达里诺尔有机碳形态分布特征
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摘要
本文以达里诺尔为研究对象,运用环境地球化学、土壤学和沉积学的理论和方法,注重环境中载体的关联信息的综合获取和时空变化对比。以沉积物有机碳形态分布特征研究为主线,揭示了有机碳形态分布差异性机制,以期为探讨有机碳形态对沉积物碳循环积累科学依据。取得了以下进展和结论。
1.表层沉积物中不同形态及组分有机碳的含量顺序为：LFOC 2.研究结果表明,湖泊浅水区LCOC、LFOC所占TOC比例较高,深水区HM和TCOC含量较高,揭示湖泊深浅、生物量分布和外源输入对有机碳的形态及活性有重要影响。
3.总体而言,沉积物柱芯中各形态有机碳含量随沉积深度呈递减趋势。TCOC、HM和HFOC随着深度增加呈明显的减少趋势。
4.有机碳形态及其与氮磷等营养元素的相关性研究表明,LFOC、COC和SCOC有机碳向无机碳转化的纽带,对湖泊碳循环的贡献大于TCOC, LFOC、LCOC和SCOC。
5.C/N的空间分布揭示达里诺尔不同湖区沉积物中有机质具有不同来源；沉积物中有机氮水平尚清洁,有机指数基本为中清洁水平,沉积物中营养盐对底栖生物均有最低生态毒性效应,个别站点的TN甚至对底栖生物产生严重生态毒性效应。
Based on the recent theory and method of Environmental Geochemistry,Sedimentology and Soil science, this thesis taken Dalinuoer lake as the research object researched distributing characteristic of the sedimentary organic carbon speciation via seeking synthetical informations from environmental carrier of spatial and temporal changes in comparison. This paper focuses on distributing characteristics of organic carbon in order to reveal the differences among organic carbon distrubition each other and to discover theoretical basis for carbon organic cycling in sedimentary environment. The results are described as follows:
1. Concentrations of OC form were in the sequence of LFOC 2. The contents of LFOC,HFOC,LCOC,SCOC and TCOC in surface sediments of Dalinuoer lake shown the decreasing trend from the deepwater area to shallow water; The various forms of organic carbon in the surface sediments showed highvalues; The results showed that LCOC and LFOC share a higher proportion in TOC from deepwater area, HM and TCOC share a higher content in deep lake,which revealed that the depth of lake、the distribution of biomass and external matter had serious effect on the species and activity of OC.
3. Research has shown that the distributions of OC forms in the sediments indicated obvious regional characteristics for the difference in geographic environment.The concentrations of OC forms in upper layer of the core sediment decreased gradually with increase in depth, specially, the concentrations of TCOC、HM and HFOC in the core sediment decreased obviously with increase in depth;
4. LHOC of sediments in Dalinuoer lake are more important and active to the carbon cycling than other organic carbon forms. LCOC and SCOC are a transformable bond from organic carbon to inorganic carbon;
5. Via rational use of organic nitrgon,organic index and eco-toxicity assessment for evaluating the surface sediment in Dalinuoer, It is concluded that the southwest of lake is polluted by organic matter and the northeast of lake is polluted by organic nitrgon.The exo-toxicity assessment indcated that the DLNE 9 area was the only safety for the benthos survive. C/N in spatial distriubtion indicated the origin of sedimentary organic matter.
This thesis presents organic carbon speciation classification, characteritic of organic carbon distribution in Dalinuoer sediment. It provides the basic information and referential value for OC speciations in typical high-salinity lake, especially for organic carbon cycling in Neimenggu-Xinjiang Plateau.Theoretical information and methods are made available to further understanding the processes and impact of Eutrophication and carbon cycle on sedimentary organic carbon in lake ecosystems.
1.表层沉积物中不同形态及组分有机碳的含量顺序为：LFOC
3.总体而言,沉积物柱芯中各形态有机碳含量随沉积深度呈递减趋势。TCOC、HM和HFOC随着深度增加呈明显的减少趋势。
4.有机碳形态及其与氮磷等营养元素的相关性研究表明,LFOC、COC和SCOC有机碳向无机碳转化的纽带,对湖泊碳循环的贡献大于TCOC, LFOC、LCOC和SCOC。
5.C/N的空间分布揭示达里诺尔不同湖区沉积物中有机质具有不同来源；沉积物中有机氮水平尚清洁,有机指数基本为中清洁水平,沉积物中营养盐对底栖生物均有最低生态毒性效应,个别站点的TN甚至对底栖生物产生严重生态毒性效应。
Based on the recent theory and method of Environmental Geochemistry,Sedimentology and Soil science, this thesis taken Dalinuoer lake as the research object researched distributing characteristic of the sedimentary organic carbon speciation via seeking synthetical informations from environmental carrier of spatial and temporal changes in comparison. This paper focuses on distributing characteristics of organic carbon in order to reveal the differences among organic carbon distrubition each other and to discover theoretical basis for carbon organic cycling in sedimentary environment. The results are described as follows:
1. Concentrations of OC form were in the sequence of LFOC
3. Research has shown that the distributions of OC forms in the sediments indicated obvious regional characteristics for the difference in geographic environment.The concentrations of OC forms in upper layer of the core sediment decreased gradually with increase in depth, specially, the concentrations of TCOC、HM and HFOC in the core sediment decreased obviously with increase in depth;
4. LHOC of sediments in Dalinuoer lake are more important and active to the carbon cycling than other organic carbon forms. LCOC and SCOC are a transformable bond from organic carbon to inorganic carbon;
5. Via rational use of organic nitrgon,organic index and eco-toxicity assessment for evaluating the surface sediment in Dalinuoer, It is concluded that the southwest of lake is polluted by organic matter and the northeast of lake is polluted by organic nitrgon.The exo-toxicity assessment indcated that the DLNE 9 area was the only safety for the benthos survive. C/N in spatial distriubtion indicated the origin of sedimentary organic matter.
