摘要
苯酚是工业废水中常见的污染物,其危害已引起世界各国的普遍重视。生物法能够利用微生物的新陈代谢作用将其降解并转化为无害物质,是目前最通用的苯酚废水处理技术之一。本文开展三相鼓泡塔及气升式环流生物反应器固定化热带假丝酵母处理苯酚废水过程中局部瞬态流体流动、相间传质及生物降解性能的实验、理论模型与数值模拟研究,在生物法处理苯酚废水技术领域具有广阔的应用前景,同时在多相复杂生物反应过程模型化方面也具有重要的学术研究价值。
首先分别建立了模拟气液固三相鼓泡塔及气升式环流反应器局部流体力学特性动态行为特征的三维瞬态计算流体力学(CFD)模型,并采用多尺度组分(MUSIG)模型描述气泡尺寸分布行为。通过模型模拟计算分别得到了三相鼓泡塔及气升式环流反应器内的局部时均流体力学特性如气含率、轴向液相速度等随表观气速、轴向高度、固体粒子加入量等操作条件的变化规律,并采用电导探头及三维激光多普勒测速仪实验测量结果验证了该模型的可靠性。同时应用该CFD模型分别合理预测了三相鼓泡塔及气升式环流反应器内的局部瞬态流体力学特性如气含率、固含率、液相速度和气泡尺寸等的时空分布。
然后分别建立了模拟气液固三相鼓泡塔及气升式环流生物反应器固定化热带假丝酵母细胞降解苯酚间歇过程降酚性能动态行为特征的三维瞬态CFD模型,模型耦合了三相流体流动、组分相间传质和本征生化反应的相互作用,并采用MUSIG模型描述气泡尺寸分布行为。通过模型模拟计算分别得到了三相鼓泡塔及气升式环流生物反应器内的体积平均流体力学特性、组分质量浓度及组分相间质量输运源项差等随表观气速、初始苯酚浓度、固体粒子加入量等操作条件的变化规律,并通过高效液相色谱及溶氧电极实验测量数据与体积平均液相溶氧和苯酚浓度随时间变化的模型模拟结果进行比较,验证了该模型的可靠性。通过组分相间质量输运源项的比较,发现组分相间传质是过程的限速步骤。同时应用该CFD模型分别合理预测了三相鼓泡塔及气升式环流生物反应器固定化苯酚降解过程中局部瞬态降酚性能的动态行为特征如气含率、平均气泡直径、液相速度、气液固各相氧浓度、液固各相苯酚浓度、固相菌体浓度和气泡尺寸等的时空分布。
最后对三相鼓泡塔和气升式环流生物反应器固定化热带假丝酵母苯酚降解性能的CFD模型模拟结果进行了比较,证实气升式环流生物反应器流型规整,苯酚降解性能优于鼓泡塔生物反应器。
Phenol is a common pollutant in many industrial effluents, whose damage to the environment as well as to human beings has given rise to the worldwide concern about its effective treatment. Bio-treatment method, which can degrade phenol and then transform it into harmless substances through microorganisms’metabolism effect, has become one of the most popular phenol wastewater treatment methods. The experimentation, theoretical modeling and numerical simulation study on the local transient multi-phase fluid flow, interfacial mass transfer and biodegradation characteristics of the batch phenol biodegradation by immobilized Candida tropicalis in the gas-liquid-solid three-phase bubble column and airlift loop bioreactors, will definitely find its wide application in the field of phenol wastewater bio-treatment, as well as in the aspect of scientific learning of the complicated multi-phase bio-reaction process modeling.
Firstly, the three-dimensional (3D) transient computational fluid dynamics (CFD) model has been set up for simulating the dynamic behaviors of the local hydrodynamics in the gas-liquid-solid three-phase bubble column and airlift loop reactors respectively, with multi size group (MUSIG) model adopted to describe the bubble size distribution behaviors. The local time-averaged hydrodynamics such as gas holdup and axial liquid velocity changing with the varied operating conditions such as superficial gas velocity, axial position and solid loading in the three-phase bubble column and airlift loop reactors are calculated through model simulations respectively, and the reliability of the model is validated through the experimental results obtained by conductivity probe and 3D Laser Doppler Anemometry. At the same time, the time and space distributions of the local transient hydrodynamics such as gas holdup, solid holdup, liquid velocity and bubble size in the three-phase bubble column and airlift loop reactors are reasonably predicted by the developed CFD model respectively.
Secondly, the 3D transient CFD model has been set up for simulating the dynamic behaviors of the batch phenol biodegradation characteristics by immobilized Candida tropicalis in the gas-liquid-solid three-phase bubble column and airlift loop bioreactors respectively, coupling of the interactions of the three-phase fluid flow, species interfacial mass transfer and intrinsic bio-reaction, with the MUSIG model adopted to describe the bubble size distribution behaviors. The volume-averaged hydrodynamics, species mass concentrations and species interfacial mass transport source differences changing with the varied operating conditions such as superficial gas velocity, initial phenol concentration and solid loading in the three-phase bubble column and airlift loop bioreactors are calculated through model simulations respectively, and the reliability of the model is validated through the experimental results of the liquid phase oxygen and phenol mass concentrations obtained by DO electrode and HPLC. It is found that the species interfacial mass transfer is the rate-limiting step in the process through comparison between the species interfacial mass transport sources. At the same time, the time and space distributions of the local transient dynamic behaviors of the immobilized batch phenol biodegradation such as gas holdup, Sauter mean bubble diameter, liquid velocity, gas, liquid and solid phase oxygen mass concentrations, liquid and solid phase phenol mass concentrations, solid phase cell concentration and bubble size in the three-phase bubble column and airlift loop bioreactors are reasonably predicted by the developed CFD model respectively.
At last, phenol biodegradation behaviors between the three-phase bubble column bioreactor and the three-phase airlift loop bioreactor are compared through CFD model simulations, which confirm that the airlift loop bioreactor has a more regular flow pattern, and a better phenol biodegradation performance compared with the bubble column bioreactor.
