaces" Synthesized by a Novel Room-Temperature Solid-State Reaction: Controlled Linking of Metal-Oxide-Based Nanoparticles [J]. Angew. Chem. Int. Ed. 2002,41: 579-582.
[66] A. Muller, S. Roy, M. Schmidtmann, H. Bogge. Urea as "deus ex machine" in giant molybdenum blue type cluster synthesis: an unusual hybrid compound with perspectives for related nano, supramolecular and extended structures [J]. Chem. Comm., 2002,2000-2002.
[67] L. Cronin, C. Beugholt, E. Krickemeyer, M. Schmidtmann, H. B5gge, P. K6gerler, T. K. K. Luong, A. Muller. "Molecular Symmetry Breakers" Generating Metal-Oxide-Based Nanoobject Fragments as Synthons for Complex Structures: [{Mo_(128)Eu_4O_(388)H_(10)(H_2O)_(81)}_2]~(20-), a Giant-Cluster Dimer [J]. Angew. Chem. Int. Ed., 2002,41:2805-2808.
[68] A. Miiller, E. Krickemeyer, H. Bogge, M. Schmidtmann, S. Roy, A. Berkle. Changeable Pore Sizes Allowing Effective and Specific Recognition by a Molybdenum-Oxide Based "Nanosponge": En Route to Sphere-Surface and Nanoporous-Cluster Chemistry [J]. Angew. Chem. Int. Ed., 2002, 41: 3604-3609.
[69] A. Muller, B. Botar, P. Kogerler, A. Berkle. A potassium selective "nanosponge" with well defined pores [J]. Chem. Comm., 2002, 2944-2945.
[70] L. Cronin, E. Diemann, A. Muller. Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls [M]. In: Inorganic Experiments (Ed.: J. D. Woollins), Wiley-VCH, Weinheim, 2003,340-346.
[71] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Botar, M. O. Talismanova. Drawing Samll Cations into Highly Charged Porous Nanocontainers Reveals "Water" Assembly and Related Interaction Problems [J]. Angew. Chem. Int. Ed., 2003,42: 2085-2090.
[72] A. Muller, L. Toma, H. Bogge, M. Schmidtmann, P. Kogerler. Synergetic activation of "silent receptor" sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K~+ and SO_4~(2-) ions into a molybdenum oxide-based nanoobject [J]. Chem. Comm., 2003,??2000-2001.
[73] A. Muller, S. K. Das, S. Talismanov, S. Roy, E. Beckmann, H. Bogge, M. Schmidtmann, A. Merca, A. Berkle, Y. Zhou, L. Zhang. Trapping Cations in Specific Positions in Tuneable 'Artificial Cell' Channels: New Nanochemistry Perspectives [J]. Angew. Chem. Int. Ed., 2003, 42: 5039-5044.
[74] A. Muller, S. K. Das, E. Krickemeyer, C. Kuhlmann. Polyoxomolybdate Clusters: Giant Wheels and Balls [J]. Inorganic Syntheses 34 (Ed.: J. R. Shapley), Wiley, New York, 2004,191-200.
[75] A. Muller, Y. Zhou, L. Zhang, H. Bogge, M. Schmidtmann, M. Dressel, J. van Slageren. En route to coordination chemistry under confined conditions in a porous capsule: Pr~(3+) with different coordination shells [J]. Chem. Comm., 2004,2038-2039.
[76] A. Muller, S. K. Das, P. Kogerler, H. Bogge, M. Schmidtmann, A. X. Trautwein, V. Schunemann, E. Krickemeyer, W. Preetz. A New Type of Supramolecular Compound: Molybdenum-Oxide-Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a Two-Dimensional Network [J]. Angew. Chem. Int. Ed., 2000, 39: 3413-3417.
[77] A. Mttller, H. Reuter, S. Dillinger. Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts [J]. Angew. Chem. Int. Ed. Engl., 1995,34:2328-2361.
[78] A. Muller, F. Peters, MT Pope, D. Gatteschi. Polyoxometalates: Very Large Strucrures-Nanoscale Magnets[J]. Chem. Rev., 1998, 98: 239-271.
[79] A. Muller, P. K6gerler. From Simple Building Blocks to Structures with Increasing Size and Complexity [J]. Coord. Chem. Rev., 1999,182: 3-17.
[80] A. Muller, P. Kogerler, C. Kuhlmann. A Variety of Combinatorially Linkable Units as Disposition: From a Giant Icosahedral Keplerate to Multi-Oxide Based Network Structures [J]. J. Chem. Soc, 1999; 1347-1358.
[81] J. Fielden , L. Cronin, C. Beugholt and A. Muller. Towards the Construction??of Mesoscopic Species with Emergent and Functional Properties via the Derivatisation of Molybdenum-Oxide 'Giant-Wheel' Cluster [J]. J. Mol. Struct. (Theochem), 2000,500:181-193.
[82] A. Muller, P. KOgerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology:'From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001,222:193-218.
[83] P. Kdgerler, A. Muller. Chemistry with Nanoparticles: Linking of Ring-and Ball- Shaped Species [M]. In: "Polyoxometalate Chemistry for Nano-Composite Design", (Eds. T. Yamase, M. T. Pope). Kluwer, New York, 2002,pp.1-15.
[84] A. Muller, S. Roy. En Route From the Mystery of Molybdenum Blue via Related Manipulatable Building Bolcks to Aspects of Materials Science [J]. Coord. Chem. Rev., 2003,245:153-166.
[85] C. N. R. Rao, A. Mttller, A. K. Cheetham. Nanomaterials-An Introduction [M]. In "The Chemistry of Nanomaterials: Synthesis, Properties and Applications", Vol. I (Eds. C. N. R. Rao, A. Muller, A. K. Cheetham). Wiley-VCH, Weinheim, 2004,1-11.
[86] M.T. Pope, A. Mttller. Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines [J]. Angew. Chem. Int. Ed. Engl., 1991,30: 34-48.
[87] M.I. Khan, A. Mttller, S. Dillinger, H. Bogge, Q. Chen, J. Zubieta. Cation Inclusion within the Mixed-Valence Polyanion Cluster [(Mo~(VI)O_3)_4Mo~V_(12)O_(28)(OH)_(12)]~(8-): Syntheses and Structures of (NH_4)_7[NaMo_(16)(OH)_(12)O_(40)] 4H_2O and (Me_2NH_2)_6[H-2Mo_(16)(OH)_(12)O_(40)] [J]. Angew. Chem. Int. Ed., 1993,32:1780-1781.
[88] A. Muller, S. Dillinger, E. Krickemeyer, H. Bogge, W. Plass, A. Stammler, R.C. Haushalter. [H_2 in (Mo~V_2O_4)_6O_4(μ_2-OH)_(12)(Mo~(VI)O_3_4]~(6-) and [Na in {(Mo~V_2O_4)_3(μ_2-OH)_3H(PhPO_3)_4}_2]~(7-): A Further Example for the Validity of the Concept of Unit Construction in Polyoxometalate Chemistry [J]. Z. Naturforsch. B, 1997,52:1301-1302.
[89] P. Mialane, A. Dolbecq, L. Lisnard, A. Mallard, J. Marrot, F. Secheresse. [3-PMo_(12)O_(36)(OH)_4-{La(H_2O)_4}_4]~(5+): The First 3-PMo_(12)O_(40) Keggin ion and its association with the two-electron-reduced 3-PMo_(12)O_(40) Isomer [J]. Angew. Chem. Int. Ed., 2002,41:2398-2401.
[90] A. Muller, M. C. R. Henry. Nanocapsule Water-based Chemistry [J]. Compt. Rend. Chim., 2003,6:1201-1208.
[91] A. Muller, S. K. Das, E. Krichemeyer, P. Kogerler, H. Bogge, M. Schmidtmann. Cross-linking nanostructured spherical capsules as building units by crystal engineering: related chemistry [J]. Solid state Science, 2000, 2: 847-854.
[92] F. Al-Ali, A. Brun, F. Rodrigues, G. Etemad-Moghadam, I. Rico-Lattes. New Catanionic Amphiphiles Derived from the Associative Systems (α. -Hydroxyalkyl)-phosphinic or ( α -Hydroxyalkyl)-phosphonic Acid/Cetyltrimethylammonium Hydroxide. Preparation, Characterization, and Self-Organization Properties [J]. Langmuir, 2003,19:6678-6684.
[93] A. Meister, M. Dubois, L. Belloni, T. Zemb. Equation of State of Self-Assembled Disklike and Icosahedral Crystallites in the Dilute range [J]. Langmuir, 2003,19: 7259-7263.
[94] H.Q. Yin, M. Mao, J.B. Huang, H.L. Fu. Two-Phase Region in the DTAB/SL mixed Surfactant System [J]. Langmuir, 2002,18: 9198-9203.
[95] R. Beck, Y. Abe, T. Terabayashi, H. Hoffmann. A Novel L3-Phase from a Ca-Salt of an Anionic Surfactant and a Cosurfactant [J]. J. Phys. Chem. B, 2002,106: 3335-3338.
[96] A. Zapf, U. Homfeck, G Platz, H. Hoffmann. Investigation of the L3 Phase in Systems Containing Calcium Dodecyl Sulfate, Alcohol, and Water [J]. Langmuir, 2001,17:6113-6118.
[97] A. Zapf, R. Beck, G Platz, H. Hoffmann, "Calcium Surfactant: A Review [J]", Advances in Colloid and Interface Science, 2003,100 -102:349-380.
[98] J. L. Anderson, V. Pino, E. C. Hagberg, V. V. Sheares, D. W. Armstrong. Surfactatn Solvation Effects and Miccelle Formation in Ionic Liquids [J]. ??Chem. Comm., 2003,2444-2445.
[99] T. Nakashima, N. Kimizuka. Vesicles in Salt: Formation of Bilayer Membranes from Dialkyldimethylammonium. Bromides in Ether-containing Ionic Liquids. Chem. Lett., 2002,10:1018-1019.
[100] D.C. Steytler, E. Rumsey, M. Thorpe, J. Eastoe, R.K. Heenan. Phosphate Surfactants for Water-in-CO_2 Microemulsions. Langmuir, 2001, 17: 7948-7950.
[101] D.A. Canelas, D.E. Berts, J.M. Desimone. Dispersion polymerization of styrene in supercritical carbon-dioxide-importance of effective surfactants [J]. Macromolecules, 1996,29:2818-2821.
[102] J. Hao. Microemulsion polymerization of acrylamide and styrene: effect of the structures of reaction media [J]. J. Polym. Sci. Part A: Polym. Chem., 2001,39:3220-3234.
[103] H. Klaus, H. Hoffmann, J. Hao. Classic La-phases as opposed to vesicle phases in cationic-anionic surfactant mixtures [J]. J. Phys. Chem. B., 2000, 104:2781-2784.
[104] J. Hao. Effect of the structures of microemulsions on chemical reactions [J]. Colloid. Poly. Sci., 2000,278:150-154.
[105] J. Hao. Studies on chemical reactions in microemulsion media (I) hydrolysis kinetics studies in microemulsion system for CTAB/n-butano/25% n-octane/water [J]. J. Dispersion Sci. Tech., 2000,21(1): 19-30.
[106] J. Hao, J. Hu, S. Shang, H. Liu. C NMR and ESR studies on the association between sodium 3-dodecylether-2-hydroxyproply-l-sulfonate and polyvinyl-pyn-olidone [J]. J. Dispersion Sci. Tech., 1999,20(5): 1345-1357.
[107] J. Hao, W. Liu, G. Xu, L. Zheng. Vesicles from salt-free cationic-anionic surfactant solutions [J]. Langmuir, 2003,19: 10635-10640. .
[108] J. Hao, Z. Yuan, W. Liu, H. Hoffmann. In Situ Vesicle Formation by a Kinetic Reaction in Aqueous Mixtures of Single-Tailed Catanionic Surfactants [J]. J. Phys. Chem. B., 2004,108: 5105-5112.
[109] A. Song, S. Dong, X. Jia, J. Hao, W. Liu, T. Liu. An Onion Phase in Salt-Free??Zero-Charged Catanionic Surfactatn Solutions [J]. Angew. Chem. Int. Ed., 2005,44:4018-4021.
[110] J. Hao, A. Song, J. Wang, X. Chen. W. Zhuang. F. Shi, F. Zhou, W. Liu. Self-assembled structure in room-temperature ionic liquids [J]. J. Phys. Chem. B, 2005,109(22): 11126-11134.
[111] A. Song, X. Jia, M. Tehg, J. Hao. Ca~(2+)-and Ba~(2+)-ligand coordinated unilamellar, multilamellar, and oligovesicular vesicles [J]. Chem. Eur. J., 2007,13:496-501.
[112] J. Hao, J. Wang, W. Liu, H. Hoffmann. Zn~(2+)-induced vesicle formation. J. Phys. Chem. B, 2004,108(4): 5105-5112.
[113] J. Wang, A. Song, X. Jia, J. Hao, W. Liu, H. Hoffmann. Two route to vesicle formation: Metal-ligand complexation and ionic interactions [J]. J. Phys. Chem. B., 2005,109: 11126-11134.
[114] M. Winterhalter, W. Helfrich. Bending elasticity of electrically charged bilayers: coupled monolayers, neutral surfaces, and balancing stresses [J]. J. Phys. Chem., 1992,96: 327-330.
[115] F. A. M. Leermakers, J. M. H. M. Scheutjens. Statistical thermodynamics of association colloids, 2, Lipid vesicles [J]. J. Phys. Chem., 1989, 93: 7417-7426.
[116] S. A. Safran, P. A. Pincus, D. A. Andelman. Stability and phase behavior of mixed surfactant vesicles [J]. Science, 1990,248: 354-356.
[117] T. Liu. Supramolecular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124: 10942-10943.
[118] A. Mtuller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant" molecular wheels [J]. Chem. Commun., 2001:1928-1929.
[119] Rounding Up Nanoclusters-Nanotechnology. Materialstoday, 2004,7(1): 10.
[120] M. T. Pone and A. Muller. polvoxometalates: From Diatonic solids to antiretroviral activity [M]. Kluwer Dordrecht, The Netherlands, 1994.78.
[121] I. V. Kozhevnikov. Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions [J]. Chem, Rev., 1998, 98: 171-198.
[122] N. Mizuno, M. Misono. Heterogeneous Catalysis [J]. Chem. Rev., 1998, 98: 199--217.
[123] I. A. Weinstock. Homogeneous-Phase Electron-Transfer Reactions of Polyoxometalates [J]. Chem. Rev., 1998,98: 113-170.
[124] M. Sadakane, E. Steckhan. Electrochemical Properties of Polyoxometalates as Electrocatalysis [J], Chem. Rev., 1998,98:219-237.
[125] T. Yamase. Photo-and Electrochromism of Polyoxometalates and Related Materials [J]. Chem. Rev., 1998,98: 307-325.
[126] J. T. Rhule, C. L. Hill, D. A. Judd, R. F. Schinazi. Polyoxometalates in Medicine [J]. Chem. Rev., 1998,98: 327-357.
