超支化树脂水溶液中二维和三维银纳米粒子的合成及其生物抑菌性能的研究
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摘要
超支化聚合物已在涂料、添加剂、医药、超分子化学、光学及光电学材料等诸多领域有广泛应用。本论文合成了具有不同端基的超支化高分子聚合物考察其分子量分布、热分析性质、对大肠杆菌和金黄色葡萄球菌的抑菌作用等,结果表明含有氨基超支化聚胺酯和含有-CSS-基团的端基为氨基的超支化聚合物均具有一定的抑菌性能,含有-CSS-基团的超支化聚合物具有更好的抑菌活性。
在材料化学领域,银纳米材料被广泛用于摄影、催化、光子学、光电子学、信息存储、表面增强拉曼散射、制作磁场磁流体和抑制细菌生长,因此银纳米材料的合成与形貌控制一直是热门话题之一。
本论文在叙述当前的不同的控制银纳米粒子的形貌的基础上,同时也提供了一种新的环境友好的,在室温下合成两种不同形貌的Ag纳米粒子的新方法。首次在超支化聚合物溶液中利用超声的方法制备出八面体银纳米粒子,并且在相似的条件下获得六边形银纳米纳米盘。用透射电镜和扫描电镜表征了银纳米粒子的形貌特征,用选区电子衍射分析了复合纳米材料的晶体结构,用激光动态扫描仪测试符合纳米材料的zeta电位及电泳淌度,用紫外-可见光分光光度计分析了复合纳米材料的光学特性,分析不同的官能团作用下银纳米粒子的形貌,结果表明,在本文所述的方法中银纳米粒子的形状控制的因素是还原剂还原能力的强弱。我们通过改变反应物的比例合成不同的纳米粒子,但是多得到的是具有不同几何形貌的银纳米粒子。
采用抑菌曲线和滤纸片法研究了八面体银纳米粒子和六边形银纳米盘的抑菌性能。实验表明:该二维和和三维银纳米的复合材料对大肠杆菌和金黄色葡萄球菌的生长具有良好的抑制作用。
Hyperbranched polymers are widely used in many fields such as coatings, additives, medicine, supramolecular chemistry, optics and optoelectronics. In this paper, we synthesize different end-group of the hyperbranched polymers and study its molecular weight distribution, thermal analysis, inhibitory effect on the growth of E. coli and Staphylococcus aureus bacteriostasis, etc. The results show that the amino-containing hyperbranched polyurethane and containing -CSS- groups in the amino-terminated hyperbranched polymer have some antibacterial properties; -CSS-containing group of the hyperbranched polymer has better antibacterial activity.
In the field of Materials Chemistry, silver nano-materials are widely used in photography, catalysis, photonics, optoelectronics, information storage, magnetic fluid, surface-enhanced Raman scatteringand inhibit bacterial growth, so silver nano-materials synthesis and morphology control has been a hot topic.
This paper describes the current controlling of the morphology of silver nanoparticles and provides a new method of preparing two morphology-different Ag nanoparticles with hyperbranched polymer (HBP) in an environmentally-benefit way at room temperature. 3D (Octahedron) and 2D (hexagon plate-like) silver nanoparticles were first obtained with NH_2-ended HBP (NH_2-HBP) and OH-ended HBP (OH-HBP) respectively at room temperature in aqueous solution. We characterizates silver nanoparticles morphology by using transmission electron microscopy and scanning electron microscopy, analysizes the composite crystal structure of nano-materials by using selected area electron diffraction, test the zeta potential and electrophoretic mobility of nano-materials with the laser dynamic scanners, detectes the optical properties of the composite nano-materials with UV - visible spectrophotometer analysis, dicusses the role of different functional groups in forming different morphology of silver nanoparticles, the results show that the method described in this article, the shape-controlled factor is the reduction capability of the corresponding substituent. We changed the ratio of reactants to synthesis different shapes nanoparticles, but most are to be geometric with different morphology of the silver nanoparticles.
We used inhibition curves and filter paper goods to study the law of antimicrobial performance for octahedron silver nanoparticles and hexagon silver nano-plate and their hyperbranched polymer composite. Experimental results show that: the two-dimensional and three-dimensional silver nanoparticles and their composite material have a good inhibitory effect on the growth of E. coli and Staphylococcus aureus.
在材料化学领域,银纳米材料被广泛用于摄影、催化、光子学、光电子学、信息存储、表面增强拉曼散射、制作磁场磁流体和抑制细菌生长,因此银纳米材料的合成与形貌控制一直是热门话题之一。
本论文在叙述当前的不同的控制银纳米粒子的形貌的基础上,同时也提供了一种新的环境友好的,在室温下合成两种不同形貌的Ag纳米粒子的新方法。首次在超支化聚合物溶液中利用超声的方法制备出八面体银纳米粒子,并且在相似的条件下获得六边形银纳米纳米盘。用透射电镜和扫描电镜表征了银纳米粒子的形貌特征,用选区电子衍射分析了复合纳米材料的晶体结构,用激光动态扫描仪测试符合纳米材料的zeta电位及电泳淌度,用紫外-可见光分光光度计分析了复合纳米材料的光学特性,分析不同的官能团作用下银纳米粒子的形貌,结果表明,在本文所述的方法中银纳米粒子的形状控制的因素是还原剂还原能力的强弱。我们通过改变反应物的比例合成不同的纳米粒子,但是多得到的是具有不同几何形貌的银纳米粒子。
采用抑菌曲线和滤纸片法研究了八面体银纳米粒子和六边形银纳米盘的抑菌性能。实验表明:该二维和和三维银纳米的复合材料对大肠杆菌和金黄色葡萄球菌的生长具有良好的抑制作用。
Hyperbranched polymers are widely used in many fields such as coatings, additives, medicine, supramolecular chemistry, optics and optoelectronics. In this paper, we synthesize different end-group of the hyperbranched polymers and study its molecular weight distribution, thermal analysis, inhibitory effect on the growth of E. coli and Staphylococcus aureus bacteriostasis, etc. The results show that the amino-containing hyperbranched polyurethane and containing -CSS- groups in the amino-terminated hyperbranched polymer have some antibacterial properties; -CSS-containing group of the hyperbranched polymer has better antibacterial activity.
In the field of Materials Chemistry, silver nano-materials are widely used in photography, catalysis, photonics, optoelectronics, information storage, magnetic fluid, surface-enhanced Raman scatteringand inhibit bacterial growth, so silver nano-materials synthesis and morphology control has been a hot topic.