引文
[1] Bajaj M, Gallert C, Winter J, Biodegradation of high phenol containing synthetic wastewater by an aerobic fixed bed reactor, Bioresource Technology, 2008, 99(17): 8376~8381
[2] Hsieh FM, Huang C, Lin TF, et al., Study of sodium tripolyphosphate-crosslinked chitosan beads entrapped with Pseudomonas putida for phenol degradation, Process Biochemistry, 2008, 43: 83~92
[3] Chen YM, Lin TF, Huang C, et al., Cometabolic degradation kinetics of TCE and phenol by Pseudomonas putida, Chemosphere, 2008, 72(11): 1671~1680
[4] Sevillano X, Isasi JR, Penas FJ, Feasibility study of degradation of phenol in a fluidized bed bioreactor with a cyclodextrin polymer as biofilm carrier, Biodegradation, 2008, 19(4): 589~597
[5] Kim JH, Oh KK, Lee ST, et al., Biodegradation of phenol and chlorophenols with defined mixed culture in shake-flasks and a packed bed reactor, Process Biochemistry, 2002, 37(12): 1367~1373
[6] Aksu Z, Akpinar D, Kabasakal E, et al., Simultaneous biosorption of phenol and nickel from binary mixtures onto dried aerobic activated sludge, Process Biochemistry, 1999, 35(3-4): 301~308
[7] Oller ALW, Agostini E, Talano MA, et al., Overexpression of a basic peroxidase in transgenic tomato (Lycopersicon esculentum Mill. cv. Pera) hairy roots increases phytoremediation of phenol, Plant Science, 2005, 169(6): 1102~1111
[8] Lante A, Crapisi A, Krastanov A, et al., Biodegradation of phenols by laccase immobilised in a membrane reactor, Process Biochemistry, 2000, 36(1-2): 51~58
[9] Christoskova ST, Stoyanova M, Degradation of phenolic waste waters over Ni-oxide, Water Research, 2001, 35(8): 2073~2077
[10] WHO, Phenol, Environmental Health Criteria-EHC 161, World Health Organization, Geneva, 1994
[11]姚华群,液相色谱法测定工业废水中苯酚,兰化科技,1998,16(4):240~242
[12]张锦,李圭白,马军,含酚废水的危害及处理方法的应用特点,化学工程师,2001,83(2):36~37
[13]陆爱民,含酚废水处理技术的现状与进展,高桥石化,2001,16(5):48~50
[14]张海涛,我国含酚废水处理技术研究进展,上海环境科学,2001,20(2):60~62
[15]蔡永源,含酚废水处理技术,化工进展,1996(6):27~30,62
[16]张海涛,黄霞琼,近期含酚废水处理研究动态,上海化工,2001,26(14):4~6
[17]曾炳蔚,郑景涛,我国含酚废水处理技术应用近况,石化技术,1997,4(1):63~66
[18]乌锡康,有机化工废水治理技术,北京:化学工业出版社,1999
[19] Magne P, Walker PL, Phenol adsorption on GAC: application to the regeneration of GACs polluted with phenol, Carbon, 1986, 24(2): 101~107
[20]张全兴,刘天华,我国应用树脂吸附法处理有机废水的进展,化工环保,1994,14(6):344~347
[21]戴酞元,杨义燕,杨天雪,络合萃取法处理苯酚废水技术,化工进展,1991,6:40~46
[22]孙贤波,杜慧芳,乳化液膜法提取苯酚的动力学研究,环境化学,1999,18(1):46~51
[23]潘碌亭,肖锦,乳化液膜技术在分离有机物中的应用进展,膜科学与技术,1999,19(5):19~22
[24]曾炳蔚,郑景涛,我国含酚废水处理技术的应用近况,化工时刊,1997,11 (7):18~21,17
[25] Wan YH, Wang XD, Zhang XJ, Treatment of high concentration wastewater by liquid membrane with N503 as mobile carrier, Journal of Membrane Science, 1997, 135(2): 263~270
[26]雷乐成,水处理高级氧化技术,北京:化学工业出版社,2001
[27]陈云华,周鑫玉,潘玲等,臭氧氧化去除水中芳香族化合物机理初探,化工环保,1998,18(2):74~81
[28] Yang SX, Li X, Zhu WP, et al., Catalytic activity, stability and structure of multi-walled carbon nanotubes in the wet air oxidation of phenol, Carbon, 2008, 46(3): 445~452
[29] Ayude A, Rodriguez T, Font J, et al., Effect of gas feed flow and gas composition modulation on activated carbon performance in phenol wet air oxidation, 2007, 62(24): 7351~7358
[30] Wang JB, Zhu WP, Yang SX, et al., Catalytic wet air oxidation of phenol with pelletized ruthenium catalysts, Applied Catalysis B-Environmental, 2008, 78(1-2): 30~37
[31] Barner HE, Huang CY, Johnson T, et al., Supercritical water oxidation: an emerging technology, Journal of Hazardous Materials, 1992, 31(1): 1~17
[32]丁军委,冯成武,陈丰秋等,超临界水氧化法处理含酚废水,环境污染与防治,2000,22(1):1~3,46
[33] Hayashi R, Ohkuma K, Tonokura K, et al., Contribution of ionic reactions to sub-and supercritical water oxidation of phenol, Journal of Chemical Engineering of Japan, 2007, 40(7): 556~564
[34] Gondal MA, Sayeed MN, Seddigi Z, Laser enhanced photo-catalytic removal of phenol from water using p-type NiO semiconductor catalyst, 2008, 155(1-2): 83~89
[35] Mario S, Photocatalysis and environment: trends and applications, Kluwer Academic, Academic Publishers, 1998
[36] Pourabbas B, Jamshidi B, Preparation of MoS2 nanoparticles by a modified hydrothermal method and the photo-catalytic activity of MoS2/TiO2 hybrids in photo-oxidation of phenol, Journal of Hazardous Materials, 2008, 138(1-3): 55~62
[37] Iurascu B, Siminiceanu I, Vincente M, Phenol degradation in water through a heterogeneous photo-fenton process, Environmental Engineering and Management Journal, 6(6): 479~482
[38] Chen CL, Wu JH, Liu WT, Identification of important microbial populations in the mesophilic and thermophilic phenol-degrading methanogenic consortia, Water Research, 42(8-9): 1963~1976
[39] Tepe O, Dursun AY, Combined effects of external mass transfer and biodegradation rates on removal of phenol by immobilized Ralstonia eutropha in a packed bed reactor, Journal of Hazardous Materials, 2008, 151(1): 9~16
[40] Bruno F, Curini R, Di Corcia A, et al., Determination of surfactants and some of their metabolites in untreated and anaerobically digested sewage sludge by subcritical water extraction followed by liquid chromatography-mass spectrometry, Environmental Science and Technology, 2000, 36(19): 4156~4161
[41] Pinto RTP, Lintomen L, Luz LFL, et al., Strategies for recovering phenol from wastewater: thermodynamic evaluation and environmental concerns, Fluid Phase Equilibria, 2005, 228(SI): 447~457
[42] Contreras EM, Albertario ME, Bertola NC, et al., Modelling phenol biodegradation by activated sludges evaluated through respirometric techniques, Journal of Hazardours Materials, 2008, 158(2-3): 366~374
[43] Dapaah SY, Hill GA, Biodegradation of chlorophenol mixtures by Pseudomonas putida, Biotechnology and Bioengineering, 1992, 40(11): 1353~1358
[44] Hinteregger C, Leitner R, Loidl M, et al., Degradation of phenol and phenolic compounds by Psuedomonas putida EKII, Applied Microbiology and Biotechnology, 1992, 37(2): 252~259
