TiC-Ni金属陶瓷高温力学性能研究
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摘要
TiC-Ni金属陶瓷作为WC-Co的替代材料,主要应用于切削加工。但由于其脆性大的缺点,限制了其应用范围。到目前为止,有关TiC-Ni金属陶瓷高温力学性能尤其是高温蠕变性能的研究还很少。本文使用CSS—3905型电子蠕变松弛试验机对自蔓延燃烧结合准静压技术合成的TiC-Ni进行了大量的高温拉伸实验和高温蠕变实验。通过蠕变模型拟合出实验曲线,得出了材料在不同温度下的最小蠕变速率、应力指数和激活能。为了研究材料损伤和材料硬度之间的关系,使用显微维氏硬度计测量了TiC-Ni材料在拉伸、蠕变实验前后硬度的变化,实验结果表明材料的硬度变化没有明确的特征。
As an alternative material of WC-Co, TiC-Ni cermets is mainly used in machining aero. However the britleness of this material limits its scope of application. So far, there has been only a few study on high temperature mechanical properties especially high-temperature creep properties on TiC-Ni cermets. In this article, the author carried out a large number of high-temperature tensile/creep tests on TiC-Ni materials prepared by SHS-PHIP technology by using the CSS—3905 creep testing machine. Creep models were used to simulate experimental data. Then the minimum creep rates, stress exponents, and activation energy were also calculated. To investigate the relationship between damage and hardness, micro-Vickers hardness tester was used to measure the hardness of TiC-Ni before and after the tensile/creep experiments. Experimental results showed that the changes of hardness during the experiments had no defining characteristics.
As an alternative material of WC-Co, TiC-Ni cermets is mainly used in machining aero. However the britleness of this material limits its scope of application. So far, there has been only a few study on high temperature mechanical properties especially high-temperature creep properties on TiC-Ni cermets. In this article, the author carried out a large number of high-temperature tensile/creep tests on TiC-Ni materials prepared by SHS-PHIP technology by using the CSS—3905 creep testing machine. Creep models were used to simulate experimental data. Then the minimum creep rates, stress exponents, and activation energy were also calculated. To investigate the relationship between damage and hardness, micro-Vickers hardness tester was used to measure the hardness of TiC-Ni before and after the tensile/creep experiments. Experimental results showed that the changes of hardness during the experiments had no defining characteristics.
引文
【1】赵金龙.几种自蔓延高温合成技术及其基础研究应用：[博士学位论文].大连：大连理工大学,2001
【2】汪方文.自蔓延合成Si3N4晶粒生长规律及控制：[硕士学位论文].沈阳：沈阳工业大学,2007
【3】谢燕春.SHS法制备Al2O3+TiB2+FeAl (NiAl)复合材料的研究：[硕士学位论文].济南：山东科技大学,2007
[5]Xinghong Zhang, Xiaodong He, Jiecai Han, et,al.Combustion synthesis and densification of large-scale TiC-xNi cermets. Meterial Letters,56(2002):183～187
【6】张幸红,曲伟,张学忠,赫晓东,韩杰才.TiC-Ni材料燃烧合成与致密化工艺参数的优化.宇航材料工艺,2000(3)：38～40
【7】王俊,周尧和.用高能超声制备金属基复合材料的现状与发展.铸造,1999(12)：40～45
【8】王喜伟.碳纤维增强镍基复合材料的制备方法研究：[硕士学位论文].哈尔滨：哈尔滨工业大学,2007
【9】吴岩.机械活化烧结TiC-Ni系金属陶瓷的组织及力学性能：[硕士学位论文].沈阳工业大学,2005
【10】李建伟.TiC-金属复合材料的自蔓延高温合成机理研究.洛阳工业高等专科学校学报,2007(12)：1-3
