挥发性有机物催化燃烧消除的研究
|
摘要
随着社会经济的不断发展,挥发性有机物(VOCs)的污染问题越来严重。特别是其中的芳烃类严重污染了大气,对人们的身体健康构成了严重威胁,受到了广泛关注。在诸多的处理方法中,催化燃烧由于燃烧温度低、燃烧效率高、能耗低、无二次污染等优点被看做处理VOCs最具前景技术。在整个处理系统中,催化剂是比较关键的部分,其性能优劣直接关系到催化燃烧的效率。常用的催化剂有贵金属类,过渡金属氧化物类。贵金属催化剂活性较高,但考虑价格资源等因素,过渡金属氧化物除活性稍逊色外,其它方面其更具竞争力,对其进行了研究。
首先以SiO_2为载体,MMn(M为Cu、Fe、Co、Ni)为活性组分,浸渍法制备了负载型催化剂。为提高催化性能,制备了Ce改性的FeMn系列催化剂,在常压下评价了其活性,及不同空速对催化剂活性的影响,进行了催化剂稳定性测试。评价结果表明:在FeMn/SiO_2体系中,Fe、Mn摩尔比相同时,活性组分含量为30%时催化剂有最佳活性;活性组分含量相同时,Fe、Mn摩尔比相同时催化活性最佳,在空速为3.4×10~4 h~(-1),甲苯浓度为1000ppm条件下,甲苯250℃起燃,280℃完全燃烧。空速升高,催化剂活性有一定下降。采用XRD,TPR对其进行了结构表征:活性组分含量低时,在载体表面均匀分布,但氧化还原性较弱;活性组分含量较高时,含量较多的物种在载体表面富集形成晶体,提高了催化剂氧化还原能力;
以SBA-15为载体,CoMn为活性组分,浸渍法制备了负载型催化剂。评价了催化剂的性能、及不同空速条件下其活性,发现活性组分含量相同,CoMn摩尔比为3:7时,催化剂有较好活性;CoMn摩尔比为3:7,活性组分含量为35%时催化剂活性最佳:空速为3.4×10~4 h~(-1)时,甲苯浓度1000ppm,甲苯235℃起燃,265℃完全燃烧。空速增大,催化剂活性先增大后降低。采用XRD,TPR,TEM,BET进行了结构表征:活性组分含量较高时,孔道有一定收缩,孔径、孔容、比表面积均有一定程度减少,但介孔结构仍然保持。
为强化传热性能,减小压降,参考负载型催化剂活性数据的基础上,以CoMn氧化物为活性组分,FeCrAl合金片为第一载体,SBA-15、Al_2O_3为第二载体制备并评价了金属基催化剂的性能,考察了不同空速对催化剂性能的影响。活性组分含量相同时,CoMn摩尔比为3:7有最佳活性;固定CoMn摩尔比,活性组分含量为40%催化剂活性最佳,在空速为3.4×10~4h~(-1)时,甲苯浓度为1000ppm,其250℃起燃,335℃完全燃烧。
With the economic development of the society,the pollution of Volatile Organic Compounds(VOCs),especially the aromatic gas becomes more and more serious.The aromatic gas compound is not only responsible for air pollution but is also harmful to people's health.Recently,the removal of the aromatic gas has drawn much attention among researchers.
In all of the methods used in VOCs processing,catalyst combustion is taken as the first method to be applied due to its advantages such as:low combustion temperature,few energy consumption and absence of secondary pollution.In this processing system,catalyst is the most important factor because the efficiency of the system depends on the catalyst activity.The common used catalysts are noble metals based-catalysts and transition metal-based catalysts.The noble metal-based catalysts have better activity. However,due to high cost and limited availability of noble metals,transition metal-based catalysts are preferred to noble metal-based catalysts although the former have a lower activity.For this reason we have conducted a research study on them.
First of all,we have prepared the particle supported catalysts with SiO_2 as support and MMn as the active component(M stands for Cu,Fe,Co,Ni).The FeMn-based catalysts modified with Ce promoter were also prepared in order to improve their activity and the evaluation of their activity was carried out at. atmospheric pressure.The effect of different Gas Hourly Space Velocities (GHSVs) on the catalyst activity as well as the stability of the catalyst were also investigated.The results of this investigation have shown that:in the catalyst system of FeMn/SiO_2,when Fe、Mn has the same molar ratio,the catalyst had better performance;when the content of active component is 30% and Fe,Mn had the same molar ratio,the catalyst performance was also the best:When the space velocity is 3.4×10~4,toluene concentration of 1000ppm, toluene initial combustion at the temperature of 250℃,complete combustion at the temperature of 280℃.When the space velocity increased,the catalyst activity turned down to a certain degree.The characterization of the catalysts was carried out using some characterization methods such as XRD and TPR: when there is a few amount of the active component,this can uniformly be distributed on the support,but the reduction will be weak;when there is a lot of amount of active component,the excess amount of the active component would concentrate on the surface of support in the form of crystals,then the reduction of the catalyst would be increased indeed.
Furthermore,the particle supported catalysts were prepared by the impregnation method with SBA-15 as support and CoMn oxide as the activity component.The catalyst activity,under different space velocities,was evaluated.It can be seen that when the activity component was maintained at the same value,with CoMn molar ratio of 3:7,the catalyst had better performance;and when the CoMn has the molar ratio of 3:7,the activity component of 35%,the catalyst performance is the best when the space velocity is 3.4×10~4,toluene concentration of 1000ppm,toluene initial combustion at temperature of 235℃,complete combustion at temperature of 265℃.When the space velocity increases,the catalyst activity increases first and then decreases.The characterization of the catalysts was carried out using characterization methods such as XRD and TPR:BET,TEM:when the amount of the activity component is high,the channels of the support have a certain degree of contraction and the pore size,pore volume,specific surface area also decrease to some extent,but the stucture of the mesoporous is maintained.
In order to enhance heat transfer performance,reduce the pressure drop encountered in previous particle catalysts,we prepared and evaluated the monolithic catalysts with a metallic support:With the same CoMn oxide as an active component,the FeCrAl metal was used as the first support,SBA-15, Al_2O_3 as the second support.The effect different space velocities on the catalyst activity was studied.The results have shown that when the active component of the catalysts were the same,with CoMn molar ratio of 3:7,the catalyst has better performance;when the CoMn molar ratio was kept at the same value,with the active component of 40%,the catalyst performance was the best.When the space velocity is 3.4×10~4 h~(-1),the concentration of toluene is 1000ppm,toluene initial combustion at the temperature of 250℃,toluene complete combustion at the temperature of 335℃.
