静电纺丝技术制备无机/有机纳米杂化光致变色纳米带与表征
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摘要
纳米带以其独特的性质,在光、电等领域有巨大的潜在的应用价值,从而引起科学家们的高度重视。光致变色材料广泛应用于信息存储、装饰和包装材料、信号显示等领域。采用静电纺丝技术,将光致变色纳米粒子掺入到高分子中制备无机-有机光致变色纳米带,是一个新颖的研究课题。
本文将AgX水溶胶、AgX有机溶胶、双硫腙锌(Zn(HDz)_2)分别掺入到聚乙烯醇(PVA)、聚甲基丙烯酸甲酯(PMMA)、聚乙烯吡咯烷酮(PVP)中利用溶胶-凝胶法配制成具有一定粘度的前驱体溶液,采用静电纺丝技术制备了AgX/PVA复合纳米带、AgX/PMMA复合纳米带、Zn(HDz)_2/PVA复合纳米带及AgX/PVP复合纳米纤维。采用XRD、FTIR、SEM、UV-Vis等测试手段对其进行结构表征和性能测试。结果表明,所制备的AgX/PVA、Zn(HDz)_2/PVA复合纳米带宽度为1～2μm,厚度为100nm;AgX/PMMA复合纳米带宽度为5～10μm,厚度为1μm;AgX/PVP复合纳米纤维直径为200nm。所制备的纳米复合材料都具有良好的光致变色性质。
Nanoribbons have aroused much attention from many scientists due to their particular properties and greatly potential applications in light, electricity and so on. Photochromatic material can be used in information storage, decorative material, package material, signal display and other fields because of their unique characteristics. It is a novel research subject to insert photochromic nanoparticles into polymer to prepare inorganic compounds/polymer nanometer hybrid photochromic composite nanoribbons by electrospinning.
In this disseration, sol-gel technique was employed to prepare the precusor solution with certain viscosity by mixing AgX hydrosol, AgX organosol, Zn(HDz)_2 with PVA, PMMA, and PVP, respectively and prepared AgX/PVA composite nanoribbons, AgX/PMMA composite nanoribbons, Zn(HDz)_2/PVA composite nanoribbons and AgX/PVP composite nanofibers using electrospinning technique. The samples were systematically characterized by XRD, FTIR, SEM, UV-Vis, et al. The results illustrate that the width of AgX/PVA, Zn(HDz)_2/PVA composite nanoribbons are all in 1～2μm and the thickness is about 100nm; the width of AgX/PMMA composite nanoribbons are all in 5～10μm and the thickness is about 1μm; the diameter of AgX/PVP composite nanofibers are around 200nm. These samples which we have mentioned above all have excellent photochromism effect.
本文将AgX水溶胶、AgX有机溶胶、双硫腙锌(Zn(HDz)_2)分别掺入到聚乙烯醇(PVA)、聚甲基丙烯酸甲酯(PMMA)、聚乙烯吡咯烷酮(PVP)中利用溶胶-凝胶法配制成具有一定粘度的前驱体溶液,采用静电纺丝技术制备了AgX/PVA复合纳米带、AgX/PMMA复合纳米带、Zn(HDz)_2/PVA复合纳米带及AgX/PVP复合纳米纤维。采用XRD、FTIR、SEM、UV-Vis等测试手段对其进行结构表征和性能测试。结果表明,所制备的AgX/PVA、Zn(HDz)_2/PVA复合纳米带宽度为1～2μm,厚度为100nm;AgX/PMMA复合纳米带宽度为5～10μm,厚度为1μm;AgX/PVP复合纳米纤维直径为200nm。所制备的纳米复合材料都具有良好的光致变色性质。
Nanoribbons have aroused much attention from many scientists due to their particular properties and greatly potential applications in light, electricity and so on. Photochromatic material can be used in information storage, decorative material, package material, signal display and other fields because of their unique characteristics. It is a novel research subject to insert photochromic nanoparticles into polymer to prepare inorganic compounds/polymer nanometer hybrid photochromic composite nanoribbons by electrospinning.
