GF/VE复合材料在去离子水和硫酸溶液中的腐蚀行为研究
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摘要
玻璃纤维增强乙烯基酯树脂(GF/VE)复合材料因其优良的力学和耐腐蚀性能,常作为化学容器等较高耐腐蚀性要求的壳体材料使用。但是在实际应用中由于各种复杂的环境因素(湿度、温度、化学介质等)的协同作用,复合材料的树脂基体、增强纤维和界面会受到不同程度的腐蚀,对复合材料的力学性能产生很大的影响,从而影响其使用寿命。因此,模拟GF/VE复合材料的实际使用环境研究其腐蚀行为,对选取性能优异的壳体材料及其使用寿命的预测具有非常重要的指导意义。
本文选择两种玻璃纤维增强乙烯基酯树脂复合材料(GF/VEA和GF/VEB)及其树脂基体(VEA和VEB),对比研究其静态和动态力学性能及其在55℃、40wt%硫酸水溶液中的变化以及吸湿特性,并用SEM和FTIR分析其微观结构和组成变化,研究界面粘结对两种复合材料在硫酸介质中腐蚀行为的影响。进而选择界面粘结性能和耐蚀性能较好的GF/VEB复合材料,对其在去离子水和硫酸介质中的腐蚀行为进行比较,并采用材料强度预测模型对GF/VEB复合材料进行弯曲强度的寿命预测。
静态和动态力学性能测试结果表明,复合材料GF/VEB较GF/VEA具有更好的界面粘结性能。通过对相同的浸泡时间内两种复合材料及其树脂浇注体在硫酸介质中的质量变化率比较和红外分析表明,VEA和VEB两种树脂在硫酸溶液中的耐蚀性能相似,从而GF/VEA和GF/VEB复合材料耐酸蚀性能的差异主要取决于界面粘结的不同。
通过动态力学性能、剪切性能和弯曲性能的研究表明,纤维与树脂界面粘结情况越好,复合材料的性能保留率越高。从而复合材料GF/VEB的耐酸性能优于复合材料GF/VEA。因此,两者相比,复合材料GF/VEB更适合作为防腐容器壳体材料使用。
通过对GF/VEB复合材料在去离子水和硫酸溶液中的腐蚀行为比较表明,在去离子水中,GF/VEB复合材料的腐蚀主要因吸湿塑化和轻微的界面脱粘导致弯曲强度轻微下降,而弯曲模量几乎不变；而在硫酸介质中,除了吸湿塑化还因树脂基体的水解脆化和玻璃纤维的裂纹化,导致更严重的界面脱粘破坏,从而弯曲强度和弯曲模量均有明显的降低。
采用材料强度预测模型对GF/VEB复合材料进行弯曲强度预测,预测值与试验值拟合较好,并根据材料的弯曲强度对GF/VEB复合材in料的使用寿命进行预测,结果表明GF/VE复合材料在硫酸溶液中的使用寿命比其去离子水中的使用寿命短约16倍。
Glass fiber reinforced vinylester composites (GF/VE) have been used as shell materials for chemical containers due to superior mechanical properties and good corrosion resistance. However, in practical applications, these composites may take degradation in mechanical properties owing to the corrosion of the matrix, glass fiber and interface of the composites by the synergy of complicated environmental factors (humidity, temperature, medium, et al), resulting in the deterioration in service performance and long-term durability. Therefore, it is necessary to study the corrosion behavior of the GF/VE composites by simulating actual service environment for the purpose to select suitable shell materials for chemical containers.
In this study, the moisture absorption, static and dynamic mechanical properties of two kinds of glass fiber reinforced vinylester resin composites (GF/VEA and GF/VEB) and their resin casts (VEA and VEB) in 55℃,40wt% sulfuric acid solution were comparatively studied. The microstructure and componential change were also studied using SEM and FTIR analysis. The results show that the GF/VEB composite presents a better interfacial adhesion and thus shows higher corrosion resistance than the GF/VEB composite. So the GF/VEB composite is chosen as a more suitable shell material for anticorrosive containers, and has been taken further studies in this study.
In order to further investigate the corrosion mechanisms of the GF/VEB composite in sulfuric acid solution, we further comparatively investigated the corrosion behavior of the GF/VEB composite and VEB casts in distilled water and sulfuric acid solution. The results show that the flexural strength of GF/VEB composite in distilled water decline slightly and the flexural modulus is almost unchanged due to the plasticization resulting from moisture absorption and the slight interfacial de-bonding. While in sulfuric acid solution, both the flexural strength and the modulus of the GF/VE composite decrease clearly because of the more severe damages on the interface adhesion, which result from the brittleness and cracking of matrix, the cracking and/or breakage of glass fibers as well as the plasticization of the matrix.
The materials strength prediction model for polymer composite laminates was applied in this paper. The good consistency between the predicted and experimental values indicates that the model can be applied to predicate the residual strength and service lifetime of the GF/VE composite. The results show that the GF/VE composite in sulfuric acid solution presents almost 16 times shorter life time than in distilled water when the 50%of flexural strength retention is considered as the failure point.
