Er-Mn-Ti三元系合金相图773K等温截面
|
摘要
利用X射线衍射分析、差热分析以及金相分析等技术测定了Er-Mn-Ti三元系的相组成和相关系。在773K下,该三元系存在Mn_(15)Ti_(85),αMnTi,βMnTi,Mn_2Ti,Mn_5Ti,ErMn_(12),Er_6Mn_(23)和ErMn_2 8个二元化合物。用相消失法并结合点阵常数法确定了773K下,Ti在Mn中的最大固溶度约为8at.%;Mn在Mn_2Ti中的成分范围约为61-69at.%Mn。Er在Mn_2Ti相中的最大固溶度小于1at.%Er。在这个系统中没有观察到三元化合物。根据分析结果,构筑了Er-Mn-Ti三元系合金相图773K等温截面。该等温截面由11个单相区、19个两相区和9个三相区组成。
11个单相区是:α(Er),β(Ti),γ(Mn_(15)Ti_(85)),δ(αMnTi),ε(βMnTi),ζ(Mn_2Ti),η(Mn_5Ti),θ(Mn),ι(ErMn_(12)),κ(Er_6Mn_(23))和λ(ErMn_2)。
19个两相区是:α+β,β+γ,γ+δ,δ+ε,ε+ζ,ζ+η,η+θ,θ+ι,ι+κ,κ+λ,λ+α,α+γ,α+δ,α+ε,α+ζ,ζ+λ,ζ+κ,η+κ和θ+κ。
9个三相区是:α+β+γ,α+γ+δ,α+δ+ε,α+ε+ζ,α+ζ+λ,ζ+κ+λ,ζ+η+κ,η+θ+κ和θ+ι+κ。
The Phase relationship in the Er-Mn-Ti ternary system at 773K has been investigated by X-ray powder diffraction with the aid of differential thermal analysis(DTA)and optical microanalysis techniques in this work.The eight binary compounds Mn_(15)Ti_(85),αMnTi,βMnTi,Mn_2Ti,Mn_5Ti,ErMn_(12),Er_6Mn_(23)and ErMn_2 have been confirmed in this system at 773K.The maximum solid solubility of Ti in Mn is about 8at.%Ti.The homogeneity range of Mn_2Ti extends from about 61at.%to 69at.%Mn.The maximum solid solubility of Er in Mn_2Ti phase is about less than 1at.%Er.No ternary compounds were found in this ternary system.The isothermal section of phase diagram consists of eleven single-phase regions,nineteen two-phase regions and nine three-phase regions.
The eleven single-phase regions are:α(Er),β(Ti),γ(Mn_(15)Ti_(85)),δ(αMnTi),ε(βMnTi),ζ(Mn_2Ti),η(Mn_5Ti),θ(Mn),ι(ErMn_(12)),κ(Er_(6)Mn_(23)), andλ(ErMn_2).
The nineteen two-phase regions are:α+β,β+γ,γ+δ,δ+ε,ε+ζ,ζ+η,η+θ,θ+ι,ι+κ,κ+λ,λ+α,α+γ,α+δ,α+ε,α+ζ,ζ+λ,ζ+κ,η+κandθ+κ.
The nine three-phase regions are:α+β+γ,α+γ+δ,α+δ+ε,α+ε+ζ,α+ζ+λ,ζ+κ+λ,ζ+η+κ,η+θ+κandθ+ι+κ.
11个单相区是:α(Er),β(Ti),γ(Mn_(15)Ti_(85)),δ(αMnTi),ε(βMnTi),ζ(Mn_2Ti),η(Mn_5Ti),θ(Mn),ι(ErMn_(12)),κ(Er_6Mn_(23))和λ(ErMn_2)。
19个两相区是:α+β,β+γ,γ+δ,δ+ε,ε+ζ,ζ+η,η+θ,θ+ι,ι+κ,κ+λ,λ+α,α+γ,α+δ,α+ε,α+ζ,ζ+λ,ζ+κ,η+κ和θ+κ。
9个三相区是:α+β+γ,α+γ+δ,α+δ+ε,α+ε+ζ,α+ζ+λ,ζ+κ+λ,ζ+η+κ,η+θ+κ和θ+ι+κ。
The Phase relationship in the Er-Mn-Ti ternary system at 773K has been investigated by X-ray powder diffraction with the aid of differential thermal analysis(DTA)and optical microanalysis techniques in this work.The eight binary compounds Mn_(15)Ti_(85),αMnTi,βMnTi,Mn_2Ti,Mn_5Ti,ErMn_(12),Er_6Mn_(23)and ErMn_2 have been confirmed in this system at 773K.The maximum solid solubility of Ti in Mn is about 8at.%Ti.The homogeneity range of Mn_2Ti extends from about 61at.%to 69at.%Mn.The maximum solid solubility of Er in Mn_2Ti phase is about less than 1at.%Er.No ternary compounds were found in this ternary system.The isothermal section of phase diagram consists of eleven single-phase regions,nineteen two-phase regions and nine three-phase regions.