[127] D. E. Katsoulis. A survey of applications of polyoxometalates [J]. Chem. Rev., 1998,98:359-387.
[128] J. H. Fendler. Nanoparticles and nanostructured films: preparation, characterization, and applications [M]. Wiley-VCH, Weinheim, 1998,56-89.
[129] M. Clemente-leon, C. Mingotaud, B. Agricole, C. J. Gomez- Barcia, E. Coronado, P. Delhaes. Application of the Langmuir-Blodget technique to polyoxometalates: towards new magnetic films [J]. Angew, Chem. Int. Ed. Engl., 1997,36:1114-1116.
[130] C. G. Janauer, A. Dobley, J.D. Guo, P. Zavalij, M. S. Whittingham. Novel Tungsten, Molybdenum, and Vanadium Oxides Containing Surfactant Ions [J]. Chem. Mater., 1996,8:2096-2101.
[131] A. Stein, M. Fendorf, T. P. Jarvie, K.T. Muller, A. J. Tenesi, T. E. Mallouk. Salt-Gel Synthesis of Porous Transition-Metal Oxides [J]. Chem. Mater., 1995,7:304-313.
[132] D. G. Kurth, P. Lehmann, D. Volkmer, H. Co1fen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters (SECs): ??385-393.
[133] P. M. Harrison, P. Arosio. The Ferritins: Molecular Properties, Iron Storage Function and Cellular, Regulation [J]. Biochim, Biophys. Acta -Bioenergetics, 1996,1275:161-203.
[134] A. M. Donald, A. H. Windle. Liquid Crystalline Polymers [M]. Vol. 1 Cambridge University Press, Cambridge, 1992,18-32.
[135] P. G. de Gennes, J. Prost. The physics of Liquid Crystals [M]. Oxford University Press, Oxford, 1995.
[136] J. N. Murrel, A. D. Jenkins. Properties of Liquids and Solutions, 2nd ed. [M]. Wiley, New York, NY, 1993,215-236.
[137]赵国玺，朱步瑶．表面活性剂作用原理[M]．中国轻工业出版社，2003， 267-279.
[138] V. Luzzati, H. Mustacchi, A. Skoulios. The structures of the liquid-crystal phases of some soap and water systems [J]. Discuss. Faraday Soc, 1958, 25: 43-50.
[139] F. B. Rosevear. reaction of alkyl iodides with aryliodoso derivatives [J]. J. Am. Oil Chem. Soc, 1954, 31: 628-639.
[140] J. M. Corkill, J. F. Goodman, T. Walker, J. Wyer. The multiple equilibrium model of micelle formation [J]. Proc. Roy. Soc. 1969, A 312: 243-255.
[141] P. Ekwall. Advances Liquid Crystals [M]. Brown G H. ed. Vol 3 New York: Acdemic press, 1978.41.
[142] K. Fontell, K. K. Fox, E. Hansson. On the structures of the cubic phase 1L in some lipid-water systems [J]. Mol. Cryst. Liquid, Cryst. Lett., 1985,1: 9-17.
[143] V. Luzzati. Biological Membranes [M]. D. Chapman, ed. New York: Academic Press, 1986. Ch 3.
[144] K. Fontell. Cubic phases in surfactant and surfactant-like lipid systems [M]. Colloid Polym. Sci., 1990,268:264-285.
[145] J. P. Gabriel, P. Davidson. New trends in colloidal liquid crystals based on mineral moieties m Adv Mater 2000 12:9-20 .
[146] A. S. Sonin. Introduction to physics of liquid crystals [J]. Colloid, J., 1998,
??60:129-151.
[147] J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenker. A new family of mesoporous molecular sieves prepared with liquid crystal templates [J]. J. Am.' Chem. Soc, 1992, 114: 10834-10843.
[148] D. M. Antonelli, M. Trudeau. Phase changes and electronic properties in toroidal mesoporous molybdenum oxides [J]. Angew. Chem. 1999, 111: 1555-1559. Angew. Chem. Int. Ed., 1999,38:1471-1475.
[149] S. Polarz, B. Smarsly, M. Antonietti. Colloidal organization and clusters: self-assembly of polyoxometalate-surfactant complexes towards three-dimensional organized structures [J]. ChemPhysChem, 2001, 7: 457-461.
[150] M. Antonietti, S. Henke, A. Thunemann. Highly ordered, mesomorphosus materials with ultra-low surface energies: polyelectrolyte-surfactant complexes with fluorinated surfaces [J]. Adv. Mater., 1996,8: 41-45.
[151] M. Antonietti, C. Burger, A. Th u nemann. Polyelectrolyte-surfactant complexes: a new class of highly ordered polymer materials [J], TRIP, 1997, 5:262-267.
[152] M. Antonietti, C. Burger, A. Thunemann. Polyelectrolyte-liquid complexes as membrane mimetic systems [J]. Curr. Opin. Colloid Interf. Sci., 1996, 1: 667-671.
[153] S. Polarz, B. Smarsly, C. Goltner, M. Antonietti. The interplay of colloidal organization and oxo-cluster chemistry: polyoxometalate-silica hybrids-materials with a nanochemical function [J]. Adv. Mater., 2000, 12:1503-1507.
[154] S. S. Kim, W. Z. Zhang, T. J. Pinnavaia. Ultralstable mesostructured silica vesicles [J]. Science, 1998,282:1302-1305.
[155] D. H. W. Hubert M. June. P. M. Frederik. P. H. H, Bomans. J. Meuldiik. A. L.German. Vesicle-directed growth of silica [J]. Adv. Mater., 2000, 12:??1286-1290.
[156] D. H. W. Hubert, M. Jung, A. L. German. Vesicle templating [J]. Adv. Mater, 2000,12:1291-1294.
[157] S. Chiruvolu, S. Walker, J. Israelachvili, F. -J. Schmitt, D. Leckband, J. A. Zasadzinski. Higher order self assembly of vesicles by site specific binding [J]. Science, 1994,264 : 1753-1756.
[158] S. A. Walker, M. T. Kennedy, J. A. Zasadzinski. Encapsulation of bilayer vesicles by self-assembly [J]. Nature, 1997,387: 61-64.
[159] Y. Jin, L. Bi, Y. Shao, S. Dong. Bobust core-shell supramolecular assemblies based on cationic vesicles and ring-shaped {Mo_(154)} polyoxomolybdate nanoclusters: template-directed synthesis and characterizations [J]. Chem. Eur. J., 2004,10:3225-3231.
[1] C. W. Scheele, Samtliche Physische und Chemische Werke [M]. Hermbstadt, D. S. F. Ed. Martin Sandig oHG: Niederwalluf/Wiesbaden, 1971, 1: 185 (reprint: original 1793).
[2] Berzelius, J. J. Beitrag zur naheren Kenntniss des Molybdans. Poggend. Ann. Phys. Chem. 1826,6: 369-392.
[3] A. Muller, S. K. Das, E. Krickemeyer, C. Kuhlmann, Polyoxomolybdate Clusters: Giant Wheels and Balls [M], J. Shapley (Ed.), Wiley, New York Inorg. Synth. 2004,34: 191-200.
[4] L. Cronin, E. Diemann, A. Muller, Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls in Inorganic Experiments [M], J.D. Woollins (Ed), Wiley-VCH Weinheim, 2003,340-346.
[5] A. Muller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. B6gge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na_(15)[Mo_(154)~(VI)Mo_(28)~VO_(426)H_(14)(H_2O)_(70)]_(0.5)[Mo_(124)~(VI)Mo_(28)~VO_(457)H_(14)(H_2O)_(68)]_(0.5).ca.400H_2O and Na_(22)[Mo_(118)~(VI)Mo~(28)~VO_(442)H_(14)(H_2O)_(58)]-ca.250H_2O [J]. Z. Anorg. Allg. Chem. 1999,625:1187-1192.
[6] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. B5gge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[7] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew.Chem.Int.Ed., 1998,37: 3359-3363.
[8] A. Muller, B. Botar, S. K. Das, H. Bogge, M. Schmidtmann, A. Merca. On the??complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron 2004,23:2381-2385.
[9] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters. J. Clust. Sci., 2003, 14(3): 215-226.
[10] A. Muller, P. Kdgerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev. 2001,222:193-218.
[1] A. Muller, P. Kogerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001,222: 193-218.
[2] A. Miiller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions:Na_(15)[Mo~(VI)_(126)Mo~V_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5)[Mo~(VI)_(124)Mo~V_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5) ca.400 H_2O and Na_(22)[Mo~(VI)_(118)Mo~V_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. anorg.allg. Chem., 1999,625: 1187-1192.
[3] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters.Organizational Forms of Matter: An Inorganic Super Fullerene and KeplerateBased on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37:3359-3363.
[4] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh.Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann.Archimedean Synthesis and Magic Numbers: "Sizing" GiantMolybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J].Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[5] T. Liu; E. Diemann, H. Li, A.W.M. Dres, A. Miiller. Self-assembly in aqueoussolution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003,426: 59-62.
[6] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A.Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant"molecular wheels [J]. Chem. Commun., 2001: 1928-1929.
[7] T. Liu. Supramolecular structures of polyoxomolybdate-based GiantMolecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124:10942-10943.
[8] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc, 2003, 125: 312-313.
[9] T. Liu. Surfactant-Induced Trans-Interface Transportation and Complex Formation of Giant Polyoxomolybdate-Based Clusters [J]. J. Clust. Sci., 2003, 14:215-226.
[10] S. Polarz, B. Smarsly, M. Antonietti. Colloidal Organization and Clusters: Self-Assembly of Polyoxometalate-Surfactant Complexes towards Three-Dimensional Organized Structures [J]. ChemPhyChem., 2001, 7: 457-461.
[11] D. G Kruth, P. Lehmann, D. Volkmer, A. Muller, D. Schwahn. Biologically inspired polyoxometalate-surfactant composite materials. Investigations on the structures of discrete, surfactant-encapsulated clusters, monolayers, and Langmuir-Blodgett films of (DODA)_(40)(NH_4)_2[(H_2O)n in Mo_(132)O_(372)(CH_3CO_2)_(30)(H_2O)_(72)] [J]. J. Chem. Soc. Dalton Trans., 2000, 21: 3989-3998.
[12] D. G Kurth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters(SECs):(DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] [J]. Chem. Eur. J., 2000, 6: 385-393.
[13] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G Kruth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Krebs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme [J]. J. Am. Chem. Soc, 2002,124(35): 10489-10496.
[14] Z. Persin, K. Stana-Kleinschek, T. Kreze. Hydrophilic/Hydrophobic Characteristics of Different Cellulose Fibres Monitored by Tensiometry [J]. Croat. Chem. Acta., 2002, 75: 271-280.
[15]庄国波， 徐为勃．表面张力测定的几张方法[J]．江苏广播电视大学学报， 1994，4：60-63．
[16]赵国玺，朱步瑶．表面活性剂作用原理[M]．中国轻工业出版社，2003，, 2003, 94-105.
[17] D. G. Kruth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. D. Chesne. Surfactant-Encapsulated Clusters (SECs): (DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(83)(H_2O)_(18)], a Case Study. Chem. Eur. J., 2000,6:385-393.
[18] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G. Kurth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Kerbs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme. J. Am. Chem. Soc., 124,10489-10496.
[19] C. Tanford. Micelle Shape and Size. J. Phys. Chem., 76,3020-3024.
[20] 颜肖慈，罗明道．界面化学[M]．化学工业出版社，2004，117．
[21]董元彦，李宝华，路福绥．物理化学[M]．科学出版社，1999，172．
[22] P. C. Hiemenz, R. Rajagopalan. Principles of Colloid and Surface Chemistry (Marcel Dekker, New York). Third Ed, Revised and expanded. 1997,12.
[23] C. Burger, J. Hao, Q. Ting, H. Isobe, M. Sawamura, E. Nakamura, B. Chu. Multilayer Vesicles and Vesicle Clusters Formed by the Fullerene-Based Surfactant C6o(CH_3)_5K [J]. J. Colloid Inter. Sci.,2004,275:632-641.
[1] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[2] A. Muller, V. P. Fedin, C. Kuhlmann, H. Bogge, M. Schmidtmann. A hydrogen-bonded cluster with "onion-type" structure, encapsulated and induced by a spherical cluster shell: [(H_2O)_n in Mo~(VI)_(72)MoV_(60)O_(372)(HCO_2)_(30)(H_2O)_(72)]~(42-) [J]. Chem. Comm., 1999,927-928.
[3] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999,38:3238-3241.
[4] A. Muller, S. Polarz, S. K. Das, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Hauptfleisch. "Open and Shut" for Guests in Molybdenum-Oxide-Based Giant Spheres, Baskets, and Rings Containing the Pentagon as a Common Structural Element [J]. Angew. Chem. Int. Ed. Engl., 1999,38: 3241-3245.
[5] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, C. Beugholt, P. Kdgerler, C. Lu. Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO_3)_(176)(H_2O)_(80)H_(32)] [J]. Angew. Chem. Int. Ed. Engl., 1998,37:1220-1223.
[6] A. Mailer, M. Koop, H. Bogge, M. Schmidtmann, C. Beugholt. Exchanged ligands on the surface of a giant cluster: [(MoO_3)_(176)(H_2O)_(63)(CH_3OH)_(17)H_n]~((32-n))-[J]. Chem. Comm., 1998,1501-1502.
[7] A. Muller, S. Q. N. Shah, H. Bogge, M. Schmidtmann. Molecular growth from a Mo_(176) to a Mo_(248) cluster [J]. Nature, 1999,397:48-50.
[8] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, P. Kogerler, C. Rosu, E. Beckmann. "Nanoobjects" by Self-Assembly Concomitant with??Modifications under Alterable Boundary Conditions: Incorporation of Paramagnetic Metal Centers (Cu~2+)) in Ring-Shaped Molybdenum-Oxide Based Clusters [J]. Angew. Chem. Int. Ed., 2001,40:4034-4037.
[9] A. Muller, E. Beckmann, H. Bdgge, M. Schmidtmann, A. Dress. Inorganic Chemistry Goes Protein Size: A Mo_(368) Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int. Ed., 2002, 41: 1162-1167.
[10] A. Muller, B. Botar, S. K. Das, H. B6gge, M. Schmidtmann, A. Merca. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron, 2004,23:2381-2385.
[11] T. Liu; E. Diemann, H. Li, A.W.M. Dress, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426:59-62.
[12] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant molecular wheels" [J]. Chem. Commun., 2001:1928-1929.
[13] Y. Zhu, A. Cammers-Goodwin, B. Zhao, A. Dozier, E. C. Dickey. Kinetic Precipitation of Solution-Phase Polyoxomolybdate Followed by Transmission Electron Microscopy: A Window to Solution-Phase Nanostructure [J]. Chem. Eur. J., 2004,10:2421-2427.
[14] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc., 2003,125: 312-313.
[15] B. Chen, H. Jiang, Y. Zhu, A. Cammers, J. P. Selegue. Monitoring the Growth of Polyoxomolybdate Nanoparticles in Suspension by Flow Field-Flow Fractionation [J]. J. Am. Chem. Soc, 2005,127:4166-4167. .