[11]Guoqing Xiao, Quncheng Fan, Meizhuan Gu. Dissolution-precipitation mechanism of self-propagating high-temperature synthesis of TiC-Ni cermet. Materials Science and Engineering A,382(2004):132～140
【12】肖国庆,范群成,顾美转,金志浩.TiC-Ni金属陶瓷自蔓延高温合成中的显微组织演变.中国有色金属学报,2004,14(6)：1013～1017
【13】张幸红,韩杰才,郝晓东等.Ni含量对SHS法合成TiC-Ni基金属陶瓷的影响.复合材料学报,1999(10)：26～27
【14】章小波,刘红梅,等.化学成分对TiC-Ni系金属陶瓷显微组织的影响.硬质合金,2008,25(1)：6-10
[15]X. Qi,N.Eigena,E.Aust,F.Gartner,T.Klassena, R. BormannaTwo-body abrasive wear of nano-and microcrystalline TiC-Ni-based thermal spray coatings.Surface & Coatings Technology,2006(200):5037～5047
【16】张幸红,韩杰才,郝晓东,等.燃烧合成TiC—Ni材料的室温及高温力学性能.复合材料学报,2001(2)：72～75
[17]张幸红,曲伟,张学忠,等.燃烧合成TiC_Ni金属陶瓷研究与试验的热膨胀特性.粉末冶金技术,2000,18(4)：243-244
[18]Yuxin Li, Peikang Bai, Yaomin Wang,et,al. Effect of TiC content on Ni-TiC composites by direct laser fabrication. Materials and Design,2009(30):1409～1412
[19]彭玉娟.稀土对激光熔覆镍基合金涂层的影响：[硕士学位论文].沈阳：辽宁工程技术大学,2003
[20]陈哲源,徐江,刘文今,钟敏霖.激光熔覆MOS2-TiC-Ni减摩耐磨复合涂层组织及磨损性能的研究.材料热处理学报,2007,28(8)：253～258
[21]Yuxin Li,Peikang Bai,Yaoming Wang.Effect of Ni contents on the microstructure and mechanical properties of TiC-Ni cermets obtained by direct laser fabrication.Journal of Refractory Metals & Hard Materials,2009(27):552～555
[22]Y.T.Pei,T.C.Zuo.Gradient microstructure in laser clad TiC-reinforced Ni-alloy composite coating.Materials Science and Engineering A,1998(241):259～263
[23]Chul-Jin Choi.Preparation of ultrafine TiC-Ni cermet powders by mechanical alloying.Journal of Materials Processing Technology,2000(104):127～132
[24]姚海玉,王引真,王海芳,王玮.超音速火焰喷涂合成TiC-Ni涂层滑动磨损性能研究.材料热处理学报,2006,27(2)：79～82
[25]姚海玉,王引真,王海芳,王玮.Ni对超音速火焰喷涂合成TiC-Ni涂层组织和耐磨性能的影响.材料开发与应用,2005,20(5)：1-4
[26]石建稳,王引真,李小龙.Mo的添加对反应超音速火焰喷涂合成TiC-Ni金属陶瓷涂层组织和性能的影响.硅酸盐通报,2005(1)：29～32
[27]吴岩,于宝海,任英磊,张海峰.活化烧结制备TiC-Ni金属陶瓷复合材料及其性能.材料科学与工程学报,2005,23(3)
[28]胡俊华,吴玉萍,曹明,林萍华.高能球磨对等离子控制原位合成TiC-Ni熔覆层的影响.金属热处理,2007,32(11)：30～34
[29]J.C.LaSalvia,D.K.Kim, M.A.Meyersa.Effect of Mo on microstructure and mechanical properties of TiC—Ni-based cermets produced by combustion synthesis—impact forging technique.Meterials Science and Engineering A,1996(206):71～80
[30]张幸红,韩杰才,赫晓东,杜善义.TiC-Ni-Mo复合材料的燃烧合成研究.无机材料学报,1999,14(3)：443～448
[31]胡正前,张文华,孙文华.等离子喷涂TiC-Ni-Mo金属陶瓷涂层成分对组织与性能影响的研究.复合材料学报,1999,16(3)：87～90
[32]栾振涛,周丽,殷凤仕,李树军.SHS-PHIP法制备TiC-Ni(Mo)金属陶瓷.热加工工艺,2006(6)：35～37
[33]Yong Choi,N.I.Baik,et,al. Corrosion and wear properties of TiC-Ni-Mo composites produced by direct consolidation during a self-propagating high-temperature reaction.composite science and tehcnology,2001(61):981～986
[34]J.Zackrisson,A.Larsson,H.O.Andre.Microstructure of the Ni binder phase in a TiC-Mo2C-Ni cermet.Micron,2001(32):707～712
[35]Jiang Xu,T,Wenjin Liu,Minlin Zhong.Microstructure and dry sliding wear behavior of MoS2-TiC-Ni composite coatings prepared by laser cladding.Surface & Coatings Technology,2006(200):4227～4232