This thesis presents organic carbon speciation classification, characteritic of organic carbon distribution in Dalinuoer sediment. It provides the basic information and referential value for OC speciations in typical high-salinity lake, especially for organic carbon cycling in Neimenggu-Xinjiang Plateau.Theoretical information and methods are made available to further understanding the processes and impact of Eutrophication and carbon cycle on sedimentary organic carbon in lake ecosystems.
引文
[1]杨忠芳,朱立,陈岳龙 现代环境地球化学[M]地质出版社,1999,151-152
[2]Tenzer G E,Meyers P A et al. Sedimengtary organic matter record of recent environmental changes in the ST Marys Riverecosystem, Michigon Ontario border [J] Organic Geochemistry,1990,30(2-3):133-146
[3]朱光伟,陈英旭 沉积物中有机质的环境行为研究进展[J]湖泊科学,2001,13(2)：272-279
[4]IPCC(Internation Panel of climate Change) Land use, Land-use Change [R] Cambrodge and New Pork:Cambrodge University Press,2000,
[5]刘清玉,戴雪荣 巢湖沉积物有机碳分布变化特征 [J] 上海地质,2008,1：13-17
[6]L.霍坎松M·杨松 湖泊沉积学原理,郑光膺译[M] 北京：科学出版社1992
[7]王苏民,吉磊 呼伦湖晚第四纪湖相地层沉积学及湖面波动历史[J]湖泊科学,1995,7(4)：297-306
[8]Orem W H, Burnett W C,Landing W M W B. Jell lake Palau:Earth diagenesis of organic matter in sediments of an anoxic marine lake [J] Limnol Oceanogr,1991,36(37):526-534
[9]Hansen L S,Blackburn T H. Aerobic and Anaerobic Mineralization in Marine Sediment Microcosms [J] Mar.Ecol.Prog.Ser.1991,75:283-291
[10]ShimeI D S. Terrestrial ecosystem and the carbon clcye [J] GiobaI Change BiOIogy,1995,1:77-91.
[11]Bordovskiy O K.,Accumulation and transfomation of organic.substances in marine sediments [J] Ma rine,GeoIogy,1965,31:64-71
[12]宋金明 中国近海沉积物-海水界面化学[M]北京：海洋出版社,1997,222.
[13]袁华茂,吕晓霞.自然粒度下渤海沉积物中有机碳的地球化学特征[J].环境化学,2003,22(2)：115-120.
[14]蓝先洪 中国主要河口沉积有机地球化学研究[J]海洋地质动态,2003,19(9)：1-4
[15]张文菊 童成立 水分对湿地沉积物有机碳矿化的影响[J]生态学报2005,25(2)：249-253
[16]杨春霞 轻组有机质对太湖沉积物氮、磷矿化的影响 [J]环境科学研究,2009 22(3)：1001-1007
[17]吴健,沈吉 兴凯湖沉积物有机碳和氮及其稳定同位素反映的28kaBP以来区域古气候环境变化[J]沉积学报,2010 28(2)：365-372
[18]Craig H Geochim Cosmochim Acta 1953,3:53-92
[19]蔡德陵,蔡爱智 黄河口区有机碳同位素地球化学研究[J]中国科学(B辑),1993,23(10)：1105-1113
[20]吴敬禄,曾海鳌,林琳 不同气候区湖泊有机碳同位素对区域环境变化的响应[J] 矿物岩石地球化学通报,2007,26(z1)：425-426
[21]Dean W E,Arthur M A,Claypool G E.DepIetion of δ13C in Cretaceous marine organic matter:source, diagenetic, or environmental signal [J] Marine Geology,1986,70:119-157.
[22]D'Angelo EM, Reddy KR. Diagenesis of organic matter in a wetland receiving hypereutrophic lake water:I.Distribution of dissolved nutrients in the soil and water column [J] Environ Qual,1994,23(5):928-936.
[23]Wallschlager D,Desai M V M, Spengler M, et al. How humic substances dominate mercury geochemistry in contaminated floodplain soils and sediments [J] J Environ Qual,1998,27(5):1044-1054.
[24]Drouillard K G C,iborowski J J H,Lazar R et al. Estimation of the uptake of organochlorines by the mayfly Hexagenia limbata(Ephemeroptera:Ephemeridae) [J] J Great Lakes Res,1996,22(1):26-35
[25]Keppler F Eiden R Niedan V et al. Halocarbons produced by natural oxidation processes during degration of organic matter [J] Nature,2000,403:298-301.
[26]张发兵,胡维平.胡雄星等 太湖湖泊水体碳循环模型研究,[J] 水科学进展,2008,19(2)：171-178
[27]王小燕.黄旗海湖积物中有机质及有机碳同位素古气候意义的研究,[S]硕士学位论文,中国科学院盐湖研究所,2000
[28]张文菊 典型湿地生态系统碳蓄积与碳循环模拟 [B] 博士学位论文,华中农业大学,2006
[29]王仕禄,刘丛强,万国江等.贵州百花湖分层晚期有机质降解过程与溶解N2O循环[J]第四纪研究2004,24(5)：569-577
[30]Benner R,Fogel M Lsprague E K et al Depletion of 13C in lignin and its implications for stable isotope studies [J] Nature,1987,708-710
[31]Dou S,Tardy Y,Zhang J J et al. Study on the thermodynamics stability of soil humic and fulvic acids In Humic Substances and Soil and Water Environment,Embrapa. Brazil.2004,413-415
[32]张文菊 洞庭湖湿地有机碳垂直分布与组成特征[J]环境科学,2005,26(3)：56-60
[33]傅积平.土壤结合态腐殖质的分组测定[J]土壤通报,1983,2：36-37
[34]Rutterber K C.Development of a sequential extraction method for different forms of phosphorus in marine sediments[J] Limnol & Oceanogr,1992,37(7):1460-1482
[35]Janzen H H Campbell C A Brandt S A, et al. Light-Fraction organic matter in soils from long-term crop rotations [J] Soil Sci. A m.,1992,56:1799-1805
[36]蔡进功,郭志刚,李从先等 水体中有机质的类型与有机质沉积作用[J]同济大学学报(自然科学版),2005,33(2)：1213-1218
[37]倪进治,徐建民,谢正苗.土壤轻组有机质[J]环境污染治理技术与设备,2000,1(2)：58-64
[38]徐明岗,于荣,伯仁.土壤活性有机质的研究进展[J]土壤肥料,2000,(6)：3-7
[39]Gregorich EG,Carter MR,Angers DA et al Toward a minimum date set to assess soil organic matter quality in agricultural soils [J] Can Soil Sci,1994,74:367-385
[40]梁爱珍,张晓平,杨学明等.土壤粗有机质的研究进展[J]地理科学进展,2006,25(3)：128-136.
