烷基羧基羟肟酸合成及铝硅浮选性能研究
|
摘要
开发低品位铝土矿高效正浮选捕收剂以提高我国一水硬铝石型铝土矿的铝硅比,对解决我国氧化铝生产中存在的问题具有重大意义。本文研究了烷基羧基羟肟酸系列捕收剂的合成方法及其对一水硬铝石、高岭石和伊利石的浮选性能,通过吸附量、zeta电位和红外光谱分析等手段,探讨了烷基羟肟酸类捕收剂与矿物的作用机理。
用羟胺与相应的酸酯为原料合成了CMCA、CDHA和CTHA三种捕收剂,并通过红外光谱和元素分析等手段对化合物进行表征。
单矿物浮选实验结果表明：对一水硬铝石,CTHA、CDHA和CMCA的捕收能力相当强,明显高于对高岭石和伊利石的捕收能力；其中CTHA的捕收能力稍微强于CDHA,但远大于CMCA。在pH5-9,药剂浓度为2×10-4 mol/L时,CTHA和CDHA对一水硬铝石的浮选回收率均大于90%,对高岭石和伊利石的浮选回收率均小于30%。因此,在pH5-9范围内,采用CTHA和CDHA有可能实现一水硬铝石与高岭石和伊利石的有效分离。人工混矿试验表明,CTHA能有效分离一水硬铝石与铝硅酸盐矿物；氧化铝回收率均大于85%,同时精矿铝硅比也有显著提高,所以CTHA很可能成为一种新型的高效铝土矿捕收剂。
矿粒扫描电镜(SEM)照片(×10,000)表明：一水硬铝石颗粒为椭圆形,高岭石和伊利石颗粒为不规则的形状。吸附量曲线表明,CTHA在一水硬铝石表面的吸附量远大于在高岭石和伊利石表面的吸附量,与浮选实验结果一致。Zeta电位和红外光谱分析表明,捕收剂在一水硬铝石表面通过-COOH、-NHOH与矿物表面的铝离子(Al3+)形成双环螯合物的化学吸附,而在高岭石和伊利石表面主要是物理吸附。
In order to solve the problem in alumina production, it is important to develop new collectors of direct flotation for improving the Al/Si (mass ratio of Al2O3 to SiO2) of diasporic bauxite in China. In this paper, the synthesis of novel alkyl carboxyl hydroxamic acids and their flotation properties to diaspore, kaolinite and illite have been studied. The adsorption mechanism of the new collectors on the minerals has been investigated through adsorption amount, zeta potential, SEM and IR spectrum measurements.
Three carboxyl hydroxamic acids, CMCA, CDHA and CTHA were synthesized by reaction of hydroxylamine hydrochloride with relevant ester. The molecular structures of synthesized products have been identified by IR spectrum and element analysis.
The results of flotation tests for single minerals indicate that the collecting ability of carboxyl hydroxamic acids for diaspore, kaolinite and illite is in the order of CTHA > CDHA> CMCA, the collecting ability and selectivity of CTHA are better than those of CDHA and CMCA. Using CTHA and CDHA as collector in the pH range of 5-9, diaspore have good flotation recovery; However, kaolinite and illite still keep a relatively low flotation recovery. At the dosage of 2×10-4 mol/L, both CDHA and CTHA show excellent collecting abilities for diaspore with the recoveries over 90%, but for kaolinite and illite the recoveries were less than 30%. Therefore, it is possible to separate the diaspore from such silicate minerals as kaolinite and illite using CTHA and CDHA as collector in the pH range of 5-9. So, CTHA may become a new type of selective collectors for direct flotation to remove aluminosilicate minerals from bauxite. The results of separation of artificially mixed minerals present that the mass ratio of Al2O3 to SiO2 was increased to a high level, and the recovery of Al2O3 is more than 85%.
SEM (×10,000) shows that diaspore takes oval shape, kaolinite and illite takes irregular appearance. The adsorption measurement indicates that the adsorption on diaspore is lager than that on kaolinite and illite, which is generally consistent with the flotation tests. Zeta potential and IR spectrum measurements approve that the interaction of the collector on the diaspore surface is mainly a chemical adsorption, while the adsorption on kaolinite and illite is mainly dominated by physical adsorption. The chemical adsorption of chelator ion on diaspore may take place through-COOH,-NHOH and the Al3+ on the surface of mineral to form double rings.
用羟胺与相应的酸酯为原料合成了CMCA、CDHA和CTHA三种捕收剂,并通过红外光谱和元素分析等手段对化合物进行表征。
单矿物浮选实验结果表明：对一水硬铝石,CTHA、CDHA和CMCA的捕收能力相当强,明显高于对高岭石和伊利石的捕收能力；其中CTHA的捕收能力稍微强于CDHA,但远大于CMCA。在pH5-9,药剂浓度为2×10-4 mol/L时,CTHA和CDHA对一水硬铝石的浮选回收率均大于90%,对高岭石和伊利石的浮选回收率均小于30%。因此,在pH5-9范围内,采用CTHA和CDHA有可能实现一水硬铝石与高岭石和伊利石的有效分离。人工混矿试验表明,CTHA能有效分离一水硬铝石与铝硅酸盐矿物；氧化铝回收率均大于85%,同时精矿铝硅比也有显著提高,所以CTHA很可能成为一种新型的高效铝土矿捕收剂。
矿粒扫描电镜(SEM)照片(×10,000)表明：一水硬铝石颗粒为椭圆形,高岭石和伊利石颗粒为不规则的形状。吸附量曲线表明,CTHA在一水硬铝石表面的吸附量远大于在高岭石和伊利石表面的吸附量,与浮选实验结果一致。Zeta电位和红外光谱分析表明,捕收剂在一水硬铝石表面通过-COOH、-NHOH与矿物表面的铝离子(Al3+)形成双环螯合物的化学吸附,而在高岭石和伊利石表面主要是物理吸附。
In order to solve the problem in alumina production, it is important to develop new collectors of direct flotation for improving the Al/Si (mass ratio of Al2O3 to SiO2) of diasporic bauxite in China. In this paper, the synthesis of novel alkyl carboxyl hydroxamic acids and their flotation properties to diaspore, kaolinite and illite have been studied. The adsorption mechanism of the new collectors on the minerals has been investigated through adsorption amount, zeta potential, SEM and IR spectrum measurements.
Three carboxyl hydroxamic acids, CMCA, CDHA and CTHA were synthesized by reaction of hydroxylamine hydrochloride with relevant ester. The molecular structures of synthesized products have been identified by IR spectrum and element analysis.
