用户名: 密码: 验证码:
新型干式微孔过滤除尘器控制黑烟污染的实验研究
详细信息    本馆镜像全文|  推荐本文 |  |   获取CNKI官网全文
摘要
我国是目前世界以煤为主要能源的国家之一,工业燃煤陶瓷窑炉在煤的燃烧过程中会产生大量的黑烟。黑烟的主要成分是炭黑,造成了严重的大气污染。炭黑粒径较小,并具有疏水性的表面。由于炭黑的特殊性质,传统的烟尘治理技术难以有效去除炭黑。
     本论文首先从炭黑粒子产生的机理出发,对炭黑的物理化学性质作了深入的研究,为后面黑烟的去除作好准备。在对炭黑特性的详细研究、阅读大量文献的思考后提出了一种去除炭黑的新方法:对传统袋式除尘器进行改造、更新,采用陶瓷质微孔管代替传统的纤维滤料,研制开发出一种新型干式微孔过滤除尘器,用干法过滤去除黑烟。
     微孔陶瓷具有很好的化学稳定性和热稳定性,且机械强度高,刚性大,不容易外形变化和孔径变型,气孔分布均匀,使用寿命长,再生、清渣简易,维修方便,运行费用低。可以代替棉布、丝织物、塑料、贵金属网等滤材。价格低,并消除了这些滤材存在的缺陷,从而提高生产效率,降低生产成本,取得显著的经济效益。微孔陶瓷的这些优异性能,使它在化工、石油、冶金、机械、炼油、纺织、医药、食品、酿酒、火电、电镀、核工业等行业中广泛用于扩散、吸收、混合、流态化、过滤等操作。还可用作催化剂载体。在环保领域中,更显出微孔陶瓷在治理“三废”方面的独特功能和使用价值。
     本实验通过对微孔陶瓷干法过滤除尘器的研究,了解并介绍了微孔陶瓷滤料的基本性质。通过在不同的入口粉尘浓度和过滤速度的状态下对该设备进行测试,对风量、反吹时间等的具体操作方式进行了调整,让整个设备工作方式更加合理。并对反吹,粒径分布,分级效率等问题做了更加深入的研究和探讨。同时对设备本身的压力损失等工作情况做了初步的校核和测量,以供参考。
In China the fuel of most industrial ceramic kilns depends on coal.During the burning of the industrial coal-burning ceramic kilns, much black smoke created. It brings grave air-pollution It also do harm to surrounding environment and people’s health .Its main component is carbon black. Because of the pricular characteristics of carbon black----the surface of it is hydrophobic and its partical is very tiny and wispy, dust remove technique can not remove it efficiently.
     This paper made in-depth studies for the mechanism of the physical and chemical properties and made a prepared for removing the carbon black. A new method had been proposed after reading lots of documents carbon black: use of microporous ceramic tube instead of the traditional fiber filter, developed a new kind of dry microporous filtration dust catcher to remove the carbon black.
     The microporous ceramic tube has good chemical and thermal stability ,high mechanical strength and rigidity, it’s shape and aperture variant is not easy to change and the pore distribution is uniform it has long service life, regeneration, easy maintenance and low-cost operation. it can substitute for cotton, silk, fabrics, plastics, metals net filter and low prices . Microporous ceramic these excellent performance make it in the chemical, petroleum, metallurgy, machinery, petroleum refining, textiles, medicine, food, wine, thermal power, electroplating, the nuclear industry are wide used in industries such as proliferation, absorption, and mixed flow pattern , filtering operation. Also can be used as catalyst support. In the field of environmental protection, it is even more porous ceramic show in the governance of the "three wastes" and the unique features of value.
     Through studying the dry-type microporous filtration dust catcher and understand the fundamental nature. Through the entrance of dust in different concentration and the filtration rate of the state of equipment to test the air flow, purge-time specific mode of operation have been adjusted so that the entire equipment working methods more reasonable. And done a more in-depth study about back blowing, particle size distribution, issues such as efficiency grading and discussion. At the same time the pressure on the equipment itself, such as loss of work done a preliminary check and measurement,for reference.