The eleven single-phase regions are:α(Er),β(Ti),γ(Mn_(15)Ti_(85)),δ(αMnTi),ε(βMnTi),ζ(Mn_2Ti),η(Mn_5Ti),θ(Mn),ι(ErMn_(12)),κ(Er_(6)Mn_(23)), andλ(ErMn_2).
The nineteen two-phase regions are:α+β,β+γ,γ+δ,δ+ε,ε+ζ,ζ+η,η+θ,θ+ι,ι+κ,κ+λ,λ+α,α+γ,α+δ,α+ε,α+ζ,ζ+λ,ζ+κ,η+κandθ+κ.
The nine three-phase regions are:α+β+γ,α+γ+δ,α+δ+ε,α+ε+ζ,α+ζ+λ,ζ+κ+λ,ζ+η+κ,η+θ+κandθ+ι+κ.
引文
[1]徐光宪,稀土,冶金工业出版社,1995.
[2]刘余九,稀土,冶金工业出版社,1983.
[3]刘光华,稀土固体材料学,机械工业出版社,1997.
[4]梁敬魁,相图与相结构(上、下册),科学出版社,1993.
[5]张圣弼,李道子,相图—原理、计算及在材料中的应用,冶金工业出版社,1986.
[6]陆学善,相图与相变,中国科学技术大学出版社,1990.
[7]鲍德佑.氢能的最新发展[J].新能源,1994,16(3):1.3.
[8]廖小珍,刘文华.贮氢合金的进展[J].稀有金属,2001,25(2):139.
[9]Reilly J.J.,Wiswall R H.,J.Inorg Chem,1968,7:2254.
[10]U.S.Patent3375676,1968.
[11]山下敏夫,蒲生孝治,森胁良夫等。日本金属协会志,1977,41:148.
[12]Shaltiel D,Jacob I,DavidovD,[J]Less-commom Met,1977,53:117.
[13]蒲生孝治,森胁良夫等,National Technical Report,1983,29(1):78.
[14]Topler J.,Feucht K.Z.Phys,Chem,1989,164:1451.
[15]Ming Au,Pourarian F.,Simizu S et al,[J]Alloys Comp,1995,223:1.
[16]Lee H.H.,Lee K.Y.,and Lee J.Y.,The Ti-base metal hydride electrode for Ni-MH rechargeable batter,[J]Alloys Comp,1996,239:63-70.
[17]Zhan Feng,Bao Deyou,Qin Guangyong et al.,Advanced Materials and Process,Second Sino-Russion Symposium,Xi'an,China,1993.3,11.
[18]Zhan Feng,Bao Deyou,Jiang Lijun et al,[J]Alloys Comp,1995,231:907.
[19]黄太仲,吴铸,黄铁生等,退火热处理对TiMn基储氢合金结构及性能的影响,中国有色金属学报,2003.2,91-95.
[20]张勇,郭生武,柳永宁,Ti-Mn基储氢合金电化学容量的一个简易模型,中国有色金属学报,2001.2,79-83.
[21]J.L.Murray,Binary Alloy Phase Diagrames,2615-2617.
[22]Gamo T,Moriwaki Y,Yanagihara N et al,Int.J.Hydrogen Energy,1985,10:39.
[23]钱久信,陈健,叶于浦,金属学报,1987,23(6):A534.
[24]李景虹,先进电池材料,北京:化学工业出版社,2004,132-133.
[25]Kim D M,Lee S M,Jung J H,Jang K J,Lee J Y,J.Electrochem Soc,1998,145:93.
[26]徐艳辉,耿伟贤,陈昀,陈长聘,Ti-Mn基储氢合金研究进展,材料科学于工程,2000.9,130-134.
[27]张虎林编,张兆仪审,109种化学元素浅释,北京,化学工业出版社,1988年.
[28]稀有金属应用,冶金工业出版社,第二版,1985.
[29]郭顺勤编,铬、锰的性质及其应用,高等教育出版社,1992.
[30][日]草道英武等编,金属钛及其应用,冶金工业出版社,1989.
[31]T.B.Massalski,H.Okamoto,P.R.Subramanian and L.Kacprzak(eds.),Binary Alloy Phase Diagrams,Vol.2,The Materials Information Society,Materials Park,OH,2nd edn.,1990.
