摘要
既节能又产能的废水厌氧生物处理工艺符合可持续发展原则的治理废水途径,其在工业废水处理中成功应用的关键在于高效厌氧生物反应器的发展和应用。基于传统的厌氧折流板反应器(ABR)发展而来的新型高效厌氧生物反应器——周期厌氧折流板反应器(PABR)在处理实际工业废水的运行模式优化、水力学特性和微生物学特性等方向尚存空白丞待研究,为此本文采用一种4隔室PABR在三种不同的阀门切换模式和频率下处理实际中药废水,分别在进水平均有机负荷率(OLR)约为1,2,4和6kgCOD/(m3·d)的条件下运行了12,24,24和6d,水力停留时间(HRT)恒为2d。
运行结果表明,无论采用何种阀门切换模式,稳定时PABR各隔室气体甲烷百分含量、pH和碱度均沿程递增,但挥发性脂肪酸(VFA)沿程递减。OLR的提升导致出水化学需氧量(COD)和VFA的增加。顺时针切换模式运行的PABR在OLR=4.38kgCOD/(m3·d)时,COD去除率可达86.36﹪,但在OLR提升至均值6kgCOD/(m3·d)后迅速酸化;不切换模式运行的PABR在OLR=6.45kgCOD/(m3·d)时,COD去除率可达92.51﹪,但气体产量过大所引起的生物固体迁移和流失导致气体产量隔室和COD去除率最大的隔室沿程向后迁移,使得前两个隔室因为累积了大量的VFA而酸化;每隔一隔室切换模式运行的PABR在OLR=6.37kgCOD/(m3·d)时,COD去除率可达92.51﹪,用于中药废水处理的长期运行具备更强的适应性和稳定性。无论切换模式、隔室流序和OLR如何,进水及各隔室上清液的分子量分布(MWD)谱图定性分析的变化趋势与它们COD浓度及去除率、甲烷产量和气体产量定量变化的趋势是一致的。
水力学特性研究结果表明,PABR与其他反应器相比死区很少,这与ABR是相同的。PABR的死区分为生物死区和水力死区两部分。空反应器停留时间分布(RTD)试验中每隔一隔室切换模式运行的PABR死区最小;不切换模式运行的PABR死区最大。接种种泥后,无论OLR大小如何,其死区比较结果与空反应器比较结果相同。无论切换模式如何,生物死区成为PABR死区大小的主要贡献者,但生物死区的影响随OLR的提升而降低。在所有试验条件下,PABR的流动模式处于平推流和完全混合的“中间状态”。
采用变性梯度凝胶电泳(DGGE)分析PABR内微生物群落动态变化的结果表明,无论采用何种阀门切换模式,PABR各隔室内微生物多样性及群落结构均不相同;而同一隔室在不同OLR条件下达到稳定时的群落结构和优势种群数量具有时序动态性。各隔室内部微生物群落的动态变化趋势与PABR效能的变化趋势相符。在相同的OLR提升方案下,切换模式和频率的不同对各隔室内部微生物群落结构动态变化的不同起决定性作用。
The successful application of anaerobic technology, which can economize and generate energy and accords with the principles of sustainable development in approach of wastewater treatment, to the treatment of industrial wastewaters is critically dependent on the development, and use, of high rate anaerobic bioreactors. Periodic anaerobic baffled reactor (PABR), which is a novel reactor based on anaerobic baffled reactor (ABR) design concept, is required to investigate for operating manner optimization, hydrodynamic characteristics and microorganism characteristics in actual industrial wastewater treatment. Therefore, a four-compartment PABR was used to treat actual Chinese traditional medicine wastewater run in various switching manners and frequencies continuously at stable hydraulic residence time (HRT) of 2d, using a feed with average organic loading rates (OLRs) at about 1, 2, 4 and 6 kgCOD/(m3·d) for 12, 24, 24 and 6 d respectively.
Operating results showed that methane percentage of biogas and pH and alkalinity increased while volatile fatty acids (VFA) concentrations decreased along the reactor at stable state whichever switching manner the PABR run in. A raised OLR lifted the chemical oxygen demand (COD) concentration and VFA concentrations in effluent. The PABR operated in an‘clockwise sequential’switching manner, of which COD removal rate was 86.36﹪at OLR =4.38kgCOD/(m3·d), soured fast after average OLR at about 6kgCOD/(m3·d). Movement and losing of solids caused by great gas production led to the compartment with both maximum gas production and maximum COD removal rate moved along the PABR run in a T=∞switching manner, of which COD removal rate was 92.51﹪at OLR=6.45kgCOD/(m3·d), leaving the two front compartments soured with cumulative VFA. The PABR operated in an‘every second’switching manner, of which COD removal rate was 92.51﹪at OLR=6.37kgCOD/(m3·d), had better adaptability and stability treating Chinese traditional medicine wastewater in the long run. The variation trend of qualitative analysis on molecular weight distribution (MWD) chromatogram of influent and of bulk liquid from each compartment was consistent with the alteration trend of COD concentration, COD removal rate, gas production and methane production in each compartment of PABR no matter what the switching manner, and the compartment sequence and the OLR were.
Results from hydrodynamic characteristics research showed that the fraction of dead space in PABR was similar to that in ABR, which was low in comparison with other reactor designs. Dead space may be divided into two categories, hydraulic and biological. In RTD studies without biomass the hydraulic dead space in the PABR run in an‘every second’switching manner was the lowest while that in the PABR run in a T=∞switching manner was the highest. The same trend was obtained with the total dead space in RTD studies with biomass no matter what the OLR was. Biological dead space was the major contributor to dead space but affected decreasingly at higher OLR whichever switching manner the PABR run in. The flow patterns within the PABRs were intermediate between plug-flow and perfectly mixed under all the conditions tested.
