自组装单分子层的原位表面增强拉曼散射和拉曼映射分析
|
摘要
自组装单分子膜(Self-assembled monolayers, SAMs)技术经20多年的研究,在基础理论和应用上取得了突飞猛进的发展。倍受关注的SAMs体系主要有烷基硫醇类、有机硅烷类和脂肪酸及其衍生物。这些分子成膜条件易控,膜有序且取向性好、排列紧密而稳定,在生物化学、医学、传感器制备、纳米科学、金属缓蚀、材料科学等领域已有成功应用。
应该指出的是,SAMs技术仍处在方兴未艾阶段,目前需要解决的课题有:(一)发现更多的SAMs体系,尤其是具双功能或多功能位的成膜分子; (二)由于SAMs过程完全自发,膜结构取决于分子和基底以及分子间的作用方式,且受环境因素影响大,因此深刻了解SAMs构效关系,是拓展自组装技术应用的关键。由于自组装膜是分子在基底表面的单层吸附,这对分析技术的灵敏度有很高要求。常用的SAMs表征手段有电化学方法、X光电子能谱(XPS)、俄歇电子能谱(AES)、扫描隧道显微镜(STM)、原子力显微镜(AFM)、石英微天平(QCM)、接触角(Contacting angle)测定、傅立叶变换红外光谱(FTIR)、拉曼光谱(Raman spectroscopy)和表面增强拉曼散射(SERS)分析、椭圆偏振光谱(Ellipsometry)、二次谐波发生(SHG)、和频发生(SFG)、静态二次离子质谱(SSIMS)、高能或低能电子衍射(HEED或LEED )、X射线衍射(XD)、以及近边扩展X射线吸收精细结构(NEXAFS)。利用这些分析技术,人们对SAMs结构和成膜机理已有了一定的认识。然而,其中SHG、SSIMS、HEED、LEED、XPS和AES实验时需要高真空,条件苛刻; STM和AFM虽然能获得二维原子级图象信号,但缺乏分子选择性; FTIR和Raman技术能提供分子水平的信息,但尚未在二维尺度达到系统研究SAMs的层次,特别是对具多位点的成膜分子。
上世纪90年代以后,随着共焦显微激光拉曼技术的出现,使拉曼光谱分析的空间分辨率和仪器灵敏度大大提高。借助XY-自动扫描平台和Z轴自聚焦系统,可实现对表面的Raman mapping,获得的光谱包含分子空间二维分布的振动信息,在材料应力研究中已大显身手,但目前该技术在自组装单分子层研究领域的应用较少。本论文的重点是通过高空间分辨率的显微共焦和可达单分子水平检测灵敏度的SERS技术联用,进行Raman mapping实验,在不同介质中,观察包括辅酶NAD、巯基嘌呤和植酸化合物等具多吸附位点成膜分子,在金属基底上的自组装过程,并评价膜的二维有序性以及环境因子的影响程度。根据振动量化计算和SERS机制,解析SAMs膜结构。在此基础上,进行电化学和原位光谱电化学分析,考察膜的稳定性和构效关系。本论文具体内容如下:
(1)运用SERS mapping技术,分析了银电极表面形貌对NAD分子自组装机理的影响(第2章)。通过不同的处理方法,获得了两种银表面,经STM表征
Over the past two decades, self-assembled monolayers (SAMs) technique has witnessed tremendous growth in theory and application. The most attractive SAMs systems involve monolayers of fatty acids, of organosilicon derivatives and of alkanethiolates due to their controllably orderly uniformity with compact array, which provides versatile potentials to be employed in the fields of biologic chemistry, medicine, preparation of sensor, nano science, material science and inhibition of metal from corrosion, etc.
However, it should be pointed out that the developing pace of SAMs technique has been still on the way. Recently, some key issues are drawing increasing attentions as follows:
(1) Exploration of novel SAMs systems, in particular, the self-assembling molecules with dual or multiple adsorption sites;
(2) Investigation of the fundamental relationships between the monolayers structures and properties as a basic need to extend their further applications since the self-assembly process is completely spontaneous and adsorption mode dependent with interaction of molecules and subtract.
The self-assembled film at a monolayer level calls for the analytical methods with high sensitivity. The routine investigations of monolayers are conducted by using ellipsometry, contacting angle, electrochemistry, quartz crystal microbalance(QCM), infrared reflectance absorption spectroscopy (IRRAS), Raman spectroscopy, second harmonic generation(SHG), sum frequency generation(SFG), static second ion mass spectroscopy(SSIMS), X-ray photoelectron spectroscopy (XPS), high or low energy electron diffraction (HEED or LEED), X-Ray diffraction (XD) , near-edge extended X-ray adsorption fine structure (NEXAFS), scanning tunnel microscopy (STM), Auger electron spectroscopy(AES) and atomic force microscopy (AFM), etc. According to the above observations, insights into the self-assembling mechanism and film structure have been reached. However, some of aforementioned methods require high vacuum such as XPS, HEED or LEED and STM or AFM can provide image of monolayers in two dimensions, but the information is not for particular molecular species. Normal Raman spectroscopy and FTIR present molecular vibration information and are seldom used to study on the molecules with dual or multiple adsorption sites in two dimensions.
The advent of confocal laser Raman scattering analytical technique since
1990’s has enabled the spatial resolution and sensitivity of instrument to be increased. Aided with a XY stage strictly controlled by program and PC, Raman mapping has been extensively and successfully employed in analysis for stress distribution of material surface in two dimensions owing to its rich molecular vibration information. In present thesis, we wish to extend the Raman mapping technique together with the super sensitive surface enhanced Raman scattering method to examine the SAMs of molecules with multiple adsorption sites such as nicotinamide adenine dinucleotide (NAD), 6-mercaptopurine(6MP) and inositol hexphosphates (IP6), which are formed at various metallic surfaces under different media. Based on the obtained spectral information, the features of SAMs including the orderly uniformity and the impact factors from chemical environment have been explored. Furthermore, in light of the calculation results for vibrational spectra by quantum chemistry methods along with the SERS mechanism, the structure of the monolayers could be deduced. And also, the electrochemical and in situ spectroelectrochemical methods are used to observe the relationships of structure-properties and examine the stability of SAMs. The main contents of this thesis include following parts: (1) The mechanism of NAD monolayers self-assembled at the silver electrode as well as the effect of surface morphology on the process have been studied by the use of SERS mapping technique(Chapter 2). Two kinds of silver surfaces were obtained with the chemical and electrochemical methods and their average roughness degree are 40 ± 25 nm and 110 ± 50 nm as estimated from their STM image. At more even surface, formation of NAD SAMs was a much rapid process. In the case of a relatively rough silver surface, an intermediate state of adsorption of NAD molecules was found and the stable structure of NAD SAMs could be reached only after a long dynamic self-organized process. According to the SERS-based mechanism, NAD molecules should be vertically adsorbed at the silver surface to form the monolayers via N7 and NH2. The proposed orientation of NAD monolyers is in agreement with the result of minimized energy calculation of molecular configuration. (2) The impacts of potentials on the structure of NAD SAMs at the silver surface have been investigated by using in situ SERS electrochemical methods (Chapter 3). NAD molecule is composed of two 5`-nucleotide bases, AMP and nicotinamide ribose 5`-phosphate, which are linked together with a pyrophosphate bridge. The flexibility of this linkage provides a freedom to some extent for the adenine and nicotinamide moieties to change their conformation in dependence on
the chemical or physical micro-environment nearby the surface. However, question regarding the effect of the charged surface on the adsorption mode of NAD is still open. As the SAMs can provide a simple and good physical mode for understanding of interface phenomena, and the SERS signal is free from the interference of molecules in bulk solution. An NAD modified silver electrode was prepared. In situ SERS spectra indicate the change of NAD adsorption mode at the silver with the shift of potential and desorption of NAD monolayers from the surface occurring around the potential at -0.1 Vvs SCE. And the electrolyte in buffer solution might be a key influencing factor on the adsorption behavior of NAD at the silver surface. (3)This part is the first report and at molecular level investigating the relationship between the structure and properties of monolyers from phytic acid at the silver surface by using SERS mapping, electrochemistry and in situ SERS spectroelectrochemistry (Chapter 4). Phytic acid is an environmentally friendly anti-corrosive agent. Six phosphate groups of IP6 molecule possess the chelating capability with metal and the configuration of IP6 in solution is dependent of the pH value. On the basis of results of SERS mapping and quantum chemistry calculation, one concludes that in a solution of pH 1.27, IP6 tends to anchor at the silver surface via one phosphate group to assemble the monolayers and under pH=13, it adsorb chemically at the surface through four co-planar phosphate groups after the change of configuration. The former orientation is considered as much compact and the later more stable, leading to the different but the excellent inhibition efficiency. (4) The self-assembling process of IP6 at the roughened copper surface from the sodium salt of phytic acid solution has been observed on line with the time dependent SERS spectroscopy (Chapter 5). In domestic water, copper corrosion could be inhibited in the presence of Ca and Mg-salts with the inhibition efficiency around 90 %, and in the case of Na-salt, the maximum inhibition just reached 65.3 %, although it is completely soluble and would promote the formation of a passive film according to results of electrochemical experiment. In situ SERS spectroscopic investigations revealed that the self-assembling of IP6 at the roughened copper surface in a Na-salt phytic acid solution took two steps involving firstly self-cleaning the surface and then forming IP6 monolayers. Based on the calculation results for vibration spectrum of IP6 molecule with PM3 method and SERS mapping, a model for IP6 molecule adsorbed chemically on the roughened copper via two co-planar phosphate moieties was suggested. The copper surface with the IP6 monolayers presents the inhibiting action in a 0.1 mol L-1 KCl solution but the relative inhibition efficiency is of 41.2 %
because of the water co-adsorption. (5) SERS mapping was extended to study the SAMs of IP6 at the iron electrode (Chapter 6). After roughening the iron surface by a special oxidation-reduction cycle into SERS active substrate and IP6 self-assembled onto the surface, spectroscopic measurements were carried out. Based on the recorded SERS spectra and quantum chemistry calculation for vibrational modes of IP6 molecule with PM3 method, the adsorption ways of IP6 SAMs formed at the roughened iron surface from bulk solutions with various pH conditions were deduced. In the case of pH 5, the IP6 molecules locate at the surface via four co-planar phosphates, while the pH value of IP6 solution was 11.27,it is assumed that only one phosphate group was adsorbed on the iron surface. The results of electrochemical polarization measurements indicate that inhibition efficiency of IP6 SAMs formed at pH 5 due to the stronger interaction with the iron surface was higher than that formed at pH11.27. (6) A protocol of the combination of SERS mapping technique and DFT calculation method has been applied to look into the monolyers of 6-mercaptopurine of an electron transferring promoter formed at the gold surface (chapter 7). We obtained the normal acid solution Raman spectrum of 6MP for the first time. The SERS spectroscopic results suggest both of the resulted 6MP SAMs from acid and alkaline media finally adopt the same adsorption mode of the S atom of pyrimidine moiety and N7 atom of imidazale moiety anchoring at the gold surface in a vertical way. It was found that the detaching process of the 6MP SAMs from the surface involves one electron reduction and the potential at about 0.7 V vs SCE through in-situ SERS spectroelectrochemical studies. (7)The pH dependent SERS studies have been conducted on 6-mercaptopurine monolayers at the silver surface (Chapter 8). It is concluded that 6MP adsorbs on the silver electrode with a tilted orientation via S, N1, N7 atoms in the acid medium and in the case of alkaline medium it adopts the head-on adsorption modes with S and N1 atoms anchoring the silver surface; however, 6MP molecule turns to the same standing up orientation on the electrode through the S and N7 atoms after the acid or basic solution removed.
应该指出的是,SAMs技术仍处在方兴未艾阶段,目前需要解决的课题有:(一)发现更多的SAMs体系,尤其是具双功能或多功能位的成膜分子; (二)由于SAMs过程完全自发,膜结构取决于分子和基底以及分子间的作用方式,且受环境因素影响大,因此深刻了解SAMs构效关系,是拓展自组装技术应用的关键。由于自组装膜是分子在基底表面的单层吸附,这对分析技术的灵敏度有很高要求。常用的SAMs表征手段有电化学方法、X光电子能谱(XPS)、俄歇电子能谱(AES)、扫描隧道显微镜(STM)、原子力显微镜(AFM)、石英微天平(QCM)、接触角(Contacting angle)测定、傅立叶变换红外光谱(FTIR)、拉曼光谱(Raman spectroscopy)和表面增强拉曼散射(SERS)分析、椭圆偏振光谱(Ellipsometry)、二次谐波发生(SHG)、和频发生(SFG)、静态二次离子质谱(SSIMS)、高能或低能电子衍射(HEED或LEED )、X射线衍射(XD)、以及近边扩展X射线吸收精细结构(NEXAFS)。利用这些分析技术,人们对SAMs结构和成膜机理已有了一定的认识。然而,其中SHG、SSIMS、HEED、LEED、XPS和AES实验时需要高真空,条件苛刻; STM和AFM虽然能获得二维原子级图象信号,但缺乏分子选择性; FTIR和Raman技术能提供分子水平的信息,但尚未在二维尺度达到系统研究SAMs的层次,特别是对具多位点的成膜分子。
上世纪90年代以后,随着共焦显微激光拉曼技术的出现,使拉曼光谱分析的空间分辨率和仪器灵敏度大大提高。借助XY-自动扫描平台和Z轴自聚焦系统,可实现对表面的Raman mapping,获得的光谱包含分子空间二维分布的振动信息,在材料应力研究中已大显身手,但目前该技术在自组装单分子层研究领域的应用较少。本论文的重点是通过高空间分辨率的显微共焦和可达单分子水平检测灵敏度的SERS技术联用,进行Raman mapping实验,在不同介质中,观察包括辅酶NAD、巯基嘌呤和植酸化合物等具多吸附位点成膜分子,在金属基底上的自组装过程,并评价膜的二维有序性以及环境因子的影响程度。根据振动量化计算和SERS机制,解析SAMs膜结构。在此基础上,进行电化学和原位光谱电化学分析,考察膜的稳定性和构效关系。本论文具体内容如下:
(1)运用SERS mapping技术,分析了银电极表面形貌对NAD分子自组装机理的影响(第2章)。通过不同的处理方法,获得了两种银表面,经STM表征
Over the past two decades, self-assembled monolayers (SAMs) technique has witnessed tremendous growth in theory and application. The most attractive SAMs systems involve monolayers of fatty acids, of organosilicon derivatives and of alkanethiolates due to their controllably orderly uniformity with compact array, which provides versatile potentials to be employed in the fields of biologic chemistry, medicine, preparation of sensor, nano science, material science and inhibition of metal from corrosion, etc.
However, it should be pointed out that the developing pace of SAMs technique has been still on the way. Recently, some key issues are drawing increasing attentions as follows:
(1) Exploration of novel SAMs systems, in particular, the self-assembling molecules with dual or multiple adsorption sites;
(2) Investigation of the fundamental relationships between the monolayers structures and properties as a basic need to extend their further applications since the self-assembly process is completely spontaneous and adsorption mode dependent with interaction of molecules and subtract.
The self-assembled film at a monolayer level calls for the analytical methods with high sensitivity. The routine investigations of monolayers are conducted by using ellipsometry, contacting angle, electrochemistry, quartz crystal microbalance(QCM), infrared reflectance absorption spectroscopy (IRRAS), Raman spectroscopy, second harmonic generation(SHG), sum frequency generation(SFG), static second ion mass spectroscopy(SSIMS), X-ray photoelectron spectroscopy (XPS), high or low energy electron diffraction (HEED or LEED), X-Ray diffraction (XD) , near-edge extended X-ray adsorption fine structure (NEXAFS), scanning tunnel microscopy (STM), Auger electron spectroscopy(AES) and atomic force microscopy (AFM), etc. According to the above observations, insights into the self-assembling mechanism and film structure have been reached. However, some of aforementioned methods require high vacuum such as XPS, HEED or LEED and STM or AFM can provide image of monolayers in two dimensions, but the information is not for particular molecular species. Normal Raman spectroscopy and FTIR present molecular vibration information and are seldom used to study on the molecules with dual or multiple adsorption sites in two dimensions.
The advent of confocal laser Raman scattering analytical technique since
1990’s has enabled the spatial resolution and sensitivity of instrument to be increased. Aided with a XY stage strictly controlled by program and PC, Raman mapping has been extensively and successfully employed in analysis for stress distribution of material surface in two dimensions owing to its rich molecular vibration information. In present thesis, we wish to extend the Raman mapping technique together with the super sensitive surface enhanced Raman scattering method to examine the SAMs of molecules with multiple adsorption sites such as nicotinamide adenine dinucleotide (NAD), 6-mercaptopurine(6MP) and inositol hexphosphates (IP6), which are formed at various metallic surfaces under different media. Based on the obtained spectral information, the features of SAMs including the orderly uniformity and the impact factors from chemical environment have been explored. Furthermore, in light of the calculation results for vibrational spectra by quantum chemistry methods along with the SERS mechanism, the structure of the monolayers could be deduced. And also, the electrochemical and in situ spectroelectrochemical methods are used to observe the relationships of structure-properties and examine the stability of SAMs. The main contents of this thesis include following parts: (1) The mechanism of NAD monolayers self-assembled at the silver electrode as well as the effect of surface morphology on the process have been studied by the use of SERS mapping technique(Chapter 2). Two kinds of silver surfaces were obtained with the chemical and electrochemical methods and their average roughness degree are 40 ± 25 nm and 110 ± 50 nm as estimated from their STM image. At more even surface, formation of NAD SAMs was a much rapid process. In the case of a relatively rough silver surface, an intermediate state of adsorption of NAD molecules was found and the stable structure of NAD SAMs could be reached only after a long dynamic self-organized process. According to the SERS-based mechanism, NAD molecules should be vertically adsorbed at the silver surface to form the monolayers via N7 and NH2. The proposed orientation of NAD monolyers is in agreement with the result of minimized energy calculation of molecular configuration. (2) The impacts of potentials on the structure of NAD SAMs at the silver surface have been investigated by using in situ SERS electrochemical methods (Chapter 3). NAD molecule is composed of two 5`-nucleotide bases, AMP and nicotinamide ribose 5`-phosphate, which are linked together with a pyrophosphate bridge. The flexibility of this linkage provides a freedom to some extent for the adenine and nicotinamide moieties to change their conformation in dependence on
the chemical or physical micro-environment nearby the surface. However, question regarding the effect of the charged surface on the adsorption mode of NAD is still open. As the SAMs can provide a simple and good physical mode for understanding of interface phenomena, and the SERS signal is free from the interference of molecules in bulk solution. An NAD modified silver electrode was prepared. In situ SERS spectra indicate the change of NAD adsorption mode at the silver with the shift of potential and desorption of NAD monolayers from the surface occurring around the potential at -0.1 Vvs SCE. And the electrolyte in buffer solution might be a key influencing factor on the adsorption behavior of NAD at the silver surface. (3)This part is the first report and at molecular level investigating the relationship between the structure and properties of monolyers from phytic acid at the silver surface by using SERS mapping, electrochemistry and in situ SERS spectroelectrochemistry (Chapter 4). Phytic acid is an environmentally friendly anti-corrosive agent. Six phosphate groups of IP6 molecule possess the chelating capability with metal and the configuration of IP6 in solution is dependent of the pH value. On the basis of results of SERS mapping and quantum chemistry calculation, one concludes that in a solution of pH 1.27, IP6 tends to anchor at the silver surface via one phosphate group to assemble the monolayers and under pH=13, it adsorb chemically at the surface through four co-planar phosphate groups after the change of configuration. The former orientation is considered as much compact and the later more stable, leading to the different but the excellent inhibition efficiency. (4) The self-assembling process of IP6 at the roughened copper surface from the sodium salt of phytic acid solution has been observed on line with the time dependent SERS spectroscopy (Chapter 5). In domestic water, copper corrosion could be inhibited in the presence of Ca and Mg-salts with the inhibition efficiency around 90 %, and in the case of Na-salt, the maximum inhibition just reached 65.3 %, although it is completely soluble and would promote the formation of a passive film according to results of electrochemical experiment. In situ SERS spectroscopic investigations revealed that the self-assembling of IP6 at the roughened copper surface in a Na-salt phytic acid solution took two steps involving firstly self-cleaning the surface and then forming IP6 monolayers. Based on the calculation results for vibration spectrum of IP6 molecule with PM3 method and SERS mapping, a model for IP6 molecule adsorbed chemically on the roughened copper via two co-planar phosphate moieties was suggested. The copper surface with the IP6 monolayers presents the inhibiting action in a 0.1 mol L-1 KCl solution but the relative inhibition efficiency is of 41.2 %
because of the water co-adsorption. (5) SERS mapping was extended to study the SAMs of IP6 at the iron electrode (Chapter 6). After roughening the iron surface by a special oxidation-reduction cycle into SERS active substrate and IP6 self-assembled onto the surface, spectroscopic measurements were carried out. Based on the recorded SERS spectra and quantum chemistry calculation for vibrational modes of IP6 molecule with PM3 method, the adsorption ways of IP6 SAMs formed at the roughened iron surface from bulk solutions with various pH conditions were deduced. In the case of pH 5, the IP6 molecules locate at the surface via four co-planar phosphates, while the pH value of IP6 solution was 11.27,it is assumed that only one phosphate group was adsorbed on the iron surface. The results of electrochemical polarization measurements indicate that inhibition efficiency of IP6 SAMs formed at pH 5 due to the stronger interaction with the iron surface was higher than that formed at pH11.27. (6) A protocol of the combination of SERS mapping technique and DFT calculation method has been applied to look into the monolyers of 6-mercaptopurine of an electron transferring promoter formed at the gold surface (chapter 7). We obtained the normal acid solution Raman spectrum of 6MP for the first time. The SERS spectroscopic results suggest both of the resulted 6MP SAMs from acid and alkaline media finally adopt the same adsorption mode of the S atom of pyrimidine moiety and N7 atom of imidazale moiety anchoring at the gold surface in a vertical way. It was found that the detaching process of the 6MP SAMs from the surface involves one electron reduction and the potential at about 0.7 V vs SCE through in-situ SERS spectroelectrochemical studies. (7)The pH dependent SERS studies have been conducted on 6-mercaptopurine monolayers at the silver surface (Chapter 8). It is concluded that 6MP adsorbs on the silver electrode with a tilted orientation via S, N1, N7 atoms in the acid medium and in the case of alkaline medium it adopts the head-on adsorption modes with S and N1 atoms anchoring the silver surface; however, 6MP molecule turns to the same standing up orientation on the electrode through the S and N7 atoms after the acid or basic solution removed.