[32]H.R.Kirchmayr and W.Lugscheider,Z.Metallkd,58(3),185-188(1967).
[33]Villars P.,Pearson'S Handbook,desk edition,Crystallographic Data for Intermetallic Phases,ASM,Materials Park,Oh,1997,Vol.2.
[34]R.L.Beck,USAEC,EAR-10,60(1960),quoted in[Shunk].
[35]N.C.Baenziger and J.L.Moriarty,J,Acta Crystallogr,14,948-950(1961).
[36]葛志明编,钛的二元系相图,国际工业出版社,1977.
[37]R.Beck,U.S.At.Energy Comm.LAR- 10,93(1960).
[38]B.Love,WADD Tech.Report60-74,Part Ⅰ(1960).
[39]R.Wang,Mater.Sci.Eng,7(3),135-140(1976).
[40]虞觉亮,易文质等,二元合金状态图集,上海科学技术出版社,1987.
[41]R.P.Elliott,Constitution of Binary Alloys,New York 1965.
[42]F.A.Shunk,Constitution of Binary Alloys,New York 1969.
[43]李树棠,晶体X射线衍射学基础,冶金工业出版社,1990.
[44]梁敬魁,相图与相结构的测定,在全国X-射线衍射学术会议上的报告,1982.
[45]梁敬魁,粉末衍射法测定晶体结构(上、下册),科学出版社,2003.
[46]马世良,金属X射线衍射学,西北工业大学出版社,1986.
[47]E.利弗森,材料的特征检测(Ⅰ、Ⅱ部分),科学出版社,1998.
[48]Materials Data JADE Release 5,XRD Pattern Processing,Materials Data Inc.(MDI).
[49]E.B.潘钦科等,金相实验室,冶金工业出版社,1956.
[50]韩得伟,金属学实验指导书,中南工业大学出版社,1990.
[51]肖特,裴卓,金相浸蚀手册,科学普及出版社,1982.
[52]魏全金,金属电子显微分析,冶金工业出版社,1990.
[53]余煜,材料结构分析基础,科学出版社,2000.
[54]J.H.Wernick,S.E.Hassko,Phys.Chem.Solids.18(2)(1961)207-209.
[55]F.E.Wang,J.V.Gilfrich,Acta Crystallogr.21(1966)476-481.
[56]P.I.Kripyakevich,D.P.Frankevich,Soviet Phys.Crystallogr.(Kristallografiya)10(4)(1965)468-469.
[57]A.Hellawell,W.Hume-Rothery,Philos.Trans.R.Soc.(Lond.)249(1957)417-454.
[58]Liu Jingqi,Ding Ren,Qian Jiqin,Zhuang Yinghong,Huang Jinli.J Alloys Compd.414(2006)94-96.
[59]Liu Jingqi,Qian Jiqin,Ding Ren,Zhuang Yinghong,Huang Jinli.J Alloys Compd.414(2006)97-99.
[60]侯增寿,卢光熙,《金属学原理》,上海科学技术出版社,1990.
[2]刘余九,稀土,冶金工业出版社,1983.
[3]刘光华,稀土固体材料学,机械工业出版社,1997.
[4]梁敬魁,相图与相结构(上、下册),科学出版社,1993.
[5]张圣弼,李道子,相图—原理、计算及在材料中的应用,冶金工业出版社,1986.
[6]陆学善,相图与相变,中国科学技术大学出版社,1990.
[7]鲍德佑.氢能的最新发展[J].新能源,1994,16(3):1.3.
[8]廖小珍,刘文华.贮氢合金的进展[J].稀有金属,2001,25(2):139.
[9]Reilly J.J.,Wiswall R H.,J.Inorg Chem,1968,7:2254.
[10]U.S.Patent3375676,1968.
[11]山下敏夫,蒲生孝治,森胁良夫等。日本金属协会志,1977,41:148.
[12]Shaltiel D,Jacob I,DavidovD,[J]Less-commom Met,1977,53:117.
[13]蒲生孝治,森胁良夫等,National Technical Report,1983,29(1):78.
[14]Topler J.,Feucht K.Z.Phys,Chem,1989,164:1451.
[15]Ming Au,Pourarian F.,Simizu S et al,[J]Alloys Comp,1995,223:1.
[16]Lee H.H.,Lee K.Y.,and Lee J.Y.,The Ti-base metal hydride electrode for Ni-MH rechargeable batter,[J]Alloys Comp,1996,239:63-70.
[17]Zhan Feng,Bao Deyou,Qin Guangyong et al.,Advanced Materials and Process,Second Sino-Russion Symposium,Xi'an,China,1993.3,11.