[16] T. Liu. Supramolecular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124: 10942-10943; 2004, 126:406. (Add/Cor.)??{Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions. Lagmuir, 2005,21: 2713-2720.
[18] G. Liu, Y. Cai, T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc, 2004,126: 16690-16691.
[19] G. Liu, T. Liu. Strong attraction among the fully hydrophilic {Mo(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc, 2005,127: 6942-6943.
[20] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters[J]. J. Clust. Sci., 2003, 14(3): 215-226.
[21] G. Liu, M. Cons, T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005,118: 27-29.
[22] G. Liu, T. Liu, S. S. Mal, U. Kortz. Wheel-Shaped Polyoxotungstate [Cu_(20)Cl(OH)_(24)(H_2O)_(12)(P_8W_(48)O_(184))]~(25-) Macroanions Form Supramolecular "Blackberry" Structure in Aqueous Solution [J]. J. Am. Chem. Soc., 2006, 128(31): 10103-10110.
[23] T. Liu, B. Imber, E. Diemann, G. Liu, K. Cokleski, H. Li, Z. Chen, A. Muller. Deprotonations and Charges of Weil-Defined {Mo_(72)Fe_(30)} Nanoacids Simply Stepwise Tuned by pH Allow Control/Variation of Related Self-Assembly Processes [J]. J. Am. Chem. Soc, 2006,128:15914-15920.
[24] A. Song, S. Dong, X. Jia, J. Hao, W. Liu, T. Liu. An Onion Phase in Salt-Free Zero-Charged Cationionic Surfactant Solutions [J]. Angew. Chem. Int. Ed., 2005,44:4018-4021.
[25] J. Wang, A. Song, X. Jia, J. Hao, W. Liu, H. Hoffmann. Two Routes to Vesicle Formation: Metal-Ligand Complexation and Ionic Interactions [J]. J. Phys. Chem. B, 2005,109: 11126-11134.
[26] H. Li, X. Jia, Y. Li, X. Shi, J. Hao, A Salt-Free Zero-Charged Aqueous Onion-Phase Enhances the Solubility of Fullerene C_(60) in Water [J]. J. Phys. Chem. B, 2006,110:68-74.
[27] Y. Li, H. Li, X. Jia, X. Jia, J. Hao, W. Liu. Electrochemical Behavior of C_(60) films and C_(60)/Lipid Films in Ionic Liquids [J]. Carbon, 2006,44: 894-899.
[28] F. Menger, V. Seredyuk, M. Kitaeva, A. Yaroslavov, N. Melik-Nubarov. Migration of Poly-L-lysine through a Lipid Bilayer [J]. J. Am. Chem. Soc, 2003,125:2846-2847.
[29] Y.-C. Tan, K. Hettiarachchi, M. Siu, Y.-R. Pan, A. P. Lee. Controlled Microfluidic Encapsulation of Cells, Proteins, and Microbeads in Lipid Vesicles [J]. J. Am. Chem. Soc, 2006,128: 5656-5658.
[30] B. Peker, J. J. Wuu, J. R. Swartz. Affinity Purification of Lipid Vesicles [J]. Biotechnol. Prog., 2004,20:262-268.
[31] F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann. Advanced Inorganic Chemistry [M]. 6~(th) ed, Wiley: New York, 1999.
[32] M. T. Pope, A. Muller. Polyoxometalate Chemistry: An Old Field with New Dimensions in Veral Disciplines [J]. Angew. Chem. Int. Ed., 1991,30: 34-48.
[33] L. Verhoef, M. L. Kistler, A. Bhatt, J. Groenewold, M. Klokkenburg, S. Veen, S. Roy, T. Liu, W. Kegel. Charge Regulation as a Stabilization Mechanism for Shell-Like Structures. Phy. Rev. Lett, unpublished data.
[34] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed., 1998, 37: 3360-3363.
[35] D. Long, L. Cronin. Towards Polyoxometalate-Integrated Nanosystems [J]. hem. Eur. J., 2006,12: 3698-3706.
[36] 赵徐声．碱金属[M]．上海教育出版社，1981，4．
[1] 贾祥凤，范大伟，唐培芹，郝京诚，马丽英，刘天波．纳米级无机聚钼酸盐“二级有序聚集体”[J]．物理化学学报，2006，22(10)：1300-1304． Cited by Elsevier. X. Jia, D. Fan, P. Tang, J. Hao, L. Ma, T. Liu. "Second Organized Structures" of Nanoscale Inorganic Polyoxomolybdate Compounds [J]. Acta. Phys.-Chim. Sin. 2006 22(10): 1300-1304.
[2] T. Liu, E. Diemann, H. Li, A.W.M. Dress, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426: 59-62.
[3] G. Liu, T. Liu. Strong attraction among the fully hydrophilic {Mo_(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc., 2005, 127: 6942-6943.
[4] G. Liu, Y. Cai, T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc., 2004, 126: 16690-16691.
[5] G. Liu, M. Cons, T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005, 118: 27-29.
[6] G. Liu, T. Liu. Thermodynamic properties of the unique self-assembly of {Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions. Lagmuir, 2005, 21: 2713-2720.
[7] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters. J. Clust. Sci., 2003, 14(3): 215-226,
[8] T. Liu. Supramolecular Structures of Polyoxomolybdate-Based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc. 2002, 124: 10942-10943.
[9] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc. 2003, 125:312-313.
[10] L. A. Matheson, N. Nichols. The Cathode Ray Oscillograph Applied to the Dropping Mercury Electrode [J]. Trans. Electrochem. Sot., 1938, 73: 193-210.
[11] J. E. B. Randles. A Cathode Ray Polarograph [J]. Trans. Faraday Soc., 1948, 44: 322-327.
[12] J. E. B. Randles. A Cathode Ray Polarograph. Part Ⅱ.—The Current-Voltage Vurves [J]. Trans. Faraday Soc., 1948, 44: 327-338.
[13] A. Sevcik. Oscillographic Polargraphy with Periodic Triangular Voltage [J]. Collect. Czech. Chem. Commun., 1948, 13: 348-377.
[14] 查全性．电极过程动力学导论(第三版)[M]．北京科学出版社，2002．89-112．
[15] 刘永辉．电化学测试技术(第一版)[M]．北京航空学院出版社，1987．46-72。
[16] 陈永乐，杨孙楷．膜伏安法及其在分析化学中的应用[M]．北京地质出版社，1987，23-45．
[17] 黄慰曾，高小霞，杨文治(F．Anson讲授)．电化学和电分析化学[M]．北京大学出版社，1983，16-32．
[1] Scheele, C. W.; In Samtliche Physische und Chemische Werke (ed. Hermbstadt, DSF) Ed. Martin Sandig OHG: Niederwalluf/Wiesbaden, 1971, 1:185 (reprint: original 1793)
[2] Liu, T.; Diemann, E.; Li, H.; Dress, AWM; Muller, A. Nature, 2003, 426: 59-62.
[3] Liu, G.; Liu, T. J. Am. Chem. Soc., 2005, 127: 6942-6943.
[4] Liu, G.; Cai, Y.; Liu, T. J. Am. Chem. Soc., 2004, 126: 16690-16691.
[5] Liu, G.; Cons, M.; Liu, T. J. Mol. Liq., 2005, 118: 27-29.
[6] Liu, G.; Liu, T. Lagmuir, 2005, 21: 2713-2720.
[7] Liu, T. J. Clust. Sci., 2003, 14: 215-226.
[8] (a) Muller, A.; Das, S. K.; Krickemeyer, E.; Kuhlmann, C. Inorg. Synth., 2004, 34: 191-200. (b) Cronin, L.; Diemann, E.; Muller, A. Inorganic Experiments, 2003: 340-346.
[9] Muller, A.; Krichemeyer, E.; Bogge, H.; Schmidtmann, M.; Peters, F. Angew. Chem. Int. Ed., 1998, 37: 3360-3363.
[10] Muller, A.; Fedin, V. P.; Kuhlmann, C.; Bogge, H.; Schmidtmann, M. Chem. Commun., 1999: 927-928.
[11] Muller, A.; Sarkar, S.; Shah, S. Q. N.; Bogge, H.; Schmidtmann, M.; Sarkar, Sh.; Kogerler, P.; Hauptfleisch, B.; Trautwein, A. X.; Schunemann, V. Angew, Chem, Int. Ed., 1999, 38: 3238-3241.
[12] Muller, A.; Polarz, S.; Krichemeyer, S. K. E.; Bogge, H.; Schmidtmann, M.; Hauptfleisch, B. Angew, Chem. Int. Ed., 1999, 38. 3241-3244.
[13] Muller, A.; Kogerler, P.; Kuhlmann, C. Chem. Commun.; 1999: 1347-1348.
[14] Muller, A.; Krichemeyer, E.; Bogge, H.; Schmidtmann, M.; Beugholt, C.; Kogerler, P.; Lu, C.Angew, Chem. Int. Ed., 1998, 37: 1220-1223.
[15] Jiang, C. C., Wei, Y. G.; Liu, Q.; Zhang, S. W.; Shao, M. C.; Tang, Y. Q. Chem. Commun, 1998: 1937-1938.
[16] Muller, A.; Koop, M.; Bogge, H.; Schmidtmann, M.; Teugholt, C. Chem. Commun., 1999: 1501-1502.
[17] Muller, A.; Shan, S. Q. N.; Bogge, H.; Schmidtmann, M. Nature, 1999, 397:48
[18] Muller, A.; Beckmann, E.; Bogge, H.; Schmidtmann, M.; Kogerler, P.; Rosu, C.; Beckmann, E. Angew. Chem. Int. Ed., 2001, 40: 4034-4037.
[19] (a) Muller, A.; Beckmann, E.; Bogge, H.; Schmidtmann, M.; Dress, A. Angew. Chem. Int. Ed., 2002, 41:1162-1165. (b) Muller, A.; Botar, B.; Das, S. K.; Bogge, H.; Schmidtmann, M.; Merca, A. Polyhedron 2004, 23: 2381-2385.
[20] Muller, A.; Henry, M. CR. Chimie, 2003, 6: 1201-1208.
[21] Muller, A.; Meyer, J.; Krickemeyer, E.; Beugholt, C., Bogge, H.; Peters, F.; Schmidtmann, M.; Kogeder, P.; Koop, M. J. Chem. Eur. J., 1998, 4: 1000-1006.
[22] Muller, A.; Peters, F.; Pope, M. T.; Gattesehi, D. Chem. Rev., 1998, 98. 239-271.
[23] Muller, A.; Roy, S.; Coord. Chem. Rev., 2003, 245: 153-166.
[24] Muller, A.; Diemann, E.; Kuhlmann, C.; Eimer, W.; Serain, C.; Tak, T.; Knochel, A.; Pranzas, P. K. ChemComm 2001: 1928-1929.
[25] Rounding up nanoclusters, Materialstoday, 2004, 7(1): 10
[26] Hao, J.; Hoffmann, H. Curr. Opin. Colloid Inter. Sci. 2004, 9: 279-281.
[27] Polarz, S.; Smarsly, B.; Antoniett, M.; Chemphyschem, 2001, 7: 457-461.
[28] Kurth, D. G.; Lehmann, P.; Volkmer, D.; Kogerler, P.; Sarkar, S.; Bogge, H.; Schmidtmann, M.; Sarkar, Sh. Chem. Eur. J., 2000, 6: 385-393.
[29] Bu, W.; Li, H.; Sun, H.; Yin, S.; Wu, L. J. Am. Chem. Soc., 2005, 127: 8016-8017.
[30] Volkmer, D.; Chesne, A. D.; Kurth, D. G.; Schmablegger, H.; Lehmann, P.; Koop, M. J.. Am. Chem. Soc., 2000, 122: 1995-1996.
[1] A. MUller, P. Kogerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001, 222: 193-218.
[2] A. Muller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na_(15) [Mo~(Ⅵ)_(126)Mo~(Ⅴ)_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5) [Mo~(Ⅵ)_(124)Mo~(Ⅴ)_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5) ca. 400 H_2O and Na_(22)[Mo~(Ⅵ)_(118)Mo~(Ⅴ)_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. anorg. allg. Chem., 1999, 625: 1187-1192.
[3] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[4] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[5] T. Liu; E. Diemann, H. Li, A.W.M. Dres, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426: 59-62.
[6] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Talc, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant" molecular wheels [J]. Chem. Commun., 2001: 1928-1929.
[7] T. Liu. Supramoleeular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc., 2002, 124: 10942-10943.
[8] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc., 2003, 125: 312-313.
[9] T. Liu. Surfactant-Induced Trans-Interface Transportation and Complex Formation of Giant Polyoxomolybdate-Based Clusters [J]. J. Clust. Sci., 2003, 14: 215-226.
[10] (a)S. Polarz, B. Smarsly, M. Antonietti. Colloidal Organization and Clusters: Self-Assembly of Polyoxometalate-Surfactant Complexes towards Three-Dimensional Organized Structures [J]. ChemPhyChem., 2001, 7: 457-461. (b) D. G. Kruth, P. Lehmann, D. Volkmer, A. Muller, D. Schwahn. Biologically inspired polyoxometalate-surfactant composite materials. Investigations on the structures of discrete, surfactant-encapsulated clusters, monolayers, and Langrnuir-Blodgett films of (DODA)_(40)(NH_4)_2[(H_2O)n in Mo_(132)O_(372)(CH_3CO_2)_(30)(H_2O)_(72)] [J]. J. Chem. Soc. Dalton Trans., 2000, 21: 3989-3998.
[11] D. G. Kurth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters (SECs): (DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] [J]. Chem. Eur. J., 2000, 6: 385-393.
[12] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G. Kruth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Krebs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme [J]. J. Am. Chem. Soc., 2002, 124(35): 10489-10496.
[13] C. Tanford. Micelle Shape and Size. J. Phys. Chem., 76, 3020-3024.
[14] P. C. Hiemenz, R. Rajagopalan. Principles of Colloid and Surface Chemistry (Marcel Dekker, New York). Third Ed, Revised and expanded. 1997, 12.
[1] Liu, T.; Diemann, E.; Li, H.; Dress, A. W. M.; Muller, A. Nature 2003, 426, 59-62.
[2] Muller, A.; Diemann, E.; Kuhlmann, C.; Eimer, W.; Serain, C.; Tak, T.; Knochel, A.; Pranzzas, P. K. Chem. Commun. 2001, 1928-1929.
[3] Zhu, Y.; Cammers-Goodwin, A.; Zhao, B.; Dozier, A.; Dickey, E. C. Chem. Eur. J. 2004,10, 2421-2423.
[4] Liu, T. J. Am. Chem. Soc. 2003, 125, 312-313.
[5] Chen, B.; Jiang, H.; Zhu, Y.; Cammers, A.; Selegue, J. P. J. Am. Chem. Soc. 2005, 127, 4166-4167.
[6] Liu, T. J.. Am. Chem. Soc. 2002, 124, 10942-10943; 2004, 126, 406-407 (Add./Cor.).