[45] Chitra S, Sekaran G, Padmavathi S, et al., Removal of phenolic compounds from wastewater using mutant strain of Pseudomonas pictorum, The Journal of General and Applied Microbiology, 1995, 41: 229~237
[46] Iliuta I, Larachi F, Modeling simultaneous biological clogging and physical plugging in trickle-bed bioreactors for wastewater treatment, Chemical Engineering Science, 2005, 60(5): 1477~1489
[47] Li DY, Eberspacher J, Wagner B, et al., Degradation of 2,4,6-trichlorophenol by Azotobacter sp. strain GP1, Applied and Environmental Microbiology, 1991, 57(7): 1920~1928
[48] Morsen A, Rehm HJ, Degradation of phenol by mixed culture of Pseudomonas putida and Cryptococcus elinovii absorbed on activated carbon, Applied Microbiology and Biotechnology, 1987, 26(3): 283~288
[49] Kozel TR, Virulence factors of Cryptococcus neoformans, Trends Microbiology, 1995, 3(8): 295~299
[50] Bergauer P, Fonteyne PA, Nolard N, et al., Biodegradation of phenol and phenol-related compounds by Psychrophilic and cold-tolerant alpine yeasts, Chemosphere, 2005, 59(7): 909~918
[51] Chen WM, Chang JS, Wu CH, et al., Characterization of phenol and trichloroethene degradation by the Rhizobium Ralstonia taiwanensis, Research in Microbiology, 2004, 155(8): 672~680
[52] Semple KT, Cain RB, Metabolism of phenols by Ochromonas danica, FEMS Microbiology Letters, 1995, 133(3): 253~257
[53] Semple KT, Cain RB, Degradation of phenol and its methylated homologues by Ochromonas danica, FEMS Microbiology Letters, 1997, 152(1): 133~139
[54] Semple KT, Heterotrophic growth on phenolic mixtures by Ochromonas danica, Research in Microbiology, 1998, 149(1): 65~72
[55] Kim MH, Hao OJ, Cometabolic degradation of chlorophenols by Acinetobacter species, Water Research, 1999, 33(2): 562~574
[56] Benndorf D, Loffhagen N, Babel W, Protein synthesis patterns in Acinetobacter calcoaceticus induced by phenol and catechol show specificities of responses to chemostress, FEMS Microbiology Letters, 2001, 200(2): 247~252
[57] Borde X, Guieysse B, Delgado O, et al., Synergistic relationships in algal-bacterial microcosms for the treatment of aromatic pollutants, Bioresource Technology, 2003, 86(3): 293~300
[58] Kanekar P, Sarnaik S, Kelkar A, Microbial technology for management of phenol bearing dyestuff wastewater, Water Science and Technology, 1996, 33(8): 47~51
[59] Zhang XL, Gao PP, Chao QF, et al., Microdiversity of phenol hydroxylase genes among phenol-degrading isolates of Alcaligenes sp. from an activated sludge system, FEMS Microbiology Letters, 2004, 237(2): 369~375
[60] Rehfuss M, Urban J, Alcaligenes faecalis subsp. Phenolicus subsp. nov. a phenol-degrading, denitrifying bacterium isolated from a graywater bioprocessor, 107Systematic and Applied Microbiology, 2005, 28(5): 421~429
[61] Clement P, Matus V, Cardenas L, Degradation of trichlorophenols by Alcaligenes eutrophus JMP134, FEMS Microbiology Letters, 1995, 127(1-2): 51~55
[62] Hill GA, Milne BJ, Nawrocki PA, Cometabolic degradation of 4- chlorophenol by Alcaligenes eutrophus, Applied Microbiology and Biotechnology, 1996, 46(2): 163~168
[63] Valenzuela J, Bumann U, Cespedes R, et al., Degradation of chlorophenols by Alcaligenes eutrophus JMP134 (pJP4) in bleached kraft mill effluent, Applied and Environmental Microbiology, 1997, 63(1): 227~232
[64] Luke AK, Burton SG, A novel application for Neurospora crassa: Progress from batch culture to a membrane bioreactor for the bioremediation of phenols, Enzyme and Microbial Technology, 2001, 29(6-7): 348~356
[65] Larmar RT, Larsen MJ, Kirt TK, Sensitivity to and degradation of pentachlorophenol by Phanerochaete sp., Applied and Environmental Microbiology, 1990, 56(11): 3519~3526
[66] Perez RR, Benito GG, Miranda MP, Chlorophenol degradation by Phanerochaete chrysosporium, Bioresource Technology, 1997, 60(3): 207~213
[67] Chen KC, Lin YH, Chen WH, et al., Degradation of phenol by PAA-immobilized Candida tropicalis, Enzyme and Microbial Technology, 2002, 31(4): 490~497
[68] Fialova A, Boschke E, Bley T, Rapid monitoring of the biodegradation of phenol-like compounds by the yeast Candida maltosa using BOD measurements, International Biodeterioration & Biodegradation, 2004, 54(1): 69~76
[69] Godjevargova T, Aleksieva Z, Ivanova D, Cell immobilization of Trichosporon cutaneum strain with phenol degradation ability on new modified polymer carriers, Process Biochemistry, 2000, 35(7): 699~704
[70] Aleksieva Z, Ivanova TD, Godjevargova T, et al., Degradation of some phenol derivatives by Trichosporon cutaneum R57, Process Biochemistry, 2002, 37(11): 1215~1219
[71] Godjevargova T, Ivanova D, Alexieva Z, et al., Biodegradation of toxic organic components from industrial phenol production waste waters by free and immobilized Trichosporon cutaneum R57, Process Biochemistry, 2003, 38(6): 915~920
[72]姜岩,Candida tropicalis激光育种技术及其降酚特性研究:[博士学位论文],天津;天津大学,2005
[73] Morita M, Kudo N, Uernoto H, et al., Protective effect of immobilized ammonia oxidizers and phenol-degrading bacteria on nitrification in ammonia- and phenol-containing wastewater, Engineering in Life Sciences, 2007, 7(6): 587~592
[74] Ozaki H, Liu Z, Terashima Y, Utilization of microorganisms immobilized with magnetic particles for sewage and wastewater treatment, Water Science and Technology, 1991, 23(4-6): 1125~1136
[75] Annadurai G, Babu SR, Mahesh KPO, et al., Adsorption and bio-degradation of phenol by chitosan-immobilized Pseudomonas putida (NICM 2174), Bioprocess Engineering, 2000, 22(6): 493~501
[76] Branyik T, Kuncova G, Paca J, The use of silica gel prepared by sol-gel method and polyurethane foam as microbial carriers in the continuous degradation of phenol, Applied Microbiology and Biotechnology, 2000, 54(2): 168~172