本文选择两种玻璃纤维增强乙烯基酯树脂复合材料(GF/VEA和GF/VEB)及其树脂基体(VEA和VEB),对比研究其静态和动态力学性能及其在55℃、40wt%硫酸水溶液中的变化以及吸湿特性,并用SEM和FTIR分析其微观结构和组成变化,研究界面粘结对两种复合材料在硫酸介质中腐蚀行为的影响。进而选择界面粘结性能和耐蚀性能较好的GF/VEB复合材料,对其在去离子水和硫酸介质中的腐蚀行为进行比较,并采用材料强度预测模型对GF/VEB复合材料进行弯曲强度的寿命预测。
静态和动态力学性能测试结果表明,复合材料GF/VEB较GF/VEA具有更好的界面粘结性能。通过对相同的浸泡时间内两种复合材料及其树脂浇注体在硫酸介质中的质量变化率比较和红外分析表明,VEA和VEB两种树脂在硫酸溶液中的耐蚀性能相似,从而GF/VEA和GF/VEB复合材料耐酸蚀性能的差异主要取决于界面粘结的不同。
通过动态力学性能、剪切性能和弯曲性能的研究表明,纤维与树脂界面粘结情况越好,复合材料的性能保留率越高。从而复合材料GF/VEB的耐酸性能优于复合材料GF/VEA。因此,两者相比,复合材料GF/VEB更适合作为防腐容器壳体材料使用。
通过对GF/VEB复合材料在去离子水和硫酸溶液中的腐蚀行为比较表明,在去离子水中,GF/VEB复合材料的腐蚀主要因吸湿塑化和轻微的界面脱粘导致弯曲强度轻微下降,而弯曲模量几乎不变；而在硫酸介质中,除了吸湿塑化还因树脂基体的水解脆化和玻璃纤维的裂纹化,导致更严重的界面脱粘破坏,从而弯曲强度和弯曲模量均有明显的降低。
采用材料强度预测模型对GF/VEB复合材料进行弯曲强度预测,预测值与试验值拟合较好,并根据材料的弯曲强度对GF/VEB复合材in料的使用寿命进行预测,结果表明GF/VE复合材料在硫酸溶液中的使用寿命比其去离子水中的使用寿命短约16倍。
Glass fiber reinforced vinylester composites (GF/VE) have been used as shell materials for chemical containers due to superior mechanical properties and good corrosion resistance. However, in practical applications, these composites may take degradation in mechanical properties owing to the corrosion of the matrix, glass fiber and interface of the composites by the synergy of complicated environmental factors (humidity, temperature, medium, et al), resulting in the deterioration in service performance and long-term durability. Therefore, it is necessary to study the corrosion behavior of the GF/VE composites by simulating actual service environment for the purpose to select suitable shell materials for chemical containers.
In this study, the moisture absorption, static and dynamic mechanical properties of two kinds of glass fiber reinforced vinylester resin composites (GF/VEA and GF/VEB) and their resin casts (VEA and VEB) in 55℃,40wt% sulfuric acid solution were comparatively studied. The microstructure and componential change were also studied using SEM and FTIR analysis. The results show that the GF/VEB composite presents a better interfacial adhesion and thus shows higher corrosion resistance than the GF/VEB composite. So the GF/VEB composite is chosen as a more suitable shell material for anticorrosive containers, and has been taken further studies in this study.
In order to further investigate the corrosion mechanisms of the GF/VEB composite in sulfuric acid solution, we further comparatively investigated the corrosion behavior of the GF/VEB composite and VEB casts in distilled water and sulfuric acid solution. The results show that the flexural strength of GF/VEB composite in distilled water decline slightly and the flexural modulus is almost unchanged due to the plasticization resulting from moisture absorption and the slight interfacial de-bonding. While in sulfuric acid solution, both the flexural strength and the modulus of the GF/VE composite decrease clearly because of the more severe damages on the interface adhesion, which result from the brittleness and cracking of matrix, the cracking and/or breakage of glass fibers as well as the plasticization of the matrix.
The materials strength prediction model for polymer composite laminates was applied in this paper. The good consistency between the predicted and experimental values indicates that the model can be applied to predicate the residual strength and service lifetime of the GF/VE composite. The results show that the GF/VE composite in sulfuric acid solution presents almost 16 times shorter life time than in distilled water when the 50%of flexural strength retention is considered as the failure point.
