稀土掺杂氧化钇纳米发光材料的合成及发光性能的研究
|
摘要
稀土掺杂的Y2O3纳米发光材料具有优良的发光性能和发光效率。特别是Y2O3：Eu3+发光位于610nm,是三基色(红色)之一,同时研究表明纳米尺寸的Y2O3：Eu3+是一种导体,同时又保持了体相材料的稳定性和发光特征,可以解决体相材料在FED和PDP应用中的问题,同时还可以改善涂屏工艺,因而成为FED和PDP的红色荧光粉中具有应用潜力的发光材料。
在本文中,我们系统的阐述了稀土掺杂Y203发光材料的发光机理和发光性能。我们采用水热合成法制备了以氧化钇为基质掺杂不同的稀土离子等一系列纳米发光材料,并对它们的结构和发光性能进行了详细的探讨。并通过一系列实验条件如水热温度,pH值,焙烧温度等进行了研究。为了更进一步的探讨以氧化钇为基质掺杂不同的稀土离子发光材料的发光颜色和发光强度的规律变化,我们共掺了双稀土离子(Eu,Tb),(Tb,Dy),(Eu,Dy)于氧化钇基质中。为进一步探讨非稀土离子在氧化钇晶格中对掺杂稀土离子发光性能的影响,我们共掺了碱土金属离子(Mg, Ca)于Y2O3：Eu3+中,在发光强度方面进行了详细的讨论,并得到了非常好的实验结果。
在本文中,我们利用水热法合成的单掺稀土离子,双掺稀土离子以及共掺引入不等价取代的碱土金属离子的样品,在基础领域科研方面取得了一系列重要结论和创新性结果。为稀土掺杂的Y2O3纳米发光材料成为一种极具发展前景的发光材料打下了坚实的基础。
Y2O3:Eu3+ is a conductor, while maintaining the stability of bulk materials and luminescence characteristics of bulk materials,which can solve the FED and PDP applications,this can improve the Tu-screen technology, thus the red phosphor has the potential applications of the FED and PDP's luminous material.In this article, we have adopted a series of hydrothermal synthesis of rare-earth ions co-doped as well as single-blending, and alkaline earth metal ions co-doped Y2O3 matrix in the samples of the light-emitting materials,and systematic and comprehensive study of the structure of the synthesized samples and optical performance in order to choose high quality, high-performance light-emitting material.We obtained experimental results were summarized as follows.
In the first chapter, we systematically discusses the introduction of nano materials,nano-rare earth luminescent material definition,classification and the special nature of the composition. At the same time, in this chapter we are also discuss with Y2O3 as a substrate luminescence of rare earth doped nano-materials research background, research status application,background. We use hydrothermal synthesis to prepare a series of yttrium oxide as a substrate doped with different rare earth ions nano-light-emitting materials.Their structure and luminescence properties has been studied. We researched through a series of experimental conditions,hot water temperature, pH, calcination temperature and so on. Finally, we have synthesized rare-earth-doped yttrium optimum reaction temperature is 160℃,the best reaction time is 6h, reaction solution the lowest pH value is 12.In the Y2O3:Eu system, we get such result from their fluorescence excitation and emission spectra,which, for different concentrations of Eu-doped Y2O3:Eu system, through the luminous intensity to be compared, Eu optimal doping ion is 5%, when over the concentration, due to concentration quenching effect of making it luminous intensity of dampening. In the Y2O3:Tb system and Y2O3:Dy system, on their respective rare-earth Tb, Dy ions,the luminescence properties of Y2O3 were discussed. At the same time, we have different concentrations of Tb, Dy ion doping on the luminescence properties of Y2O3 and luminous intensity are compared.End up,for Y2O3:Tb system, Tb ion optimum doping content is 4%, while for Y2O3:Dy system, Dy ion optimum doping content is 1%.
We synthesized Eu, Tb double ions,Eu, Dy double ions,Tb,Dy double ions co-doped in Y2O3 samples by hydrothermal method.We studied the morphology, luminescence properties and emitting color of the samples by TEM, fluorescence excitation and emission spectra, CIE. In the sample of Eu,Tb double ions co-doped in Y2O3,we can get that the luminous intensity of the Eu,Tb double ions in Y2O3 changed with the modification of ions'proportion under the excitation of 307nm UV. Especially when Eu, Tb ion ratio is 1:5,Eu, Tb ion green and red luminous intensity ratio is 1.15,the color of the complex light is similar to yellow white.Meanwhile,through the excitation spectrum, we can get that Tb3+may transfer energy to Eu3+in the co-doped samples.In the sample of Eu,Dy double ions co-doped in Y2O3,we can get that the luminous intensity and color of the Eu,Dy changed with the modification of ions'proportion under the excitation of 350nm UV.Because the luminous color of Dy is light, when Eu, Dy ratio is 3:1 and 2:1,the color of the complex light is red. In the sample of Tb,Dy double ions co-doped in Y2O3,we can get that the luminous intensity and color of the Eu,Dy changed with the modification of ions'proportion under the excitation of 350nm UV.Especially when Tb,Dy ion ratio is 1:1,Tb ions and Dy ions' characteristic peaks of emission intensity is same, so we can get satisfactory complex white color and the color coordinates of CIE (0.3072,0.353)with the standard white light (0.33,0.33)is very close.It can achieve to the practical application with the improvement of luminous intensity.
We synthesized Eu, Mg and Eu, Ca co-doped in Y2O3 samples by hydrothermal method.We studied the morphology, luminescence properties and emitting color of the samples by TEM,SEM, fluorescence excitation and emission spectra. In this experiment, the prepared samples of Eu, Mg, and Eu, Ca co-doped in the Y2O3 co-doped are in uniform nano-rod structure,the size of these nano-rods are nanoscale and the length is about 1000 nm, the diameter is 30-50 nm. The luminous intensity of co-doped samples increases with the increasing of Mg2+ Ca2+ ion concentration.Until the co-doped ion concentration is in 3% Mg2+,5%Ca2+,it reaches its maximum. At this time,compared with non co-doped samples,the fluorescent light intensity of Y2O3:Eu5%Mg 3%,and Y2O3:Eu5%Ca5%is 1.25 times and 1.1 times. This enhancement provide an experimental basis for improving the luminescence intensity of phosphor. Meanwhile, in this experiment, we explained the reasons for the enhancement of the luminous intensity of the co-doped samples.For this enhancement we give two possible explanations.one is based on experimental results we get, because of divalent rare-earth ions are not equivalent to the non-replacement of the defect levels generated, so that trivalent Eu ions in the charge transitions when there is a strong energy absorption, it caused an increase in luminous intensity. Another explanation is that not equivalent to non-rare earth ions in the crystal lattice of the matrix caused crystal field magnification of the activator ion Eu. These two arguments for understanding the role of co-doped ions are very meaningful.
在本文中,我们系统的阐述了稀土掺杂Y203发光材料的发光机理和发光性能。我们采用水热合成法制备了以氧化钇为基质掺杂不同的稀土离子等一系列纳米发光材料,并对它们的结构和发光性能进行了详细的探讨。并通过一系列实验条件如水热温度,pH值,焙烧温度等进行了研究。为了更进一步的探讨以氧化钇为基质掺杂不同的稀土离子发光材料的发光颜色和发光强度的规律变化,我们共掺了双稀土离子(Eu,Tb),(Tb,Dy),(Eu,Dy)于氧化钇基质中。为进一步探讨非稀土离子在氧化钇晶格中对掺杂稀土离子发光性能的影响,我们共掺了碱土金属离子(Mg, Ca)于Y2O3：Eu3+中,在发光强度方面进行了详细的讨论,并得到了非常好的实验结果。
在本文中,我们利用水热法合成的单掺稀土离子,双掺稀土离子以及共掺引入不等价取代的碱土金属离子的样品,在基础领域科研方面取得了一系列重要结论和创新性结果。为稀土掺杂的Y2O3纳米发光材料成为一种极具发展前景的发光材料打下了坚实的基础。
Y2O3:Eu3+ is a conductor, while maintaining the stability of bulk materials and luminescence characteristics of bulk materials,which can solve the FED and PDP applications,this can improve the Tu-screen technology, thus the red phosphor has the potential applications of the FED and PDP's luminous material.In this article, we have adopted a series of hydrothermal synthesis of rare-earth ions co-doped as well as single-blending, and alkaline earth metal ions co-doped Y2O3 matrix in the samples of the light-emitting materials,and systematic and comprehensive study of the structure of the synthesized samples and optical performance in order to choose high quality, high-performance light-emitting material.We obtained experimental results were summarized as follows.