[7] Liu, G.; Liu, T. Langmuir, 2005, 21, 2713-2720.
[8] Liu, G.; Cai, Y.; Liu, T. J. Am. Chem. Soc. 2004, 126, 16690-16691.
[9] Liu, G.; Liu, T. J. Am. Chem. Soc. 2005, 127, 6942-6943.
[10] Liu, T. J. Clust. Sci., 2003, 14, 215-226.
[11] Liu, G.; Cons, M., Liu, T. J. Mol. Liq., 2005, 118, 27-29.
[12] Liu, G.; Liu, T.; Mal, S. S.; Kortz, U. J.. Am. Chem. Soc. 2006, 128, 10103-10104.
[13] Muller, A.; Kogerler, P.; Kuhlmann, C. Chem. Commun. 1999, 1347-1348.
[14] Cronin, L.; in Comprehensive Coordinatioon Chemistry Ⅱ, Vol. 7 ed. McClevety, J. A.; Meyer, T. J. Elsvier, Amsterdam, 2004, P.1.
[15] Long, D. Cronin L. Chem. Eur. J. 2006, 12, 3698-3701.
[16] Verhoef, L.; Kistler, M. L.; Bhatt, A.; Groenewold, J.; Klokkenburg, M.; Veen, S.; Roy, S.; Liu, T.; Kegel, W. Phy. Rev. Lett unpublished data.
[17] Liu, T.; Imber, B.; Diemann, E.; Liu, G.; Cokleski, K.; Li, H.; Chen, Z.; Muller, A. J. Am. Chem. Soc. Unpublished data.
[18] Muller, A.; Sarkar, S.; Shah, S. Q. N.; Bogge, H.; Schmidtmann, M.; Saarkar, S.; Koerler, P.; Hauptfleisch, B.; Trautwein, A. X.; Schunemann, V. Angew. Chem., Int. Ed. Engl. 1999, 38, 3238-3241.
[19] Muller, A.; Krickemeyer, E.; Bogge, H.; Schmidtmann, M.; Peters, F. Angew.Chem. Int. Ed. 1998, 37, 3360-3363.
[20] Provencher, S. W. Biophys. J. 1976, 16, 29-31.
[21] Watanabe, M.; Sakairi, K.; Inoue, M. J. Electroanal. Chem. 1994, 375, 415-417.
[22] Zana, R. J.. Colloid Inter. Sci. 1980, 78, 330-332.
[2] T. Liu; E. Diemann; H. Li; A.W.M. Dress; A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003,426: 59-62.
[3] G. Liu; T. Liu. Strong attraction among the fully hydrophilic {Mo_(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc., 2005,127: 6942-6943.
[4] G. Liu; Y. Cai; T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc, 2004,126: 16690-16691.
[5] G. Liu; M. Cons; T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005,118: 27-29.
[6] G. Liu; T. Liu. Thermodynamic properties of the unique self-assembly of {Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions[J]. Lagmuir, 2005,21:2713-2720.
[7] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters [J]. J. Clust. Sci., 2003, 14(3): 215-226.
[8] A. Muller, E. Diemann. The bis(tertrathiotungstato) nickelate(II) ion, a novel complex with WS_4~(2-) ion as a ligand [J]. Chem. Comm., 1971,65-67.
[9] E. Koniger-Ahlborn, A. Muller. Crystalline compound with isolated W_3S_3~(2-) ion: a thio analog of transition metal isopolyanions [J]. Angew. Chem. Int. Ed. Engl. 1975,14:573-574.
[10] D. Rehder, E. T. K. Haupt, H. B8gge, A. Muller. Countercation Transport Modeled by Porous Spherical Molybdenum Oxide Based Nanocapsules [J], Chem. Asian J., 2006,1: 76-81.??High Negative Charge and Cubane-Like Mo_4S_4-Moiety: On the Significance of Cyanothiomolybdates for the Prebiotic Evolution [J]. Angew. Chem. Int. Ed. Engl., 1982,21: 795-796.
[12] A. Muller, W. Hellmann, H. Bogge, R. Jostes, M. Rdmer, U. Schimanski. [Fe_3W_3S_(14)]~(4-), A Novel Hexanuclear, "Pure" Bimetal-Sulfur Cluster with Fe_3(μ_3-S)_2 Center [J]. Angew. Chem. Int. Ed. Engl. 1982,21: 860-861.
[13] A. Muller, M. Romer, H. B6gge, E. Krickemeyer, D. Bergmann. [Cu_6S_(17)]~(2-), a Novel Binary Discrete Polynuclear CuI Complex with Several Interesting Structural Features: The Arrangement of the Metal Atoms and Co-ordination of Ligands [J]. Chem. Comm., 1984, 348-349.
[14] A. Muller, R. Jostes, W. Eltzner, Chong-Shi Nie, E. Diemann, H. Bogge, M. Zimmermann, M. Dartmann, U. Reinsch-Vogell, Shun Che, S. J. Cyvin, B. N. Cyvin. Synthetic, Spectroscopic, X-ray Structural, and Quantum-Chemical Studies of Cyanothiomolybdates with Mo_2S, Mo2S_2, Mo_3S_4, and Mo_4S_4 Cores: A Remarkable Class of Species Existing with Different Electron Populations and Having the Same Central Units as the Ferredoxins [J]. Inorg. Chem., 1985,24:2872-2884.
[15] A. Muller, K. Schmitz, E. Krickemeyer, M. Penk, H. Bogge. [Pd_2S_(28)]~(4-): A 30-Membered Cage Containing an Entrapped Cation [J]", Angew. Chem. Int. Ed. Engl., 1986,25:453-454.
[16] A. Muller, E. Krickemeyer, H. Bogge. Darstellung und Kristall-Struktur von R[ReS_4], R'[ReS_9], (NH_4)_4[Re_4S_(22)] 2H_2O, R'2[Cl_2Fe(MoS_4)FeCl_2]_x[Cl_2Fe(ReS_4)FeCl_2]_(1-x), R_2‘[(ReS_4)Cu_3I_4] und RR_2’[(ReS_4)Cu_5Br_7] (R = NEt_4; R‘ = PPh_4; x = 0,3; 0,5) [J]. Z. anorg. allg. Chem., 1987,554:61-78.
[17] A. Muller, N. H. Schladerbeck, E. Krickemeyer, H. B6gge,.K. Schmitz, E. Bill, A. X.Trautwein. Darstellung von Metall-Schwefel-Clustern durch einfache Reaktion von Metallsalzen mit H_2S: R_2(NH_4)[Cu_3S_(12)], R_2[Cu_4S_(12)] CH_3CN, R_2[Cu_4S_(1.28)], R_2[Fe_2S_2(S_5)_2], R_2[Fe_4S_4Br_4], R_2[Fe_4S_4Br_2Cl_2],??allg. Chem., 1989, 570: 7-36.
[18] A. Muller, E. Krickemeyer, M. Penk, V. Wittneben, J. Doring. [H_6As_(10)Mo_(24)O_(90)]~(8-), a Heteropolyanion Comprising Two Linked Spherical Fragments, and Reduced Keggin Anions as Its Degradation Products [J]. Angew. Chem. Int. Ed. Engl., 1990,29: 88-90.
[19] A. Muller, E. Krickemeyer. Molybdenum-sulfur clusters [M]. In: Inorganic Synthesis, Vol. 27 (Ed.: A. P. Ginsberg), Wiley, New York (1990).
[20] A. Muller, M. Penk, R. Rohlfing, E. Krickemeyer, J. Doring. Topologically Interesting Cages for Negative Ions with Extremely High "Coordination Number": An Unusual Property of V-0 Clusters [J]. Angew. Chem. Int. Ed. Engl. 1990,29:926-927.
[21] A. Muller, R. Rohlfing, J. Doring, M. Penk. Formation of a Cluster Sheath around a Central Cluster by a "Self-Organization Process": the Mixed Valence Polyoxovanadate [V_(34)O_(82)]~(10-)[J]. Angew. Chem. Int. Ed. Engl., 1991, 30: 588-590.
[22] A. Muller, E. Krickemeyer, V. Wittneben, H. Bogge, M. Lemke. (NH_4)_2 [Re_2S_(16)], a Soluble Metal Sulfide with Interesting Electronic Properties and Unusual Reactivity [J]. Angew. Chem. Int. Ed. Engl., 1991,30:1512-1514.
[23] A. Muller, E. Krickemeyer, M. Penk, R. Rohlfing, A. Armatage, H. Bogge. Template-Controlled Formation of Cluster Shells or a Type of Molecular Recognition: Synthesis of [HV_(22)O_(54)(ClO_4)]~(6-) and [H_2V_(18)O_(44)(N_3)]~(5-) [J]. Angew. Chem. Int. Ed. Engl., 1991, 30: 1674-1677.
[24] A. Muller, K. Hovemeier, R. Rohlfing. A Novel Host/Guest System with a Nanometer Large Cavity for Anions and Cations: [2 NH_4~+, 2Cl~- in V_(14)O_(22)(OH)_4(H_2O)_2 (C_6H_5PO_3)-8]~(6-) [J]. Angew. Chem. Int. Ed. Engl., 1992,31: 1192-1195.
[25] A. Muller, R. Rohlfing, E. Krickemeyer, H. Bogge. Control of the Linkage of Inorganic Fragments of V-O Compounds: From Cluster Shells as Carcerands via Cluster Aggregates to Sold-State Structures [J]. Angew. Chem. Int. Ed. Engl., 1993,32:909-912.
[26] A. Muller, V. P. Fedin, E. Diemann, H. B5gge, E. Krickemeyer, D. S61ter, A. M. Giuliani, R. Barbieri, P. Adler. Reductive Addition at the W_3S_4~(4+) Core by Sn~(2+) or an Unusual Supramolecular System: A Synergetic Reaction Leading to the Host Guest Compound (Me_2NH_2)_6[(SCN)_9W_3S-4SnCl_3]0.5H_2O. Inorg. Chem., 1994,33:2243-2247.
[27] A. Muller, E. Krickemeyer, H. Bogge, H. Ratajczak, A. Armatage. A Building Principle of Amorphous Chalcogenides of Transition Metals: The "Extrusion" of the Electron-Rich Cluster [Re_4S_2(SO_2)_4(CN)_(10)]~(8-) from a-Re_2S_7 [J]. Angew. Chem. Int. Ed. Engl., 1994,33:770-773.
[28] A. Muller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bogge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann. [Mo_(57)Fe_6(NO)_6O_(174)(OH)_3(H_2O)_(24)]~(15-): A Highly Symmetrical Giant Cluster with an Unusual Cavity and the Possibility of Positioning Paramagnetic Centers on Extremely Large Cluster Surfaces [J]. Angew. Chem. Int. Ed. Engl., 1994,33: 849-851.
[29] A. Muller. E. Krickemeyer, S. Dillinger, H. Bogge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing. New Perspectives in Polyoxometalate Chemistry by Isolation of Compounds Containing Very Large Moieties as Transferable Building Blocks: (NMe_4)_5[As_2Mo_8V_4AsO_(40)] 3H_2O, (NH_4)_(21)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] ·65H_2O, (NH_2Me_2)_(18)(NH_4)_6[Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] 14H_2O, and (NH_4)_(12)[Mo_(36)(NO)_4O_(108)(H_2O)(16)] · 33H_2O [J]. Z. anorg. allg. Chem., 1994, 620: 599-619.
[30] A. Muller, E. Krickemeyer, J. Meyer, H. Bogge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke. [Mo_(154)(NO)_(14)O_(420)(OH)(28)(H_2O)_(70)]~((25±5)-) : A Water-Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24 000 [J]. Angew. Chem. Int. Ed. Engl., 1995,34:2122-2124.
[31] A. Mttller, K. Hovemeier, E. Krickemeyer, H. Bogge. Modelling the Remote-Controlled Organization of Particles in a Nanodimensional Cavity: Synthesis and Properties of (Et_3NH)_3(tBuNH_3)_2Na_2[(H_2O)_2, N~(3-) in??V_(14)O_(22)(OH)_4(PhPO_3)_8] ·6H_2O ·2 DMF [J]. Angew. Chem. Int. Ed. Engl., 1995, 34: 779-781.
[32] A. Muller, J. Meyer, E. Krickemeyer, E. Diemann, Molybdenum Blue: A 200 Year Old Mystery Unveiled [J]. Angew. Chem. Int. Ed. Engl., 1996, 35: 1206-1208.
[33] A. Muller, K. U. Johannes, W. Plass, H. Bogge, E. Krahn, K. Schneider. Uber grunes Bis-(2-Iminoisopropyl-thiophenolato)-nickel(II) und weitere, ahnliche Ni~(II)-Komplexe [J]. Z. anorg. allg. Chem., 1996,622: 1765-1772.
[34] A. Mailer, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer. An Unusual Polyoxomolybdate: Giant Wheels Linked to Chains [J]. Angew. Chem. Int. Ed. Engl., 1997,36:483-486.
[35] A. Muller, R. Sessoli, E. Krickemeyer, H. Bogge, J. Meyer, D. Gatteschi, L. Pardi, J. Westphal, K. Hovemeier, R. Rohlfing, J. Doring, F. Hellweg, C. Beugholt, M. Schmidtmann. Polyoxovanadates: High-Nuclearity Spin Clusters with Interesting Host-Guest Systems and Different Electron Populations. Synthesis, Spin Organization, Magnetochemistry, and Spectroscopic Studies [J]. Inorg. Chem. 1997,36: 5239-5250.
[36] A. Muller, E. Krickemeyer, H. B6gge, M. Schmidtmann, C. Beugholt, P. Kogerler, C. Lu. Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO_3)_(176)(H_2O)_(80)H_(32)] [J]. Angew. Chem. Int. Ed. Engl., 1998,37:1220-1223.
[37] A. Muller, J. Meyer, E. Krickemeyer, C. Beugholt, H. BSgge, F. Peters, M. Schmidtmann, P. KSgerler, M. J. Koop. Unusual Stepwise Assembly and Molecular Growth: [H_(140MO_(37)O_(112)]~(14-) and [H_3Mo_(57)V_6(NO)-6O_(189)(H_2O)_(12)(MoO)_6]~(21-)[J]. Chem. Europ. J., 1998, 4: 1000-1006.
[38] A. Muller, A. Hildebrand, E. Krickemeyer, M. I. Khan, M. Penk, H. Bogge, F. Secheresse. Generating Structural Motifs between Three-Dimensional Solids and Discrete Species Based on the {CuNCS} Unit: (PPh_4)[(ReS_4)Cu_2(NCS)_2］1998,4:1932-1937.
[39] A. Muller, J. Meyer, H. Bogge, A. Stammler, A. Botar. Trinuclear Fragments as Nucleation Centres: New Polyoxoalkoxyvanadates by (Induced) Self-Assembly [J]. Chem. Europ. J., 1998,4: 1388-1397.
[40] A. Muller, M. Koop, H. Bogge, M. Schmidtmann, C. Beugholt. Exchanged ligands on the surface of a giant cluster: [(MoO_3)_(176)(H_2O)_(63)(CH_3OH)_(17)H_n]~(32-n) [J]. Chem. Comm., 1998, 1501-1502.