引文
[1] 姜志勇,赵利民,孙柏峰.大气污染及其控制对策[J].长春大学学报,2004,14(8):2-83
    [2] 沈鸿,羌宁.燃煤窑炉黑烟消除技术[J].能源环境保护,2003,4(17):34-36
    [3] 黄宾.陶瓷仿古砖生产的技术演变[J].佛山陶瓷,2005,102(6):1-3
    [4] 史君洁.再论燃煤黑烟治理[J].玻璃与搪瓷,1999,28(3):58-63
    [5] 郝吉明,马广大.大气污染控制工程[M].北京:高等教育出版社,2002:213-214
    [6] 金智新,于红.我国亟待实施优质煤炭资源储备战略[J].中国煤炭,2005,31(12):29-31
    [7] 方理力.工业炉窑的环境污染治理探讨[J].有色设备,2000,36(5):8-12
    [8] 陈继真,赵麦群,杨君刚等.渗碳滴剂的热解特性及炭黑的形成过程[J].西安理工大学学报,1996,12(1):21-31.
    [9] 朱兆华,李兆新.陶瓷窑炭黑消除试验[J].化学工业与工程技术,1998,19(2):31-32.
    [10] 黄浪欢,曾令可,任雪潭等.陶瓷窑炉 NOx 的污染与防治[J].中国陶瓷,2000,36(6):23-25
    [11] 刘永杰,孙杰理,离树恒等.以煤为燃料的热工设备中黑烟的产生原因及防治[J].济南大学学报,2002,16(1):56-58
    [12] 沈帅冰.浅谈建筑陶瓷厂生产中的除尘措施[J].山东陶瓷,2000,23(3):29-31
    [13] 黄学敏,张承中.大气污染控制工程实践教程[M].北京:化学工业出版社,2003:24-25.
    [14] Dod R L, Brown N J,Mowrer F W.Smoke emission factors from medium-scale Fires.Part2[J].Aerosol Science and Technology,1989,10(1):20-27
    [15] Oberdorster G., Geliein R M, Ferin J.et al. Association of particulate air pollution and acute mortality in volvement of ultra fine particle[J]. Inhalation Topical,1995,136(7):111-124
    [16] Goldstein B D. The relationship between respiratory illnesses in primary school Children and the use of gas for cooking[J]:II.Factors affecting nitrogen dioxide levels in the home Int. Epidemiol,1979,321(8):339-345
    [17] Seaton A , Dennekamp M , Hypothesis ill health associated with new concentration of nitrogen dioxide an effect of ultra fine particles.Thorax,2003,58(9):1012-1015
    [18] Zhao Juan Yang , Xu dong . Photo catalytic oxidation for indoor airpurification[J].Building and Environment,2003,38(5):645-654
    [19] Charles J,Wescheler,Helen C.Shields indoor ozone terrene reactions as a source of indoor particles[J].Atmos Environ,1999,33(15):2301-2312
    [20] 夏清,曾光明,李彩亭等.陶瓷工业窑炉烟气一体化治理研究[J].陶瓷,2000,146(4):18-21
    [21] Alexia A . Air pollution in Athens basin and health risk assessment[J] Environmental Monitoring and Assessment,2002,80(3):277-299
    [22] 邹力力,高思源.建筑陶瓷工业的粉尘危害及安全评价[J].能源及环境,2007,18:21-23
    [23] 何亚丽,朱伟萍.燃煤型硫氧化物的控制对策[J].煤炭工程,2005,18:37-39
    [24] 贾毅峰,兰雯.浅谈氮氧化物的污染与治理技术[J].广西轻工业,2007,9:98-99
    [25] 中国医学科学院卫生研究所卫生防护研究室[M].烟气测试技术.北京:人民卫生出版社,1981:20-24
    [26] 张士信,刘艳萍,诸葛福乐.消烟反烧燃煤机在日用陶瓷隧道窑上的应用[J].山东陶瓷,2000,23(2):12-14
    [27] 史君洁.关于燃煤工业炉窑黑烟治理技术的评价[J].中国环保产业,2004,36(5):34-36
    [28] Calle S,Contal P,Thomas D,et al.Evolutions of efficiency and pressure drop of filter media during clogging and cleaning cycles[J].Powder Technology,2002,12(6):213-217.