In the first chapter, we systematically discusses the introduction of nano materials,nano-rare earth luminescent material definition,classification and the special nature of the composition. At the same time, in this chapter we are also discuss with Y2O3 as a substrate luminescence of rare earth doped nano-materials research background, research status application,background. We use hydrothermal synthesis to prepare a series of yttrium oxide as a substrate doped with different rare earth ions nano-light-emitting materials.Their structure and luminescence properties has been studied. We researched through a series of experimental conditions,hot water temperature, pH, calcination temperature and so on. Finally, we have synthesized rare-earth-doped yttrium optimum reaction temperature is 160℃,the best reaction time is 6h, reaction solution the lowest pH value is 12.In the Y2O3:Eu system, we get such result from their fluorescence excitation and emission spectra,which, for different concentrations of Eu-doped Y2O3:Eu system, through the luminous intensity to be compared, Eu optimal doping ion is 5%, when over the concentration, due to concentration quenching effect of making it luminous intensity of dampening. In the Y2O3:Tb system and Y2O3:Dy system, on their respective rare-earth Tb, Dy ions,the luminescence properties of Y2O3 were discussed. At the same time, we have different concentrations of Tb, Dy ion doping on the luminescence properties of Y2O3 and luminous intensity are compared.End up,for Y2O3:Tb system, Tb ion optimum doping content is 4%, while for Y2O3:Dy system, Dy ion optimum doping content is 1%.
We synthesized Eu, Tb double ions,Eu, Dy double ions,Tb,Dy double ions co-doped in Y2O3 samples by hydrothermal method.We studied the morphology, luminescence properties and emitting color of the samples by TEM, fluorescence excitation and emission spectra, CIE. In the sample of Eu,Tb double ions co-doped in Y2O3,we can get that the luminous intensity of the Eu,Tb double ions in Y2O3 changed with the modification of ions'proportion under the excitation of 307nm UV. Especially when Eu, Tb ion ratio is 1:5,Eu, Tb ion green and red luminous intensity ratio is 1.15,the color of the complex light is similar to yellow white.Meanwhile,through the excitation spectrum, we can get that Tb3+may transfer energy to Eu3+in the co-doped samples.In the sample of Eu,Dy double ions co-doped in Y2O3,we can get that the luminous intensity and color of the Eu,Dy changed with the modification of ions'proportion under the excitation of 350nm UV.Because the luminous color of Dy is light, when Eu, Dy ratio is 3:1 and 2:1,the color of the complex light is red. In the sample of Tb,Dy double ions co-doped in Y2O3,we can get that the luminous intensity and color of the Eu,Dy changed with the modification of ions'proportion under the excitation of 350nm UV.Especially when Tb,Dy ion ratio is 1:1,Tb ions and Dy ions' characteristic peaks of emission intensity is same, so we can get satisfactory complex white color and the color coordinates of CIE (0.3072,0.353)with the standard white light (0.33,0.33)is very close.It can achieve to the practical application with the improvement of luminous intensity.
We synthesized Eu, Mg and Eu, Ca co-doped in Y2O3 samples by hydrothermal method.We studied the morphology, luminescence properties and emitting color of the samples by TEM,SEM, fluorescence excitation and emission spectra. In this experiment, the prepared samples of Eu, Mg, and Eu, Ca co-doped in the Y2O3 co-doped are in uniform nano-rod structure,the size of these nano-rods are nanoscale and the length is about 1000 nm, the diameter is 30-50 nm. The luminous intensity of co-doped samples increases with the increasing of Mg2+ Ca2+ ion concentration.Until the co-doped ion concentration is in 3% Mg2+,5%Ca2+,it reaches its maximum. At this time,compared with non co-doped samples,the fluorescent light intensity of Y2O3:Eu5%Mg 3%,and Y2O3:Eu5%Ca5%is 1.25 times and 1.1 times. This enhancement provide an experimental basis for improving the luminescence intensity of phosphor. Meanwhile, in this experiment, we explained the reasons for the enhancement of the luminous intensity of the co-doped samples.For this enhancement we give two possible explanations.one is based on experimental results we get, because of divalent rare-earth ions are not equivalent to the non-replacement of the defect levels generated, so that trivalent Eu ions in the charge transitions when there is a strong energy absorption, it caused an increase in luminous intensity. Another explanation is that not equivalent to non-rare earth ions in the crystal lattice of the matrix caused crystal field magnification of the activator ion Eu. These two arguments for understanding the role of co-doped ions are very meaningful.
引文
[1](a)祝洪良,杨德仁,浙江大学,博士毕业论文.(b)张立德,牟季美,纳米材料和纳米结构,科学出版社,2001.(c) Michael U.Niemann, Sesha S.Srinivasan, Ayala R. Phani,Ashok Kumar, D.Yogi Goswami, and Elias K. Stefanakos, Nanomaterials for Hydrogen Storage Applications:A Review,Journal of Nanomaterials,2008
[2]Chen, XD;Wan, CQ;Sung, HHY,Control of Channel Size for Selective Guest Inclusion with Inlaid Anionic Building Blocks in a Porous Cationic Metal-Organic Host Framework, CHEMISTRY-A EUROPEAN JOURNAL 2009,15,6518
[3]Zhang, JC;Zhang, YG;Wang, Nanomaterial Modifications on Conductivity of Coal Conveyer Belt,JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE,2008,5,1497
[4]Zhang, X; Shi, F;Niu,Superhydrophobic surfaces:from structural control to functional application, JOURNAL OF MATERIALS CHEMISTRY,2008,18,621
[5]Song, HY;Jiang, HF;Liu, T, Preparation and photocatalytic activity of alkali titanate nano materials A(2)Ti(n)O(2n+1)(A=Li, Na and K),MATERIALS RESEARCH BULLETIN,2007,42,334
[6]Higuchi, M;Hayashi,A; Kurth, DG,Metal ion assembly in macromolecules, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2006,6,1533
[7]Liu, ZH;Wang, Y;Ge, GP,Synthesis of fluorescent composite macromolecules by using organic/inorganic assemblies as structural units,JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2006,6,3947
[8]Chujo, Y, Organic-Inorganic Nano-Hybrid Materials,KONA-POWDER AND PARTICLE, 2007,25,255
[9]Waddon, AJ;Coughlin,Crystal structure of polyhedral oligomeric silsequioxane (POSS) nano-materials:A study by x-ray diffraction and electron microscopy, CHEMISTRY OF MATERIALS,2003,15,4555
[10]Song, HH;Liu, ZH; Guo, HQ,Manufacture of organic/inorganic composite materials by using supramolecular assembly as construction blocks,ACTA POLYMERICASINICA,2003,5,609
[11]J. Hu,etal,CHEMISTRY AND PHYSICS IN ONE DIMENSION:SYNTHESIS AND PROPERTIES OF MANOWIRES AND NANOTUBES, J. Solid State Chem.1999,148,325
[12]J.Hu, etal, Observation of an Exotic Baryon with S=+1 in Photoproduction from the Proton, Chem. Lett.2005,5,74
[13]N.Klinger, etal, Thermodynamics of Si-CO System, J.AM.Ceram.Soc.1966, 49,369.