In this disseration, sol-gel technique was employed to prepare the precusor solution with certain viscosity by mixing AgX hydrosol, AgX organosol, Zn(HDz)_2 with PVA, PMMA, and PVP, respectively and prepared AgX/PVA composite nanoribbons, AgX/PMMA composite nanoribbons, Zn(HDz)_2/PVA composite nanoribbons and AgX/PVP composite nanofibers using electrospinning technique. The samples were systematically characterized by XRD, FTIR, SEM, UV-Vis, et al. The results illustrate that the width of AgX/PVA, Zn(HDz)_2/PVA composite nanoribbons are all in 1～2μm and the thickness is about 100nm; the width of AgX/PMMA composite nanoribbons are all in 5～10μm and the thickness is about 1μm; the diameter of AgX/PVP composite nanofibers are around 200nm. These samples which we have mentioned above all have excellent photochromism effect.
引文
[1]史鸿鑫,王农跃,项斌等.化学功能材料功能概论[M].化学工业出版社,2006,3-51
[2]金怀龙.静电纺丝技术制备功能高分子纳米纤维与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2008
[3]Pan Z W,Dai Z R,Wang Z L.Nanobelts of semiconductingoxides[J].Science,2001,291(5510):1947-1949
[4]YAO Qi-Jun,LI de-jie.Progress in field emission display with carbon nanotube emitter[J].Vacuum electronics,2002,4(6):6-9
[5]Xiang Yang Kong,Zhong Lin Wang.Structures of indium oxide nanobelts[J].Solid State Communications,2003,128(1):1-4
[6]CUI Y,WEI Q,PARK H,et al.Nanowire Nanosensors for Highly Sensitive and Selective Detection of Biological and Chemical Species[J].Science,2001,293(5533):1289
[7]LAW M,KIND H,MESSER B,et al.Photochemical sensing of NO_2 with SnO_2 nanoribbon nanosensors at room temperature[J].Angew.Chem.Int.Ed,2002,41(13):2405-2408
[8]周菊红,王涛,陈友存,张元广.水热法合成一维纳米材料的研究进展[J].化学通报,2008,7(1):510-517
[9]Z Y Yuan,J F Colomer,B L Su,et al.Titanium oxide nanoribbons[J].Chem Phys Lett,2002,363(34):362-366
[10]黄在银.TiO_2纳米带的水热合成表征及光催化性能[J].广西民族学院学报(自然科学版).2005,11(4):117-120
[11]马林.夏军保,陈卫祥等.WS_2纳米带的水热合成与表征[J].浙江大学学报.2006.40(5):832-835
[12]奚伊.胡陈果,韩向宇.水热合成ZnO纳米带[J].纳米科技,2006.3(6):45-47
[13]祁琰媛,陈文,麦立强等.过氧钼酸溶胶制备的MoO_3纳米带及其电化学性能研究[J].稀有金属,2007,31(1):67-71
[14]TAO You-Rong,ZHANG Yu-Ling,WEN Le-Le,W U Xing-Cai.Synthesis,Characterization and Gas-sensing Properties of Sodillm Titanate Nanobelts[J].Chinese Journal of Indganic Chemistry,2008,24(10):1570-1575
[15]D.E.Zhang,X.D.Pan,H.Zhu,S.Z.Li,et al.A Simple Method to Synthesize Cadmium Hydroxide Nanobelts[J].Nanoscale Res Lett,2008,3(8):284-288
[16]Dekun Ma,Shaoming Huang,Lijie Zhang,et al.One-pot synthesis and magnetic,electrical properties of single-crystalline α-MnO nanobelt[J].Chemical Physics Letters,2008,462(1):96-99