The results of flotation tests for single minerals indicate that the collecting ability of carboxyl hydroxamic acids for diaspore, kaolinite and illite is in the order of CTHA > CDHA> CMCA, the collecting ability and selectivity of CTHA are better than those of CDHA and CMCA. Using CTHA and CDHA as collector in the pH range of 5-9, diaspore have good flotation recovery; However, kaolinite and illite still keep a relatively low flotation recovery. At the dosage of 2×10-4 mol/L, both CDHA and CTHA show excellent collecting abilities for diaspore with the recoveries over 90%, but for kaolinite and illite the recoveries were less than 30%. Therefore, it is possible to separate the diaspore from such silicate minerals as kaolinite and illite using CTHA and CDHA as collector in the pH range of 5-9. So, CTHA may become a new type of selective collectors for direct flotation to remove aluminosilicate minerals from bauxite. The results of separation of artificially mixed minerals present that the mass ratio of Al2O3 to SiO2 was increased to a high level, and the recovery of Al2O3 is more than 85%.
SEM (×10,000) shows that diaspore takes oval shape, kaolinite and illite takes irregular appearance. The adsorption measurement indicates that the adsorption on diaspore is lager than that on kaolinite and illite, which is generally consistent with the flotation tests. Zeta potential and IR spectrum measurements approve that the interaction of the collector on the diaspore surface is mainly a chemical adsorption, while the adsorption on kaolinite and illite is mainly dominated by physical adsorption. The chemical adsorption of chelator ion on diaspore may take place through-COOH,-NHOH and the Al3+ on the surface of mineral to form double rings.
引文
[1]林强,王晓玲,王淀佐.一类螯合捕收剂α-肟基磷酸酯的制备及其结构与性能的关系[J].化工冶金,1997,18(4)：312-317
[2]蒋玉仁,胡岳华,曹学峰.新型螯合捕收剂COBA结构与捕收性能的关系[J].中国有色金属学报,2001,11(4)：703-706
[3]任俊,卢寿慈,池汝安.1-羟基-2-萘甲羟肟酸浮选氟碳铈矿作用机理[J].中国有色金属学报,1996,6(4)：24-28
[4]Ren J, Lu S, Song S, et al. A new collector for rare earth mineral flotation[J]. Miner Eng,1997,10(12):1395-1404
[5]朱一民,周菁.萘羟肟酸浮选黑钨矿作用机理研究[J].有色金属,1999,51(4)：31-34
[6]西尔克西A A.用己基硫代乙胺作捕收剂从毒砂中浮选分离黄铁矿[J].国内金属矿选矿,2001,4：19-23
[7]Barbaro M, Urbina R H, Cozza C, et al. Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collectorInt[J].In Int J Miner Proc 1997,50(4):275-287
[8]马拉比里AM.一种新螯合捕收剂与硫化铜矿物的作用机理[J].国外金属矿选矿,1994,5：27-35
[9]朱建光.2001年浮选药剂的进展[J].国外金属矿选矿,2002,2：4-11
[10]蒋玉仁,曹育才,薛玉兰TCPO螯合捕收剂的结构与性能关系[J].破产综合利用,2001,(3)：18-22
[11]戈保梁,张文彬.氧化铜矿选矿研究进展[J].云南冶金,1994,4：13-18
[12]李军,孙克已.螯合剂BTA浮选孔雀石机理研究[J].湖南有色金属,1995,11(3)：28-30
[13]朱建光.2000年浮选药剂进展[J].国外金属矿选矿,2001,3：10-16
[14]Ackerman PK,Harris GH,Klimpel RR.Use of xanthogen formates as collectors in the flotation of copper sulfides and pyrite[J].Int.J.Miner.Process,2000,58(1-4): 1-13
[15]阿克尔曼P K.用黄原酸甲酸酯做捕收剂浮选硫化铜和黄铁矿[J].国外金属矿选矿,2000,7：22-26
[16]林强,朱继生,刘道发,等.黄原酸甲酸酯的合成研制与浮选性能评价[J].有色金属(选矿部分)2005,2：44-46
[17]程新潮.黑钨矿、白钨矿、莹石、方解石分离基础理论和新方法的研究[D]. 长沙：中南工业大学,1996
[18]陈竟清,赖景陀,叶少歧,等.锡石捕收剂-水杨氧肟酸[J].有色金属(选矿部分),1987,3：26-28
[19]徐金球,徐晓军,王景伟.1-羟基2-萘甲羟肟酸的合成及对稀土矿物的捕收性能[J].有色金属,2002,54(3)：72-73
[20]江信开.含钙矿物浮选分离新方法及其机理研究[D].北京：北京矿冶研究总院.1986
[21]朱建光.同分异构原理在合成两性捕收剂中的应用[J].中南工业大学学报,1993,24(5)：596-601
[22]陈远望.当前世界铝土矿和氧化铝的供应形式[J].金属世界,2005,4：6-8
[23]刘广义.一水硬铝石型铝土矿浮选脱硅新药剂及其理论研究[D].长沙：中南大学,1999
[24]刘中凡,杜雅君.我国铝土矿资源综合分析[J].轻金属,2000,12：8-12
[25]杨重愚.氧化铝生产工艺[M].北京：冶金工业出版社,1993,1-21
[26]王庆义.氧化铝生产[M].北京：冶金工业出版社,1995,1-13
[27]吴秀铭,徐锦.影响我国铝硅业生存与发展的几大问题[J].世界有色金属,1997,7：4-10
[28]穆新和.我国铝土矿资源合理开发利用的探讨[J].矿产与地质,2002,16(5)：313-315
[29]张文帅.我国铝土矿能源消耗的基本情况[J].世界有色金属,2001,5：24-29
[30]黄攀峰,张国范,冯其明.铝土矿浮选脱硅研究进展[J].破产保护与利用,2003,1：50-54
[31]凌石生,章晓林,尚旭,等.铝土矿物理选矿脱硅研究概述[J].国外金属矿选矿2006,7：9-12
[32]张云海.高岭石与一水硬铝石反浮选分离的研究[D].沈阳：东北大学：2005
[33]刘水红,方启.铝土矿选矿脱硅技术研究现状评述[J].矿冶,2004,13(4)：24-29
[34]蒋昊.铝土矿浮选脱硅过程中阳离子捕收剂与矿物和含铝硅酸矿物作用的溶液化学研究[D].长沙：中南大学：2004
[35]皮尔斯M J.化学药剂在矿物加工中的应用概况国外[J].金属矿选矿,2005,5：5-11
[36]蒋昊,胡岳华,徐竞,等.阴离子捕收剂浮选一水硬铝石溶液化学机理[J].矿物工程,2001,21(2)：27-29
[37]Hinds S A, Husain K, Liu N. Beneficiation of bauxite tailings[J].Light metals, 1985,2:24-28