引文
[1]郝志勇,李玲,吴福虎,等.耐腐蚀性乙烯基酯树脂的研究与应用[J].塑料制造,2007,7：94-98
[2]潘玉琴.玻璃钢复合材料基体树脂的发展现状[J].纤维复合材料,2006,5.4：55-59
[3]胡晓斌,马玉录,王正东,等RTM用乙烯基酯树脂的固化反应研究[J].玻璃钢复合材料,1996,2：17-20
[4]奏伟,张志谦,黄玉东,等.RTM成型复合材料界面及其改性的研究[J].高技术通讯,2002,2：66-68
[5]韩玮,陈南梁.玻璃钢复合材料发展综述[J].纺织导报,2000,6：43-45
[6]张纪元.大型醛酸蓄电池的结构[J].电池工业,1999,4(5)：189-191
[7]Somjai Kajorncheappunngam. The effects of environmental aging on the durability of glass/epoxy composites[R]. Virginia:College of Engineering and Mineral Resources at West Virginia University,1999
[8]Abeysinghe H. P., Edwards W., Pritchard G., et al. Degradation of crosslinked resins in water and electrolyte solutions [J]. Polymer,1982,23(11):1785-1790
[9]Lin Y.C., Chen Xu. Moisture sorption-desorption-resorption characteristics and its effect on the mechanical behavior of the epoxy system [J]. Polymer,2005,46(25):11994-12003
[10]Apicella A.,Tessieri R.,Cataldis C. Sorption modes of water in glassy epoxies[J]. Journal of Membrane Science,1985,18:211-225
[11]Li Rong Bao, Albert F. Yee, Charles Y. C. Lee. Moisture absorption and hygrothermal aging in a bismaleimide resin [J]. Polymer,2001,42(17):7327-7333
[12]周润培.环氧乙烯基酯树脂(Ⅱ)环氧乙烯基酯树脂在酸、碱、盐溶液中的稳定性[J].热固性树脂,2003,18(1)：40-42
[13]Adamson M. J. Thermal expansion and swelling of cured epoxy resin used in graphite/epoxy composite materials [J]. Journal of Material Science,1980,15(7):1736-1745
杨专钊,田伟,刘道新,等.碳纤维环氧复合材料的吸湿溶胀行为[J].腐蚀与防护,2008,29(5)：251-253
Bellenger V., Verdu J. Structure-properties relationships for densely cross-linked epoxide-amine systems based on epoxide or amine mixtures, part 2:water absorption and diffusion [J]. Journal of Material Science,1989,24(1):63-68
[16]DeNeve, Shanahan MER, Reynolds JD. Water absorption by an epoxy resin and its effect on the mechanical properties and infra-red spectra [J]. Polymer,1993,34(24):5099-5105
[17]Sonawala S. P., Spontak R. J. Degradation kinetics of glass-reinforced polyesters in chemical environments. Part Ⅰ:Aqueous solutions [J]. Journal of Materials Science,1996,31(18):4745-4756
[18]Joannie W. Chin, Khaled Aouadi, Michael. R. Haight, et al. Tinh Nguyen. Effects of water, salt solution and simulated concrete pore solution on the properties of composite matrix resins used in civil engineering applications [J]. Polymer Composites,2001,22 (2):282-297
[19]Y. Jack Weitsman. Effects of Fluids on Polymeric Composites—A Review [J].Comprehensive Composite Materials.2003,2(11):369-401
[20]Chateauminois A., Vincent L., Chabert B., et al. Study of the interfacial degradation of a glass-epoxy composite during hygrothermal aging using water diffusion measurements and dynamic
mechanical thermal analysis [J]. Polymer,1994,35(22):4766-4799
[21]Chaplin A, Hamerton I., Herman H., et al. Studying water uptake effects in resins based on cyanate ester/bismaleimide blends [J]. Polymer,2000,41(11):3945-3956
[22]Li Rong Bao, Albert F. Yee. Effect of temperature on moisture absorption in a bismaleimide resin and its carbon fiber composites [J]. Polymer,2002,43(14):3987-3997
[23]Netravali A. N., Fornes R. E., Gilbert R. D., et al. Effects of water sorption at different temperatures on permanent changes in an epoxy [J]. Journal of Applied Polymer Science,1985, 30(4):1573-1578
[24]Morgan. R J, O'neal J. E., Fanter D. I.. The effect of moisture on the physical and mechanical integrity of epoxies [J]. Journal of Material Science,1980,15(3):751-764