This paper describes the current controlling of the morphology of silver nanoparticles and provides a new method of preparing two morphology-different Ag nanoparticles with hyperbranched polymer (HBP) in an environmentally-benefit way at room temperature. 3D (Octahedron) and 2D (hexagon plate-like) silver nanoparticles were first obtained with NH_2-ended HBP (NH_2-HBP) and OH-ended HBP (OH-HBP) respectively at room temperature in aqueous solution. We characterizates silver nanoparticles morphology by using transmission electron microscopy and scanning electron microscopy, analysizes the composite crystal structure of nano-materials by using selected area electron diffraction, test the zeta potential and electrophoretic mobility of nano-materials with the laser dynamic scanners, detectes the optical properties of the composite nano-materials with UV - visible spectrophotometer analysis, dicusses the role of different functional groups in forming different morphology of silver nanoparticles, the results show that the method described in this article, the shape-controlled factor is the reduction capability of the corresponding substituent. We changed the ratio of reactants to synthesis different shapes nanoparticles, but most are to be geometric with different morphology of the silver nanoparticles.
We used inhibition curves and filter paper goods to study the law of antimicrobial performance for octahedron silver nanoparticles and hexagon silver nano-plate and their hyperbranched polymer composite. Experimental results show that: the two-dimensional and three-dimensional silver nanoparticles and their composite material have a good inhibitory effect on the growth of E. coli and Staphylococcus aureus.
引文
[1]L.K.Johnson,C.M.Killian,M.Brookhart,New Pd(Ⅱ)-and Ni(Ⅱ)-Based Catalysts for Polymerization of Ethylene and a-Olefins,J.Am.Chem.Soc.,1995,117,6414
[2]Gao C,Yan D.Progress in Polym Sci,2004,29:183-2751
[3]P.J.Flory,Molecular Size Distribution in Three Dimensional Polymers Ⅳ,Branched Polymers Containing A-R-Bf-1 Type Units,J.Am.Chem.Soc.1952,74,2718
[4]Flory P J.,Principles of Polymer Chemistry,Cornel University Press,1953,361
[5]Y.H.Kim,O.W.Webster.Water-Soluble Hyperbranched Polyphenylene:A Unimolecular Micelle,J.Am.Chem.Soc.1990,112,4593
[6]C.J.Hawker,J.M.J.Frechet,Preparation of Polymers with Controlled Molecular Architecture.A New Convergent Approach to Dendritic Macromolecules.J.Am.Chem.Soc.,1990,112,7638
[7]Y.H.Kim,O.W.Webster,Hyperbranched Polyphenylenes.Macromolecules,1992,25,5561
[8]K.E.Uhrich,C.J.Hawker,J.M.J.Frechet,S.R.Turner.One-Pot Synthesis of Hyperbranched Polyethers.Macromolecules,1992,25,4583
[9]M.Suzuki,A.Ii,T.Saegusa.Multibranching Polymerization:Palladium-Catalyzed Ring-Opening Polymerization of Cyclic Carbonate to Produce Hyperbranched Dendritic Polyamine,Macromolecules,1992,25,7071
[10]Y.H.Kim.Lyotropic Liquid Crystalline Hyperbranched Aromatic Polyamides.J.Am.Chem Soc.1992,114,4947
[11]D.A Tomalia,M.Hall,D.M.Hedstrand,Hydrogen Transfer from 1-Naphthol Triplet to Ground-State Benzophenone:Kinetic Evidence against Proposed Exciplex Intermediacy,J.Am.Chem.Soc.1987,109,1600
[12]魏焕郁,施文芳.超支化聚合物的结构特征.合成及应用.高等化学学报,2001,22:338-34
[13]Li Z X,Liu J H,Yang S Y,et al.J Polym Sci,Part A:Polym Chem,2006,44,5729-57391
[14]Sunder A,Hanselmann R,Frey H,et al.Macromolecules,1999,32:4240-42461
[15]Mai Y,Zhou Y,Yan D.Macromolecules,2005,38:8679-86861
[16]Frechet J M J,Henmi M,Gitsov I,el al.Science,1995,269:1080-10831
[17]Simon P F W,Muller AN H E.Macromolecular Theory and Simulations,2000,9:621-6271
[18]Fu Y,Vandendriessche A,Dehaen W,et al.Macromolecules,2006,39:5183-51861
[19]Jikei M,Chon S H,Kakimoto M,et al.Macromolecules,1999,32:2061-20641
[20]Emrick T,Chang H T,Frechet J M J.Macromolecules,1999,32:6380-63821
[21]Unal S,Long T E.Macromolecules,2006,39:2788-27931
[22]Wang D,Liu Y,Hong C,et al.J Polym Sci,Part A:Polym Chem,2005,43:5127-51371
[23]Unal S,Lin Q,Mourey T H,et al.Macromolesules,2005,38,3246-32541
[24]Kricheldorf H R,Vakhtangishvili L,Fritsch D.J Polym Sci,Part A:Polym Chem,2002,40:2967-29781
[25]Lin Q,Long T E.Macromolesules,2003,36:9809-98161
[26]Choi J,Tan L,Baek J.Macromolesules,2006,39:9057-90631
[27]车鹏超,和亚宁,王晓工.高分子学报,2007,1:21-251
[28]王海侨,王换方,卢红斌等.高等学校化学学报,2007,2:388-390
[29]Gao C,Yan D.Progress in Polym Sci,2004,29:183-2751
[30]Li X,Lu X,Lin Y,et al.Macromolecules,2006,39:7889-78991
[31]Wang D,Zheng Z,Hong C,et al.J Polym Sci,Part A:Polym Chem,2006,44:6226-62421
[32]易吕凤,李全涛,徐祖硕.化学进展,2007,19(2Ⅱ3):356-3611
[33]侣庆法,范晓东,王生杰等.高分子通报,2006,6:44-561
[34]李爱香,鲁在君,谭业邦等.高分子通报,2005,2:6-131
[35]赵雅青,董炎明等.化学进展,2005,17(5):868-8751
[36]Blencowe A,Caiulo N,Cosstick K,et al.Macromolecules,2007,40:939-9491
[37]Voit B.Comptes Rendus Chimie,2003,6:821-8321
[38]Voit B.J Polym Sci,Part A:Polym Chem,2005,43:2679-26991