[38]方启学,董国智,郭建,等.铝土矿选矿脱硅研究现状与展望[J].破产综合利用,2001，2：26-31
[39]Li L F, Zhang G X, Kang W G, et al. The beneficiation of accumulative diaspore predesilication and elimination of the iron content[J].J Central South Uni Tec(Natural Science),1980,4:82-88
[40]张国范,冯其明,卢毅屏,等.油酸钠对一水硬铝石和高岭石的捕收机理[J].中国有色金属学报,2001,11(2)：298-301
[41]张国范,冯其明,卢毅屏,等.六偏磷酸钠在铝土矿浮选中的应用[J].中南工业大学学报,2001,32(2)：127-130
[42]Ishchenko V V. Flotation of silica from bauxite[J].Izv Vyssh Ucheb Zaved Tsvet Metall,1974,3:7-11
[43]Anishchenko N M, Andreev P I, Kirichenko T F. Interaction of cation reagents in the flotation of chamosite-gibbsite bauxites[J].Izv Vyssh Uchebn Zaved Tsvet Met,1972,4:12-16
[44]Folcy E, Tittle K. Remove of iron oxides from bauxite ores[J].Inst Mining Met Proc,1991,9:59-65
[45]Herder P C. Forces between hydrophobed mica surfaces immersed in dodecylammonium choride solution[J].Col Inter Sci,1990,134:336-345
[46]Ray D T. Study on the beneficiation of bauxite in the Tatun volcanic area[J]. Taiwan Kuang Yeh Chi Shu,1980,18:69-81
[47]王恩孚,马朝建,陆钦芳,等.选矿-拜耳法处理中国高硅铝土矿生产氧化铝的探讨[J].轻金属,1996,7：3-7
[48]赵世民,胡岳华,王淀佐,等.N-(2-氨乙基)-月桂酰胺浮选硅铝酸盐矿物的研究[J].物理化学学报,2003,19(6)：573-576
[49]赵世民,胡岳华,王淀佐,等.N-(3-氨乙基)-月桂酰胺对铝硅酸矿物的浮选[J].中国有色金属学报,2003,13(5)：1273-1277
[50]李海普,胡岳华,蒋玉仁,等.变性淀粉在铝硅矿物浮选分离中的作用机理[J].中国有色金属学报,2001,11(4)：697-701
[51]赵声贵,钟宏,刘广义.季铵盐捕收剂对铝硅矿物的浮选行为[J].金属矿山,2007,(2)：45-47
[52]Zhao S G, Zhong H, Liu G Y. Effect of quaternary ammonium salts on flotation behaviour of aluminosilicate minerals[J].J Cent South Technol, 2007,14(4):500-503
[53]Chen X Q, Hu Y H, Wang Y H. Mechanisms of flotation separation of diaspore and kaolinite by quaternary ammonium salt DTAL[J].Trans Nonferrous Met Soc China,2004,14(3):609-612
[54]凌石生,张文彬.铝土矿反浮选脱硅药剂研究概述[J].国外金属矿选矿,2008,2：20-24
[55]程平平,钟宏,余新阳,等.QAx224捕收剂反浮选分离一水硬铝石和高岭石的试验研究[J].金属矿山,2009,1：55-58,73
[56]赵声贵.烷基胍硫酸盐系列捕收剂的合成及其对铝硅酸盐矿物的浮选性能[D].长沙：中南大学,2007
[57]胡岳华,蒋昊,邱冠周,等.一水硬铝石型铝土矿铝硅浮选分离的溶液化学[J].中国有色金属学报,2001,11(1)：125-130
[58]黄传兵,王毓华,陈兴华,等.铝土矿反浮选脱硅研究综述[J].金属矿山,2005,6：21-24
[59]Brown S, Meroueh S O, Fridman R, et al. Quest for selectivity in inhibition of matrix metalloproteinases[J].Curr Top Med Chem,2004,4:1227-1238
[60]Kelly W K, Marks P A. Drug insight:Histone deacetylase inhibitors development of the new targeted anticancer agent suberoylanilide hydroxamic acid[J].Nat Clin Pract Oncol,2005,2:150-157
[61]Flipo M, Beggyn T, Charton J, et al. A library of novel hydroxamic acids targeting the metallo-protease family:Design, parallel synthesis and screening[J]. Bioorg Med Chem Lett,2007,15(1):63-76
[62]Nuti E, Orlandini E, Nencetti S, et al. Carbonic anhydrase and matrix metallopro-teinase inhibitors, inhibition of human tumor-associated isozymes IX and cytosolic isozyme Ⅰ and Ⅱ with sulfonylated hydroxamates[J].Bioorg Med Chem Lett,2007,15(6):2298-2311
[63]Charrier C, Roche J, Gesson J R, et al. Antiproliferative activities of a library of hybrids between indanones and HDAC inhibitor SAHA and MS-275 analogues[J].Bioorg Med Chem Lett,2007,17(22):6142-6146
[64]Oyelere A K, Green P, Guerrant W, et al. Synthesis and receptor binding properties of chimeric peptides containing a μ-opioid receptor ligand and nociceptin/orphanin FQ receptor ligand Ac-RYYRIK-amide[J].Bioorg Med Chem Lett,2008,16(18):4839-4841
[65]Kim H K, Lee K, Park B W, et al. Synthesis, enzymatic inhibition, and cancer cell growth inhibition of novel δ-lactam-based histone deacetylase (HDAC) inhibitors[J].Bioorg Med Chem Lett,2006,16(15):4068-4070
[66]Marson C M, Mahadevan T, Dines J, et al. Structure-activity relationships of aryloxyalkanoic acid hydroxyamides as potent inhibitors of histone deacetylase[J].Bioorg Med Chem Lett,2007,17(1):136-141
[67]Belvedere S, Witter D J, Yan J M, et al. Aminosuberoyl hydroxamic acids (ASHAs):A potent new class of HDAC inhibitors[J].Bioorg Med Chem Lett,2007,17(14):3969-3971
[68]Lee S, Shinji C, Ogura K, et al. Design, synthesis, and evaluation of isoindolinone-hydroxamic acid derivatives as histone deacetylase (HDAC) inhibitors [J].Bioorg Med Chem Lett,2007,17(17):4895-4900