[17]鲁娟,韩巧凤.杨绪杰等.Bi_2S_3纳米带的制备及其谱学性能研究[J].光谱学及光谱分析,2009,29(1):48-51
[18]嵇天浩,侯少凡,杜海燕,孙家跃.六方相WO_3纳米带的制备与表征[J].无机化学学报,2009,25(5):818-822
[19]Haiyan Luo,Mingdeng Wei,Kemei Wei.A new metastable phase of crystallized MoO_3·0.3H_2O nanobelts[J].Materials Chenistry and Physics,2009,113(15):85-90
[20]吴迪.吴建.卟啉的分子自组装[J].化学世界,2004,45(10):551-555
[21]LUO Y H,LIU H W,XI F,et al.Supramolecular Assembling of Poly(Phenylene Vinylene) with Crown-Ether-Derivatives to Form Nanoribbons[J].J.Am.Chem.Soc,2003,125(21):6447-6451
[22]邹强,张之圣,李海燕等.高分子自组装ZnO纳米带合成过程的研究[J].无机化学学报.2006,9(22):1675-1678
[23]陈升红,齐俊杰,黄运华等.Sn掺杂ZnO半导体纳米带的制备、结构和性能[J].物理化学学报,2007,23(1):55-58
[24]郭彦,吴强,王喜章.氧化镓纳米带的合成和发光性质研究[J].无机化学学报,2005,21(5):669-671
[25]黄运华,张跃,贺建等.氧化锌纳米带的低温无催化热蒸发制备及其表征[J].物理化学学报,2005,21(3):239-243
[26]应鹏展,倪自丰,修伟杰等.超长SnO_2纳米带的制备及表征的研究[J].中国矿业大学学报,2006,35(2):206-208
[27]ZHANG Jiang,ZHAO Yan-Ming.Synthersis,Structure and Growth Mechanism of Magnesium Borate Nanobelts[J].Acta Phys.Chim.Sin,2006,22(1):110-113
[28]倪自丰,应鹏展,罗勇等.碳热还原法制备SnO_2纳米带及其表征分析[J].无机材料报,2007,22(4):609-612
[29]Zhiqiang Wang,Xuedong Liu,Jiangfeng Gong,et al.Epitaxial Growth of ZnO Nanowires on ZnS Nanobelts by Metal Organic Chemical Vapor Deposition[J].Crystal Growth & Design,2008,11(8):3911-3913
[30]赵勇,俞进,盛广沪等.碳纳米带的催化生长及其机理的研究[J].硅酸盐通报,2008,27(2):264-268
[31]孔德强,袁运法,白召军等.溶胶凝胶法合成莫来石纳米带[J].无机化学学报,2006,2(22):359-362
[32]Ch.V.Subba Reddy,Y.Y.Qi,W.Jin,Q.Y.Zhu,et al.An electrochemical investigation on(MoO_3+PVP+PVA)nanobelts for lithium batteries[J].J Solid State Electrochem,2007,11(9):1239-1243
[33]Morton,W.J.Method of dispersing fluids[P].US Patent,1902,705691.
[34]FORMHALS A.Process and apparatus for preparing artificial threads:US,1975504[P].1934
[35]Li Dan,Xia Younan.Electrospinning of nanofibers:Reinventing the wheel[J].Advanced Materials,2004,16(14):1151-1170
[36]A.Koski,K.Yim,S.Shivkumar.Effect of molecular weight on fibrous PVA produced by electrospinning[J].Materials Letters,2004,58(34):493-497
[37]Muzafar A.Kanjwal,Nasser A.M.Barakat,et al.Physiochemical characterizations of nanobelts consisting of three mixed oxides(Co_3O_4,CuO,and MnO_2) prepared by electrospinning technique[J].J Mater Sci,2008,43(16):5489-5494
[38]李志国.静电纺丝技术制备二氧化钛纳米材料与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2008
[39]李欣.静电纺丝技术制备稀土配合物/PMMA纳米带与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2009
[40]张瑞刚,杨合情等.GaN纳米带、纳米环和Z字结构纳米线在金属镓颗粒上的原位生长及其发光性质[J].中国科学,2008,38(3):205-217