[77] Chen KC, Lin YH, Chen WH, et al., Degradation of phenol by PAA-immobilized Candida tropicalis, Enzyme Microbial Technology, 2002, 31(4): 490~497
[78] Chung TS, Loh KC, Goh SK, Development of cellulose acetate membranes for bacteria immobilization to remove phenol, Journal of Applied Polymer Science, 1998, 68(10): 1677~1688
[79] Chung TP, Wu PC, Juang RS, Use of microporous hollow fibers for improved biodegradation of high-strength phenol solutions, Journal of Membrane Science, 2005, 258(1-2): 55~63
[80] Godjevargova T, Aleksieva Z, Ivanova D, Cell immobilization of Trichosporon cutaneum strain with phenol degradation ability on new modified polymer carriers, Process Biochemistry, 2000, 35(7): 699~704
[81] Pazarlioglu NK, Telefoncu A, Biodegradation of phenol by Pseudomonas putida immobilized on activated pumice particles, Process Biochemistry, 2005, 40(5): 1807~1814
[82] Beshay U, Abd-El-Haleem D, Moawad H, et al., Phenol biodegradation by free and immobilized Acinetobacter, Biotechnology Letters, 2002, 24(15): 1295~1297
[83]鲁路,海藻酸盐水溶液凝胶化转变的临界行为:[博士学位论文],华南理工大学,2006
[84] Aksu Z, Bulbui G, Determination of the effective diffusion coefficient of phenol in Ca-alginate-immobilized P. putida beads, Enzyme and Microbial Technology, 1999, 25(3-5): 344~348
[85] Karel SF, Libicki SB, Robertson CR, The immobilization of whole cells: engineering principles, Chemical Engineering Science, 1985, 40(8): 1321~1354
[86] Bandhyopadhyay K, Das D, Bhattacharyya P, et al., Reaction engineering studies on biodegradation of phenol by Pseudomonas putida MTCC 1194 immobilized on calcium alginate, Biochemical Engineering Journal, 2001, 8(3): 179~186
[87] Chung TP, Tseng HY, Juang RS, Mass transfer effect and intermediate detection for phenol degradation in immobilized Pseudomonas putida systems, ProcessBiochemistry, 2003; 38(10): 1497~1507
[88] Pai SL, Hsu YL, Chong NM, et al., Continuous degradation of phenol by Rhodococcus sp. immobilized on granular activated carbon and in calcium alginate, Bioresource Technology, 1995, 51(1): 37~42
[89] Torres LG, Sanchez-de-la-Vega A, Beltran NA, et al., Production and characterization of a Ca-alginate biocatalyst for removal of phenol and chlorophenols from wastewaters, Process Biochemistry, 1998, 33(6): 625~634
[90] Yang PY, Wang ML, Packed-emrapped-mixed microbial cells for small wastewater treatment, Water Science and Technology,1990, 22(3): 343~350
[91] Aksu Z, Bulbui G, Investigation of the combined effects of external mass transfer and biodegradation rates on phenol removal using immobilized P. Putida in a packed-bed column reactor, Enzyme and Microbial Technology, 1998, 22(4): 397~403
[92] Anselmo AM, Novais JM, Degradation of phenol by immobilized mycelium of Fusarium flocciferum in continuous culture, Water Science and Technology, 1992, 25(1): 161~168
[93] Bandhyopadhyay K, Das D, Maiti BR, Solid matrix characterization of immobilized Pseudomonas putida MTCC 1194 used for phenol degradation, Applied Microbiology and Biotechnology, 1999, 51(6): 891~895
[94] Bettmann H, Rehm HJ, Degradation of phenol by polymer entrapped microorganism, Applied Microbiology and Biotechnology, 1984, 20(5): 285~290
[95] Juarez-Ramirez C, Ruiz-Ordaz N, Cristiani-Urbina E, et al., Degradation kinetics of phenol by immobilized cells of Candida tropicalis in fluidized bed reactor, World Journal of Microbiology & Biotechnology, 2001, 17(7): 697~705
[96]周定,侯文华,固定化微生物法处理含酚废水的研究,环境科学,1990,11(1):2~5
[97] Kantarci N, Borak F, Ulgen KO, Bubble column reactors, Process Biochemistry, 2005, 40(7): 2263~2283
[98] Wen JP, Jia XQ, Cheng XR, et al., Characteristics of three-phase internal loop airlift bioreactors with complete gas recirculation for non-Newtonian fluids, Bioprocess and Biosystems Engineering, 2005, 27(3): 193~205
[99] Galindez-Mayer J, Ramon-Gallegos J, Ruiz-Ordaz N, et al., Phenol and 4-chlorophenol biodegradation by yeast Candida tropicalis in a fluidized bed reactor, Biochemical Engineering Journal, 2008, 38(2): 147~157
[100] Gonzalez G, Herrera MG, Garcia MT, et al., Biodegradation of phenol in a continuous process: comparative study of stirred tank and fluidized-bed bioreactors, Bioresource Technology, 2001, 76(3): 245~251
[101] Hannaford AM, Kuek C, Aerobic batch degradation of phenol usingimmobilized Pseudomonas putida, Journal of Industrial Microbiology & Biotechnology, 1999, 22(2): 121~126
[102] Kotsou M, Kyriacou A, Lasaridi K, et al., Integrated aerobic biological treatment and chemical oxidation with Fenton’s reagent for the processing of green table olive wastewater, Process Biochemistry, 2004, 39(11): 1653~1660
[103] Mordocco A, Kuek C, Jenkins R, Continuous degradation of phenol at low concentration using immobilized Pseudomonas putida, Enzyme and Microbial Technology, 1999, 25(6): 530~536
[104] Ruiz-Ordaz N, Ruiz-Lagunez JC, Castanon-Gonzalez JH, et al., Phenol biodegradation using a repeated batch culture of Candida tropicalis in a multistage bubble column, Revista Latinoamericana de Microbiologia, 2001, 43(1): 19~25
[105] Raja Rao TBML, Sonolikar RL, Pentu Saheb S, Influence of magnetic field on the performance of bubble columns and airlift bioreactor with submersed microorganisms, Chemical Engineering Science, 1997, 52(21-22): 4155~4160
[106] Shishido M, Kojima T, Araike YK, et al., Biological phenol degradation by immobilized activated sludge in gel bead with three-phase fluidized-bed bioreactor, Chemical Engineering Research & Design, Transactions of the Institute of Chemical Engineers, Part A, 1995, 73(A6): 719~726
[107] Ryan DR, Leukes WD, Burton SG, Fungal bioremediation of phenolic wastewaters in an airlift reactor, Biotechnology Progress, 2005, 21(4): 1068~1074
[108] Viggiani A, Olivieri G, Siani L, et al., An airlift biofilm reactor for the biodegradation of phenol by Pseudomonas stutzeri OX1, Journal of Biotechnology, 2006, 123(4): 464~477