[25]Yunhua Yu, Peng Li, Gang Sui, et al. Effects of Hygrothermal Aging on the Thermal Mechanical Properties of Vinylester Resin and its Pultruded Carbon Fiber Composites [J]. Polymer Composites,2009,30(10):1458-1464
[26]Zheng Q., Morgan R. J. Synergistic thermal-moisture damage mechanisms of epoxy and their carbon fiber composites [J]. Journal of Composite Materials,1993,27 (15):1465-1478
[27]Hiltz J. A., Keough I. A. A study of the effect of absorbed water on the Tg of a poly(amideimide) using DMA and DSC[J]. Thermochimica Acta,1992,212:151-162
[28]McKague E. L., Reynolds J. D., Jr., Halkias J. E.. Swelling and glass transition relations for epoxy matrix material in humid environments [J]. Journal of Applied Polymer Science,1978, 22(6):1643-1655
[29]Apicella A., Migliaresi C., Nicodemo L., et al. Water sorption and mechanical properties of a glass-reinforced polyester resin [J]. Composites,1982,13(4):406-410
[30]Thomson K. W., Wong T., Broutman L. J. The plasticization of an epoxy resin by dibutylphthalate and water[J]. Polymer Engineering Science,1984,24(16):1270-1276
[31]Jiming Zhou, James P. Lucas. Hygrothermal effects of epoxy resin, part Ⅱ:variations of glass transition temperature [J]. Polymer,1999,40(20):5513-5522
[32]王天堂,陆士平.双酚A型环氧乙烯基酯树脂及层合板的耐碱性比较[J].化工设备与管道,2002,39(1)：47-50
[33]Morii T., Tanimoto T., Hamada H.,et al. Fracture and acoustic emission characteristics of glass fiber reinforced plastics panels for hot water [J]. Polymer Composites,1994,15(3):206-216
[34]齐双春,470乙烯基酯树脂耐H2SO4腐蚀性能的研究.河北化工,2009,32(12)：15-17
[35]齐双春,赵英强,曾严.470乙烯基酯树脂耐NaOH腐蚀性能研究[J].热固性树脂,2009,24(6)：38-40
[36]肖迎红,汪信,陆路德,等.玻纤增强热塑性聚醋复合材料湿热老化研究[J].工程塑料应用,2001,29(9)：35-37
[37]黄故,孙红霞.玻璃纤维增强复合材料在水环境中的性能[J].纺织学报,2007,28(3)：42-44
[38]刘建华,赵亮,李松梅,等.盐雾环境对玻璃纤维增强树脂基复合材料力学性能的影响[J].复合材料学报,2007,34,(3)：18-22
[39]董琳琳,黄故.海水环境下玻璃纤维／聚酯基复合材料的性能研究[J].天津工业大学学报,2007,26(7)：25-27
[40]詹茂盛,刘德顺.单向玻纤增强BMI复合材料的酸雨和温热老化行为[J].合成材料老化与应用,2007,36(1)：8-16
[41]张凯,马艳,杨世全,卢永刚.碳纤维复合材料的耐腐蚀性能[J].化学推进剂与高分子材料,2009,7(4)：1-5
[42]Y.J. Weitsman, M. Elahi, Effects of Fluids on the Deformation, Strength and Durability of Polymeric Composites-An Overview [J]. Mechanics of Time-Dependent Materials,2000,4: 107-126
[43]Wellington Chu, Lixin Wu, Vistasp M. Karbhari, Comparative Degradation of Pultruded E-Glass/Vinylester in Deionized Water, Alkaline Solution, and Concrete Leachate Solution[J]. Journal of Applied Polymer Science,2006.99:1405-1414
[44]Tsotsis T. K., Lee S. M. Long-term durability of carbon-and glass-epoxy composite materials in wet environments [J]. Proceding of the American Society for Composites,1996:613-624
[45]A. Kootsookos, A.P. Mouritz,Seawater durability of glass-and carbon-polymer composites[J].Composites Science and Technology,2004,64:11503-1511
[46]Salar Bagherpour, Roholah Bagheri, Ahmad Saatchi. Effects of concentrated HC1 on the mechanical properties of storage aged fiber glass polyester composite [J]. Materials and Design, 2009,30:271-277
[47]栗晓飞,张琦,项民.浸泡腐蚀对复合材料导电性能和力学性能的影响[J].材料工程.2009,2：1-5
[48]A.Bergeret,L Ferry, P. Lenny. Influence of the fiber/matrix interface on aging mechanisms of glass fiber reinforced thermoplastic composites (PA-6,6,PET,PBT) in a hydrothermal environment[J].Polymer Degradation and Stability,2009,94(9):1315-1324
[49]Zhang Jihua, Zhan Maosheng.Visual experiments for water absorbing process of fibre-reinforced composites [J]. Journal of Composite Materials,2004,38(6):779-790