[14]Xiong, HY;Sun, SR; Jiang, Y,Application of Modern New Materials in Product Design,9th IEEE International Conference on Computer-Aided Industrial Design and Conceptual Design,2008,759-764
[15]Tietz, F; Nikolopoulos,P, Metal/Ceramic Interface Properties and Their Effects on SOFC Development, FUEL CELLS,2009,9,867
[16]Makino, A; Kazahari, A; Zhang, W, et al.Synthesis of soft/hard magnetic FePt-based glassy alloys with supercooled liquid region, JOURNAL OF APPLIED PHYSICS,2008,104
[17]张克从,近代晶体学基础,科学出版社,1998。
[18]Cui, P; Yuan, SL; Xu, GY,Phytoliths in Mealies Corns and Preparation of SiO2 Nano-materials, JOURNAL OF INORGANIC MATERIALS,2009,24,512
[19]Raj, CJ; Lincoln, MB;Das,SJ, Synthesis and characterization of doped lithium aluminate nanocrystalline particles by sol-gel method,CRYSTAL RESEARCH AND TECHNOLOGY,2008,43,823
[20]Lee, PL; Sun, YC;Ling, YC,Magnetic nano-adsorbent integrated with lab-on-valve system for trace analysis of multiple heavy metals, JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2009,24,320
[21]Eychmuller A. Structure and Photophysics of Semiconductor Nanocrystals,J. Phys Chem,104,6514,2000.
[22]W.P. Halperin, Quantum size effects in metal particles,Rev.Mod. Phys.58,533, 1986.
[23]刘行仁,王晓君,何大伟.加入WTO我国稀土发光材料面临的机遇和挑战[J].中国稀土学报,2002,20(6)：491-494
[24]Wegh R T,Donker H,Oskam K D.Visible guantum cutting in LiGdF4:Eu3+ though downconversion[J].Seience,1999,283:663
[25]Huang Lihui, Liu Xingren, Liu Hai et al.Room temperature intense emission at 1534nm in Er-doped Gd3A12Si3O12 glass[J].Appl.Phys.Lett.,2000, 77(18):2849
[26]Qiang Li, Lian Gao,Yan Dongsheng, Effects of grain size on W avelength of Y2O3:Eu emission spectra, J.Nanostructured. Materials,1997,8(7),825-831.
[27]谢平波,段昌圭,等,纳米晶Y2SiO5：Eu的浓度猝灭研究,发光学报,1998,19(1)19-23
[28]SOO Y L, MING z H, HuANG s W, Local structures around Mn Luminescent centers in Mn-doped nanocrystals of ZnS,J.Physical. Review B,1994,50(11), 7602-7607
[29]Zhang YW, Yan Z G,You L P,et al. General synthesis and characterization of monocrystalline lanthanide orthophos phate nanowires,[J].Eur. J. Inorg. Chem, 2003,(22):4099-4104.
[30]姚嫦娲,将建中,热分解法制备纳米材料,浙江大学硕士论文,2007
[31]KONRAN A, T FRIES,A GAHN,Chemical vaporsynthesis and luminescence properties of nanocrystalline cubic Y2O3:Eu, Journal of Applied Physics,1999, 86(6),3129-3133
[32]W.L Fan, X. Y.Song, Y.X. Bu, S.X. Sun, X. Zhao,Selected-Control Hydrothermal Synthesis and Formation Mechanism of Monazite-and Zircon-Type LaVO4 Nanocrystals,J. Phys.Chem. B,2006,110,23247-23254
[33]阿木日沙那,杨桦,稀土掺杂钒酸盐、铝酸盐纳米荧光粉的制备和发光性质的研究,吉林大学博士毕业论文,2008
[34]Bhargava R N, Gallagher D,Hong X, et al. Phys. Rev. Lett.,1994,72,416.
[35]Bhargava R N. J. Lumin.,1996,70,85.
[36]李建宇,稀土光学材料及其应用,化学工业出版社,2003
[37]J.Dhanaraj;R. Jagannathan,;T. R. N.Kutty and Chung-Hsin Lu. J. Phys. Chem. B,2001,105,11098
[38]Tao Y,Zhao G, Zhang W, et al.J.Mater. Res. Bull.,1991,32,501
[39]李强,高濂,严东生.[J].现代技术陶瓷,1998,(增刊)：155-158
[40]Williams D K, Bihari B,Tissue B M,et al.J.Phys. Chem. B.1998,102,916
[41]Williams D K, Yuan H B,Tissue B M,J.Lumin.,1999,83&84,297
[42]Sharma P K,Jilavi M H,Nass R,et al. J. Lumin.,1999,82,187-193)
[43]Lindong Sun, Cheng Qian, Chunsheng Liao, Xiaoli Wang, Chunhua Yan, Luminescent properties of Li+doped nanosized Y2O3:Eu, Solid State Communication,2001,119,393
[44]M.K.CHONG, K. PITA,C.H.KAM,Photoluminescence of sol-gel derived Y2O3:Eu3+thin-film phosphors with Mg2+and Al3+co-doping, Appl. Phys.A
2004,79,433
[45]R. Debnath,A. Nayak, A. Ghosh, On the enhancement of luminescence efficiency of Y2O3:Eu3+red phosphor by incorporating (Al3+, B3+) in the host lattice, Chemical Physics Letters,2007,444,324
[46]Ling Li, Jinhui Tao,Haihua Pan, Hanmin Chen, Xiaowei Wu, Feijian Zhu, Xurong Xu and Ruikang Tang, Colour tuning of core-shell fluorescent materials,Journal of Materials Chemistry,2008
[47]Yunfeng Bai, Yuxiao Wang, Guanya Peng, Wang Zhang, Yueke Wang, Kun Yang, Xueru Zhang, Yinglin Song, Enhanced white light emission in Er/Tm/Yb/Li codoped Y2O3 nanocrystals,Optics Communications 2009,282, 1922
[48]Qiang Li, Lian Gao, and Dongsheng Yan, Effects of the Coating Process on Nanoscale Y2O3:Eu3+Powders,Chem. Mater.1999,11,533-535
[49]Jun Yang, Zewei Quan, Deyan Kong, Xiaoming Liu, and Jun Lin, Y2O3:Eu3+ Microspheres:Solvothermal Synthesis and Luminescence Properties,Crystal Growth& Design,2007,7,730
[50]Xia Li,Qiang Li, Zhiguo Xia, Lin Wang, Wenxun Yan, Jiyang Wang, and R. I. Boughton, Growth and Characterization of Single-Crystal Y2O3:Eu Nanobelts Prepared with a Simple Technique, Crystal Growth& Design,2006, 6,2193
[51]Yunxia Zhang, Jun Guo, Tim White, Timothy Thatt Yang Tan, and Rong Xu, Y2O3:Tb Nanocrystals Self-Assembly into Nanorods by Oriented Attachment Mechanism,J. Phys. Chem. C,2007,111,7893-7897
[52]Suyuan Zeng,Kaibin Tang,Tanwei Li,Zhenhua Liang,3D-flower-like Y2O3:Eu3+nanostructures:Template-free synthesis and its luminescence properties, Journal of Colloid and Interface Science,2007,31,6921-929
[1]李建宇,稀土光学材料及其应用,化学工业出版社,2003
[2]Zhang YW, Yan Z G,You L P, et al. General synthesis and characterization of monocrystalline lanthanide orthophos phate nanowires,[J].Eur. J. Inorg. Chem, 2003,(22):4099-4104.