[69]Hanessian S, Auzzas L, Giannini G, et al. ω-Alkoxy analogues of SAHA (vorinostat) as inhibitors of HDAC:A study of chain-length and stereochemical dependence[J].Bioorg Med Chem Lett,2007,17(22):6261-6265
[70]Chen X T, Corbett R L, Covington M B, et al. A new 4-(2-methylquinolin-4-ylmethyl) phenyl Pl'group for the β-amino hydroxamic acid derived TACE inhibitors[J].Bioorg Med Chem Lett,2007,17(7):1865-1870
[71]Su H, Nebbioso A, Carafa V, et al. Design, synthesis and biological evaluation of novel compounds with conjugated structure as anti-tumor agents[J].Bioorg Med Chem,2008,16(17):7992-8002
[72]李云兰,王晓剑,杨莉,等.高效液相色谱法测定抗癌原料药芳香异羟肟酸二丁基锡[J].分析实验室,2007,26(8)：21-24
[73]李青山,尚先梅,吴军.芳香异羟肟酸有机锡抗癌化合物的初步构效关系[J].中国科学,2008,38(5)：429-440
[74]王亚琦,边占喜.1’-庚基二茂铁异羟肟酸稀土螯合物的合成与表征[J].稀土,2008,29(3)：1-4
[75]蒋玉仁,胡岳华,曹学锋.新型螯合剂COBA的结构与捕收性能的关系[J].中国有色金属学报,2001,11(4)：702-706
[76]车丽萍,余永富,庞金兴等.羟肟酸类捕收剂的合成、性质及在稀土矿物浮选中的作用机理[J].稀土,2004,25(6)：74-80
[77]Bolm C, Kuhn T. Asymmetric epoxidation of allylic alcohols using vanadium complexes of (N)-hydroxy-[2.2]paracyclophane-4-carboxylic amides[J]. Synlett,2000,6:899-901
[78]Hoshino Y, Yamamoto H. Novel a-Amino acid-based hydroxamic acid ligands for vanadium-catalyzed asymmetric epoxidation of allylic alcohols[J].J Am Chem Soc,2000,122:10452-10453
[79]Li H B, Li J Z, Qin S Y. Synthesis, oxygenation and catalytic expoxidation performance of transition-metal hydroxamate with benzo-15 Crown-5 transition[J].Met Chem,2006,31:129-134
[80]吕志凤,李鸿波,战风涛,等.异羟肟酸过渡金属配合物的合成和催化氧化性能研究[J].四川大学学报(自然科学版),2000,37(3)：426-431
[81]陈骏如,张瑞,胡家元等.羟胺酸钴配合物催化混合二甲苯的选择性氧化性氧化[J].化学研究与应用,2002,14(2)：178-181
[82]Li H B, Hao M A, Qin C, et al. An efficient aerobic oxidation for p-xylene to p-toluic acid catalyzed by cobalt (Ⅱ) hydroxamates with benzo-15-crown-5[J].React Kinet Catal Lett,2007,91(2):299-306
[83]Li H B, Qin C, Yang W B, et al. Dioxygen affinities and catalytic oxidation performance of cobalt(Ⅱ) hydroxamates with benzo-15-crown-5 pendants[J] Chin.Chem.Lett,2007,18(1):103-106
[84]刘富安,李建章,黄生田,等.聚醚桥连二异羟肟酸配合物催化羧酸酯水解的动力学研究[J].化学研究与应用,2005,17(4)：507-510
[85]黄生田,李建章,刘富安等.聚醚桥连二异羟肟酸双核配合物催化PNPP水解的反应动力学[J].催化学报,2005,26(1)：43-48
[86]Li J Z, Li H B, Xie J Q, et al. PNPP catalytic hydrolysis by mono-and binuclear transition-metal complexes with polyether-bridged dihydroxamic acids[J].Transition Met Chem,2004,29:823-829
[87]Xiang Y, Zeng X C, Cheng S Q, et al. Metallomicellar catalysis cleavage of p-nitrophenyl picolinate catalyzed by binuclear meta cmplexes coordinating tripeptide in CTAB micellar solution[J].J Colloid Interface Sci, 2001,235(1):114-118
[88]Yazal El J, Pang Y P. Proton dissociation energies of zinc-coordinated hydroxamic acids and their relative affinities for zinc:insight into design of inhibitors of zinc-containing proteinases[J].J phys Chem B, 2000,104(27):6499-6504
[89]江浩,常志远,潘永军,等.异羟肟酸型配位体对TBP萃取金属钚行为的影响研究[J].核化学与放射化学,2000,22(1)：1-7
[90]郑卫芳,刘黎明,常志远.乙异羟肟酸改善Purex流程铀产品中U-Pu的分离[J].原子能科学技术,2000,34(2)：110-115
[91]郑卫芳,江浩,朱建明,等.短链羟肟酸对Pu(Ⅳ)的配位、还原及反萃[J].核化学与放射化学,2003,25(2)：65-68
[92]张平,刘秀琴,王建晨,等.乙异羟肟酸TRPO简化流程中的应用[J].核化学与放射化学,2004,26(3)：158-161
[93]王碧,许桂丽,胡星琪.含羟肟酸侧基高分子重金属捕收剂处理含铅废水的研究[J].化学研究与应用,2008,20(5)：561-564
[94]符剑刚,钟宏,张正国,等.以猪油为原料合成羟肟酸[J].中南大学学报(自然科学版),2004,35(2)：239-243
[95]Esteves M A,Vaz M CT, Gonsalves M, et al. Siderophore analogues,Synthesis and chelating properties of a new macrocyclic trishydroxamate ligand[J].J Chem Soc, Dalton Trans,1995,15:2565-2573
[96]曾伟,曾贵玉,秦圣英.异羟肟酸的合成与应用研究进展[J].有机化学,2003,23(11)：1213-1218
[97]Reddy A S,Kumar M S, et al. A convenient method for the preparation of hydroxamic aids[J].Tetrahedron Lett,2000,41(33):6285-6288
[98]Appendino G, Berton L, Minassi A, et al. An expeditious hydroxyamidation of carboxylic acids[J].Tetrahedron Lett,2005,46(31):5113-5115
[99]Yamada K, Kanekiyo T, Tanaka S, et al. Novel intramolecular photo-rearrangement of alkane nitronate anions[J].J Am Chem Soc,1981,103 (23):7003-7005
[100]Chittari P, Thomas A, Rajappa S. Synthesis of novel cyclic hydroxamic acids[J].Tetrahedron Lett,1994,35(22):3973-3976