[50]Hodzic A, Kim J K, l_owe A E, et al. The effect of water aging on the interphase region and fracture toughless in polymer/glass composites [J]. Composites Science and technology,2004,64( 2195
[51]Stephanie Mallarineo, Jean-Francois Chailan, Jean-Louis Vernet. Interphase study in cyanate/glass fiber composites using thermomechannical analysis and micro-thermal analysis[J]. Composites Science and Technology,2009,69:28-32
[52]Ping Seng Chua, Dynamic mechanical analysis studies of the interphase[J]. Polymer Composites,2004,8(5):308-313
[53]肖文萍,许俊华,朱怡超.腐蚀环境因子对环氧树脂基复合材料性能影响研究[J].装备环境工程,2008,5(6)：76-81
[54]茆诗松,王玲玲,加速寿命试验[M].北京：科学出版社,2000：25-28
[55]Mathew Celina, Kenneth T. Gillen, R.A. Assink. Accelerated aging and lifetime prediction: Review of non-Arrhenius behaviour due to two competing processes [J]. Polymer Degradation and Stability.2005,90:395-404
[56]Kenneth T. Gillen, Robert Bernstein, Dora K. Derzon, Evidence of non-Arrhenius behaviour from laboratory aging and 24-year field aging of polychloroprene rubber materials[J].Polymer Degradation and Stability,2005,87:57-67
[57]Kenneth T. Gillen, Mathew Celina, Clough RL, et al. Extrapolation of accelerated aging data e Arrhenius or erroneous?[J]. Trends Polym Sci,1997;5:250
[58]V.N.Bulmanis,G.M.Gunyaev,V.V.Krivonos,RISA.SPAVIAM[D],Moscow, USSR,1991
[59]叶宏军,詹美珍,Г.М.古尼耶夫,等.T300／4211复合材料的使用寿命评估[J],材料工程,1995,10：3-5
[60]肇研,梁朝虎.聚合物基复合材料自然老化寿命预测方法[J].航空材料学报,2001,21,2：55-58
[61]张纪元.国外潜艇蓄电池概况[J].蓄电池,1994,24(4)：195-198
[62]刘观政,李地红,黄力刚,等.玻璃钢在盐雾环境中腐蚀机制和性能演变规律的试验研究[J].玻璃钢／复合材料,2008,1：35-40
[63]严艳,于运花,杨小平.玻纤增强乙烯基酯树脂复合材料在硫酸水溶液中的腐蚀速率研究[J].玻璃钢／复合材料,2008,5：23-2
[64]陈伟明,王成忠,周同悦,等.T800碳纤维复合材料界面吸湿性能分析[J].玻璃钢／复合材料,2006,5：20-24
[65]A. R. Maligno, N. A. Warrior, A. C. Long. Effects of interphase material properties in unidirectional fibre reinforced composites [J]. Composites Science and Technology,2010,70(1):36-44.
[66]L. Gautier, B. Mortaigne, V. Bellenger. Interface damage study of hydrothermally aged glass fiber-reinforced polyester composites [J]. Composites Science and Technology,999,59(16):2329-2337
[67]V. M. Karbharil. E-Glass/Vinylester Composites in Aqueous Environments:Effects on Short-Beam Shear Strength [J]. Journal of Composites for Construction,2004,8(2):148-156
[68]Kubat J, Rigdahl M, Welander M. haracterization of interfacial interactions in high density polyethy-lene filled with ass spheres using dynamic-mecha-nical analysis[J]. Journal of Applied Polymer Science,1990,39(7):1527-1534
[69]Ashida Miehio, Noguchi Tom, Mashimo Satoshi.Dynamic moduli for short fiber-CR composites[J], Journal of Applied Polymer Science,1985,30(3):1011-1021
[70]于运花,曾炜,李默宇,等.碳纤维缠绕复合材料NOL环的吸湿过程与性能的关系[J].复合材料学报,2009,26(2)：72-78
[71]Boinard E, Pethrick RA, Dalzel-Job J, et al. Influence of resin chemistry on water uptake and environmental ageing in glass fibre reinforced composites-polyester and vinyl ester laminates [J]. Journal of Materials Science,2000,35(8):1931-1937
[72]周同悦,于运花,陈伟明,等.乙烯基酯树脂及其炭纤维复合材料的湿热老化行为[J].高分子材料科学与工程,2006,22(5)：166-170
[73]E. P. GelE. P. Gellert, D. M. Turleyl. Seawater immersion ageing of glass-fibre reinforced polymer laminates for marine applications [J]. Composites:Part A,1999,30(11):1259-1265
[74]Lixin Wu, Karen Murphy, Vistasp M. Arbhari,et al. Short-Term Effects of Sea Water on E-glass/Vinylester Composites[J].Journal of Applied Polymer Science,2002,84(14):2760-2767.