[109] Zhang Y, Quan X, Rittmann BE, et al., IAL-CHS (internal airlift loop-ceramic honeycomb supports) reactor used for biodegradation of 2,4-dichlorophenol and phenol, Water Science & Technology, 2004, 49(11-12): 247~254
[110] Quan XC, Shi HC, Zhang YM, et al., Biodegradation of 2,4-dichlorophenol and phenol in an airlift inner-loop bioreactor immobilized with Achromobacter sp. Separation and Purification Technology, 2004, 34(1-3): 97~103
[111] Jakobsen HA, Lindborg H, Dorao CA, Modeling of bubble column reactors: progress and limitations, Industrial and Engineering Chemistry Research, 2005, 44(14): 5107~5151
[112] Jia XQ, Wen JP, Jiang Y, et al., Modeling of batch phenol biodegradation in internal loop airlift bioreactor with gas recirculation by Candida tropicalis, Chemical Engineering Science, 2006, 61(11): 3463~3475
[113] Monahan SM, Vitankar VS, Fox RO, CFD predictions for flow-regimetransitions in bubble columns, AIChE Journal, 2005, 51(7): 1897~1923
[114]冯伟,气液两相流生物反应器流动与降酚特性动态行为研究:[博士学位论文],天津;天津大学,2006
[115] Delnoij E, Kuipers JAM, van Swaaij WPM, Computational fluid dynamics applied to gas-liquid contactors, Chemical Engineering Science, 1997, 52(21-22): 3623~3638
[116] Lapin A, Lubbert A, Numerical simulation of the dynamics of two-phase gas-liquid flows in bubble columns, Chemical Engineering Science, 1994, 49(21): 3661~3674
[117] Sokolichin A, Eigenberger G, Gas-liquid flow in bubble columns and loop reactors: Part I, Detailed modeling and numerical simulation, Chemical Engineering Science, 1994, 49(24): 5735~5746
[118] Sokolichin A, Eigenberger G, Lapin A, et al., Dynamic numerical simulation of gas-liquid two-phase flows: Euler/Euler versus Euler/Lagrange, Chemical Engineering Science, 1997, 52(4): 611~626
[119] Pan Y, Dudukovic MP, Chang M, Numerical investigation of gas-driven flow in 2-D bubble columns, AIChE Journal, 2000, 46(3): 434~449
[120] Chen P, Sanyal J, Dudukovic MP, CFD modeling of bubble columns flows: implementation of population balance, Chemical Engineering Science, 2004, 59(22-23): 5201~5207
[121] Hagesaether L, Jakobsen HA, Svendsen HF, Modeling of the dispersed-phase size distribution in bubble columns, Industrial and Engineering Chemistry Research, 2002, 41(10): 2560~2570
[122] Lehr F, Mewes D, A transport equation for the interfacial area density applied to bubble columns, Chemical Engineering Science, 2001, 56(3): 1159~1166
[123] Lehr F, Millies M, Mewes D, Bubble-size distributions and flow fields in bubble columns, AIChE Journal, 2002, 48(11): 2426~2443
[124] Sanyal J, Marchisio DL, Fox RO, et al., On the comparison between population balance models for CFD simulation of bubble columns, Industrial and Engineering Chemistry Research, 2005, 44(14): 5063~5072
[125] van den Hengel EIV, Deen NG, Kuipers JAM, Application of coalescence and breakup models in a discrete bubble model for bubble columns, Industrial and Engineering Chemistry Research, 2005, 44(14): 5233~5245
[126] Buwa VV, Ranade VV, Dynamics of gas-liquid flow in a rectangular bubble column: experiments and single/multi-group CFD simulations, Chemical Engineering Science, 2002, 57(22-23): 4715~4736
[127] Olmos E, Gentric C, Vial C, et al., Numerical simulation of multiphase flow in bubble column reactors: Influence of bubble coalescence and break-up,Chemical Engineering Science, 2001, 56(21-22): 6359~6365
[128]袁清,气相脉冲式鼓泡塔流动与传质的实验研究及CFD数值模拟:[硕士学位论文],天津;天津大学,2007
[129] Krishna R, van Baten JM, Urseanu MI, Three-phase Eulerian simulation of bubble column reactors operating in the churn-turbulent regime: a scale-up strategy, Chemical Engineering Science, 2000, 55(16): 3275~3286
[130] Mudde RF, Simonin O, Two- and three-dimensional simulations of a bubble plume using a two-fluid model, Chemical Engineering Science, 1999, 54(21): 5061~5069
[131] Sanyal J, Vasquez S, Roy S, et al., Numerical simulation of gas-liquid dynamics in cylindrical bubble column reactors, Chemical Engineering Science, 1999, 54(21): 5071~5083
[132] Sokolichin A, Eigenberger G, Applicability of the standard k-εturbulence model to the dynamic simulation of bubble columns: Part I. Detailed numerical simulations, Chemical Engineering Science, 1999, 54(13-14): 2273~2284
[133] Delnoij E, Kuipers JAM, van Swaaij WPM, A three-dimensional CFD model for gas-liquid bubble columns, Chemical Engineering Science, 1999, 54(13-14): 2217~2226
[134] Pfleger D, Gomes S, Gilbert N, et al., Hydrodynamic simulations of laboratory scale bubble columns fundamental studies of the Eulerian-Eulerian modelling approach, Chemical Engineering Science, 1999, 54(21): 5091~5099
[135] Ranade VV, Tayalia Y, Modelling of fluid dynamics and mixing in shallow bubble column reactors: influence of sparger design, Chemical Engineering Science, 2001, 56(4): 1667~1675
[136] Deen NG, van Sint Annaland M, Kuipers JAM, Multi-scale modeling of dispersed gas-liquid two-phase flow, Chemical Engineering Science, 2004, 59(8-9): 1853~1861
[137] Delnoij E, Lammers FA, Kuipers JAM, et al., Dynamic simulation of dispersed gas-liquid two-phase flow using a discrete bubble model, Chemical Engineering Science, 1997, 52(9): 1429~1458
[138] Ekambara K, Dhotre MT, Joshi JB, CFD simulations of bubble column reactors: 1D, 2D and 3D approach, Chemical Engineering Science, 2005, 60(23): 6733~6746
[139] Krishna R, van Baten JM, Eulerian simulations of bubble columns operating at elevated pressures in the churn turbulent flow regime, Chemical Engineering Science, 2001, 56(21-22): 6249~6258
[140] Pfeger D, Becker S, Modelling and simulation of the dynamic flow behavior in a bubble column, Chemical Engineering Science, 2001, 56(4): 1737~1747
[141] Spicka P, Dias MM, Lopes JCB, Gas-liquid flow in a 2D column: Comparison between experimental data and CFD modeling, Chemical Engineering Science, 2001, 56(21-22): 6367~6383