[41]Spyeher G,Sollins P,Rose S.Carbon and nitrogen ill the light fraction of a forest soft vertical distribution and seasonal pattern[J] Soil Science,1983,135:79-86
[42]Whalena J K,Bottomley P J,Mymld D D Carbon and nitrogen mineralization from from and light and heavy-fraction to soil soil [J] Soil Biology & Biochemistry,2000,32:1345-1352
[43]Dalal R C,Mayer R J. Long-term trends in fertility of soil under continuous cultivation and cereal cropping in southern queensland,VI.Loss of total nitrogen from different particle size and density fractions, Aust [J] Soil Res,1987,25:83-93
[44]王文颖,王启基,鲁子豫 高寒草甸土壤组分碳氮含量及草甸退化对组分碳氮的影响[J]中国科学D辑：地球科学,39(5)：647-654
[45]张建国,聂俊华,杜振字 施用复合生物有机肥对烤烟产量和品质的效应[J]湖南农业大学学报,2004,30(2)：115-119.
[46]金相灿主编.沉积物污染化学[M]北京：中国环境科学出版社,1992,26-27,72-74
[47]李学垣 土壤化学[M]北京高等教育出版社,2001,46-47
[48]妥进才,陈俊 青海湖：研究地质微生物的天然实验室[J]高校地质学报,2005,11(2)：187-193
[49].Boskey.AL Biomineralization:conflicts, challenges, and opportunities [J] Cell Biochem Suppl 1998,30-31:83-91.
[50]来航线等.几种微生物对土壤腐殖质形成的作用[J]西北农业大学学报,1997,25(6),79-82
[51]张崇邦 东北麦田土壤微生物、小型动物及其生化活性的季节动态[J] 植物营养与肥料学报2002,8(3),372-376
[52]D Angelo E M,Reddy K R. Diagenesis of organic matter in a wetland receiving hyperutrophic lake wate: Distribution of dissolved nutrients in the soil and water column[J] Enviiron Qual,1994,23(5):928-936
[53]陈俊,姚素平 微生物地球化学及研究进展[J]地质评论,2004,50(2)：620-641
[54]王建龙,文湘华 现代环境生物技术[M]第二版,清华大学出版社,2008,9：306
[55]Ehrlich H I.Geomicrobiology [M] 3rded,Marcel Dker, Inc., New York.1996.
[56]Iedin M,Pedersen K.The environmentalimpact of mine wastesrles of microganisms and their significance in treatment of mine wastes[J] Earth Sci. Rev,1996,41:67-108
[57]张彩凤,段月娟,闫降凤 译,KimH.Tan著关于腐殖质的议题,[M]腐植酸 译文 2009,5：32-37
[58]Kim H. Tan. Humic matter in soil and the environment:principles and controversies [M] Marcel Dekker, inc 2003:1-13
[59]Eladia M,pena-Mendez Humic substance-compounds of still unknown structure:application in agriculture, industry, environment, and biomedicine [J] Apple Biomed 2005,3:13-14
[60]Tsutsuki l,Kuwatsuka A.Charaterization of humin metal complexes in a buried volcanic ash soil profile and a peat soil [J] Soil Sci Plant Nutr,1992,38(2):297-306
[61]张晋京,窦森 土壤腐殖质分组研究[J]土壤通报,2004,35(6)：706-713
[62]彭福泉 我国几种主要土壤中腐殖质性质的研究[J]土壤学报,1985,22(1)：64-73
[63]徐跃,姚天全.气候因素对土壤有机质组成和性质的影响[J]山地研究.1994,12(3)： 163-68
[64]Xing B S,Seunghan K Peter V.Characterization of the sequentially extracted humic acids and ahumin from a soil inwestem massachusetts [J] Soil Science,2003,168(12):880-887
[65]窦森.土壤腐殖物质形成转化及其微生物学机理研究进展[J]吉林农业大学学报,2008,30(4)：538-547
[66]Augfis N,Cargeau C. Structure and origin of insoluble and non-hydrolysable, aliphatic organic matter in a forest Soil [J] Organic Geochemistry,1998,28(2):119-124.
[67]陈同斌,陈志军 土壤中溶解性有机质及其对污染物吸附和解吸行为的影响[J]植物营养与肥料学报,1998,4(3)：201-210
[68]王连峰,潘根兴,石盛莉等.酸沉降影响下庐山森林生态系统土壤溶解性有机碳分布[J]植物营养与肥料学报,2002,14(1)：126-130
[69]Hruska J Kram. P Incearsed dissolved organic carbon(DOC) in central European streams is driven by reducitons in ionic strength rather than climate change or decreasing acidity[J] Environ. Sci. Technol.2009, 43,4320-4326
[70]郭圣荣主译.生物高分子(第一卷)木质素、腐殖质和煤[M]北京：化学工业出版社,2004
[71]Stigliani WMChanges in valued "capacities" of soils and sediments as indicators and time-delayed environmental sffects [J] Environ. Monit. Assess,1998
[72]董生旺 达里诺尔碳、氮、磷环境地球化学研究[S]硕士学位论文,内蒙古大学,2009
[73]张玉,何江 内蒙古达里诺尔湖水质现状调查[J]水产科学,2008,27(12)：671-673
[74]李月梅,王跃思 开垦对高寒草甸土壤有机碳影响的初步研究[J]地理科研进展,2005,24(6)：59-65
[75]毛海芳 乌梁素海、岱海有机碳地球化学特征,[S]硕士学位论文,内蒙古大学,2009
[76]Barrios E, Buresh R J, Sprent J I. Organic matter in soil particle size and density fractions from maize and legume cropping systems [J]Soil Biology and Biochemistry,1996,28:185-193.