[41] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[42] A. Miiller, S. Q. N. Shah, H. Bogge, M. Schmidtmann. Molecular growth from a Mo_(176) to a Mo_(248) cluster [J]. Nature, 1999,397: 48-50.
[43] A. Muller, E. Krickemeyer, H. B6gge, M. Schmidtmann, C. Beugholt, S. K. Das, F. Peters. Giant Ring-Shaped Building Blocks Linked to Form a Layered Cluster Network with Nanosized Channels: [Mo~(VI)_(124)Mo~V_(28)O_(429)(μ_3-O)_(28)H_(14)(H_2O)_(66.5)]~(16-) [J]. Chem. Eur. J., 1999, 5: 1496-1502.
[44] A. Muller, V. P. Fedin, C. Kuhlmann, H. B6gge, M. Schmidtmann. A hydrogen-bonded cluster with 'onion-type' structure, encapsulated and induced by a spherical cluster shell: [(H_2O)_n in Mo~(VI)_(72)Mo~V_(60)O_(372)(HCO_2)_(30)(H_2O)_(72)]~(42-) [J]. Chem. Comm., 1999,927-928.
[45] A. Muller, S. K. Das, H. Bogge, C. Beugholt, M. Schmidtmann. Assembling nanosized ring-shaped synthons to an anionic layer structure based on the synergetically induced functional complementarity of their surface-sites: Na_(21)[Mo~(VI)_(126)Mo~V_(28)O_(462)H_(14)(H_2O)_(54)(H_2PO_2)_7]_xH_2O (x≈300 [J]. Chem. Comm., 1999,1035-1036.
[46] A. Miiller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized
??Ring-Shaped Anions:400 H_2O and Na_(22)[Mo~(VI)_(118)Mo~V_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. Anorg. Allg. Chem., 1999, 625: 1187-1192.
[47] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl. 1999, 38: 3238-3241.
[48] A. Muller, S. Polarz, S. K. Das, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Hauptfleisch. "Open and Shut" for Guests in Molybdenum-Oxide-Based Giant Spheres, Baskets, and Rings Containing the Pentagon as a Common Structural Element [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3241-3245.
[49] A. Muller, V. P. Fedin, C. Kuhlmann, H.-D. Fenske, G. Baum, H. Bogge, B. Hauptfleisch. "Adding" stable functional complementary, nucleophilic and electrophilic clusters: a synthetic route to [{(SiW_(11)O_(39)) Mo_3S_4(H_2O)_3(μ-OH)}_2]~(10-) and [{(P_2W_(17)O_(61))Mo_3S_4(H_2O)_3(μ-OH)}_2]~(14-) as examples [J]. Chem. Comm., 1999, 1189-1190.
[50] A. Muller, M. Koop, H. Bogge, M. Schmidtmann, F. Peters, P. Kogerler, Chem. Comm. Building blocks as disposition in solution: [{Mo~(VI)O_3(H_2O)}_(10){V~(IV)O(H_2O)}_(20){(Mo~(VI)/Mo~(VI)_5O_(21))(H_2O)_3}_(10)({Mo~(VI)O_2(H_2O) _2)_(5/2))_2 ({NaSO_4}_5)_2]~(20-) a giant spherical cluster with unusual structural features of interest for supramolecular and magneto chemistry [J]. 1999, 1885-1886.
[51] A. Miiller, C. Beugholt, M. Koop, S. K. Das, M. Schmidtmann, H. Bogge. Facile and Optimized Syntheses and Structures of Crystalline Molybdenum Blue Compounds Including one with an Interesting High Degree of Defects: Na_(26)[Mo_(142)O_(432)(H_2O)_(58)H_(14)] ca. 300 H_2O and Na_(16)[(MoO_3)_(176)(H_2O)_(63) (CH_3OH)_(17)H_(16)] ca. 600 H_2O 6 CH_3OH [J]. Z. anorg. allg. Chem., 1999, 625: 1960-1962.
[52] V. Bereau, E. Cadot, H. Bogge, A. Muller, F. Secheresse. Addition of {M_2S_2O_2}~(2+) , M = Mo, W, to A-a-[PW_9O_(34)]~(9-) . Synthesis and Structural Characterizations in the Solid State and in Solution [J]. Inorg. Chem., 1999, 38: 5803-5808.
[53] A. Muller, S. Q. N. Shah, H. Bogge, M. Schmidtmann, P. Kogerler, B. Hauptfleisch, S. Leiding, K. Wittier. 30 Electrons "Trapped" in a Spherical Matrix: A Molybdenum Oxide-Based Nanostructured Keplerate Reduced by 36 Electrons [J]. Angew. Chem. Int. Ed. Engl., 2000, 39: 1614-1616.
[54] A. Muller, E. Krickemeyer, S. K. Das, S. Sarkar, H. Bogge, M. Schmidtmann, P. Kogerler, Sh. Sarkar. Linking Icosahedral, Strong Molecular Magnets {Mo~(VI)Fe~(III)_(30)} to Layers - A Solid-State Reaction at Room Temperature [J]. Angew. Chem. Int. Ed. Engl., 2000,39:1612-1614.
[55] A. Miiller, C. Beugholt, H. Bogge, M. Schmidtmann. Influencing the Size of Giant Rings by Manipulating their Curvatures:Na_6[Mo_(120)O_(366)(H_2O)_(48)H_(12){Pr(H_2O)_5}_6] ca. 200 H_2O with Open Shell Metal Centers at the Cluster Surface [J]. Inorg. Chem., 2000, 39: 3112-3113.
[56] A. Muller, S. K. Das, H. Bogge, M. Schmidtmann, P. Kogerler, A. X. Trautwein, V. Schunemann, E. Krickemeyer, W. Preetz, H. U., Gudel. A New Type of Supramolecular Compound: Molybdenum-Oxide-Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a Two-Dimensional Network [J]. Angew. Chem. Int. Ed., 2000,39: 3413-3417.
[57] A. Muller, C. Kuhlmann, H. Bogge, M. Schmidtmann, M. Baumann, E. Krickemeyer. Mo~V_2O_4~(2+) Directs the Formation and Subsequent Linking of Potential Building Blocks under Different Boundary Conditions: A Related Set of Novel Cyclic Polyoxomolybdates [J]. Eur. J. Inorg. Chem., 2001, 2271-2277.
[58] A. Miiller, S. K. Das, C. Kuhlmann, H. B6gge, M. Schmidtmann, E. Diemann, E. Krickemeyer, J. Hormes, H. Modrow, M. Schindler. On the option of generating novel type surfaces with multiphilic ligands wihtin the??cavity of a giant metal-oxide based wheel type cluster: chemical reactions with well-defined nanoobjects [J]. Chem. Comm. 2001, 655-656.
[59] A. Muller, S. K. Das, H. B8gge, M. Schmidtmann. Generation of cluster capsules (I_h) from decomposition products of a smaller cluster (Keggin - T_d) while surviving ones get encapsulated: species with core-shell topology formed by a fundamental symmetry-driven reaction [J]. A. Botar, Chem. Comm., 2001,657-658.
[60] A. Miiller, R. Maiti, M. Schmidtmann, H. Bogge, S. K. Das, W. Zhang. Mimicking oxide surfaces: different types of defects and ligand coordination at well defined positions of a molybdenum oxide based nanocluster [J]. Chem. Comm. 2001, 2126-2127.
[61] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, P. Kogerler, C. Rosu, E. Beckmann. "Nanoobjects" by Self-Assembly Concomitant with Modifications under Alterable Boundary Conditions: Incorporation of Paramagnetic Metal Centers (Cu~(2+)) in Ring-Shaped Molybdenum-Oxide Based Clusters [J]. Angew. Chem. Int. Ed., 2001, 40: 4034-4037.
[62] A. Miiller, E. Beckmann, H. B6gge, M. Schmidtmann, A. Dress. Inorganic Chemistry Goes Protein Size: A Mo_(368) Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int. Ed., 2002,41: 1162-1167.
[63] A. Muller, B. Botar, S. K. Das, H. Bogge, M. Schmidtmann, A. Merca. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron, 2004, 23: 2381-2385.
[64] A. Muller, E. Diemann, S. Q. N. Shah, C. Kuhlmann, M. C. Letzel. Soccer-playing metal oxide giant spheres: a first step towards patterning structurally well defined nano-object collectives [J]. Chem. Comm., 2002, 440-441.
[65] A. Muller, S. K. Das, M. Talismanova, H. Bogge, P. K6gerler, M. Schmidtmann, S. Talismanov, M. Luban, E. Krickemeyer. Paramagnetic??Keplerate "Necklaces" Synthesized by a Novel Room-Temperature Solid-State Reaction: Controlled Linking of Metal-Oxide-Based Nanoparticles [J]. Angew. Chem. Int. Ed. 2002,41: 579-582.
[66] A. Muller, S. Roy, M. Schmidtmann, H. Bogge. Urea as "deus ex machine" in giant molybdenum blue type cluster synthesis: an unusual hybrid compound with perspectives for related nano, supramolecular and extended structures [J]. Chem. Comm., 2002,2000-2002.
[67] L. Cronin, C. Beugholt, E. Krickemeyer, M. Schmidtmann, H. B5gge, P. K6gerler, T. K. K. Luong, A. Muller. "Molecular Symmetry Breakers" Generating Metal-Oxide-Based Nanoobject Fragments as Synthons for Complex Structures: [{Mo_(128)Eu_4O_(388)H_(10)(H_2O)_(81)}_2]~(20-), a Giant-Cluster Dimer [J]. Angew. Chem. Int. Ed., 2002,41:2805-2808.
[68] A. Miiller, E. Krickemeyer, H. Bogge, M. Schmidtmann, S. Roy, A. Berkle. Changeable Pore Sizes Allowing Effective and Specific Recognition by a Molybdenum-Oxide Based "Nanosponge": En Route to Sphere-Surface and Nanoporous-Cluster Chemistry [J]. Angew. Chem. Int. Ed., 2002, 41: 3604-3609.
[69] A. Muller, B. Botar, P. Kogerler, A. Berkle. A potassium selective "nanosponge" with well defined pores [J]. Chem. Comm., 2002, 2944-2945.
[70] L. Cronin, E. Diemann, A. Muller. Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls [M]. In: Inorganic Experiments (Ed.: J. D. Woollins), Wiley-VCH, Weinheim, 2003,340-346.
[71] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Botar, M. O. Talismanova. Drawing Samll Cations into Highly Charged Porous Nanocontainers Reveals "Water" Assembly and Related Interaction Problems [J]. Angew. Chem. Int. Ed., 2003,42: 2085-2090.
[72] A. Muller, L. Toma, H. Bogge, M. Schmidtmann, P. Kogerler. Synergetic activation of "silent receptor" sites leading to a new type of inclusion complex: integration of a 64-membered ring comprising K~+ and SO_4~(2-) ions into a molybdenum oxide-based nanoobject [J]. Chem. Comm., 2003,??2000-2001.
[73] A. Muller, S. K. Das, S. Talismanov, S. Roy, E. Beckmann, H. Bogge, M. Schmidtmann, A. Merca, A. Berkle, Y. Zhou, L. Zhang. Trapping Cations in Specific Positions in Tuneable 'Artificial Cell' Channels: New Nanochemistry Perspectives [J]. Angew. Chem. Int. Ed., 2003, 42: 5039-5044.
[74] A. Muller, S. K. Das, E. Krickemeyer, C. Kuhlmann. Polyoxomolybdate Clusters: Giant Wheels and Balls [J]. Inorganic Syntheses 34 (Ed.: J. R. Shapley), Wiley, New York, 2004,191-200.
[75] A. Muller, Y. Zhou, L. Zhang, H. Bogge, M. Schmidtmann, M. Dressel, J. van Slageren. En route to coordination chemistry under confined conditions in a porous capsule: Pr~(3+) with different coordination shells [J]. Chem. Comm., 2004,2038-2039.
[76] A. Muller, S. K. Das, P. Kogerler, H. Bogge, M. Schmidtmann, A. X. Trautwein, V. Schunemann, E. Krickemeyer, W. Preetz. A New Type of Supramolecular Compound: Molybdenum-Oxide-Based Composites Consisting of Magnetic Nanocapsules with Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a Two-Dimensional Network [J]. Angew. Chem. Int. Ed., 2000, 39: 3413-3417.
[77] A. Mttller, H. Reuter, S. Dillinger. Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts [J]. Angew. Chem. Int. Ed. Engl., 1995,34:2328-2361.
[78] A. Muller, F. Peters, MT Pope, D. Gatteschi. Polyoxometalates: Very Large Strucrures-Nanoscale Magnets[J]. Chem. Rev., 1998, 98: 239-271.
[79] A. Muller, P. K6gerler. From Simple Building Blocks to Structures with Increasing Size and Complexity [J]. Coord. Chem. Rev., 1999,182: 3-17.
[80] A. Muller, P. Kogerler, C. Kuhlmann. A Variety of Combinatorially Linkable Units as Disposition: From a Giant Icosahedral Keplerate to Multi-Oxide Based Network Structures [J]. J. Chem. Soc, 1999; 1347-1358.
[81] J. Fielden , L. Cronin, C. Beugholt and A. Muller. Towards the Construction??of Mesoscopic Species with Emergent and Functional Properties via the Derivatisation of Molybdenum-Oxide 'Giant-Wheel' Cluster [J]. J. Mol. Struct. (Theochem), 2000,500:181-193.
[82] A. Muller, P. KOgerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology:'From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001,222:193-218.
[83] P. Kdgerler, A. Muller. Chemistry with Nanoparticles: Linking of Ring-and Ball- Shaped Species [M]. In: "Polyoxometalate Chemistry for Nano-Composite Design", (Eds. T. Yamase, M. T. Pope). Kluwer, New York, 2002,pp.1-15.
[84] A. Muller, S. Roy. En Route From the Mystery of Molybdenum Blue via Related Manipulatable Building Bolcks to Aspects of Materials Science [J]. Coord. Chem. Rev., 2003,245:153-166.
[85] C. N. R. Rao, A. Mttller, A. K. Cheetham. Nanomaterials-An Introduction [M]. In "The Chemistry of Nanomaterials: Synthesis, Properties and Applications", Vol. I (Eds. C. N. R. Rao, A. Muller, A. K. Cheetham). Wiley-VCH, Weinheim, 2004,1-11.
[86] M.T. Pope, A. Mttller. Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines [J]. Angew. Chem. Int. Ed. Engl., 1991,30: 34-48.
[87] M.I. Khan, A. Mttller, S. Dillinger, H. Bogge, Q. Chen, J. Zubieta. Cation Inclusion within the Mixed-Valence Polyanion Cluster [(Mo~(VI)O_3)_4Mo~V_(12)O_(28)(OH)_(12)]~(8-): Syntheses and Structures of (NH_4)_7[NaMo_(16)(OH)_(12)O_(40)] 4H_2O and (Me_2NH_2)_6[H-2Mo_(16)(OH)_(12)O_(40)] [J]. Angew. Chem. Int. Ed., 1993,32:1780-1781.