[36]Ning Liu,Sheng Chao,Xinming Huang. Effects of TiC-TiN addition on the microstructure and mechanical properties of ultra-fine grade Ti (C, N)-Ni cermets. Journal of the European Ceramic Society,2006(26):3861～3870
[37]Kyoon Choi,Jinwoo Choi,et,al. Effect of coalescence on the grain coarsening during liquid-phase sintering of TaC-TiC-Ni cermets.Acta Material,2000(48):3125～3129
[38]Zhixing Guo,Ji Xiong,Mei Yang,Xiangyu Song,Cijin Jiang.Effect of Mo2C on the microstructure and properties of WC-TiC-Ni cemented carbide.International Journal of Refractory Metals & Hard Materials,2008(26):601～605
[39]Yongzhong Jin,Ying Liu,Yankun Wang,Jinwen Ye.Influence factors and microstructure evolution during preparation of nanocrystalline (Ti, W, Mo, V)(C, N)-Ni composite powders. Journal of Refractory Metals & Hard Materials,2009(27):957～961
[40]Xiaobo Zhang,Ning Liu,Chunlan Rong.Microstructure and fracture toughness of TiC-ZrC-WC-Mo-Ni cermets.International Journal of Refractory Metals & Hard Materials,2008(26):346～356
[41]A.aard,P.Krakhmalev,J.Bergstrom.Microstructural characterization and wear behavior of (Fe,Ni)-TiC MMC prepared by DMLS.Journal of Alloys and Compounds,2006(421):166～171
[42]H.Kwon,S.Kang.Microstructure and mechanical properties of TiC-WC-(Ti,W)C-Ni cermets.Materials Science and Engineering A,2009(520):75～79
[43]S.Bolognini,G.Feusier,D.Mari, et, al. TiMoCN-based cermets high-temperature deformation.International Journal of Refractory Metals & Hard Materials,2003(21):19～29
[44]T.Cutard, T.Viatte, G.Feusier. Microstructure and high temperature mechanical properties of TiC0.7N0.3-Mo2C-Ni cermets. Materials Science and Engineering A,1996(209):218～227
[45]J.S.LIN and Y.MIYAMOTO.Notch effect of surface compression and the toughening of graded A12O3-TiC-Ni materials. Acta Material,2000(48):767～775
[46]S.Bolognini,G.Feusier,D.Mari,T.Viatte,W.Benoit.High temperature mechanical behaviour of Ti(C,N)-Mo-Co cermets.Internahonal Journal of Refractory Metals & Hard Materials,1998(16):257-268
[47]聂桂平.2CrllNiMOVNbNB钢的高温蠕变特性实验研究：[硕士学位论文].北京,华北电力大学,2002
[48]杨宗学.3D-C-SiC的高温拉伸蠕变性能：[硕士学位论文].西安：西北工业大学,2002
[49]X.D.Hui,Y.S.Yang,Z.F.Wang,G.Q.Yuan,X.C.Chen.High temperature creep behavior of in-situ TiC particulate reinforced Fe-Cr-Ni matrix composite.Materials Science and Engineering A,2000(282):187～192
[50]K.Okuyama,T.Sakuma.High temperature plastic flow in TiC-20wt.%Mo2C-20wt.%Ni cermet.Materials Science and Engineering A,1995(194):63～68
【2】汪方文.自蔓延合成Si3N4晶粒生长规律及控制：[硕士学位论文].沈阳：沈阳工业大学,2007
【3】谢燕春.SHS法制备Al2O3+TiB2+FeAl (NiAl)复合材料的研究：[硕士学位论文].济南：山东科技大学,2007
[5]Xinghong Zhang, Xiaodong He, Jiecai Han, et,al.Combustion synthesis and densification of large-scale TiC-xNi cermets. Meterial Letters,56(2002):183～187