[77]Alvarez C R, Alvarez R, Grigera M S, et al. Associations between organic matter fractions and the active soil microbial biomass [J] Soil Biology and Biochemistry,1998,30:767-773.
[78]周群英,王士芬.环境工程微生物学,[M]高等教育出版社,第3版,北京.2008,115-126
[79]Fischer,H,Wanner S.C., Push M. Microbes abundance and production in river sediment(POM) [J] Biochemistry,2002,61:35-37
[80]Marxsen J.Measurement of Microbes production in atream-bed sediments via leucine incorporation [J] FEMS Micro,Ecol,
[81]徐建民,袁可能.土壤结合态腐殖质的形成特点及其结合特征[J]土壤学报,1995,32(2)：151-581
[82]李文军 开封城市土壤有机质组成、性质及其重金属赋存分析[S]硕士学位论文,河南大学,2009：54-55
[83]催俊涛 微生物在土壤腐殖质形成与转化作用的研究[B]博士学位论文,吉林农业大学,2005
[84]Frias J,Ribas F. A method for the measurement of biodegradable organic carbon in waters [J] Water Research,1992 26(2):255-258
[85]Frias J,Ribas F Comparision of methods for the measurement of biodegradable organic carbon and assimilable organic carbon in water [J] Wat. Res 1995,29(12):2785-2788
[86]Skjemstad J O, Dalal R C, Barron P F. Spectroscopic investigations of cultivation effects on organic matter of vertisols [J] Soil Sci. Soc Am,1986,50:354-359
[87]Haynes R J,Beare M H Aggregation and organic matter storage in meso-thermal, humid soils.In:Carter MR, Stewart BA eds,Advances in soil science. Structure and organic matter storage in agriculture soils. CRC Lewis Publishers[J] Boca Raca Raton,1996,213-262
[88]Carter M.R.,Anger D.A.,Kunellius H.T. Soil structure form and stability and organic matter under cool-season perennial grasses[J] Soil Sci. Soc. Am.,1994,58 1194-1199
[89]刘兴健,葛晨东 人类活动对海南省小海泻湖沉积环境的影响[J]环境化学,2007,26(30)：384-387
[90]Krishnamurthy R V,Bhattacharya S K,Sheela Kusumgar. Palaeoclimatic changes deduced from13C/12C and C/N ratios of Karewa lake sediments [J] India. Nature,1986,323:150-152
[91]Wagner B,Melles M,Hahne J et al 2000 Holocene climate history of Geographical Socienty Q East Greenland-evidence from lake sediments [J] Palaeogeography, Palaeoclimateology Palaeoecology 2000,160:45-68
[92]Nakai N, Koyama M. Reconstruction of palaeoenvironment from the vie-points of the inorganic constituents, C/N ratio and carbon isotopic ratio in the 1400m core taken from lake Biwa.In:S.Horie(editor),History of Lake Biwa, Kyoto Univ Coontrib,1987,137-156
[93]Anne Muller.Ulrike Mathesius.The Palaeoenvironment of coastal lagoons in the southern Baltic Sea The application of sedimentaru Corg/N ratios as source indicators of organic matter [J] Palaeogeography,Palaeoclimatology, Palaeoecology.1999,145:1-16
[94]Giresse P Maley J Brenac P Lake Quaternary Plaeoenvironment in the Lake Barombi Mbo(West Cameron)Deduced From Pollern And Carbon Isotopes of Organic Matter,\[M] Palaeogeography Palaeoclimatology, Palaeoecology 1994,107:65-78
[95]朱松泉,窦宏身.洪泽湖[M]合肥：中国科学技术大学出版,1993,94-95
[96]潘红玺.横断山区湖泊中溶解氧的分布特征[J].湖泊科学,1990,2(2)：53-60
[97]隆浩 季风边缘区全新世中期气候变化韵古湖泊记录[S]硕士学位论文,兰州大学,2006
[98]Ruttenberg K C,Goni M A.Phosphorus Distribution,C:N:Pratios, and δ13C in Arctic, Tempreate,and Tropical Sediments:Tools for Charactrtizing Buck Sedimentary Organic Matter [J] Marine Geology, 1997,139:123-145.
[99]Carpenter SR.Phosphorus control is critical to mitigating eutrophication.Proceedings of National [J] Academy of Scieences,2008,105:11039-11040.
[100]Jφrgensen NOG，Niels OGOrganic nitrogen.In:Likens GE ed.Encyclopedia of Inland Waters. [J]London:Academic Press,2009, Vol.2:832-851.
[101]Worsfold PJ,Monbet P,Tappin AD et al.Characterisation and quantification of organic phosphorus and organic nitrogen components in aquatic systems:A Review [J] Analytica Chimica Acta,2008,624:37-58.
[102]吴丰昌,王立英,黎文等.天然有机质及其在地表环境中的重要性[J]湖泊科学,2008,20(1)：1-12.