    [29] 管诗骈,高翔,谭永杰等.燃烧过程中炭黑颗粒生成机理的研究发展[J].能源与环境,2003,12(3):31-34.
    [30] 陈卫华.锅炉烟气湿式净化技术研究[J].环境工程,2001,19(5):35-37
    [31] Frenklach M,Warnatz J.Detailed modeling of PAH profiles in a sooting low pressure acetylene flame.Combust,1987,51(6):265-273
    [32] Anna D,Violi A.A kinetic model for the formation of aromatic hydrocarbons in premixed laminar flames.Powder Technology,1998,12(3):101-110
    [33] COLKETMB,HALL R J. SootFormation in Combustion(Bockhorn H,ed.: Success and Uncertainties in Modeling SootFormation in Laminar,Premixed Flame .Berlin:Springer Verlag,1994,43-57
    [34] 米文霞,杜志军,谷进军.燃煤锅炉的节能环保改造与技术管理[J].设备管理与维修,2005,(6):37-39
    [35] 李玉林.倒焰窑消烟除尘的技术原理与工艺设计[J].福州大学学报(自然科学版),19971997,25(5):121-123
    [36] 李秀林.烟气污染治理燃煤倒焰窑烟尘治理方案初探[J].环境工程,2001,19(3):30-33
    [37] 李志华.袋式除尘器所用滤料分析[J].特种橡胶制品,2004,25(3):37-40
    [38] R.A.科比特.环境工程标准手册[M].北京:科学出版社,2003:436-441
    [39] 周露亮,石棋,罗民华等.燃煤窑炉烟尘治理措施的探讨[J].中国陶瓷工业,1999,6(3):21-25
    [40] Shemwell,Brooke,Atal ,et al.A labor investigation on combined in-furnace sorbent injection and hot flue-gas filtration to simultaneously capture SO2,NOX , HCl and particulate emission[J] . Environmental Science and Technology,2000,34(22):4855-4866
    [41] 宋君祥,刘华,寇志奇等.刚玉 2 莫来石 2 碳化硅质过滤器的开发[J].耐火材料,1997:31(3):156-158
    [42] 朱新文,江东亮,谭寿洪.多孔陶瓷的制备、性能及应用:(1)多孔陶瓷的制造工艺[J].陶瓷学报,2003,24(1):40-45
    [43] 徐振平,郭敏.一种孔径分布能控制的多孔陶瓷[J].硅酸盐通报,1996(4):49-60
    [44] 孙宏伟,谢灼利,郑冲.微孔α -Al2O3 陶瓷膜管的制备与性能[J].无机材料学报,1998,13(5):698-702
    [45] Sundermann E,Viedt J.Method of manufacturing ceramic foam bodies.US Pat, No,3745201,1973-07-10
    [46] 吴皆正,易石阳,欧阳琨.可控微米级多孔陶瓷的研制[J].硅酸盐通报,1993(3):4-9
    [47] Lyckfeldt O , Ferreia J M F . Processing of Porous Ceramics by Starch Consolidation.J Eur Ceram Soc,1998,18:131-140
    [48] Liu D M.Control of pore geometry on influencing the mechanical p roperty of porous hydroxyapat2atite bioceramic. Mater Sci Lett,1996,15(6):419-421.
    [49] Film B D,Bordia R K,Zimmerman A,et al.Evolution of defect size and strength of porous alumina during sintering.Eur Ceram Soc,2000,20:2561-2568.
    [50] Werner K, Maria S. Method of manufacturing porous sintered inorganic bodies with large open pore volume.US Pat,No,4588540,1986-05-13.
    [51] Zhang G J,Jian F Y,Tatsuki O.Fabrication of porous ceramics with directionlly aligned continuous pores.J Am Ceram Soc,2001,84(6):1395-1397.
    [52] Schwartzwalder K,Arthur H,SomersV,et al.Method of Making porous ceramic articles.US Pat,No,3090094,1963-05-21.