[41]苏碧桃,胡常林,左显维,雷自强.Cd(OH)_2和CdO纳米带的制备[J].化学试剂,2008,30(12):897-898
[42]杨枣.彭坤等.纳米带的研究进展[J].材料科学与工艺,2006,5(14):538-542
[43]Pan Zhengwei,Dai Zurong,Wang Zhonglin.Nanobelts of semiconducting oxides[J].Science,2001,291(5510):1947-1949
[44]Li Quan,Wang Chunrui.One-step fabrication of uniform Si-core/CdSe-Sheath nanocables[J].J.Am.Chem.Soc.2003,125(33):9892-9893
[45]赵文元,王亦军.功能高分子材料化学[M].化学工业出版社.2004,259-263
[46]焦剑,姚军燕.功能高分子材料[M].化学工业出版社,2007,146-150
[47]王匆敏,潘桂兰,赵利华等.有机光致变色材料的最新成就与机遇[J].有机化学,2001,21(11):954-961
[48]于伟利.静电纺丝技术制备光致变色超细纤维与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2006
[49]W.S.Johnson and G.H.Daub.Organic Reaction.6[M].New York:John Willy and Sons Inc.1951.1-73
[50]Y.Yokoyama.Fulgides for memories and switches[J].Chem.Rev.,2000,100(5):1717-1793
[51]廖宁放,巩马理,徐瑞颐等.光致变色俘精酸酐体系的单光束双光子多层记录特性[J].科学通报,2001,16(5):1345-1348
[52]P.Bamfield,M.Hutchings.Chromic Phenomena-The Technological Applications of Colour Chemistry[M].Bodmin,UK:MPG Books Ltd,2001.7-33
[53]姚保利,陈鼓,王英利等.双色俘精酸酐薄膜的双波长图像光存储[J].光学学报.2005,25(2):220-223
[54]J C B Waddingtor.J.Am.Chem.Soc.1964,86:2351
[55]H Kamagawa et al.J.Polym.Sci.1968,A-1(6):2967
[56]孔德星.偶氮苯类光致变色高分子化合物的合成及应用[J].工业科技,2007,36(2):57
[57]梁卫东,杨爱梅,王志国等.偶氮苯衍生物的光致变色性及应用[J].甘肃农业大学学报,2001,36(1):38-43
[58]罗千福.范曲立,黄维.二芳基乙烯类光致变色材料的合成概述[J].有机化学.2007,27(2):175-187
[59]解仁国,庄家骐,王凌凌.一种具有高光致变色性能的WO_3/ZnO纳米粒子复合体系[J].高等学校化学学报,2003,24(11):2086-2088
[60]郑向军.王利亚,郭建权等.镧系元素-N,N-二(2-氧吡咯-1-甲基)甘氨酸-啉菲咯啉三元体系的光致变色[J].无机化学学报,2000.5(2):152-158
[61]Pedro Gomez-Romero,Clement Sanchez.功能杂化材料[M].化学工业出版社,2006,1-266
[62]张心亚,黎永津,傅和青等.无机-有机杂化纳米材料的控制合成与结构组装的研究进展[J].材料导报.2007,21(5):32-35
[63]Orialchi C O,Lerner M M.Poly(pyrrole) and poly(thiophene) / clay nanocomposites[J].Mater Res Bull,1995,30(6):723
[64]Carlucci L,Gianf ranco C.1,2 and 3-dimentional polyericframes in the coordination chemistry of AgBF_4 with pyrazine:The first example of three interpenet rating 3-dimentional triconnected nets[J].J Am ChemSoc,1995,117(25):4562
[65]李宏途,张宏文,王静媛等.用原子转移自由基聚合方法制备新型含有高分子金属配合物的无机-有机杂化材料[J].高等学校化学学报,2005,126(7):1381
[66]Mori H,Seng D C,Zhang M,et al.Hybrid nanoparticles with hyperbranched polymer shells via self-condensing atom transfer radical polymerization from silica surfaces[J].Langmuir,2002,18(9):3682
[67]刘安华.温永向,张利利.含硅有机/无机纳米杂化材料[J].功能材料,2005,5(36):658-661
[68]J.DOSHI,D.H.RENEKER.Electrospinning Process and Application of Electrospun Fibers[J].Journal of Electrostatics,1995,35(23):151 - 160