[18]Zhan Feng,Bao Deyou,Jiang Lijun et al,[J]Alloys Comp,1995,231:907.
[19]黄太仲,吴铸,黄铁生等,退火热处理对TiMn基储氢合金结构及性能的影响,中国有色金属学报,2003.2,91-95.
[20]张勇,郭生武,柳永宁,Ti-Mn基储氢合金电化学容量的一个简易模型,中国有色金属学报,2001.2,79-83.
[21]J.L.Murray,Binary Alloy Phase Diagrames,2615-2617.
[22]Gamo T,Moriwaki Y,Yanagihara N et al,Int.J.Hydrogen Energy,1985,10:39.
[23]钱久信,陈健,叶于浦,金属学报,1987,23(6):A534.
[24]李景虹,先进电池材料,北京:化学工业出版社,2004,132-133.
[25]Kim D M,Lee S M,Jung J H,Jang K J,Lee J Y,J.Electrochem Soc,1998,145:93.
[26]徐艳辉,耿伟贤,陈昀,陈长聘,Ti-Mn基储氢合金研究进展,材料科学于工程,2000.9,130-134.
[27]张虎林编,张兆仪审,109种化学元素浅释,北京,化学工业出版社,1988年.
[28]稀有金属应用,冶金工业出版社,第二版,1985.
[29]郭顺勤编,铬、锰的性质及其应用,高等教育出版社,1992.
[30][日]草道英武等编,金属钛及其应用,冶金工业出版社,1989.
[31]T.B.Massalski,H.Okamoto,P.R.Subramanian and L.Kacprzak(eds.),Binary Alloy Phase Diagrams,Vol.2,The Materials Information Society,Materials Park,OH,2nd edn.,1990.
[32]H.R.Kirchmayr and W.Lugscheider,Z.Metallkd,58(3),185-188(1967).
[33]Villars P.,Pearson'S Handbook,desk edition,Crystallographic Data for Intermetallic Phases,ASM,Materials Park,Oh,1997,Vol.2.
[34]R.L.Beck,USAEC,EAR-10,60(1960),quoted in[Shunk].
[35]N.C.Baenziger and J.L.Moriarty,J,Acta Crystallogr,14,948-950(1961).
[36]葛志明编,钛的二元系相图,国际工业出版社,1977.
[37]R.Beck,U.S.At.Energy Comm.LAR- 10,93(1960).
[38]B.Love,WADD Tech.Report60-74,Part Ⅰ(1960).
[39]R.Wang,Mater.Sci.Eng,7(3),135-140(1976).
[40]虞觉亮,易文质等,二元合金状态图集,上海科学技术出版社,1987.
[41]R.P.Elliott,Constitution of Binary Alloys,New York 1965.
[42]F.A.Shunk,Constitution of Binary Alloys,New York 1969.
[43]李树棠,晶体X射线衍射学基础,冶金工业出版社,1990.
[44]梁敬魁,相图与相结构的测定,在全国X-射线衍射学术会议上的报告,1982.
[45]梁敬魁,粉末衍射法测定晶体结构(上、下册),科学出版社,2003.
[46]马世良,金属X射线衍射学,西北工业大学出版社,1986.
[47]E.利弗森,材料的特征检测(Ⅰ、Ⅱ部分),科学出版社,1998.
[48]Materials Data JADE Release 5,XRD Pattern Processing,Materials Data Inc.(MDI).
[49]E.B.潘钦科等,金相实验室,冶金工业出版社,1956.
[50]韩得伟,金属学实验指导书,中南工业大学出版社,1990.
[51]肖特,裴卓,金相浸蚀手册,科学普及出版社,1982.
[52]魏全金,金属电子显微分析,冶金工业出版社,1990.
[53]余煜,材料结构分析基础,科学出版社,2000.
[54]J.H.Wernick,S.E.Hassko,Phys.Chem.Solids.18(2)(1961)207-209.
[55]F.E.Wang,J.V.Gilfrich,Acta Crystallogr.21(1966)476-481.
[56]P.I.Kripyakevich,D.P.Frankevich,Soviet Phys.Crystallogr.(Kristallografiya)10(4)(1965)468-469.
[57]A.Hellawell,W.Hume-Rothery,Philos.Trans.R.Soc.(Lond.)249(1957)417-454.
[58]Liu Jingqi,Ding Ren,Qian Jiqin,Zhuang Yinghong,Huang Jinli.J Alloys Compd.414(2006)94-96.
[59]Liu Jingqi,Qian Jiqin,Ding Ren,Zhuang Yinghong,Huang Jinli.J Alloys Compd.414(2006)97-99.
[60]侯增寿,卢光熙,《金属学原理》,上海科学技术出版社,1990.