[39]Nelly P(?)rignon,Anne-Francoise Mingotaud,Jean-Daniel Marly,~* Isabelle Rico-Lattes,and Christophe Mingotaud Formation and Stabilization in Water of Metal Nanoparticles by a Hyperbranched Polymer Chemically Analogous to PAMAM Dendrimers Chem.Mater.,2004,16(24),pp 4856-4858
[40]S Wei,Y Zhu,Y Zhang,J Xu Preparation and characterization of hyperbranched aromatic polyamides/Fe3O4 magnetic nanocomposite 2006,66:1272-1277
[41]Jameel Ahmad Khan,Rajesh Kumar Kainthan,Munia Ganguli,Jayachandran N.Kizhakkedathu,Yogendra Singh,and Souvik Maiti Water Soluble Nanoparticles from PEG-Based Cationic Hyperbranched Polymer and RNA That Protect RNA from Enzymatic Degradation Biomacromolecules,2006,7(5),pp 1386-1388
[42]Chun-Yan Hong,Ye-Zi You,Decheng Wu,Ye Liu,and Cai-Yuan PanMultiwalled Carbon Nanotubes Grafted with Hyperbranched Polymer Shell via SCVP Macromolecules,2005,38(7),pp 2606-2611
[43]Youyong Xu,Chao Gao,Hao Kong,Deyue Yan,Yi Zheng Jin,and Paul C.P.Watts Growing Multihydroxyl Hyperbranched Polymers on the Surfaces of Carbon Nanotubes by in Situ Ring-Opening Polymerization Macromolecules,2004,37(24),pp 8846-8853
[44]Hideharu Mori,Alexander B(o|¨)ker,Georg Krausch,and Axel H.E.M(u|¨)ller Surface-Grafted Hyperbranched Polymers via Self-Condensing Atom Transfer Radical Polymerization from Silicon Surfaces Macromolecules,2001,34(20),pp 6871-6882
[45]Fujiki K,Sakamoto M,Sato T.Tsubokawa N.J Macromol Sci Pure Appl Chem.2000,37:357
[46]Shi B.Lu XC.Zou R.et al.Observations of the topography and friction properties of macromolecular thin films at the nanometer scale Wear,2001,251:1177
[47]J.L.Hedilck,C.J.Hawker,R.D.Miller,R.Twieg,S.A.Srinivasan,and M.Trolls(?)s Structure Control in Organic-Inorganic Hybrids Using Hyperbranched High-Temperature Polymers Macromolecules,1997,30(24),pp 7607-7610
[48]周庆成,滕枫,黄红敏,贺庆国,白凤莲.发光学报,2005,26(4):441-447
[49]彭汉,董宇平,贾德民,唐本忠.科学通报,2004,49(24):2617-2619
[50]Yang W,Zhen H Y,Jiang C Y,Su L J,Jiang JX,Shi H H,GaoY.Synthetic Metals,Sep 2005,153,(1-3):189-192
[51]王艳梅,魏杰.感光科学与光化学,2003,21(2):126-131
[52]寿崇琦,赵乔宾,周长利,张志良,贾海波,李关宾,陈立仁.分析化学研究简报,2004,32(2):241-243
[53]Dodiuk-Kenig H,Lizenboim K Eppelbaum I,Zalsman B,Kenig S.Journal of Adhesion Science & Technology,2004,18(15-16):1723-1737
[54]Dodiuk-Kenig,Buchman A,Kenig S.Composite Interfaces.2004,11(7):453-469
[55]Dodiuk H,Gold Z,Kenig S.Journal of Adhesion Science & Technology,2004,18(3):301-311
[56]Cang Xu,Wenfang Shi,Ming CongO.el al.European Polymer Journal,2004,(40):483
[57]Cang Xu,Wenfang Shi,Shijun Shen.Journal of Polymer Science:Part B:Polymer Physics,2004,42:2649
[58]S Unal,I Yilgor,E Yilgor,J P Sheth,GL Wilkes,T E Long.Macromo,2004,34:7081-7084
[59]Mona Abdelrehim,Hanmut Koseph Langenwalter,Brigitte Voit.Journal of Science:PartA:Polymer Chemistry,2004,42:3062-3081
[60]Ling Hong,Liyi Shi,Xiaozhen Tang.Macromolecules.2003,36:4989-4994
[6l]张华林,刘竞超,万金涛,黄先威.绝缘材料,2004,(6):27-29
[62]冯宗财,徐成刚.高分子材料与科学,2004,20(4):134-137
[63]Higa Mitsuru,Fujino Yukiko,Koumoto Taihei,Kitani Ryousuke,Egashira Satsuki.Electrochimica Acta,Jun2005,50(19):3832-383
[64]Chao Gao,Deyue Yan.Macromolecules,2003,36,613-620
[65]Crmg J Hawker,Jean MJ Frechet,Robert B Grubbs,Julian Dao.J.Am.Chem.Soc.1995,117:10763-10764
[66]Yamamoto Yutaka.European Polymer Journal,Mar2003,39(3):545
[1]YAN D,ZHOU Z.Molecular weight distribution of byperbranched polymers generated from polycondensation of AB_2 type monomers in the presence of multifunctional core moieties[J].Macromolecules,1999,32(3).819-824.
[1]J(o|¨)rg P.Kottmann and Olivier J.F.Martin.,Plasmon resonances of silver nanowires with a nonregular cross section,Phys.Rev B 64 235402.
[2]Benjamin J.Wiley,Y.C.,Joseph M.McLellan,Yujie Xiong,Zhi-Yuan Li,David Ginger,and Younan Xia,.Synthesis and Optical Properties of Silver Nanobars and Nanorice,Nano lett.7,(2007) 1032-1036.
[3]Yeechi Chen, K.M., and David S.Ginger, Dependence of Fluorescence Intensity on the Spectral Overlap between Fluorophores and Plasmon Resonant Single Silver Nanoparticles, Nano lett.7 (2007), 690-696
[4]Alexander O.Govorov, and Itai Carmeli, Hybrid Structures Composed of Photosynthetic System and Metal Nanoparticles: Plasmon Enhancement Effect, Nano Lett.7(2007)620-625.
[5]Leif J.Sherry, R.J., Chad A.Mirkin, George C.Schatz, and Richard P.Van Duyne,Localized Surface Plasmon Resonance Spectroscopy of Single Silver Triangular Nanoprisms, Nano lett.6 (2006) 2060-2065.
[6]Varun Sambhy, M.M.M., Blake R.Peterson, and Ayusman Sen, Silver Bromide Nanoparticle/Polymer Composites: Dual Action Tunable Antimicrobial Materials, J.Am.Chem.Soc.128 (2006) 9798-9808
[7]#12
[8]El-Sayed, M.A., Some interesting properties of metals confined in time and nanometer space of different shapes, Acc.Chem.Res.34 (2001 )257-264.
[9]Rongchao Jin, Y.Charles Cao, Encai Hao, Gabriella S.Me'traux, George C.Schatz & Chad A.Mirkin., Controlling anisotropic nanoparticle growth through plasmon excitation, Nature, 425 (2003) 487-490.