引文
[1] Bigelow W C, Pickett D L, Zisman W A. Oleophobic monolayers: I. Films adsorbed from solution in non-polar liquids. Journal of Colloid and Interface Science,1946, 1(6): 513-538
[2] Zisman W A. Relation of the equilibrium contact angle to liquid and solid constitution. In Contact Angle, Wettability and Adhesion. Advance in Chemistry Series, 1964, 43(1):1-51
[3] Sagiv J. Organized monolayers by adsorption 1. Formation and structure of oleophobic monolayers on solid surfaces. Journal of the American Chemical Society, 1980, 102(1):92-98.
[4] Nuzzo R. G, Allara D L. Adsorption of bifunctional organic disulfides on gold surfaces. Journal of the American Chemical Society, 1983, 105(13): 4481-4483
[5] Swalen J D, Allara D L, Andrade J D, et al. Molecular monolayers and films. A panel report for the Materials Sciences Division of the Department of Energy. Langmuir, 1987, 3(6): 932-950
[6] Ducharme Y, Wuest J D. Use of hydrogen bonds to control molecular aggregation. Extensive, self-complementary arrays of donors and acceptors. Journal of Organic Chemistry, 1988, 53(24):5787-5789
[7] Ulman, A. An Introduction to Ultrathin Organic Films.Boston: Academic Press, 1991.
[8] Zerkowski J , MacDonald J C, Seto C T, et al. Design of Organic Structures in the Solid State: Molecular Tapes Based on the Network of Hydrogen Bonds Present in the Cyanuric Acid.cntdot.Melamine Complex. Journal of the American Chemical Society, 1994, 116(6): 2382-2391
[9] 李景虹, 程广金, 董绍俊. 一种新型有序超薄有机膜——自组膜. 化学通报, 1995,10:11-18
[10] 董献堆, 陆君涛, 查全性. 巯基化合物自组装单分子层的研究进展.电化学, 1995,1(3):248-258
[11] Ulman A. Formation and Structure of Self-Assembled Monolayers. Chemical Reviews, 1996, 96(4): 1533-1554
[12] Wirth M J , Fairbank R W P, Hafeez O F. Mixed Self-Assembled Monolayers in Chemical Separations. Science, 1997,275(5296): 44-47
[13] Rdler J O, Koltover I, Salditt T, et al. Structure of DNA-Cationic Liposome Complexes: DNA Intercalation in Multilamellar Membranes in Distinct Interhelical Packing Regimes. Science, 1997, 275(5301): 810-814
[14] Spector M S, Schnur J M. DNA Ordering on a Lipid Membrane. Science, 1997, 275(2301): 791-792
[15] Sowerby S J, Michael E W, Wolfgang M H. Self-Assembly at the Prebiotic Solid-Liquid Interface: Structures of Self-Assembled Monolayers of Adenine and Guanine Bases Formed on Inorganic Surfaces. The Journal of Physical Chemistry B, 1998, 102(30): 5914-5922
[16] Ulman A. Self-Assembled Monolayers of 4-Mercaptobiphenyls, Accounts of Chemical Research, 2001, 34(11): 855-863
[17] 杨生荣, 任嗣利, 张俊彦等.自组装单分子膜的结构及其自组装机理. 高等学校化学学报, 2 0 0 1,22, (3): 470-476
[18] 李扬眉,陈志春,何 琳等. 生物大分子自组装膜及其应用研究进展. 化学进展, 2002, 14(3):212-216
[19] 杨学耕,陈慎豪,马厚义等. 金属表面自组装缓蚀功能分子膜. 化学进展, 2003, 15(2): 123-128
[20] Dubios L H, Nuzzo R G. Synthesis, structure and properties of model organic surfaces. Annual Review of Physical Chemistry, 1992, 43: 437-463.
[21] 邓文礼, 杨林静, 王琛等. 烷基硫醇分子自组装研究进展 .科学通报, 1998,43(5):449-457
[22] Nishizawa M, Sunagawa T, Yoneyama H. Underpotential Deposition of Cop-per on Gold Electrodes through Self-Assembled Monolayers of Propanethiol. Langmuir, 1997, 13: 5215-5217
[23] Sung M M , Sung K, Chang G K, et al. Self-Assembled Monolayers of Alkanethiols on Oxidized Copper Surfaces. Journal of Physical Chemistry B, 2000, 104(10): 2273-2277
[24] Ron H, Cohen H, Matlis S, et al. Self-Assembled Monolayers on Oxidized Metals. 4. Superior n-Alkanethiol Monolayers on Copper. The Journal of Physical Chemistry B, 1998, 102(49): 9861-9869
[25] Tao Y T, Hietpas G D, Allara D L. HCl Vapor-Induced Structural Rearrangements of n-Alkanoate Self-Assembled Monolayers on Ambient Silver, Copper, and Aluminum Surfaces. Journal of the American Chemical Society,1996, 118(28): 6724-6735
[26] Zamborini F P, Crooks R M. Corrosion Passivation of Gold by n-Alkanethiol Self-Assembled Monolayers: Effect of Chain Length and End Group. Langmuir, 1998, 14(12): 3279-3286
[27] Wade R. Thompson and Jeanne E. Pemberton Surface Raman Scattering of Self-Assembled Monolayers of (3-Mercaptopropy1) trimethoxysilane on Silver: Orientational Effects of Hydrolysis and Condensation Reactions. Chemistry of Materials, 1993, 5(3):241-244
[28] Saito N, Wu Y, Hayashi K, et al. Principle in Imaging Contrast in Scanning Electron Microscopy for Binary Microstructures Composed of Organosilane Self-Assembled Monolayers. Journal of the American Chemical Society, 2003, 107(3): 664-667
[29] Zhao X l and Kopelman R. Mechanism of Organosilane Self-Assembled Monolayer Formation on Silica Studied by Second-Harmonic Generation. The Journal of Physical Chemistry, 1996, 100(26): 11014 -11018
[30] Brito R, Rodriguez V A, Figueroa J, et al. Adsorption of 3-mercapto-propyltrimethoxysilane and 3-aminopropyltrimethoxy-silane at platinum electrodes. Journal of Electroanalytical Chemistry, 2002, 520(1-2): 47-52
[31] Wang R W, Baran G and Wunder S L, Packing and Thermal Stability of Polyoctadecylsiloxane Compared with Octadecylsilane Monolayers. Langmuir, 2000, 16(15): 6298-6305
[32] Rolando J. Tremont, Daniel R. Blasini, Carlos R. Cabrera Controlled self-assembly of mercapto and silane terminated molecules at Cu surfaces. Journal of Electroanalytical Chemistry, 2003, 556 : 147-158
[33] Thompson W R, Pemberton J E. Characterization of Octadecylsilane and Stearic Acid Layers on Al2O3 Surfaces by Raman Spectroscopy. Langmuir, 1995, 11(5): 1720-1725
[34] Samant M G, Brown C A , Gordon J G. An epitaxial organic film. The self-assembled monolayer of docosanoic acid on silver (111). Langmuir, 1993, 9(4): 1082-1085
[35] Allara D L, Nuzzo R G. Spontaneously organized molecular assemblies. 2. Quantitative infrared spectroscopic determination of equilibrium structures of solution-adsorbed n-alkanoic acids on an oxidized aluminum surface. Langmuir, 1985, 1(1): 52-66
[36] Tao Y T. Structural comparison of self-assembled monolayers of n-alkanoic acids on the surfaces of silver, copper, and aluminum. Journal of the American Chemical Society, 1993, 115(10):4350-4358
[37] Tao Y T, Lee M T, Chang S C. Effect of biphenyl and naphthyl groups on the structure of self-assembled monolayers: packing, orientation, and wetting properties. Journal of the American Chemical Society, 1993, 115(21):9547-9555
[38] Allara D L, Nuzzo R G. Spontaneously organized molecular assemblies. 1. Formation, dynamics, and physical properties of n-alkanoic acids adsorbed from solution on an oxidized aluminum surface. Langmuir, 1985, 1(1):45-51
[39] Aronoff Y G, Chen B, Lu G, et al. Stabilization of Self-Assembled Monolayers of Carboxylic Acids on Native Oxides of Metals. Journal of the American Chemical Society, 1997,119 (2):259-262
[40] Mitsuya M, Sugita N. Chemisorption of Dicarboxylic Acids on an Si(111) Surface and Subsequent Chemical Reactions at the Surface of Adsorbed Molecular Layers. Langmuir, 1997, 13(26): 7075-7079
[41] Lee H, Kepley L J , Hong H G,Mallouk T E. Inorganic analogs of Langmuir-Blodgett films: adsorption of ordered zirconium 1,10-decanebis-phosphonate multilayers on silicon surfaces. Journal of the American Chemical Society, 1988,110 (2):618-620
[42] Yim C T, Pawsey S, Morin F G, et al. Dynamics of Octadecyl-phosphonate Monolayers Self-Assembled on Zirconium Oxide: A Deuterium NMR Study. The Journal of Physical Chemistry B, 2002, 106(7):1728-1733
[43] Yang H C, Aoki K, Hong H G, et al.Growth and characterization of metal (II) alkanebisphosphonate multilayer thin films on gold surfaces. Journal of the American Chemical Society, 1993, 115 (25):11855-11862.
[44] Lee B S, Chi Y S, Lee J K, et al. Imidazolium Ion-Terminated Self-Assembled Monolayers on Au: Effects of Counteranions on Surface Wettability. Journal of the American Chemical Society, 2004 126(2):480-481
[45] Silverman B M, Wieghaus K A, Schwartz J. Comparative Properties of Siloxane vs Phosphonate Monolayers on A Key Titanium Alloy. Langmuir, 2005, 21(1):225-228.
[46] Horne J C, Huang Y, Liu G Y, et al.Correspondence between Layer Morphology and Intralayer Excitation Transport Dynamics in Zirconium-Phosphonate Monolayers. Journal of the American Chemical Society, 1999,121 (18):4419-4426.
[47] Wu A, Talham D R, Photoisomerization of Azobenzene Chromophores in Organic/Inorganic Zirconium Phosphonate Thin Films Prepared Using a Combined Langmuir-Blodgett and Self-Assembled Monolayer Deposition. Langmuir, 2000, 16(19): 7449-7456
[48] Wang X, Lieberman M. Zirconium-phosphonate monolayers with embedded disulfide bonds. Langmuir, 2003, 19(18):7346-7353.
[49] Benitez I O, Bujoli B, Camus L J, et al. Monolayers as Models for Supported Catalysts: Zirconium Phosphonate Films Containing Manganese (III) Porphy-rins. Journal of the American Chemical Society, 2002, 124(16): 4363-4370.
[50] Byrd H, Whipps S, Pike J. Role of the template layer in organizing self-assembled films: zirconium phosphonate monolayers and multilayers at a Langmuir-Blodgett template. Journal of the American Chemical Society, 1994,116 (1):295-301
[51] Cao G, Hong H G, Mallouk T E. Layered metal phosphates and phosphonates: from crystals to monolayers. Accounts of Chemical Research, 1992, 25(9):420-427
[52] Doneux Th, Buess-Herman Cl, Lipkowski J. Electrochemical and FTIR characterization of the self-assembled monolayer of 2-mercapto-benzimi-dazole on Au(111). Journal of Electroanalytical Chemistry, 2004, 564:65-75
[53] Arduengo III A J, Moran J R, Rodriguez-Parada J, et al.Molecular Control of Self-Assembled Monolayer Films of Imidazole-2-thiones: Adsorption and Reactivity. Journal of the American Chemical Society, 1990, 112(16):6153-6154
[54] van Esch J H, Nolte R J M, Ringsdorf H. Monolayers of Chiral Imidazole Amphiphiles: Domain Formation and Metal Complexation. Langmuir, 1994, 10(6):1955-1961
[55] Liu M, Kira A, Nakahara H,et al. Complex formation between monolayers of long-chain imidazole and benzimidazole derivatives and transition metal ions.Thin Solid Films, 1997, 295(1-2): 250-254
[56] Melissa J, David K. A second-harmonic generation study of a corrosion inhibitor on a mild steel electrode. Journal of Electroanalytical Chemistry, 1992, 340(1-2): 301-313
[57] Kong D S, Wan L J, Han M J,et al. Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study. Electrochimica Acta, 2002, 48(4):303-309
[58] Pang S f, Li C, Huang J G,et al. Monolayers of novel amphiphile with schiff base moiety as headgroup and its complex of copper (II). Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 178(1): 143-149
[59] Morrin A, Moutloali R M, Killard A J, et al. Electrocatalytic sensor devices: (I)cyclopentadienylnickel(II)thiolato Schiff base monolayer self-assembled on gold. Talanta, 2004, 64(1): 30-38
[60] 孔德生,陈慎豪, 万立骏等. Schiff碱N-aete-N在Au(111)上自组装单分子膜的电化学及STM研究. 高等学校化学学报,2003,24(10): 1847-1851
[61] DiMilla P A, Folkers J P, Biebuyck H A, et al.Wetting and Protein Adsorption of Self-Assmebled Monolayers of Alkane-thiolates Supported on Transparent Films of Gold. Journal of the American Chemical Society, 1994, 116(5): 2225-2226
[62] Laibinis P E, Whitesides G M, Allara D L, et al. Comparison of the Structures and Wetting Properties of Self-Assembled Monolayers of n-Alkanethiols on the Coinage Metal Surfaces, Cu, Ag, Au. Journal of the American Chemical Society, 1991, 113(19):7152-7167
[63] Dick L A, Haes A J, Van Duyne R P. Distance and Orientation Dependence of Heterogeneous Electron Transfer: A Surface-Enhanced Resonance Raman Scattering Study of Cytochrome c Bound to Carboxylic Acid Terminated Alkanethiols Adsorbed on Silver Electrodes.The Journal of Physical Chemistry B, 2000,104 (49):11752-11762
[64] Finklea H O, Hanshew D D. Electron-transfer kinetics in organized thiol monolayers with attached pentaammine (pyridine) ruthenium redox centers. Journal of the American Chemical Society, 1992,114 (9): 3173-3181
[65] Xu J, Li H L, Zhang Y. Relationship between Electronic Tunneling Coeffici-ent and Electrode Potential Investigated Using Self-Assembled Alkanethiol Monolayers on Gold Electrodes. The Journal of Physical Chemistry, 1993, 97(44): 11497-11500
[66] Finklea H O, Ravenscroft M S, Snider D A. Electrolyte and temperature effects on long range electron transfer across self-assembled monolayers. Langmuir, 1993, 9 (1):223-227.
[67] Yamamoto Y, Nishihara H, Aramaki K. Self-Assembled Layers of Alkanethiols on Copper for Protection Against Corrosion. Journal of Elctrochemistry Society, 1993, 140 (2):436-443
[68] laibinis P E, Whitesides G M.Omega.-Terminated alkanethiolate monolayers on surfaces of copper, silver, and gold have similar wettabilities. Journal of the American Chemical Society, 1992, 114(6):1990-1995
[69] Finklea H O, Snider D A, Fedyk J. Passivation of pinholes in octadecanethiol monolayers on gold electrodes by electrochemical polymerization of phenol. Langmuir, 1990, 6(2):371-376.
[70] Sandhyarani N, Pradeep T.An investigation of the structure and properties of layered copperthiolates. Journal of Materials Chemistry, 2001, 11(4):1294-1299
[71] Ron H, Cohen H, Matlis S, et al. Self-assembled monolayers on oxidized metals. 4. Superior n-alkanethiol monolayers on copper.The Journal of Physical Chemistry B, 1998,102 (49):9861-9869
[72] Mekhalif, Z.; Laffineur, F.; Couturier, N.; Delhalle, J.; Elaboration of Self-Assembled Monolayers of n-Alkanethiols on Nickel Polycrystalline Substrates: Time, Concentration, and Solvent Effects. Langmuir, 2003, 19(3): 637-645.