首先以SiO_2为载体,MMn(M为Cu、Fe、Co、Ni)为活性组分,浸渍法制备了负载型催化剂。为提高催化性能,制备了Ce改性的FeMn系列催化剂,在常压下评价了其活性,及不同空速对催化剂活性的影响,进行了催化剂稳定性测试。评价结果表明:在FeMn/SiO_2体系中,Fe、Mn摩尔比相同时,活性组分含量为30%时催化剂有最佳活性;活性组分含量相同时,Fe、Mn摩尔比相同时催化活性最佳,在空速为3.4×10~4 h~(-1),甲苯浓度为1000ppm条件下,甲苯250℃起燃,280℃完全燃烧。空速升高,催化剂活性有一定下降。采用XRD,TPR对其进行了结构表征:活性组分含量低时,在载体表面均匀分布,但氧化还原性较弱;活性组分含量较高时,含量较多的物种在载体表面富集形成晶体,提高了催化剂氧化还原能力;
以SBA-15为载体,CoMn为活性组分,浸渍法制备了负载型催化剂。评价了催化剂的性能、及不同空速条件下其活性,发现活性组分含量相同,CoMn摩尔比为3:7时,催化剂有较好活性;CoMn摩尔比为3:7,活性组分含量为35%时催化剂活性最佳:空速为3.4×10~4 h~(-1)时,甲苯浓度1000ppm,甲苯235℃起燃,265℃完全燃烧。空速增大,催化剂活性先增大后降低。采用XRD,TPR,TEM,BET进行了结构表征:活性组分含量较高时,孔道有一定收缩,孔径、孔容、比表面积均有一定程度减少,但介孔结构仍然保持。
为强化传热性能,减小压降,参考负载型催化剂活性数据的基础上,以CoMn氧化物为活性组分,FeCrAl合金片为第一载体,SBA-15、Al_2O_3为第二载体制备并评价了金属基催化剂的性能,考察了不同空速对催化剂性能的影响。活性组分含量相同时,CoMn摩尔比为3:7有最佳活性;固定CoMn摩尔比,活性组分含量为40%催化剂活性最佳,在空速为3.4×10~4h~(-1)时,甲苯浓度为1000ppm,其250℃起燃,335℃完全燃烧。
With the economic development of the society,the pollution of Volatile Organic Compounds(VOCs),especially the aromatic gas becomes more and more serious.The aromatic gas compound is not only responsible for air pollution but is also harmful to people's health.Recently,the removal of the aromatic gas has drawn much attention among researchers.
In all of the methods used in VOCs processing,catalyst combustion is taken as the first method to be applied due to its advantages such as:low combustion temperature,few energy consumption and absence of secondary pollution.In this processing system,catalyst is the most important factor because the efficiency of the system depends on the catalyst activity.The common used catalysts are noble metals based-catalysts and transition metal-based catalysts.The noble metal-based catalysts have better activity. However,due to high cost and limited availability of noble metals,transition metal-based catalysts are preferred to noble metal-based catalysts although the former have a lower activity.For this reason we have conducted a research study on them.
First of all,we have prepared the particle supported catalysts with SiO_2 as support and MMn as the active component(M stands for Cu,Fe,Co,Ni).The FeMn-based catalysts modified with Ce promoter were also prepared in order to improve their activity and the evaluation of their activity was carried out at. atmospheric pressure.The effect of different Gas Hourly Space Velocities (GHSVs) on the catalyst activity as well as the stability of the catalyst were also investigated.The results of this investigation have shown that:in the catalyst system of FeMn/SiO_2,when Fe、Mn has the same molar ratio,the catalyst had better performance;when the content of active component is 30% and Fe,Mn had the same molar ratio,the catalyst performance was also the best:When the space velocity is 3.4×10~4,toluene concentration of 1000ppm, toluene initial combustion at the temperature of 250℃,complete combustion at the temperature of 280℃.When the space velocity increased,the catalyst activity turned down to a certain degree.The characterization of the catalysts was carried out using some characterization methods such as XRD and TPR: when there is a few amount of the active component,this can uniformly be distributed on the support,but the reduction will be weak;when there is a lot of amount of active component,the excess amount of the active component would concentrate on the surface of support in the form of crystals,then the reduction of the catalyst would be increased indeed.
Furthermore,the particle supported catalysts were prepared by the impregnation method with SBA-15 as support and CoMn oxide as the activity component.The catalyst activity,under different space velocities,was evaluated.It can be seen that when the activity component was maintained at the same value,with CoMn molar ratio of 3:7,the catalyst had better performance;and when the CoMn has the molar ratio of 3:7,the activity component of 35%,the catalyst performance is the best when the space velocity is 3.4×10~4,toluene concentration of 1000ppm,toluene initial combustion at temperature of 235℃,complete combustion at temperature of 265℃.When the space velocity increases,the catalyst activity increases first and then decreases.The characterization of the catalysts was carried out using characterization methods such as XRD and TPR:BET,TEM:when the amount of the activity component is high,the channels of the support have a certain degree of contraction and the pore size,pore volume,specific surface area also decrease to some extent,but the stucture of the mesoporous is maintained.
In order to enhance heat transfer performance,reduce the pressure drop encountered in previous particle catalysts,we prepared and evaluated the monolithic catalysts with a metallic support:With the same CoMn oxide as an active component,the FeCrAl metal was used as the first support,SBA-15, Al_2O_3 as the second support.The effect different space velocities on the catalyst activity was studied.The results have shown that when the active component of the catalysts were the same,with CoMn molar ratio of 3:7,the catalyst has better performance;when the CoMn molar ratio was kept at the same value,with the active component of 40%,the catalyst performance was the best.When the space velocity is 3.4×10~4 h~(-1),the concentration of toluene is 1000ppm,toluene initial combustion at the temperature of 250℃,toluene complete combustion at the temperature of 335℃.