【6】张幸红,曲伟,张学忠,赫晓东,韩杰才.TiC-Ni材料燃烧合成与致密化工艺参数的优化.宇航材料工艺,2000(3)：38～40
【7】王俊,周尧和.用高能超声制备金属基复合材料的现状与发展.铸造,1999(12)：40～45
【8】王喜伟.碳纤维增强镍基复合材料的制备方法研究：[硕士学位论文].哈尔滨：哈尔滨工业大学,2007
【9】吴岩.机械活化烧结TiC-Ni系金属陶瓷的组织及力学性能：[硕士学位论文].沈阳工业大学,2005
【10】李建伟.TiC-金属复合材料的自蔓延高温合成机理研究.洛阳工业高等专科学校学报,2007(12)：1-3
[11]Guoqing Xiao, Quncheng Fan, Meizhuan Gu. Dissolution-precipitation mechanism of self-propagating high-temperature synthesis of TiC-Ni cermet. Materials Science and Engineering A,382(2004):132～140
【12】肖国庆,范群成,顾美转,金志浩.TiC-Ni金属陶瓷自蔓延高温合成中的显微组织演变.中国有色金属学报,2004,14(6)：1013～1017
【13】张幸红,韩杰才,郝晓东等.Ni含量对SHS法合成TiC-Ni基金属陶瓷的影响.复合材料学报,1999(10)：26～27
【14】章小波,刘红梅,等.化学成分对TiC-Ni系金属陶瓷显微组织的影响.硬质合金,2008,25(1)：6-10
[15]X. Qi,N.Eigena,E.Aust,F.Gartner,T.Klassena, R. BormannaTwo-body abrasive wear of nano-and microcrystalline TiC-Ni-based thermal spray coatings.Surface & Coatings Technology,2006(200):5037～5047
【16】张幸红,韩杰才,郝晓东,等.燃烧合成TiC—Ni材料的室温及高温力学性能.复合材料学报,2001(2)：72～75
[17]张幸红,曲伟,张学忠,等.燃烧合成TiC_Ni金属陶瓷研究与试验的热膨胀特性.粉末冶金技术,2000,18(4)：243-244
[18]Yuxin Li, Peikang Bai, Yaomin Wang,et,al. Effect of TiC content on Ni-TiC composites by direct laser fabrication. Materials and Design,2009(30):1409～1412
[19]彭玉娟.稀土对激光熔覆镍基合金涂层的影响：[硕士学位论文].沈阳：辽宁工程技术大学,2003
[20]陈哲源,徐江,刘文今,钟敏霖.激光熔覆MOS2-TiC-Ni减摩耐磨复合涂层组织及磨损性能的研究.材料热处理学报,2007,28(8)：253～258
[21]Yuxin Li,Peikang Bai,Yaoming Wang.Effect of Ni contents on the microstructure and mechanical properties of TiC-Ni cermets obtained by direct laser fabrication.Journal of Refractory Metals & Hard Materials,2009(27):552～555
[22]Y.T.Pei,T.C.Zuo.Gradient microstructure in laser clad TiC-reinforced Ni-alloy composite coating.Materials Science and Engineering A,1998(241):259～263
[23]Chul-Jin Choi.Preparation of ultrafine TiC-Ni cermet powders by mechanical alloying.Journal of Materials Processing Technology,2000(104):127～132
[24]姚海玉,王引真,王海芳,王玮.超音速火焰喷涂合成TiC-Ni涂层滑动磨损性能研究.材料热处理学报,2006,27(2)：79～82
[25]姚海玉,王引真,王海芳,王玮.Ni对超音速火焰喷涂合成TiC-Ni涂层组织和耐磨性能的影响.材料开发与应用,2005,20(5)：1-4
[26]石建稳,王引真,李小龙.Mo的添加对反应超音速火焰喷涂合成TiC-Ni金属陶瓷涂层组织和性能的影响.硅酸盐通报,2005(1)：29～32
[27]吴岩,于宝海,任英磊,张海峰.活化烧结制备TiC-Ni金属陶瓷复合材料及其性能.材料科学与工程学报,2005,23(3)
[28]胡俊华,吴玉萍,曹明,林萍华.高能球磨对等离子控制原位合成TiC-Ni熔覆层的影响.金属热处理,2007,32(11)：30～34
[29]J.C.LaSalvia,D.K.Kim, M.A.Meyersa.Effect of Mo on microstructure and mechanical properties of TiC—Ni-based cermets produced by combustion synthesis—impact forging technique.Meterials Science and Engineering A,1996(206):71～80
[30]张幸红,韩杰才,赫晓东,杜善义.TiC-Ni-Mo复合材料的燃烧合成研究.无机材料学报,1999,14(3)：443～448
[31]胡正前,张文华,孙文华.等离子喷涂TiC-Ni-Mo金属陶瓷涂层成分对组织与性能影响的研究.复合材料学报,1999,16(3)：87～90
[32]栾振涛,周丽,殷凤仕,李树军.SHS-PHIP法制备TiC-Ni(Mo)金属陶瓷.热加工工艺,2006(6)：35～37
[33]Yong Choi,N.I.Baik,et,al. Corrosion and wear properties of TiC-Ni-Mo composites produced by direct consolidation during a self-propagating high-temperature reaction.composite science and tehcnology,2001(61):981～986