[73] Kudelski A. Chemisorption of 2-Mercaptoethanol on Silver, Copper and Gold: Direct Raman Evidence of Acid-Induced Changes in Adsorption/ Desorption Equilibria. Langmuir, 2003, 19(9): 3805-3813
[74] Sellers H, Ulman A, Shnidman Y, et al.Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers. Journal of the American Chemical Society, 1993, 115(21): 9389-9401
[75] Ohtsuka T, Sat Y, Uosaki K. Dynamic Ellipsometry of a Self-Assembled Monolayer of a Ferrocenylalkanethiol during Oxidation-Reduction Cycles. Langmuir, 1994, 10 (10):3658-3662
[76] Porter M D, Bright T B, Allara D L, et al. Spontaneously Organized Molecular Assemblies. 4. Structural Characterization of n-Alkyl Thiol Monolayers on Gold by Optical Ellipsometry, Infrared Spectroscopy, and Electrochemistry. Journal of the American Chemical Society, 1987,109 (12): 3559-3568
[77] Joo S W, Han S W, Kim K. Adsorption Characteristics of 1,3-Propanedithiol on Gold: Surface-Enhanced Raman Scattering and Ellipsometry Study. The Journal of Physical Chemistry B, 2000, 104(26):6218-6224
[78] Harke M, Stelzle M, Motschmann H R. Microscopic ellipsometry: imaging on arbitrary reflecting supports. Thin Solid Films,1996, 284-285():412-416
[79] Kang J F, Jordan R, Ulman A. Wetting and Fourier Transform Infrared Spectroscopy tudies of Mixed Self-Assembled Monolayers of4’-Methyl-4-mercaptobiphenyl and 4’-Hydroxy-4-mercap-tobiphenyl. Langmuir, 1998, 14(15):3983-3985
[80] Evans S D, Urankar E, Ulman A,et al.Self-Assembled Monolayers of Alkanethiols Containing a Polar Aromatic Group: Effects of the Dipole Position on Molecular Packing, Orientation, and Surface Wetting Properties. Journal of the American Chemical Society, 1991, 113(11): 4121-4131
[81] Ulman A, Evans S D, Shnidman Y,et al. Concentration-Driven Surface Transition in the Wetting ofMixed Alkanethiol Monolayers on Gold. Journal of the American Chemical Society, 1991, 113(5):1499-1506
[82] Nuzzo R G, Dubois L H, Allara D L. Fundamental studies of microscopic wetting on organic surfaces. 1. Formation and structural characterization of a self-consistent series of polyfunctional organic monolayers. Journal of the American Chemical Society, 1990, 112(2): 558-569
[83] Diao P, Guo M, Tong R. Characterization of defects in the formation process of self-assembled thiol monolayers by electrochemical impedance spectroscopy. Journal of Electroanalytical Chemistry, 2001, 495 (2):98-105
[84] Cui X L, Jiang D L, Diao P, et al.Assessing the apparent effective thickness of alkanethiol self-assembled monolayers in different concentrations of Fe(CN)63-:Fe(CN)6 4-by ac impedance spectroscopy. Journal of Electroanalytical Chemistry, 1999, 470(1): 9-13
[85] Janek R P and Fawcett W R. Impedance Spectroscopy of Self-Assembled Monolayers on Au(111): Evidence for Complex Double-Layer Structure in Aqueous NaClO4 at the Potential of Zero Charge.The Journal of Physical Chemistry B, 1997, 101(42): 8550-8558
[86] Boubour E and Lennox R B. Potential-Induced Defects in n-Alkanethiol Self-Assembled Monolayers Monitored by Impedance Spectroscopy. The Journal of Physical ChemistryB, 2000, 104 (38):9004-9010
[87] Finklea H O, Snider D A, Fedyk J. Characterization of Octadecanethiol-Coated Gold Electrodes as Microarray Electrodes by Cyclic Voltammetry and ac Impedance Spectroscopy. Langmuir, 1993,9(12):3660-3667
[88] 程志亮, 杨秀荣. 电化学交流阻抗技术表征自组装多层膜. 分析化学, 2001, 29(1):6-10
[89] Chidsey C E D, Loiacono D N. Chemical functionality in self-assembled monolayers: structural and electrochemical properties. Langmuir, 1990, 6(3):682-691.
[90] Krysinski P, Brzostowska-Smolska M. Capacitance characteristics of self-assembled monolayers on gold electrode. Bioelectrochemistry and Bioenrgytics, 1998, 44(2):163-168
[91] Ekeroth J and Konradsson P. Monitoring the interfacial capacitance at self-assembled phosphate monolayers on gold electrodes upon interaction with calcium and magnesium. Analytical Chemistry, 2002, 74(9):1979-1985
[92] Kakiuchi T, Iida M, Imabayashi S. Double-layer-capacitance titration of self-assembled monolayers of ω-functionalized alkanethiols on Au(111) surface. Langmuir, 2000, 16(12):5397-5401
[93] Nishiyama K, Tahara S, Uchida Y. Structural differences in self-assembled monolayers of anthraquinone derivatives on silver and gold electrodes studied by cyclic voltammetry and in situ SERS spectroscopy. Journal of Electroanalytical Chemistry, 1999, 478 (1-2):83-91
[94] 傅崇岗, 苏昌华, 单瑞峰. 半胱氨酸自组装膜修饰金电极的电化学特性. 物理化学学报,2004, 20(2):207-210
[95] Wirde M and Gelius U. Self-sssembled monolayers of cystamine and cysteamine on gold studied by XPS and voltammetry. Langmuir, 1999, 15(19):6370-6378
[96] Brito R, Tremont R, Cabrera C R. Electron transfer kinetics across derivatized self-assembled monolayers on platinum: a cyclic voltammetry and electroche-mical impedance spectroscopy study. Journal of Electroanalytical Chemistry, 2004, 574(1): 15-22
[97] Che G; Li Z; Zhang H,et al.Voltammetry of defect sites at a self-assembled monolayer on a gold surface. Journal of Electroanalytical Chemistry, 1998, 453(1-2):9-17
[98] Diao P, Jiang D, Cui X, et al. Studies of structural disorder of self-assembled thiol monolayers on gold by cyclic voltammetry and ac impedance. Journal of Electroanalytical Chemistry, 1999, 464(1):61-67
[99] Gothelf K V. Self-assembled monolayers of long-chain xanthic acids on gold studied by voltammetry. Journal of Electroanalytical Chemistry, 2000, 494 (2):147-150
[100] Ion A, Partali V, Sliwka H, et al. Electrochemistry of a carotenoid self-assembled monolayer. Electrochemistry Communications, 2002, 4(9): 674-678
[101] Arias Z G, álvarez J L M, and Fonseca J M L. Electrochemical chara-cterization of a mixed self-assembled monolayer of 6-thioguanine and guanine on a mercury electrode. Journal of Colloid and Interface Science, 2004, 276(1):132-137
[102] Muskal N, Mandler D. Thiol self-assembled monolayers on mercury surfaces: the adsorption and electrochemistry of v-mercaptoalkanoic acids. Electrochi-mica Acta, 1999, 45 (4-5): 537-548
[103] Flink S, Boukamp B A, van den Berg A. Electrochemical Detection of Electrochemically Inactive Cations by Self-Assembled Monolayers of Crown Ethers. Journal of the American Chemical Society, 1998, 120(19): 4652-4657
[104] Yu H Z, Wang Y Q, Cheng J Z, et al. Electrochemical Behavior of Azobenz-ene Self-Assembled Monolayers on Gold. Langmuir, 1996, 12(11): 2843-2848
[105] Beulen M W J, Kastenberg M I, van Veggel F C J M, et al. Electrochemical Stability of Self-Assembled Monolayers on Gold. Langmuir, 1998, 14(26):7463-7467
[106] Hu K, Chai Z, Whitesell J K, et al. In situ monitoring of diffuse double layer structure changes of electrochemically addressable self-assembled monolayers with an atomic force microscope. Langmuir, 1999, 15(9):3343-3347
[107] Chidsey C E D and Loiacono D N. Chemical functionality in self -assembled monolayers: structural and electrochemical properties. Langmuir, 1990, 6(3):682-691
[108] Han S W, Ha T H, Kim C H,et al. Self-Assembly of Anthraquinone -2-carboxylic Acid on Silver: Fourier Transform Infrared Spectroscopy, Ellipsometry, Quartz Crystal Microbalance, and Atomic Force Microscopy Study. Langmuir, 1998, 14 (21):6113-6120
[109] Nakano K, Sato T, Tazaki M,et al. Self-assembled monolayer formation from decaneselenol on polycrystalline gold as characterized by electrochemical measurements, quartz-crystal microbalance, XPS, and IR Spectroscopy. Langmuir, 2000, 16(5): 2225-2229
[111] Viana A S, Kalaji M, and Abrantes L M. Electrochemical quartz crystal microbalance study of self-assembled monolayers and multilayers of ferrocenylthiol derivatives on gold. Langmuir, 2003, 19(22):9542-9544
[112] Schneider T W and Buttry D A. Electrochemical quartz crystal microbalance studies of adsorption and desorption of self-assembled monolayers of alkyl thiols on gold. Journal of the American Chemical Society, 1993,115 (26):12391-12397
[113] Sugihara K and Shimazu K. Electrode potential effect on the surface pKa of a self-assembled 15-mercaptohexadecanoic acid monolayer on a gold/quartz crystal microbalance electrode. Langmuir, 2000, 16(18): 7101-7105
[114] Jan R, Tilo W, Wolfgang K, et al.A new affinity biosensor: Self-assembled thiols as selective monolayer coatings of quartz crystal microbalances. Biosensors and Bioelectronics, 1996, 11(6-7): 591-598
[115] Ebara Y and Okahata Y. A kinetic study of concanavalin a binding to glycolipid monolayers by using a quartz-crystal microbalance. Journal of the American Chemical Society, 1994,116 (25):11209-11212
[116] Liao S, Shnidman Y, and Ulman A. Adsorption kinetics of rigid 4-mercaptobiphenyls on gold. Journal of the American Chemical Society, 2000, 122(15): 3688-3694
[117] Eisert F, Dannenberger O, and Buck M. Molecular orientation determined by second-harmonic generation: Self-assembled monolayers. Physical Review B, 1998, 58(16):10860-10870
[118] Zhao X and Kopelman R. Mechanism of organosilane self-assembled monolayer formation on silica studied by second-harmonic generation.The Journal of Physical Chemistry, 1996, 100(26): 11014-11018
[119] Mania A A, Schultzb Z D, Champagnec B, et al.Molecule orientation in self-assembled monolayers determined by infrared-visible sum-frequency generation spectroscopy.Applied Surfuce Science, 2004,237(1-4):444-449
[120] Lagutchev A S, Song K J, Huang J Y. et al. Self-assembly of alkylsiloxane monolayers on fused silica studied by XPS and sum frequency generation spectroscopy. Chemical Physics, 1998, 226(3): 337-349
[121] Ye S, Nihonyanagi S and Uosaki K. Sum frequency generation (SFG) study of the pH-dependent water structure on a fused quartz surface modied by anoctadecyltrichlorosilane (OTS) monolayer. Physical Chemistry and Chemical Physics, 2001, 3(13):3463-3469
[122] Zolk M, Eisert F, Pipper J. Solvation of oligo(ethylene glycol)-terminated self-assembled monolayers studied by vibrational sum frequency spectroscopy. Langmuir, 2000, 16(14): 5849-5852
[123] Whelan C M, Smyth M R, Barnes C J,et al.An XPS study of heterocyclic thiol self-assembly on Au 111. Applied Surface Science, 1998 , 134(1-4):144–158
[124] Noh J, Ito E, Nakajima K,et al. High-resolution STM and XPS studies of thiophene self-Assembled monolayers on Au (111). The Journal of Physical Chemistry B, 2002, 106(26):7139-7141
[125] Sinapi F, Delhalle J, Mekhalif Z. XPS and electrochemical evaluation of two-dimensional organic films obtained by chemical modification of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on copper surfaces. Materials Science and Engineering C, 2002, 22(2):345-353
[126] Wang Y, Yu Q, Zhang Y,et al. Self-assembled monolayers of 3-MPT and its mixed-monolayers with alkanethiol on silver: studies by XPSand electrochemical methods. Applied Surface Science, 2004, 229 (1-4):377-386
[127] Hutt D A, Cooper E, Leggett G J. Structure and mechanism of photooxidation of self-assembled monolayers of alkylthiols on silver studied by XPS and static SIMS. The Journal of Physical Chemistry B, 1998, 102(1): 174-184
[128] 张 祺, 黄惠忠, 何会新等.角分辨XPS 对自组装单分子层厚度和官能团位置的定性及定量研究. 化学物理学报,1997, 10(3):201-204
[129] Whitesides G M, Laibinis P E. Wet chemical approaches to the characterization of organic surfaces: self-assembled monolayers, wetting, and the physical-organic chemistry of the solid-liquid interface. Langmuir, 1990, 6(1):87-96.
[130] Lee J, Lee J, and Yates J T. Comparison of Methanethiol Adsorption on Ag (110) and Cu(110)s Chemical Issues Related to Self-Assembled Monolayers. The Journal of Physical Chemistry B, 2004, 108(5): 1686-1693
[131] Azzaroni O, Vela E, Fonticelli M, et al.Electrodesorption potentials of self-assembled alkanethiolate monolayers on copper electrodes. An experimental and theoretical study. The Journal of Physical Chemistry B, 2003,107 (48): 13446-13454
[132] Kondoh H and Nozoye H. Effects of electron irradiation on methylthiolate monolayer on Au (111): electron-stimulated desorption. The Journal of Physical Chemistry B, 1998, 102(13):2367-2372
[133] Hayes W A, Kim H, Yue X, et al. Nanometer-scale patterning of surfaces using self-assembly chemistry. 2. Preparation, characterization, and electrochemical behavior of two-component organothiol monolayers on gold surfaces. Langmuir, 1997, 13(10): 2511-2518
[134] 李 斌,曾长淦,李群祥等. Au(111)表面自组装硫醇单分子膜的STM成像机理. 电子显微学报,2003, 22(3):189-193
[135] Giancarlo L C, Fang H, Rubin S M, et al.Influence of the substrate on order and image contrast for physisorbed, self-assembled molecular monolayers: STM studies of functionalized hydrocarbons on graphite and MoS2. The Journal of Physical Chemistry B, 1998, 102(50):10255-10263
[136] Schuurmans N, Uji-i H, Mamdouh W, et al. Design and STM Investigation of intramolecular folding in self-assembled monolayers on the surface. Journal of the American Chemical Society, 2004, 126(43): 13884-13885
[137] Hartwich J, Sundermann M, Kleineberg U, et al.STM writing of artificial nanostructures in alkanethiol-type self-assembled monolayers. Applied Surface Science, 1999, 144–145:538-542
[138] Kong D, Yuan S, Sun Y,et al. Self-assembled monolayer of o-aminothiop-henol on Fe(110)surface: a combined study by electrochemistry, in situ STM, and molecular simulations.Surfuce Science, 2004, 573(2):272-283
[139] Giz M J, Duong B, Tao N J. In situ STM study of self-assembled mercap-topropionic acid monolayers for electrochemical detection of dopamine. Journal of Electroanalytical Chemistry, 1999, 465(1):72-79
[140] Klein H, Battaglini N, Bellini B, et al. STM of mixed alkylthiol self-assembled monolayers on Au 111. Materials Science and Engineering C, 2002, 19(l-2):279-283
[141] Sawaguchi T, Sato Y, Mizutani F. In situ STM imaging of individual molecules in two-component self-assembled monolayers of 3-mercaptop-ropionic acid and 1-decanethiol on Au(111). Journal of Electroanalytical Chemistry, 2001, 496 (l-2):50-60
[142] Resch R, Grasserbauer M, Friedbacher G, et al. In situ and ex situ AFM investigation of the formation of octadecylsiloxane monolayers. Applied Surface Science, 1999, 140(1-2): 168-175
[143] 董飒英,王洪仁,罗国安.自组装金电极的电化学测试及其FTIR和A FM.分析分析科学学报,2002,18(5):357—360
[144] Nakasa A, Akiba U, Fujihira M. Self-assembled monolayers containing biphenyl derivatives as challenge for nc-AFM. Applied Surface Science, 2000,157 (4):326-331
[145] Uchihashi T, Ishida T,Komiyama M, et al.High-resolution imaging of organic monolayers using noncontact AFM. Applied Surface Science, 2000, 157(4) :244-250
[146] Li Y J, Tero R, Nagasawa T. Deposition of 10-undecenoic acid self-assembled layers on H-Si (111) surfaces studied with AFM and FT-IR.
Applied Surface Science, 2004,238 (1-4):238-241
[147] Wold D J. and Frisbie C D. Formation of metal-molecule-metal tunnel junctions: microcontacts to alkanethiol monolayers with a conducting AFM Tip. Journal of the American Chemical Society, 2000, 122(12): 2970-2971
[148] Vallant T, Brunner H, Mayer U, et al.Formation of self-assembled octadecylsiloxane monolayers on mica and silicon surfaces studied by atomic force microscopy and infrared spectroscopy. The Journal of Physical Chemistry B, 1998, 102(37):7190-7197
[149] Doudevski I and Schwartz D K. Mechanisms of self-assembled monolayer desorption determined using in situ atomic force microscopy. Langmuir, 2000, 16(24):9381-9384
[150] Wei Z Q, Wang C, Zhu CF, et al. Study on single-bond interaction between amino-terminated organosilane self-assembled monolayers by atomic force microscopy. Surfuce Science, 2000, 459 (3): 401-412
[151] Okabe Y, Akiba U, Fujihira M. Chemical force microscopy of CH and COOH terminalgroups in mixed self-assembled monolayers by pulsed-force -mode atomic force microscopy. Applied Surface Science, 2000, 157(4):398-404
[152] Himmelhaus M, Gauss I, Buck M, et al. Eisert F, et al. Adsorption of docosanethiol from solution on polycrystalline silver surfaces: an XPS and NEXAFS study. Journal of Electron Spectroscopy and Related Phenamena, 1998, 92(1-3):139-149
[153] Rieley H, Price N J, White R G, et al. A NEXAFS and UPS study of thiol monolayers self-assembled on gold. Surface Science, 1995, 331-333(1):189-195
[154] La Y, Jung Y J, Kang T H, et al. NEXAFS Studies on the Soft X-ray Induced Chemical Transformation of a 4-Nitrobenzaldimine Monolayer. Langmuir, 2003, 19(23):9984-9987
[155] Genzer J, Efimenko K, and Fischer D A .Molecular orientation and grafting density in semifluorinated self-assembled monolayers of mono-, di-,and trichloro silanes on silica substrates. Langmuir, 2002, 18(6): 9307-9311
[156] Parent Ph., Laffon C, and Tourillon G. Adsorption of acrylonitrile on Pt(ll1) and Au(ll1) at 95 K in the monolayer and multilayer ranges studied by NEXAFS, UPS, and FT-IR. The Journal of Physical Chemistry, 1995, 99(14):5058-5066
[157] Kondoh H, Nambu A, Ehara Y, et al. Substrate dependence of self-assembly of alkanethiol: X-ray absorption fine structure study. The Journal of Physical Chemistry B, 2004, 108(34):12946-12954
[158] Yan C, Golzhauser A, and Grunze M, et al. Formation of alkanethiolate self-assembled monolayers on oxidized gold surfaces. Langmuir, 1999, 15(7):2414-2419
[159] Stahl U, Gador D, Soukopp A, et al. Coverage-dependent superstructures in chemisorbed NTCDA monolayers: a combined LEED and STM study. Surfuce Science, 1998, 414(3): 423–434
[160] Bardi U, Magnanelli S, and Rovida G. LEED Study of benzene and naphthalene monolayers adsorbed on the basal plane of graphite. Langmuir, 1987, 3(2):159-163
[161] Himmel H J, Woll Ch., Gerlach R,et al. Structure of heptanethiolate monolayers on Au(111): adsorption from Solution vs vapor deposition. Langmuir, 1997, 13(4):602-605
[162] Strong L, Whitesides G M. Structures of self-assembled monolayer films of organosulfur compounds adsorbed on gold single crystals: electron diffraction studies. Langmuir, 1988, 4(3): 546-558.