[10]Tan Yiwei, Li Yongfang, Zhu Daoben.Encyclopedia of Nanoscience and Nanotechnology[J], 2004, 8(32): 9
[11]Cushing B L et al.Recent Advances in the Liquid-Phase Syntheses of Inorganic Nanoparticles Chem Rev, 2004, 104(9): 3893
[12]Clemens B et al.Chemistry and Properties of Nanocrystals of Different Shapes Chem Rev [J], 2005, 105(4): 1025
[13]John et al.A general template-based method for the preparation of nanomaterials J Mater Chem[J], 1997,7(7): 1075
[14]Forrer P, Schlottig F, Siegenthaler H et al.Electrochemical preparation and surface properties of gold nanowire arrays formed by the template technique Journal of Applied Electrochemistry[J], 2000, 30(5): 533
[15]Huczko A Template-based synthesis of nanoma terials.Appl Phys A[J], 2000, 70(4):365
[16]Francis G M, Palmer R E.The place ofgold in the nabo world Gold Bull[J], 1996,29(2): 47
[17]Choi J et al.Hexagonally arranged monodisperse silver nanowires with adjustable diameter and high aspect ratio Chem Mater[J], 2003, 15(3): 776
[18]Sauer G et al.Highly ordered monocrystalline silver nanowire arrays J Appl Phys[J],2002, 91(5): 3243
[19]Barbie M et al.Single crystal silver nanowires prepared by the metal amplification method J Appl Phys[J], 2002, 91(11): 9341
[20]Wu Yiying et al.Templated Synthesis of Highly Ordered Mesostructured Nanowires and Nanowire Arrays Nano Lett[J], 2004,4(12): 2337
Huang M H et al.Ag nanowire formation within mesoporous silica Chem Commun[J],2000,(12): 1063
Murphy C J, Jana N R.Controlling the aspect ratio of inorganic nanorods and nanowires Adv Mater[J], 2002, 14(1): 80
Jana N R et al.Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio Chem Com[J], 2001, 1(7): 617
Jana N R et al.Wet chemical synthesis of high aspect ratio cylindrical gold nanorods J Phys Chem B[J], 2001, 105(19): 4065
Jana N R et al.Seed-Mediated Growth Approach for Shape-Controlled Synthesis of Spheroidal and Rod-like Gold Nanoparticles Using a Surfactant Template Adv Mater[J],2001, 13(18): 1389
Dabin Yu et al.Formation and Reductive Desorption of Mercaptohexanol Monolayers on Mercury J Phys Chem B[J], 2005, 109(12): 5497
Dabin Yu et al.Controlled Synthesis of Monodisperse Silver Nanocubes in Water J Am Chem Soc[J], 2004, 126(41): 13 200
Sun Y, Xia Y.Large-Scale Synthesis of Uniform Silver Nanowires Through a Soft,Self-Seeding, Polyol Process Adv Mater[J], 2002, 14(11): 833
Sun Y et al.Uniform Silver Nanowires Synthesis by Reducing AgN03 with Ethylene Glycol in the Presence of Seeds and Poly(Vinyl Pyrrolidone).Chem Mater[J], 2002,14(11): 4736
Michael Giersig, Isabel Pastoriza-Santos and Luis M.Liz-Marzan.Evidence of an aggregative mechanism during the formation of silver nanowires in N,N-dimethylformamide J Mater Chem[J], 2004, 14(4): 607
Isabel Pastoriza-Santos and Luis M.Liz-Marzan et al.Formation of PVP-Protected Metal Nanoparticles in DMF Langmuir[J], 2002, 18(7): 2888
Isabel Pastoriza-Santos, LM Liz-Marzan.Formation and stabilization of silver nanoparticles through reduction by N, N-dimethylformamide Langmuir[J], 1999, 15(4):948
Jin R et al.Controlling anisotropic nanoparticle growth through plasmon excitation Nature[J], 2003,425: 487
Jin R et al.Photoinduced Conversion of Silver Nanospheres to Nanoprisms Science[J],2001,294: 1901
Isabel Pastoriza-Santos et al.Synthesis of silver nanoprisms in DMF Nano Lett[J], 2002,2(8): 903
Chen Sihai et al.Synthesis and Characterization of Truncated Triangular Silver Nanoplates Nano Lett[J], 2002, 2(9): 1003
Chen Sihai et al.Silver Nanoplates: Size Control in Two Dimensions and Formation Mechanisms J Phys Chem B[J], 2004, 108(18): 5500
Sun Y, Mayers B, Xia Y.Transformation of Silver Nanospheres into Nanobelts and Triangular Nanoplates through a Thermal Process Nano Lett[J], 2003, 3(5): 675
Gabriella S, Mirkin C A.Rapid Thermal Synthesis of Silver Nanoprisms with Chemically Tailorable Thickness.Adv Mater[J], 2005, 17(4): 412
Sun Yugang, Xia Younan.Shape-Controlled Synthesis of Gold and Silver Nanoparticles.Science, 2002,298:2176
[41]Tian Z Q et al.Surface-Enhanced Raman Scattering:From Noble to Transition Metals and from Rough Surfaces to Ordered Nanostructures J Phys Chem B[J],2002,106(37):9463
[42]Wiley B et al.Polyol Synthesis of Silver Nanoparticles:Use of Chloride and Oxygen to Promote the Formation of Single-Crystal,Truncated Cubes and Tetrahedrons Nano Lett[J],2004,4(9):1733
[43]Sang Hyuk Im,Yun Tack Lee,Benjamin Wiley,Younan Xia.Large-Scale Synthesis of Silver Nanocubes:The Role of HCl in Promoting Cube Perfection and Monodispersity Angew Chem Int Ed[J],2005,44(14):2154
[44]Lee Y T,Im S H,Wiley B et al.Quick formation of single-crystal nanocubes of silver through dual functions of hydrogen gas in polyol synthesis Chemical Physics Letters[J],2005,411(4-6):479
[45]Benjamin Wiley,Yugang Sun,Brian Mayers,and Younan Xia,Shape-Controlled Synthesis of Metal Nanostructures:The Case of Silver,Chem EurJ,11(2005):454-463.
[46]Yujie Xiong,I.W.,Jingyi Chen,Honggang Cai,Zhi-Yuan Li,and Younan Xia,Poly(vinyl pyrrolidone):A Dual Functional Reductant and Stabilizer for the Facile Synthesis of Noble Metal Nanoplates in Aqueous Solutions.Langmuir,22(2006)8563-8570.
[47]Yujie Xiong,I.W.,Jingyi Chen,Honggang Cai,Zhi-Yuan Li,and Younan Xia,Poly(vinyl pyrrolidone):A Dual Functional Reductant and Stabilizer for the Facile Synthesis of Noble Metal Nanoplates in Aqueous Solutions,Langmuir,2006,22,(20),8563-8570
[48]Xia,Y.X.a.Y.Shape-Controlled Synthesis of Metal Nanostructures:The Case of Palladium,Adv.Mater.2007,19,3385-3391.
[49]Benjamin Wiley;Yugang Sun;and Xia,Y.Synthesis of Silver Nanostructures with Controlled Shapes and Properties,Acc.Chem.Res.2007,40,1067-1076.
[50]Johannes V.Barth,Giovanni Costantini & Klaus Kern.Engineering atomic and molecular nanostructures at surfaces.Nature2005,437,671-679.
[51]郭永康,鲍培谛编著,光学教程,四川大学出版社,成都,1996,357.
[52]吴强,郭光灿编著,光学,中国科学技术大学出版社,合肥,1996,369.
[53]左榘编著,激光散射原理及在高分子科学中的应用,河南科学技术出版社,1994.
[54]Lina A.Gugliotti,D.L.F.,Bruce E.Eaton,RNA-Mediated Metal-Metal Bond Formation in the Synthesis of Hexagonal Palladium Nanoparticles Science 2004,304,850-852.