[34]J.Zackrisson,A.Larsson,H.O.Andre.Microstructure of the Ni binder phase in a TiC-Mo2C-Ni cermet.Micron,2001(32):707～712
[35]Jiang Xu,T,Wenjin Liu,Minlin Zhong.Microstructure and dry sliding wear behavior of MoS2-TiC-Ni composite coatings prepared by laser cladding.Surface & Coatings Technology,2006(200):4227～4232
[36]Ning Liu,Sheng Chao,Xinming Huang. Effects of TiC-TiN addition on the microstructure and mechanical properties of ultra-fine grade Ti (C, N)-Ni cermets. Journal of the European Ceramic Society,2006(26):3861～3870
[37]Kyoon Choi,Jinwoo Choi,et,al. Effect of coalescence on the grain coarsening during liquid-phase sintering of TaC-TiC-Ni cermets.Acta Material,2000(48):3125～3129
[38]Zhixing Guo,Ji Xiong,Mei Yang,Xiangyu Song,Cijin Jiang.Effect of Mo2C on the microstructure and properties of WC-TiC-Ni cemented carbide.International Journal of Refractory Metals & Hard Materials,2008(26):601～605
[39]Yongzhong Jin,Ying Liu,Yankun Wang,Jinwen Ye.Influence factors and microstructure evolution during preparation of nanocrystalline (Ti, W, Mo, V)(C, N)-Ni composite powders. Journal of Refractory Metals & Hard Materials,2009(27):957～961
[40]Xiaobo Zhang,Ning Liu,Chunlan Rong.Microstructure and fracture toughness of TiC-ZrC-WC-Mo-Ni cermets.International Journal of Refractory Metals & Hard Materials,2008(26):346～356
[41]A.aard,P.Krakhmalev,J.Bergstrom.Microstructural characterization and wear behavior of (Fe,Ni)-TiC MMC prepared by DMLS.Journal of Alloys and Compounds,2006(421):166～171
[42]H.Kwon,S.Kang.Microstructure and mechanical properties of TiC-WC-(Ti,W)C-Ni cermets.Materials Science and Engineering A,2009(520):75～79
[43]S.Bolognini,G.Feusier,D.Mari, et, al. TiMoCN-based cermets high-temperature deformation.International Journal of Refractory Metals & Hard Materials,2003(21):19～29
[44]T.Cutard, T.Viatte, G.Feusier. Microstructure and high temperature mechanical properties of TiC0.7N0.3-Mo2C-Ni cermets. Materials Science and Engineering A,1996(209):218～227
[45]J.S.LIN and Y.MIYAMOTO.Notch effect of surface compression and the toughening of graded A12O3-TiC-Ni materials. Acta Material,2000(48):767～775
[46]S.Bolognini,G.Feusier,D.Mari,T.Viatte,W.Benoit.High temperature mechanical behaviour of Ti(C,N)-Mo-Co cermets.Internahonal Journal of Refractory Metals & Hard Materials,1998(16):257-268
[47]聂桂平.2CrllNiMOVNbNB钢的高温蠕变特性实验研究：[硕士学位论文].北京,华北电力大学,2002
[48]杨宗学.3D-C-SiC的高温拉伸蠕变性能：[硕士学位论文].西安：西北工业大学,2002
[49]X.D.Hui,Y.S.Yang,Z.F.Wang,G.Q.Yuan,X.C.Chen.High temperature creep behavior of in-situ TiC particulate reinforced Fe-Cr-Ni matrix composite.Materials Science and Engineering A,2000(282):187～192
[50]K.Okuyama,T.Sakuma.High temperature plastic flow in TiC-20wt.%Mo2C-20wt.%Ni cermet.Materials Science and Engineering A,1995(194):63～68