[101]Rajappa S, Thomas A. Synthesis of cyclic hydroxamic acids from aliphatic nitro compounds[J].Tetrahedron,1995,51(38):10571-10580
[102]Brewer G A, Sinn E. Oxidation of phenacetin and related amides to their hydroxamic acids, crystal structures of the dioxomolybdenum(VI) hydroxamates derived from phenacetin and acetanilide[J].Inorg Chem,1981,20(6):1823-1830
[103]Neset S M, Benneche T, Undheim K. Synthesis of cyclic hydroxamic acids by oxidation of secondary amines with dimethyldioxirane[J].Acta.Chem.Scand, 1993,47(11):1141-1143
[104]Murahashi S, Oda T, Sugahara T, et al. Tungstate-catalyzed oxidation of tetrahydroquinolin es with hydrogen peroxide:A novel ethod for the synthesis of cyclic hydroxamic acids[J].J Org Chem,1990,55(6):1744-1749
[105]Corbett M D, Corbett B R. Reaction of nitroso aromatics with glyoylic acid. A new path to hydroxamic acids[J].J.Org.Chem,1980,45(14):2834-2839
[106]Ursie S.Nigovie B,Vreek V, et al. Formation of hydroxamic acids promoted by metal ions, interaction of aldehyde carbonyl group with C-nitroso group in the presence of ferric ions[J].Tetrahedron Lettl995,36(52):9547-9550
[107]Richter L S, Desai M C.A TFA-cleavable linkage for solid-phase synthesis of hydroxamic acids[J].Tetrahedron Lett,1997,38(3):321-322
[108]Golebiowski A, Klopfenstein S. Solid supported synthesis of hydroxamic acids[J].Tetrahedron lett,1998,39(21):3397-3400
[109]Choi J, Park J G, Pang Y P. Convenient synthesis of a library of discrete hydroxamic acids using the hydroxythiophenol (Marshall) resin[J].Tetrahedron Lett,2008,49(7):1103-1106
[110]Szarka Z, Skoda-Folder R, Kollar L, et al. Highly efficient synthesis of steroidal hydroxamic acid derivatives via gomogeneous catalytic carbonylation reaction[J].Tetrahedron,2000,56(29):5253-5257
[111]见百熙.浮选药剂[M].北京工业出版社,1981：310-314
[112]Hussain S A, Demirci S, Ozbayoglu G. Zeta potential measurements on three' clays from Turkey and effects of clays on coal flotation[J].J Colloid Interface Sci,1996,184(2):535-541
[113]Liu G Y, Zhong H, Hu Y H, et al.The role of cationic polyacryamide in the reverse fotation of diaspric bauxite[J].Miner Eng,2007,20(13):1191-1199
[114]Wang Y H, Huang, C B, Hu Y H, et al. Benefication of diaspore-bauxite ore by selective flocculation with a polyacrylate flocculant[J].Miner Eng, 2008,21(9):664-672
[115]Huang C B, Wang, Y H. Removal of aluminosilicates from diasporic-bauxite by selective flocculation using sodium polyacrylate[J].Sep Purif Technol,2008, 59:299-303
[116]黄传兵,王毓华,兰叶.有机絮凝剂HSPA分选一水硬铝石型铝土矿的机理[J].中国有色金属学报,2006,16(7)：1250-1256
[117]Cao X F, Hu Y H, Xu J. Synthesis of γ-alkoxy-propylamines and their collecting properties on aluminosilicate minerals[J].J Cent South Univ Technol 2004,11(3):280-285
[118]Zhao S M,Wang D Z, Hu Y H, et al. Flotation of aluminosilicates using N-(2-aminoethyl)-1-naphthaleneacetamide[J].Miner Eng,2003,16 (10):1031-1033
[119]蒋昊,胡岳华,覃文庆,等.直链烷基胺浮选铝硅矿物机理[J].中国有色金属学报,2001,11(4)：687-692
[2]蒋玉仁,胡岳华,曹学峰.新型螯合捕收剂COBA结构与捕收性能的关系[J].中国有色金属学报,2001,11(4)：703-706
[3]任俊,卢寿慈,池汝安.1-羟基-2-萘甲羟肟酸浮选氟碳铈矿作用机理[J].中国有色金属学报,1996,6(4)：24-28
[4]Ren J, Lu S, Song S, et al. A new collector for rare earth mineral flotation[J]. Miner Eng,1997,10(12):1395-1404
[5]朱一民,周菁.萘羟肟酸浮选黑钨矿作用机理研究[J].有色金属,1999,51(4)：31-34
[6]西尔克西A A.用己基硫代乙胺作捕收剂从毒砂中浮选分离黄铁矿[J].国内金属矿选矿,2001,4：19-23
[7]Barbaro M, Urbina R H, Cozza C, et al. Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collectorInt[J].In Int J Miner Proc 1997,50(4):275-287
[8]马拉比里AM.一种新螯合捕收剂与硫化铜矿物的作用机理[J].国外金属矿选矿,1994,5：27-35
[9]朱建光.2001年浮选药剂的进展[J].国外金属矿选矿,2002,2：4-11
[10]蒋玉仁,曹育才,薛玉兰TCPO螯合捕收剂的结构与性能关系[J].破产综合利用,2001,(3)：18-22
[11]戈保梁,张文彬.氧化铜矿选矿研究进展[J].云南冶金,1994,4：13-18
[12]李军,孙克已.螯合剂BTA浮选孔雀石机理研究[J].湖南有色金属,1995,11(3)：28-30
[13]朱建光.2000年浮选药剂进展[J].国外金属矿选矿,2001,3：10-16
[14]Ackerman PK,Harris GH,Klimpel RR.Use of xanthogen formates as collectors in the flotation of copper sulfides and pyrite[J].Int.J.Miner.Process,2000,58(1-4): 1-13
[15]阿克尔曼P K.用黄原酸甲酸酯做捕收剂浮选硫化铜和黄铁矿[J].国外金属矿选矿,2000,7：22-26
[16]林强,朱继生,刘道发,等.黄原酸甲酸酯的合成研制与浮选性能评价[J].有色金属(选矿部分)2005,2：44-46