引文
[1]将文举.大气污染控制工程[M].四川,四川大学出版社:2001
[2]童志权.大气污染控制工程[M].北京,机械工业出版社:2006
[3]张林,陈欢林,柴红.挥发性有机物废弃的膜法处理工艺研究进展[J].化工环保,2002,22(2):75-80
[4]唐伟.钙钛矿型催化剂对VOCs催化燃烧的研究[D].浙江,浙江工业大学:2005
[5]Daisey,J M,Hodgson A T,et al.Volatile organic compounds in twelve califomia office building:classes,concentrations and sources[J].Atoms Environment,1994,(28):3557-3562
[6]孙佩石,杨显万,谢蕴国,等.生物法净化低浓度挥发性有机废气的动力学问题探讨[J].环境科学学报,1999,19(2):153-158
[7]曹耀华,杨绍文,金梅等.纳米二氧化钛降解有机污染物的试验研究[J].矿产保护与利用,2002,(3):37-40
[8]秦朝远,乔彤森.生物法处理气体中易挥发性有机物研究进展[J].石化技术与应用2006,24(1):49-53
[9]Burgess J E,Parsons S A,Stuetz R M.Developments in odour control and waste gastreatment biotechnology[J].Biotechnology Advances,2001,19(1):35-63
[10]Yang Y F,Jiang A X,Xie B.Progress on study of microbiological treatment to odour[J].Environmental Protection Science,2001,27(105):3-6
[11]Cero L,Winer A M.Biofiltration An innovative air pollution control technology for VOCs emissions[J].Jounal of Air Waste Manage Assocation,1991,41(8):1045-1054
[12]谭天恩,聂勇,晏乃强.第十一届全国化学工程科技报告会论文集[C].湘潭:中国化工学会化学程专业委员会,2002,487
[13]Van K,Heeseh E J,Pemen A J.Elements of pulsed oronan on thermal plaSinas of Pollution control and sustainable develoPment[J].Journal of Electrostatics,2001,51(3):218-224
[14]李志荣,赵津.催化燃烧技术机理及其研究进展初探[J].科技情报开发与经济,2005,15(15):163-164
[15]DaVyH.The eolleeted work of Sir HumPhrey Davy[M].Smith Eldernad Co Comhill London.1940
[16]孙锦宜,林西平.环保催化材料与应用[M].化学工业出版社,2002,156
[17]谭明侠,王国军,谢建川.VOCs催化燃烧技术[J].四川化工,2006,2:12-15
[18]李慧卿.阳极氧化不锈钢膜担载贵金属催化剂的VOCs燃烧反应活性研究[D].浙江:浙江大学分析化学系,2004
[19]Tahir S F,Koh C A.Catalytic destruction of volatile ogrnanic compound emissions by platinum based catalyst[J].Chemosphere,1999,38(9):2109-2116
[20]Brink R W,Mulder P,Louw R.Catalytic Combustion of chlorobenzene on Pt/γ-Al_2O_3 in the presence of aliphatic hydrocarbons[J].Catalysis Today 1999,54(1):101-106
[21]Panayiotis P,Ioannides T,Verykios X E.VOC Removal:Investiggation of ethylacetate oxidation over supported Pt catalyst[J].Catalysis Today,1999,54(1):81-92
[22]罗孟飞,袁贤鑫.Pt-Pd/Al_2O_3燃烧催化剂的活性和稳定性[J].燃料化学学报,1995,23(1):23-25
[23]Kazu O,Takeshi K,Hideaki T,et al.Toluene combustion over palladium supported on various metal oxide supports[J].Applied Catalysis B:Environmental,2003,44(4):325-331
[24]Sekizawa K,Widjaja H,Maeda S,et al.Low Temperature oxidation of methane over Pd/SnO_2 Catalyst[J].Applied Catalysis A:General,2000,200(1-2):211-217
[25]Arai H,Machida M.Recent progress in high-temperature Catalytic combustion[J].Catalysis Today,1991,10(1):81-94
[26]Farrauto R J,Hobson M C,Kennelly T,et al.Catalytic chemistry of supported palladium for combustion of methane[J].Applied Catalysis A:General,1992,81(2):227-237
[27]Mac J G.Low Temperature oxidation of methane over Pd/SnO_2 catalyst[J].Scipita Metal mater,1994,31(3):1115
[28]Simona M,Salvatore S,Carmelo C,et al.Catalytic Combustion of Volatile organic compounds on gold/iron oxide catalyst[J].Applied Catalyst B:Enviormental,2000,28(2):245-251
[29]Simona M,Salvatore S,Carmelo C,et al.Catalytic Combustion of Volatile organic compounds on gold/Cerium oxide catalyst[J].Applied Catalyst B:Enviormental,2003,40(1):43-49
[30]Li C Y,Shen Y N,Jia M I,et al.Catalytic combustion of formaldehyde on gold/iron-oxide catalysts[J].Catalysis Communications,2008,9(1):355-361
[31]Pinna F,Signoretto M,Strukul G,et al.Ruthenium as a DisPersing Agentin Carbon-SuPPorted Palladium[J].Jounral of Catalysis,1995,155(1):166-169
[32]Chong K R,Boorman P M,Lewis J M,et al.A comparison of alumina,carbon,and carbon-covered alumina as supports for Ni,Sb,Mo additives:Carbon deposition and model compound reaction studies[J].1991,182(2):537-550
[33]Salvador O,Lisardo B,Herrninio S,et al.Kinetics of the deep oxidation of benzene,toluene,n-hexane and their binary mixtures overa platinum on γ-alumina catalyst[J].Applied Catalysis B:Environmental,2002,38(2):139-149
[34]Larsson P O,Anderson A,Wallenberg L R,et al.Combustion of CO and toluene;characterization of copper oxide supported on titania and activity comparisons with supported cobalt,iron and manganese oxide[J].Jounal of Catalysis,1996,163(1):279-291
[35]应卫勇,SungkonoI E,龟山秀雄.MnCuO_x/Al_2O_3催化剂上的催化燃烧及其动力学研究[J].华东理工大学学报,1999,32(6):636-639
[36]Ataloglou T,Fountzoula C,Bourikas K,et al.Cobalt oxide/g-alumina catalysts prepared by equilibrium deposition filtration:The influence of the initial cobalt concentration on the structure of the oxide phase and the activity for complete benzene oxidation.Applied Catalysis A:General,2005,288(1-2):1-9
[37]黄海凤,陈银飞,唐伟,卢晗锋.VOCs催化燃烧催化剂Mn/γ-Al_2O_3和CuMn/γ-Al_2O_3的性能研究[J].高校化学工程学报,2004,2(18):152-155
[38]黄海凤,唐伟.Cu-Mn复合氧化物及稀士助剂对VOCs催化燃烧性能的研究[J].浙江工业大学学报,2004,32(4):407-410
[39]余凤江,张丽丹.苯催化燃烧反应Cu-Mn-Ce-Zr-O催化剂催化活性的研究[J].北京化工大学学报,2001,28(4):67-72
[40]Okumura K,Kobayashi T,Hideaki,et al.Toluene combustion over palladium supported on various metal oxide supports[J].Applied Catalysis B:Environmental,2003,44(4):325-331
[41]Li W B,Chu W B,Zhuang M,et al.Catalytic oxidation of toluene on Mn-containingmixed oxides prepared in reverse microemulsions[J].Catalysis Today,2004,93-95(1):205-209
[42]Everaert K,Baeyens J.Catalytic combustion of volatile organic compounds[J].Journal of Hardous Materials,2004,109(1-3):113-139.