Results from denaturing gradient gel electrophoresis (DGGE) analysis of dynamic changes in microbial communities in PABR showed that microbial diversity and community structure were different between the compartments no matter which switching manner the PABR run in. Microbial community structure and dominant community amount in stable state at different OLR were temporally dynamic in one compartment. The trend of dynamic changes in microbial communities in each compartment accorded with the trend of alteration in performance of PABR. Under the same lifting of OLR, the difference in dynamic changes in microbial communities in each compartment depended on the difference in switching manner and frequency.
引文
1 Iza J., Colleran E., Paris J. M., et al. International workshop on anaerobic treatment technology for municipal and industrial wastewaters: summary paper. Wat. Sci. Technol. 1991, 24(8): 1~16
2 Weiland P. and Rozzi A. The start-up, operation and monitoring of high-rate anaerobic treatment systems: discussers report. Wat. Sci. Technol. 1991, 24(8): 257~277
3 Barber W. P. and Stuckey D. C. Start-up strategies for anaerobic baffled reactors treating a synthetic sucrose feed. Proceedings of the 8th International Conference on Anaerobic Digestion, Sendai, Japan. 1997, 2: 32~39
4 陈琰,沈耀良.厌氧折流板反应器处理低浓度废水运行特性试验.苏州科技学院学报(工程技术版).2006,19(4):35~38
5 宋铁红,高艳娇,张勇.ABR 反应器处理低浓度污水启动试验研究.环境科学与技术.2006,29(1):26~27
6 Witthauer D. and Stuckey D. C. Laboratory studies on anaerobic processes to treat dilute organic waster in developing countries. Study by IRCWD, EAWAG Dübendorf, Switzerland. 1982
7 Grobicki A. M. W. and Stuckey D. C. The role of formate in the anaerobic baffled reactor. Water Research. 1989, 23(12): 1599~1602
8 Henze M. and Harremo?s P. Anaerobic treatment of wastewater in fixed film reactors: a literature review. Wat. Sci. Technol. 1983, 15(8/9): 1~101
9 Boopathy R. and Tilche A. Anaerobic-digestion of high-strength molasses waste-water using a hybrid anaerobic baffled reactor. Water Research. 1991, 25(7): 785~790
10 Nachaiyasit S. The effect of process parameters on reactor performance in an anaerobic baffled reactor. PH.D. Dissertation, Department of Chemical Engineering, Imperial College, London, U.K. 1995
11 Nachaiyasit S. and Stuckey D. C. The effect of shock loads on the performance of an anaerobic baffled reactor (ABR), 2. Step and transient hydraulic shocks at constant feed strength. Water Research. 1997, 31:2747~2755
12 Polprasert C., Kemmadamrong P. and Tran F. T. Anaerobic baffled reactor (ABR) process for treating a slaughterhouse wastewater. Environ. Technol. 1992. 13: 857~865
13 Orozco A. Anaerobic wastewater treatment using an open plug flow baffled reactor at low temperature. 5th International Symposium on Anaerobic Digestion, Bologna, Italy. 1988: 759~762
14 Kato M. T., Field J. A. and Lettinga G.. The anaerobic treatment of low strength wastewaters. Proceedings of the 8th International Conference on Anaerobic Digestion, Sendai, Japan. 1997, 1: 356~363
15 Alette A.M. Langenhoff, Narisara Intrachandra And David C. Stuckey. Treatment of dilute soluble and colloidal wastewater using an anaerobic baffled reactor: Influence of hydraulic retention time. Water Research. 2000, 34 (4): 1307~1317
16 沈耀良,孙立柱,管闻等.ABR 反应器处理低浓度废水的研究.江苏环境科技.2004,17(4):1~5
17 胡细全,李兆华,蔡鹤生.低浓度下冲击负荷对厌氧折流板反应器的影响.环境科学与技术.2006,29(3):76~78
18 胡细全,李兆华,蔡鹤生.厌氧折流板反应器处理低浓度废水的运行特性研究.环境污染治理技术与设备.2006,7(2):79~83
19 R. Grover, S.S. Marwaha and J.F. Kennedy. Studies on the use of an anaerobic baffled reactor for the continuous anaerobic digestion of pulp and paper mill black liquors. Process Biochemistry. 1999, 34: 653~657
20 Holt C. J., Matthew R. G. S. and Terzis E. A comparative study using the anaerobic baffled reactor to treat a phenolic wastewater. Proceedings of the 8th International Conference on Anaerobic Digestion, Sendai, Japan. 1997, 2: 40~47
21 Nachaiyasit S. and Stuckey D. C. The effect of low temperature on the performance of an anaerobic baffled reactor (ABR). J. Chem. Tech. Biotechnol. 1997, 69: 276~284