Wellington Chu, Lixin Wu, Vistasp M. Karbhari, Durability evaluation of moderate temperature cured E-glass/vinylester systems [J]. Composite Structure,2004,66(1-4):367-376
[76]H.L. Luo, J.J. Lian, Y.Z. Wan, et al. Carbon-epoxy composite with different interface condition[J].Materials science and engineering:,2006,425(1-2):70-77
[77]Somjai Kajomcheappunngam, The effects of environmental aging on the durability of glass/epoxy composites [D].Virginia:College of Engineering and mineral resources at west virginia university,1999
[78]Karbhari VM, Dynamic mechanical anyalysis of water on E-glass vinylester composites.Journal reinforced plastic composite [J],2006,25(6):631-644
[79]Pascault JP, Sautereau H, Verdu J, et al. Thermosetting polymers[M].Marcel Dekker,2002
[80]Guijun Xian, Vistasp M. Karbhari.Segmental relaxation of water-agede ambient cured epoxy [J],Polymer degradation and stability,2007,92(9):1650-1659
[81]S.R.Patel,S.W.Case, Durability of hygrothermally aged graphite/epoxy woven composite under combined hygrothermal conditions [J].International journal of fatigue,2002,24:5717-5725
[2]潘玉琴.玻璃钢复合材料基体树脂的发展现状[J].纤维复合材料,2006,5.4：55-59
[3]胡晓斌,马玉录,王正东,等RTM用乙烯基酯树脂的固化反应研究[J].玻璃钢复合材料,1996,2：17-20
[4]奏伟,张志谦,黄玉东,等.RTM成型复合材料界面及其改性的研究[J].高技术通讯,2002,2：66-68
[5]韩玮,陈南梁.玻璃钢复合材料发展综述[J].纺织导报,2000,6：43-45
[6]张纪元.大型醛酸蓄电池的结构[J].电池工业,1999,4(5)：189-191
[7]Somjai Kajorncheappunngam. The effects of environmental aging on the durability of glass/epoxy composites[R]. Virginia:College of Engineering and Mineral Resources at West Virginia University,1999
[8]Abeysinghe H. P., Edwards W., Pritchard G., et al. Degradation of crosslinked resins in water and electrolyte solutions [J]. Polymer,1982,23(11):1785-1790
[9]Lin Y.C., Chen Xu. Moisture sorption-desorption-resorption characteristics and its effect on the mechanical behavior of the epoxy system [J]. Polymer,2005,46(25):11994-12003
[10]Apicella A.,Tessieri R.,Cataldis C. Sorption modes of water in glassy epoxies[J]. Journal of Membrane Science,1985,18:211-225
[11]Li Rong Bao, Albert F. Yee, Charles Y. C. Lee. Moisture absorption and hygrothermal aging in a bismaleimide resin [J]. Polymer,2001,42(17):7327-7333
[12]周润培.环氧乙烯基酯树脂(Ⅱ)环氧乙烯基酯树脂在酸、碱、盐溶液中的稳定性[J].热固性树脂,2003,18(1)：40-42
[13]Adamson M. J. Thermal expansion and swelling of cured epoxy resin used in graphite/epoxy composite materials [J]. Journal of Material Science,1980,15(7):1736-1745
杨专钊,田伟,刘道新,等.碳纤维环氧复合材料的吸湿溶胀行为[J].腐蚀与防护,2008,29(5)：251-253
Bellenger V., Verdu J. Structure-properties relationships for densely cross-linked epoxide-amine systems based on epoxide or amine mixtures, part 2:water absorption and diffusion [J]. Journal of Material Science,1989,24(1):63-68
[16]DeNeve, Shanahan MER, Reynolds JD. Water absorption by an epoxy resin and its effect on the mechanical properties and infra-red spectra [J]. Polymer,1993,34(24):5099-5105
[17]Sonawala S. P., Spontak R. J. Degradation kinetics of glass-reinforced polyesters in chemical environments. Part Ⅰ:Aqueous solutions [J]. Journal of Materials Science,1996,31(18):4745-4756
[18]Joannie W. Chin, Khaled Aouadi, Michael. R. Haight, et al. Tinh Nguyen. Effects of water, salt solution and simulated concrete pore solution on the properties of composite matrix resins used in civil engineering applications [J]. Polymer Composites,2001,22 (2):282-297
[19]Y. Jack Weitsman. Effects of Fluids on Polymeric Composites—A Review [J].Comprehensive Composite Materials.2003,2(11):369-401
[20]Chateauminois A., Vincent L., Chabert B., et al. Study of the interfacial degradation of a glass-epoxy composite during hygrothermal aging using water diffusion measurements and dynamic
mechanical thermal analysis [J]. Polymer,1994,35(22):4766-4799
[21]Chaplin A, Hamerton I., Herman H., et al. Studying water uptake effects in resins based on cyanate ester/bismaleimide blends [J]. Polymer,2000,41(11):3945-3956
[22]Li Rong Bao, Albert F. Yee. Effect of temperature on moisture absorption in a bismaleimide resin and its carbon fiber composites [J]. Polymer,2002,43(14):3987-3997