[43]Thomas J K,Thoi H H,Neng Y S,et al.Polymerization of acetylenes and cyclic olefins induced by metal carbynes[J].Journal of American Chemestry Society,1984,106(9):2659-2668
[44]Deo G,Wachs I E.Reactivity of Supported Vanadium Oxide Catalysts:The Partial Oxidation of Methanol[J].Journal of Catalysis,1994,146(2):323-334
[45]Terribile D,Alessandro,Leitenburg C,et al.Catalytic combustion of hydrocarbons with Mn and Cu-doped ceria-zirconia solid solutions[J].Catalysis Today,1999,47(1-4):133-140
[46]薛屏,沈岳年,孙燕华,等.La_(0.8)Sr_(0.2)MnO_3和La_(0.8)Sr_(0.2)CoO_3在γ-Al_2O_3上的载体效应研究[J].分子催化,1998,12(6):424-428
[47]Irusta S,Pina M P,Menendez M.,et al.Catalytic combustion of volatile organic compounds over La-Based Perovskites[J].Journal of Catalysis,1998,179(2):400-412
[48]Choudhary V R,Deshmukh G M,Pataskar S G.Low temperature complete combustion of dilute toluene and methyl ethyl ketone over transition metal-doped ZrO2(cubic) catalysts[J].Catalysis Communications,2004,5(3):115-119
[49]范丽萍,陈敏,邵杰,等.Zr柱撑蒙脱土上负载稀土铈及铜铈催化剂的制备与表征[J].无机化学学报,2007,23(4):1-5
[50]Hyoung S K,Tae W K,Hyoung L K,et al.Complete benzene oxidation over Pt-Pd bimetal catalyst supported onγ-alumina:influenceof Pt-Pd ratio on the catalytic activity.Applied Catalysis A:General,2005,280(2):125-131
[51]Ryme J,Ehret G,Hilaire L,et al.Microemulsionsin the preparation of highly active combustion catalysts[J].Catalysis Today,2002,75(1-4):297-303
[52]Papaefthimiou P,Ioannides T,Verykios X E.Performance of doped Pt/TiO_2(W6+) catalysts for combustion of volatile organic compounds[J].Applied Catalysis B:Environmental,1998,15(1-2):75-92
[53]Xia F J,Wu X L,Liu P S.Methods for determining aperture of porous material[J].Journal of Clincal Rehabilitive Tissue Eingineering Research,2008,12(41):8183-8187
[54]吴越,刘持标.介孔无机材料的合成、特性和应用前景[J].石油化工,1998,27:212-220
[55]Becker L,Foerster H.Oxidative decomposition of benzene and its methyl derivatives catalyzed by copper and palladium ion-exchanged Y-type zeolites Applied Catalysis B:Environmental[J].1998,17(1-2):43-49
[56]Xia Q H,Hiajat K,Kawi S.Adsorption and catalytic combustion of aromatics on platinum-Supported MCM-41 materials[J].Catalysis Today,2001,68(1-3):255-262
[57]Taralunga M,Mijoin J,Magnoux P.Catalytic destruction of chlorinated POPs-Catalytic oxidation of chloro benzene over PtHFAU catalysts[J].Applied Catalysis B:Environmental [J].2005,60(3-4):163-171
[58]Beck J S,Vartuli J C,Roth W J.A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates[J].Journal of American Chemical Society,1992,114(27):10834-10843
[59]徐如人,庞文琴.分子筛与多孔材料化学[M].北京:科学出版社,2004,533-534
[60]李时瑶,李淑莲,李恒强,等.两种催化剂在甲苯燃烧反应中的催化性能研究[J].Einvironment Science,1997,18:45-47
[61]Malaonado-Hodar F J,Moreno-Castilla C,Perez-Cadenas A.F.Catalytic combustion of toluene on platinum-monolithic carbon aerogels[J].Applied Catalysis B:Environment,2004, 54(4):217-224
[62]王爱琴.蜂窝陶瓷载体上沸石分子筛的原位合成及在NO_x中的应用[D].辽宁大连:中科院大连化物所,2001
[63]Latty J A.Improvement of toluene catalytic combustion by addition of cesium in copper exchanged zeolites the catalyst of the British Patent[P].2107837(1985)
[64]Ataloglou T,Fountzoula C,Bourikas K,et al.Cohalt oxide/γ-alumina catalyst prepared by eqalibrium deposition filtration:The influence of the intial cobalt concentration on the structure of the oxide phase and the activity for complete benzene oxidation[J].Applied catalysis A:General,2005,288:1-9
[65]梁莉,蔺焕章,吴红苑.摩托车涂装有机废气的处理工艺及设备应用[J].广州化工,2002,30(2):47-48
[66]Zhao D Y,Feng J L,Huo Q S,et al.Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores[J].Science,1998,379(23):548-552
[67]赵起龙,沈健,袁兴东,杨立娜.介孔分子筛SBA-15的研究进展[J].广州化工,2005,(1):15-21
[68]Koranyi T I,Vit Z,Poduval D G,et al.SBA-15-Supported Nickel Phosphide Hydrotreating Catalysts[J].Journal of Catalysis,2008,253(1):119-131
[69]武宝萍,元玉台,袁兴东等.介孔分子筛SBA-15催化合成柠檬酸三丁酯[J].工业催化,2004,12(1):32-35
[70]翟彦青.催化燃烧用金属载体整体式催化剂的制备及表征[D].天津:天津大学化工学院.2004
[71]李鹏,童志权,黄妍,等.新型CuMn/TiO_2苯类催化燃烧催化剂的研制及活性实验[J].环境科学学报,2008,28(3):1-8
[72]杨玉霞,徐贤伦.负载铜锰复合氧化物催化剂上有机废气(VOCs)的催化燃烧性能[J].工业催化,2005,13(增):433-434
[73]Palacio L A,Silva J M,Ribeiro F R,et al.Catalytic oxidation of volatile organic compounds with a newprecursor type copper vanadate[J].Catalysis Today,2008,133-135(1):502-508