22 Lawrence A. W. and McCarty P. L. Kinetics of methane fermentation in anaerobic treatment. J. WPCF. 1969, 41: R1~R17.
23 Alette A. M. Langenhoff and David C. Stuckey. Treatment of dilutewastewater using an anaerobic baffled reactor: Effect of low temperature. Water. Research. 2000, 34(15): 3867~3875
24 胡细全,李兆华,蔡鹤生.低温对处理低浓度废水的厌氧折流板反应器性能的影响.安全与环境工程.2005,25(9):52~54
25 Boopathy R. and Sievers D. M. Performance of a modified anaerobic baffled reactor to treat swine waste. Trans. ASAE. 1991, 34(6): 2573~2578
26 Ramaraj Boopathy. Biological treatment of swine waste using anaerobic baffled reactors. Bioresource Technology. 1998, 64: 1~6
27 Fannin K. F., Srivastra V. J., Conrad J. R., et al. Marine biomass program: anaerobic digester system development. Annual Report for General Electric Company, IGT Project 65044, Institute of Gas Technology, IIT Centre, 3424 S. State Street, Chicago, IL 60616. 1981
28 Bachmann A., Beard V. L. and McCarty P. L. Comparison of fixed film reactors with a modified sludge blanket reactor, fixed film biologica processes for wastewater treatment, ed. Y. C. Wu and E. D. Smith. Noyes Data, NJ. 1983
29 Tilche A. and Yang X. Light and scanning electron microscope observations on the granular biomass of experimental SBAF and HABR reactors. Proceedings of Gasmat Workshop, Netherlands. 1987, 170~178
30 Orozco A. Pilot and full-scale anaerobic treatment of low-strength wastewater at sub-optimal temperature (15℃) with a hybrid plug flow reactor. Proceedings of the 8th International Conference on Anaerobic Digestion, Sendai, Japan. 1997, 2: 183~191
31 P.J. Sallis and S. Uyanik. Granule Development in a split-feed anaerobic baffled reactor. Bioresource Technology. 2003, 89: 255~265
32 William P. Barber and David C. Stuckey. Nitrogen removal in a modified anaerobic baffled reactor (ABR): 1, Denitrification. Water Research. 2000, 34(9): 2413~2422
33 William P. Barber and David C. Stuckey. Nitrogen Removal in a modified anaerobic baffled reactor (ABR): 2, Nitrification Water Research. 2000, 34(9): 2423~2432
34 Igor Bodik, Karol Kratochvil, Eva Gasparikova, et al. Nitrogen removal in an anaerobic baffled filter reactor with aerobic post-treatment. BioresourceTechnology. 2003, 86: 79~84
35 Chynoweth D. P., Srivastra V. J. and Conrad J. R. Research study to determine the feasibility of producing methane gas from sea kelp. Annual Report for General Electric Company, IGT Project 30502, Institute of Gas Technology, IIT Centre, 3424 S. State Street, Chicago, IL 60616. 1980
36 Fannin K. F., Srivastra V. J., Mensinger J., et al. Marine biomass program: anaerobic digester process development. Annual Report for General Electric Company, IGT Project 65044 and 30547, Institute of Gas Technology, IIT Centre, 3424 S. State Street, Chicago, IL 60616. 1982
37 Yang P. Y. and Moengangongo T. H. Operational stability of a horizontally baffled anaerobic reactor for diluted Seine wastewater in the tropics. Trans. ASAE. 1987, 30(4), 1105~1110
38 Fox P. Venkatasubbiah V. Coupled anaerobic/aerobic treatment of high-sulphate wastewater with sulphate reduction and biological sulphide oxidation. Wat. Sci. Technol. 1996, 34(5~6): 359~366
39 Boopathy R., Larsen V. F. and Senior E. Performance of anaerobic baffled reactor (ABR) in treating distillery wastewater from a Scotch whisky factory. Biomass. 1988, 16(2): 133~143
40 Garuti G., Dohanyos M. and Tilche A. Anaerobic-aerobic combined process for the treatment of sewage with nutrient removal: the Ananox1 process. Wat. Sci. Technol. 1992, 25(7): 383~394
41 Bae J. H., Song K.-B. and Cho K.-M. Comparison of operational characteristics of UASB and ABR: organic removal efficiency and the variations of PH2 and PCO. Proceedings of the 8th International Conference on Anaerobic Digestion, Sendai, Japan. 1997, 1: 164~171
42 Yang X., Garuti G., Farina R., et al. Process differences between a sludge bed filter and an anaerobic baffled reactor treating soluble wastes. 5th International Symposium on Anaerobic Digestion, Bologna, Italy. 1988, 355~360