[142] Thakre SS, Joshi JB, CFD simulation of bubble column reactors: importance of drag force formulation, Chemical Engineering Science, 1999, 54(21): 5055~5060
[143] Vitankar VS, Dhotre MT, Joshi JB, A low Reynolds number k-εmodel for the prediction of flow pattern and pressure drop in bubble column reactors, Chemical Engineering Science, 2002, 57(16): 3235~3250
[144] Bagatin R, Andrigo P, Protto L, et al., Fluid dynamics of gas-liquid airlift reactors through CFD packages, Computational Technologies for Fluid/Thermal/Structural/Chemical Systems With Industrial Applications, 1999, PVP-Vol. 397-1: 293~303
[145] Cartland Glover GM, Blazej M, Generalis SC, et al., Three-dimensional gas-liquid simulation of an airlift bubble column reactor, Chemical Papers, 2003, 57(6): 387~392
[146] Oey RS, Mudde RF, Van Den Akker HEA, Numerical simulations of an oscillating internal-loop airlift reactor, Canadian Journal of Chemical Engineering, 2003, 81(3-4): 684~691
[147] Van Baten JM, Ellenberger J, Krishna R, Hydrodynamics of internal air-lift reactors: Experiments versus CFD simulations, Chemical Engineering and Processing, 2003, 42(10): 733~742
[148] Van Baten JM, Ellenberger J, Krishna R, Using CFD to describe the hydrodynamics of internal air-lift reactors, Canadian Journal of Chemical Engineering, 2003, 81(3-4): 660~668
[149] Mudde RF, Van Den Akker HEA, 2D and 3D simulations of an internal airlift loop reactor on the basis of a two-fluid model, Chemical Engineering Science, 2001, 56(21-22): 6351~6358
[150] Van Baten JM, Krishna R, Comparison of hydrodynamics and mass transfer in airlift and bubble column reactors using CFD, Chemical Engineering & Technology, 2003, 26(10): 1074~1079
[151] Blazej M, Cartland Glover GM, Generalis SC, et al., Gas-liquid simulation of an airlift bubble column reactor, Chemical Engineering and Processing, 2004, 43(2): 137~144
[152] Michele V, Hempel DC, Liquid flow and phase holdup-measurement and CFD modeling for two-and three-phase bubble columns, Chemical Engineering Science, 2002, 57(11): 1899~1908
[153] Cartland Glover GM, Generalis SC, Gas-liquid-solid flow modelling in a bubblecolumn, Chemical Engineering Processing, 2004, 43(2): 117~126
[154] Zhang XY, Ahmadi G, Eulerian-Lagrangian simulations of liquid-gas-solid flows in three-phase slurry reactors, Chemical Engineering Processing, 2005, 60(18): 5089~5104
[155] Oey RS, Mudde RF, Portela LM, et al., Simulation of a slurry airlift using a two-fluid model, Chemical Engineering Science, 2001, 56(2): 673~681
[156] Feng W, Wen JP, Jia XQ, et al., Modeling for local dynamic behaviors of phenol biodegradation in bubble columns, AIChE Journal, 2006, 52(8): 2864~2875
[157] Feng W, Wen JP, Liu CY, et al., Modeling of local dynamic behavior of phenol degradation in an internal loop airlift bioreactor by yeast Candida tropicalis, Biotechnology and Bioengineering, 2007, 97(2): 251~264
[158] Laakkonen M, Moilanen P, Alopaeus V, et al., Dynamic modeling of local reaction conditions in an agitated aerobic fermenter, AIChE Journal, 2006, 52(5): 1673~1689
[159] Boyer C, Duquenne AM, Wild G, Measuring techniques in gas-liquid and gas-liquid-solid reactors, Chemical Engineering Science, 2002, 57(16): 3185~3215
[160] Joshi JB, Patil TA, Ranade VV, et al., Measurement of hydrodynamic parameters in multiphase sparged reactors, Reviews in Chemical Engineering, 1990, 6(2-3): 73~227
[161] Daly JG, Patel SA, Bukur DB, Measurement of gas holdups and Sauter mean bubble diameters in bubble column reactors by dynamic gas disengagement method, Chemical Engineering Science, 1992, 47(13-14): 3647~3654
[162] Camarasa E, Vial C, Poncin S, et al., Influence of coalescence behaviour of the liquid and of gas sparging on hydrodynamics and bubble characteristics in a bubble column, Chemical Engineering and Processing, 1999, 38(4-6): 329~344
[163] Lee DJ, Luo X, Fan LS, Gas disengagement technique in a slurry bubble column operated in the coalesced bubble regime, Chemical Engineering Science, 1999, 54(13-14): 2227~2236
[164] Begovich JM, Watson JS, An electroconductivity method for the measurement of axial variation of holdups in three-phase fluidized beds, AIChE Journal, 1978, 24(2): 351~354
[165] Uribe-Salas A, Gomez CO, Finch JA, A conductivity technique for gas and solids holdup determination in three-phase reactors, Chemical Engineering Science, 1994, 49(1): 1~10
[166] Kumar SB, Moslemian D, Dudukovic MP, Aγ-ray tomographic scanner for imaging voidage distribution in two-phase flow systems, Flow Measurement Instrumentation, 1995, 6(1): 61~73
[167] Froystein T, Flow imaging by gamma-ray Tomography: Data processing and reconstruction techniques, Frontiers in Industrial Process Tomography II, Delft, 1997, pp. 185-187
[168] Schmitz D, Mewes D, Tomographic imaging of transient multiphase flow in bubble columns, Chemical Engineering Journal, 2000, 77(1-2): 99~104
[169] Mann R, Dickin FJ, Wang M, et al., Application of electrical resistance tomography to interrogate mixing processes at plant scale, Chemical Engineering Science, 1997(13), 52: 2087~2097
[170] Reinecke N, Mewes D, Investigation of the two-phase flow in trickle-bed reactors using capacitance tomography, Chemical Engineering Science, 1997, 52(13): 2111~2127
[171] Reinecke N, Petritsch G, Schmitz D, et al., Tomographic measurement techniques-visualisation of multiphase flows, Chemical Engineering & Technology, 1998, 21(1): 7~18
[172] Warsito, Ohkawa M, Kawata N, et al., Cross-sectional distributions of gas and solid holdups in slurry bubble column investigated by ultrasonic computed tomography, Chemical Engineering Science, 1999, 54(21): 4711~4728