[3]姚嫦娲,将建中,热分解法制备纳米材料,浙江大学硕士论文,2007
[4]KONRAN A, T FRIES,A GAHN, Chemical vaporsynthesis and luminescence properties of nanocrystalline cubic Y2O3:Eu, Journal of Applied Physics,1999, 86(6),3129-3133
[5]W.L Fan, X. Y. Song, Y. X. Bu, S.X. Sun, X. Zhao, Selected-Control Hydrothermal Synthesis and Formation Mechanism of Monazite-and Zircon-Type LaVO4 Nanocrystals, J. Phys. Chem. B,2006,110,23247-23254
[6]J. A. Capobianco,F. Vetrone, T. DIAlesio,G. Tessari,A. Speghini and M. Bettinelli, Optical spectroscopy of nanocrystalline cubic Y2O3:Er3.obtained by combustion synthesis, Phys. Chem. Chem. Phys.,2000,2,3203-3207
[7]Christopher A. Traina and Jeffrey Schwartz, Surface Modification of Y2O3 Nanoparticles, Langmuir 2007,23,9158-9161
[8]Laura Muresan, Elisabeth-Jeanne Popovici,Rodica Grecu, Lucian Barbu Tudoran, Studies on the synthesis of europium activated yttrium oxide by wet-chemical method 1.Influence of precursor quality on phosphor photoluminescence properties, Journal of Alloys and Compounds,xxx,(2008),xxx-xxx
[9]D.N. Krasikov,A.V. Scherbinin,A.N.Vasil'ev,I.A. Kamenskikh, V.V. Mikhailin, Model of Y2O3-Yb charge-transfer luminescence based on ab initio cluster calculations, Journal of Luminescence,2008
[10]C.A. Kodaira, R. Stefani,A.S.Maia, M.C.F.C.Felinto, H.F.Brito, Optical investigation of Y2O3:Sm nanophosphor prepared by combustion and Pechini methods, Journal of Luminescence,2007,127,616-622
[11]Qiang Lu, AiHua Li,FengYunGuo,Liang Sun and LianCheng Zhao, Experimental study on the surface modification of Y2O3:Tm3+/Yb3+ nanoparticles to enhance upconversion fluorescence and weaken aggregation, Nanotechnology,2008,19,145701
[12]Guixia Liu, Guangyan Hong, Synthesis of SiO2/Y2O3:Eu core-shell materials and hollow spheres,Journal of Solid State Chemistry,2005,178,1647-1651
[13]M.Raukas,A. Konrad,K.C.Mishra,Luminescence in nano-size Y2O3:Ce,
Journal of Luminescence 122-123(2007)773-775
[14]Cory D.Cress,Christopher S.Redino,Brian J.Landi,Ryne P. Raffaelle, Alpha-particle-induced luminescence of rare-earth-doped Y2O3 nanophosphors, Journal of Solid State Chemistry 2008,181,2041-2045
[15]Gautom Kumar Das and Timothy Thatt Yang Tan, Rare-Earth-Doped and Codoped Y2O3 Nanomaterials as Potential Bioimaging Probes, J. Phys.Chem. C2008,112,11211-11217
[16]MKDevaraju, S Yin and T Sato, A rapid hydrothermal synthesis of rare earth oxide activated Y(OH)3 and Y2O3 nanotubes,Nanotechnology 2009,20 305302
[17]Peter A. Tanner,Lianshe Fu, Morphology of Y2O3:Eu3+prepared by hydrothermal synthesis, Chemical Physics Letters,2009,470,75-79
[18]Wang Chaonan, ZhangWeiping, Yin Min, Preparation and spectroscopic properties of Y2O3:Eu3+nanopowders and ceramics,Journal of Alloys and Compounds,2009,474,180-184
[19]M.K. Devara ju,ShuYin,TsugioSato,Solvothermal synthesis,controlled morphology and optical properties of Y2O3:Eu3+nanocrystals,Journal of Crystal Growth,2009,311,580-584
[20]K.M. Nissamudeen, S.Sankar, A.H. Bahna, K.G.Gopchandran, Studies on the influence of lithiumin corporationin the photoluminescence of Y2O3:Eu3+thin films,Journal of Physics and Chemistry of Solid,2009,70,821-826
[21]Shrout TR and Halliyal A.Preparation of Lead-based ferroelectric relaxors for capacitors.[J]American Ceramic Society of Bulletin,1987,66:704-711.
[22]PARK C Heol-hee, PARK So-jung, YU Byung-yong, et al. UV xcitation of Y3Al5O12:Tb phosphor prepared by a sol-gel process [J].Mater Sci Lett,2000, 9(2):335-338.
[1].M.I.Martinez-Rubio,T.G.Ireland,G.R.Fern,J.Silver,M.J.Snowden, A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir.17(2001)7145.
[2].S.H.Chao,S.H.Kwon,J.S.Yoo,C.W.Oh,J.D.Lee,K. J.Hong,S.J.Kwon,J. Electrochem. Soc.147(2000)3143.
[3]P.N.Prasad, Nanophotonics, John Wiley&Sons, NY,2004.
[4]F.Wang, W.B.Tan, Y.Zhang, X. Fan, M.Wang, Luminescent nanomaterials for biological labelling,Nanotechnology.17 (2006) R1.
[5]Q.Lu, A. Li, F.Y.Guo,L. Sun, L.C.Zhao, Experimental study on the surface modification of Y2O3:Tm3+/Yb3+nanoparticles to enhance upconversion fluorescence and weaken aggregation, Nanotechnology.19 (2008)145701.
[6]K.L. Frindell, M.H. Bartl,A. Popitsch, G.D.Stucky, Sensitized Luminescence of Trivalent Europium by Three-Dimensionally Arranged Anatase Nanocrystals in Mesostructured Titania Thin Films,Angew Chem. Int. Ed.41(2002)960.
[7]G.Wakefied,E.Holland,P.J.Dobson,T.L. Hutchison,Adv Mater.13(2001)1 557-60.
[8]J.H.Gwak, S.H.Park, J.E.Jang, S.J.Lee, J.E.Jung, J.M.Kim, High resolution phosphor screening method for full-color field emission display applications, J Vac Sci TechnolB.18(2000)1101-5.
[9]J.CPark, H.K.Moon, D. K.Kim, S.H.Byeon, B.C.Kim and K.S.Suh,Morphology and cathodoluminescence of Li-doped GdO:Eu, a red phosphor...Appl Phys. Lett.77(2000)2162.
[10]Y.C.Kang, S.B.Park, I.W.Lenggoroand, K.Okuyama,Gd2O3:Eu phosphor particles with sphericity, submicron size and non-aggregation characteristics,J. Phys. Chem. Solids.60(1999)379.
[11]B.Mercier, C.Dujardin, G.Ledoux, C.Louis and O.Tillement, Observation of the gap blueshift on GdO:Eu nanoparticles,J. Appl. Phys.96(2004)650.
[12]M.I. Martinez-Rubio,T. G. Ireland,G.R. Fern, J.Silver and M.J.Snowden, A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir,2001,17,7145.
[13]M.Yin, W.Zhang, S.Xia and J.-C.Krupa, Luminescence of nanometric scale
Y2SiO5:Eu3+,J. Lumin.,1996,68,335.
[14]Y. H.Zhou and J.Lin, Preparation of Y3Al5O12:Eu phosphors by citric-gel method and their luminescent...Opt.Mater.,2002,27,1426.
[15]X. Zeng, G.Zhao, J. Xu, H. Li, X. He, H.Pang and M.Jie, Thermal conductivity and refractive indices of Nd:GdVO4 crystals,J.Cryst.Growth, 2005,274,495.
[16]G. Panayiotakis, D.Cavouras, I.Kandarakis and C.Nomicos,A study of X-ray luminescence and spectral compatibility of europium-activated yttrium-vanadate (YVO4:Eu) screens Appl. Phys. A,1996,62,483.
[17]K. Y.Jung and H.W.Lee, Enhanced luminescent properties of Y3Al5O12:Tb3+,Ce3+phosphor prepared by spray pyrolysis,J. Lumin.,2007, 126,469
[18]L. Li, W.Jiang, H. Pan, X. Xu, Y.Tang, J.Ming, Z. Xu and R. Tang, J. Phys.Chem. C,2007,111,4111.