43 Xing J. and Tilche A. The effect of hydraulic retention time on the hybrid anaerobic baffled reactor performance at constant loading. Biomass Bioenergy. 1992, 3(1): 25~29
44 Boopathy R. and Tilche A. Pelletization of biomass in a hybrid anaerobicbaffled reactor (HABR) treating acidified waste-water. Bioresource Technol. 1992, 40(2): 101~107
45 Xing J., Boopathy R. and Tilche A. Model evaluation of hybrid anaerobic baffled reactor treating molasses waste-water. Biomass and Bioenergy. 1991, 1(5): 267~274
46 Bachmann A., Beard V. L. and McCarty P. L. Performance characteristics of the anaerobic baffled reactor. Water Research. 1985, 19(1): 99~106
47 Grobicki A. M. W. and Stuckey D. C. Performance of the anaerobic baffled reactor under steady state and shock loading conditions. Biotechnol. Bioeng. 1991, 37: 344~355
48 Grobicki A. M. W. and Stuckey D. C. Hydrodynamic characteristics of the anaerobic baffled reactor. Water Research. 1992, 26: 371~378
49 Nachaiyasit S. and Stuckey D. C. Microbial response to environmental changes in an anaerobic baffled reactor (ABR). Antonie van Leeuwenhoek. 1995, 67: 111~123
50 Barber W. P. and Stuckey D. C. Influence of startup strategies on the performance of an anaerobic baffled reactor. Environ. Technol. 1998, 19: 489~501
51 Nachaiyasit S. and Stuckey D. C. The effect of shock loads on the performance of an anaerobic baffled reactor (ABR), 1. Step changes in feed concentration at constant retention time. Water Research. 1997, 31: 2737~2747
52 龚敏,赵九旭,蒲仕刁等.ABR 工艺预处理木薯酒糟废水的工程应用.环境科学与技术.2002,25(5):36~37
53 刘豆豆,乔梁,赵大传等.ABR 处理甘薯淀粉废水的试验研究.山东大学学报(工学版). 2006,36(4):70~74
54 杨玉楠,胡训杰,石强等.ABR 处理淀粉废水的反应规律研究.给水排水.2006,32(10):57~61
55 沈耀良,赵丹,王惠民.ABR 处理高浓度淀粉制品加工废水运行特性的研究.给水排水.2002,28(9):33~36
56 沈耀良,王惠民,赵丹.厌氧折流板反应器处理淀粉废水及污泥特性.上海环境科学.2002,21(3):139~142
57 陈洪斌,张国政,高廷耀.厌氧折流板反应器处理豆制品废水的研究.中国沼气.1999,17(1):12~16
58 梁拴粉,张安龙,马艳.采用厌氧折流板反应器处理爆破法草浆废液.纸和造纸.2006,25(3):54~56
59 武桐,付军,刘翔.ABR-SBR 法处理草浆造纸中段废水试验研究.环境污染治理技术与设备.2004,5(1):72~76
60 雷中方,陆雍森,徐庆平.用厌氧折流板反应器处理碱法草浆黑液.上海环境科学.1995,14(5):19~22
61 杨卿,张安龙.碱法草浆中段废水水解-酸化预处理的研究.纸和造纸.2004,8(增刊):56~58
62 杨卿,张安龙.碱法草浆中段废水的水解酸化预处理试验.中华纸业.2004,25(9):49~51
63 张安龙,曹艳娜.半化学浆制浆废水可生化性研究.中华纸业.2006,27(12):75~77
64 孙剑辉,张波,彭云辉.厌氧折流板反应器处理玉米秆纤维浆粕废水的研究.环境污染治理技术与设备.2002,3(9):83~85
65 孙剑辉,吴俊峰,张波.冲击负荷对厌氧折流板反应器运行性能的影响.水处理技术.2004,30(6):362~364
66 贺嵩邡,易辰俞,戴友芝.厌氧折流板反应器处理有机磷农药废水的研究.工业用水与废水.2002,33(4):26~28
67 潘杨,黄勇,沈耀良等.厌氧折流板反应器处理有机农药废水的试验研究.环境污染与防治.2006,28(7):504~507
68 曹晓莹,沈耀良.ABR 反应器处理草甘膦废水的研究.工业水处理.2004,24(7):28~29,50
69 沈耀良,曹晓莹.草甘膦生产废水及其厌氧处理技术.工业用水与废水.2005,36(1):29~31
70 戴友芝,施汉昌,钱易.有毒物冲击负荷对厌氧折流板反应器的影响.中国环境科学.2000,20(1):40~44
71 戴友芝,冀静平,施汉昌等.厌氧折流板反应器对有毒有机物冲击负荷的适应性.环境科学.2000,21(1):94~97
72 徐金兰,黄廷林,王志盈.聚乙烯醇(PVA)厌氧生物降解特性试验研究.环境污染治理技术与设备.2004,5(10):30~34
73 徐金兰,黄廷林,王志盈.厌氧折流板反应器处理难降解 PVA 废水.中国环境科学.2005,25(1):65~69 - 114 -
74 孙剑辉,艾涤非,高健磊等.厌氧折流板反应器处理邻硝基苯胺废水的研究.郑州大学学报(工学版).2005,26(2):60~62
75 潘艳艳,邢国平,颜玲等.缺氧折流板反应器处理苯胺废水的研究.环境保护科学.2002,28(109):24~25,47
76 孙剑辉,孙胜鹏,张波.厌氧折流板反应器处理硝基苯废水的研究.工业水处理.2005,7:69~71
77 张波,孙剑辉,王番等.厌氧折流板反应器处理硝基苯废水的研究.环境污染治理技术与设备.2006,7(4):136~138
78 张波,陈金龙,王番等.厌氧折流板反应器处理化纤厂棉浆粕综合废水的试验研究.环境污染与防治.2005,27(3):209~210
79 宋炜,付永胜,王磊等.ABR 处理猪场废水试验研究.农业环境科学学报.2006,25(增刊):172~175
80 周磊,魏好程,陈朱蕾.厌氧折流板反应器处理粪便污水的试验研究.亚热带资源与环境学报.2006,1(2)
81 巩有奎,相会强,穆兰.厌氧折流板反应器降解青霉素废水的特性研究.现代化工.2006,26(增刊):172~175
82 高艳娇,王柯菲,戴红军等.厌氧折流板反应器启动问题探讨.辽宁工学院学报.2006,26(1):60~62
83 方玲玲,周元祥.应用厌氧折流板反应器处理制药废水的研究.安徽化工.2006,140:56~57
84 吴慧芳,王世和,夏明芳等.ABR 处理印染废水水温影响特性及降解模型.工业水处理.2006,26(10):39~43
85 吴慧芳,陆继来,王世和等.折流式水解反应器处理印染前道废水进水pH 值的影响.中国沼气.2006,24(1):21~23
86 马乐凡,李晓琳.水解酸化-活性污泥法处理制浆中段废水.湖南造纸.2000,4:5~8
87 毛卫兵,陆少鸣,朱争亮.厌氧折流板反应器在制药废水处理中的研究.工业安全与环保.2004,30(10):3~5
88 买文宁,孙中党.两相厌氧系统处理抗生素生产废水.中国给水排水.2003,19(7):95~96
89 邱波,郭静,邵敏等.ABR 反应器处理制药废水的启动运行.中国给水排水.2000,16(8):42~44
90 鞠宇平,张林生.ABR-SBR 工艺处理电泳涂膜废水.中国给水排水.2003,19(2):51~52
91 张林生,鞠宇平.水解酸化-序批式活性污泥法(ABR-SBR)处理电泳废水的研究.环境污染治理技术与设备.2002,3(10):51~54
92 王向华,朱晓东,张丽等.厌氧折流板反应器/氧化沟处理高浓度淀粉废水.工业水处理.2006,26(6):66~68
93 任志勇,徐庆东.生物技术处理油田采出水的模拟试验研究.石油机械.2004,32(6):7~10
94 苏德林,王建龙,刘凯文等.ABR-BAF 工艺处理采油废水的中试研究.中国给水排水.2006,22(1):22~26
95 许国栋,胡波.生化法处理油脂化工废水.工业用水与废水.2003,34(4):42~44