[173] Fournier T, Jeandey C, Optimization of an experimental setup for void fraction determination by the X-ray attenuation technique. In J.M. Delhaye & G. Cognet (Eds.), Measuring techniques in gas-liquid two-phase flows, Berlin, Heidelberg, New York, Tokyo: Springer, 1993, pp. 199~228
[174] Nicol RS, Davidson JF, Gas holdup in circulating bubble columns, Transactions of the Institution of Chemical Engineers, A: Chemical Engineering Research and Design, 1988, 66(2): 152~158
[175] Utiger M, Stuber F, Duquenne AM, et al., Local measurements for the study of external loop airlift hydrodynamics, Canadian Journal of Chemical Engineering, 1999, 77(2): 375~382
[176] Jones J, Owen C, Delhaye JM, Transient and statistical measurement techniques for two-phase flows, International Journal of Multiphase Flow, 1976, 3(2): 89~116
[177] Groen JS, Mudde RF, van den Akker HEA, Time dependant behaviour of the flow in a bubble column, Transactions of the Institution of Chemical Engineers, A: Chemical Engineering Research and Design, 1995, 73(6): 615~620
[178] Chabot J, Farag H, De Lasa H, Fluid dynamics of bubble columns at elevated temperature modelling and investigation with refractive fiber optic sensor, Chemical Engineering Journal, 1998, 70(2): 105~113
[179] Choi KH, Lee WK, Comparison of probe methods for measurement of bubble properties, Chemical Engineering Communications, 1990(1), 91, 35~47
[180] Frohlich S, Lotz M, Larson B, et al., Characterization of a pilot plant airlift tower loop reactor: III. Evaluation of local properties of the dispersed gas phase during yeast cultivation and in model media, Biotechnology and Bioengineering, 1991, 38(1): 56~64
[181] Hogsett S, Ishii M, Local two-phase flow measurements using sensor techniques, Nuclear Engineering and Design, 1997, 175(1-2): 15~24
[182] Thang NT, Davis MR, The structure of bubbly flow through venturis, International Journal of Multiphase Flow, 1979, 5(1): 17~37
[183] Liu TJ, Bubble size and entrance length effects on void development in a vertical channel, International Journal of Multiphase Flow, 1993, 19(1): 99~113
[184] Cartellier A, Simultaneous void fraction measurement, bubble velocity, and size estimate using a single optical probe in gas-liquid two-phase flows, Review of Scientific Instruments, 1992, 63(11): 5442~5453
[185] Barrau E, Riviere N, Poupot C, et al., Single and double optical probes in air–water two-phase flows: Real time signal processing and sensor performance, International Journal of Multiphase Flow, 1999, 25(2): 229~256
[186] Bruuns HH, Hot wire aneometry, Principles and signal analysis, New York: Oxford University Press Inc., 1995
[187] Broring S, Fischer J, Korte T, et al., Flow structure of the dispersed gasphase in real multiphase chemical reactors investigated by a new ultrasound-Doppler technique, Canadian Journal of Chemical Engineering, 1991, 69(6): 1247~1256
[188] Stravs AA, Stockar UV, Measurement of interfacial areas in gas-liquid dispersions by ultrasonic pulse transmission, Chemical Engineering Science, 1985, 40(7): 1169~1175
[189] Sakai N, Onozaki M, Saegusa H, et al., Fluid dynamics in coal liquefaction reactors using neutron absorption tracer technique, AIChE Journal, 2000, 46(8): 1688~1693
[190] Rammohan AR, Dudukovic MP, Ranade VV, Eulerian flow field estimation from particle rajectories: numerical experiments for stirred tank type flows, Industrial & Engineering Chemistry Research, 2003, 42(12): 2589~2601
[191] Khopkar AR, Rammohan AR, Ranade VV, et al., Gas-liquid flow generated by a Rushton turbine in stirred vessel: CARPT/CT measurements and CFD simulations, Chemical Engineering Science, 2005, 60(8-9): 2215~2229
[192] Chaouki J, Larachi F, Dudukovic MP, Noninvasive tomographic and velocimetric monitoring of multiphase flows, Industrial & Engineering Chemistry Research, 1997, 36(11): 4476~4503
[193] Reese J, Mudde RF, Lee DJ, et al., Analysis of multiphase systems through particle image velocimetry, American Institute of Chemical EngineersSymposium Series, 1996, 92(310): 161~167
[194] Northrup MA, Kulp TJ, Angel SM, et al., Direct measurement of interstitial velocity field variations in a porous medium using 4uorescent-particle image velocimetry, Chemical Engineering Science, 1993, 48(1): 13~21
[195] Delnoij E, Kuipers JAM, van Swaaij WPM, et al., Measurement of gas–liquid two-phase flow in bubble columns using ensemble correlation PIV, Chemical Engineering Science, 2000, 55(17): 3385~3395
[196] Gladden LF, Nuclear magnetic resonance in chemical engineering: Principles and applications, Chemical Engineering Science, 1994, 49(20): 3339~3408
[197] Sederman AJ, Johns ML, Bramley AS, et al., Magnetic resonance imaging of liquid flow and pore structure within packed beds, Chemical Engineering Science, 1997, 52(14): 2239~2250
[198] Sederman AJ, Johns ML, Alexander P, et al., Structure-flow correlations in packed beds, Chemical Engineering Science, 1998, 53(12): 2117~2128
[199] Sharma S, Mantle MD, Gladden LF, et al., Determination of bed voidage using water substitution and 3D magnetic resonance imaging, bed density and pressure drop in packed-bed reactors, Chemical Engineering Science, 2001, 56(2): 587~593
[200] Mudde RF, Groen JS, van den Akker HEA, Liquid velocity field in a bubble column: LDA experiments, Chemical Engineering Science, 1997, 52(21-22): 4217~4224
[201] Becker S, De Bie H, Sweeney J, Study on the flow structure in an aerated flat apparatus using Laser Doppler Anemometry, Chemical Engineering & Technology, 2000, 23(3): 222~226
[202] Vial C, LainLe R, Poncin S, et al., Influence of gas distribution and regime transition on liquid velocity and turbulence in a 3-D bubble column, Chemical Engineering Science, 2001, 56(3): 1085~1093
[203] Vial C, Poncin S, Wild G, A simple method for regime identification and flow characterisation in bubble columns and airlift reactors, Chemical Engineering and Processing, 2001, 40(2): 135~151