[74]Piotrowska A M,Syczewska K Combustion of volatile organic compounds in two-component mixtures over monolithic perovskite catalysts[J].Catalyst Today,2000,59(3-4):269-278
[75]Dula R,Janik R,Machej T,et al.Mn-containing catalytic materials for the total combustion of toluene:The role of Mn localisation in the structure of LDH precursor[J].Catalysis Today,2007,119(2):327-331
[76]谢云龙,罗孟飞,杨五六.Cu-Mn复合氧化物催化剂的制备和VOCs催化燃烧性能[J].工业催化,2005,13(增).409-410
[77]张广宏,季生福,万会军,等·CuMn基SBA-15催化剂的制备及其甲苯催化燃烧消除的性能[J].北京化工大学学报,2008,35(1):1-6
[78]Monkiedje A,Spiteller M,Jacqueline S N,et al.Influence of metalaxyl and mefenoxam-based fungicides on chemical and biochemical attributes of soil quality under field conditions in a southern humid forest zone of Cameroon[J].Soil Biology And Biochemistry,2007,39(4):836-842
[79]Solis T V,Vigon P V,Aivarez S,et al.Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst[J].Catalysis Communications,2007,32(8):2037-2042
[80]Centeno M A,Paulis M,Montes M,et al.Catalytic combustion of volatile organic compounds on Au/CeO_2/Al_2O_3 and Au/Al_2O_3 catalysts[J].Applied Catalysis A:General,2002,234(1-2):65-78
[81]Zhou R,Cao Y,Yan S R,et al.Rare earth(Y,La,Ce)-promoted V-HMS mesoporous catalysts for oxidative dehydrogenation of propane[J].Applied Catalysis A:General,2002,236(1-2):103-111
[82]Wang Y J,Jie X F.Function of ceria in oxidation catalysis[J].Chinese Journal of Power Sources,2001,26(1):43-46
[83]Jiang X Y,Zhou R X.Effects of CeO_2 on dispersion state and catalytic property of CuO/Al_2O_3[J].Journal of Molecular Catalysis,1999,13(3):176-180
[84]丁华.Ce_(0.5)Zr_(0.5)O_2固溶体的制备与其催化甲苯燃烧的性能[J].辽宁化工,2006,35(3):145-147
[85]袁慎忠,薛群山,张燕,等.CeZr复合氧化物在VOCs治理中的应用[J].中国稀土学报,2005,23(专辑):72-75
[86]袁慎忠,薛群山,张燕,等.CeZr复合氧化物在VOCs治理中的应用[J].中国稀土学报,2005,23(专辑):72-75
[87]靳广洲,殷惠玲.氧化铈对负载型氧化铜催化剂的助催化作用[J].石油大学学报,1997,21(2):76-78
[88]张成华,杨勇,陶志超,李廷真.Cu、K助剂对FeMn/SiO_2催化费托合成的影响[J].物理化学学报.2006,22(11):1310-1316
[89]翟庆洲,蔡建岩,于辉,等.SBA-15分子筛的合成研究[J].硅酸盐学报,2006,34(3):385-388
[90]Mu Z,Li J J,Duan M H,et al.Catalytic combustion of benzene on Co/CeO_2/SBA-15 and Co/SBA-15 catalysts[J].Catalysis Communications,2008,9(9):1874-1877
[91]Frantisek K,Tomas R,Jana D,Valandi M,et al.Mixed oxides obtained from Co and Mn containing layered double hydroxides:Preparation,characterization,and catalytic properties[J].Journal of Solid State Chemistry,2006,179(3):812-823
[92]卢泽湘,吴平易,季生福,等.Pt/SBA-15、Pt/SBA-16催化剂的合成、表征及甲烷催化燃烧性能[J].分子催化,2008,22(4):368-373
[93]王伟,季生福,银凤翔,等.Ce_(1-x)Ni_xO_2/Al_2O_3/FeCrAl催化剂的制备及其甲烷催化燃烧性能[J].分子催化,2006,20(6):525-529
[94]江浩,郭杨龙,张志刚,等.Ni对单Pd型挥发性有机废气净化催化剂的助催化作用[J].无机化学学报,22(7):1210-1214
[95]赵雷洪,张庆豹,罗孟飞,等.Pd-Ce_(0.4)Zr_(0.6)O_2直接涂覆的整体催化剂的甲苯催化燃烧性能[J].中国稀土学报,2007,25(6):682-687
[96]张庆豹,赵雷洪,滕波涛,等.用于甲苯催化燃烧的Pd/Ce_(0.8)Zr_(0.2)O_2/基底整体催化剂[J].催化学报,2008,29(4):373-378
[97]何仪,王华,李光明,等.有机废气催化燃烧技术[J].江苏环境科技,2004,17(1):35-38
[98]谭明侠,王国军,谢建川.VOCs催化燃烧技术[J].川化,2006,2:12-15
[99]李正林,薛屏.用反相微乳法制备二甲苯燃烧催化剂CuMnO_x[J].宁夏大学学报,2008,29(1):56-60
[100]薛屏,沈岳年,孙燕华,等.La_(0.8)Sr_(0.2)MnO_3和La_(0.8)Sr_(0.2)CoO_3在C-Al_2O_3上的载体效应研究[J].分子催化,1998,12(6):424-428
[101]侯岩峰,范国良,宋崇林,等.La_(1-x)Ce_xCoO_3系钙钛矿型催化剂应用于柴油机尾气净化 催化性能的研究[J].燃料化学学报,2006,34(1):85-90
[102]赵伟,李进军,牟真,等.稀土复合钴基HMS催化剂的制备及其氯苯催化燃烧性能[J].中国稀土学报,2007,25(1):22-26
[103]王觅堂,李梅,柳召刚,等.稀土在催化燃烧中的应用研究进展[J].稀土,28(5):104-109
[104]唐运雪.有机废气处理技术与前景展望[J].湖南有色金属,2005,21(5):31-35
[2]童志权.大气污染控制工程[M].北京,机械工业出版社:2006
[3]张林,陈欢林,柴红.挥发性有机物废弃的膜法处理工艺研究进展[J].化工环保,2002,22(2):75-80
[4]唐伟.钙钛矿型催化剂对VOCs催化燃烧的研究[D].浙江,浙江工业大学:2005
[5]Daisey,J M,Hodgson A T,et al.Volatile organic compounds in twelve califomia office building:classes,concentrations and sources[J].Atoms Environment,1994,(28):3557-3562
[6]孙佩石,杨显万,谢蕴国,等.生物法净化低浓度挥发性有机废气的动力学问题探讨[J].环境科学学报,1999,19(2):153-158
[7]曹耀华,杨绍文,金梅等.纳米二氧化钛降解有机污染物的试验研究[J].矿产保护与利用,2002,(3):37-40
[8]秦朝远,乔彤森.生物法处理气体中易挥发性有机物研究进展[J].石化技术与应用2006,24(1):49-53
[9]Burgess J E,Parsons S A,Stuetz R M.Developments in odour control and waste gastreatment biotechnology[J].Biotechnology Advances,2001,19(1):35-63
[10]Yang Y F,Jiang A X,Xie B.Progress on study of microbiological treatment to odour[J].Environmental Protection Science,2001,27(105):3-6
[11]Cero L,Winer A M.Biofiltration An innovative air pollution control technology for VOCs emissions[J].Jounal of Air Waste Manage Assocation,1991,41(8):1045-1054