[103]Fu PQ, Wu FC, Liu CQ et al Spectorscopic characterization and molecular weight distribution of dissolved organic matter in sediment porewaters from Lake Erhai, Southwest [J] Biogeochemistry, 2006,81:179-189
[104]Sharpley A,Tunney H Phosphorus research strategies to meet agricultural and environmental challenges of the 21 st century [J] Journal of Environmental Quality,2000,29(1):176-251
[105]Burdige Dj, Zheng SL.The biogeochemical cycling of dissolved organic nitrogen in estuarine sediments [J] Limnology and Oceaography,1998,43:1796-1813
[106]Stepanauskas R,Leonardos L,Tranvik KJ. Bioavaibility of wetland-derived DON to freshwater and marine bacterioplankton [J] Limnology and Oceanography,1999,44:1477-1485
[107]Carmand R, Edlund G, Damberg C. Distrbution of organic and inorganic for measurement of dissolved organic nirogen in seawater [J] Marine Chemistry,2002,78:171-184
[108]Turner BL, McKelvie ID, Haygarth PM. Characterization of water-extractable soil organic phosphorus by phosphatase hydrolysis [J] Soil Biology and Biochemistry,2002,34:29-37
[109]Newman RH,Tate KR.Soil phosphorus chacterization by 31P nuclear magnetic resonance [J] Communications in Soil Science and Plant Analysis,1980,11:835-842
[110]Nordstrom D K,Southam G Geomicrobiology of sulfide mineral oxidation [J] Rev. Mineral Geochem 1997,35:361-382
[111]Lovely D R, Stolz J F, Nord GL Phillips E J P Anaerobic production of magnetite by a dissimilatory iron-reducing microorganism [J] Nature,1987,330:252-254
[112]Ehrlich H L Geomicrobiology,3rded [M] Marcel Dekker Inc., New York 1996
[113]Tong Yong Lin,Guofang, Ke Xin, et al. Comparison of microbial community between two shallow freshwater lakes in middle Yangtze basin, East China [J]. Chemosphere,2005,60 (1):85-92
[114]冯峰,王辉 东湖沉积物中微生物量与碳、氮、磷的相关性[J]中国环境科学,2006,26(3)：342-345
[115]魏中青,刘丛强等 贵州红枫湖沉积物中有机质的降解与微生物作用[J]科学通报,2005,50(14)：1486-1489
[116]张恒军 河流沉积物中微生物对营养盐释放的影响研究[S]硕士学位论文,中山大学,2004
[117]沈宏,曹志洪,胡正义.土壤活性有机碳的表征及其生态效应[J]生态学杂志,1999,18(3)：32-38
[118]Ann-Loiuse,Haglund Peter lantz, Erik Tomblom Depth distribution of active Microbes activity in lake sediment [J] FEMs Microbiology,2002,46:31-38
[119]Wenjun ZH,Aixiao H,Chengli T et al Estimating organic carbon stroge in temperate wetland profiles in Northeast China [J] Geoderma,2008,146:311-316
[120]Lovey D R,Kashefi K,Vargas M et al Reduction of humic subtances and Fe(III) by hyperthemophilic microorganism [J] Chemical geology,2000,169(3-4):289-298
[121]武春媛,李芳柏,周顺桂 腐殖质呼吸作用及其生态学意义[J]生态学报,2009,29(2)：1535-1542
[122]王永华,钱少猛,徐南妮等.巢湖东区底泥污染物分布特征及评价[J].环境科学研究,2004,17(6)：22-25.
[123]Bernstein B,Zehr E I,Dean R A et al Characteristics of Colletotrichum species responsible for anthracnose disease of various fruits [J] Plant Disease,1998,82(6):596-605
[124]Mudroch A, Azcue D J M. Manual of Aquatic Sediment Sampling [M]. Boca Raton,Florida:Lewis Publications,1995,224.
[125]邬红娟,崔博,吕晋等 武汉湖泊底栖动物群落结构及水质生态评价[J]华中科技大学学报(自然科学版),2005,33(10)95-98
[2]Tenzer G E,Meyers P A et al. Sedimengtary organic matter record of recent environmental changes in the ST Marys Riverecosystem, Michigon Ontario border [J] Organic Geochemistry,1990,30(2-3):133-146
[3]朱光伟,陈英旭 沉积物中有机质的环境行为研究进展[J]湖泊科学,2001,13(2)：272-279
[4]IPCC(Internation Panel of climate Change) Land use, Land-use Change [R] Cambrodge and New Pork:Cambrodge University Press,2000,
[5]刘清玉,戴雪荣 巢湖沉积物有机碳分布变化特征 [J] 上海地质,2008,1：13-17
[6]L.霍坎松M·杨松 湖泊沉积学原理,郑光膺译[M] 北京：科学出版社1992
[7]王苏民,吉磊 呼伦湖晚第四纪湖相地层沉积学及湖面波动历史[J]湖泊科学,1995,7(4)：297-306
[8]Orem W H, Burnett W C,Landing W M W B. Jell lake Palau:Earth diagenesis of organic matter in sediments of an anoxic marine lake [J] Limnol Oceanogr,1991,36(37):526-534
[9]Hansen L S,Blackburn T H. Aerobic and Anaerobic Mineralization in Marine Sediment Microcosms [J] Mar.Ecol.Prog.Ser.1991,75:283-291
[10]ShimeI D S. Terrestrial ecosystem and the carbon clcye [J] GiobaI Change BiOIogy,1995,1:77-91.
[11]Bordovskiy O K.,Accumulation and transfomation of organic.substances in marine sediments [J] Ma rine,GeoIogy,1965,31:64-71
[12]宋金明 中国近海沉积物-海水界面化学[M]北京：海洋出版社,1997,222.
[13]袁华茂,吕晓霞.自然粒度下渤海沉积物中有机碳的地球化学特征[J].环境化学,2003,22(2)：115-120.
[14]蓝先洪 中国主要河口沉积有机地球化学研究[J]海洋地质动态,2003,19(9)：1-4
[15]张文菊 童成立 水分对湿地沉积物有机碳矿化的影响[J]生态学报2005,25(2)：249-253
[16]杨春霞 轻组有机质对太湖沉积物氮、磷矿化的影响 [J]环境科学研究,2009 22(3)：1001-1007
[17]吴健,沈吉 兴凯湖沉积物有机碳和氮及其稳定同位素反映的28kaBP以来区域古气候环境变化[J]沉积学报,2010 28(2)：365-372
[18]Craig H Geochim Cosmochim Acta 1953,3:53-92
[19]蔡德陵,蔡爱智 黄河口区有机碳同位素地球化学研究[J]中国科学(B辑),1993,23(10)：1105-1113
[20]吴敬禄,曾海鳌,林琳 不同气候区湖泊有机碳同位素对区域环境变化的响应[J] 矿物岩石地球化学通报,2007,26(z1)：425-426
[21]Dean W E,Arthur M A,Claypool G E.DepIetion of δ13C in Cretaceous marine organic matter:source, diagenetic, or environmental signal [J] Marine Geology,1986,70:119-157.