[163] Hutta D A and Leggett G J. Static secondary ion mass spectrometry studies of self-assembled monolayers: electron beam degradation of alkanethiols on gold. Journal of Materials Chemistry, 1999, 9(4): 923-928
[164] Offord D A, John C M, Linford M R, et al. Contact angle goniometry, ellipsometry, and time-of-flight secondary ion mass spectrometry of gold supported, mixed self -assembled monolayers formed from alkyl mercaptans. Langmuir, 1994, 10(3):883-889
[165] Frisbie C D, Martin J R, Jr. Duff R R, et al. Use of high lateral resolution secondary ion mass spectrometry to characterize self-assembled monolayers on microfabricated structures. Journal of the American Chemical Society, 1992, 114(18):7142-7145
[166] Shimoyama Y. Growth process of poly (3-dodecyl thiophene) self-assembled monolayers: FTIR-RAS and gravimetric studies. Thin Solid Films, 2004, 464–465:403-407
[167] Doneux Th., Buess-Herman Cl, Lipkowski J. Electrochemical and FTIR characterization of the self-assembled monolayer of 2-mercapto-benzimidazole on Au(111). Journal of Electroanalytical Chemistry, 2004, 564: 65-75
[168] Zhang J, Zhao J,Zhang H L, et al. Structural evaluation of azobenzene-functionalized self-assembled monolayers on gold by reflectance FTIR spectroscopy. Chemical Physics Letters, 1997, 271(1-3):90-94
[169] Mielczarski J A and Mielczarski E. Determination of molecular orientation and thickness of self-assembled monolayers of oleate on apatite by FTIR reflection spectroscopy. The Journal of Physical Chemistry, 1995, 99(10):3206-3217
[170] Yu H Z, Ye S, Zhang H L, et al.Molecular Orientation and electrochemical stability of azobenzene self-assembled monolayers on gold: an in-situ FTIR study. Langmuir, 2000, 16(17): 6948-6954
[171] Han H S, Han S W, Kim C H, et al.Adsorption and reaction of 4-nitrobenzoic acid on ω-functionalized alkanethiol monolayers on powdered silver: infrared and Raman Spectroscopy study.Langmuir, 2000, 16(3):1149-1157
[172] Elmore D L, Chase D B, Liu Y, et al. Infrared spectroscopy and spectroscopic imaging of n-propyl trichlorosilane monolayer films self-assembled on glass substrates. Vibrational Spectroscopy, 2004, 34 (1):37-45
[173] Mielczarski J A and Mielczarski E. Infrared external reflection spectroscopy of adsorbed monolayers in a region of strong absorption of substrate. The Journal of Physical Chemistry B, 1999, 103(28): 5852-5859
[174] Tao Y T and Lin W L. Infrared spectroscopic study of chemically induced dewetting in liquid crystalline types of self-assembled monolayers. The Journal of Physical Chemistry B, 1997, 101(47): 9732-9740
[175] Zhang Z J, Yoshida N, Imae T. Self-assembled monolayer of an alkanoic acid-derivatized porphyrin on gold surface: a structural investigation by surface plasmon resonance, ultraviolet–visible, and infrared spectroscopies. Journal of Colloid and Interface Science, 2001,243(2): 382-387
[176] Mihailova B, Engstrom V, Hedlund J,et al. Infrared spectroscopic study of a c-mercaptopropyltrimethoxysilane monolayer on a gold surface. Journal of Materials Chemistry, 1999, 9(7): 1507-1510
[177] a. Raman C V and Krishman K S A new type of secondary radiation. Nature, 1928, 121(3048):501-502, b. Raman C V A. change of wavelength in light scattering. Nature,1928,121(3049): 619-620
[178] Raman C V. A new radiation. Indian Journal of Physics, 1928, 2():387-398.
[179] 潘家来编. 激光拉曼光谱在有机化学上的应用,北京:化学工业出版社,1986
[180] 朱自莹,顾仁敖,陆天虹. 拉曼光谱在化学中的应用. 沈阳:东北大学出版社,1998
[181] 田中群,任斌,吴德印等. 激光拉曼光谱研究电化学界面的新进展. 厦门大学学报(自然科学版),2001, 40(2):134-147
[182] Fleischmann M, Hendra P J, Mcquillan A J. Raman spectraof pyridine adsor-bed at a silver electrode.Chemical Physics Letters,1974, 26(2):163-166.
[183] Jeanmaire D L, Van Duyne R P. Surface Raman pectroelectrochemistry, Part I: Heterocyclic, aromaticandamines adsorbed on the anodized silver electrode. Journal of Electroanalytical Chemistry, 1977, 84(1):1-20.
[184] Nie S, Emory S R. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science, 1997, 275(5303):1102-1106.
[185] Kneipp K, Wang Y, Kneipp H,et al. Single molecule detection using surface-enhanced Raman scattering(SERS). Physical Review Letters, 1997, 78(9): 1667-1670.
[186] 武建劳,郇宜贤, 傅克德等. 表面增强拉曼散射概述. 光散射学报, 1994, 6(1):52-62
[187] 武建劳. 郇宜贤. 傅克德等. 表面增强拉曼散射概述. 光散射学报, 1994, 6(2):109-118
[188] Creighton, J. In Spectroscoopy of Surface; Clark R., Hestere R., Eds.; London: John Willey & Sons Ltd., 1988: 37
[189] Weaver M J, Zou S Z, Chan H Y H. The new interfacial ubiquity of surface-enhanced Raman spectroscopy. Analytical Chemistry, 2000, 72 (1): 38A-47A
[190] Tian, Z Q, Ren B, Wu D Y. Surface-enhanced Raman scattering: from noble to transition metals and from Rough surfaces to ordered nanostructures. The Journal of Physical Chemistry B, 2002, 106(37): 9463-9483
[191] Gu R A, Shen X Y, Liu G K,et al. Surface-Enhanced Raman Scattering from Bare Zn Electrode. The Journal of Physical Chemistry B, 2004, 108(45):17519-17522
[192] Schoenfisch M H and Pemberton J E. Effects of electrolyte and potential on the in situ structure of alkanethiol self-assembled monolayers on silver. Langmuir, 1999, 15(2): 509-517
[193] Kim J H, Cotton T M, and Uphaus R A. Electrochemical and Raman characterization of molecular recognition sites in self-assembled monolayers. The Journal of Physical Chemistry, 1988, 92(20):5575-5578
[194] Kudelski A. Chemisorption of 2-mercaptoethanol on silver, copper, and gold: direct Raman evidence of acid-induced changes in adsorption/desorption equilibria. Langmuir, 2003, 19(9): 3805-3813
[195] Bryant M A and Pemberton J E. Surface Raman scattering of self-assembled monolayers formed from 1-alkanethiols at Ag. Journal of the American Chemical Society, 1991, 113 (10):3629-3636
[196] Caldwell W B, Campbell D J, Chen K. A highly ordered self-assembled monolayer film of an azobenzenealkanethiol on Au(111): electrochemical properties and structural characterization by synchrotron in-plane X-ray diffraction, atomic force microscopy, and surface-enhanced Raman spectroscopy. Journal of the American Chemical Society, 1995,117 (22): 6071-6082
[197] Kudelski A and Hill W. Raman study on the structure of cysteamine mono-layers on silver. Langmuir, 1999, 15(9): 3162-3168
[198] Bryant M A, Joa S L, and Pemberton J E. Raman scattering from monolayer films of thiophenol and 4-mercaptopyridine at Pt surfaces. Langmuir, 1992, 8(3):753-756
[199] Culha M, Stokes D, Allain L R,et al. Surface-enhanced Raman scattering substrate based on a self-assembled monolayer for use in gene diagnostics. Analytical Chemistry, 2003, 75(22):6196-6201
[200] Murgida D H,Hildebrandt P Electron-Transfer Processes of Cytochrome c at Interfaces.New Insights by Surface-Enhanced Resonance Raman Spectrosc-opy. Accounts of Chemical Research, 2004, 37(11): 854-861
[201] Maoee T, Li S. Surface-enhanced Raman scattering from functionalized self-assembled monolayers Part 1. Distance dependence of enhanced Raman scattering from a terminal phenyl group. Analytical Chimica Acta, 1995, 307(2-3):333-340
[202] Yu H Z, Zhang J, Zhang H L, et al. Surface-enhanced Raman scattering (SERS) from azobenzene self-assembled “sandwiches”. Langmuir, 1999, 15(1):16-19
[203] Jiang C, Zhao J, Therese H A, et al. Raman imaging and spectroscopy of heterogeneous individual carbon nanotubes. The Journal of Physical Chemistry B, 2003, 107(34):8742-8745
[204] RayIII K and McCreery R L. Spatially resolved Raman spectroscopy of carbon electrode surfaces: observations of structural and chemical heterogeneity. Analytical Chemistry, 1997, 69(22):4680-4687
[205] Balss K M, Kuo T C and Bohn P W. Direct chemical mapping of elect-rochemically generated patial composition gradients on thin gold films with surface-enhanced Raman spectroscopy. The Journal of Physical Chemistry B, 2003, 107(4):994-1000
[206] Lee C J, Pezzotti G, Okui Y, et al.Raman microprobe mapping of residual microstresses in 3C-SiC film epitaxial lateral grown on patterned Si(111). Applied Surface Science, 2004, 228(1-4):10-16
[207] Aroca R F and Constantino C J L. Surface-enhanced Raman scattering: imaging and mapping of Langmuir-Blodgett monolayers physically adsorbed onto silver island films. Langmuir, 2000, 16(12):5425-5429
[208] Yang X M, Tryk D A, Ajito K, et al. Surface-enhanced Raman scattering imaging of photopatterned self-assembled monolayers. Langmuir, 1996, 12(23):5525-5527
[209] Zhu T, Yu H Z, Wang J,et al. Two-dimensional surface enhanced Raman mapping of differently prepared gold substrates with an azobenzene self-assembled monolayer. Chemical Physics Letters, 1997, 265 (3-5):334-340
[210] Pople J A, Segal G A. Approximate self-consistent molecular orbital theory. III. CNDO results for AB2 and AB3 systems. Journal of Chemical Physics, 1966, 44(9):3289-96
[211] Pople J A, Segal G A. Approximate self-consistent molecular orbital theory. II. Calculations with complete neglect of differential overlap. Journal of Chemical Physics, 1965, 43(10; Pt. 2): S136-S149, discussion: S150-S151
[212] Pople J A, Santry D P, Segal G A. Approximate self-consistent molecular orbital theory. I. Invariant procedures. Journal of Chemical Physics, 1965, 43(10; Pt. 2): S129-S135
[213] Pople J A, Beveridge D L, Dobosh P A. Approximate self-consistent molecular-orbital theory. V. Intermediate neglect of differential overlap. Journal of Chemical Physics, 1967, 47(6):2026-2033
[214] Stewart J J P. Optimization of parameters for semiempirical methods I. Method. Journal of Computational Chemistry, 1989, 10(2):209-220
[215] Stewart J J P. Optimization of parameters for semiempirical methods II. Applications. Journal of Computational Chemistry, 1989, 10(2): 221-264
[216] Coolidge M B, Marlin J E, Stewart J J P. Calculations of molecular vibrational frequencies using semiempirical methods. Journal of Computational Chemistry, 1991, 12(8): 948-952
[217] Becke A D. Density-functional exchange-energy approximation with correct asymptotic behavior. Physical Review A, 1988, 38 (6): 3098-3100
[218] Korolevich M V, Zhbankov R G. Theoretical vibrational spectroscopy and the structure of nitrosubstituted glucopyranosides. Journal of Molecular Structure, 2000, 556(1-3): 157-172
[219] Mroginski M A, Nemeth K, Magdo I, et al. Calculation of the vibrational spectra of linear tetrapyrroles. 2. Resonance Raman spectra of hexamethylpyrromethene monomers. The Journal of Physical Chemistry B, 2000, 104(46): 10885-10899.
[220] El-Azhary A A, Suter H U, Kubelka J. Experimental and theoretical investigation of the geometry and vibrational frequencies of 1,2,3-triazole, 1,2,4-triazole, and tetrazole anions. The Journal of Physical Chemistry A, 1998,102(3): 620-629.
[221] Chen S P, Hosten C M, Vivoni A, Birke R L, et al. SERS investigation of NAD+ adsorbed on a silver electrode. Langmuir, 2002, 18(25): 9888-9900
[222] Cinta S, Morari C, Vogel E, et al.Vibrational studies of B6 vitamin. Vibrat-ional Spectroscopy, 1999, 19(2): 329-334
[223] Bernd S, Peter F, Siegfried S. The assignment of the vibrations of substituted mercaptotetrazoles based on quantum chemical calculations. Journal of Molecular Structure, 1999, 482-483(): 231-235
[224] Hideaki S, Yoshihiro Y, Koichi O, Raman spectra of polycyclic aromatic hydrocarbons. Comparison of calculated Raman intensity distributions with observed spectra for naphthalene, anthracene, pyrene, and perylene. Journal of Molecular Structure, 1998, 442(1-3): 221-234
[225] Foley M S C, Braden D A, Hudson B S, et al. Ab initio and resonance Raman studies of hexafluoro-1,3-butadiene. The Journal of Physical Chemistry A, 1997, 101(8): 1455-1459.
[226] Wu D Y, Hayashi M, Shiu Y J, et al. A quantum chemical study of bonding interaction, vibrational frequencies, force constants, and vibrational coupling of pyridine-Mn (M = Cu, Ag, Au; n = 2-4). The Journal of Physical Chemistry A, 2003, 107(45): 9658-9667
[227] Bockris J, Khan S, Surface Electrochemistry: A Molecular Level Approach, New York:Plenum Pub. Corp. 1993
[228] Beek J, Deng H, Callander R, et al. Vibrational analysis of NADH cofactors bound to glycerol-3-phosphate dehydrogenase and dogfish lactate dehydrogenase. Journal of Raman Spectroscopy, 2002, 83 (5): 397-403
[229] Koglin E, Sequaris J M, Valenta P. Surface Raman spectra of nucleic acid components adsorbed at a silver electrode. Journal of Molecular Structure, 1980, 60(): 421-425
[230] Watanabe T, Kawanami O, Katoh H, et al. SERS study of molecular adsorp-tion: Some nucleic acid bases on Ag electrodes. Surfure Science, 1985, 158 (1-3):341-351.
[231] Otto C, Mul F, Huizinga A, et al. Surface enhanced Raman scattering of derivatives of adenine: the importance of the external amino group in adenine for surface binding. The Journal of Physical Chemistry, 1988, 92 (5): 1239-1244
[232] Taniguchi I, Umekita K, Yasukouchi K. Surface-enhanced Raman scattering of nicotinamide adenine dinucleotide (NAD+) adsorbed on silver and gold electrodes. Journal of Electroanalytical Chemistry, 1986,202 (1-2): 315-322
[233] Siiman O, Rivellini R., Patel R., Orientation and conformation of NAD and NADH adsorbed on colloidal silver, Inorganic Chemistry, 1988,27(22): 3940-3949
[234] Cotton T., in: Clark R, Hestere R (Eds.), Spectroscopy of Surface, John Willey & Sons Ltd, London, 1988, p. 121.
[235] Liu J, Fryxell G E, Qian M, et al. Interfacial chemistry in self-assembled nanoscale materials with structural orderin. Pure and Applied Chemistry, 2000, 72 (1-2): 269-279
[236] Nakamura C, Inuyama Y, Shirai K, et al. Detection of porphyrin using a short peptide immobilized on a surface plasmon resonance sensor chip. Biosensors and Bioelectrics, 2001, 16 (9-12) :1095-1100
[237] Zhang X H, Wang S F. Voltammtric behavior of noradrenaline at 2-mercapt-oethanol self-assembled monolayer modified gold electrode and its analytical application. Sensors,2003,3 (3): 61-68
[238] Nadolny G, Zundel G. Protonation, conformation and hydrogen bonding of nicotinamide adenine dinucleotide — an FT-IR study. Journal of Molecular Structure,1996, 385 (2): 81-87
[239] Austin J, Hester R, Surface-enhanced Raman Spectroscopy of NAD+ and related compounds. Journal of the Chemical Society-Faraday Transactions 1, 1989, 85(5):1159-1168
[240] Xiao Y, Wang T, Wang X,et al. Surface-enhanced near-infrared Raman spectroscopy of nicotinamide adenine dinucleotides on a gold electrode. Journal of Electroanalytical Chemistry, 1997,433 (1-2): 49-57.
[241] Suh J, Moskovits M.Surface-enhanced Raman spectroscopy of amino acids and nucleotide bases adsorbed on silver. Journal of the American Chemical Society, 1986,108 (16): 4711-4718
[242] Xiao Y, Gao X, Markwell J. In-situ monitoring of the interaction of lactate dehydrogenase with NAD on a gold electrode by FT-SERS. Journal of Electroanalytical Chemistry, 1999, 465 (2):187-194
[243] Chen H, Long Y. Study of biomolecules by combining electrochemistry with UV/Vis, IR and surface enhanced Raman scattering spectroscopy by a novel flow microcell. Analytical Chimica Acta, 1999, 382 (1-2):171-177
[244] Jensen M, Elving P. Nicotinamide adenine dinucleotide (NAD+). Formal potential of the NAD+/NAD· couple and NAD· dimerization rate. Biochimica Et Biophysica Acta, 1984, 764(3): 310-315
[245] Persson B, Gorton L. A chemically modified graphite electrode for electroc-atalytic oxidation of reduced nicotinamide adenine dinucleotide based on a phenothiazine derivative, 3-β-naphthoyl-toluidine blue O. Journal of Electroanalytical Chemistry, 1990, 287 (1): 61-80
[246] Schmakel C, Santhanam K, Elving P. Nicotinamide adenine dinucleotide (NAD+) and related compounds. Electrochemical redox pattern and allied chemical behavior. Journal of the American Chemical Society, 1975, 97(18):5083-5092
[247] Tang H, Hajizadeh K, Halsall H, et al. Flow-injection analysis with electr-ochemical detection of reduced nicotinamide adenine dinucleotide using 2, 6-dichloroindophenol as a redox coupling agent. Analytical Biochemistry, 1991, 192(1): 243-250.
[248] Sampath S, Lev O. Electrochemical oxidation of NADH on sol–gel derived, surface renewable, non-modified and mediator modified composite-carbon electrodes. Journal of Electroanalytical Chemistry, 1998, 446(1-2): 57-65
[249] Subramanian R, lakshminarayanan V. Effect of adsorption of some azoles on copper passivation in alkaline medium. Corrosion Science, 2002, 44(3): 535-554
[250] Truc T A, Pébère N, Hang T T X, et al. Study of the synergistic effect observed for the corrosion protection of a carbon steel by an association of phosphates. Corrosion Science, 2002, 44: 2055-2071
[251] Notoya T, Otieno-alego V, Schweinsberg D. The corrosion and polarization behaviour of copper in domestic water in the presence of Ca, Mg and Na-Salts of phytic acid. Corrosion Science, 1995, 37(1): 55-65
[252] Cao P, Gu R, Tian Z. Electrochemical and surface-enhanced Raman spectr-oscopy studies on inhibition of iron corrosion by benzotriazole. Langmuir, 2002, 18(20): 7609-7615
[253] Bentiss, F, Traisnel M, Vezin H, et al. Electrochemical study of substituted triazoles adsorption on mild steel. Industrial and Engineering Chemistry Research, 2000, 39(10): 3732-3736
[254] Tan J, Bailey S, Kinsella B. An investigation of the formation and destruction of corrosion inhibitor films using electrochemical impedance spectroscopy (EIS). Corrosion Science, 1996, 38(9): 1545-1561
[255] Manov S, Lamazouere A, ArieA? L. Electrochemical study of the corrosion behaviour of zinc treated with a new organic chelating inhibitor. Corrosion Science, 2000, 42(7): 1235-1248
[256] Marconato J, Bulhoes L, Temperini M. A spectroelectrochemical study of the inhibition of the electrode process on copper by 2-mercapto-benzothiazole in ethanolic solutions. Electrochimica Acta, 1998, 43(7): 771-780
[257] Cao P, Yao J, Zheng J, et al. Comparative study of inhibition effects of benzotriazole for metals in neutral solutions as observed with surface-enhanced Raman spectroscopy. Langmuir, 2002, 18(1):100-104
[258] Yamamoto H, Ota Y. Japanese Patent, Japanese Kokai Tokkyo Koho JP 60 194,088[85 194 088] , 1985
[259] 张洪生. 植酸在金属防护中的应用. 四川化工与腐蚀控制,1999, 2(5):34 -38
[260] Bebot-Brigaud A, Dange C, Fauconnier N,et al. 31P NMR, potentiometric and spectrophotometric studies of phytic acid ionization and complexation properties toward Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ . Journal of Inorganic Biochemistry, 1999, 75(1): 71-78
[261] Bauman A, Chateauneuf G, Boyd B, et al. Conformational inversion processes in phytic acid: NMR spectroscopic and molecular modeling studies. Tetrahedron Letters, 1999, 40(24): 4489-4492
[262] Ramachandran S, Tsai B L, Blanco M, et al. Self-assembled monolayer mechanism for corrosion inhibition of iron by imidazolines. Langmuir, 1996, 12(26): 6419-6428.
[263] Kepley J L, Crooks M R, Ricco J A. A selective SAW-based organoph-osphonate chemical sensor employing a self-assembled, composite monola-yer: a new paradigm for sensor design. Analytical Chemistry, 1992, 64 (24): 3191-3193
[264] Laibinis E P, Whitesides M. G. Self-assembled monolayers of n-alkane-thiolates on copper are barrier films that protect the metal against oxidation by air. Journal of the American Chemistry Society, 1992, 114(23): 9022-9028.