[69]冯秀丽.纳米AgCl-PMMA杂化材料的制备与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2003
[70]何颖.纳米AgBr-PMMA杂化材料的制备与表征:[硕士学位论文].长春:长春光学精密机械学院.2002
[71]于明昕,周啸.金属双硫腙在聚合物介质中的光致变色行为[J].功能材料,2001,32(2):203-205
[72]吴世康,沈燕清.双硫腙汞络合物在高分膜内的光色互变研究[J].功能高分子学报,1990,3(8):3-7
[73]Meriwether L S,Breither E C,Sloan C Let al.Kinetic and infrared study of photochromism of metal dithizonates[J].J Am Chem Soc.,1965,87:4448
[74]宋美荣,张治军.AgX光致变色机理及其在聚合物中的应用[J].河南大学学报,2003,33(4):66-69
[2]金怀龙.静电纺丝技术制备功能高分子纳米纤维与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2008
[3]Pan Z W,Dai Z R,Wang Z L.Nanobelts of semiconductingoxides[J].Science,2001,291(5510):1947-1949
[4]YAO Qi-Jun,LI de-jie.Progress in field emission display with carbon nanotube emitter[J].Vacuum electronics,2002,4(6):6-9
[5]Xiang Yang Kong,Zhong Lin Wang.Structures of indium oxide nanobelts[J].Solid State Communications,2003,128(1):1-4
[6]CUI Y,WEI Q,PARK H,et al.Nanowire Nanosensors for Highly Sensitive and Selective Detection of Biological and Chemical Species[J].Science,2001,293(5533):1289
[7]LAW M,KIND H,MESSER B,et al.Photochemical sensing of NO_2 with SnO_2 nanoribbon nanosensors at room temperature[J].Angew.Chem.Int.Ed,2002,41(13):2405-2408
[8]周菊红,王涛,陈友存,张元广.水热法合成一维纳米材料的研究进展[J].化学通报,2008,7(1):510-517
[9]Z Y Yuan,J F Colomer,B L Su,et al.Titanium oxide nanoribbons[J].Chem Phys Lett,2002,363(34):362-366
[10]黄在银.TiO_2纳米带的水热合成表征及光催化性能[J].广西民族学院学报(自然科学版).2005,11(4):117-120
[11]马林.夏军保,陈卫祥等.WS_2纳米带的水热合成与表征[J].浙江大学学报.2006.40(5):832-835
[12]奚伊.胡陈果,韩向宇.水热合成ZnO纳米带[J].纳米科技,2006.3(6):45-47
[13]祁琰媛,陈文,麦立强等.过氧钼酸溶胶制备的MoO_3纳米带及其电化学性能研究[J].稀有金属,2007,31(1):67-71
[14]TAO You-Rong,ZHANG Yu-Ling,WEN Le-Le,W U Xing-Cai.Synthesis,Characterization and Gas-sensing Properties of Sodillm Titanate Nanobelts[J].Chinese Journal of Indganic Chemistry,2008,24(10):1570-1575
[15]D.E.Zhang,X.D.Pan,H.Zhu,S.Z.Li,et al.A Simple Method to Synthesize Cadmium Hydroxide Nanobelts[J].Nanoscale Res Lett,2008,3(8):284-288
[16]Dekun Ma,Shaoming Huang,Lijie Zhang,et al.One-pot synthesis and magnetic,electrical properties of single-crystalline α-MnO nanobelt[J].Chemical Physics Letters,2008,462(1):96-99
[17]鲁娟,韩巧凤.杨绪杰等.Bi_2S_3纳米带的制备及其谱学性能研究[J].光谱学及光谱分析,2009,29(1):48-51
[18]嵇天浩,侯少凡,杜海燕,孙家跃.六方相WO_3纳米带的制备与表征[J].无机化学学报,2009,25(5):818-822
[19]Haiyan Luo,Mingdeng Wei,Kemei Wei.A new metastable phase of crystallized MoO_3·0.3H_2O nanobelts[J].Materials Chenistry and Physics,2009,113(15):85-90
[20]吴迪.吴建.卟啉的分子自组装[J].化学世界,2004,45(10):551-555