96 侯思琰,庞金钊,杨宗政等.ABR 反应器结合白腐菌好氧处理对染料废水脱色的研究.天津科技大学学报.2006,21(1):40~43
97 许玉东,陈维辉,江智清.混凝沉淀-厌氧折流板反应池-两级好氧生化工艺处理毛毯废水.环境污染治理技术与设备.2002,3(5):28~30
98 杨颖波,王连俊.ABR-MBR 处理纺织废水.污染防治技术.2003,16(4):38~40
99 张彦,张立秋,肖桃生.混凝-ABR-活性污泥法组合工艺处理印染废水.广州大学学报(自然科学版).2004,3(5):470~473
100 曾国驱,任随周,许玫英等.ABR 结合 SBR 法处理印染废水的研究.微生物学通报.2005,32(6):68~73
101 吴慧芳,陆继来,王世和等.ABR 水解/生物接触氧化处理印染废水.中国给水排水.2005,21(10):52~54
102 王绍斌,刘云奎,杨学海等.亚麻生产废水两相厌氧处理的研究.工业用水与废水.2004,35(1):39~41
103 吕国强,金建.A2/O 工艺处理绢纺生产废水.中国给水排水.2003,19(6):59~61
104 杨虹,李道棠,朱章玉等.集约化养猪场冲栏水的达标处理.上海交通大学学报.2000,34(4):558~560
105 王新,倪晋仁,翟凤敏.IABR-IBAF 工艺处理猪场稳定塘废水的试验研究.四川环境.2005,24(4):1~4
106 张彤,庞金钊,孙铁军等.ABR-SBR 工艺在屠宰废水处理中的试验研究.水科学与工程技术.2006. 5: 22~24
107 朱杰,付永胜.生物脱氮处理过程中氮素转化规律的研究.环境化学.2006,25(5):624~628
108 林晓生,程汉林,张雪冰等.厌氧水解-生物铁填料法-生物接触氧化处理调味品废水的研究.广东化工.2004,2:59~61
109 郭士元,张立建,童健等.ABR-SBR 工艺处理咖啡因生产废水的中试研究.工业水处理.2007,27(1):34~36
110 沈耀良,赵丹,杨铨大等.厌氧-好氧法处理渗滤液与城市污水混合废水的可行性.污染防止技术.2000,13(2):63~67
111 王显胜,黄继国,邹东雷等.ABR-接触氧化-化学氧化组合工艺处理垃圾渗滤液方法研究.环境污染与防治.2005,27(1):53~55
112 王永广,杨剑锋.微电解水解好氧工艺处理硝基苯废水.扬州大学学报(自然科学版).2002,5(4):74~79
113 易辰俞,戴友芝,贺嵩邡.农药中间体甲基氯化物废水的处理新工艺.水处理技术.2003,29(5):286~288
114 张继杰,黄焱歆.列车集便器污水处理设备研究.铁道劳动安全卫生与环保.2006,33(3):131~134
115 Soledad Gurierrez, Alberto Hernandez and Maria Vinas. Mechanism of degradation of wool wax in the anaerobic treatment of woolscouring wastewater. Wat Sci Tech. 1999, 40(8): 17~23
116 M. Vossoughi, M. Shakeri and I. Alemzadeh. Performance of anaerobic baffled reactor treating synthetic wastewater influenced by decreasing COD/SO4 ratios. Chemical Engineering and Processing. 2003, 42: 811~816
117 J. Amirfakhri, M. Vossoughi and M. Soltanieh. Assessment of desulfurization of natural gas by chemoautotrophic bacteria in an anaerobic baffled reactor (ABR). Chemical Engineering and Processing. 2006, 45: 232~237
118 Ozlem Sel?uk Ku??u and Delia Teresa Sponza. Treatment efficiencies of a sequential anaerobic baffled reactor (ABR)/completely stirred tank reactor (CSTR) system at increasing p-nitrophenol and COD loading rates. Process Biochemistry. 2006, 36: 1484~1492
119 刘大银,毕亚凡,李庆新等.ABR 反应器处理生活污水的研究.华中师范大学学报(自然科学版).2003,37(4):514~517
120 杨秀玲,杨宗政,庞金钊等.具有硝化作用的异养菌脱除氨氮的性能研究.天津科技大学学报.2005,20(1):24~26
121 张振庭,宋铁红,王翠兰.不同填料 ABR 反应器酸化效果对比研究.吉林建筑工程学院学报.2005,22(1):41~43
122 苏鸿洋,夏雪芬,董发开.复合式折流板厌氧反应器处理城市污水.福州大学学报(自然科学版).2002,30(6):908~912
123 苏鸿洋,夏雪芬,董发开.复合式厌氧反应器处理城市污水试验研究.环境科学与技术.2003,26(3):48~50
124 杨琦,尚海涛.ABR 工艺处理生活污水研究.中国沼气.2006,24(1):9~14
125 傅嘉媛,董发开.组合式折流板厌氧池处理城镇污水(中试).中国给水排水.2003,19(13):1~4
126 苏鸿洋,夏雪芬.HABR 反应器处理城镇污水启动试验研究.云南环境科学.2006,25(1):47~49
127 信欣,胡细全,蔡鹤生.厌氧折流板反应器处理生活污水的运行特性.环境污染治理技术与设备.2005,6(10):41~44
128 孙剑辉,孙胜鹏,张波.组合式厌氧折流板反应器处理城市污水的研究.天津理工大学学报.2005,21(1):82~84
129 崔玉波,尹军,曲波等.厌氧填料折流板反应器的启动试验.中国给水排水.2002,18(7):75~76
130 H. Yu and G. K. Anderson. Performance of a combined anaerobic reactor for municipal wastewater treatment at ambient temperature. Resources Conservation and Recycling. 1996, 17: 259~271
131 徐金兰,王志盈,高峰等.HRT 与有机负荷对 ABR 各隔室净化功能的影响分析.西安建筑科技大学学报(自然科学版).2004,36(1):55~60
132 郭静,李清雪.厌氧浮动生物膜反应器与厌氧折流板反应器处理高浓度有机废水工艺比较.污染防治技术.1998,11(4):234~236
133 李清雪,华玉芝.厌氧折流板反应器处理高浓度有机废水.河北建筑科技学院学报.2003,20(3):13~14
134 徐金兰,王志盈.关于 ABR 系统中酸解过程的特征及其恢复调控问题.环境科学学报.2004,24(1):20~26
135 徐金兰,王志盈,高峰等.HRT 与有机负荷对 ABR 各隔室净化功能的影响分析.西安建筑科技大学学报(自然科学版).2004,36(1):55~60
136 徐金兰,王志盈,刘可等.ABR 系统中酸解过程的污泥特性及分析.环境污染治理技术与设备.2004,5(2):46~51
137 Williamson K. and McCarty P. L. A model of substrate utilization by bacterial films. J. WPCF. 1976, 48(1), 9~24
138 Rittmann B. E. and McCarty P. L. Variable-order model of bacterial-film kinetics. J. Environ. Eng. Division. 1978, 104 (EE5), 889~900
139 Pavlostathis S. G. and Giraldo-Gomez E. Kinetics of anaerobic treatment: a critical review. Cri. Rev. Environ. Control. 1991, 21(5,6): 411~490
140 Tjandra Setiadi, Husaini and Asis Djajadiningrat. Palm oil mill effluent treatment by anaerobic baffled reactors: Recycle effects and biokinetic Parameters. Wat Sci Tech. 1996, 34(11): 59~66
141 王存政,李建萍,黄继国等.ABR 反应器基质降解动力学有关参数的试验研究.吉林大学学报(地球科学版).2004,34(2):149~151
142 信欣,胡细全,蔡鹤生等.ABR 处理生活污水的指标沿程变化及动力学研究.环境科学与技术.2006,29(8):8~9,14