[265] Jennings K G, Laibinis P E. Self-assembled monolayers of alkanethiols on copper provide corrosion resistance in aqueous environments. Colloids and Surfaces A, 1996,116 (): 105-114
[266] Epple M, Bittner M A, Kuhnke K, et al. Alkanethiolate Reorientation during Metal Electrodeposition. Langmuir, 2002,18 (3):773-784
[267] Li F, Lu Y, Xue G, et al. The adsorption and bonding of ω-mercaptoalkanols on HNO3 etched copper. Chemical Physics Letters,1997,264(3-4):376-380
[268] Quan Z, Chen S, Li Y, et al. Adsorption behaviour of Schiff base and corrosion protection of resulting films to copper substrate. Corrosion Science, 2002, 44(4): 703-715
[269] Subramanian R, Lakshminarayanan V. Effect of adsorption of some azoles on copper passivation in alkaline medium. Corrosion Science, 2002, 44 (4):535-554
[270] Gomma G K. Effect of azole compounds on corrosion of copper in acid medium. Materials Chemistry and Physics, 1998, 56 (1): 27-34
[271] Shinohara Y, Ota Y, Yamamoto H, et al. Japanese Patent, Japanese Kokai Tokkyo Koho JP 61 030,685 [86 30 685] , (1986)
[272] Sinniah K, Cheng J, Terrettaz S, et al. Self-assembled omega. Hydroxylalk-anethiol monolayers with internal functionalities: electrochemical and infrared structural characterizations of ether-containing monolayers. The Journal of Physical Chemistry, 1995, 99 (39):14500-14505
[273] Edinger K, Goelzhaeuser A, Demota K, et al. Formation of self-assembled monolayers of n-alkanethiols on gold: a scanning tunneling microscopy study on the modification of substrate morphology. Langmuir, 1993, 9 (1): 4-8
[274] El-Deab M S, Ohsaka T. Molecular-level design of binary self-assembled monolayers on polycrystalline gold electrodes. Electrochimica Acta, 2004, 49 (13) :2189-2194
[275] Stefan I C, Mandler D, Scherson D A. In situ FTIR-ATR studies of functi-onalized self-assembled bilayer interactions with metal ions in aqueous solutions. Langmuir, 2002, 18 (18):6976-6980
[276] Luo H, Weaver M J. Surface-enhanced Raman scattering as a versatile vibrational probe of transition-metal interfaces: thiocyanate coordination modes on platinum-group versus coinage-metal electrodes. Langmuir, 1999, 15 (25): 8743-8749
[277] Crane G L, Wang D X, Sears M L, et al. SERS surfaces modified with a 4-(2-Pyridylazo)resorcinol disulfide derivative: detection of copper, lead, and cadmium. Analytical Chemistry, 1995, 67 (2):360-364
[278] Allen S C, Van Duyne P R. Molecular generality of surface-enhanced Raman spectroscopy (SERS). A detailed investigation of the hexacyanoruthenate ion adsorbed on silver and copper electrodes. Journal of the American Chemistry Society, 1981,103 (25):7497-7501
[279] Gao J S, Tian Z Q. Surface enhanced Raman scattering of pyridine at copper electrodes excited with a 514.5 nm line. Chemical Physics Letters, 1996,262 (1-2):151-154
[280] Dewar M J S, Zoebisch E G, Healy E F, et al. Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model. Journal of the American Chemistry Society, 1985,107 (13): 3902-3909
[281] Dewar M JS, Dieter K M. Evaluation of AM1 calculated proton affinities and deprotonation enthalpies. Journal of the American Chemistry Society, 1986,108 (25): 8075-8086
[282] Stewart J J P, MOPAC: a semiempirical molecular orbital program. Journal of Computo-Aided Molecular Design, 1990, 4 (1): 1-105
[283] Lefèvre G, Walcarius A, Ehrhardt J J, et al. Sorption of iodide on cuprite (Cu2O). Langmuir, 2000, 16 (10):4519-4527
[284] Texier F, Servant L, Bruneel JL, et al.In situ probing of interfacial processes in the electrodeposition of copper by confocal Raman microspectro- scopy. Journal of Electroanalytical Chemistry, 1998, 446 (1-2):189–203
[285] Xu J F, Ji W, Shen Z X, et al. Preparation and characterization of CuO nanocrystals. Journal of Solid State Chemistry, 1999,147 (2): 516-519
[286] Zou S Z, Chen Y X, Mao. B W, et al. SERS studies on electrode/electrolyte interfacial water I. Ion effects in the negative potential region. Journal of Electroanalytical Chemistry, 1997,424 (1-2): 19-24
[287] Cao P G, Yao J L, Ren B, et al.Surface-enhanced Raman scattering from bare Fe electrode surfaces. Chemical Physics Letters, 2000, 316(1-2): 1-5
[288] Gu R A, Cao P G, Yao J L., et al. Surface Raman spectroscopic studies on the adsorption of pyridine at bare iron electrodes. Journal of Electroanalytical Chemistry, 2001, 505(1):95-99
[289] Cao P G, Yao J L, Ren B, et al.Potential Dependence of the orientation of thiocyanate adsorbed on an iron electrode as probed by surface-enhanced Raman spectroscopy. The Journal of Physical Chemistry. B, 2002, 106(29): 7283-7285
[290] Cao P G, Yao J L, Ren B, et al. Surface-enhanced Raman scattering spectra of thiourea adsorbed at an iron electrode in NaClO4 solution. The Journal of Physical Chemistry, 2002, 106(39): 10150-10156
[291] Yao J L, Ren B, Huang Z F, et al. Extending surface Raman spectroscopy to transition metals for practical applications IV. A study on corrosion inhibition of benzotriazole on bare Fe electrodes. Electrochimica Acta, 2003, 48(9):1263-1271
[292] Wang G H, Shi J C, Yang H F, et al. Surface-enhanced Raman scattering of imidazole adsorbed on an iron surface. Journal of Raman Spectroscopy, 2002, 33(2): 125–130
[293] Pineda T, Sevilla JM, Roman AJ, et al. Electrochemical evidence on the molten globule conformation of cytochrome c. Biochimica Biophysics Acta, 1997, 1343(2):227-34.
[294] Taniguchi I, Iseki M, Toyosawa K, et al. Purines as new promoters for the voltammetric response of horse heart cytochrome c at a gold electrode. Journal of Electroanalytical Chemistry, 1984, 164(20): 385-391
[295] Taniguchi I, Higo N, UmekitaK, et al. Electrochemical behavior of horse heart cytochrome c in acid solutions using a 6-mercaptopurine modified gold electrode. Journal of Electroanalytical Chemistry, 1986, 206(1-2): 341-348
[296] Ion A, Banica F G, Luca C. Ligand-catalysed metal ion reduction. Voltammetric determination of rate and formation constants for the nickel complex with 6-mercaptopurine-9-D-riboside. Journal of Electroanalytical Chemistry, 1998, 444 (1-2):11-18
[297] Madueno R, Pineda T, Sevilla M, et al. An Electrochemical Study of the SAMs of 6-Mercaptopurine (6MP) at Hg and Au (111) Electrodes in Alkaline Media M. Langmuir, 2002, 18(10): 3903-3909
[298] Vivoni A, Chen S, Ejeh D, et al.Determination of the orientation of 6-mercaptopurine adsorbed on a silver electrode by surface-enhanced Raman spectroscopy and normal mode calculations. Langmuir, 2000, 16(7):3310-3316
[299] Boland T, Ratner D. Two-dimensional assembly of purines and pyrimidines on Au (111). Langmuir, 1994, 10(10): 3845-3852
[300] Gao P, Weaver M J. Metal-adsorbate vibrational frequencies as a probe of surface bonding: halides and pseudohalides at gold electrodes. The Journal of Physical Chemistry, 1986, 90(17): 4057-4063
[301] Kohn W, Becke A D, Parr R G. Density functional theory of electronic structure. The Journal of Physical Chemistry, 1996, 100(31): 12974-12980
[302] Adamo C, Barone V. Toward reliable adiabatic connection models free from adjustable parameters. Chemical Physics Letters, 1997, 274 (1-3): 242-250
[303] Zhu T, Yu H, Wang J, et al.Two-dimensional surface enhanced Raman mapping of differently prepared gold substrates with an azobenzene self-assembled monolayer. Chemical Physics Letters, 1997, 265(3-5): 334-340
[304] Yang H, Yang Y, Liu Z, et al.Self-assembled monolayer of NAD at silver surface: a Raman mapping study. Surface Science, 2004, 555(1-2): 1-8
[305] Moskovits M, Sun J S. Surface selection rules for surface-enhanced Raman spectroscopy: calculations and application to the surface-enhanced Raman spectrum of phthalazine on silver. The Journal of Physical Chemistry, 1984, 88(23): 5526-5530
[306] Mohtat N, Byloos M, Soucy M, et al.Electrochemical evidence of the adsorption of alkanethiols on two sites on Ag(111). Journal of Electroanalytical Chemistry, 2000, 484(2): 120-130
[307] Weisshaar D E, Lamp B D, Porter M D. Thermodynamically controlled electrochemical formation of thiolate monolayers at gold: characterization and comparison to self-assembled analogs. Journal of the American Chemistry Society, 1992, 114(14): 5860-5862
[308] Walczak M M, Chung C, Stole S M, et al. Structure and interfacial properties of spontaneously adsorbed n-alkanethiolate monolayers on evaporated silver surfaces. Journal of the American Chemistry Society, 1991, 113(7): 2370-2378
[309] Walczak M M, Popenoe D D, Deinhammer R S, et al.Reductive desorption of alkanethiolate monolayers at gold: a measure of surface coverage. Langmuir, 1991, 7(11): 2687-2693
[310] Yang D F, Al-Maznai H, Morin M. Vibrational study of the fast reductive and the slow oxidative desorptions of a nonanethiol self-assembled monolayer from a Au(111) single crystal electrode. The Journal of Physical Chemistry B, 1997, 101(7):1158-1166
[311] Yang D F, Wilde C P, Morin M. Studies of the electrochemical removal and efficient Re-formation of a monolayer of hexadecanethiol self-assembled at an Au(111) single crystal in aqueous solutions. Langmuir, 1997, 13(2): 243-249
[312] Wong S J, Porter M D. Origin of the multiple voltammetric desorption waves of long-chain alkanethiolate monolayers chemisorbed on annealed gold electrodes. Journal of Electroanalytical Chemistry, 2000, 485(2):135-143
[313] Yang D F, Wilde C P, Morin M. Electrochemical desorption and adsorption of nonyl mercaptan at gold single crystal electrode surfaces. Langmuir, 1996, 12(26): 6570-6577
[314] Zhong C J, Zak J, PorterM D. Voltammetric reductive desorption characteristics of alkanethiolate monolayers at single crystal Au(111) and (110) electrode surfaces. Journal of Electroanalytical Chemistry, 1997, 421(1-2): 9-13
[315] Szeghalmi A V, Leopold L, P?nzaru S,et al. Adsorption of 6-mercaptopurine and 6-mercaptopurine riboside on silver colloid: a pH dependent surface enhanced Raman spectroscopy and density functional theory study. Part I. 6-Mercaptopurine. Journal of Molecular Structure, 2005, 735-736(1): 103-113
[2] Zisman W A. Relation of the equilibrium contact angle to liquid and solid constitution. In Contact Angle, Wettability and Adhesion. Advance in Chemistry Series, 1964, 43(1):1-51
[3] Sagiv J. Organized monolayers by adsorption 1. Formation and structure of oleophobic monolayers on solid surfaces. Journal of the American Chemical Society, 1980, 102(1):92-98.
[4] Nuzzo R. G, Allara D L. Adsorption of bifunctional organic disulfides on gold surfaces. Journal of the American Chemical Society, 1983, 105(13): 4481-4483
[5] Swalen J D, Allara D L, Andrade J D, et al. Molecular monolayers and films. A panel report for the Materials Sciences Division of the Department of Energy. Langmuir, 1987, 3(6): 932-950
[6] Ducharme Y, Wuest J D. Use of hydrogen bonds to control molecular aggregation. Extensive, self-complementary arrays of donors and acceptors. Journal of Organic Chemistry, 1988, 53(24):5787-5789
[7] Ulman, A. An Introduction to Ultrathin Organic Films.Boston: Academic Press, 1991.
[8] Zerkowski J , MacDonald J C, Seto C T, et al. Design of Organic Structures in the Solid State: Molecular Tapes Based on the Network of Hydrogen Bonds Present in the Cyanuric Acid.cntdot.Melamine Complex. Journal of the American Chemical Society, 1994, 116(6): 2382-2391
[9] 李景虹, 程广金, 董绍俊. 一种新型有序超薄有机膜——自组膜. 化学通报, 1995,10:11-18
[10] 董献堆, 陆君涛, 查全性. 巯基化合物自组装单分子层的研究进展.电化学, 1995,1(3):248-258
[11] Ulman A. Formation and Structure of Self-Assembled Monolayers. Chemical Reviews, 1996, 96(4): 1533-1554
[12] Wirth M J , Fairbank R W P, Hafeez O F. Mixed Self-Assembled Monolayers in Chemical Separations. Science, 1997,275(5296): 44-47
[13] Rdler J O, Koltover I, Salditt T, et al. Structure of DNA-Cationic Liposome Complexes: DNA Intercalation in Multilamellar Membranes in Distinct Interhelical Packing Regimes. Science, 1997, 275(5301): 810-814
[14] Spector M S, Schnur J M. DNA Ordering on a Lipid Membrane. Science, 1997, 275(2301): 791-792
[15] Sowerby S J, Michael E W, Wolfgang M H. Self-Assembly at the Prebiotic Solid-Liquid Interface: Structures of Self-Assembled Monolayers of Adenine and Guanine Bases Formed on Inorganic Surfaces. The Journal of Physical Chemistry B, 1998, 102(30): 5914-5922
[16] Ulman A. Self-Assembled Monolayers of 4-Mercaptobiphenyls, Accounts of Chemical Research, 2001, 34(11): 855-863
[17] 杨生荣, 任嗣利, 张俊彦等.自组装单分子膜的结构及其自组装机理. 高等学校化学学报, 2 0 0 1,22, (3): 470-476
[18] 李扬眉,陈志春,何 琳等. 生物大分子自组装膜及其应用研究进展. 化学进展, 2002, 14(3):212-216
[19] 杨学耕,陈慎豪,马厚义等. 金属表面自组装缓蚀功能分子膜. 化学进展, 2003, 15(2): 123-128
[20] Dubios L H, Nuzzo R G. Synthesis, structure and properties of model organic surfaces. Annual Review of Physical Chemistry, 1992, 43: 437-463.
[21] 邓文礼, 杨林静, 王琛等. 烷基硫醇分子自组装研究进展 .科学通报, 1998,43(5):449-457
[22] Nishizawa M, Sunagawa T, Yoneyama H. Underpotential Deposition of Cop-per on Gold Electrodes through Self-Assembled Monolayers of Propanethiol. Langmuir, 1997, 13: 5215-5217
[23] Sung M M , Sung K, Chang G K, et al. Self-Assembled Monolayers of Alkanethiols on Oxidized Copper Surfaces. Journal of Physical Chemistry B, 2000, 104(10): 2273-2277
[24] Ron H, Cohen H, Matlis S, et al. Self-Assembled Monolayers on Oxidized Metals. 4. Superior n-Alkanethiol Monolayers on Copper. The Journal of Physical Chemistry B, 1998, 102(49): 9861-9869
[25] Tao Y T, Hietpas G D, Allara D L. HCl Vapor-Induced Structural Rearrangements of n-Alkanoate Self-Assembled Monolayers on Ambient Silver, Copper, and Aluminum Surfaces. Journal of the American Chemical Society,1996, 118(28): 6724-6735
[26] Zamborini F P, Crooks R M. Corrosion Passivation of Gold by n-Alkanethiol Self-Assembled Monolayers: Effect of Chain Length and End Group. Langmuir, 1998, 14(12): 3279-3286
[27] Wade R. Thompson and Jeanne E. Pemberton Surface Raman Scattering of Self-Assembled Monolayers of (3-Mercaptopropy1) trimethoxysilane on Silver: Orientational Effects of Hydrolysis and Condensation Reactions. Chemistry of Materials, 1993, 5(3):241-244
[28] Saito N, Wu Y, Hayashi K, et al. Principle in Imaging Contrast in Scanning Electron Microscopy for Binary Microstructures Composed of Organosilane Self-Assembled Monolayers. Journal of the American Chemical Society, 2003, 107(3): 664-667
[29] Zhao X l and Kopelman R. Mechanism of Organosilane Self-Assembled Monolayer Formation on Silica Studied by Second-Harmonic Generation. The Journal of Physical Chemistry, 1996, 100(26): 11014 -11018
[30] Brito R, Rodriguez V A, Figueroa J, et al. Adsorption of 3-mercapto-propyltrimethoxysilane and 3-aminopropyltrimethoxy-silane at platinum electrodes. Journal of Electroanalytical Chemistry, 2002, 520(1-2): 47-52
[31] Wang R W, Baran G and Wunder S L, Packing and Thermal Stability of Polyoctadecylsiloxane Compared with Octadecylsilane Monolayers. Langmuir, 2000, 16(15): 6298-6305
[32] Rolando J. Tremont, Daniel R. Blasini, Carlos R. Cabrera Controlled self-assembly of mercapto and silane terminated molecules at Cu surfaces. Journal of Electroanalytical Chemistry, 2003, 556 : 147-158
[33] Thompson W R, Pemberton J E. Characterization of Octadecylsilane and Stearic Acid Layers on Al2O3 Surfaces by Raman Spectroscopy. Langmuir, 1995, 11(5): 1720-1725
[34] Samant M G, Brown C A , Gordon J G. An epitaxial organic film. The self-assembled monolayer of docosanoic acid on silver (111). Langmuir, 1993, 9(4): 1082-1085
[35] Allara D L, Nuzzo R G. Spontaneously organized molecular assemblies. 2. Quantitative infrared spectroscopic determination of equilibrium structures of solution-adsorbed n-alkanoic acids on an oxidized aluminum surface. Langmuir, 1985, 1(1): 52-66
[36] Tao Y T. Structural comparison of self-assembled monolayers of n-alkanoic acids on the surfaces of silver, copper, and aluminum. Journal of the American Chemical Society, 1993, 115(10):4350-4358
[37] Tao Y T, Lee M T, Chang S C. Effect of biphenyl and naphthyl groups on the structure of self-assembled monolayers: packing, orientation, and wetting properties. Journal of the American Chemical Society, 1993, 115(21):9547-9555
[38] Allara D L, Nuzzo R G. Spontaneously organized molecular assemblies. 1. Formation, dynamics, and physical properties of n-alkanoic acids adsorbed from solution on an oxidized aluminum surface. Langmuir, 1985, 1(1):45-51
[39] Aronoff Y G, Chen B, Lu G, et al. Stabilization of Self-Assembled Monolayers of Carboxylic Acids on Native Oxides of Metals. Journal of the American Chemical Society, 1997,119 (2):259-262
[40] Mitsuya M, Sugita N. Chemisorption of Dicarboxylic Acids on an Si(111) Surface and Subsequent Chemical Reactions at the Surface of Adsorbed Molecular Layers. Langmuir, 1997, 13(26): 7075-7079
[41] Lee H, Kepley L J , Hong H G,Mallouk T E. Inorganic analogs of Langmuir-Blodgett films: adsorption of ordered zirconium 1,10-decanebis-phosphonate multilayers on silicon surfaces. Journal of the American Chemical Society, 1988,110 (2):618-620
[42] Yim C T, Pawsey S, Morin F G, et al. Dynamics of Octadecyl-phosphonate Monolayers Self-Assembled on Zirconium Oxide: A Deuterium NMR Study. The Journal of Physical Chemistry B, 2002, 106(7):1728-1733
[43] Yang H C, Aoki K, Hong H G, et al.Growth and characterization of metal (II) alkanebisphosphonate multilayer thin films on gold surfaces. Journal of the American Chemical Society, 1993, 115 (25):11855-11862.