[21]LUO Y H,LIU H W,XI F,et al.Supramolecular Assembling of Poly(Phenylene Vinylene) with Crown-Ether-Derivatives to Form Nanoribbons[J].J.Am.Chem.Soc,2003,125(21):6447-6451
[22]邹强,张之圣,李海燕等.高分子自组装ZnO纳米带合成过程的研究[J].无机化学学报.2006,9(22):1675-1678
[23]陈升红,齐俊杰,黄运华等.Sn掺杂ZnO半导体纳米带的制备、结构和性能[J].物理化学学报,2007,23(1):55-58
[24]郭彦,吴强,王喜章.氧化镓纳米带的合成和发光性质研究[J].无机化学学报,2005,21(5):669-671
[25]黄运华,张跃,贺建等.氧化锌纳米带的低温无催化热蒸发制备及其表征[J].物理化学学报,2005,21(3):239-243
[26]应鹏展,倪自丰,修伟杰等.超长SnO_2纳米带的制备及表征的研究[J].中国矿业大学学报,2006,35(2):206-208
[27]ZHANG Jiang,ZHAO Yan-Ming.Synthersis,Structure and Growth Mechanism of Magnesium Borate Nanobelts[J].Acta Phys.Chim.Sin,2006,22(1):110-113
[28]倪自丰,应鹏展,罗勇等.碳热还原法制备SnO_2纳米带及其表征分析[J].无机材料报,2007,22(4):609-612
[29]Zhiqiang Wang,Xuedong Liu,Jiangfeng Gong,et al.Epitaxial Growth of ZnO Nanowires on ZnS Nanobelts by Metal Organic Chemical Vapor Deposition[J].Crystal Growth & Design,2008,11(8):3911-3913
[30]赵勇,俞进,盛广沪等.碳纳米带的催化生长及其机理的研究[J].硅酸盐通报,2008,27(2):264-268
[31]孔德强,袁运法,白召军等.溶胶凝胶法合成莫来石纳米带[J].无机化学学报,2006,2(22):359-362
[32]Ch.V.Subba Reddy,Y.Y.Qi,W.Jin,Q.Y.Zhu,et al.An electrochemical investigation on(MoO_3+PVP+PVA)nanobelts for lithium batteries[J].J Solid State Electrochem,2007,11(9):1239-1243
[33]Morton,W.J.Method of dispersing fluids[P].US Patent,1902,705691.
[34]FORMHALS A.Process and apparatus for preparing artificial threads:US,1975504[P].1934
[35]Li Dan,Xia Younan.Electrospinning of nanofibers:Reinventing the wheel[J].Advanced Materials,2004,16(14):1151-1170
[36]A.Koski,K.Yim,S.Shivkumar.Effect of molecular weight on fibrous PVA produced by electrospinning[J].Materials Letters,2004,58(34):493-497
[37]Muzafar A.Kanjwal,Nasser A.M.Barakat,et al.Physiochemical characterizations of nanobelts consisting of three mixed oxides(Co_3O_4,CuO,and MnO_2) prepared by electrospinning technique[J].J Mater Sci,2008,43(16):5489-5494
[38]李志国.静电纺丝技术制备二氧化钛纳米材料与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2008
[39]李欣.静电纺丝技术制备稀土配合物/PMMA纳米带与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2009
[40]张瑞刚,杨合情等.GaN纳米带、纳米环和Z字结构纳米线在金属镓颗粒上的原位生长及其发光性质[J].中国科学,2008,38(3):205-217
[41]苏碧桃,胡常林,左显维,雷自强.Cd(OH)_2和CdO纳米带的制备[J].化学试剂,2008,30(12):897-898
[42]杨枣.彭坤等.纳米带的研究进展[J].材料科学与工艺,2006,5(14):538-542
[43]Pan Zhengwei,Dai Zurong,Wang Zhonglin.Nanobelts of semiconducting oxides[J].Science,2001,291(5510):1947-1949
[44]Li Quan,Wang Chunrui.One-step fabrication of uniform Si-core/CdSe-Sheath nanocables[J].J.Am.Chem.Soc.2003,125(33):9892-9893
[45]赵文元,王亦军.功能高分子材料化学[M].化学工业出版社.2004,259-263