[19]J. Qiu, K. Miura, H. Inouye, Y. Kondo, T. Mitsuyu and K. Hirao, Femtosecond laser-induced three-dimensional bright and long-lasting...,Appl. Phys. Lett., 1998,73,1763.
[20]B.Moine and G. Bizarri, Rare-earth doped phosphors:oldies or goldies, Mater. Sci. Eng.,B,2003,105,2.
[21]C.R. Ronda, T.Ju" stel and H.Nikol, Rare earth phosphors:fundamentals and applications,J. Alloys Compd,1998,275-277,669.
[22]E. J.Bosze, J. Carver, S.Singson, J.McKittrick and G. A. Hirata, Long-Ultraviolet-Excited White-Light Emission in Rare-Earth-Activated Yttrium-Oxyorthosilicate,J. Am. Ceram. Soc,2007,90,2484.
[23]C. Feldmann,T. Ju" stel,C. R. Ronda and P. J. Schmidt,Adv. Funct. Mater.,2003,13,511.
[1].Chao, S.H.;Kwon, S.H.;Yoo, J.S.;Oh, C.W.;Lee,J.D.;Hong,K. J.;Kwon, S. J. J. Electrochem. Soc. (2000),147,3143.
[2].Martinez-Rubio,M.I.;Ireland,T.G.;Fern,G.R.;Silver,J.;Snowden,M.J.A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir,2001,17,7145.
[3]C.N.R.Rao, Mater. Sci. Enging.B,18(1993)1.
[4]C.D. Veitch, Synthesis of polycrystalline yttrium iron garnet and yttrium aluminium garnet from organic precursors,J. Mater. Sci.26(1991)6527.
[5]Y.C. Kang, H,S.Roh. S.B.Park, Preparation of Y2O3:Eu Phosphor Particles of Filled Morphology at High Precursor Concentrations by Spray Pyrolysis,Adv.Mater.12 (2000) 451.
[6]D.K. Wilams, B.M.Tissue, Preparation and Fluorescence Spectroscopy of Bulk Monoclinic Eu3+:Y2O3 and Comparison to Eu3+:Y2O3 Nanocrystals, J.Phys.Chem.B 102(1998)916
[7]Y. Tao, G. W. Zhao, W.P.Zhang,S.D.Xia, Mater.Res.Bull.32(1997) 501
[8]L.D. Sun, J. Yao, C.H. Liu, C.S.Liao, C.H.Yan, Rare earth activated nanosized oxide phosphors:synthesis and optical properties, J. Lumin.87—89(2000)447
[9]Jun Yang, Zewei Quan, Deyan Kong, Xiaoming Liu, Jun Lin,Size-tailored synthesis and luminescent properties of one-dimensional Gd2O3:...,Crystal Growth and Design,(2007)7,730--735
[10]R. Debnath,A. Nayak, A. Ghosh. On the enhancement of luminescence efficiency of Y2O3:Eu3+red phosphor by incorporating (Al3+, B3+) in the host lattice,Chemical Physics Letters,444(2007)324-327
[11]A.S.Gouveia-Neto, E.B.da Costa, P.V.dos Santos,L.A.Bueno, S.J.L. Ribeiro, Twentyfold blue upconversion emission enhancement through thermal effects in Pr3+/Yb3+-codoped fluoroindate glasses excited at 1.064 μm, J. Appl. Phys.94, 5678 (2003)
[12]J.H.Jeong, J.S.Bae, S.S.Yi, J.C.Park, Y.S.Kim,Photoluminescence characteristics of Li-doped Y2O3:Eu3+thin-film phosphors on sapphire substrates,J. Phys.:Condens. Matter 15,567(2003)
[13]J.H. Jeong, B.K. Moon, H.J.Seo, J.S.Bae, S.S.Yi, I.W.Kim, H.L. Park, Improved photoluminescence of pulsed-laser-ablated Y2O3:Eu3+thin-film phosphors by Gd substitution,Appl Phys. Lett.83,1346 (2003)
[14]M.G. Ko, J.C.Park, D.K. Kim, S.H.Byeon,Low-voltage cathodoluminescence property of Li-doped Gd2-xYxO3:Eu3+,J. Luminesc.104,215(2003)
[15].J.H.Jeong, B.K. Moon, H.J.Seo, J.S.Bae, S.S.Yi,I.W.Kim, H.L. Park,Scaling behavior of ferroelectric hysteresis loop in pulsed-laser-deposited SrBiTaO. Appl. Phys. Lett.83,1346(2003)
[16]M.G.Ko, J.C.Park, D.K. Kim, S.H. Byeon,Low-voltage cathodoluminescence property of Li-doped Gd2-xYxO3:Eu3+,J. Luminesc.104,215(2003)
[17]Xia Li, Qiang Li,Zhiguo Xia, Lin Wang, Wenxun Yan, Jiyang Wang, and R.I. Boughton, Growth and Characterization of Single-Crystal Y2O3:Eu Nanobelts Prepared with a Simple Technique, Crystal Growth& Design,2006, 6,2193
[18].B.D.Cullity, S.R. Stock (2001)Elements of X-ray Diffraction.
[19].Wang, Z. L. Self-Assembly of Gold Nanorods,J. Phys. Chem. B,2000,104, 1153.
[20].(a)Silver, J.;Martunez, M.I.;Ireland, T. G.;Withnall, R.J.J.Phys.Chem. B 2001,105,7200. (b) Maitric,M.;Antic,B.;Balanda, M.;Rodic, D.;Napijalo, M. L. J. Phys.:Condens. Matter 1997,9,4103.
[21].E.J. Bosze, G.A. Hirata, L.E.Shea-Rohwer, J. McKittrick,Improving the efficiency of a blue-emitting phosphor by an energy transfer from Gd3+to Ce3+
,J. Luminesc.104,47 (2003)
[22].Z.P. Ai,Hugely enhanced electroluminescence from mesoporous ZnO particles, Opt. Mater.24,589 (2003)
[23].W.W.Zhang, W.P.Zhang, P.B.Xie, M.Yin, H.T.Chen, L. Jing, Y.S.Zhang, L.R. Lou, S.D.Xia,Optical properties of nanocrystalline Y2O3:Eu depending on its odd structure,J. Colloid Interface Sci.262,588 (2003)
[24].M.K.CHONG,K. PITA,C.H.KAM,Photoluminescence of sol-gel derived Y2O3:Eu3+thin-film phosphors with Mg2+and Al3+co-doping, Appl Phys. A 2004,79,433
[2]Chen, XD;Wan, CQ;Sung, HHY,Control of Channel Size for Selective Guest Inclusion with Inlaid Anionic Building Blocks in a Porous Cationic Metal-Organic Host Framework, CHEMISTRY-A EUROPEAN JOURNAL 2009,15,6518
[3]Zhang, JC;Zhang, YG;Wang, Nanomaterial Modifications on Conductivity of Coal Conveyer Belt,JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE,2008,5,1497
[4]Zhang, X; Shi, F;Niu,Superhydrophobic surfaces:from structural control to functional application, JOURNAL OF MATERIALS CHEMISTRY,2008,18,621
[5]Song, HY;Jiang, HF;Liu, T, Preparation and photocatalytic activity of alkali titanate nano materials A(2)Ti(n)O(2n+1)(A=Li, Na and K),MATERIALS RESEARCH BULLETIN,2007,42,334
[6]Higuchi, M;Hayashi,A; Kurth, DG,Metal ion assembly in macromolecules, JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2006,6,1533
[7]Liu, ZH;Wang, Y;Ge, GP,Synthesis of fluorescent composite macromolecules by using organic/inorganic assemblies as structural units,JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY,2006,6,3947
[8]Chujo, Y, Organic-Inorganic Nano-Hybrid Materials,KONA-POWDER AND PARTICLE, 2007,25,255
[9]Waddon, AJ;Coughlin,Crystal structure of polyhedral oligomeric silsequioxane (POSS) nano-materials:A study by x-ray diffraction and electron microscopy, CHEMISTRY OF MATERIALS,2003,15,4555
[10]Song, HH;Liu, ZH; Guo, HQ,Manufacture of organic/inorganic composite materials by using supramolecular assembly as construction blocks,ACTA POLYMERICASINICA,2003,5,609
[11]J. Hu,etal,CHEMISTRY AND PHYSICS IN ONE DIMENSION:SYNTHESIS AND PROPERTIES OF MANOWIRES AND NANOTUBES, J. Solid State Chem.1999,148,325
[12]J.Hu, etal, Observation of an Exotic Baryon with S=+1 in Photoproduction from the Proton, Chem. Lett.2005,5,74
[13]N.Klinger, etal, Thermodynamics of Si-CO System, J.AM.Ceram.Soc.1966, 49,369.