[23]Netravali A. N., Fornes R. E., Gilbert R. D., et al. Effects of water sorption at different temperatures on permanent changes in an epoxy [J]. Journal of Applied Polymer Science,1985, 30(4):1573-1578
[24]Morgan. R J, O'neal J. E., Fanter D. I.. The effect of moisture on the physical and mechanical integrity of epoxies [J]. Journal of Material Science,1980,15(3):751-764
[25]Yunhua Yu, Peng Li, Gang Sui, et al. Effects of Hygrothermal Aging on the Thermal Mechanical Properties of Vinylester Resin and its Pultruded Carbon Fiber Composites [J]. Polymer Composites,2009,30(10):1458-1464
[26]Zheng Q., Morgan R. J. Synergistic thermal-moisture damage mechanisms of epoxy and their carbon fiber composites [J]. Journal of Composite Materials,1993,27 (15):1465-1478
[27]Hiltz J. A., Keough I. A. A study of the effect of absorbed water on the Tg of a poly(amideimide) using DMA and DSC[J]. Thermochimica Acta,1992,212:151-162
[28]McKague E. L., Reynolds J. D., Jr., Halkias J. E.. Swelling and glass transition relations for epoxy matrix material in humid environments [J]. Journal of Applied Polymer Science,1978, 22(6):1643-1655
[29]Apicella A., Migliaresi C., Nicodemo L., et al. Water sorption and mechanical properties of a glass-reinforced polyester resin [J]. Composites,1982,13(4):406-410
[30]Thomson K. W., Wong T., Broutman L. J. The plasticization of an epoxy resin by dibutylphthalate and water[J]. Polymer Engineering Science,1984,24(16):1270-1276
[31]Jiming Zhou, James P. Lucas. Hygrothermal effects of epoxy resin, part Ⅱ:variations of glass transition temperature [J]. Polymer,1999,40(20):5513-5522
[32]王天堂,陆士平.双酚A型环氧乙烯基酯树脂及层合板的耐碱性比较[J].化工设备与管道,2002,39(1)：47-50
[33]Morii T., Tanimoto T., Hamada H.,et al. Fracture and acoustic emission characteristics of glass fiber reinforced plastics panels for hot water [J]. Polymer Composites,1994,15(3):206-216
[34]齐双春,470乙烯基酯树脂耐H2SO4腐蚀性能的研究.河北化工,2009,32(12)：15-17
[35]齐双春,赵英强,曾严.470乙烯基酯树脂耐NaOH腐蚀性能研究[J].热固性树脂,2009,24(6)：38-40
[36]肖迎红,汪信,陆路德,等.玻纤增强热塑性聚醋复合材料湿热老化研究[J].工程塑料应用,2001,29(9)：35-37
[37]黄故,孙红霞.玻璃纤维增强复合材料在水环境中的性能[J].纺织学报,2007,28(3)：42-44
[38]刘建华,赵亮,李松梅,等.盐雾环境对玻璃纤维增强树脂基复合材料力学性能的影响[J].复合材料学报,2007,34,(3)：18-22
[39]董琳琳,黄故.海水环境下玻璃纤维／聚酯基复合材料的性能研究[J].天津工业大学学报,2007,26(7)：25-27
[40]詹茂盛,刘德顺.单向玻纤增强BMI复合材料的酸雨和温热老化行为[J].合成材料老化与应用,2007,36(1)：8-16
[41]张凯,马艳,杨世全,卢永刚.碳纤维复合材料的耐腐蚀性能[J].化学推进剂与高分子材料,2009,7(4)：1-5
[42]Y.J. Weitsman, M. Elahi, Effects of Fluids on the Deformation, Strength and Durability of Polymeric Composites-An Overview [J]. Mechanics of Time-Dependent Materials,2000,4: 107-126
[43]Wellington Chu, Lixin Wu, Vistasp M. Karbhari, Comparative Degradation of Pultruded E-Glass/Vinylester in Deionized Water, Alkaline Solution, and Concrete Leachate Solution[J]. Journal of Applied Polymer Science,2006.99:1405-1414
[44]Tsotsis T. K., Lee S. M. Long-term durability of carbon-and glass-epoxy composite materials in wet environments [J]. Proceding of the American Society for Composites,1996:613-624
[45]A. Kootsookos, A.P. Mouritz,Seawater durability of glass-and carbon-polymer composites[J].Composites Science and Technology,2004,64:11503-1511
[46]Salar Bagherpour, Roholah Bagheri, Ahmad Saatchi. Effects of concentrated HC1 on the mechanical properties of storage aged fiber glass polyester composite [J]. Materials and Design, 2009,30:271-277
[47]栗晓飞,张琦,项民.浸泡腐蚀对复合材料导电性能和力学性能的影响[J].材料工程.2009,2：1-5
[48]A.Bergeret,L Ferry, P. Lenny. Influence of the fiber/matrix interface on aging mechanisms of glass fiber reinforced thermoplastic composites (PA-6,6,PET,PBT) in a hydrothermal environment[J].Polymer Degradation and Stability,2009,94(9):1315-1324
[49]Zhang Jihua, Zhan Maosheng.Visual experiments for water absorbing process of fibre-reinforced composites [J]. Journal of Composite Materials,2004,38(6):779-790
[50]Hodzic A, Kim J K, l_owe A E, et al. The effect of water aging on the interphase region and fracture toughless in polymer/glass composites [J]. Composites Science and technology,2004,64( 2195
[51]Stephanie Mallarineo, Jean-Francois Chailan, Jean-Louis Vernet. Interphase study in cyanate/glass fiber composites using thermomechannical analysis and micro-thermal analysis[J]. Composites Science and Technology,2009,69:28-32