    [53] Washbourne,Colin.Catalyst Carriers.US Pat,No,3972834,1976-08-03.
    [54] 李安明,唐竹兴,王树海等.陶瓷注凝成型工艺的新进展[J].现代技术陶瓷,1998(2):26231.
    [55] 范小林,冯春祥,宋永才等.先驱体转化发制备耐腐蚀性过滤器用多孔陶瓷材料:(1)泡沫状多孔先驱体的合成 [C].中国空间科学学会空间材料专业委员会“99”学术交流会,昆明,1999 年 8 月,93-99.
    [56] Sieber H,Vogli E,Mullier F,et al.CV I2R gas phase processing of porous biomorphic SiC ceramics.Key EngMater,2002,19(3):206-213.
    [57] Hong L S,Lai H T.Pore structure modification of porous support by PPCVD: A technique to Reduce permeability loss. J Chin Inst Chem Eng,1999,30(3):189-197.
    [58] 张华民,王志群.无机分离膜的研究现状与发展前景.无机分离膜的制备与表征[J].无机材料学报,1993,8(1):4-5
    [59] 朱承翔,路庆华.从《SCIENCE》和《NATURE》文献看多孔材料制备的最新动态[J].化工新型材料,2000,29(1):22-25
    [60] Sofie S W,Dogan F.Freeze Casting of Aqueous Alumina Slurries with Glycerol.J Am Ceram Soc,2001,84(7):1459-1464.
    [61] 马文,沈卫平,董红英,等.多孔陶瓷的制造工艺及进展[J].粉末冶金技术,2002,20(6):365-368
    [62] Takayuki F,Motohide A.Synthesis of porous ceramics with complex pore structure by freeze dry processing.J Am Ceram Soc,2001,84(1):230-232
    [63] Kiyoshi A,John W H.Porous ceramic bodies with interconnected pore channels by a novel freeze casting technique.J Am Ceram Soc,2005,88(3):777-779.
    [64] Omatete O , Janney M A . Gel2casting a new ceramic forming p rocess[J].American ceramic society bulletin,1991,70(10):1641-1650.
    [65] Sepulveda P,Qrtega F S,Innocentini M,et al.Properties of highly porous hydroxyapatite obtained by the gel2casting of foams.J Am Ceram Soc,2000,83(12):3021-3024.
    [66] 贾天敏,江度,刘素英等.过滤器净化金属液机理及含过滤器的浇铸系统设计[J].铸造,1998(5):22-26
    [67] 刘辉,孙伟,覃文庆,等.多孔陶瓷材料的应用及发展前景[J].矿冶工程,2003,23(6):69-71
    [68] 韩永生,李健保,魏强民.多孔陶瓷材料应用及制备的研究进展[J].材料导报,2002,16(3):26-29
    [69] Berthold N,Sabine T,Rainer S,et al.Porous bore rep lacement materials.USPat,No,5650108,1997-07-22.
    [70] Keisuke I,Akiral A.Dentalmaterial. US Pat,No.5869548,1999-02-09.
    [71] 金宗哲,卫罡,黄丽容.微米多孔陶瓷板及制备方法 [P].中国专利,No.CN1657501,2005-08-24.
    [72] 姚强.大气污染和固体废物的防治[M].北京:中国环境保护产业协会,2004:121-165
    [73] Hsiao Lin Huang,Shin Hao Yang.Characteristics of polysulfone membrane filters[J].Journal of Aerosol Science,2006,6(1):163-167
    [74] 李志华.袋式除尘器所用滤料分析[J].特种橡胶制,2004,25(3):37-40
    [75] 孙嘉如,梁三定,周铁祥等.袋式除尘器集中除尘与新技术应用[J].建材发展导向,2004,(1):78-81
    [76] 王琳,施永生.改性滤料表面结构特性的研究[J].有色金属,2005,32(3):53-56
    [77] Humphries W.Influence of cloth structure on dust dislodgement from fabric filters[J].Powder Technology,1981,(28):189
    [78] Ellenbecker M.J,Leith D.Dust removal from non-woven fabrics-cleaning methods need to be improved[J].Filtration,1981,18(9):316-319

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700