[88] A. Muller, S. Dillinger, E. Krickemeyer, H. Bogge, W. Plass, A. Stammler, R.C. Haushalter. [H_2 in (Mo~V_2O_4)_6O_4(μ_2-OH)_(12)(Mo~(VI)O_3_4]~(6-) and [Na in {(Mo~V_2O_4)_3(μ_2-OH)_3H(PhPO_3)_4}_2]~(7-): A Further Example for the Validity of the Concept of Unit Construction in Polyoxometalate Chemistry [J]. Z. Naturforsch. B, 1997,52:1301-1302.
[89] P. Mialane, A. Dolbecq, L. Lisnard, A. Mallard, J. Marrot, F. Secheresse. [3-PMo_(12)O_(36)(OH)_4-{La(H_2O)_4}_4]~(5+): The First 3-PMo_(12)O_(40) Keggin ion and its association with the two-electron-reduced 3-PMo_(12)O_(40) Isomer [J]. Angew. Chem. Int. Ed., 2002,41:2398-2401.
[90] A. Muller, M. C. R. Henry. Nanocapsule Water-based Chemistry [J]. Compt. Rend. Chim., 2003,6:1201-1208.
[91] A. Muller, S. K. Das, E. Krichemeyer, P. Kogerler, H. Bogge, M. Schmidtmann. Cross-linking nanostructured spherical capsules as building units by crystal engineering: related chemistry [J]. Solid state Science, 2000, 2: 847-854.
[92] F. Al-Ali, A. Brun, F. Rodrigues, G. Etemad-Moghadam, I. Rico-Lattes. New Catanionic Amphiphiles Derived from the Associative Systems (α. -Hydroxyalkyl)-phosphinic or ( α -Hydroxyalkyl)-phosphonic Acid/Cetyltrimethylammonium Hydroxide. Preparation, Characterization, and Self-Organization Properties [J]. Langmuir, 2003,19:6678-6684.
[93] A. Meister, M. Dubois, L. Belloni, T. Zemb. Equation of State of Self-Assembled Disklike and Icosahedral Crystallites in the Dilute range [J]. Langmuir, 2003,19: 7259-7263.
[94] H.Q. Yin, M. Mao, J.B. Huang, H.L. Fu. Two-Phase Region in the DTAB/SL mixed Surfactant System [J]. Langmuir, 2002,18: 9198-9203.
[95] R. Beck, Y. Abe, T. Terabayashi, H. Hoffmann. A Novel L3-Phase from a Ca-Salt of an Anionic Surfactant and a Cosurfactant [J]. J. Phys. Chem. B, 2002,106: 3335-3338.
[96] A. Zapf, U. Homfeck, G Platz, H. Hoffmann. Investigation of the L3 Phase in Systems Containing Calcium Dodecyl Sulfate, Alcohol, and Water [J]. Langmuir, 2001,17:6113-6118.
[97] A. Zapf, R. Beck, G Platz, H. Hoffmann, "Calcium Surfactant: A Review [J]", Advances in Colloid and Interface Science, 2003,100 -102:349-380.
[98] J. L. Anderson, V. Pino, E. C. Hagberg, V. V. Sheares, D. W. Armstrong. Surfactatn Solvation Effects and Miccelle Formation in Ionic Liquids [J]. ??Chem. Comm., 2003,2444-2445.
[99] T. Nakashima, N. Kimizuka. Vesicles in Salt: Formation of Bilayer Membranes from Dialkyldimethylammonium. Bromides in Ether-containing Ionic Liquids. Chem. Lett., 2002,10:1018-1019.
[100] D.C. Steytler, E. Rumsey, M. Thorpe, J. Eastoe, R.K. Heenan. Phosphate Surfactants for Water-in-CO_2 Microemulsions. Langmuir, 2001, 17: 7948-7950.
[101] D.A. Canelas, D.E. Berts, J.M. Desimone. Dispersion polymerization of styrene in supercritical carbon-dioxide-importance of effective surfactants [J]. Macromolecules, 1996,29:2818-2821.
[102] J. Hao. Microemulsion polymerization of acrylamide and styrene: effect of the structures of reaction media [J]. J. Polym. Sci. Part A: Polym. Chem., 2001,39:3220-3234.
[103] H. Klaus, H. Hoffmann, J. Hao. Classic La-phases as opposed to vesicle phases in cationic-anionic surfactant mixtures [J]. J. Phys. Chem. B., 2000, 104:2781-2784.
[104] J. Hao. Effect of the structures of microemulsions on chemical reactions [J]. Colloid. Poly. Sci., 2000,278:150-154.
[105] J. Hao. Studies on chemical reactions in microemulsion media (I) hydrolysis kinetics studies in microemulsion system for CTAB/n-butano/25% n-octane/water [J]. J. Dispersion Sci. Tech., 2000,21(1): 19-30.
[106] J. Hao, J. Hu, S. Shang, H. Liu. C NMR and ESR studies on the association between sodium 3-dodecylether-2-hydroxyproply-l-sulfonate and polyvinyl-pyn-olidone [J]. J. Dispersion Sci. Tech., 1999,20(5): 1345-1357.
[107] J. Hao, W. Liu, G. Xu, L. Zheng. Vesicles from salt-free cationic-anionic surfactant solutions [J]. Langmuir, 2003,19: 10635-10640. .
[108] J. Hao, Z. Yuan, W. Liu, H. Hoffmann. In Situ Vesicle Formation by a Kinetic Reaction in Aqueous Mixtures of Single-Tailed Catanionic Surfactants [J]. J. Phys. Chem. B., 2004,108: 5105-5112.
[109] A. Song, S. Dong, X. Jia, J. Hao, W. Liu, T. Liu. An Onion Phase in Salt-Free??Zero-Charged Catanionic Surfactatn Solutions [J]. Angew. Chem. Int. Ed., 2005,44:4018-4021.
[110] J. Hao, A. Song, J. Wang, X. Chen. W. Zhuang. F. Shi, F. Zhou, W. Liu. Self-assembled structure in room-temperature ionic liquids [J]. J. Phys. Chem. B, 2005,109(22): 11126-11134.
[111] A. Song, X. Jia, M. Tehg, J. Hao. Ca~(2+)-and Ba~(2+)-ligand coordinated unilamellar, multilamellar, and oligovesicular vesicles [J]. Chem. Eur. J., 2007,13:496-501.
[112] J. Hao, J. Wang, W. Liu, H. Hoffmann. Zn~(2+)-induced vesicle formation. J. Phys. Chem. B, 2004,108(4): 5105-5112.
[113] J. Wang, A. Song, X. Jia, J. Hao, W. Liu, H. Hoffmann. Two route to vesicle formation: Metal-ligand complexation and ionic interactions [J]. J. Phys. Chem. B., 2005,109: 11126-11134.
[114] M. Winterhalter, W. Helfrich. Bending elasticity of electrically charged bilayers: coupled monolayers, neutral surfaces, and balancing stresses [J]. J. Phys. Chem., 1992,96: 327-330.
[115] F. A. M. Leermakers, J. M. H. M. Scheutjens. Statistical thermodynamics of association colloids, 2, Lipid vesicles [J]. J. Phys. Chem., 1989, 93: 7417-7426.
[116] S. A. Safran, P. A. Pincus, D. A. Andelman. Stability and phase behavior of mixed surfactant vesicles [J]. Science, 1990,248: 354-356.
[117] T. Liu. Supramolecular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124: 10942-10943.
[118] A. Mtuller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant" molecular wheels [J]. Chem. Commun., 2001:1928-1929.
[119] Rounding Up Nanoclusters-Nanotechnology. Materialstoday, 2004,7(1): 10.
[120] M. T. Pone and A. Muller. polvoxometalates: From Diatonic solids to antiretroviral activity [M]. Kluwer Dordrecht, The Netherlands, 1994.78.
[121] I. V. Kozhevnikov. Catalysis by Heteropoly Acids and Multicomponent Polyoxometalates in Liquid-Phase Reactions [J]. Chem, Rev., 1998, 98: 171-198.
[122] N. Mizuno, M. Misono. Heterogeneous Catalysis [J]. Chem. Rev., 1998, 98: 199--217.
[123] I. A. Weinstock. Homogeneous-Phase Electron-Transfer Reactions of Polyoxometalates [J]. Chem. Rev., 1998,98: 113-170.
[124] M. Sadakane, E. Steckhan. Electrochemical Properties of Polyoxometalates as Electrocatalysis [J], Chem. Rev., 1998,98:219-237.
[125] T. Yamase. Photo-and Electrochromism of Polyoxometalates and Related Materials [J]. Chem. Rev., 1998,98: 307-325.
[126] J. T. Rhule, C. L. Hill, D. A. Judd, R. F. Schinazi. Polyoxometalates in Medicine [J]. Chem. Rev., 1998,98: 327-357.
[127] D. E. Katsoulis. A survey of applications of polyoxometalates [J]. Chem. Rev., 1998,98:359-387.
[128] J. H. Fendler. Nanoparticles and nanostructured films: preparation, characterization, and applications [M]. Wiley-VCH, Weinheim, 1998,56-89.
[129] M. Clemente-leon, C. Mingotaud, B. Agricole, C. J. Gomez- Barcia, E. Coronado, P. Delhaes. Application of the Langmuir-Blodget technique to polyoxometalates: towards new magnetic films [J]. Angew, Chem. Int. Ed. Engl., 1997,36:1114-1116.
[130] C. G. Janauer, A. Dobley, J.D. Guo, P. Zavalij, M. S. Whittingham. Novel Tungsten, Molybdenum, and Vanadium Oxides Containing Surfactant Ions [J]. Chem. Mater., 1996,8:2096-2101.
[131] A. Stein, M. Fendorf, T. P. Jarvie, K.T. Muller, A. J. Tenesi, T. E. Mallouk. Salt-Gel Synthesis of Porous Transition-Metal Oxides [J]. Chem. Mater., 1995,7:304-313.
[132] D. G. Kurth, P. Lehmann, D. Volkmer, H. Co1fen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters (SECs): ??385-393.
[133] P. M. Harrison, P. Arosio. The Ferritins: Molecular Properties, Iron Storage Function and Cellular, Regulation [J]. Biochim, Biophys. Acta -Bioenergetics, 1996,1275:161-203.
[134] A. M. Donald, A. H. Windle. Liquid Crystalline Polymers [M]. Vol. 1 Cambridge University Press, Cambridge, 1992,18-32.
[135] P. G. de Gennes, J. Prost. The physics of Liquid Crystals [M]. Oxford University Press, Oxford, 1995.
[136] J. N. Murrel, A. D. Jenkins. Properties of Liquids and Solutions, 2nd ed. [M]. Wiley, New York, NY, 1993,215-236.
[137]赵国玺，朱步瑶．表面活性剂作用原理[M]．中国轻工业出版社，2003， 267-279.
[138] V. Luzzati, H. Mustacchi, A. Skoulios. The structures of the liquid-crystal phases of some soap and water systems [J]. Discuss. Faraday Soc, 1958, 25: 43-50.
[139] F. B. Rosevear. reaction of alkyl iodides with aryliodoso derivatives [J]. J. Am. Oil Chem. Soc, 1954, 31: 628-639.
[140] J. M. Corkill, J. F. Goodman, T. Walker, J. Wyer. The multiple equilibrium model of micelle formation [J]. Proc. Roy. Soc. 1969, A 312: 243-255.
[141] P. Ekwall. Advances Liquid Crystals [M]. Brown G H. ed. Vol 3 New York: Acdemic press, 1978.41.
[142] K. Fontell, K. K. Fox, E. Hansson. On the structures of the cubic phase 1L in some lipid-water systems [J]. Mol. Cryst. Liquid, Cryst. Lett., 1985,1: 9-17.
[143] V. Luzzati. Biological Membranes [M]. D. Chapman, ed. New York: Academic Press, 1986. Ch 3.
[144] K. Fontell. Cubic phases in surfactant and surfactant-like lipid systems [M]. Colloid Polym. Sci., 1990,268:264-285.
[145] J. P. Gabriel, P. Davidson. New trends in colloidal liquid crystals based on mineral moieties m Adv Mater 2000 12:9-20 .
[146] A. S. Sonin. Introduction to physics of liquid crystals [J]. Colloid, J., 1998,
??60:129-151.
[147] J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T.-W. Chu, D. H. Olson, E. W. Sheppard, S. B. McCullen, J. B. Higgins, J. L. Schlenker. A new family of mesoporous molecular sieves prepared with liquid crystal templates [J]. J. Am.' Chem. Soc, 1992, 114: 10834-10843.
[148] D. M. Antonelli, M. Trudeau. Phase changes and electronic properties in toroidal mesoporous molybdenum oxides [J]. Angew. Chem. 1999, 111: 1555-1559. Angew. Chem. Int. Ed., 1999,38:1471-1475.
[149] S. Polarz, B. Smarsly, M. Antonietti. Colloidal organization and clusters: self-assembly of polyoxometalate-surfactant complexes towards three-dimensional organized structures [J]. ChemPhysChem, 2001, 7: 457-461.
[150] M. Antonietti, S. Henke, A. Thunemann. Highly ordered, mesomorphosus materials with ultra-low surface energies: polyelectrolyte-surfactant complexes with fluorinated surfaces [J]. Adv. Mater., 1996,8: 41-45.
[151] M. Antonietti, C. Burger, A. Th u nemann. Polyelectrolyte-surfactant complexes: a new class of highly ordered polymer materials [J], TRIP, 1997, 5:262-267.
[152] M. Antonietti, C. Burger, A. Thunemann. Polyelectrolyte-liquid complexes as membrane mimetic systems [J]. Curr. Opin. Colloid Interf. Sci., 1996, 1: 667-671.
[153] S. Polarz, B. Smarsly, C. Goltner, M. Antonietti. The interplay of colloidal organization and oxo-cluster chemistry: polyoxometalate-silica hybrids-materials with a nanochemical function [J]. Adv. Mater., 2000, 12:1503-1507.
[154] S. S. Kim, W. Z. Zhang, T. J. Pinnavaia. Ultralstable mesostructured silica vesicles [J]. Science, 1998,282:1302-1305.
[155] D. H. W. Hubert M. June. P. M. Frederik. P. H. H, Bomans. J. Meuldiik. A. L.German. Vesicle-directed growth of silica [J]. Adv. Mater., 2000, 12:??1286-1290.
[156] D. H. W. Hubert, M. Jung, A. L. German. Vesicle templating [J]. Adv. Mater, 2000,12:1291-1294.
[157] S. Chiruvolu, S. Walker, J. Israelachvili, F. -J. Schmitt, D. Leckband, J. A. Zasadzinski. Higher order self assembly of vesicles by site specific binding [J]. Science, 1994,264 : 1753-1756.
[158] S. A. Walker, M. T. Kennedy, J. A. Zasadzinski. Encapsulation of bilayer vesicles by self-assembly [J]. Nature, 1997,387: 61-64.