[14]Xiong, HY;Sun, SR; Jiang, Y,Application of Modern New Materials in Product Design,9th IEEE International Conference on Computer-Aided Industrial Design and Conceptual Design,2008,759-764
[15]Tietz, F; Nikolopoulos,P, Metal/Ceramic Interface Properties and Their Effects on SOFC Development, FUEL CELLS,2009,9,867
[16]Makino, A; Kazahari, A; Zhang, W, et al.Synthesis of soft/hard magnetic FePt-based glassy alloys with supercooled liquid region, JOURNAL OF APPLIED PHYSICS,2008,104
[17]张克从,近代晶体学基础,科学出版社,1998。
[18]Cui, P; Yuan, SL; Xu, GY,Phytoliths in Mealies Corns and Preparation of SiO2 Nano-materials, JOURNAL OF INORGANIC MATERIALS,2009,24,512
[19]Raj, CJ; Lincoln, MB;Das,SJ, Synthesis and characterization of doped lithium aluminate nanocrystalline particles by sol-gel method,CRYSTAL RESEARCH AND TECHNOLOGY,2008,43,823
[20]Lee, PL; Sun, YC;Ling, YC,Magnetic nano-adsorbent integrated with lab-on-valve system for trace analysis of multiple heavy metals, JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2009,24,320
[21]Eychmuller A. Structure and Photophysics of Semiconductor Nanocrystals,J. Phys Chem,104,6514,2000.
[22]W.P. Halperin, Quantum size effects in metal particles,Rev.Mod. Phys.58,533, 1986.
[23]刘行仁,王晓君,何大伟.加入WTO我国稀土发光材料面临的机遇和挑战[J].中国稀土学报,2002,20(6)：491-494
[24]Wegh R T,Donker H,Oskam K D.Visible guantum cutting in LiGdF4:Eu3+ though downconversion[J].Seience,1999,283:663
[25]Huang Lihui, Liu Xingren, Liu Hai et al.Room temperature intense emission at 1534nm in Er-doped Gd3A12Si3O12 glass[J].Appl.Phys.Lett.,2000, 77(18):2849
[26]Qiang Li, Lian Gao,Yan Dongsheng, Effects of grain size on W avelength of Y2O3:Eu emission spectra, J.Nanostructured. Materials,1997,8(7),825-831.
[27]谢平波,段昌圭,等,纳米晶Y2SiO5：Eu的浓度猝灭研究,发光学报,1998,19(1)19-23
[28]SOO Y L, MING z H, HuANG s W, Local structures around Mn Luminescent centers in Mn-doped nanocrystals of ZnS,J.Physical. Review B,1994,50(11), 7602-7607
[29]Zhang YW, Yan Z G,You L P,et al. General synthesis and characterization of monocrystalline lanthanide orthophos phate nanowires,[J].Eur. J. Inorg. Chem, 2003,(22):4099-4104.
[30]姚嫦娲,将建中,热分解法制备纳米材料,浙江大学硕士论文,2007
[31]KONRAN A, T FRIES,A GAHN,Chemical vaporsynthesis and luminescence properties of nanocrystalline cubic Y2O3:Eu, Journal of Applied Physics,1999, 86(6),3129-3133
[32]W.L Fan, X. Y.Song, Y.X. Bu, S.X. Sun, X. Zhao,Selected-Control Hydrothermal Synthesis and Formation Mechanism of Monazite-and Zircon-Type LaVO4 Nanocrystals,J. Phys.Chem. B,2006,110,23247-23254
[33]阿木日沙那,杨桦,稀土掺杂钒酸盐、铝酸盐纳米荧光粉的制备和发光性质的研究,吉林大学博士毕业论文,2008
[34]Bhargava R N, Gallagher D,Hong X, et al. Phys. Rev. Lett.,1994,72,416.
[35]Bhargava R N. J. Lumin.,1996,70,85.
[36]李建宇,稀土光学材料及其应用,化学工业出版社,2003
[37]J.Dhanaraj;R. Jagannathan,;T. R. N.Kutty and Chung-Hsin Lu. J. Phys. Chem. B,2001,105,11098
[38]Tao Y,Zhao G, Zhang W, et al.J.Mater. Res. Bull.,1991,32,501
[39]李强,高濂,严东生.[J].现代技术陶瓷,1998,(增刊)：155-158
[40]Williams D K, Bihari B,Tissue B M,et al.J.Phys. Chem. B.1998,102,916
[41]Williams D K, Yuan H B,Tissue B M,J.Lumin.,1999,83&84,297
[42]Sharma P K,Jilavi M H,Nass R,et al. J. Lumin.,1999,82,187-193)
[43]Lindong Sun, Cheng Qian, Chunsheng Liao, Xiaoli Wang, Chunhua Yan, Luminescent properties of Li+doped nanosized Y2O3:Eu, Solid State Communication,2001,119,393
[44]M.K.CHONG, K. PITA,C.H.KAM,Photoluminescence of sol-gel derived Y2O3:Eu3+thin-film phosphors with Mg2+and Al3+co-doping, Appl. Phys.A
2004,79,433
[45]R. Debnath,A. Nayak, A. Ghosh, On the enhancement of luminescence efficiency of Y2O3:Eu3+red phosphor by incorporating (Al3+, B3+) in the host lattice, Chemical Physics Letters,2007,444,324
[46]Ling Li, Jinhui Tao,Haihua Pan, Hanmin Chen, Xiaowei Wu, Feijian Zhu, Xurong Xu and Ruikang Tang, Colour tuning of core-shell fluorescent materials,Journal of Materials Chemistry,2008
[47]Yunfeng Bai, Yuxiao Wang, Guanya Peng, Wang Zhang, Yueke Wang, Kun Yang, Xueru Zhang, Yinglin Song, Enhanced white light emission in Er/Tm/Yb/Li codoped Y2O3 nanocrystals,Optics Communications 2009,282, 1922
[48]Qiang Li, Lian Gao, and Dongsheng Yan, Effects of the Coating Process on Nanoscale Y2O3:Eu3+Powders,Chem. Mater.1999,11,533-535
[49]Jun Yang, Zewei Quan, Deyan Kong, Xiaoming Liu, and Jun Lin, Y2O3:Eu3+ Microspheres:Solvothermal Synthesis and Luminescence Properties,Crystal Growth& Design,2007,7,730
[50]Xia Li,Qiang Li, Zhiguo Xia, Lin Wang, Wenxun Yan, Jiyang Wang, and R. I. Boughton, Growth and Characterization of Single-Crystal Y2O3:Eu Nanobelts Prepared with a Simple Technique, Crystal Growth& Design,2006, 6,2193
[51]Yunxia Zhang, Jun Guo, Tim White, Timothy Thatt Yang Tan, and Rong Xu, Y2O3:Tb Nanocrystals Self-Assembly into Nanorods by Oriented Attachment Mechanism,J. Phys. Chem. C,2007,111,7893-7897
[52]Suyuan Zeng,Kaibin Tang,Tanwei Li,Zhenhua Liang,3D-flower-like Y2O3:Eu3+nanostructures:Template-free synthesis and its luminescence properties, Journal of Colloid and Interface Science,2007,31,6921-929
[1]李建宇,稀土光学材料及其应用,化学工业出版社,2003
[2]Zhang YW, Yan Z G,You L P, et al. General synthesis and characterization of monocrystalline lanthanide orthophos phate nanowires,[J].Eur. J. Inorg. Chem, 2003,(22):4099-4104.