[12]谭天恩,聂勇,晏乃强.第十一届全国化学工程科技报告会论文集[C].湘潭:中国化工学会化学程专业委员会,2002,487
[13]Van K,Heeseh E J,Pemen A J.Elements of pulsed oronan on thermal plaSinas of Pollution control and sustainable develoPment[J].Journal of Electrostatics,2001,51(3):218-224
[14]李志荣,赵津.催化燃烧技术机理及其研究进展初探[J].科技情报开发与经济,2005,15(15):163-164
[15]DaVyH.The eolleeted work of Sir HumPhrey Davy[M].Smith Eldernad Co Comhill London.1940
[16]孙锦宜,林西平.环保催化材料与应用[M].化学工业出版社,2002,156
[17]谭明侠,王国军,谢建川.VOCs催化燃烧技术[J].四川化工,2006,2:12-15
[18]李慧卿.阳极氧化不锈钢膜担载贵金属催化剂的VOCs燃烧反应活性研究[D].浙江:浙江大学分析化学系,2004
[19]Tahir S F,Koh C A.Catalytic destruction of volatile ogrnanic compound emissions by platinum based catalyst[J].Chemosphere,1999,38(9):2109-2116
[20]Brink R W,Mulder P,Louw R.Catalytic Combustion of chlorobenzene on Pt/γ-Al_2O_3 in the presence of aliphatic hydrocarbons[J].Catalysis Today 1999,54(1):101-106
[21]Panayiotis P,Ioannides T,Verykios X E.VOC Removal:Investiggation of ethylacetate oxidation over supported Pt catalyst[J].Catalysis Today,1999,54(1):81-92
[22]罗孟飞,袁贤鑫.Pt-Pd/Al_2O_3燃烧催化剂的活性和稳定性[J].燃料化学学报,1995,23(1):23-25
[23]Kazu O,Takeshi K,Hideaki T,et al.Toluene combustion over palladium supported on various metal oxide supports[J].Applied Catalysis B:Environmental,2003,44(4):325-331
[24]Sekizawa K,Widjaja H,Maeda S,et al.Low Temperature oxidation of methane over Pd/SnO_2 Catalyst[J].Applied Catalysis A:General,2000,200(1-2):211-217
[25]Arai H,Machida M.Recent progress in high-temperature Catalytic combustion[J].Catalysis Today,1991,10(1):81-94
[26]Farrauto R J,Hobson M C,Kennelly T,et al.Catalytic chemistry of supported palladium for combustion of methane[J].Applied Catalysis A:General,1992,81(2):227-237
[27]Mac J G.Low Temperature oxidation of methane over Pd/SnO_2 catalyst[J].Scipita Metal mater,1994,31(3):1115
[28]Simona M,Salvatore S,Carmelo C,et al.Catalytic Combustion of Volatile organic compounds on gold/iron oxide catalyst[J].Applied Catalyst B:Enviormental,2000,28(2):245-251
[29]Simona M,Salvatore S,Carmelo C,et al.Catalytic Combustion of Volatile organic compounds on gold/Cerium oxide catalyst[J].Applied Catalyst B:Enviormental,2003,40(1):43-49
[30]Li C Y,Shen Y N,Jia M I,et al.Catalytic combustion of formaldehyde on gold/iron-oxide catalysts[J].Catalysis Communications,2008,9(1):355-361
[31]Pinna F,Signoretto M,Strukul G,et al.Ruthenium as a DisPersing Agentin Carbon-SuPPorted Palladium[J].Jounral of Catalysis,1995,155(1):166-169
[32]Chong K R,Boorman P M,Lewis J M,et al.A comparison of alumina,carbon,and carbon-covered alumina as supports for Ni,Sb,Mo additives:Carbon deposition and model compound reaction studies[J].1991,182(2):537-550
[33]Salvador O,Lisardo B,Herrninio S,et al.Kinetics of the deep oxidation of benzene,toluene,n-hexane and their binary mixtures overa platinum on γ-alumina catalyst[J].Applied Catalysis B:Environmental,2002,38(2):139-149
[34]Larsson P O,Anderson A,Wallenberg L R,et al.Combustion of CO and toluene;characterization of copper oxide supported on titania and activity comparisons with supported cobalt,iron and manganese oxide[J].Jounal of Catalysis,1996,163(1):279-291
[35]应卫勇,SungkonoI E,龟山秀雄.MnCuO_x/Al_2O_3催化剂上的催化燃烧及其动力学研究[J].华东理工大学学报,1999,32(6):636-639
[36]Ataloglou T,Fountzoula C,Bourikas K,et al.Cobalt oxide/g-alumina catalysts prepared by equilibrium deposition filtration:The influence of the initial cobalt concentration on the structure of the oxide phase and the activity for complete benzene oxidation.Applied Catalysis A:General,2005,288(1-2):1-9
[37]黄海凤,陈银飞,唐伟,卢晗锋.VOCs催化燃烧催化剂Mn/γ-Al_2O_3和CuMn/γ-Al_2O_3的性能研究[J].高校化学工程学报,2004,2(18):152-155
[38]黄海凤,唐伟.Cu-Mn复合氧化物及稀士助剂对VOCs催化燃烧性能的研究[J].浙江工业大学学报,2004,32(4):407-410
[39]余凤江,张丽丹.苯催化燃烧反应Cu-Mn-Ce-Zr-O催化剂催化活性的研究[J].北京化工大学学报,2001,28(4):67-72
[40]Okumura K,Kobayashi T,Hideaki,et al.Toluene combustion over palladium supported on various metal oxide supports[J].Applied Catalysis B:Environmental,2003,44(4):325-331
[41]Li W B,Chu W B,Zhuang M,et al.Catalytic oxidation of toluene on Mn-containingmixed oxides prepared in reverse microemulsions[J].Catalysis Today,2004,93-95(1):205-209
[42]Everaert K,Baeyens J.Catalytic combustion of volatile organic compounds[J].Journal of Hardous Materials,2004,109(1-3):113-139.