143 S. Uyanik, P.J. Sallis and G.K. Anderson The effect of polymer addition on granulation in an anaerobic baffled reactor (ABR). Part I: Process performance. Water Research. 2002, 36: 933~943
144 戴友芝,施汉昌,冀静平等.厌氧折流板反应器处理有毒废水及其污泥特性的研究.环境科学学报.2000,20(3):284~289
145 Chan OC, Liu WT and Fang HHP. Study of microbial community of brewery-treating granular sludge by denaturing gradient gel electrophoresis of 16S rRNA gene. Water Science Technology. 2001, 43: 77~82
146 Akarsubasi AT, Ince O, Oz NA, et al. Evaluation of performance, acetoclastic methanogenic activity and archaeal composition of full-scale UASB reactors treating alcohol distillery wastewaters. Process Biochemistry. 2006, 41(1): 28~35
147 Buzzini AP, Sakamoto IK, Varesche MB, et al. Evaluation of the microbial diversity in an UASB reactor treating wastewater from an unbleached pulp plant. Process Biochemistry. 2006, 41(1): 168~176
148 Zhang Y, Aiyuk S, Xu H, et al. Study of microbial community structures in UASB sludge treating municipal wastewater by denaturing gradient gel electrophoresis of 16S rDNA. Science China C (Life Science). 2005,48:128~135
149 Liu WT, Chan OC and Fang HHP. Microbial community dynamics during start-up of acidogenic anaerobic reactors. Water Research. 2002, 36: 3203~3210
150 Connaughton S, Collins G. O and Flaherty V. Development of microbial community structure and activity in a high-rate anaerobic bioreactor at 18 0C. Water Research. 2006, 40: 1009~1017
151 Park JS and Lee CH. Removal of soluble COD by a biofilm formed on a membrane in a jet loop type membrane bioreactor. Water Research. 2005, 39: 4609~4622
152 S. Uyanik, P.J. Sallis and G.K. Anderson. The effect of polymer addition on granulation in an anaerobic baffled reactor (ABR). Part II: Compartmentalization of bacterial populations. Water Research. 2002, 36: 944~955
153 Jianlong Wang, Yongheng Huang and Xuan Zhao. Performance and characteristics of an anaerobic baffled reactor. Bioresource Technology. 2004, 93: 205~208
154 徐金兰,黄廷林,王志盈.ABR 中厌氧颗粒污泥的微生物学特性.中国给水排水.2004,20(10):49~51
155 宋铁红,赵勇胜,崔玉波等.厌氧折流板反应器中酸化菌活性研究. 吉林大学学报(地球科学版).2006,36(3):429~432
156 任随周,郭俊,曾国驱等.处理印染废水的厌氧折流板反应器中的微生物种群组成及分布规律.生态学报.2005,25(9):2297~2302
157 曾国驱,任随周,曹渭等.兼性厌氧苯胺降解菌的分离鉴定及其特性.环境科学.2006,27(8):54~56
158 芦家娟,王毅力,赵洪涛等.ABR 反应器的启动及颗粒污泥特征的研究.环境化学.2007,26(1):10~16
159 胡细全,李兆华,蔡鹤生等.ABR 处理低浓度废水的启动研究.湖北大学学报(自然科学版).2005,27(2):180~183
160 J.C. Akunna and M. Clark. Performance of a granular-bed anaerobic vaffled reactor (GRABBR) rreating whisky distillery wastewater. Bioresource Technology. 2000, 74: 257~261
161 M.I. Baloch, J.C. Akunna and P.J. Collier. The performance of a phaseseparated granular bed bioreactor treating brewery wastewater. Bioresource Technology. 2007, 98: 1849~1855
162 Santegoeds CM, Ferdelman TG, Muyzer G, et al. Structural and functional dynamics of sulfate-reducing populations in bacterial bio-films. Appl Environ Microbiol. 1998, 64: 3731–3739
163 Onda S, Hiraishi A, Matsuo Y, et al. Polyphasic approaches to the identification of predominant polyphosphate-accumulating organisms in a laboratory-scale anaerobic/aerobic activated sludge system. J Gen Appl Microbiol. 2002, 48: 43~54
164 Tang Y, Shigematsu T, Ikbal, et al. The effects of microaeration on the phylogenetic diversity of microorganisms in a thermophilic anaerobic municipal solid-waste digester. Water Research. 2004, 38: 2537~2550
165 Rincón B, Raposo F, Borja R, et al. Performance and microbial communities of a continuous stirred tank anaerobic reactor treating two-phases olive mill solid wastes at low organic loading rates. Journal of Biotechnology. 2006, 121: 534~543
166 B. Calli, B. Mertoglu, K. Roest, et al. Comparison of long-term performances and final microbial compositions of anaerobic reactors treating landfill leachate. Bioresource Technology 2006, 97: 641~647
167 M. Keyser, R.C. Witthuhn, C. Lamprecht, et al. PCR-based DGGE fingerprinting and identification of methanogens detected in three different types of UASB granules. Systematic and Applied Microbiology. 2006, 29: 77~84