[17]程新潮.黑钨矿、白钨矿、莹石、方解石分离基础理论和新方法的研究[D]. 长沙：中南工业大学,1996
[18]陈竟清,赖景陀,叶少歧,等.锡石捕收剂-水杨氧肟酸[J].有色金属(选矿部分),1987,3：26-28
[19]徐金球,徐晓军,王景伟.1-羟基2-萘甲羟肟酸的合成及对稀土矿物的捕收性能[J].有色金属,2002,54(3)：72-73
[20]江信开.含钙矿物浮选分离新方法及其机理研究[D].北京：北京矿冶研究总院.1986
[21]朱建光.同分异构原理在合成两性捕收剂中的应用[J].中南工业大学学报,1993,24(5)：596-601
[22]陈远望.当前世界铝土矿和氧化铝的供应形式[J].金属世界,2005,4：6-8
[23]刘广义.一水硬铝石型铝土矿浮选脱硅新药剂及其理论研究[D].长沙：中南大学,1999
[24]刘中凡,杜雅君.我国铝土矿资源综合分析[J].轻金属,2000,12：8-12
[25]杨重愚.氧化铝生产工艺[M].北京：冶金工业出版社,1993,1-21
[26]王庆义.氧化铝生产[M].北京：冶金工业出版社,1995,1-13
[27]吴秀铭,徐锦.影响我国铝硅业生存与发展的几大问题[J].世界有色金属,1997,7：4-10
[28]穆新和.我国铝土矿资源合理开发利用的探讨[J].矿产与地质,2002,16(5)：313-315
[29]张文帅.我国铝土矿能源消耗的基本情况[J].世界有色金属,2001,5：24-29
[30]黄攀峰,张国范,冯其明.铝土矿浮选脱硅研究进展[J].破产保护与利用,2003,1：50-54
[31]凌石生,章晓林,尚旭,等.铝土矿物理选矿脱硅研究概述[J].国外金属矿选矿2006,7：9-12
[32]张云海.高岭石与一水硬铝石反浮选分离的研究[D].沈阳：东北大学：2005
[33]刘水红,方启.铝土矿选矿脱硅技术研究现状评述[J].矿冶,2004,13(4)：24-29
[34]蒋昊.铝土矿浮选脱硅过程中阳离子捕收剂与矿物和含铝硅酸矿物作用的溶液化学研究[D].长沙：中南大学：2004
[35]皮尔斯M J.化学药剂在矿物加工中的应用概况国外[J].金属矿选矿,2005,5：5-11
[36]蒋昊,胡岳华,徐竞,等.阴离子捕收剂浮选一水硬铝石溶液化学机理[J].矿物工程,2001,21(2)：27-29
[37]Hinds S A, Husain K, Liu N. Beneficiation of bauxite tailings[J].Light metals, 1985,2:24-28
[38]方启学,董国智,郭建,等.铝土矿选矿脱硅研究现状与展望[J].破产综合利用,2001，2：26-31
[39]Li L F, Zhang G X, Kang W G, et al. The beneficiation of accumulative diaspore predesilication and elimination of the iron content[J].J Central South Uni Tec(Natural Science),1980,4:82-88
[40]张国范,冯其明,卢毅屏,等.油酸钠对一水硬铝石和高岭石的捕收机理[J].中国有色金属学报,2001,11(2)：298-301
[41]张国范,冯其明,卢毅屏,等.六偏磷酸钠在铝土矿浮选中的应用[J].中南工业大学学报,2001,32(2)：127-130
[42]Ishchenko V V. Flotation of silica from bauxite[J].Izv Vyssh Ucheb Zaved Tsvet Metall,1974,3:7-11
[43]Anishchenko N M, Andreev P I, Kirichenko T F. Interaction of cation reagents in the flotation of chamosite-gibbsite bauxites[J].Izv Vyssh Uchebn Zaved Tsvet Met,1972,4:12-16
[44]Folcy E, Tittle K. Remove of iron oxides from bauxite ores[J].Inst Mining Met Proc,1991,9:59-65
[45]Herder P C. Forces between hydrophobed mica surfaces immersed in dodecylammonium choride solution[J].Col Inter Sci,1990,134:336-345
[46]Ray D T. Study on the beneficiation of bauxite in the Tatun volcanic area[J]. Taiwan Kuang Yeh Chi Shu,1980,18:69-81
[47]王恩孚,马朝建,陆钦芳,等.选矿-拜耳法处理中国高硅铝土矿生产氧化铝的探讨[J].轻金属,1996,7：3-7
[48]赵世民,胡岳华,王淀佐,等.N-(2-氨乙基)-月桂酰胺浮选硅铝酸盐矿物的研究[J].物理化学学报,2003,19(6)：573-576
[49]赵世民,胡岳华,王淀佐,等.N-(3-氨乙基)-月桂酰胺对铝硅酸矿物的浮选[J].中国有色金属学报,2003,13(5)：1273-1277
[50]李海普,胡岳华,蒋玉仁,等.变性淀粉在铝硅矿物浮选分离中的作用机理[J].中国有色金属学报,2001,11(4)：697-701
[51]赵声贵,钟宏,刘广义.季铵盐捕收剂对铝硅矿物的浮选行为[J].金属矿山,2007,(2)：45-47
[52]Zhao S G, Zhong H, Liu G Y. Effect of quaternary ammonium salts on flotation behaviour of aluminosilicate minerals[J].J Cent South Technol, 2007,14(4):500-503
[53]Chen X Q, Hu Y H, Wang Y H. Mechanisms of flotation separation of diaspore and kaolinite by quaternary ammonium salt DTAL[J].Trans Nonferrous Met Soc China,2004,14(3):609-612
[54]凌石生,张文彬.铝土矿反浮选脱硅药剂研究概述[J].国外金属矿选矿,2008,2：20-24
[55]程平平,钟宏,余新阳,等.QAx224捕收剂反浮选分离一水硬铝石和高岭石的试验研究[J].金属矿山,2009,1：55-58,73
[56]赵声贵.烷基胍硫酸盐系列捕收剂的合成及其对铝硅酸盐矿物的浮选性能[D].长沙：中南大学,2007
[57]胡岳华,蒋昊,邱冠周,等.一水硬铝石型铝土矿铝硅浮选分离的溶液化学[J].中国有色金属学报,2001,11(1)：125-130
[58]黄传兵,王毓华,陈兴华,等.铝土矿反浮选脱硅研究综述[J].金属矿山,2005,6：21-24
[59]Brown S, Meroueh S O, Fridman R, et al. Quest for selectivity in inhibition of matrix metalloproteinases[J].Curr Top Med Chem,2004,4:1227-1238
[60]Kelly W K, Marks P A. Drug insight:Histone deacetylase inhibitors development of the new targeted anticancer agent suberoylanilide hydroxamic acid[J].Nat Clin Pract Oncol,2005,2:150-157
[61]Flipo M, Beggyn T, Charton J, et al. A library of novel hydroxamic acids targeting the metallo-protease family:Design, parallel synthesis and screening[J]. Bioorg Med Chem Lett,2007,15(1):63-76
[62]Nuti E, Orlandini E, Nencetti S, et al. Carbonic anhydrase and matrix metallopro-teinase inhibitors, inhibition of human tumor-associated isozymes IX and cytosolic isozyme Ⅰ and Ⅱ with sulfonylated hydroxamates[J].Bioorg Med Chem Lett,2007,15(6):2298-2311
[63]Charrier C, Roche J, Gesson J R, et al. Antiproliferative activities of a library of hybrids between indanones and HDAC inhibitor SAHA and MS-275 analogues[J].Bioorg Med Chem Lett,2007,17(22):6142-6146