[52]Ping Seng Chua, Dynamic mechanical analysis studies of the interphase[J]. Polymer Composites,2004,8(5):308-313
[53]肖文萍,许俊华,朱怡超.腐蚀环境因子对环氧树脂基复合材料性能影响研究[J].装备环境工程,2008,5(6)：76-81
[54]茆诗松,王玲玲,加速寿命试验[M].北京：科学出版社,2000：25-28
[55]Mathew Celina, Kenneth T. Gillen, R.A. Assink. Accelerated aging and lifetime prediction: Review of non-Arrhenius behaviour due to two competing processes [J]. Polymer Degradation and Stability.2005,90:395-404
[56]Kenneth T. Gillen, Robert Bernstein, Dora K. Derzon, Evidence of non-Arrhenius behaviour from laboratory aging and 24-year field aging of polychloroprene rubber materials[J].Polymer Degradation and Stability,2005,87:57-67
[57]Kenneth T. Gillen, Mathew Celina, Clough RL, et al. Extrapolation of accelerated aging data e Arrhenius or erroneous?[J]. Trends Polym Sci,1997;5:250
[58]V.N.Bulmanis,G.M.Gunyaev,V.V.Krivonos,RISA.SPAVIAM[D],Moscow, USSR,1991
[59]叶宏军,詹美珍,Г.М.古尼耶夫,等.T300／4211复合材料的使用寿命评估[J],材料工程,1995,10：3-5
[60]肇研,梁朝虎.聚合物基复合材料自然老化寿命预测方法[J].航空材料学报,2001,21,2：55-58
[61]张纪元.国外潜艇蓄电池概况[J].蓄电池,1994,24(4)：195-198
[62]刘观政,李地红,黄力刚,等.玻璃钢在盐雾环境中腐蚀机制和性能演变规律的试验研究[J].玻璃钢／复合材料,2008,1：35-40
[63]严艳,于运花,杨小平.玻纤增强乙烯基酯树脂复合材料在硫酸水溶液中的腐蚀速率研究[J].玻璃钢／复合材料,2008,5：23-2
[64]陈伟明,王成忠,周同悦,等.T800碳纤维复合材料界面吸湿性能分析[J].玻璃钢／复合材料,2006,5：20-24
[65]A. R. Maligno, N. A. Warrior, A. C. Long. Effects of interphase material properties in unidirectional fibre reinforced composites [J]. Composites Science and Technology,2010,70(1):36-44.
[66]L. Gautier, B. Mortaigne, V. Bellenger. Interface damage study of hydrothermally aged glass fiber-reinforced polyester composites [J]. Composites Science and Technology,999,59(16):2329-2337
[67]V. M. Karbharil. E-Glass/Vinylester Composites in Aqueous Environments:Effects on Short-Beam Shear Strength [J]. Journal of Composites for Construction,2004,8(2):148-156
[68]Kubat J, Rigdahl M, Welander M. haracterization of interfacial interactions in high density polyethy-lene filled with ass spheres using dynamic-mecha-nical analysis[J]. Journal of Applied Polymer Science,1990,39(7):1527-1534
[69]Ashida Miehio, Noguchi Tom, Mashimo Satoshi.Dynamic moduli for short fiber-CR composites[J], Journal of Applied Polymer Science,1985,30(3):1011-1021
[70]于运花,曾炜,李默宇,等.碳纤维缠绕复合材料NOL环的吸湿过程与性能的关系[J].复合材料学报,2009,26(2)：72-78
[71]Boinard E, Pethrick RA, Dalzel-Job J, et al. Influence of resin chemistry on water uptake and environmental ageing in glass fibre reinforced composites-polyester and vinyl ester laminates [J]. Journal of Materials Science,2000,35(8):1931-1937
[72]周同悦,于运花,陈伟明,等.乙烯基酯树脂及其炭纤维复合材料的湿热老化行为[J].高分子材料科学与工程,2006,22(5)：166-170
[73]E. P. GelE. P. Gellert, D. M. Turleyl. Seawater immersion ageing of glass-fibre reinforced polymer laminates for marine applications [J]. Composites:Part A,1999,30(11):1259-1265
[74]Lixin Wu, Karen Murphy, Vistasp M. Arbhari,et al. Short-Term Effects of Sea Water on E-glass/Vinylester Composites[J].Journal of Applied Polymer Science,2002,84(14):2760-2767.
Wellington Chu, Lixin Wu, Vistasp M. Karbhari, Durability evaluation of moderate temperature cured E-glass/vinylester systems [J]. Composite Structure,2004,66(1-4):367-376
[76]H.L. Luo, J.J. Lian, Y.Z. Wan, et al. Carbon-epoxy composite with different interface condition[J].Materials science and engineering:,2006,425(1-2):70-77
[77]Somjai Kajomcheappunngam, The effects of environmental aging on the durability of glass/epoxy composites [D].Virginia:College of Engineering and mineral resources at west virginia university,1999
[78]Karbhari VM, Dynamic mechanical anyalysis of water on E-glass vinylester composites.Journal reinforced plastic composite [J],2006,25(6):631-644
[79]Pascault JP, Sautereau H, Verdu J, et al. Thermosetting polymers[M].Marcel Dekker,2002
[80]Guijun Xian, Vistasp M. Karbhari.Segmental relaxation of water-agede ambient cured epoxy [J],Polymer degradation and stability,2007,92(9):1650-1659
[81]S.R.Patel,S.W.Case, Durability of hygrothermally aged graphite/epoxy woven composite under combined hygrothermal conditions [J].International journal of fatigue,2002,24:5717-5725