168 Baris Calli, Bulent Mertoglu, Bulent Inanc, et al. Methanogenic diversity in anaerobic bioreactors under extremely high ammonia levels. Enzyme and Microbial Technology 2005, 37: 448~455
169 邢薇,左剑恶,孙寓姣等.利用 FISH 和 DGGE 对产甲烷颗粒污泥中微生物种群的研究.环境科学.2006,27(11):2268~2272
170 刘彬彬,张峰,冯晓西等.对降解喹啉的厌氧生物反应器中重要功能菌群的鉴定.生态学报.2006,26(5):1390~1394
171 Lapara TM, Nakatsu CH, Pantea L, et al. Phylogenetic analysis of bacterial communities in mesophilic and thermophilic bioreactors treating pharmaceutical wastewater. Appl Environ Microbiol.2000, 66: 3951~3959
172 Silvey P, Pullammanappallil PC, Blackall L, et al. Microbial ecology of the leach bed anaerobic digestion of unsorted municipal solid waste. Water Science Technology. 2000, 41: 9~16
173 Ueno Y, Haruta S, Ishii M, et al. Changes in product formation and bacterial community by dilution rate on carbohydrate fermentation by methanogenic microflora in continuous flow stirred tank reactor. Appl Microbiol Biotechnol. 2001, 57: 65~73
174 Nakagawa T, Sato S, Yamamoto Y, et al. Successive changes in community structure of an ethylbenzene-degrading sulfate-reducing consortium. Water Research. 2002, 36: 2813~2823
175 Pereira MA, Roest K, Stams AJM, et al. Molecular monitoring of microbial diversity in expanded granular sludge bed (EGSB) reactors treating oleic acid. FEMS Microbiol Ecol. 2002, 41: 95~103
176 Narihiro T, Abe T, Yamanaka Y, et al. Microbial population dynamics during fed-batch operation of commercially available garbage composters. Appl Microbiol Biotechnol. 2004, 65: 488~495
177 Xing D, Ren N, Gong M, et al. Monitoring of microbial community structure and succession in the biohydrogen production reactor by denaturing gradient gel electrophoresis (DGGE). Sci China C (Life Science) 2005, 48:155~162
178 Roest K, Heilig HG, Smidt H, et al. Community analysis of a full-scale anaerobic bioreactor treating paper mill wastewater. Systematic and Applied Microbiology. 2005, 28: 175~185
179 Muhammad Farhan Arooj, Sun-Kee Han, Sang-Hyun Kim, et al. Sludge characteristics in anaerobic SBR system producing hydrogen gas. Water Research. 2007, 41: 1177~1184
180 Chiu-Yue Lin, Chia-Yin Lee, I. Cheng Tseng, et al. Biohydrogen production from sucrose using base-enriched anaerobic mixed microflora. Process Biochemistry. 2006, 41: 915~919
181 Zhen-Peng Zhang, Kuan-Yeow Show, Joo-Hwa Tay, et al. Effect of hydraulic retention time on biohydrogen production and anaerobic microbial community. Process Biochemistry. 2006, 41: 2118~2123
182 Sachiko Yoshie, Naohiro Noda, Tomoko Miyano, et al. Microbial Community Analysis in the Denitrification Process of Saline-Wastewater byDenaturing Gradient Gel Electrophoresis of PCR-Amplified 16s rDNA and the Cultivation Method. Journal of Bioscience and Bioengineering. 2001, 92(4): 346~353
183 Alper T. Akarsubasi, Orhan Ince, Betul Kirdar, et al. Effect of wastewater composition on archaeal population diversity. Water Research. 2005, 39: 1576~1584
184 Dong-Hoon Kim, Sun-Kee Han, Sang-Hyoun Kim, et al. Effect of gas sparging on continuous fermentative hydrogen production. International Journal of Hydrogen Energy. 2006, 31: 2158~2169
185 裘湛,闻岳,黄翔峰等.PCR-DGGE 技术在水解酸化/缺氧法处理采油废水的微生物研究中的应用.环境污染与防治.2006,28(6):439~442
186 胡宝兰,郑平,胡安辉等.Anammox 反应器的启动及其菌群演变的研究.农业工程学报.2005,21(7):107~110
187 许春红,买文宁,赵继红等.PCR-DGGE 研究厌氧复合床反应器中微生物种群多样性.河南科学.2006,24(5):754~756
188 任艳红,徐向阳,唐全.降解五氯酚厌氧生物反应器微生物种群结构的分子特性研究.环境科学学报.2005,25(2):214~219
189 黄爱群,傅以钢,陈皓等.降解 2-氯酚厌氧污泥中微生物种群结构研究.同济大学学报(自然科学版)..2006,34(12):1651~1656
190 邢德峰,任南琪,宋业颖等.DG-DGGE 分析产氢发酵系统微生物群落动态及种群多样性.生态学报.2005,25(7):1818~1823
191 邢德峰,任南琪,宫曼丽.PCR-DGGE 技术解析生物制氢反应器微生物多样性.环境科学.2005,26(2):172~176
192 宫曼丽,任南琪,邢德峰.丁酸型发酵生物制氢反应器的运行特性研究.环境科学学报.2005,25(2):275~278
193 L. V. Skiadas and G. Lyberatos. The periodic anaerobic baffled reactor. Water Science and Technology. 1998, 38: 401~408
194 I. V. Skiadas, H. N. Gavala and G. Lyberatos. Modelling of the periodic anaerobic baffled reactor (PABR) based on the retaining factor concept. Water Research. 2000, 34(15): 3725~3736