[22]D'Angelo EM, Reddy KR. Diagenesis of organic matter in a wetland receiving hypereutrophic lake water:I.Distribution of dissolved nutrients in the soil and water column [J] Environ Qual,1994,23(5):928-936.
[23]Wallschlager D,Desai M V M, Spengler M, et al. How humic substances dominate mercury geochemistry in contaminated floodplain soils and sediments [J] J Environ Qual,1998,27(5):1044-1054.
[24]Drouillard K G C,iborowski J J H,Lazar R et al. Estimation of the uptake of organochlorines by the mayfly Hexagenia limbata(Ephemeroptera:Ephemeridae) [J] J Great Lakes Res,1996,22(1):26-35
[25]Keppler F Eiden R Niedan V et al. Halocarbons produced by natural oxidation processes during degration of organic matter [J] Nature,2000,403:298-301.
[26]张发兵,胡维平.胡雄星等 太湖湖泊水体碳循环模型研究,[J] 水科学进展,2008,19(2)：171-178
[27]王小燕.黄旗海湖积物中有机质及有机碳同位素古气候意义的研究,[S]硕士学位论文,中国科学院盐湖研究所,2000
[28]张文菊 典型湿地生态系统碳蓄积与碳循环模拟 [B] 博士学位论文,华中农业大学,2006
[29]王仕禄,刘丛强,万国江等.贵州百花湖分层晚期有机质降解过程与溶解N2O循环[J]第四纪研究2004,24(5)：569-577
[30]Benner R,Fogel M Lsprague E K et al Depletion of 13C in lignin and its implications for stable isotope studies [J] Nature,1987,708-710
[31]Dou S,Tardy Y,Zhang J J et al. Study on the thermodynamics stability of soil humic and fulvic acids In Humic Substances and Soil and Water Environment,Embrapa. Brazil.2004,413-415
[32]张文菊 洞庭湖湿地有机碳垂直分布与组成特征[J]环境科学,2005,26(3)：56-60
[33]傅积平.土壤结合态腐殖质的分组测定[J]土壤通报,1983,2：36-37
[34]Rutterber K C.Development of a sequential extraction method for different forms of phosphorus in marine sediments[J] Limnol & Oceanogr,1992,37(7):1460-1482
[35]Janzen H H Campbell C A Brandt S A, et al. Light-Fraction organic matter in soils from long-term crop rotations [J] Soil Sci. A m.,1992,56:1799-1805
[36]蔡进功,郭志刚,李从先等 水体中有机质的类型与有机质沉积作用[J]同济大学学报(自然科学版),2005,33(2)：1213-1218
[37]倪进治,徐建民,谢正苗.土壤轻组有机质[J]环境污染治理技术与设备,2000,1(2)：58-64
[38]徐明岗,于荣,伯仁.土壤活性有机质的研究进展[J]土壤肥料,2000,(6)：3-7
[39]Gregorich EG,Carter MR,Angers DA et al Toward a minimum date set to assess soil organic matter quality in agricultural soils [J] Can Soil Sci,1994,74:367-385
[40]梁爱珍,张晓平,杨学明等.土壤粗有机质的研究进展[J]地理科学进展,2006,25(3)：128-136.
[41]Spyeher G,Sollins P,Rose S.Carbon and nitrogen ill the light fraction of a forest soft vertical distribution and seasonal pattern[J] Soil Science,1983,135:79-86
[42]Whalena J K,Bottomley P J,Mymld D D Carbon and nitrogen mineralization from from and light and heavy-fraction to soil soil [J] Soil Biology & Biochemistry,2000,32:1345-1352
[43]Dalal R C,Mayer R J. Long-term trends in fertility of soil under continuous cultivation and cereal cropping in southern queensland,VI.Loss of total nitrogen from different particle size and density fractions, Aust [J] Soil Res,1987,25:83-93
[44]王文颖,王启基,鲁子豫 高寒草甸土壤组分碳氮含量及草甸退化对组分碳氮的影响[J]中国科学D辑：地球科学,39(5)：647-654
[45]张建国,聂俊华,杜振字 施用复合生物有机肥对烤烟产量和品质的效应[J]湖南农业大学学报,2004,30(2)：115-119.
[46]金相灿主编.沉积物污染化学[M]北京：中国环境科学出版社,1992,26-27,72-74
[47]李学垣 土壤化学[M]北京高等教育出版社,2001,46-47
[48]妥进才,陈俊 青海湖：研究地质微生物的天然实验室[J]高校地质学报,2005,11(2)：187-193
[49].Boskey.AL Biomineralization:conflicts, challenges, and opportunities [J] Cell Biochem Suppl 1998,30-31:83-91.
[50]来航线等.几种微生物对土壤腐殖质形成的作用[J]西北农业大学学报,1997,25(6),79-82
[51]张崇邦 东北麦田土壤微生物、小型动物及其生化活性的季节动态[J] 植物营养与肥料学报2002,8(3),372-376
[52]D Angelo E M,Reddy K R. Diagenesis of organic matter in a wetland receiving hyperutrophic lake wate: Distribution of dissolved nutrients in the soil and water column[J] Enviiron Qual,1994,23(5):928-936
[53]陈俊,姚素平 微生物地球化学及研究进展[J]地质评论,2004,50(2)：620-641
[54]王建龙,文湘华 现代环境生物技术[M]第二版,清华大学出版社,2008,9：306
[55]Ehrlich H I.Geomicrobiology [M] 3rded,Marcel Dker, Inc., New York.1996.