[55]Benjamin J.Wiley,S.H.I.,Zhi-Yuan Li,Joeseph McLellan,Andrew Siekkinen,and Younan Xia,Maneuvering the Surface Plasmon Resonance of Silver Nanostructures through Shape-Controlled Synthesis J.Phys.Chem.B,2006,110,(32),15666-15675.
[1]沈萍,范秀蓉等主编微生物学实验,北京:高等教育出版社,2003,53.
[2]林敬东,杨振威,钟怀国,许增收,廖代伟,银纳米粒子的形貌可控研究,化学研究及应用,2007,19(2),169-171.
[3]廖学红,朱俊杰,赵小宁,陈洪渊,银纳米粒子的电化学合成,高等学校化学学报,2000,12(21),1837-1839
[4]Sonit Kumar Gogoi,P.G.,Anumita Paul,A.Ramesh,Siddhartha Sankar Ghosh,and Arun Chattopadhyay,Green Fluorescent Protein-Expressing Escherichia coli as a Model System for Investigating the Antimicrobial Activities of Silver Nanoparticles.Langmuir,2006,22(22),9322-9328.
[5]Chun-Nam Lok,C.-M H.,Rong Chen,Qing-Yu He,Wing-Yiu Yu,Hongzhe Sun,Paul Kwong-Hang Tam,Jen-Fu Chiu,and Chi-Ming Che,Proteomic Analysis of the Mode of Antibacterial Action of Silver Nanoparticles.J.Proteome Res.2006,5,(4),916-924.
[6]Block,S.Disinfection,Sterilization and PreserVation,3rd ed.;Lea & Febiger:Philadelphia,PA,1983.
[7]Mammen,H.C.;Choi,S.-K.;Whitesides,G.M.Polyvalent Interactions in Biological Systems:Implications for Design and Use of Multivalent Ligands and Inhibitors.Angew.Chem.,Int.Ed.1998,37,2754-2794.
[8]Yuan,H.L.;Tazuke,S.Inter- and Intramolecular Interactions of Polymer as Studied by Fluorescence Spectroscopy XVI Polym.J.1983,15,125.
[9]Donaruma,L.G.;Vogl,O.;Ottenbrite,R.M.Anionic Polymeric Drugs;John Wiley &Son:New York,1980.
[10]Donoruma,L.G.;Vogl,O.Polymeric Drugs;Academic Press:New York,1978.
[11]Davies,A.;Bentley,M.Field,B.S.J.Appl.Bacteriol.1968,31,448-452.
[12]Chen,C.Z.;Beck Tan,N.C.;Cooper,S.L.Incorporation of dimethyldodecylammonium chloride functionalities onto poly(propylene imine)dendrimers significantlyenhances their antibacterial properties Chem.Commun.1999,1585-1586.
[13]Chris Zhisheng Chen,N.C.B.-T.,Prasad Dhurjati,Tina K.van Dyk,Robert A.LaRossa,and Stuart L.Cooper,Quaternary Ammonium Functionalized Poly(propylene imine) Dendrimers as Effective Antimicrobials:Structure-ActivityStudies.Biomacromolecules 2000,1,473-480.
[14]Ramos,A.C.S.;Dantas Neto,A.A.;Castro Dantas,T.N.C.Braz J.Chem.Eng.,1997(14):159-165
[15]Helander IM,Nunniaho-Lassila EL,Ahvenainen R,et al.Chitosan disrupts the barrier properties of the outer membrane of Gram-negative bacteria[J].Intenational Journal of Microbiology,2001(71):235-244
[16]Chen,S.P.;Wu,G.Z.;Zeng,H.Y.Preparation of high antimicrobial activity thiourea chitosan-Ag~+-complex.Carbohydr.Polym.2005,60:33-38.
[17]Wang,X.H.;DU,Y.M.;Liu,H.Preparation,characterization and antimicrobial activity of chitosan-Zn complex.Carbohydr.Polym.,2004,56:21-26.
[18]P.V.AshaRani,G.L.K.M.,Manoor Prakash Hande,and Suresh Valiyaveettil,Cytotoxicity and Genotoxicity of Silver Nanoparticles in Human Cells.ACS Nano 2009.
[2]Gao C,Yan D.Progress in Polym Sci,2004,29:183-2751
[3]P.J.Flory,Molecular Size Distribution in Three Dimensional Polymers Ⅳ,Branched Polymers Containing A-R-Bf-1 Type Units,J.Am.Chem.Soc.1952,74,2718
[4]Flory P J.,Principles of Polymer Chemistry,Cornel University Press,1953,361
[5]Y.H.Kim,O.W.Webster.Water-Soluble Hyperbranched Polyphenylene:A Unimolecular Micelle,J.Am.Chem.Soc.1990,112,4593
[6]C.J.Hawker,J.M.J.Frechet,Preparation of Polymers with Controlled Molecular Architecture.A New Convergent Approach to Dendritic Macromolecules.J.Am.Chem.Soc.,1990,112,7638
[7]Y.H.Kim,O.W.Webster,Hyperbranched Polyphenylenes.Macromolecules,1992,25,5561
[8]K.E.Uhrich,C.J.Hawker,J.M.J.Frechet,S.R.Turner.One-Pot Synthesis of Hyperbranched Polyethers.Macromolecules,1992,25,4583
[9]M.Suzuki,A.Ii,T.Saegusa.Multibranching Polymerization:Palladium-Catalyzed Ring-Opening Polymerization of Cyclic Carbonate to Produce Hyperbranched Dendritic Polyamine,Macromolecules,1992,25,7071
[10]Y.H.Kim.Lyotropic Liquid Crystalline Hyperbranched Aromatic Polyamides.J.Am.Chem Soc.1992,114,4947
[11]D.A Tomalia,M.Hall,D.M.Hedstrand,Hydrogen Transfer from 1-Naphthol Triplet to Ground-State Benzophenone:Kinetic Evidence against Proposed Exciplex Intermediacy,J.Am.Chem.Soc.1987,109,1600
[12]魏焕郁,施文芳.超支化聚合物的结构特征.合成及应用.高等化学学报,2001,22:338-34
[13]Li Z X,Liu J H,Yang S Y,et al.J Polym Sci,Part A:Polym Chem,2006,44,5729-57391
[14]Sunder A,Hanselmann R,Frey H,et al.Macromolecules,1999,32:4240-42461
[15]Mai Y,Zhou Y,Yan D.Macromolecules,2005,38:8679-86861
[16]Frechet J M J,Henmi M,Gitsov I,el al.Science,1995,269:1080-10831
[17]Simon P F W,Muller AN H E.Macromolecular Theory and Simulations,2000,9:621-6271
[18]Fu Y,Vandendriessche A,Dehaen W,et al.Macromolecules,2006,39:5183-51861
[19]Jikei M,Chon S H,Kakimoto M,et al.Macromolecules,1999,32:2061-20641