[204] Joshi JB, Computational flow modelling and design of bubble column reactors, Chemical Engineering Science, 2001, 56(21-22): 5893~5933
[205] Magaud F, Souhar M, Wild G, et al., Experimental study of bubble columns hydrodynamics, Chemical Engineering Science, 2001, 56(15): 4597~4607
[206] Latifi MA, Rode S, Midoux N, et al., The use of microelectrodes for the determination of flow regimes in a trickle-bed reactor, Chemical Engineering Science, 1992, 47(8): 1955~1961
[207] Rode S, Midoux N, Latifi MA, et al., Hydrodynamics and liquid-solid masstransfer mechanisms in packed beds operating in cocurrent gas-liquid downflow: An experimental study using electrochemical shear rate sensors, Chemical Engineering Science, 1994, 49(9): 1383~1401
[208] Serizawa A, Kataoka I, Mishigoshi I, Turbulence structure of air-water bubbly flow-1. measuring techniques, International Journal of Multiphase Flow, 1975, 2(3): 221~259
[209] Menzel T, in der Weide T, Staudacher O, et al., Reynolds shear stress for modeling of bubble column reactors, Industrial & Engineering Chemistry Research, 1990, 29(6): 988~994
[210] Young MA, Carbonell RG, Ollis DF, Airlift bioreactors: Analysis of local two-phase hydrodynamics, AIChE Journal, 1991, 37(3): 403~428
[211] Ligrani PM, Singer BA, Baun LR, Miniature five-hole pressure probe for measurement of three mean velocity components in low speed flow, Journal of Physics E: Scientific Instruments, 1989, 22(10): 868~876
[212] Cho SH, Becker HA, Response of static pressure probes in turbulent streams, Experiments in fluids, 1985, 3(2): 93~102
[213] Torres-Guerrero H, Ploidy study in Sporothrix schenkii, Fungal Genetics and Biology, 1999, 27(1): 49~54
[214] Kibret M, Somitsch W, Robra KH, Characterization of a phenol degrading mixed population by enzyme assay, Water Research, 2000, 34(4): 1127~1134
[215] Liu TJ, Bankoff SG, Structure of air water bubbly flow in a vertical pipe-II. Void fraction, bubble velocity and bubble size distribution, International Journal of Heat and Mass Transfer, 1993, 36(4): 1061~1072
[216]闻建平,下喷自吸环流反应器内局部流动传质及分形特性的研究:[博士学位论文],天津;天津大学,1995
[217]李颖珂,规整填料单元内流场的LDV测量及其小波分析:[硕士学位论文],天津;天津大学,2006
[218]夏振炎,姜楠,湍射流的三维LDV测量,流体力学实验与测量,2002,16(2):72~77
[219] Cui Z, Fan LS, Turbulence energy distributions in bubbling gas-liquid and gas-liquid-solid flow systems, Chemical Engineering Science, 2004, 59(8-9): 1755~1766
[220] Feng W, Wen JP, Fan JH, et al., Local hydrodynamics of gas-liquid-nanoparticles three-phase fluidization, Chemical Engineering Science, 2005, 60(24): 6887~6898
[221] Fennell DE, Rhee SK, Ahn YB, et al., Detection and characterization of a dehalogenating microorganism by terminal restriction fragment length polymorphism fingerprinting of 16S rRNA in a sulfidogenic,2-bromophenol-utilizing enrichment, Applied and Environmental Microbiology, 2004, 70(2): 1169~1175
[222] Ishii M, Zuber N, Drag coefficient and relative velocity in bubbly, droplet or particulate flows, AIChE Journal, 1979, 25(5): 843~855
[223] Wen CY, Yu YH, Mechanics of fluidization, Chemical Engineering Progress, 1966, 62(62): 100~111
[224] Sato Y, Sekoguchi K, Liquid velocity distribution in two-phase bubble flow, International Journal of Multiphase Flow, 1975, 2(1): 79~95
[225] Schallenberg J, EnβJH, Hempel DC, The important role of local dispersed phase hold-ups for the calculation of three-phase bubble columns, Chemical Engineering Science, 2005, 60(22): 6027~6033
[226] Olmos E, Gentric C, Midoux N, Numerical description of flow regime transitions in bubble column reactors by a multiple gas phase model, Chemical Engineering Science, 2003, 58(10): 2113~2121
[227] Luo SM, Svendsen HF, Theoretical model for drop and bubble breakup in turbulent dispersions, AIChE Journal, 1996, 42(5): 1225~1233
[228] Prince MJ, Blanch HW, Bubble coalescence and break-up in air-sparged bubble columns, AIChE Journal, 1990, 36(10), 1485~1499
[229] Chen P, Dudukovic MP, Sanyal J, Three-dimensional simulation of bubble column flows with bubble coalescence and breakup, AIChE Journal, 2005, 51(3): 696~712
[230] Padial NT, VanderHeyden WB, Rauenzahn RM, et al., Three-dimensional simulation of a three-phase draft-tube bubble column, Chemical Engineering Science, 2000, 55(16): 3261~3273
[231] Krishna R, van Baten JM, Urseanu MI, et al., Design and scale up of a bubble column slurryreactor for Fisch-Tropsch synthesis, Chemical Engineering Science, 2001, 56(2): 537~545
[232] Banerjee I, Modak JM, Bandopadhyay K, et al., Mathematical model for evaluation of mass transfer limitations in phenol biodegradation by immobilized Pseudomonas putida, Journal of Biotechnology, 2001, 87(3): 211~223
[233] ANSYS CFX-Solver, Release 10.0: Theory, ANSYS Canada Ltd.: Waterloo, Canada, 2005
[234] Washburn EW, International Critical Table, McGraw-Hill: New York, 1926
[235] Jiang Y, Wen JP, Li HM, et al., The biodegradation of phenol at high initial concentration by the yeast Candida tropicalis, Biochemical Engineering. Journal, 2005, 24(3): 243~247
[236] Livingston AG, Chase HA, Modeling phenol degradation in a fluidized-bed bioreactor, AIChE Journal, 1989, 35(12): 1980~1992
[237] Dhanasekharan KM, Sanyal J, Jain A, et al., A generalized approach to model oxygen transfer in bioreactors using population balances and computational fluid dynamics, Chemical Engineering Science, 2005, 60(1): 213~218
[238] Arters DC, Fan LS, Solid-liquid mass transfer in a gas-liquid-solid fluidized bed, Chemical Engineering Science, 1986, 41(1): 107~115
[239] Escobedo J, Mansoori GA, Asphaltene and other heavy-organic particle deposition during transfer and production operations, In Proceedings-SPE Annual Technical Conference and Exhibition, 1995, Pi: 343~358