[64]Oyelere A K, Green P, Guerrant W, et al. Synthesis and receptor binding properties of chimeric peptides containing a μ-opioid receptor ligand and nociceptin/orphanin FQ receptor ligand Ac-RYYRIK-amide[J].Bioorg Med Chem Lett,2008,16(18):4839-4841
[65]Kim H K, Lee K, Park B W, et al. Synthesis, enzymatic inhibition, and cancer cell growth inhibition of novel δ-lactam-based histone deacetylase (HDAC) inhibitors[J].Bioorg Med Chem Lett,2006,16(15):4068-4070
[66]Marson C M, Mahadevan T, Dines J, et al. Structure-activity relationships of aryloxyalkanoic acid hydroxyamides as potent inhibitors of histone deacetylase[J].Bioorg Med Chem Lett,2007,17(1):136-141
[67]Belvedere S, Witter D J, Yan J M, et al. Aminosuberoyl hydroxamic acids (ASHAs):A potent new class of HDAC inhibitors[J].Bioorg Med Chem Lett,2007,17(14):3969-3971
[68]Lee S, Shinji C, Ogura K, et al. Design, synthesis, and evaluation of isoindolinone-hydroxamic acid derivatives as histone deacetylase (HDAC) inhibitors [J].Bioorg Med Chem Lett,2007,17(17):4895-4900
[69]Hanessian S, Auzzas L, Giannini G, et al. ω-Alkoxy analogues of SAHA (vorinostat) as inhibitors of HDAC:A study of chain-length and stereochemical dependence[J].Bioorg Med Chem Lett,2007,17(22):6261-6265
[70]Chen X T, Corbett R L, Covington M B, et al. A new 4-(2-methylquinolin-4-ylmethyl) phenyl Pl'group for the β-amino hydroxamic acid derived TACE inhibitors[J].Bioorg Med Chem Lett,2007,17(7):1865-1870
[71]Su H, Nebbioso A, Carafa V, et al. Design, synthesis and biological evaluation of novel compounds with conjugated structure as anti-tumor agents[J].Bioorg Med Chem,2008,16(17):7992-8002
[72]李云兰,王晓剑,杨莉,等.高效液相色谱法测定抗癌原料药芳香异羟肟酸二丁基锡[J].分析实验室,2007,26(8)：21-24
[73]李青山,尚先梅,吴军.芳香异羟肟酸有机锡抗癌化合物的初步构效关系[J].中国科学,2008,38(5)：429-440
[74]王亚琦,边占喜.1’-庚基二茂铁异羟肟酸稀土螯合物的合成与表征[J].稀土,2008,29(3)：1-4
[75]蒋玉仁,胡岳华,曹学锋.新型螯合剂COBA的结构与捕收性能的关系[J].中国有色金属学报,2001,11(4)：702-706
[76]车丽萍,余永富,庞金兴等.羟肟酸类捕收剂的合成、性质及在稀土矿物浮选中的作用机理[J].稀土,2004,25(6)：74-80
[77]Bolm C, Kuhn T. Asymmetric epoxidation of allylic alcohols using vanadium complexes of (N)-hydroxy-[2.2]paracyclophane-4-carboxylic amides[J]. Synlett,2000,6:899-901
[78]Hoshino Y, Yamamoto H. Novel a-Amino acid-based hydroxamic acid ligands for vanadium-catalyzed asymmetric epoxidation of allylic alcohols[J].J Am Chem Soc,2000,122:10452-10453
[79]Li H B, Li J Z, Qin S Y. Synthesis, oxygenation and catalytic expoxidation performance of transition-metal hydroxamate with benzo-15 Crown-5 transition[J].Met Chem,2006,31:129-134
[80]吕志凤,李鸿波,战风涛,等.异羟肟酸过渡金属配合物的合成和催化氧化性能研究[J].四川大学学报(自然科学版),2000,37(3)：426-431
[81]陈骏如,张瑞,胡家元等.羟胺酸钴配合物催化混合二甲苯的选择性氧化性氧化[J].化学研究与应用,2002,14(2)：178-181
[82]Li H B, Hao M A, Qin C, et al. An efficient aerobic oxidation for p-xylene to p-toluic acid catalyzed by cobalt (Ⅱ) hydroxamates with benzo-15-crown-5[J].React Kinet Catal Lett,2007,91(2):299-306
[83]Li H B, Qin C, Yang W B, et al. Dioxygen affinities and catalytic oxidation performance of cobalt(Ⅱ) hydroxamates with benzo-15-crown-5 pendants[J] Chin.Chem.Lett,2007,18(1):103-106
[84]刘富安,李建章,黄生田,等.聚醚桥连二异羟肟酸配合物催化羧酸酯水解的动力学研究[J].化学研究与应用,2005,17(4)：507-510
[85]黄生田,李建章,刘富安等.聚醚桥连二异羟肟酸双核配合物催化PNPP水解的反应动力学[J].催化学报,2005,26(1)：43-48
[86]Li J Z, Li H B, Xie J Q, et al. PNPP catalytic hydrolysis by mono-and binuclear transition-metal complexes with polyether-bridged dihydroxamic acids[J].Transition Met Chem,2004,29:823-829
[87]Xiang Y, Zeng X C, Cheng S Q, et al. Metallomicellar catalysis cleavage of p-nitrophenyl picolinate catalyzed by binuclear meta cmplexes coordinating tripeptide in CTAB micellar solution[J].J Colloid Interface Sci, 2001,235(1):114-118
[88]Yazal El J, Pang Y P. Proton dissociation energies of zinc-coordinated hydroxamic acids and their relative affinities for zinc:insight into design of inhibitors of zinc-containing proteinases[J].J phys Chem B, 2000,104(27):6499-6504
[89]江浩,常志远,潘永军,等.异羟肟酸型配位体对TBP萃取金属钚行为的影响研究[J].核化学与放射化学,2000,22(1)：1-7
[90]郑卫芳,刘黎明,常志远.乙异羟肟酸改善Purex流程铀产品中U-Pu的分离[J].原子能科学技术,2000,34(2)：110-115