[20]Emrick T,Chang H T,Frechet J M J.Macromolecules,1999,32:6380-63821
[21]Unal S,Long T E.Macromolecules,2006,39:2788-27931
[22]Wang D,Liu Y,Hong C,et al.J Polym Sci,Part A:Polym Chem,2005,43:5127-51371
[23]Unal S,Lin Q,Mourey T H,et al.Macromolesules,2005,38,3246-32541
[24]Kricheldorf H R,Vakhtangishvili L,Fritsch D.J Polym Sci,Part A:Polym Chem,2002,40:2967-29781
[25]Lin Q,Long T E.Macromolesules,2003,36:9809-98161
[26]Choi J,Tan L,Baek J.Macromolesules,2006,39:9057-90631
[27]车鹏超,和亚宁,王晓工.高分子学报,2007,1:21-251
[28]王海侨,王换方,卢红斌等.高等学校化学学报,2007,2:388-390
[29]Gao C,Yan D.Progress in Polym Sci,2004,29:183-2751
[30]Li X,Lu X,Lin Y,et al.Macromolecules,2006,39:7889-78991
[31]Wang D,Zheng Z,Hong C,et al.J Polym Sci,Part A:Polym Chem,2006,44:6226-62421
[32]易吕凤,李全涛,徐祖硕.化学进展,2007,19(2Ⅱ3):356-3611
[33]侣庆法,范晓东,王生杰等.高分子通报,2006,6:44-561
[34]李爱香,鲁在君,谭业邦等.高分子通报,2005,2:6-131
[35]赵雅青,董炎明等.化学进展,2005,17(5):868-8751
[36]Blencowe A,Caiulo N,Cosstick K,et al.Macromolecules,2007,40:939-9491
[37]Voit B.Comptes Rendus Chimie,2003,6:821-8321
[38]Voit B.J Polym Sci,Part A:Polym Chem,2005,43:2679-26991
[39]Nelly P(?)rignon,Anne-Francoise Mingotaud,Jean-Daniel Marly,~* Isabelle Rico-Lattes,and Christophe Mingotaud Formation and Stabilization in Water of Metal Nanoparticles by a Hyperbranched Polymer Chemically Analogous to PAMAM Dendrimers Chem.Mater.,2004,16(24),pp 4856-4858
[40]S Wei,Y Zhu,Y Zhang,J Xu Preparation and characterization of hyperbranched aromatic polyamides/Fe3O4 magnetic nanocomposite 2006,66:1272-1277
[41]Jameel Ahmad Khan,Rajesh Kumar Kainthan,Munia Ganguli,Jayachandran N.Kizhakkedathu,Yogendra Singh,and Souvik Maiti Water Soluble Nanoparticles from PEG-Based Cationic Hyperbranched Polymer and RNA That Protect RNA from Enzymatic Degradation Biomacromolecules,2006,7(5),pp 1386-1388
[42]Chun-Yan Hong,Ye-Zi You,Decheng Wu,Ye Liu,and Cai-Yuan PanMultiwalled Carbon Nanotubes Grafted with Hyperbranched Polymer Shell via SCVP Macromolecules,2005,38(7),pp 2606-2611
[43]Youyong Xu,Chao Gao,Hao Kong,Deyue Yan,Yi Zheng Jin,and Paul C.P.Watts Growing Multihydroxyl Hyperbranched Polymers on the Surfaces of Carbon Nanotubes by in Situ Ring-Opening Polymerization Macromolecules,2004,37(24),pp 8846-8853
[44]Hideharu Mori,Alexander B(o|¨)ker,Georg Krausch,and Axel H.E.M(u|¨)ller Surface-Grafted Hyperbranched Polymers via Self-Condensing Atom Transfer Radical Polymerization from Silicon Surfaces Macromolecules,2001,34(20),pp 6871-6882
[45]Fujiki K,Sakamoto M,Sato T.Tsubokawa N.J Macromol Sci Pure Appl Chem.2000,37:357
[46]Shi B.Lu XC.Zou R.et al.Observations of the topography and friction properties of macromolecular thin films at the nanometer scale Wear,2001,251:1177
[47]J.L.Hedilck,C.J.Hawker,R.D.Miller,R.Twieg,S.A.Srinivasan,and M.Trolls(?)s Structure Control in Organic-Inorganic Hybrids Using Hyperbranched High-Temperature Polymers Macromolecules,1997,30(24),pp 7607-7610
[48]周庆成,滕枫,黄红敏,贺庆国,白凤莲.发光学报,2005,26(4):441-447
[49]彭汉,董宇平,贾德民,唐本忠.科学通报,2004,49(24):2617-2619
[50]Yang W,Zhen H Y,Jiang C Y,Su L J,Jiang JX,Shi H H,GaoY.Synthetic Metals,Sep 2005,153,(1-3):189-192
[51]王艳梅,魏杰.感光科学与光化学,2003,21(2):126-131
[52]寿崇琦,赵乔宾,周长利,张志良,贾海波,李关宾,陈立仁.分析化学研究简报,2004,32(2):241-243
[53]Dodiuk-Kenig H,Lizenboim K Eppelbaum I,Zalsman B,Kenig S.Journal of Adhesion Science & Technology,2004,18(15-16):1723-1737
[54]Dodiuk-Kenig,Buchman A,Kenig S.Composite Interfaces.2004,11(7):453-469
[55]Dodiuk H,Gold Z,Kenig S.Journal of Adhesion Science & Technology,2004,18(3):301-311
[56]Cang Xu,Wenfang Shi,Ming CongO.el al.European Polymer Journal,2004,(40):483
[57]Cang Xu,Wenfang Shi,Shijun Shen.Journal of Polymer Science:Part B:Polymer Physics,2004,42:2649
[58]S Unal,I Yilgor,E Yilgor,J P Sheth,GL Wilkes,T E Long.Macromo,2004,34:7081-7084
[59]Mona Abdelrehim,Hanmut Koseph Langenwalter,Brigitte Voit.Journal of Science:PartA:Polymer Chemistry,2004,42:3062-3081
[60]Ling Hong,Liyi Shi,Xiaozhen Tang.Macromolecules.2003,36:4989-4994
[6l]张华林,刘竞超,万金涛,黄先威.绝缘材料,2004,(6):27-29
[62]冯宗财,徐成刚.高分子材料与科学,2004,20(4):134-137
[63]Higa Mitsuru,Fujino Yukiko,Koumoto Taihei,Kitani Ryousuke,Egashira Satsuki.Electrochimica Acta,Jun2005,50(19):3832-383
[64]Chao Gao,Deyue Yan.Macromolecules,2003,36,613-620
[65]Crmg J Hawker,Jean MJ Frechet,Robert B Grubbs,Julian Dao.J.Am.Chem.Soc.1995,117:10763-10764
[66]Yamamoto Yutaka.European Polymer Journal,Mar2003,39(3):545
[1]YAN D,ZHOU Z.Molecular weight distribution of byperbranched polymers generated from polycondensation of AB_2 type monomers in the presence of multifunctional core moieties[J].Macromolecules,1999,32(3).819-824.