[159] Y. Jin, L. Bi, Y. Shao, S. Dong. Bobust core-shell supramolecular assemblies based on cationic vesicles and ring-shaped {Mo_(154)} polyoxomolybdate nanoclusters: template-directed synthesis and characterizations [J]. Chem. Eur. J., 2004,10:3225-3231.
[1] C. W. Scheele, Samtliche Physische und Chemische Werke [M]. Hermbstadt, D. S. F. Ed. Martin Sandig oHG: Niederwalluf/Wiesbaden, 1971, 1: 185 (reprint: original 1793).
[2] Berzelius, J. J. Beitrag zur naheren Kenntniss des Molybdans. Poggend. Ann. Phys. Chem. 1826,6: 369-392.
[3] A. Muller, S. K. Das, E. Krickemeyer, C. Kuhlmann, Polyoxomolybdate Clusters: Giant Wheels and Balls [M], J. Shapley (Ed.), Wiley, New York Inorg. Synth. 2004,34: 191-200.
[4] L. Cronin, E. Diemann, A. Muller, Polyoxomolybdate Clusters: Nanoscopic Wheels and Balls in Inorganic Experiments [M], J.D. Woollins (Ed), Wiley-VCH Weinheim, 2003,340-346.
[5] A. Muller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. B6gge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na_(15)[Mo_(154)~(VI)Mo_(28)~VO_(426)H_(14)(H_2O)_(70)]_(0.5)[Mo_(124)~(VI)Mo_(28)~VO_(457)H_(14)(H_2O)_(68)]_(0.5).ca.400H_2O and Na_(22)[Mo_(118)~(VI)Mo~(28)~VO_(442)H_(14)(H_2O)_(58)]-ca.250H_2O [J]. Z. Anorg. Allg. Chem. 1999,625:1187-1192.
[6] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. B5gge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[7] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew.Chem.Int.Ed., 1998,37: 3359-3363.
[8] A. Muller, B. Botar, S. K. Das, H. Bogge, M. Schmidtmann, A. Merca. On the??complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron 2004,23:2381-2385.
[9] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters. J. Clust. Sci., 2003, 14(3): 215-226.
[10] A. Muller, P. Kdgerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev. 2001,222:193-218.
[1] A. Muller, P. Kogerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001,222: 193-218.
[2] A. Miiller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions:Na_(15)[Mo~(VI)_(126)Mo~V_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5)[Mo~(VI)_(124)Mo~V_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5) ca.400 H_2O and Na_(22)[Mo~(VI)_(118)Mo~V_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. anorg.allg. Chem., 1999,625: 1187-1192.
[3] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters.Organizational Forms of Matter: An Inorganic Super Fullerene and KeplerateBased on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37:3359-3363.
[4] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh.Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann.Archimedean Synthesis and Magic Numbers: "Sizing" GiantMolybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J].Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[5] T. Liu; E. Diemann, H. Li, A.W.M. Dres, A. Miiller. Self-assembly in aqueoussolution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003,426: 59-62.
[6] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A.Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant"molecular wheels [J]. Chem. Commun., 2001: 1928-1929.
[7] T. Liu. Supramolecular structures of polyoxomolybdate-based GiantMolecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124:10942-10943.
[8] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc, 2003, 125: 312-313.
[9] T. Liu. Surfactant-Induced Trans-Interface Transportation and Complex Formation of Giant Polyoxomolybdate-Based Clusters [J]. J. Clust. Sci., 2003, 14:215-226.
[10] S. Polarz, B. Smarsly, M. Antonietti. Colloidal Organization and Clusters: Self-Assembly of Polyoxometalate-Surfactant Complexes towards Three-Dimensional Organized Structures [J]. ChemPhyChem., 2001, 7: 457-461.
[11] D. G Kruth, P. Lehmann, D. Volkmer, A. Muller, D. Schwahn. Biologically inspired polyoxometalate-surfactant composite materials. Investigations on the structures of discrete, surfactant-encapsulated clusters, monolayers, and Langmuir-Blodgett films of (DODA)_(40)(NH_4)_2[(H_2O)n in Mo_(132)O_(372)(CH_3CO_2)_(30)(H_2O)_(72)] [J]. J. Chem. Soc. Dalton Trans., 2000, 21: 3989-3998.
[12] D. G Kurth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters(SECs):(DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] [J]. Chem. Eur. J., 2000, 6: 385-393.
[13] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G Kruth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Krebs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme [J]. J. Am. Chem. Soc, 2002,124(35): 10489-10496.
[14] Z. Persin, K. Stana-Kleinschek, T. Kreze. Hydrophilic/Hydrophobic Characteristics of Different Cellulose Fibres Monitored by Tensiometry [J]. Croat. Chem. Acta., 2002, 75: 271-280.
[15]庄国波， 徐为勃．表面张力测定的几张方法[J]．江苏广播电视大学学报， 1994，4：60-63．
[16]赵国玺，朱步瑶．表面活性剂作用原理[M]．中国轻工业出版社，2003，, 2003, 94-105.
[17] D. G. Kruth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. D. Chesne. Surfactant-Encapsulated Clusters (SECs): (DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(83)(H_2O)_(18)], a Case Study. Chem. Eur. J., 2000,6:385-393.
[18] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G. Kurth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Kerbs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme. J. Am. Chem. Soc., 124,10489-10496.
[19] C. Tanford. Micelle Shape and Size. J. Phys. Chem., 76,3020-3024.
[20] 颜肖慈，罗明道．界面化学[M]．化学工业出版社，2004，117．
[21]董元彦，李宝华，路福绥．物理化学[M]．科学出版社，1999，172．
[22] P. C. Hiemenz, R. Rajagopalan. Principles of Colloid and Surface Chemistry (Marcel Dekker, New York). Third Ed, Revised and expanded. 1997,12.
[23] C. Burger, J. Hao, Q. Ting, H. Isobe, M. Sawamura, E. Nakamura, B. Chu. Multilayer Vesicles and Vesicle Clusters Formed by the Fullerene-Based Surfactant C6o(CH_3)_5K [J]. J. Colloid Inter. Sci.,2004,275:632-641.
[1] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[2] A. Muller, V. P. Fedin, C. Kuhlmann, H. Bogge, M. Schmidtmann. A hydrogen-bonded cluster with "onion-type" structure, encapsulated and induced by a spherical cluster shell: [(H_2O)_n in Mo~(VI)_(72)MoV_(60)O_(372)(HCO_2)_(30)(H_2O)_(72)]~(42-) [J]. Chem. Comm., 1999,927-928.
[3] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999,38:3238-3241.
[4] A. Muller, S. Polarz, S. K. Das, E. Krickemeyer, H. Bogge, M. Schmidtmann, B. Hauptfleisch. "Open and Shut" for Guests in Molybdenum-Oxide-Based Giant Spheres, Baskets, and Rings Containing the Pentagon as a Common Structural Element [J]. Angew. Chem. Int. Ed. Engl., 1999,38: 3241-3245.
[5] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, C. Beugholt, P. Kdgerler, C. Lu. Formation of a Ring-Shaped Reduced "Metal Oxide" with the Simple Composition [(MoO_3)_(176)(H_2O)_(80)H_(32)] [J]. Angew. Chem. Int. Ed. Engl., 1998,37:1220-1223.
[6] A. Mailer, M. Koop, H. Bogge, M. Schmidtmann, C. Beugholt. Exchanged ligands on the surface of a giant cluster: [(MoO_3)_(176)(H_2O)_(63)(CH_3OH)_(17)H_n]~((32-n))-[J]. Chem. Comm., 1998,1501-1502.
[7] A. Muller, S. Q. N. Shah, H. Bogge, M. Schmidtmann. Molecular growth from a Mo_(176) to a Mo_(248) cluster [J]. Nature, 1999,397:48-50.
[8] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, P. Kogerler, C. Rosu, E. Beckmann. "Nanoobjects" by Self-Assembly Concomitant with??Modifications under Alterable Boundary Conditions: Incorporation of Paramagnetic Metal Centers (Cu~2+)) in Ring-Shaped Molybdenum-Oxide Based Clusters [J]. Angew. Chem. Int. Ed., 2001,40:4034-4037.
[9] A. Muller, E. Beckmann, H. Bdgge, M. Schmidtmann, A. Dress. Inorganic Chemistry Goes Protein Size: A Mo_(368) Nano-Hedgehog Initiating Nanochemistry by Symmetry Breaking [J]. Angew. Chem. Int. Ed., 2002, 41: 1162-1167.
[10] A. Muller, B. Botar, S. K. Das, H. B6gge, M. Schmidtmann, A. Merca. On the complex hedgehog-shaped cluster species containing 368 Mo atoms: simple preparation method, new spectral details and information about the unique formation [J]. Polydedron, 2004,23:2381-2385.
[11] T. Liu; E. Diemann, H. Li, A.W.M. Dress, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426:59-62.
[12] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Tak, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant molecular wheels" [J]. Chem. Commun., 2001:1928-1929.
[13] Y. Zhu, A. Cammers-Goodwin, B. Zhao, A. Dozier, E. C. Dickey. Kinetic Precipitation of Solution-Phase Polyoxomolybdate Followed by Transmission Electron Microscopy: A Window to Solution-Phase Nanostructure [J]. Chem. Eur. J., 2004,10:2421-2427.
[14] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc., 2003,125: 312-313.
[15] B. Chen, H. Jiang, Y. Zhu, A. Cammers, J. P. Selegue. Monitoring the Growth of Polyoxomolybdate Nanoparticles in Suspension by Flow Field-Flow Fractionation [J]. J. Am. Chem. Soc, 2005,127:4166-4167. .
[16] T. Liu. Supramolecular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc, 2002, 124: 10942-10943; 2004, 126:406. (Add/Cor.)??{Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions. Lagmuir, 2005,21: 2713-2720.
[18] G. Liu, Y. Cai, T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc, 2004,126: 16690-16691.
[19] G. Liu, T. Liu. Strong attraction among the fully hydrophilic {Mo(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc, 2005,127: 6942-6943.
[20] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters[J]. J. Clust. Sci., 2003, 14(3): 215-226.
[21] G. Liu, M. Cons, T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005,118: 27-29.
[22] G. Liu, T. Liu, S. S. Mal, U. Kortz. Wheel-Shaped Polyoxotungstate [Cu_(20)Cl(OH)_(24)(H_2O)_(12)(P_8W_(48)O_(184))]~(25-) Macroanions Form Supramolecular "Blackberry" Structure in Aqueous Solution [J]. J. Am. Chem. Soc., 2006, 128(31): 10103-10110.
[23] T. Liu, B. Imber, E. Diemann, G. Liu, K. Cokleski, H. Li, Z. Chen, A. Muller. Deprotonations and Charges of Weil-Defined {Mo_(72)Fe_(30)} Nanoacids Simply Stepwise Tuned by pH Allow Control/Variation of Related Self-Assembly Processes [J]. J. Am. Chem. Soc, 2006,128:15914-15920.
[24] A. Song, S. Dong, X. Jia, J. Hao, W. Liu, T. Liu. An Onion Phase in Salt-Free Zero-Charged Cationionic Surfactant Solutions [J]. Angew. Chem. Int. Ed., 2005,44:4018-4021.
[25] J. Wang, A. Song, X. Jia, J. Hao, W. Liu, H. Hoffmann. Two Routes to Vesicle Formation: Metal-Ligand Complexation and Ionic Interactions [J]. J. Phys. Chem. B, 2005,109: 11126-11134.
[26] H. Li, X. Jia, Y. Li, X. Shi, J. Hao, A Salt-Free Zero-Charged Aqueous Onion-Phase Enhances the Solubility of Fullerene C_(60) in Water [J]. J. Phys. Chem. B, 2006,110:68-74.
[27] Y. Li, H. Li, X. Jia, X. Jia, J. Hao, W. Liu. Electrochemical Behavior of C_(60) films and C_(60)/Lipid Films in Ionic Liquids [J]. Carbon, 2006,44: 894-899.
[28] F. Menger, V. Seredyuk, M. Kitaeva, A. Yaroslavov, N. Melik-Nubarov. Migration of Poly-L-lysine through a Lipid Bilayer [J]. J. Am. Chem. Soc, 2003,125:2846-2847.
[29] Y.-C. Tan, K. Hettiarachchi, M. Siu, Y.-R. Pan, A. P. Lee. Controlled Microfluidic Encapsulation of Cells, Proteins, and Microbeads in Lipid Vesicles [J]. J. Am. Chem. Soc, 2006,128: 5656-5658.
[30] B. Peker, J. J. Wuu, J. R. Swartz. Affinity Purification of Lipid Vesicles [J]. Biotechnol. Prog., 2004,20:262-268.
[31] F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann. Advanced Inorganic Chemistry [M]. 6~(th) ed, Wiley: New York, 1999.
[32] M. T. Pope, A. Muller. Polyoxometalate Chemistry: An Old Field with New Dimensions in Veral Disciplines [J]. Angew. Chem. Int. Ed., 1991,30: 34-48.
[33] L. Verhoef, M. L. Kistler, A. Bhatt, J. Groenewold, M. Klokkenburg, S. Veen, S. Roy, T. Liu, W. Kegel. Charge Regulation as a Stabilization Mechanism for Shell-Like Structures. Phy. Rev. Lett, unpublished data.
[34] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed., 1998, 37: 3360-3363.
[35] D. Long, L. Cronin. Towards Polyoxometalate-Integrated Nanosystems [J]. hem. Eur. J., 2006,12: 3698-3706.
[36] 赵徐声．碱金属[M]．上海教育出版社，1981，4．
[1] 贾祥凤，范大伟，唐培芹，郝京诚，马丽英，刘天波．纳米级无机聚钼酸盐“二级有序聚集体”[J]．物理化学学报，2006，22(10)：1300-1304． Cited by Elsevier. X. Jia, D. Fan, P. Tang, J. Hao, L. Ma, T. Liu. "Second Organized Structures" of Nanoscale Inorganic Polyoxomolybdate Compounds [J]. Acta. Phys.-Chim. Sin. 2006 22(10): 1300-1304.
[2] T. Liu, E. Diemann, H. Li, A.W.M. Dress, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426: 59-62.
[3] G. Liu, T. Liu. Strong attraction among the fully hydrophilic {Mo_(72)Fe_(30)} macroanions [J]. J. Am. Chem. Soc., 2005, 127: 6942-6943.
[4] G. Liu, Y. Cai, T. Liu. An automatic and subsequent dissolution and precipitation process in inorganic macroionic solutions [J]. J. Am. Chem. Soc., 2004, 126: 16690-16691.
[5] G. Liu, M. Cons, T. Liu. The ionic effect on supramolecular associations in polyoxomolybdate solution [J]. J. Mol. Liq., 2005, 118: 27-29.
[6] G. Liu, T. Liu. Thermodynamic properties of the unique self-assembly of {Mo_(72)Fe_(30)} inorganic macro-ions in salt-free and salt-containing aqueous solutions. Lagmuir, 2005, 21: 2713-2720.