[46]焦剑,姚军燕.功能高分子材料[M].化学工业出版社,2007,146-150
[47]王匆敏,潘桂兰,赵利华等.有机光致变色材料的最新成就与机遇[J].有机化学,2001,21(11):954-961
[48]于伟利.静电纺丝技术制备光致变色超细纤维与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2006
[49]W.S.Johnson and G.H.Daub.Organic Reaction.6[M].New York:John Willy and Sons Inc.1951.1-73
[50]Y.Yokoyama.Fulgides for memories and switches[J].Chem.Rev.,2000,100(5):1717-1793
[51]廖宁放,巩马理,徐瑞颐等.光致变色俘精酸酐体系的单光束双光子多层记录特性[J].科学通报,2001,16(5):1345-1348
[52]P.Bamfield,M.Hutchings.Chromic Phenomena-The Technological Applications of Colour Chemistry[M].Bodmin,UK:MPG Books Ltd,2001.7-33
[53]姚保利,陈鼓,王英利等.双色俘精酸酐薄膜的双波长图像光存储[J].光学学报.2005,25(2):220-223
[54]J C B Waddingtor.J.Am.Chem.Soc.1964,86:2351
[55]H Kamagawa et al.J.Polym.Sci.1968,A-1(6):2967
[56]孔德星.偶氮苯类光致变色高分子化合物的合成及应用[J].工业科技,2007,36(2):57
[57]梁卫东,杨爱梅,王志国等.偶氮苯衍生物的光致变色性及应用[J].甘肃农业大学学报,2001,36(1):38-43
[58]罗千福.范曲立,黄维.二芳基乙烯类光致变色材料的合成概述[J].有机化学.2007,27(2):175-187
[59]解仁国,庄家骐,王凌凌.一种具有高光致变色性能的WO_3/ZnO纳米粒子复合体系[J].高等学校化学学报,2003,24(11):2086-2088
[60]郑向军.王利亚,郭建权等.镧系元素-N,N-二(2-氧吡咯-1-甲基)甘氨酸-啉菲咯啉三元体系的光致变色[J].无机化学学报,2000.5(2):152-158
[61]Pedro Gomez-Romero,Clement Sanchez.功能杂化材料[M].化学工业出版社,2006,1-266
[62]张心亚,黎永津,傅和青等.无机-有机杂化纳米材料的控制合成与结构组装的研究进展[J].材料导报.2007,21(5):32-35
[63]Orialchi C O,Lerner M M.Poly(pyrrole) and poly(thiophene) / clay nanocomposites[J].Mater Res Bull,1995,30(6):723
[64]Carlucci L,Gianf ranco C.1,2 and 3-dimentional polyericframes in the coordination chemistry of AgBF_4 with pyrazine:The first example of three interpenet rating 3-dimentional triconnected nets[J].J Am ChemSoc,1995,117(25):4562
[65]李宏途,张宏文,王静媛等.用原子转移自由基聚合方法制备新型含有高分子金属配合物的无机-有机杂化材料[J].高等学校化学学报,2005,126(7):1381
[66]Mori H,Seng D C,Zhang M,et al.Hybrid nanoparticles with hyperbranched polymer shells via self-condensing atom transfer radical polymerization from silica surfaces[J].Langmuir,2002,18(9):3682
[67]刘安华.温永向,张利利.含硅有机/无机纳米杂化材料[J].功能材料,2005,5(36):658-661
[68]J.DOSHI,D.H.RENEKER.Electrospinning Process and Application of Electrospun Fibers[J].Journal of Electrostatics,1995,35(23):151 - 160
[69]冯秀丽.纳米AgCl-PMMA杂化材料的制备与表征:[硕士学位论文].长春:长春理工大学化学与环境工程学院.2003
[70]何颖.纳米AgBr-PMMA杂化材料的制备与表征:[硕士学位论文].长春:长春光学精密机械学院.2002
[71]于明昕,周啸.金属双硫腙在聚合物介质中的光致变色行为[J].功能材料,2001,32(2):203-205
[72]吴世康,沈燕清.双硫腙汞络合物在高分膜内的光色互变研究[J].功能高分子学报,1990,3(8):3-7
[73]Meriwether L S,Breither E C,Sloan C Let al.Kinetic and infrared study of photochromism of metal dithizonates[J].J Am Chem Soc.,1965,87:4448
[74]宋美荣,张治军.AgX光致变色机理及其在聚合物中的应用[J].河南大学学报,2003,33(4):66-69