[1]J(o|¨)rg P.Kottmann and Olivier J.F.Martin.,Plasmon resonances of silver nanowires with a nonregular cross section,Phys.Rev B 64 235402.
[2]Benjamin J.Wiley,Y.C.,Joseph M.McLellan,Yujie Xiong,Zhi-Yuan Li,David Ginger,and Younan Xia,.Synthesis and Optical Properties of Silver Nanobars and Nanorice,Nano lett.7,(2007) 1032-1036.
[3]Yeechi Chen, K.M., and David S.Ginger, Dependence of Fluorescence Intensity on the Spectral Overlap between Fluorophores and Plasmon Resonant Single Silver Nanoparticles, Nano lett.7 (2007), 690-696
[4]Alexander O.Govorov, and Itai Carmeli, Hybrid Structures Composed of Photosynthetic System and Metal Nanoparticles: Plasmon Enhancement Effect, Nano Lett.7(2007)620-625.
[5]Leif J.Sherry, R.J., Chad A.Mirkin, George C.Schatz, and Richard P.Van Duyne,Localized Surface Plasmon Resonance Spectroscopy of Single Silver Triangular Nanoprisms, Nano lett.6 (2006) 2060-2065.
[6]Varun Sambhy, M.M.M., Blake R.Peterson, and Ayusman Sen, Silver Bromide Nanoparticle/Polymer Composites: Dual Action Tunable Antimicrobial Materials, J.Am.Chem.Soc.128 (2006) 9798-9808
[7]#12
[8]El-Sayed, M.A., Some interesting properties of metals confined in time and nanometer space of different shapes, Acc.Chem.Res.34 (2001 )257-264.
[9]Rongchao Jin, Y.Charles Cao, Encai Hao, Gabriella S.Me'traux, George C.Schatz & Chad A.Mirkin., Controlling anisotropic nanoparticle growth through plasmon excitation, Nature, 425 (2003) 487-490.
[10]Tan Yiwei, Li Yongfang, Zhu Daoben.Encyclopedia of Nanoscience and Nanotechnology[J], 2004, 8(32): 9
[11]Cushing B L et al.Recent Advances in the Liquid-Phase Syntheses of Inorganic Nanoparticles Chem Rev, 2004, 104(9): 3893
[12]Clemens B et al.Chemistry and Properties of Nanocrystals of Different Shapes Chem Rev [J], 2005, 105(4): 1025
[13]John et al.A general template-based method for the preparation of nanomaterials J Mater Chem[J], 1997,7(7): 1075
[14]Forrer P, Schlottig F, Siegenthaler H et al.Electrochemical preparation and surface properties of gold nanowire arrays formed by the template technique Journal of Applied Electrochemistry[J], 2000, 30(5): 533
[15]Huczko A Template-based synthesis of nanoma terials.Appl Phys A[J], 2000, 70(4):365
[16]Francis G M, Palmer R E.The place ofgold in the nabo world Gold Bull[J], 1996,29(2): 47
[17]Choi J et al.Hexagonally arranged monodisperse silver nanowires with adjustable diameter and high aspect ratio Chem Mater[J], 2003, 15(3): 776
[18]Sauer G et al.Highly ordered monocrystalline silver nanowire arrays J Appl Phys[J],2002, 91(5): 3243
[19]Barbie M et al.Single crystal silver nanowires prepared by the metal amplification method J Appl Phys[J], 2002, 91(11): 9341
[20]Wu Yiying et al.Templated Synthesis of Highly Ordered Mesostructured Nanowires and Nanowire Arrays Nano Lett[J], 2004,4(12): 2337
Huang M H et al.Ag nanowire formation within mesoporous silica Chem Commun[J],2000,(12): 1063
Murphy C J, Jana N R.Controlling the aspect ratio of inorganic nanorods and nanowires Adv Mater[J], 2002, 14(1): 80
Jana N R et al.Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio Chem Com[J], 2001, 1(7): 617
Jana N R et al.Wet chemical synthesis of high aspect ratio cylindrical gold nanorods J Phys Chem B[J], 2001, 105(19): 4065
Jana N R et al.Seed-Mediated Growth Approach for Shape-Controlled Synthesis of Spheroidal and Rod-like Gold Nanoparticles Using a Surfactant Template Adv Mater[J],2001, 13(18): 1389
Dabin Yu et al.Formation and Reductive Desorption of Mercaptohexanol Monolayers on Mercury J Phys Chem B[J], 2005, 109(12): 5497
Dabin Yu et al.Controlled Synthesis of Monodisperse Silver Nanocubes in Water J Am Chem Soc[J], 2004, 126(41): 13 200
Sun Y, Xia Y.Large-Scale Synthesis of Uniform Silver Nanowires Through a Soft,Self-Seeding, Polyol Process Adv Mater[J], 2002, 14(11): 833
Sun Y et al.Uniform Silver Nanowires Synthesis by Reducing AgN03 with Ethylene Glycol in the Presence of Seeds and Poly(Vinyl Pyrrolidone).Chem Mater[J], 2002,14(11): 4736
Michael Giersig, Isabel Pastoriza-Santos and Luis M.Liz-Marzan.Evidence of an aggregative mechanism during the formation of silver nanowires in N,N-dimethylformamide J Mater Chem[J], 2004, 14(4): 607
Isabel Pastoriza-Santos and Luis M.Liz-Marzan et al.Formation of PVP-Protected Metal Nanoparticles in DMF Langmuir[J], 2002, 18(7): 2888
Isabel Pastoriza-Santos, LM Liz-Marzan.Formation and stabilization of silver nanoparticles through reduction by N, N-dimethylformamide Langmuir[J], 1999, 15(4):948
Jin R et al.Controlling anisotropic nanoparticle growth through plasmon excitation Nature[J], 2003,425: 487
Jin R et al.Photoinduced Conversion of Silver Nanospheres to Nanoprisms Science[J],2001,294: 1901
Isabel Pastoriza-Santos et al.Synthesis of silver nanoprisms in DMF Nano Lett[J], 2002,2(8): 903
Chen Sihai et al.Synthesis and Characterization of Truncated Triangular Silver Nanoplates Nano Lett[J], 2002, 2(9): 1003
Chen Sihai et al.Silver Nanoplates: Size Control in Two Dimensions and Formation Mechanisms J Phys Chem B[J], 2004, 108(18): 5500
Sun Y, Mayers B, Xia Y.Transformation of Silver Nanospheres into Nanobelts and Triangular Nanoplates through a Thermal Process Nano Lett[J], 2003, 3(5): 675
Gabriella S, Mirkin C A.Rapid Thermal Synthesis of Silver Nanoprisms with Chemically Tailorable Thickness.Adv Mater[J], 2005, 17(4): 412
Sun Yugang, Xia Younan.Shape-Controlled Synthesis of Gold and Silver Nanoparticles.Science, 2002,298:2176
[41]Tian Z Q et al.Surface-Enhanced Raman Scattering:From Noble to Transition Metals and from Rough Surfaces to Ordered Nanostructures J Phys Chem B[J],2002,106(37):9463
[42]Wiley B et al.Polyol Synthesis of Silver Nanoparticles:Use of Chloride and Oxygen to Promote the Formation of Single-Crystal,Truncated Cubes and Tetrahedrons Nano Lett[J],2004,4(9):1733
[43]Sang Hyuk Im,Yun Tack Lee,Benjamin Wiley,Younan Xia.Large-Scale Synthesis of Silver Nanocubes:The Role of HCl in Promoting Cube Perfection and Monodispersity Angew Chem Int Ed[J],2005,44(14):2154
[44]Lee Y T,Im S H,Wiley B et al.Quick formation of single-crystal nanocubes of silver through dual functions of hydrogen gas in polyol synthesis Chemical Physics Letters[J],2005,411(4-6):479
[45]Benjamin Wiley,Yugang Sun,Brian Mayers,and Younan Xia,Shape-Controlled Synthesis of Metal Nanostructures:The Case of Silver,Chem EurJ,11(2005):454-463.