[43]Thomas J K,Thoi H H,Neng Y S,et al.Polymerization of acetylenes and cyclic olefins induced by metal carbynes[J].Journal of American Chemestry Society,1984,106(9):2659-2668
[44]Deo G,Wachs I E.Reactivity of Supported Vanadium Oxide Catalysts:The Partial Oxidation of Methanol[J].Journal of Catalysis,1994,146(2):323-334
[45]Terribile D,Alessandro,Leitenburg C,et al.Catalytic combustion of hydrocarbons with Mn and Cu-doped ceria-zirconia solid solutions[J].Catalysis Today,1999,47(1-4):133-140
[46]薛屏,沈岳年,孙燕华,等.La_(0.8)Sr_(0.2)MnO_3和La_(0.8)Sr_(0.2)CoO_3在γ-Al_2O_3上的载体效应研究[J].分子催化,1998,12(6):424-428
[47]Irusta S,Pina M P,Menendez M.,et al.Catalytic combustion of volatile organic compounds over La-Based Perovskites[J].Journal of Catalysis,1998,179(2):400-412
[48]Choudhary V R,Deshmukh G M,Pataskar S G.Low temperature complete combustion of dilute toluene and methyl ethyl ketone over transition metal-doped ZrO2(cubic) catalysts[J].Catalysis Communications,2004,5(3):115-119
[49]范丽萍,陈敏,邵杰,等.Zr柱撑蒙脱土上负载稀土铈及铜铈催化剂的制备与表征[J].无机化学学报,2007,23(4):1-5
[50]Hyoung S K,Tae W K,Hyoung L K,et al.Complete benzene oxidation over Pt-Pd bimetal catalyst supported onγ-alumina:influenceof Pt-Pd ratio on the catalytic activity.Applied Catalysis A:General,2005,280(2):125-131
[51]Ryme J,Ehret G,Hilaire L,et al.Microemulsionsin the preparation of highly active combustion catalysts[J].Catalysis Today,2002,75(1-4):297-303
[52]Papaefthimiou P,Ioannides T,Verykios X E.Performance of doped Pt/TiO_2(W6+) catalysts for combustion of volatile organic compounds[J].Applied Catalysis B:Environmental,1998,15(1-2):75-92
[53]Xia F J,Wu X L,Liu P S.Methods for determining aperture of porous material[J].Journal of Clincal Rehabilitive Tissue Eingineering Research,2008,12(41):8183-8187
[54]吴越,刘持标.介孔无机材料的合成、特性和应用前景[J].石油化工,1998,27:212-220
[55]Becker L,Foerster H.Oxidative decomposition of benzene and its methyl derivatives catalyzed by copper and palladium ion-exchanged Y-type zeolites Applied Catalysis B:Environmental[J].1998,17(1-2):43-49
[56]Xia Q H,Hiajat K,Kawi S.Adsorption and catalytic combustion of aromatics on platinum-Supported MCM-41 materials[J].Catalysis Today,2001,68(1-3):255-262
[57]Taralunga M,Mijoin J,Magnoux P.Catalytic destruction of chlorinated POPs-Catalytic oxidation of chloro benzene over PtHFAU catalysts[J].Applied Catalysis B:Environmental [J].2005,60(3-4):163-171
[58]Beck J S,Vartuli J C,Roth W J.A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates[J].Journal of American Chemical Society,1992,114(27):10834-10843
[59]徐如人,庞文琴.分子筛与多孔材料化学[M].北京:科学出版社,2004,533-534
[60]李时瑶,李淑莲,李恒强,等.两种催化剂在甲苯燃烧反应中的催化性能研究[J].Einvironment Science,1997,18:45-47
[61]Malaonado-Hodar F J,Moreno-Castilla C,Perez-Cadenas A.F.Catalytic combustion of toluene on platinum-monolithic carbon aerogels[J].Applied Catalysis B:Environment,2004, 54(4):217-224
[62]王爱琴.蜂窝陶瓷载体上沸石分子筛的原位合成及在NO_x中的应用[D].辽宁大连:中科院大连化物所,2001
[63]Latty J A.Improvement of toluene catalytic combustion by addition of cesium in copper exchanged zeolites the catalyst of the British Patent[P].2107837(1985)
[64]Ataloglou T,Fountzoula C,Bourikas K,et al.Cohalt oxide/γ-alumina catalyst prepared by eqalibrium deposition filtration:The influence of the intial cobalt concentration on the structure of the oxide phase and the activity for complete benzene oxidation[J].Applied catalysis A:General,2005,288:1-9
[65]梁莉,蔺焕章,吴红苑.摩托车涂装有机废气的处理工艺及设备应用[J].广州化工,2002,30(2):47-48
[66]Zhao D Y,Feng J L,Huo Q S,et al.Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores[J].Science,1998,379(23):548-552
[67]赵起龙,沈健,袁兴东,杨立娜.介孔分子筛SBA-15的研究进展[J].广州化工,2005,(1):15-21
[68]Koranyi T I,Vit Z,Poduval D G,et al.SBA-15-Supported Nickel Phosphide Hydrotreating Catalysts[J].Journal of Catalysis,2008,253(1):119-131