[3]姚嫦娲,将建中,热分解法制备纳米材料,浙江大学硕士论文,2007
[4]KONRAN A, T FRIES,A GAHN, Chemical vaporsynthesis and luminescence properties of nanocrystalline cubic Y2O3:Eu, Journal of Applied Physics,1999, 86(6),3129-3133
[5]W.L Fan, X. Y. Song, Y. X. Bu, S.X. Sun, X. Zhao, Selected-Control Hydrothermal Synthesis and Formation Mechanism of Monazite-and Zircon-Type LaVO4 Nanocrystals, J. Phys. Chem. B,2006,110,23247-23254
[6]J. A. Capobianco,F. Vetrone, T. DIAlesio,G. Tessari,A. Speghini and M. Bettinelli, Optical spectroscopy of nanocrystalline cubic Y2O3:Er3.obtained by combustion synthesis, Phys. Chem. Chem. Phys.,2000,2,3203-3207
[7]Christopher A. Traina and Jeffrey Schwartz, Surface Modification of Y2O3 Nanoparticles, Langmuir 2007,23,9158-9161
[8]Laura Muresan, Elisabeth-Jeanne Popovici,Rodica Grecu, Lucian Barbu Tudoran, Studies on the synthesis of europium activated yttrium oxide by wet-chemical method 1.Influence of precursor quality on phosphor photoluminescence properties, Journal of Alloys and Compounds,xxx,(2008),xxx-xxx
[9]D.N. Krasikov,A.V. Scherbinin,A.N.Vasil'ev,I.A. Kamenskikh, V.V. Mikhailin, Model of Y2O3-Yb charge-transfer luminescence based on ab initio cluster calculations, Journal of Luminescence,2008
[10]C.A. Kodaira, R. Stefani,A.S.Maia, M.C.F.C.Felinto, H.F.Brito, Optical investigation of Y2O3:Sm nanophosphor prepared by combustion and Pechini methods, Journal of Luminescence,2007,127,616-622
[11]Qiang Lu, AiHua Li,FengYunGuo,Liang Sun and LianCheng Zhao, Experimental study on the surface modification of Y2O3:Tm3+/Yb3+ nanoparticles to enhance upconversion fluorescence and weaken aggregation, Nanotechnology,2008,19,145701
[12]Guixia Liu, Guangyan Hong, Synthesis of SiO2/Y2O3:Eu core-shell materials and hollow spheres,Journal of Solid State Chemistry,2005,178,1647-1651
[13]M.Raukas,A. Konrad,K.C.Mishra,Luminescence in nano-size Y2O3:Ce,
Journal of Luminescence 122-123(2007)773-775
[14]Cory D.Cress,Christopher S.Redino,Brian J.Landi,Ryne P. Raffaelle, Alpha-particle-induced luminescence of rare-earth-doped Y2O3 nanophosphors, Journal of Solid State Chemistry 2008,181,2041-2045
[15]Gautom Kumar Das and Timothy Thatt Yang Tan, Rare-Earth-Doped and Codoped Y2O3 Nanomaterials as Potential Bioimaging Probes, J. Phys.Chem. C2008,112,11211-11217
[16]MKDevaraju, S Yin and T Sato, A rapid hydrothermal synthesis of rare earth oxide activated Y(OH)3 and Y2O3 nanotubes,Nanotechnology 2009,20 305302
[17]Peter A. Tanner,Lianshe Fu, Morphology of Y2O3:Eu3+prepared by hydrothermal synthesis, Chemical Physics Letters,2009,470,75-79
[18]Wang Chaonan, ZhangWeiping, Yin Min, Preparation and spectroscopic properties of Y2O3:Eu3+nanopowders and ceramics,Journal of Alloys and Compounds,2009,474,180-184
[19]M.K. Devara ju,ShuYin,TsugioSato,Solvothermal synthesis,controlled morphology and optical properties of Y2O3:Eu3+nanocrystals,Journal of Crystal Growth,2009,311,580-584
[20]K.M. Nissamudeen, S.Sankar, A.H. Bahna, K.G.Gopchandran, Studies on the influence of lithiumin corporationin the photoluminescence of Y2O3:Eu3+thin films,Journal of Physics and Chemistry of Solid,2009,70,821-826
[21]Shrout TR and Halliyal A.Preparation of Lead-based ferroelectric relaxors for capacitors.[J]American Ceramic Society of Bulletin,1987,66:704-711.
[22]PARK C Heol-hee, PARK So-jung, YU Byung-yong, et al. UV xcitation of Y3Al5O12:Tb phosphor prepared by a sol-gel process [J].Mater Sci Lett,2000, 9(2):335-338.
[1].M.I.Martinez-Rubio,T.G.Ireland,G.R.Fern,J.Silver,M.J.Snowden, A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir.17(2001)7145.
[2].S.H.Chao,S.H.Kwon,J.S.Yoo,C.W.Oh,J.D.Lee,K. J.Hong,S.J.Kwon,J. Electrochem. Soc.147(2000)3143.
[3]P.N.Prasad, Nanophotonics, John Wiley&Sons, NY,2004.
[4]F.Wang, W.B.Tan, Y.Zhang, X. Fan, M.Wang, Luminescent nanomaterials for biological labelling,Nanotechnology.17 (2006) R1.
[5]Q.Lu, A. Li, F.Y.Guo,L. Sun, L.C.Zhao, Experimental study on the surface modification of Y2O3:Tm3+/Yb3+nanoparticles to enhance upconversion fluorescence and weaken aggregation, Nanotechnology.19 (2008)145701.
[6]K.L. Frindell, M.H. Bartl,A. Popitsch, G.D.Stucky, Sensitized Luminescence of Trivalent Europium by Three-Dimensionally Arranged Anatase Nanocrystals in Mesostructured Titania Thin Films,Angew Chem. Int. Ed.41(2002)960.
[7]G.Wakefied,E.Holland,P.J.Dobson,T.L. Hutchison,Adv Mater.13(2001)1 557-60.
[8]J.H.Gwak, S.H.Park, J.E.Jang, S.J.Lee, J.E.Jung, J.M.Kim, High resolution phosphor screening method for full-color field emission display applications, J Vac Sci TechnolB.18(2000)1101-5.
[9]J.CPark, H.K.Moon, D. K.Kim, S.H.Byeon, B.C.Kim and K.S.Suh,Morphology and cathodoluminescence of Li-doped GdO:Eu, a red phosphor...Appl Phys. Lett.77(2000)2162.
[10]Y.C.Kang, S.B.Park, I.W.Lenggoroand, K.Okuyama,Gd2O3:Eu phosphor particles with sphericity, submicron size and non-aggregation characteristics,J. Phys. Chem. Solids.60(1999)379.
[11]B.Mercier, C.Dujardin, G.Ledoux, C.Louis and O.Tillement, Observation of the gap blueshift on GdO:Eu nanoparticles,J. Appl. Phys.96(2004)650.
[12]M.I. Martinez-Rubio,T. G. Ireland,G.R. Fern, J.Silver and M.J.Snowden, A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir,2001,17,7145.