[91]郑卫芳,江浩,朱建明,等.短链羟肟酸对Pu(Ⅳ)的配位、还原及反萃[J].核化学与放射化学,2003,25(2)：65-68
[92]张平,刘秀琴,王建晨,等.乙异羟肟酸TRPO简化流程中的应用[J].核化学与放射化学,2004,26(3)：158-161
[93]王碧,许桂丽,胡星琪.含羟肟酸侧基高分子重金属捕收剂处理含铅废水的研究[J].化学研究与应用,2008,20(5)：561-564
[94]符剑刚,钟宏,张正国,等.以猪油为原料合成羟肟酸[J].中南大学学报(自然科学版),2004,35(2)：239-243
[95]Esteves M A,Vaz M CT, Gonsalves M, et al. Siderophore analogues,Synthesis and chelating properties of a new macrocyclic trishydroxamate ligand[J].J Chem Soc, Dalton Trans,1995,15:2565-2573
[96]曾伟,曾贵玉,秦圣英.异羟肟酸的合成与应用研究进展[J].有机化学,2003,23(11)：1213-1218
[97]Reddy A S,Kumar M S, et al. A convenient method for the preparation of hydroxamic aids[J].Tetrahedron Lett,2000,41(33):6285-6288
[98]Appendino G, Berton L, Minassi A, et al. An expeditious hydroxyamidation of carboxylic acids[J].Tetrahedron Lett,2005,46(31):5113-5115
[99]Yamada K, Kanekiyo T, Tanaka S, et al. Novel intramolecular photo-rearrangement of alkane nitronate anions[J].J Am Chem Soc,1981,103 (23):7003-7005
[100]Chittari P, Thomas A, Rajappa S. Synthesis of novel cyclic hydroxamic acids[J].Tetrahedron Lett,1994,35(22):3973-3976
[101]Rajappa S, Thomas A. Synthesis of cyclic hydroxamic acids from aliphatic nitro compounds[J].Tetrahedron,1995,51(38):10571-10580
[102]Brewer G A, Sinn E. Oxidation of phenacetin and related amides to their hydroxamic acids, crystal structures of the dioxomolybdenum(VI) hydroxamates derived from phenacetin and acetanilide[J].Inorg Chem,1981,20(6):1823-1830
[103]Neset S M, Benneche T, Undheim K. Synthesis of cyclic hydroxamic acids by oxidation of secondary amines with dimethyldioxirane[J].Acta.Chem.Scand, 1993,47(11):1141-1143
[104]Murahashi S, Oda T, Sugahara T, et al. Tungstate-catalyzed oxidation of tetrahydroquinolin es with hydrogen peroxide:A novel ethod for the synthesis of cyclic hydroxamic acids[J].J Org Chem,1990,55(6):1744-1749
[105]Corbett M D, Corbett B R. Reaction of nitroso aromatics with glyoylic acid. A new path to hydroxamic acids[J].J.Org.Chem,1980,45(14):2834-2839
[106]Ursie S.Nigovie B,Vreek V, et al. Formation of hydroxamic acids promoted by metal ions, interaction of aldehyde carbonyl group with C-nitroso group in the presence of ferric ions[J].Tetrahedron Lettl995,36(52):9547-9550
[107]Richter L S, Desai M C.A TFA-cleavable linkage for solid-phase synthesis of hydroxamic acids[J].Tetrahedron Lett,1997,38(3):321-322
[108]Golebiowski A, Klopfenstein S. Solid supported synthesis of hydroxamic acids[J].Tetrahedron lett,1998,39(21):3397-3400
[109]Choi J, Park J G, Pang Y P. Convenient synthesis of a library of discrete hydroxamic acids using the hydroxythiophenol (Marshall) resin[J].Tetrahedron Lett,2008,49(7):1103-1106
[110]Szarka Z, Skoda-Folder R, Kollar L, et al. Highly efficient synthesis of steroidal hydroxamic acid derivatives via gomogeneous catalytic carbonylation reaction[J].Tetrahedron,2000,56(29):5253-5257
[111]见百熙.浮选药剂[M].北京工业出版社,1981：310-314
[112]Hussain S A, Demirci S, Ozbayoglu G. Zeta potential measurements on three' clays from Turkey and effects of clays on coal flotation[J].J Colloid Interface Sci,1996,184(2):535-541
[113]Liu G Y, Zhong H, Hu Y H, et al.The role of cationic polyacryamide in the reverse fotation of diaspric bauxite[J].Miner Eng,2007,20(13):1191-1199
[114]Wang Y H, Huang, C B, Hu Y H, et al. Benefication of diaspore-bauxite ore by selective flocculation with a polyacrylate flocculant[J].Miner Eng, 2008,21(9):664-672
[115]Huang C B, Wang, Y H. Removal of aluminosilicates from diasporic-bauxite by selective flocculation using sodium polyacrylate[J].Sep Purif Technol,2008, 59:299-303
[116]黄传兵,王毓华,兰叶.有机絮凝剂HSPA分选一水硬铝石型铝土矿的机理[J].中国有色金属学报,2006,16(7)：1250-1256
[117]Cao X F, Hu Y H, Xu J. Synthesis of γ-alkoxy-propylamines and their collecting properties on aluminosilicate minerals[J].J Cent South Univ Technol 2004,11(3):280-285
[118]Zhao S M,Wang D Z, Hu Y H, et al. Flotation of aluminosilicates using N-(2-aminoethyl)-1-naphthaleneacetamide[J].Miner Eng,2003,16 (10):1031-1033
[119]蒋昊,胡岳华,覃文庆,等.直链烷基胺浮选铝硅矿物机理[J].中国有色金属学报,2001,11(4)：687-692