[44] Lee B S, Chi Y S, Lee J K, et al. Imidazolium Ion-Terminated Self-Assembled Monolayers on Au: Effects of Counteranions on Surface Wettability. Journal of the American Chemical Society, 2004 126(2):480-481
[45] Silverman B M, Wieghaus K A, Schwartz J. Comparative Properties of Siloxane vs Phosphonate Monolayers on A Key Titanium Alloy. Langmuir, 2005, 21(1):225-228.
[46] Horne J C, Huang Y, Liu G Y, et al.Correspondence between Layer Morphology and Intralayer Excitation Transport Dynamics in Zirconium-Phosphonate Monolayers. Journal of the American Chemical Society, 1999,121 (18):4419-4426.
[47] Wu A, Talham D R, Photoisomerization of Azobenzene Chromophores in Organic/Inorganic Zirconium Phosphonate Thin Films Prepared Using a Combined Langmuir-Blodgett and Self-Assembled Monolayer Deposition. Langmuir, 2000, 16(19): 7449-7456
[48] Wang X, Lieberman M. Zirconium-phosphonate monolayers with embedded disulfide bonds. Langmuir, 2003, 19(18):7346-7353.
[49] Benitez I O, Bujoli B, Camus L J, et al. Monolayers as Models for Supported Catalysts: Zirconium Phosphonate Films Containing Manganese (III) Porphy-rins. Journal of the American Chemical Society, 2002, 124(16): 4363-4370.
[50] Byrd H, Whipps S, Pike J. Role of the template layer in organizing self-assembled films: zirconium phosphonate monolayers and multilayers at a Langmuir-Blodgett template. Journal of the American Chemical Society, 1994,116 (1):295-301
[51] Cao G, Hong H G, Mallouk T E. Layered metal phosphates and phosphonates: from crystals to monolayers. Accounts of Chemical Research, 1992, 25(9):420-427
[52] Doneux Th, Buess-Herman Cl, Lipkowski J. Electrochemical and FTIR characterization of the self-assembled monolayer of 2-mercapto-benzimi-dazole on Au(111). Journal of Electroanalytical Chemistry, 2004, 564:65-75
[53] Arduengo III A J, Moran J R, Rodriguez-Parada J, et al.Molecular Control of Self-Assembled Monolayer Films of Imidazole-2-thiones: Adsorption and Reactivity. Journal of the American Chemical Society, 1990, 112(16):6153-6154
[54] van Esch J H, Nolte R J M, Ringsdorf H. Monolayers of Chiral Imidazole Amphiphiles: Domain Formation and Metal Complexation. Langmuir, 1994, 10(6):1955-1961
[55] Liu M, Kira A, Nakahara H,et al. Complex formation between monolayers of long-chain imidazole and benzimidazole derivatives and transition metal ions.Thin Solid Films, 1997, 295(1-2): 250-254
[56] Melissa J, David K. A second-harmonic generation study of a corrosion inhibitor on a mild steel electrode. Journal of Electroanalytical Chemistry, 1992, 340(1-2): 301-313
[57] Kong D S, Wan L J, Han M J,et al. Self-assembled monolayer of a Schiff base on Au(111) surface: electrochemistry and electrochemical STM study. Electrochimica Acta, 2002, 48(4):303-309
[58] Pang S f, Li C, Huang J G,et al. Monolayers of novel amphiphile with schiff base moiety as headgroup and its complex of copper (II). Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 178(1): 143-149
[59] Morrin A, Moutloali R M, Killard A J, et al. Electrocatalytic sensor devices: (I)cyclopentadienylnickel(II)thiolato Schiff base monolayer self-assembled on gold. Talanta, 2004, 64(1): 30-38
[60] 孔德生,陈慎豪, 万立骏等. Schiff碱N-aete-N在Au(111)上自组装单分子膜的电化学及STM研究. 高等学校化学学报,2003,24(10): 1847-1851
[61] DiMilla P A, Folkers J P, Biebuyck H A, et al.Wetting and Protein Adsorption of Self-Assmebled Monolayers of Alkane-thiolates Supported on Transparent Films of Gold. Journal of the American Chemical Society, 1994, 116(5): 2225-2226
[62] Laibinis P E, Whitesides G M, Allara D L, et al. Comparison of the Structures and Wetting Properties of Self-Assembled Monolayers of n-Alkanethiols on the Coinage Metal Surfaces, Cu, Ag, Au. Journal of the American Chemical Society, 1991, 113(19):7152-7167
[63] Dick L A, Haes A J, Van Duyne R P. Distance and Orientation Dependence of Heterogeneous Electron Transfer: A Surface-Enhanced Resonance Raman Scattering Study of Cytochrome c Bound to Carboxylic Acid Terminated Alkanethiols Adsorbed on Silver Electrodes.The Journal of Physical Chemistry B, 2000,104 (49):11752-11762
[64] Finklea H O, Hanshew D D. Electron-transfer kinetics in organized thiol monolayers with attached pentaammine (pyridine) ruthenium redox centers. Journal of the American Chemical Society, 1992,114 (9): 3173-3181
[65] Xu J, Li H L, Zhang Y. Relationship between Electronic Tunneling Coeffici-ent and Electrode Potential Investigated Using Self-Assembled Alkanethiol Monolayers on Gold Electrodes. The Journal of Physical Chemistry, 1993, 97(44): 11497-11500
[66] Finklea H O, Ravenscroft M S, Snider D A. Electrolyte and temperature effects on long range electron transfer across self-assembled monolayers. Langmuir, 1993, 9 (1):223-227.
[67] Yamamoto Y, Nishihara H, Aramaki K. Self-Assembled Layers of Alkanethiols on Copper for Protection Against Corrosion. Journal of Elctrochemistry Society, 1993, 140 (2):436-443
[68] laibinis P E, Whitesides G M.Omega.-Terminated alkanethiolate monolayers on surfaces of copper, silver, and gold have similar wettabilities. Journal of the American Chemical Society, 1992, 114(6):1990-1995
[69] Finklea H O, Snider D A, Fedyk J. Passivation of pinholes in octadecanethiol monolayers on gold electrodes by electrochemical polymerization of phenol. Langmuir, 1990, 6(2):371-376.
[70] Sandhyarani N, Pradeep T.An investigation of the structure and properties of layered copperthiolates. Journal of Materials Chemistry, 2001, 11(4):1294-1299
[71] Ron H, Cohen H, Matlis S, et al. Self-assembled monolayers on oxidized metals. 4. Superior n-alkanethiol monolayers on copper.The Journal of Physical Chemistry B, 1998,102 (49):9861-9869
[72] Mekhalif, Z.; Laffineur, F.; Couturier, N.; Delhalle, J.; Elaboration of Self-Assembled Monolayers of n-Alkanethiols on Nickel Polycrystalline Substrates: Time, Concentration, and Solvent Effects. Langmuir, 2003, 19(3): 637-645.
[73] Kudelski A. Chemisorption of 2-Mercaptoethanol on Silver, Copper and Gold: Direct Raman Evidence of Acid-Induced Changes in Adsorption/ Desorption Equilibria. Langmuir, 2003, 19(9): 3805-3813
[74] Sellers H, Ulman A, Shnidman Y, et al.Structure and binding of alkanethiolates on gold and silver surfaces: implications for self-assembled monolayers. Journal of the American Chemical Society, 1993, 115(21): 9389-9401
[75] Ohtsuka T, Sat Y, Uosaki K. Dynamic Ellipsometry of a Self-Assembled Monolayer of a Ferrocenylalkanethiol during Oxidation-Reduction Cycles. Langmuir, 1994, 10 (10):3658-3662
[76] Porter M D, Bright T B, Allara D L, et al. Spontaneously Organized Molecular Assemblies. 4. Structural Characterization of n-Alkyl Thiol Monolayers on Gold by Optical Ellipsometry, Infrared Spectroscopy, and Electrochemistry. Journal of the American Chemical Society, 1987,109 (12): 3559-3568
[77] Joo S W, Han S W, Kim K. Adsorption Characteristics of 1,3-Propanedithiol on Gold: Surface-Enhanced Raman Scattering and Ellipsometry Study. The Journal of Physical Chemistry B, 2000, 104(26):6218-6224
[78] Harke M, Stelzle M, Motschmann H R. Microscopic ellipsometry: imaging on arbitrary reflecting supports. Thin Solid Films,1996, 284-285():412-416
[79] Kang J F, Jordan R, Ulman A. Wetting and Fourier Transform Infrared Spectroscopy tudies of Mixed Self-Assembled Monolayers of4’-Methyl-4-mercaptobiphenyl and 4’-Hydroxy-4-mercap-tobiphenyl. Langmuir, 1998, 14(15):3983-3985
[80] Evans S D, Urankar E, Ulman A,et al.Self-Assembled Monolayers of Alkanethiols Containing a Polar Aromatic Group: Effects of the Dipole Position on Molecular Packing, Orientation, and Surface Wetting Properties. Journal of the American Chemical Society, 1991, 113(11): 4121-4131
[81] Ulman A, Evans S D, Shnidman Y,et al. Concentration-Driven Surface Transition in the Wetting ofMixed Alkanethiol Monolayers on Gold. Journal of the American Chemical Society, 1991, 113(5):1499-1506
[82] Nuzzo R G, Dubois L H, Allara D L. Fundamental studies of microscopic wetting on organic surfaces. 1. Formation and structural characterization of a self-consistent series of polyfunctional organic monolayers. Journal of the American Chemical Society, 1990, 112(2): 558-569
[83] Diao P, Guo M, Tong R. Characterization of defects in the formation process of self-assembled thiol monolayers by electrochemical impedance spectroscopy. Journal of Electroanalytical Chemistry, 2001, 495 (2):98-105
[84] Cui X L, Jiang D L, Diao P, et al.Assessing the apparent effective thickness of alkanethiol self-assembled monolayers in different concentrations of Fe(CN)63-:Fe(CN)6 4-by ac impedance spectroscopy. Journal of Electroanalytical Chemistry, 1999, 470(1): 9-13
[85] Janek R P and Fawcett W R. Impedance Spectroscopy of Self-Assembled Monolayers on Au(111): Evidence for Complex Double-Layer Structure in Aqueous NaClO4 at the Potential of Zero Charge.The Journal of Physical Chemistry B, 1997, 101(42): 8550-8558
[86] Boubour E and Lennox R B. Potential-Induced Defects in n-Alkanethiol Self-Assembled Monolayers Monitored by Impedance Spectroscopy. The Journal of Physical ChemistryB, 2000, 104 (38):9004-9010
[87] Finklea H O, Snider D A, Fedyk J. Characterization of Octadecanethiol-Coated Gold Electrodes as Microarray Electrodes by Cyclic Voltammetry and ac Impedance Spectroscopy. Langmuir, 1993,9(12):3660-3667
[88] 程志亮, 杨秀荣. 电化学交流阻抗技术表征自组装多层膜. 分析化学, 2001, 29(1):6-10
[89] Chidsey C E D, Loiacono D N. Chemical functionality in self-assembled monolayers: structural and electrochemical properties. Langmuir, 1990, 6(3):682-691.
[90] Krysinski P, Brzostowska-Smolska M. Capacitance characteristics of self-assembled monolayers on gold electrode. Bioelectrochemistry and Bioenrgytics, 1998, 44(2):163-168
[91] Ekeroth J and Konradsson P. Monitoring the interfacial capacitance at self-assembled phosphate monolayers on gold electrodes upon interaction with calcium and magnesium. Analytical Chemistry, 2002, 74(9):1979-1985
[92] Kakiuchi T, Iida M, Imabayashi S. Double-layer-capacitance titration of self-assembled monolayers of ω-functionalized alkanethiols on Au(111) surface. Langmuir, 2000, 16(12):5397-5401
[93] Nishiyama K, Tahara S, Uchida Y. Structural differences in self-assembled monolayers of anthraquinone derivatives on silver and gold electrodes studied by cyclic voltammetry and in situ SERS spectroscopy. Journal of Electroanalytical Chemistry, 1999, 478 (1-2):83-91
[94] 傅崇岗, 苏昌华, 单瑞峰. 半胱氨酸自组装膜修饰金电极的电化学特性. 物理化学学报,2004, 20(2):207-210
[95] Wirde M and Gelius U. Self-sssembled monolayers of cystamine and cysteamine on gold studied by XPS and voltammetry. Langmuir, 1999, 15(19):6370-6378
[96] Brito R, Tremont R, Cabrera C R. Electron transfer kinetics across derivatized self-assembled monolayers on platinum: a cyclic voltammetry and electroche-mical impedance spectroscopy study. Journal of Electroanalytical Chemistry, 2004, 574(1): 15-22
[97] Che G; Li Z; Zhang H,et al.Voltammetry of defect sites at a self-assembled monolayer on a gold surface. Journal of Electroanalytical Chemistry, 1998, 453(1-2):9-17
[98] Diao P, Jiang D, Cui X, et al. Studies of structural disorder of self-assembled thiol monolayers on gold by cyclic voltammetry and ac impedance. Journal of Electroanalytical Chemistry, 1999, 464(1):61-67
[99] Gothelf K V. Self-assembled monolayers of long-chain xanthic acids on gold studied by voltammetry. Journal of Electroanalytical Chemistry, 2000, 494 (2):147-150
[100] Ion A, Partali V, Sliwka H, et al. Electrochemistry of a carotenoid self-assembled monolayer. Electrochemistry Communications, 2002, 4(9): 674-678
[101] Arias Z G, álvarez J L M, and Fonseca J M L. Electrochemical chara-cterization of a mixed self-assembled monolayer of 6-thioguanine and guanine on a mercury electrode. Journal of Colloid and Interface Science, 2004, 276(1):132-137
[102] Muskal N, Mandler D. Thiol self-assembled monolayers on mercury surfaces: the adsorption and electrochemistry of v-mercaptoalkanoic acids. Electrochi-mica Acta, 1999, 45 (4-5): 537-548
[103] Flink S, Boukamp B A, van den Berg A. Electrochemical Detection of Electrochemically Inactive Cations by Self-Assembled Monolayers of Crown Ethers. Journal of the American Chemical Society, 1998, 120(19): 4652-4657
[104] Yu H Z, Wang Y Q, Cheng J Z, et al. Electrochemical Behavior of Azobenz-ene Self-Assembled Monolayers on Gold. Langmuir, 1996, 12(11): 2843-2848
[105] Beulen M W J, Kastenberg M I, van Veggel F C J M, et al. Electrochemical Stability of Self-Assembled Monolayers on Gold. Langmuir, 1998, 14(26):7463-7467
[106] Hu K, Chai Z, Whitesell J K, et al. In situ monitoring of diffuse double layer structure changes of electrochemically addressable self-assembled monolayers with an atomic force microscope. Langmuir, 1999, 15(9):3343-3347
[107] Chidsey C E D and Loiacono D N. Chemical functionality in self -assembled monolayers: structural and electrochemical properties. Langmuir, 1990, 6(3):682-691
[108] Han S W, Ha T H, Kim C H,et al. Self-Assembly of Anthraquinone -2-carboxylic Acid on Silver: Fourier Transform Infrared Spectroscopy, Ellipsometry, Quartz Crystal Microbalance, and Atomic Force Microscopy Study. Langmuir, 1998, 14 (21):6113-6120
[109] Nakano K, Sato T, Tazaki M,et al. Self-assembled monolayer formation from decaneselenol on polycrystalline gold as characterized by electrochemical measurements, quartz-crystal microbalance, XPS, and IR Spectroscopy. Langmuir, 2000, 16(5): 2225-2229
[111] Viana A S, Kalaji M, and Abrantes L M. Electrochemical quartz crystal microbalance study of self-assembled monolayers and multilayers of ferrocenylthiol derivatives on gold. Langmuir, 2003, 19(22):9542-9544
[112] Schneider T W and Buttry D A. Electrochemical quartz crystal microbalance studies of adsorption and desorption of self-assembled monolayers of alkyl thiols on gold. Journal of the American Chemical Society, 1993,115 (26):12391-12397
[113] Sugihara K and Shimazu K. Electrode potential effect on the surface pKa of a self-assembled 15-mercaptohexadecanoic acid monolayer on a gold/quartz crystal microbalance electrode. Langmuir, 2000, 16(18): 7101-7105
[114] Jan R, Tilo W, Wolfgang K, et al.A new affinity biosensor: Self-assembled thiols as selective monolayer coatings of quartz crystal microbalances. Biosensors and Bioelectronics, 1996, 11(6-7): 591-598
[115] Ebara Y and Okahata Y. A kinetic study of concanavalin a binding to glycolipid monolayers by using a quartz-crystal microbalance. Journal of the American Chemical Society, 1994,116 (25):11209-11212
[116] Liao S, Shnidman Y, and Ulman A. Adsorption kinetics of rigid 4-mercaptobiphenyls on gold. Journal of the American Chemical Society, 2000, 122(15): 3688-3694
[117] Eisert F, Dannenberger O, and Buck M. Molecular orientation determined by second-harmonic generation: Self-assembled monolayers. Physical Review B, 1998, 58(16):10860-10870
[118] Zhao X and Kopelman R. Mechanism of organosilane self-assembled monolayer formation on silica studied by second-harmonic generation.The Journal of Physical Chemistry, 1996, 100(26): 11014-11018
[119] Mania A A, Schultzb Z D, Champagnec B, et al.Molecule orientation in self-assembled monolayers determined by infrared-visible sum-frequency generation spectroscopy.Applied Surfuce Science, 2004,237(1-4):444-449
[120] Lagutchev A S, Song K J, Huang J Y. et al. Self-assembly of alkylsiloxane monolayers on fused silica studied by XPS and sum frequency generation spectroscopy. Chemical Physics, 1998, 226(3): 337-349
[121] Ye S, Nihonyanagi S and Uosaki K. Sum frequency generation (SFG) study of the pH-dependent water structure on a fused quartz surface modied by anoctadecyltrichlorosilane (OTS) monolayer. Physical Chemistry and Chemical Physics, 2001, 3(13):3463-3469
[122] Zolk M, Eisert F, Pipper J. Solvation of oligo(ethylene glycol)-terminated self-assembled monolayers studied by vibrational sum frequency spectroscopy. Langmuir, 2000, 16(14): 5849-5852
[123] Whelan C M, Smyth M R, Barnes C J,et al.An XPS study of heterocyclic thiol self-assembly on Au 111. Applied Surface Science, 1998 , 134(1-4):144–158
[124] Noh J, Ito E, Nakajima K,et al. High-resolution STM and XPS studies of thiophene self-Assembled monolayers on Au (111). The Journal of Physical Chemistry B, 2002, 106(26):7139-7141
[125] Sinapi F, Delhalle J, Mekhalif Z. XPS and electrochemical evaluation of two-dimensional organic films obtained by chemical modification of self-assembled monolayers of (3-mercaptopropyl) trimethoxysilane on copper surfaces. Materials Science and Engineering C, 2002, 22(2):345-353
[126] Wang Y, Yu Q, Zhang Y,et al. Self-assembled monolayers of 3-MPT and its mixed-monolayers with alkanethiol on silver: studies by XPSand electrochemical methods. Applied Surface Science, 2004, 229 (1-4):377-386
[127] Hutt D A, Cooper E, Leggett G J. Structure and mechanism of photooxidation of self-assembled monolayers of alkylthiols on silver studied by XPS and static SIMS. The Journal of Physical Chemistry B, 1998, 102(1): 174-184
[128] 张 祺, 黄惠忠, 何会新等.角分辨XPS 对自组装单分子层厚度和官能团位置的定性及定量研究. 化学物理学报,1997, 10(3):201-204
[129] Whitesides G M, Laibinis P E. Wet chemical approaches to the characterization of organic surfaces: self-assembled monolayers, wetting, and the physical-organic chemistry of the solid-liquid interface. Langmuir, 1990, 6(1):87-96.