[56]Iedin M,Pedersen K.The environmentalimpact of mine wastesrles of microganisms and their significance in treatment of mine wastes[J] Earth Sci. Rev,1996,41:67-108
[57]张彩凤,段月娟,闫降凤 译,KimH.Tan著关于腐殖质的议题,[M]腐植酸 译文 2009,5：32-37
[58]Kim H. Tan. Humic matter in soil and the environment:principles and controversies [M] Marcel Dekker, inc 2003:1-13
[59]Eladia M,pena-Mendez Humic substance-compounds of still unknown structure:application in agriculture, industry, environment, and biomedicine [J] Apple Biomed 2005,3:13-14
[60]Tsutsuki l,Kuwatsuka A.Charaterization of humin metal complexes in a buried volcanic ash soil profile and a peat soil [J] Soil Sci Plant Nutr,1992,38(2):297-306
[61]张晋京,窦森 土壤腐殖质分组研究[J]土壤通报,2004,35(6)：706-713
[62]彭福泉 我国几种主要土壤中腐殖质性质的研究[J]土壤学报,1985,22(1)：64-73
[63]徐跃,姚天全.气候因素对土壤有机质组成和性质的影响[J]山地研究.1994,12(3)： 163-68
[64]Xing B S,Seunghan K Peter V.Characterization of the sequentially extracted humic acids and ahumin from a soil inwestem massachusetts [J] Soil Science,2003,168(12):880-887
[65]窦森.土壤腐殖物质形成转化及其微生物学机理研究进展[J]吉林农业大学学报,2008,30(4)：538-547
[66]Augfis N,Cargeau C. Structure and origin of insoluble and non-hydrolysable, aliphatic organic matter in a forest Soil [J] Organic Geochemistry,1998,28(2):119-124.
[67]陈同斌,陈志军 土壤中溶解性有机质及其对污染物吸附和解吸行为的影响[J]植物营养与肥料学报,1998,4(3)：201-210
[68]王连峰,潘根兴,石盛莉等.酸沉降影响下庐山森林生态系统土壤溶解性有机碳分布[J]植物营养与肥料学报,2002,14(1)：126-130
[69]Hruska J Kram. P Incearsed dissolved organic carbon(DOC) in central European streams is driven by reducitons in ionic strength rather than climate change or decreasing acidity[J] Environ. Sci. Technol.2009, 43,4320-4326
[70]郭圣荣主译.生物高分子(第一卷)木质素、腐殖质和煤[M]北京：化学工业出版社,2004
[71]Stigliani WMChanges in valued "capacities" of soils and sediments as indicators and time-delayed environmental sffects [J] Environ. Monit. Assess,1998
[72]董生旺 达里诺尔碳、氮、磷环境地球化学研究[S]硕士学位论文,内蒙古大学,2009
[73]张玉,何江 内蒙古达里诺尔湖水质现状调查[J]水产科学,2008,27(12)：671-673
[74]李月梅,王跃思 开垦对高寒草甸土壤有机碳影响的初步研究[J]地理科研进展,2005,24(6)：59-65
[75]毛海芳 乌梁素海、岱海有机碳地球化学特征,[S]硕士学位论文,内蒙古大学,2009
[76]Barrios E, Buresh R J, Sprent J I. Organic matter in soil particle size and density fractions from maize and legume cropping systems [J]Soil Biology and Biochemistry,1996,28:185-193.
[77]Alvarez C R, Alvarez R, Grigera M S, et al. Associations between organic matter fractions and the active soil microbial biomass [J] Soil Biology and Biochemistry,1998,30:767-773.
[78]周群英,王士芬.环境工程微生物学,[M]高等教育出版社,第3版,北京.2008,115-126
[79]Fischer,H,Wanner S.C., Push M. Microbes abundance and production in river sediment(POM) [J] Biochemistry,2002,61:35-37
[80]Marxsen J.Measurement of Microbes production in atream-bed sediments via leucine incorporation [J] FEMS Micro,Ecol,
[81]徐建民,袁可能.土壤结合态腐殖质的形成特点及其结合特征[J]土壤学报,1995,32(2)：151-581
[82]李文军 开封城市土壤有机质组成、性质及其重金属赋存分析[S]硕士学位论文,河南大学,2009：54-55
[83]催俊涛 微生物在土壤腐殖质形成与转化作用的研究[B]博士学位论文,吉林农业大学,2005
[84]Frias J,Ribas F. A method for the measurement of biodegradable organic carbon in waters [J] Water Research,1992 26(2):255-258
[85]Frias J,Ribas F Comparision of methods for the measurement of biodegradable organic carbon and assimilable organic carbon in water [J] Wat. Res 1995,29(12):2785-2788
[86]Skjemstad J O, Dalal R C, Barron P F. Spectroscopic investigations of cultivation effects on organic matter of vertisols [J] Soil Sci. Soc Am,1986,50:354-359
[87]Haynes R J,Beare M H Aggregation and organic matter storage in meso-thermal, humid soils.In:Carter MR, Stewart BA eds,Advances in soil science. Structure and organic matter storage in agriculture soils. CRC Lewis Publishers[J] Boca Raca Raton,1996,213-262
[88]Carter M.R.,Anger D.A.,Kunellius H.T. Soil structure form and stability and organic matter under cool-season perennial grasses[J] Soil Sci. Soc. Am.,1994,58 1194-1199
[89]刘兴健,葛晨东 人类活动对海南省小海泻湖沉积环境的影响[J]环境化学,2007,26(30)：384-387
[90]Krishnamurthy R V,Bhattacharya S K,Sheela Kusumgar. Palaeoclimatic changes deduced from13C/12C and C/N ratios of Karewa lake sediments [J] India. Nature,1986,323:150-152
[91]Wagner B,Melles M,Hahne J et al 2000 Holocene climate history of Geographical Socienty Q East Greenland-evidence from lake sediments [J] Palaeogeography, Palaeoclimateology Palaeoecology 2000,160:45-68
[92]Nakai N, Koyama M. Reconstruction of palaeoenvironment from the vie-points of the inorganic constituents, C/N ratio and carbon isotopic ratio in the 1400m core taken from lake Biwa.In:S.Horie(editor),History of Lake Biwa, Kyoto Univ Coontrib,1987,137-156
[93]Anne Muller.Ulrike Mathesius.The Palaeoenvironment of coastal lagoons in the southern Baltic Sea The application of sedimentaru Corg/N ratios as source indicators of organic matter [J] Palaeogeography,Palaeoclimatology, Palaeoecology.1999,145:1-16
[94]Giresse P Maley J Brenac P Lake Quaternary Plaeoenvironment in the Lake Barombi Mbo(West Cameron)Deduced From Pollern And Carbon Isotopes of Organic Matter,\[M] Palaeogeography Palaeoclimatology, Palaeoecology 1994,107:65-78
[95]朱松泉,窦宏身.洪泽湖[M]合肥：中国科学技术大学出版,1993,94-95
[96]潘红玺.横断山区湖泊中溶解氧的分布特征[J].湖泊科学,1990,2(2)：53-60
[97]隆浩 季风边缘区全新世中期气候变化韵古湖泊记录[S]硕士学位论文,兰州大学,2006
[98]Ruttenberg K C,Goni M A.Phosphorus Distribution,C:N:Pratios, and δ13C in Arctic, Tempreate,and Tropical Sediments:Tools for Charactrtizing Buck Sedimentary Organic Matter [J] Marine Geology, 1997,139:123-145.