[13]M.Yin, W.Zhang, S.Xia and J.-C.Krupa, Luminescence of nanometric scale
Y2SiO5:Eu3+,J. Lumin.,1996,68,335.
[14]Y. H.Zhou and J.Lin, Preparation of Y3Al5O12:Eu phosphors by citric-gel method and their luminescent...Opt.Mater.,2002,27,1426.
[15]X. Zeng, G.Zhao, J. Xu, H. Li, X. He, H.Pang and M.Jie, Thermal conductivity and refractive indices of Nd:GdVO4 crystals,J.Cryst.Growth, 2005,274,495.
[16]G. Panayiotakis, D.Cavouras, I.Kandarakis and C.Nomicos,A study of X-ray luminescence and spectral compatibility of europium-activated yttrium-vanadate (YVO4:Eu) screens Appl. Phys. A,1996,62,483.
[17]K. Y.Jung and H.W.Lee, Enhanced luminescent properties of Y3Al5O12:Tb3+,Ce3+phosphor prepared by spray pyrolysis,J. Lumin.,2007, 126,469
[18]L. Li, W.Jiang, H. Pan, X. Xu, Y.Tang, J.Ming, Z. Xu and R. Tang, J. Phys.Chem. C,2007,111,4111.
[19]J. Qiu, K. Miura, H. Inouye, Y. Kondo, T. Mitsuyu and K. Hirao, Femtosecond laser-induced three-dimensional bright and long-lasting...,Appl. Phys. Lett., 1998,73,1763.
[20]B.Moine and G. Bizarri, Rare-earth doped phosphors:oldies or goldies, Mater. Sci. Eng.,B,2003,105,2.
[21]C.R. Ronda, T.Ju" stel and H.Nikol, Rare earth phosphors:fundamentals and applications,J. Alloys Compd,1998,275-277,669.
[22]E. J.Bosze, J. Carver, S.Singson, J.McKittrick and G. A. Hirata, Long-Ultraviolet-Excited White-Light Emission in Rare-Earth-Activated Yttrium-Oxyorthosilicate,J. Am. Ceram. Soc,2007,90,2484.
[23]C. Feldmann,T. Ju" stel,C. R. Ronda and P. J. Schmidt,Adv. Funct. Mater.,2003,13,511.
[1].Chao, S.H.;Kwon, S.H.;Yoo, J.S.;Oh, C.W.;Lee,J.D.;Hong,K. J.;Kwon, S. J. J. Electrochem. Soc. (2000),147,3143.
[2].Martinez-Rubio,M.I.;Ireland,T.G.;Fern,G.R.;Silver,J.;Snowden,M.J.A New Application for Microgels:Novel Method for the Synthesis of Spherical Particles of the Y2O3:Eu Phosphor Using a Copolymer Microgel of NIPAM and Acrylic Acid, Langmuir,2001,17,7145.
[3]C.N.R.Rao, Mater. Sci. Enging.B,18(1993)1.
[4]C.D. Veitch, Synthesis of polycrystalline yttrium iron garnet and yttrium aluminium garnet from organic precursors,J. Mater. Sci.26(1991)6527.
[5]Y.C. Kang, H,S.Roh. S.B.Park, Preparation of Y2O3:Eu Phosphor Particles of Filled Morphology at High Precursor Concentrations by Spray Pyrolysis,Adv.Mater.12 (2000) 451.
[6]D.K. Wilams, B.M.Tissue, Preparation and Fluorescence Spectroscopy of Bulk Monoclinic Eu3+:Y2O3 and Comparison to Eu3+:Y2O3 Nanocrystals, J.Phys.Chem.B 102(1998)916
[7]Y. Tao, G. W. Zhao, W.P.Zhang,S.D.Xia, Mater.Res.Bull.32(1997) 501
[8]L.D. Sun, J. Yao, C.H. Liu, C.S.Liao, C.H.Yan, Rare earth activated nanosized oxide phosphors:synthesis and optical properties, J. Lumin.87—89(2000)447
[9]Jun Yang, Zewei Quan, Deyan Kong, Xiaoming Liu, Jun Lin,Size-tailored synthesis and luminescent properties of one-dimensional Gd2O3:...,Crystal Growth and Design,(2007)7,730--735
[10]R. Debnath,A. Nayak, A. Ghosh. On the enhancement of luminescence efficiency of Y2O3:Eu3+red phosphor by incorporating (Al3+, B3+) in the host lattice,Chemical Physics Letters,444(2007)324-327
[11]A.S.Gouveia-Neto, E.B.da Costa, P.V.dos Santos,L.A.Bueno, S.J.L. Ribeiro, Twentyfold blue upconversion emission enhancement through thermal effects in Pr3+/Yb3+-codoped fluoroindate glasses excited at 1.064 μm, J. Appl. Phys.94, 5678 (2003)
[12]J.H.Jeong, J.S.Bae, S.S.Yi, J.C.Park, Y.S.Kim,Photoluminescence characteristics of Li-doped Y2O3:Eu3+thin-film phosphors on sapphire substrates,J. Phys.:Condens. Matter 15,567(2003)
[13]J.H. Jeong, B.K. Moon, H.J.Seo, J.S.Bae, S.S.Yi, I.W.Kim, H.L. Park, Improved photoluminescence of pulsed-laser-ablated Y2O3:Eu3+thin-film phosphors by Gd substitution,Appl Phys. Lett.83,1346 (2003)
[14]M.G. Ko, J.C.Park, D.K. Kim, S.H.Byeon,Low-voltage cathodoluminescence property of Li-doped Gd2-xYxO3:Eu3+,J. Luminesc.104,215(2003)
[15].J.H.Jeong, B.K. Moon, H.J.Seo, J.S.Bae, S.S.Yi,I.W.Kim, H.L. Park,Scaling behavior of ferroelectric hysteresis loop in pulsed-laser-deposited SrBiTaO. Appl. Phys. Lett.83,1346(2003)
[16]M.G.Ko, J.C.Park, D.K. Kim, S.H. Byeon,Low-voltage cathodoluminescence property of Li-doped Gd2-xYxO3:Eu3+,J. Luminesc.104,215(2003)
[17]Xia Li, Qiang Li,Zhiguo Xia, Lin Wang, Wenxun Yan, Jiyang Wang, and R.I. Boughton, Growth and Characterization of Single-Crystal Y2O3:Eu Nanobelts Prepared with a Simple Technique, Crystal Growth& Design,2006, 6,2193
[18].B.D.Cullity, S.R. Stock (2001)Elements of X-ray Diffraction.
[19].Wang, Z. L. Self-Assembly of Gold Nanorods,J. Phys. Chem. B,2000,104, 1153.
[20].(a)Silver, J.;Martunez, M.I.;Ireland, T. G.;Withnall, R.J.J.Phys.Chem. B 2001,105,7200. (b) Maitric,M.;Antic,B.;Balanda, M.;Rodic, D.;Napijalo, M. L. J. Phys.:Condens. Matter 1997,9,4103.
[21].E.J. Bosze, G.A. Hirata, L.E.Shea-Rohwer, J. McKittrick,Improving the efficiency of a blue-emitting phosphor by an energy transfer from Gd3+to Ce3+
,J. Luminesc.104,47 (2003)
[22].Z.P. Ai,Hugely enhanced electroluminescence from mesoporous ZnO particles, Opt. Mater.24,589 (2003)
[23].W.W.Zhang, W.P.Zhang, P.B.Xie, M.Yin, H.T.Chen, L. Jing, Y.S.Zhang, L.R. Lou, S.D.Xia,Optical properties of nanocrystalline Y2O3:Eu depending on its odd structure,J. Colloid Interface Sci.262,588 (2003)
[24].M.K.CHONG,K. PITA,C.H.KAM,Photoluminescence of sol-gel derived Y2O3:Eu3+thin-film phosphors with Mg2+and Al3+co-doping, Appl Phys. A 2004,79,433