195 K. Stamatelatou, V. Vavilin and G. Lyberatos. Performance of a glucose fed periodic anaerobic baffled reactor under increasing organic loading conditions: 2. Model prediction 1. Bioresource Technology. 2003, 88:137~142
196 K. Stamatelatou, V. Vavilin and G. Lyberatos. Performance of a glucose fed periodic anaerobic baffled reactor under increasing organic loading conditions: 1. Experimental results. Bioresource Technology. 2003, 88: 131~136
197 K.Stamatelatou, I.V.Skiadas and G.Lyberatos. On the behavior of the periodic anaerobic baffled reactor (PABR) during the transition from arbohydrate to protein-based feedings. Bioresource Technology. 2004, 92: 321~326
198 胡纪萃.厌氧废水生物处理理论与技术.中国建筑工业出版社,2003
199 国家环保总局,《水和废水检测分析方法》编委会.《水和废水检测分析方法》.中国环境科学出版社,第四版,2002
200 Miller, D. N., Bryant, J. E. and Madsen, E. L. Ghiorse, W. C., Evaluation and optimization of DNA extraction and purification procedures for soil and sediment samples. Applied Environmental Microbiology, 1999, 65: 4715~4724.
201 Bassam, B. J., Caetano-Anolles, G. and Gresshoff, P. M. Fast and sensitive silver staining of DNA in polyacrylamide gels. Analytical Biochemistry. 1991, 96: 80~83.
202 Hall, T.A. BioEdit: a user-friendly biological sequence alignment editor and analysis program for Windows 95/98/NT. Nucleic Acids Symposium Series. 1999, 41: 95~98
203 Kumar, S, Tamura, K, and Nei, M. MEGA3: Integrated software for molecular evolutionary genetics analysis and sequence alignment. Briefings in Bioinformatics. 2004, 5: 150~163
204 王欣,李清雪,魏玲玲等.厌氧折流板反应器(ABR)的低负荷启动研究.河北建筑科技学院学报.2006,23(4):42~44
205 李晓明,陈少华.厌氧折流板反应器处理高浓度有机污水的研究.茂名学院学报.2006,16(3):13~16
206 Zonglian She, Xilai Zheng, Bairen Yang, et al. Granule development and performance in sucrosefed anaerobic baffled reactors. Journal of Biotechnology. 2006, 122: 198~208
207 束琴霞,沈耀良,陈坚.ABR 反应器运行稳定性的研究.环境工程.2004,22(5):16~18
208 何仕均,黄永恒,王建龙.折流式厌氧反应器的启动性能.清华大学学报(自然科学版).2006,46(6):865~867
209 苏德林,王建龙,黄永恒等.ABR 反应器的碱度变化及调控研究.环境科学.2006,27(10):2024~2027
210 M. Faisal and Hajime Unno. Kinetic analysis of palm oil mill wastewater treatment by a modified anaerobic baffled reactor. Biochemical Engineering Journal. 2001, 9: 25~31
211 R. Marquet, M. Mietton-Peuchot and A. D. Wheatley. Characterisations of trickling filter effluent by particle size distribution and high performance size exclusion chromatography. Water Research. 1999, 33(6): 1415~1424
212 Duncan J. Barker, Gianni A. Mannucchi, Sandrine M. L. Salvi and David C. Stuckey. Characterisation of soluble residual chemical oxygen demand (COD) in anaerobic wastewater treatment effluents. Water Research. 1999, 33(11): 2499~2510
213 Schiener P., Nachaiyasit S. and Stuckey D. C. The production of soluble microbial products (SMP) in an anaerobic baffled reactor: composition, biodegradability and the effect of process parameters. Environ. Technol. 1998, 19: 391~400.
214 Kuo W. C. and Parkin G. F. Characterization of soluble microbial products from anaerobic treatment by molecular weight distribution and nickel-chelating properties. Water Research. 1996, 30(4): 915~922
215 G. Vidal, S. Videla, M.C. Diez. Molecular weight distribution of Pinus radiata kraft mill wastewater treated by anaerobic digestion. Bioresource Technology. 2001, 77: 183~191
216 Levenspiel O. Non ideal flow. In Chemical Reaction Engineering, 2nd edition. Wiley, New York, 1972: 253~308.
217 Young H. W. and Young J. C. Hydraulic characteristics of upflow anaerobic filters. J. Environ. Eng. 1988, 114(3): 621~638.
218 Stuckey D. C. Anaerobic digestion in developing countries: advances in fermentation. SCI meeting at Chelsea College, London. 1983
219 胡细全,刘大银,蔡鹤生.ABR 反应器结构对水力特性的影响.地球科学-中国地质大学学报.2004,29(3):369~374
220 郭静,李清雪,马华年等.ABR 反应器的性能及水力特性研究.中国给- 125 -水排水.1997,13(4):17~20
221 Bear J. Dynamics of fluids in porous media. Elsevier, New York. 1972
222 徐金兰,刘茵,黄廷林.多隔室厌氧折流板反应器(ABR)的水力特性试验研究.环境污染治理技术与设备.2005,6(12):52~55
223 Tomlinson E. J. and Chambers B. The effect of longitudinal mixing on the settleability of activated sludge. Technical Repart TR 122. Water Research Centre, Stevenage. 1979