[130] Lee J, Lee J, and Yates J T. Comparison of Methanethiol Adsorption on Ag (110) and Cu(110)s Chemical Issues Related to Self-Assembled Monolayers. The Journal of Physical Chemistry B, 2004, 108(5): 1686-1693
[131] Azzaroni O, Vela E, Fonticelli M, et al.Electrodesorption potentials of self-assembled alkanethiolate monolayers on copper electrodes. An experimental and theoretical study. The Journal of Physical Chemistry B, 2003,107 (48): 13446-13454
[132] Kondoh H and Nozoye H. Effects of electron irradiation on methylthiolate monolayer on Au (111): electron-stimulated desorption. The Journal of Physical Chemistry B, 1998, 102(13):2367-2372
[133] Hayes W A, Kim H, Yue X, et al. Nanometer-scale patterning of surfaces using self-assembly chemistry. 2. Preparation, characterization, and electrochemical behavior of two-component organothiol monolayers on gold surfaces. Langmuir, 1997, 13(10): 2511-2518
[134] 李 斌,曾长淦,李群祥等. Au(111)表面自组装硫醇单分子膜的STM成像机理. 电子显微学报,2003, 22(3):189-193
[135] Giancarlo L C, Fang H, Rubin S M, et al.Influence of the substrate on order and image contrast for physisorbed, self-assembled molecular monolayers: STM studies of functionalized hydrocarbons on graphite and MoS2. The Journal of Physical Chemistry B, 1998, 102(50):10255-10263
[136] Schuurmans N, Uji-i H, Mamdouh W, et al. Design and STM Investigation of intramolecular folding in self-assembled monolayers on the surface. Journal of the American Chemical Society, 2004, 126(43): 13884-13885
[137] Hartwich J, Sundermann M, Kleineberg U, et al.STM writing of artificial nanostructures in alkanethiol-type self-assembled monolayers. Applied Surface Science, 1999, 144–145:538-542
[138] Kong D, Yuan S, Sun Y,et al. Self-assembled monolayer of o-aminothiop-henol on Fe(110)surface: a combined study by electrochemistry, in situ STM, and molecular simulations.Surfuce Science, 2004, 573(2):272-283
[139] Giz M J, Duong B, Tao N J. In situ STM study of self-assembled mercap-topropionic acid monolayers for electrochemical detection of dopamine. Journal of Electroanalytical Chemistry, 1999, 465(1):72-79
[140] Klein H, Battaglini N, Bellini B, et al. STM of mixed alkylthiol self-assembled monolayers on Au 111. Materials Science and Engineering C, 2002, 19(l-2):279-283
[141] Sawaguchi T, Sato Y, Mizutani F. In situ STM imaging of individual molecules in two-component self-assembled monolayers of 3-mercaptop-ropionic acid and 1-decanethiol on Au(111). Journal of Electroanalytical Chemistry, 2001, 496 (l-2):50-60
[142] Resch R, Grasserbauer M, Friedbacher G, et al. In situ and ex situ AFM investigation of the formation of octadecylsiloxane monolayers. Applied Surface Science, 1999, 140(1-2): 168-175
[143] 董飒英,王洪仁,罗国安.自组装金电极的电化学测试及其FTIR和A FM.分析分析科学学报,2002,18(5):357—360
[144] Nakasa A, Akiba U, Fujihira M. Self-assembled monolayers containing biphenyl derivatives as challenge for nc-AFM. Applied Surface Science, 2000,157 (4):326-331
[145] Uchihashi T, Ishida T,Komiyama M, et al.High-resolution imaging of organic monolayers using noncontact AFM. Applied Surface Science, 2000, 157(4) :244-250
[146] Li Y J, Tero R, Nagasawa T. Deposition of 10-undecenoic acid self-assembled layers on H-Si (111) surfaces studied with AFM and FT-IR.
Applied Surface Science, 2004,238 (1-4):238-241
[147] Wold D J. and Frisbie C D. Formation of metal-molecule-metal tunnel junctions: microcontacts to alkanethiol monolayers with a conducting AFM Tip. Journal of the American Chemical Society, 2000, 122(12): 2970-2971
[148] Vallant T, Brunner H, Mayer U, et al.Formation of self-assembled octadecylsiloxane monolayers on mica and silicon surfaces studied by atomic force microscopy and infrared spectroscopy. The Journal of Physical Chemistry B, 1998, 102(37):7190-7197
[149] Doudevski I and Schwartz D K. Mechanisms of self-assembled monolayer desorption determined using in situ atomic force microscopy. Langmuir, 2000, 16(24):9381-9384
[150] Wei Z Q, Wang C, Zhu CF, et al. Study on single-bond interaction between amino-terminated organosilane self-assembled monolayers by atomic force microscopy. Surfuce Science, 2000, 459 (3): 401-412
[151] Okabe Y, Akiba U, Fujihira M. Chemical force microscopy of CH and COOH terminalgroups in mixed self-assembled monolayers by pulsed-force -mode atomic force microscopy. Applied Surface Science, 2000, 157(4):398-404
[152] Himmelhaus M, Gauss I, Buck M, et al. Eisert F, et al. Adsorption of docosanethiol from solution on polycrystalline silver surfaces: an XPS and NEXAFS study. Journal of Electron Spectroscopy and Related Phenamena, 1998, 92(1-3):139-149
[153] Rieley H, Price N J, White R G, et al. A NEXAFS and UPS study of thiol monolayers self-assembled on gold. Surface Science, 1995, 331-333(1):189-195
[154] La Y, Jung Y J, Kang T H, et al. NEXAFS Studies on the Soft X-ray Induced Chemical Transformation of a 4-Nitrobenzaldimine Monolayer. Langmuir, 2003, 19(23):9984-9987
[155] Genzer J, Efimenko K, and Fischer D A .Molecular orientation and grafting density in semifluorinated self-assembled monolayers of mono-, di-,and trichloro silanes on silica substrates. Langmuir, 2002, 18(6): 9307-9311
[156] Parent Ph., Laffon C, and Tourillon G. Adsorption of acrylonitrile on Pt(ll1) and Au(ll1) at 95 K in the monolayer and multilayer ranges studied by NEXAFS, UPS, and FT-IR. The Journal of Physical Chemistry, 1995, 99(14):5058-5066
[157] Kondoh H, Nambu A, Ehara Y, et al. Substrate dependence of self-assembly of alkanethiol: X-ray absorption fine structure study. The Journal of Physical Chemistry B, 2004, 108(34):12946-12954
[158] Yan C, Golzhauser A, and Grunze M, et al. Formation of alkanethiolate self-assembled monolayers on oxidized gold surfaces. Langmuir, 1999, 15(7):2414-2419
[159] Stahl U, Gador D, Soukopp A, et al. Coverage-dependent superstructures in chemisorbed NTCDA monolayers: a combined LEED and STM study. Surfuce Science, 1998, 414(3): 423–434
[160] Bardi U, Magnanelli S, and Rovida G. LEED Study of benzene and naphthalene monolayers adsorbed on the basal plane of graphite. Langmuir, 1987, 3(2):159-163
[161] Himmel H J, Woll Ch., Gerlach R,et al. Structure of heptanethiolate monolayers on Au(111): adsorption from Solution vs vapor deposition. Langmuir, 1997, 13(4):602-605
[162] Strong L, Whitesides G M. Structures of self-assembled monolayer films of organosulfur compounds adsorbed on gold single crystals: electron diffraction studies. Langmuir, 1988, 4(3): 546-558.
[163] Hutta D A and Leggett G J. Static secondary ion mass spectrometry studies of self-assembled monolayers: electron beam degradation of alkanethiols on gold. Journal of Materials Chemistry, 1999, 9(4): 923-928
[164] Offord D A, John C M, Linford M R, et al. Contact angle goniometry, ellipsometry, and time-of-flight secondary ion mass spectrometry of gold supported, mixed self -assembled monolayers formed from alkyl mercaptans. Langmuir, 1994, 10(3):883-889
[165] Frisbie C D, Martin J R, Jr. Duff R R, et al. Use of high lateral resolution secondary ion mass spectrometry to characterize self-assembled monolayers on microfabricated structures. Journal of the American Chemical Society, 1992, 114(18):7142-7145
[166] Shimoyama Y. Growth process of poly (3-dodecyl thiophene) self-assembled monolayers: FTIR-RAS and gravimetric studies. Thin Solid Films, 2004, 464–465:403-407
[167] Doneux Th., Buess-Herman Cl, Lipkowski J. Electrochemical and FTIR characterization of the self-assembled monolayer of 2-mercapto-benzimidazole on Au(111). Journal of Electroanalytical Chemistry, 2004, 564: 65-75
[168] Zhang J, Zhao J,Zhang H L, et al. Structural evaluation of azobenzene-functionalized self-assembled monolayers on gold by reflectance FTIR spectroscopy. Chemical Physics Letters, 1997, 271(1-3):90-94
[169] Mielczarski J A and Mielczarski E. Determination of molecular orientation and thickness of self-assembled monolayers of oleate on apatite by FTIR reflection spectroscopy. The Journal of Physical Chemistry, 1995, 99(10):3206-3217
[170] Yu H Z, Ye S, Zhang H L, et al.Molecular Orientation and electrochemical stability of azobenzene self-assembled monolayers on gold: an in-situ FTIR study. Langmuir, 2000, 16(17): 6948-6954
[171] Han H S, Han S W, Kim C H, et al.Adsorption and reaction of 4-nitrobenzoic acid on ω-functionalized alkanethiol monolayers on powdered silver: infrared and Raman Spectroscopy study.Langmuir, 2000, 16(3):1149-1157
[172] Elmore D L, Chase D B, Liu Y, et al. Infrared spectroscopy and spectroscopic imaging of n-propyl trichlorosilane monolayer films self-assembled on glass substrates. Vibrational Spectroscopy, 2004, 34 (1):37-45
[173] Mielczarski J A and Mielczarski E. Infrared external reflection spectroscopy of adsorbed monolayers in a region of strong absorption of substrate. The Journal of Physical Chemistry B, 1999, 103(28): 5852-5859
[174] Tao Y T and Lin W L. Infrared spectroscopic study of chemically induced dewetting in liquid crystalline types of self-assembled monolayers. The Journal of Physical Chemistry B, 1997, 101(47): 9732-9740
[175] Zhang Z J, Yoshida N, Imae T. Self-assembled monolayer of an alkanoic acid-derivatized porphyrin on gold surface: a structural investigation by surface plasmon resonance, ultraviolet–visible, and infrared spectroscopies. Journal of Colloid and Interface Science, 2001,243(2): 382-387
[176] Mihailova B, Engstrom V, Hedlund J,et al. Infrared spectroscopic study of a c-mercaptopropyltrimethoxysilane monolayer on a gold surface. Journal of Materials Chemistry, 1999, 9(7): 1507-1510
[177] a. Raman C V and Krishman K S A new type of secondary radiation. Nature, 1928, 121(3048):501-502, b. Raman C V A. change of wavelength in light scattering. Nature,1928,121(3049): 619-620
[178] Raman C V. A new radiation. Indian Journal of Physics, 1928, 2():387-398.
[179] 潘家来编. 激光拉曼光谱在有机化学上的应用,北京:化学工业出版社,1986
[180] 朱自莹,顾仁敖,陆天虹. 拉曼光谱在化学中的应用. 沈阳:东北大学出版社,1998
[181] 田中群,任斌,吴德印等. 激光拉曼光谱研究电化学界面的新进展. 厦门大学学报(自然科学版),2001, 40(2):134-147
[182] Fleischmann M, Hendra P J, Mcquillan A J. Raman spectraof pyridine adsor-bed at a silver electrode.Chemical Physics Letters,1974, 26(2):163-166.
[183] Jeanmaire D L, Van Duyne R P. Surface Raman pectroelectrochemistry, Part I: Heterocyclic, aromaticandamines adsorbed on the anodized silver electrode. Journal of Electroanalytical Chemistry, 1977, 84(1):1-20.
[184] Nie S, Emory S R. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science, 1997, 275(5303):1102-1106.
[185] Kneipp K, Wang Y, Kneipp H,et al. Single molecule detection using surface-enhanced Raman scattering(SERS). Physical Review Letters, 1997, 78(9): 1667-1670.
[186] 武建劳,郇宜贤, 傅克德等. 表面增强拉曼散射概述. 光散射学报, 1994, 6(1):52-62
[187] 武建劳. 郇宜贤. 傅克德等. 表面增强拉曼散射概述. 光散射学报, 1994, 6(2):109-118
[188] Creighton, J. In Spectroscoopy of Surface; Clark R., Hestere R., Eds.; London: John Willey & Sons Ltd., 1988: 37
[189] Weaver M J, Zou S Z, Chan H Y H. The new interfacial ubiquity of surface-enhanced Raman spectroscopy. Analytical Chemistry, 2000, 72 (1): 38A-47A
[190] Tian, Z Q, Ren B, Wu D Y. Surface-enhanced Raman scattering: from noble to transition metals and from Rough surfaces to ordered nanostructures. The Journal of Physical Chemistry B, 2002, 106(37): 9463-9483
[191] Gu R A, Shen X Y, Liu G K,et al. Surface-Enhanced Raman Scattering from Bare Zn Electrode. The Journal of Physical Chemistry B, 2004, 108(45):17519-17522
[192] Schoenfisch M H and Pemberton J E. Effects of electrolyte and potential on the in situ structure of alkanethiol self-assembled monolayers on silver. Langmuir, 1999, 15(2): 509-517
[193] Kim J H, Cotton T M, and Uphaus R A. Electrochemical and Raman characterization of molecular recognition sites in self-assembled monolayers. The Journal of Physical Chemistry, 1988, 92(20):5575-5578
[194] Kudelski A. Chemisorption of 2-mercaptoethanol on silver, copper, and gold: direct Raman evidence of acid-induced changes in adsorption/desorption equilibria. Langmuir, 2003, 19(9): 3805-3813
[195] Bryant M A and Pemberton J E. Surface Raman scattering of self-assembled monolayers formed from 1-alkanethiols at Ag. Journal of the American Chemical Society, 1991, 113 (10):3629-3636
[196] Caldwell W B, Campbell D J, Chen K. A highly ordered self-assembled monolayer film of an azobenzenealkanethiol on Au(111): electrochemical properties and structural characterization by synchrotron in-plane X-ray diffraction, atomic force microscopy, and surface-enhanced Raman spectroscopy. Journal of the American Chemical Society, 1995,117 (22): 6071-6082
[197] Kudelski A and Hill W. Raman study on the structure of cysteamine mono-layers on silver. Langmuir, 1999, 15(9): 3162-3168
[198] Bryant M A, Joa S L, and Pemberton J E. Raman scattering from monolayer films of thiophenol and 4-mercaptopyridine at Pt surfaces. Langmuir, 1992, 8(3):753-756
[199] Culha M, Stokes D, Allain L R,et al. Surface-enhanced Raman scattering substrate based on a self-assembled monolayer for use in gene diagnostics. Analytical Chemistry, 2003, 75(22):6196-6201
[200] Murgida D H,Hildebrandt P Electron-Transfer Processes of Cytochrome c at Interfaces.New Insights by Surface-Enhanced Resonance Raman Spectrosc-opy. Accounts of Chemical Research, 2004, 37(11): 854-861
[201] Maoee T, Li S. Surface-enhanced Raman scattering from functionalized self-assembled monolayers Part 1. Distance dependence of enhanced Raman scattering from a terminal phenyl group. Analytical Chimica Acta, 1995, 307(2-3):333-340
[202] Yu H Z, Zhang J, Zhang H L, et al. Surface-enhanced Raman scattering (SERS) from azobenzene self-assembled “sandwiches”. Langmuir, 1999, 15(1):16-19
[203] Jiang C, Zhao J, Therese H A, et al. Raman imaging and spectroscopy of heterogeneous individual carbon nanotubes. The Journal of Physical Chemistry B, 2003, 107(34):8742-8745
[204] RayIII K and McCreery R L. Spatially resolved Raman spectroscopy of carbon electrode surfaces: observations of structural and chemical heterogeneity. Analytical Chemistry, 1997, 69(22):4680-4687
[205] Balss K M, Kuo T C and Bohn P W. Direct chemical mapping of elect-rochemically generated patial composition gradients on thin gold films with surface-enhanced Raman spectroscopy. The Journal of Physical Chemistry B, 2003, 107(4):994-1000
[206] Lee C J, Pezzotti G, Okui Y, et al.Raman microprobe mapping of residual microstresses in 3C-SiC film epitaxial lateral grown on patterned Si(111). Applied Surface Science, 2004, 228(1-4):10-16
[207] Aroca R F and Constantino C J L. Surface-enhanced Raman scattering: imaging and mapping of Langmuir-Blodgett monolayers physically adsorbed onto silver island films. Langmuir, 2000, 16(12):5425-5429
[208] Yang X M, Tryk D A, Ajito K, et al. Surface-enhanced Raman scattering imaging of photopatterned self-assembled monolayers. Langmuir, 1996, 12(23):5525-5527
[209] Zhu T, Yu H Z, Wang J,et al. Two-dimensional surface enhanced Raman mapping of differently prepared gold substrates with an azobenzene self-assembled monolayer. Chemical Physics Letters, 1997, 265 (3-5):334-340
[210] Pople J A, Segal G A. Approximate self-consistent molecular orbital theory. III. CNDO results for AB2 and AB3 systems. Journal of Chemical Physics, 1966, 44(9):3289-96
[211] Pople J A, Segal G A. Approximate self-consistent molecular orbital theory. II. Calculations with complete neglect of differential overlap. Journal of Chemical Physics, 1965, 43(10; Pt. 2): S136-S149, discussion: S150-S151
[212] Pople J A, Santry D P, Segal G A. Approximate self-consistent molecular orbital theory. I. Invariant procedures. Journal of Chemical Physics, 1965, 43(10; Pt. 2): S129-S135
[213] Pople J A, Beveridge D L, Dobosh P A. Approximate self-consistent molecular-orbital theory. V. Intermediate neglect of differential overlap. Journal of Chemical Physics, 1967, 47(6):2026-2033
[214] Stewart J J P. Optimization of parameters for semiempirical methods I. Method. Journal of Computational Chemistry, 1989, 10(2):209-220
[215] Stewart J J P. Optimization of parameters for semiempirical methods II. Applications. Journal of Computational Chemistry, 1989, 10(2): 221-264
[216] Coolidge M B, Marlin J E, Stewart J J P. Calculations of molecular vibrational frequencies using semiempirical methods. Journal of Computational Chemistry, 1991, 12(8): 948-952
[217] Becke A D. Density-functional exchange-energy approximation with correct asymptotic behavior. Physical Review A, 1988, 38 (6): 3098-3100
[218] Korolevich M V, Zhbankov R G. Theoretical vibrational spectroscopy and the structure of nitrosubstituted glucopyranosides. Journal of Molecular Structure, 2000, 556(1-3): 157-172
[219] Mroginski M A, Nemeth K, Magdo I, et al. Calculation of the vibrational spectra of linear tetrapyrroles. 2. Resonance Raman spectra of hexamethylpyrromethene monomers. The Journal of Physical Chemistry B, 2000, 104(46): 10885-10899.
[220] El-Azhary A A, Suter H U, Kubelka J. Experimental and theoretical investigation of the geometry and vibrational frequencies of 1,2,3-triazole, 1,2,4-triazole, and tetrazole anions. The Journal of Physical Chemistry A, 1998,102(3): 620-629.
[221] Chen S P, Hosten C M, Vivoni A, Birke R L, et al. SERS investigation of NAD+ adsorbed on a silver electrode. Langmuir, 2002, 18(25): 9888-9900
[222] Cinta S, Morari C, Vogel E, et al.Vibrational studies of B6 vitamin. Vibrat-ional Spectroscopy, 1999, 19(2): 329-334
[223] Bernd S, Peter F, Siegfried S. The assignment of the vibrations of substituted mercaptotetrazoles based on quantum chemical calculations. Journal of Molecular Structure, 1999, 482-483(): 231-235
[224] Hideaki S, Yoshihiro Y, Koichi O, Raman spectra of polycyclic aromatic hydrocarbons. Comparison of calculated Raman intensity distributions with observed spectra for naphthalene, anthracene, pyrene, and perylene. Journal of Molecular Structure, 1998, 442(1-3): 221-234
[225] Foley M S C, Braden D A, Hudson B S, et al. Ab initio and resonance Raman studies of hexafluoro-1,3-butadiene. The Journal of Physical Chemistry A, 1997, 101(8): 1455-1459.