[7] T. Liu. Surfactant-induced trans-interface transportation and complex formation of giant polyoxomolybdate-based clusters. J. Clust. Sci., 2003, 14(3): 215-226,
[8] T. Liu. Supramolecular Structures of Polyoxomolybdate-Based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc. 2002, 124: 10942-10943.
[9] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc. 2003, 125:312-313.
[10] L. A. Matheson, N. Nichols. The Cathode Ray Oscillograph Applied to the Dropping Mercury Electrode [J]. Trans. Electrochem. Sot., 1938, 73: 193-210.
[11] J. E. B. Randles. A Cathode Ray Polarograph [J]. Trans. Faraday Soc., 1948, 44: 322-327.
[12] J. E. B. Randles. A Cathode Ray Polarograph. Part Ⅱ.—The Current-Voltage Vurves [J]. Trans. Faraday Soc., 1948, 44: 327-338.
[13] A. Sevcik. Oscillographic Polargraphy with Periodic Triangular Voltage [J]. Collect. Czech. Chem. Commun., 1948, 13: 348-377.
[14] 查全性．电极过程动力学导论(第三版)[M]．北京科学出版社，2002．89-112．
[15] 刘永辉．电化学测试技术(第一版)[M]．北京航空学院出版社，1987．46-72。
[16] 陈永乐，杨孙楷．膜伏安法及其在分析化学中的应用[M]．北京地质出版社，1987，23-45．
[17] 黄慰曾，高小霞，杨文治(F．Anson讲授)．电化学和电分析化学[M]．北京大学出版社，1983，16-32．
[1] Scheele, C. W.; In Samtliche Physische und Chemische Werke (ed. Hermbstadt, DSF) Ed. Martin Sandig OHG: Niederwalluf/Wiesbaden, 1971, 1:185 (reprint: original 1793)
[2] Liu, T.; Diemann, E.; Li, H.; Dress, AWM; Muller, A. Nature, 2003, 426: 59-62.
[3] Liu, G.; Liu, T. J. Am. Chem. Soc., 2005, 127: 6942-6943.
[4] Liu, G.; Cai, Y.; Liu, T. J. Am. Chem. Soc., 2004, 126: 16690-16691.
[5] Liu, G.; Cons, M.; Liu, T. J. Mol. Liq., 2005, 118: 27-29.
[6] Liu, G.; Liu, T. Lagmuir, 2005, 21: 2713-2720.
[7] Liu, T. J. Clust. Sci., 2003, 14: 215-226.
[8] (a) Muller, A.; Das, S. K.; Krickemeyer, E.; Kuhlmann, C. Inorg. Synth., 2004, 34: 191-200. (b) Cronin, L.; Diemann, E.; Muller, A. Inorganic Experiments, 2003: 340-346.
[9] Muller, A.; Krichemeyer, E.; Bogge, H.; Schmidtmann, M.; Peters, F. Angew. Chem. Int. Ed., 1998, 37: 3360-3363.
[10] Muller, A.; Fedin, V. P.; Kuhlmann, C.; Bogge, H.; Schmidtmann, M. Chem. Commun., 1999: 927-928.
[11] Muller, A.; Sarkar, S.; Shah, S. Q. N.; Bogge, H.; Schmidtmann, M.; Sarkar, Sh.; Kogerler, P.; Hauptfleisch, B.; Trautwein, A. X.; Schunemann, V. Angew, Chem, Int. Ed., 1999, 38: 3238-3241.
[12] Muller, A.; Polarz, S.; Krichemeyer, S. K. E.; Bogge, H.; Schmidtmann, M.; Hauptfleisch, B. Angew, Chem. Int. Ed., 1999, 38. 3241-3244.
[13] Muller, A.; Kogerler, P.; Kuhlmann, C. Chem. Commun.; 1999: 1347-1348.
[14] Muller, A.; Krichemeyer, E.; Bogge, H.; Schmidtmann, M.; Beugholt, C.; Kogerler, P.; Lu, C.Angew, Chem. Int. Ed., 1998, 37: 1220-1223.
[15] Jiang, C. C., Wei, Y. G.; Liu, Q.; Zhang, S. W.; Shao, M. C.; Tang, Y. Q. Chem. Commun, 1998: 1937-1938.
[16] Muller, A.; Koop, M.; Bogge, H.; Schmidtmann, M.; Teugholt, C. Chem. Commun., 1999: 1501-1502.
[17] Muller, A.; Shan, S. Q. N.; Bogge, H.; Schmidtmann, M. Nature, 1999, 397:48
[18] Muller, A.; Beckmann, E.; Bogge, H.; Schmidtmann, M.; Kogerler, P.; Rosu, C.; Beckmann, E. Angew. Chem. Int. Ed., 2001, 40: 4034-4037.
[19] (a) Muller, A.; Beckmann, E.; Bogge, H.; Schmidtmann, M.; Dress, A. Angew. Chem. Int. Ed., 2002, 41:1162-1165. (b) Muller, A.; Botar, B.; Das, S. K.; Bogge, H.; Schmidtmann, M.; Merca, A. Polyhedron 2004, 23: 2381-2385.
[20] Muller, A.; Henry, M. CR. Chimie, 2003, 6: 1201-1208.
[21] Muller, A.; Meyer, J.; Krickemeyer, E.; Beugholt, C., Bogge, H.; Peters, F.; Schmidtmann, M.; Kogeder, P.; Koop, M. J. Chem. Eur. J., 1998, 4: 1000-1006.
[22] Muller, A.; Peters, F.; Pope, M. T.; Gattesehi, D. Chem. Rev., 1998, 98. 239-271.
[23] Muller, A.; Roy, S.; Coord. Chem. Rev., 2003, 245: 153-166.
[24] Muller, A.; Diemann, E.; Kuhlmann, C.; Eimer, W.; Serain, C.; Tak, T.; Knochel, A.; Pranzas, P. K. ChemComm 2001: 1928-1929.
[25] Rounding up nanoclusters, Materialstoday, 2004, 7(1): 10
[26] Hao, J.; Hoffmann, H. Curr. Opin. Colloid Inter. Sci. 2004, 9: 279-281.
[27] Polarz, S.; Smarsly, B.; Antoniett, M.; Chemphyschem, 2001, 7: 457-461.
[28] Kurth, D. G.; Lehmann, P.; Volkmer, D.; Kogerler, P.; Sarkar, S.; Bogge, H.; Schmidtmann, M.; Sarkar, Sh. Chem. Eur. J., 2000, 6: 385-393.
[29] Bu, W.; Li, H.; Sun, H.; Yin, S.; Wu, L. J. Am. Chem. Soc., 2005, 127: 8016-8017.
[30] Volkmer, D.; Chesne, A. D.; Kurth, D. G.; Schmablegger, H.; Lehmann, P.; Koop, M. J.. Am. Chem. Soc., 2000, 122: 1995-1996.
[1] A. MUller, P. Kogerler, A.W.M. Dress. Giant Metal-Oxide-Based Spheres and Their Topology: From Pentagonal Building Blocks to Keplerates and Unusual Spin Systems [J]. Coord. Chem. Rev., 2001, 222: 193-218.
[2] A. Muller, S. K. Das, V. P. Fedin, E. Krickemeyer, C. Beugholt, H. Bogge, M. Schmidtmann, B. Hauptfleisch. Rapid and Simple Isolation of the Crystalline Molybdenum-Blue Compounds with Discrete and Linked Nanosized Ring-Shaped Anions: Na_(15) [Mo~(Ⅵ)_(126)Mo~(Ⅴ)_(28)O_(462)H_(14)(H_2O)_(70)]_(0.5) [Mo~(Ⅵ)_(124)Mo~(Ⅴ)_(28)O_(457)H_(14)(H_2O)_(68)]_(0.5) ca. 400 H_2O and Na_(22)[Mo~(Ⅵ)_(118)Mo~(Ⅴ)_(28)O_(442)H_(14)(H_2O)_(58)] ca. 250 H_2O [J]. Z. anorg. allg. Chem., 1999, 625: 1187-1192.
[3] A. Muller, E. Krickemeyer, H. Bogge, M. Schmidtmann, F. Peters. Organizational Forms of Matter: An Inorganic Super Fullerene and Keplerate Based on Molybdenum Oxide [J]. Angew. Chem. Int. Ed. Engl., 1998, 37: 3359-3363.
[4] A. Muller, S. Sarkar, S. Q. Nazir Shah, H. Bogge, M. Schmidtmann, Sh. Sarkar, P. Kogerler, B. Hauptfleisch, A. X. Trautwein, V. Schunemann. Archimedean Synthesis and Magic Numbers: "Sizing" Giant Molybdenum-Oxide-Based Molecular Spheres of the Keplerate Type [J]. Angew. Chem. Int. Ed. Engl., 1999, 38: 3238-3241.
[5] T. Liu; E. Diemann, H. Li, A.W.M. Dres, A. Muller. Self-assembly in aqueous solution of wheel-shaped Mo_(154) oxide clusters into vesicles [J]. Nature, 2003, 426: 59-62.
[6] A. Muller, E. Diemann, C. Kuhlmann, W. Eimer, C. Serain, T. Talc, A. Knochel, P. K. Pranzas. Hierarchic patterning: architectures beyond "giant" molecular wheels [J]. Chem. Commun., 2001: 1928-1929.
[7] T. Liu. Supramoleeular structures of polyoxomolybdate-based Giant Molecules in Aqueous Solution [J]. J. Am. Chem. Soc., 2002, 124: 10942-10943.
[8] T. Liu. An Unusually Slow Self-Assembly of Inorganic Ions in Dilute Aqueous Solution [J]. J. Am. Chem. Soc., 2003, 125: 312-313.
[9] T. Liu. Surfactant-Induced Trans-Interface Transportation and Complex Formation of Giant Polyoxomolybdate-Based Clusters [J]. J. Clust. Sci., 2003, 14: 215-226.
[10] (a)S. Polarz, B. Smarsly, M. Antonietti. Colloidal Organization and Clusters: Self-Assembly of Polyoxometalate-Surfactant Complexes towards Three-Dimensional Organized Structures [J]. ChemPhyChem., 2001, 7: 457-461. (b) D. G. Kruth, P. Lehmann, D. Volkmer, A. Muller, D. Schwahn. Biologically inspired polyoxometalate-surfactant composite materials. Investigations on the structures of discrete, surfactant-encapsulated clusters, monolayers, and Langrnuir-Blodgett films of (DODA)_(40)(NH_4)_2[(H_2O)n in Mo_(132)O_(372)(CH_3CO_2)_(30)(H_2O)_(72)] [J]. J. Chem. Soc. Dalton Trans., 2000, 21: 3989-3998.
[11] D. G. Kurth, P. Lehmann, D. Volkmer, H. Colfen, M. J. Koop, A. Muller, A. Du Chesne. Surfactant-encapsulated clusters (SECs): (DODA)_(20)(NH_4)[H_3Mo_(57)V_6(NO)_6O_(183)(H_2O)_(18)] [J]. Chem. Eur. J., 2000, 6: 385-393.
[12] D. Volkmer, B. Bredenkotter, J. Tellenbroker, P. Kogerler, D. G. Kruth, P. Lehmann, H. Schnablegger, D. Schwahn, M. Piepenbrink, B. Krebs. Structure and Properties of the Dendron-Encapsulated Polyoxometalate (C_(52)H_(60)NO_(12))_(12)[(Mn(H_2O))_3(SbW_9O_(33))_2], a First Generation Dendrizyme [J]. J. Am. Chem. Soc., 2002, 124(35): 10489-10496.
[13] C. Tanford. Micelle Shape and Size. J. Phys. Chem., 76, 3020-3024.
[14] P. C. Hiemenz, R. Rajagopalan. Principles of Colloid and Surface Chemistry (Marcel Dekker, New York). Third Ed, Revised and expanded. 1997, 12.
[1] Liu, T.; Diemann, E.; Li, H.; Dress, A. W. M.; Muller, A. Nature 2003, 426, 59-62.
[2] Muller, A.; Diemann, E.; Kuhlmann, C.; Eimer, W.; Serain, C.; Tak, T.; Knochel, A.; Pranzzas, P. K. Chem. Commun. 2001, 1928-1929.
[3] Zhu, Y.; Cammers-Goodwin, A.; Zhao, B.; Dozier, A.; Dickey, E. C. Chem. Eur. J. 2004,10, 2421-2423.
[4] Liu, T. J. Am. Chem. Soc. 2003, 125, 312-313.
[5] Chen, B.; Jiang, H.; Zhu, Y.; Cammers, A.; Selegue, J. P. J. Am. Chem. Soc. 2005, 127, 4166-4167.
[6] Liu, T. J.. Am. Chem. Soc. 2002, 124, 10942-10943; 2004, 126, 406-407 (Add./Cor.).
[7] Liu, G.; Liu, T. Langmuir, 2005, 21, 2713-2720.
[8] Liu, G.; Cai, Y.; Liu, T. J. Am. Chem. Soc. 2004, 126, 16690-16691.
[9] Liu, G.; Liu, T. J. Am. Chem. Soc. 2005, 127, 6942-6943.
[10] Liu, T. J. Clust. Sci., 2003, 14, 215-226.
[11] Liu, G.; Cons, M., Liu, T. J. Mol. Liq., 2005, 118, 27-29.
[12] Liu, G.; Liu, T.; Mal, S. S.; Kortz, U. J.. Am. Chem. Soc. 2006, 128, 10103-10104.
[13] Muller, A.; Kogerler, P.; Kuhlmann, C. Chem. Commun. 1999, 1347-1348.
[14] Cronin, L.; in Comprehensive Coordinatioon Chemistry Ⅱ, Vol. 7 ed. McClevety, J. A.; Meyer, T. J. Elsvier, Amsterdam, 2004, P.1.
[15] Long, D. Cronin L. Chem. Eur. J. 2006, 12, 3698-3701.
[16] Verhoef, L.; Kistler, M. L.; Bhatt, A.; Groenewold, J.; Klokkenburg, M.; Veen, S.; Roy, S.; Liu, T.; Kegel, W. Phy. Rev. Lett unpublished data.
[17] Liu, T.; Imber, B.; Diemann, E.; Liu, G.; Cokleski, K.; Li, H.; Chen, Z.; Muller, A. J. Am. Chem. Soc. Unpublished data.
[18] Muller, A.; Sarkar, S.; Shah, S. Q. N.; Bogge, H.; Schmidtmann, M.; Saarkar, S.; Koerler, P.; Hauptfleisch, B.; Trautwein, A. X.; Schunemann, V. Angew. Chem., Int. Ed. Engl. 1999, 38, 3238-3241.
[19] Muller, A.; Krickemeyer, E.; Bogge, H.; Schmidtmann, M.; Peters, F. Angew.Chem. Int. Ed. 1998, 37, 3360-3363.
[20] Provencher, S. W. Biophys. J. 1976, 16, 29-31.
[21] Watanabe, M.; Sakairi, K.; Inoue, M. J. Electroanal. Chem. 1994, 375, 415-417.
[22] Zana, R. J.. Colloid Inter. Sci. 1980, 78, 330-332.