[99]Carpenter SR.Phosphorus control is critical to mitigating eutrophication.Proceedings of National [J] Academy of Scieences,2008,105:11039-11040.
[100]Jφrgensen NOG，Niels OGOrganic nitrogen.In:Likens GE ed.Encyclopedia of Inland Waters. [J]London:Academic Press,2009, Vol.2:832-851.
[101]Worsfold PJ,Monbet P,Tappin AD et al.Characterisation and quantification of organic phosphorus and organic nitrogen components in aquatic systems:A Review [J] Analytica Chimica Acta,2008,624:37-58.
[102]吴丰昌,王立英,黎文等.天然有机质及其在地表环境中的重要性[J]湖泊科学,2008,20(1)：1-12.
[103]Fu PQ, Wu FC, Liu CQ et al Spectorscopic characterization and molecular weight distribution of dissolved organic matter in sediment porewaters from Lake Erhai, Southwest [J] Biogeochemistry, 2006,81:179-189
[104]Sharpley A,Tunney H Phosphorus research strategies to meet agricultural and environmental challenges of the 21 st century [J] Journal of Environmental Quality,2000,29(1):176-251
[105]Burdige Dj, Zheng SL.The biogeochemical cycling of dissolved organic nitrogen in estuarine sediments [J] Limnology and Oceaography,1998,43:1796-1813
[106]Stepanauskas R,Leonardos L,Tranvik KJ. Bioavaibility of wetland-derived DON to freshwater and marine bacterioplankton [J] Limnology and Oceanography,1999,44:1477-1485
[107]Carmand R, Edlund G, Damberg C. Distrbution of organic and inorganic for measurement of dissolved organic nirogen in seawater [J] Marine Chemistry,2002,78:171-184
[108]Turner BL, McKelvie ID, Haygarth PM. Characterization of water-extractable soil organic phosphorus by phosphatase hydrolysis [J] Soil Biology and Biochemistry,2002,34:29-37
[109]Newman RH,Tate KR.Soil phosphorus chacterization by 31P nuclear magnetic resonance [J] Communications in Soil Science and Plant Analysis,1980,11:835-842
[110]Nordstrom D K,Southam G Geomicrobiology of sulfide mineral oxidation [J] Rev. Mineral Geochem 1997,35:361-382
[111]Lovely D R, Stolz J F, Nord GL Phillips E J P Anaerobic production of magnetite by a dissimilatory iron-reducing microorganism [J] Nature,1987,330:252-254
[112]Ehrlich H L Geomicrobiology,3rded [M] Marcel Dekker Inc., New York 1996
[113]Tong Yong Lin,Guofang, Ke Xin, et al. Comparison of microbial community between two shallow freshwater lakes in middle Yangtze basin, East China [J]. Chemosphere,2005,60 (1):85-92
[114]冯峰,王辉 东湖沉积物中微生物量与碳、氮、磷的相关性[J]中国环境科学,2006,26(3)：342-345
[115]魏中青,刘丛强等 贵州红枫湖沉积物中有机质的降解与微生物作用[J]科学通报,2005,50(14)：1486-1489
[116]张恒军 河流沉积物中微生物对营养盐释放的影响研究[S]硕士学位论文,中山大学,2004
[117]沈宏,曹志洪,胡正义.土壤活性有机碳的表征及其生态效应[J]生态学杂志,1999,18(3)：32-38
[118]Ann-Loiuse,Haglund Peter lantz, Erik Tomblom Depth distribution of active Microbes activity in lake sediment [J] FEMs Microbiology,2002,46:31-38
[119]Wenjun ZH,Aixiao H,Chengli T et al Estimating organic carbon stroge in temperate wetland profiles in Northeast China [J] Geoderma,2008,146:311-316
[120]Lovey D R,Kashefi K,Vargas M et al Reduction of humic subtances and Fe(III) by hyperthemophilic microorganism [J] Chemical geology,2000,169(3-4):289-298
[121]武春媛,李芳柏,周顺桂 腐殖质呼吸作用及其生态学意义[J]生态学报,2009,29(2)：1535-1542
[122]王永华,钱少猛,徐南妮等.巢湖东区底泥污染物分布特征及评价[J].环境科学研究,2004,17(6)：22-25.
[123]Bernstein B,Zehr E I,Dean R A et al Characteristics of Colletotrichum species responsible for anthracnose disease of various fruits [J] Plant Disease,1998,82(6):596-605
[124]Mudroch A, Azcue D J M. Manual of Aquatic Sediment Sampling [M]. Boca Raton,Florida:Lewis Publications,1995,224.
[125]邬红娟,崔博,吕晋等 武汉湖泊底栖动物群落结构及水质生态评价[J]华中科技大学学报(自然科学版),2005,33(10)95-98