[226] Wu D Y, Hayashi M, Shiu Y J, et al. A quantum chemical study of bonding interaction, vibrational frequencies, force constants, and vibrational coupling of pyridine-Mn (M = Cu, Ag, Au; n = 2-4). The Journal of Physical Chemistry A, 2003, 107(45): 9658-9667
[227] Bockris J, Khan S, Surface Electrochemistry: A Molecular Level Approach, New York:Plenum Pub. Corp. 1993
[228] Beek J, Deng H, Callander R, et al. Vibrational analysis of NADH cofactors bound to glycerol-3-phosphate dehydrogenase and dogfish lactate dehydrogenase. Journal of Raman Spectroscopy, 2002, 83 (5): 397-403
[229] Koglin E, Sequaris J M, Valenta P. Surface Raman spectra of nucleic acid components adsorbed at a silver electrode. Journal of Molecular Structure, 1980, 60(): 421-425
[230] Watanabe T, Kawanami O, Katoh H, et al. SERS study of molecular adsorp-tion: Some nucleic acid bases on Ag electrodes. Surfure Science, 1985, 158 (1-3):341-351.
[231] Otto C, Mul F, Huizinga A, et al. Surface enhanced Raman scattering of derivatives of adenine: the importance of the external amino group in adenine for surface binding. The Journal of Physical Chemistry, 1988, 92 (5): 1239-1244
[232] Taniguchi I, Umekita K, Yasukouchi K. Surface-enhanced Raman scattering of nicotinamide adenine dinucleotide (NAD+) adsorbed on silver and gold electrodes. Journal of Electroanalytical Chemistry, 1986,202 (1-2): 315-322
[233] Siiman O, Rivellini R., Patel R., Orientation and conformation of NAD and NADH adsorbed on colloidal silver, Inorganic Chemistry, 1988,27(22): 3940-3949
[234] Cotton T., in: Clark R, Hestere R (Eds.), Spectroscopy of Surface, John Willey & Sons Ltd, London, 1988, p. 121.
[235] Liu J, Fryxell G E, Qian M, et al. Interfacial chemistry in self-assembled nanoscale materials with structural orderin. Pure and Applied Chemistry, 2000, 72 (1-2): 269-279
[236] Nakamura C, Inuyama Y, Shirai K, et al. Detection of porphyrin using a short peptide immobilized on a surface plasmon resonance sensor chip. Biosensors and Bioelectrics, 2001, 16 (9-12) :1095-1100
[237] Zhang X H, Wang S F. Voltammtric behavior of noradrenaline at 2-mercapt-oethanol self-assembled monolayer modified gold electrode and its analytical application. Sensors,2003,3 (3): 61-68
[238] Nadolny G, Zundel G. Protonation, conformation and hydrogen bonding of nicotinamide adenine dinucleotide — an FT-IR study. Journal of Molecular Structure,1996, 385 (2): 81-87
[239] Austin J, Hester R, Surface-enhanced Raman Spectroscopy of NAD+ and related compounds. Journal of the Chemical Society-Faraday Transactions 1, 1989, 85(5):1159-1168
[240] Xiao Y, Wang T, Wang X,et al. Surface-enhanced near-infrared Raman spectroscopy of nicotinamide adenine dinucleotides on a gold electrode. Journal of Electroanalytical Chemistry, 1997,433 (1-2): 49-57.
[241] Suh J, Moskovits M.Surface-enhanced Raman spectroscopy of amino acids and nucleotide bases adsorbed on silver. Journal of the American Chemical Society, 1986,108 (16): 4711-4718
[242] Xiao Y, Gao X, Markwell J. In-situ monitoring of the interaction of lactate dehydrogenase with NAD on a gold electrode by FT-SERS. Journal of Electroanalytical Chemistry, 1999, 465 (2):187-194
[243] Chen H, Long Y. Study of biomolecules by combining electrochemistry with UV/Vis, IR and surface enhanced Raman scattering spectroscopy by a novel flow microcell. Analytical Chimica Acta, 1999, 382 (1-2):171-177
[244] Jensen M, Elving P. Nicotinamide adenine dinucleotide (NAD+). Formal potential of the NAD+/NAD· couple and NAD· dimerization rate. Biochimica Et Biophysica Acta, 1984, 764(3): 310-315
[245] Persson B, Gorton L. A chemically modified graphite electrode for electroc-atalytic oxidation of reduced nicotinamide adenine dinucleotide based on a phenothiazine derivative, 3-β-naphthoyl-toluidine blue O. Journal of Electroanalytical Chemistry, 1990, 287 (1): 61-80
[246] Schmakel C, Santhanam K, Elving P. Nicotinamide adenine dinucleotide (NAD+) and related compounds. Electrochemical redox pattern and allied chemical behavior. Journal of the American Chemical Society, 1975, 97(18):5083-5092
[247] Tang H, Hajizadeh K, Halsall H, et al. Flow-injection analysis with electr-ochemical detection of reduced nicotinamide adenine dinucleotide using 2, 6-dichloroindophenol as a redox coupling agent. Analytical Biochemistry, 1991, 192(1): 243-250.
[248] Sampath S, Lev O. Electrochemical oxidation of NADH on sol–gel derived, surface renewable, non-modified and mediator modified composite-carbon electrodes. Journal of Electroanalytical Chemistry, 1998, 446(1-2): 57-65
[249] Subramanian R, lakshminarayanan V. Effect of adsorption of some azoles on copper passivation in alkaline medium. Corrosion Science, 2002, 44(3): 535-554
[250] Truc T A, Pébère N, Hang T T X, et al. Study of the synergistic effect observed for the corrosion protection of a carbon steel by an association of phosphates. Corrosion Science, 2002, 44: 2055-2071
[251] Notoya T, Otieno-alego V, Schweinsberg D. The corrosion and polarization behaviour of copper in domestic water in the presence of Ca, Mg and Na-Salts of phytic acid. Corrosion Science, 1995, 37(1): 55-65
[252] Cao P, Gu R, Tian Z. Electrochemical and surface-enhanced Raman spectr-oscopy studies on inhibition of iron corrosion by benzotriazole. Langmuir, 2002, 18(20): 7609-7615
[253] Bentiss, F, Traisnel M, Vezin H, et al. Electrochemical study of substituted triazoles adsorption on mild steel. Industrial and Engineering Chemistry Research, 2000, 39(10): 3732-3736
[254] Tan J, Bailey S, Kinsella B. An investigation of the formation and destruction of corrosion inhibitor films using electrochemical impedance spectroscopy (EIS). Corrosion Science, 1996, 38(9): 1545-1561
[255] Manov S, Lamazouere A, ArieA? L. Electrochemical study of the corrosion behaviour of zinc treated with a new organic chelating inhibitor. Corrosion Science, 2000, 42(7): 1235-1248
[256] Marconato J, Bulhoes L, Temperini M. A spectroelectrochemical study of the inhibition of the electrode process on copper by 2-mercapto-benzothiazole in ethanolic solutions. Electrochimica Acta, 1998, 43(7): 771-780
[257] Cao P, Yao J, Zheng J, et al. Comparative study of inhibition effects of benzotriazole for metals in neutral solutions as observed with surface-enhanced Raman spectroscopy. Langmuir, 2002, 18(1):100-104
[258] Yamamoto H, Ota Y. Japanese Patent, Japanese Kokai Tokkyo Koho JP 60 194,088[85 194 088] , 1985
[259] 张洪生. 植酸在金属防护中的应用. 四川化工与腐蚀控制,1999, 2(5):34 -38
[260] Bebot-Brigaud A, Dange C, Fauconnier N,et al. 31P NMR, potentiometric and spectrophotometric studies of phytic acid ionization and complexation properties toward Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ . Journal of Inorganic Biochemistry, 1999, 75(1): 71-78
[261] Bauman A, Chateauneuf G, Boyd B, et al. Conformational inversion processes in phytic acid: NMR spectroscopic and molecular modeling studies. Tetrahedron Letters, 1999, 40(24): 4489-4492
[262] Ramachandran S, Tsai B L, Blanco M, et al. Self-assembled monolayer mechanism for corrosion inhibition of iron by imidazolines. Langmuir, 1996, 12(26): 6419-6428.
[263] Kepley J L, Crooks M R, Ricco J A. A selective SAW-based organoph-osphonate chemical sensor employing a self-assembled, composite monola-yer: a new paradigm for sensor design. Analytical Chemistry, 1992, 64 (24): 3191-3193
[264] Laibinis E P, Whitesides M. G. Self-assembled monolayers of n-alkane-thiolates on copper are barrier films that protect the metal against oxidation by air. Journal of the American Chemistry Society, 1992, 114(23): 9022-9028.
[265] Jennings K G, Laibinis P E. Self-assembled monolayers of alkanethiols on copper provide corrosion resistance in aqueous environments. Colloids and Surfaces A, 1996,116 (): 105-114
[266] Epple M, Bittner M A, Kuhnke K, et al. Alkanethiolate Reorientation during Metal Electrodeposition. Langmuir, 2002,18 (3):773-784
[267] Li F, Lu Y, Xue G, et al. The adsorption and bonding of ω-mercaptoalkanols on HNO3 etched copper. Chemical Physics Letters,1997,264(3-4):376-380
[268] Quan Z, Chen S, Li Y, et al. Adsorption behaviour of Schiff base and corrosion protection of resulting films to copper substrate. Corrosion Science, 2002, 44(4): 703-715
[269] Subramanian R, Lakshminarayanan V. Effect of adsorption of some azoles on copper passivation in alkaline medium. Corrosion Science, 2002, 44 (4):535-554
[270] Gomma G K. Effect of azole compounds on corrosion of copper in acid medium. Materials Chemistry and Physics, 1998, 56 (1): 27-34
[271] Shinohara Y, Ota Y, Yamamoto H, et al. Japanese Patent, Japanese Kokai Tokkyo Koho JP 61 030,685 [86 30 685] , (1986)
[272] Sinniah K, Cheng J, Terrettaz S, et al. Self-assembled omega. Hydroxylalk-anethiol monolayers with internal functionalities: electrochemical and infrared structural characterizations of ether-containing monolayers. The Journal of Physical Chemistry, 1995, 99 (39):14500-14505
[273] Edinger K, Goelzhaeuser A, Demota K, et al. Formation of self-assembled monolayers of n-alkanethiols on gold: a scanning tunneling microscopy study on the modification of substrate morphology. Langmuir, 1993, 9 (1): 4-8
[274] El-Deab M S, Ohsaka T. Molecular-level design of binary self-assembled monolayers on polycrystalline gold electrodes. Electrochimica Acta, 2004, 49 (13) :2189-2194
[275] Stefan I C, Mandler D, Scherson D A. In situ FTIR-ATR studies of functi-onalized self-assembled bilayer interactions with metal ions in aqueous solutions. Langmuir, 2002, 18 (18):6976-6980
[276] Luo H, Weaver M J. Surface-enhanced Raman scattering as a versatile vibrational probe of transition-metal interfaces: thiocyanate coordination modes on platinum-group versus coinage-metal electrodes. Langmuir, 1999, 15 (25): 8743-8749
[277] Crane G L, Wang D X, Sears M L, et al. SERS surfaces modified with a 4-(2-Pyridylazo)resorcinol disulfide derivative: detection of copper, lead, and cadmium. Analytical Chemistry, 1995, 67 (2):360-364
[278] Allen S C, Van Duyne P R. Molecular generality of surface-enhanced Raman spectroscopy (SERS). A detailed investigation of the hexacyanoruthenate ion adsorbed on silver and copper electrodes. Journal of the American Chemistry Society, 1981,103 (25):7497-7501
[279] Gao J S, Tian Z Q. Surface enhanced Raman scattering of pyridine at copper electrodes excited with a 514.5 nm line. Chemical Physics Letters, 1996,262 (1-2):151-154
[280] Dewar M J S, Zoebisch E G, Healy E F, et al. Development and use of quantum mechanical molecular models. 76. AM1: a new general purpose quantum mechanical molecular model. Journal of the American Chemistry Society, 1985,107 (13): 3902-3909
[281] Dewar M JS, Dieter K M. Evaluation of AM1 calculated proton affinities and deprotonation enthalpies. Journal of the American Chemistry Society, 1986,108 (25): 8075-8086
[282] Stewart J J P, MOPAC: a semiempirical molecular orbital program. Journal of Computo-Aided Molecular Design, 1990, 4 (1): 1-105
[283] Lefèvre G, Walcarius A, Ehrhardt J J, et al. Sorption of iodide on cuprite (Cu2O). Langmuir, 2000, 16 (10):4519-4527
[284] Texier F, Servant L, Bruneel JL, et al.In situ probing of interfacial processes in the electrodeposition of copper by confocal Raman microspectro- scopy. Journal of Electroanalytical Chemistry, 1998, 446 (1-2):189–203
[285] Xu J F, Ji W, Shen Z X, et al. Preparation and characterization of CuO nanocrystals. Journal of Solid State Chemistry, 1999,147 (2): 516-519
[286] Zou S Z, Chen Y X, Mao. B W, et al. SERS studies on electrode/electrolyte interfacial water I. Ion effects in the negative potential region. Journal of Electroanalytical Chemistry, 1997,424 (1-2): 19-24
[287] Cao P G, Yao J L, Ren B, et al.Surface-enhanced Raman scattering from bare Fe electrode surfaces. Chemical Physics Letters, 2000, 316(1-2): 1-5
[288] Gu R A, Cao P G, Yao J L., et al. Surface Raman spectroscopic studies on the adsorption of pyridine at bare iron electrodes. Journal of Electroanalytical Chemistry, 2001, 505(1):95-99
[289] Cao P G, Yao J L, Ren B, et al.Potential Dependence of the orientation of thiocyanate adsorbed on an iron electrode as probed by surface-enhanced Raman spectroscopy. The Journal of Physical Chemistry. B, 2002, 106(29): 7283-7285
[290] Cao P G, Yao J L, Ren B, et al. Surface-enhanced Raman scattering spectra of thiourea adsorbed at an iron electrode in NaClO4 solution. The Journal of Physical Chemistry, 2002, 106(39): 10150-10156
[291] Yao J L, Ren B, Huang Z F, et al. Extending surface Raman spectroscopy to transition metals for practical applications IV. A study on corrosion inhibition of benzotriazole on bare Fe electrodes. Electrochimica Acta, 2003, 48(9):1263-1271
[292] Wang G H, Shi J C, Yang H F, et al. Surface-enhanced Raman scattering of imidazole adsorbed on an iron surface. Journal of Raman Spectroscopy, 2002, 33(2): 125–130
[293] Pineda T, Sevilla JM, Roman AJ, et al. Electrochemical evidence on the molten globule conformation of cytochrome c. Biochimica Biophysics Acta, 1997, 1343(2):227-34.
[294] Taniguchi I, Iseki M, Toyosawa K, et al. Purines as new promoters for the voltammetric response of horse heart cytochrome c at a gold electrode. Journal of Electroanalytical Chemistry, 1984, 164(20): 385-391
[295] Taniguchi I, Higo N, UmekitaK, et al. Electrochemical behavior of horse heart cytochrome c in acid solutions using a 6-mercaptopurine modified gold electrode. Journal of Electroanalytical Chemistry, 1986, 206(1-2): 341-348
[296] Ion A, Banica F G, Luca C. Ligand-catalysed metal ion reduction. Voltammetric determination of rate and formation constants for the nickel complex with 6-mercaptopurine-9-D-riboside. Journal of Electroanalytical Chemistry, 1998, 444 (1-2):11-18
[297] Madueno R, Pineda T, Sevilla M, et al. An Electrochemical Study of the SAMs of 6-Mercaptopurine (6MP) at Hg and Au (111) Electrodes in Alkaline Media M. Langmuir, 2002, 18(10): 3903-3909
[298] Vivoni A, Chen S, Ejeh D, et al.Determination of the orientation of 6-mercaptopurine adsorbed on a silver electrode by surface-enhanced Raman spectroscopy and normal mode calculations. Langmuir, 2000, 16(7):3310-3316
[299] Boland T, Ratner D. Two-dimensional assembly of purines and pyrimidines on Au (111). Langmuir, 1994, 10(10): 3845-3852
[300] Gao P, Weaver M J. Metal-adsorbate vibrational frequencies as a probe of surface bonding: halides and pseudohalides at gold electrodes. The Journal of Physical Chemistry, 1986, 90(17): 4057-4063
[301] Kohn W, Becke A D, Parr R G. Density functional theory of electronic structure. The Journal of Physical Chemistry, 1996, 100(31): 12974-12980
[302] Adamo C, Barone V. Toward reliable adiabatic connection models free from adjustable parameters. Chemical Physics Letters, 1997, 274 (1-3): 242-250
[303] Zhu T, Yu H, Wang J, et al.Two-dimensional surface enhanced Raman mapping of differently prepared gold substrates with an azobenzene self-assembled monolayer. Chemical Physics Letters, 1997, 265(3-5): 334-340
[304] Yang H, Yang Y, Liu Z, et al.Self-assembled monolayer of NAD at silver surface: a Raman mapping study. Surface Science, 2004, 555(1-2): 1-8
[305] Moskovits M, Sun J S. Surface selection rules for surface-enhanced Raman spectroscopy: calculations and application to the surface-enhanced Raman spectrum of phthalazine on silver. The Journal of Physical Chemistry, 1984, 88(23): 5526-5530
[306] Mohtat N, Byloos M, Soucy M, et al.Electrochemical evidence of the adsorption of alkanethiols on two sites on Ag(111). Journal of Electroanalytical Chemistry, 2000, 484(2): 120-130
[307] Weisshaar D E, Lamp B D, Porter M D. Thermodynamically controlled electrochemical formation of thiolate monolayers at gold: characterization and comparison to self-assembled analogs. Journal of the American Chemistry Society, 1992, 114(14): 5860-5862
[308] Walczak M M, Chung C, Stole S M, et al. Structure and interfacial properties of spontaneously adsorbed n-alkanethiolate monolayers on evaporated silver surfaces. Journal of the American Chemistry Society, 1991, 113(7): 2370-2378
[309] Walczak M M, Popenoe D D, Deinhammer R S, et al.Reductive desorption of alkanethiolate monolayers at gold: a measure of surface coverage. Langmuir, 1991, 7(11): 2687-2693
[310] Yang D F, Al-Maznai H, Morin M. Vibrational study of the fast reductive and the slow oxidative desorptions of a nonanethiol self-assembled monolayer from a Au(111) single crystal electrode. The Journal of Physical Chemistry B, 1997, 101(7):1158-1166
[311] Yang D F, Wilde C P, Morin M. Studies of the electrochemical removal and efficient Re-formation of a monolayer of hexadecanethiol self-assembled at an Au(111) single crystal in aqueous solutions. Langmuir, 1997, 13(2): 243-249
[312] Wong S J, Porter M D. Origin of the multiple voltammetric desorption waves of long-chain alkanethiolate monolayers chemisorbed on annealed gold electrodes. Journal of Electroanalytical Chemistry, 2000, 485(2):135-143
[313] Yang D F, Wilde C P, Morin M. Electrochemical desorption and adsorption of nonyl mercaptan at gold single crystal electrode surfaces. Langmuir, 1996, 12(26): 6570-6577
[314] Zhong C J, Zak J, PorterM D. Voltammetric reductive desorption characteristics of alkanethiolate monolayers at single crystal Au(111) and (110) electrode surfaces. Journal of Electroanalytical Chemistry, 1997, 421(1-2): 9-13
[315] Szeghalmi A V, Leopold L, P?nzaru S,et al. Adsorption of 6-mercaptopurine and 6-mercaptopurine riboside on silver colloid: a pH dependent surface enhanced Raman spectroscopy and density functional theory study. Part I. 6-Mercaptopurine. Journal of Molecular Structure, 2005, 735-736(1): 103-113