[69]武宝萍,元玉台,袁兴东等.介孔分子筛SBA-15催化合成柠檬酸三丁酯[J].工业催化,2004,12(1):32-35
[70]翟彦青.催化燃烧用金属载体整体式催化剂的制备及表征[D].天津:天津大学化工学院.2004
[71]李鹏,童志权,黄妍,等.新型CuMn/TiO_2苯类催化燃烧催化剂的研制及活性实验[J].环境科学学报,2008,28(3):1-8
[72]杨玉霞,徐贤伦.负载铜锰复合氧化物催化剂上有机废气(VOCs)的催化燃烧性能[J].工业催化,2005,13(增):433-434
[73]Palacio L A,Silva J M,Ribeiro F R,et al.Catalytic oxidation of volatile organic compounds with a newprecursor type copper vanadate[J].Catalysis Today,2008,133-135(1):502-508
[74]Piotrowska A M,Syczewska K Combustion of volatile organic compounds in two-component mixtures over monolithic perovskite catalysts[J].Catalyst Today,2000,59(3-4):269-278
[75]Dula R,Janik R,Machej T,et al.Mn-containing catalytic materials for the total combustion of toluene:The role of Mn localisation in the structure of LDH precursor[J].Catalysis Today,2007,119(2):327-331
[76]谢云龙,罗孟飞,杨五六.Cu-Mn复合氧化物催化剂的制备和VOCs催化燃烧性能[J].工业催化,2005,13(增).409-410
[77]张广宏,季生福,万会军,等·CuMn基SBA-15催化剂的制备及其甲苯催化燃烧消除的性能[J].北京化工大学学报,2008,35(1):1-6
[78]Monkiedje A,Spiteller M,Jacqueline S N,et al.Influence of metalaxyl and mefenoxam-based fungicides on chemical and biochemical attributes of soil quality under field conditions in a southern humid forest zone of Cameroon[J].Soil Biology And Biochemistry,2007,39(4):836-842
[79]Solis T V,Vigon P V,Aivarez S,et al.Manganese ferrite nanoparticles synthesized through a nanocasting route as a highly active Fenton catalyst[J].Catalysis Communications,2007,32(8):2037-2042
[80]Centeno M A,Paulis M,Montes M,et al.Catalytic combustion of volatile organic compounds on Au/CeO_2/Al_2O_3 and Au/Al_2O_3 catalysts[J].Applied Catalysis A:General,2002,234(1-2):65-78
[81]Zhou R,Cao Y,Yan S R,et al.Rare earth(Y,La,Ce)-promoted V-HMS mesoporous catalysts for oxidative dehydrogenation of propane[J].Applied Catalysis A:General,2002,236(1-2):103-111
[82]Wang Y J,Jie X F.Function of ceria in oxidation catalysis[J].Chinese Journal of Power Sources,2001,26(1):43-46
[83]Jiang X Y,Zhou R X.Effects of CeO_2 on dispersion state and catalytic property of CuO/Al_2O_3[J].Journal of Molecular Catalysis,1999,13(3):176-180
[84]丁华.Ce_(0.5)Zr_(0.5)O_2固溶体的制备与其催化甲苯燃烧的性能[J].辽宁化工,2006,35(3):145-147
[85]袁慎忠,薛群山,张燕,等.CeZr复合氧化物在VOCs治理中的应用[J].中国稀土学报,2005,23(专辑):72-75
[86]袁慎忠,薛群山,张燕,等.CeZr复合氧化物在VOCs治理中的应用[J].中国稀土学报,2005,23(专辑):72-75
[87]靳广洲,殷惠玲.氧化铈对负载型氧化铜催化剂的助催化作用[J].石油大学学报,1997,21(2):76-78
[88]张成华,杨勇,陶志超,李廷真.Cu、K助剂对FeMn/SiO_2催化费托合成的影响[J].物理化学学报.2006,22(11):1310-1316
[89]翟庆洲,蔡建岩,于辉,等.SBA-15分子筛的合成研究[J].硅酸盐学报,2006,34(3):385-388
[90]Mu Z,Li J J,Duan M H,et al.Catalytic combustion of benzene on Co/CeO_2/SBA-15 and Co/SBA-15 catalysts[J].Catalysis Communications,2008,9(9):1874-1877
[91]Frantisek K,Tomas R,Jana D,Valandi M,et al.Mixed oxides obtained from Co and Mn containing layered double hydroxides:Preparation,characterization,and catalytic properties[J].Journal of Solid State Chemistry,2006,179(3):812-823
[92]卢泽湘,吴平易,季生福,等.Pt/SBA-15、Pt/SBA-16催化剂的合成、表征及甲烷催化燃烧性能[J].分子催化,2008,22(4):368-373
[93]王伟,季生福,银凤翔,等.Ce_(1-x)Ni_xO_2/Al_2O_3/FeCrAl催化剂的制备及其甲烷催化燃烧性能[J].分子催化,2006,20(6):525-529
[94]江浩,郭杨龙,张志刚,等.Ni对单Pd型挥发性有机废气净化催化剂的助催化作用[J].无机化学学报,22(7):1210-1214
[95]赵雷洪,张庆豹,罗孟飞,等.Pd-Ce_(0.4)Zr_(0.6)O_2直接涂覆的整体催化剂的甲苯催化燃烧性能[J].中国稀土学报,2007,25(6):682-687
[96]张庆豹,赵雷洪,滕波涛,等.用于甲苯催化燃烧的Pd/Ce_(0.8)Zr_(0.2)O_2/基底整体催化剂[J].催化学报,2008,29(4):373-378
[97]何仪,王华,李光明,等.有机废气催化燃烧技术[J].江苏环境科技,2004,17(1):35-38
[98]谭明侠,王国军,谢建川.VOCs催化燃烧技术[J].川化,2006,2:12-15
[99]李正林,薛屏.用反相微乳法制备二甲苯燃烧催化剂CuMnO_x[J].宁夏大学学报,2008,29(1):56-60
[100]薛屏,沈岳年,孙燕华,等.La_(0.8)Sr_(0.2)MnO_3和La_(0.8)Sr_(0.2)CoO_3在C-Al_2O_3上的载体效应研究[J].分子催化,1998,12(6):424-428
[101]侯岩峰,范国良,宋崇林,等.La_(1-x)Ce_xCoO_3系钙钛矿型催化剂应用于柴油机尾气净化 催化性能的研究[J].燃料化学学报,2006,34(1):85-90
[102]赵伟,李进军,牟真,等.稀土复合钴基HMS催化剂的制备及其氯苯催化燃烧性能[J].中国稀土学报,2007,25(1):22-26
[103]王觅堂,李梅,柳召刚,等.稀土在催化燃烧中的应用研究进展[J].稀土,28(5):104-109
[104]唐运雪.有机废气处理技术与前景展望[J].湖南有色金属,2005,21(5):31-35