[46]Yujie Xiong,I.W.,Jingyi Chen,Honggang Cai,Zhi-Yuan Li,and Younan Xia,Poly(vinyl pyrrolidone):A Dual Functional Reductant and Stabilizer for the Facile Synthesis of Noble Metal Nanoplates in Aqueous Solutions.Langmuir,22(2006)8563-8570.
[47]Yujie Xiong,I.W.,Jingyi Chen,Honggang Cai,Zhi-Yuan Li,and Younan Xia,Poly(vinyl pyrrolidone):A Dual Functional Reductant and Stabilizer for the Facile Synthesis of Noble Metal Nanoplates in Aqueous Solutions,Langmuir,2006,22,(20),8563-8570
[48]Xia,Y.X.a.Y.Shape-Controlled Synthesis of Metal Nanostructures:The Case of Palladium,Adv.Mater.2007,19,3385-3391.
[49]Benjamin Wiley;Yugang Sun;and Xia,Y.Synthesis of Silver Nanostructures with Controlled Shapes and Properties,Acc.Chem.Res.2007,40,1067-1076.
[50]Johannes V.Barth,Giovanni Costantini & Klaus Kern.Engineering atomic and molecular nanostructures at surfaces.Nature2005,437,671-679.
[51]郭永康,鲍培谛编著,光学教程,四川大学出版社,成都,1996,357.
[52]吴强,郭光灿编著,光学,中国科学技术大学出版社,合肥,1996,369.
[53]左榘编著,激光散射原理及在高分子科学中的应用,河南科学技术出版社,1994.
[54]Lina A.Gugliotti,D.L.F.,Bruce E.Eaton,RNA-Mediated Metal-Metal Bond Formation in the Synthesis of Hexagonal Palladium Nanoparticles Science 2004,304,850-852.
[55]Benjamin J.Wiley,S.H.I.,Zhi-Yuan Li,Joeseph McLellan,Andrew Siekkinen,and Younan Xia,Maneuvering the Surface Plasmon Resonance of Silver Nanostructures through Shape-Controlled Synthesis J.Phys.Chem.B,2006,110,(32),15666-15675.
[1]沈萍,范秀蓉等主编微生物学实验,北京:高等教育出版社,2003,53.
[2]林敬东,杨振威,钟怀国,许增收,廖代伟,银纳米粒子的形貌可控研究,化学研究及应用,2007,19(2),169-171.
[3]廖学红,朱俊杰,赵小宁,陈洪渊,银纳米粒子的电化学合成,高等学校化学学报,2000,12(21),1837-1839
[4]Sonit Kumar Gogoi,P.G.,Anumita Paul,A.Ramesh,Siddhartha Sankar Ghosh,and Arun Chattopadhyay,Green Fluorescent Protein-Expressing Escherichia coli as a Model System for Investigating the Antimicrobial Activities of Silver Nanoparticles.Langmuir,2006,22(22),9322-9328.
[5]Chun-Nam Lok,C.-M H.,Rong Chen,Qing-Yu He,Wing-Yiu Yu,Hongzhe Sun,Paul Kwong-Hang Tam,Jen-Fu Chiu,and Chi-Ming Che,Proteomic Analysis of the Mode of Antibacterial Action of Silver Nanoparticles.J.Proteome Res.2006,5,(4),916-924.
[6]Block,S.Disinfection,Sterilization and PreserVation,3rd ed.;Lea & Febiger:Philadelphia,PA,1983.
[7]Mammen,H.C.;Choi,S.-K.;Whitesides,G.M.Polyvalent Interactions in Biological Systems:Implications for Design and Use of Multivalent Ligands and Inhibitors.Angew.Chem.,Int.Ed.1998,37,2754-2794.
[8]Yuan,H.L.;Tazuke,S.Inter- and Intramolecular Interactions of Polymer as Studied by Fluorescence Spectroscopy XVI Polym.J.1983,15,125.
[9]Donaruma,L.G.;Vogl,O.;Ottenbrite,R.M.Anionic Polymeric Drugs;John Wiley &Son:New York,1980.
[10]Donoruma,L.G.;Vogl,O.Polymeric Drugs;Academic Press:New York,1978.
[11]Davies,A.;Bentley,M.Field,B.S.J.Appl.Bacteriol.1968,31,448-452.
[12]Chen,C.Z.;Beck Tan,N.C.;Cooper,S.L.Incorporation of dimethyldodecylammonium chloride functionalities onto poly(propylene imine)dendrimers significantlyenhances their antibacterial properties Chem.Commun.1999,1585-1586.
[13]Chris Zhisheng Chen,N.C.B.-T.,Prasad Dhurjati,Tina K.van Dyk,Robert A.LaRossa,and Stuart L.Cooper,Quaternary Ammonium Functionalized Poly(propylene imine) Dendrimers as Effective Antimicrobials:Structure-ActivityStudies.Biomacromolecules 2000,1,473-480.
[14]Ramos,A.C.S.;Dantas Neto,A.A.;Castro Dantas,T.N.C.Braz J.Chem.Eng.,1997(14):159-165
[15]Helander IM,Nunniaho-Lassila EL,Ahvenainen R,et al.Chitosan disrupts the barrier properties of the outer membrane of Gram-negative bacteria[J].Intenational Journal of Microbiology,2001(71):235-244
[16]Chen,S.P.;Wu,G.Z.;Zeng,H.Y.Preparation of high antimicrobial activity thiourea chitosan-Ag~+-complex.Carbohydr.Polym.2005,60:33-38.
[17]Wang,X.H.;DU,Y.M.;Liu,H.Preparation,characterization and antimicrobial activity of chitosan-Zn complex.Carbohydr.Polym.,2004,56:21-26.
[18]P.V.AshaRani,G.L.K.M.,Manoor Prakash Hande,and Suresh Valiyaveettil,Cytotoxicity and Genotoxicity of Silver Nanoparticles in Human Cells.ACS Nano 2009.