以苯乙胺为母体的亚胺配合物的合成及结构
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摘要
自然界的许多生命现象和基本定律都是由手性即不对称性引起的,许多生物活性分子都是手性分子,手性是自然界的基本特征。不对称合成是有机合成化学研究的热点和前沿。
手性配体是手性催化剂的主体,也是不对称催化化学的基础。它的设计与合成是不对称催化研究中的主题。手性胺类配体在不对称催化反应中的应用较为广泛。本论文在以苯乙胺为原料的手性配体的合成中做了一些工作。
本论文是在本课题组以往亚胺的合成基础上开展的。以α-苯乙胺为起始原料,与脂肪酮进行缩合得到手性酮亚胺,并探索了与苯丙酮缩合的反应。然后以得到的手性酮亚胺为基础,合成了两个氮杂烯丙基配体,并得到了一个与特丁腈配位的晶体结构;同时在实验过程中,以得到的氮杂烯丙基配体为基础,进行了一部分的不对称催化Henry反应。最后,以得到的氮杂烯丙基配体为基础,通过引入二苯基磷基团,合成了相应的亚胺膦配体。
The chirality is a kind of basic characterize of the nature .Many biological phenomenon and basic law in the nature are all created by the chirality. Many biologically active molecules are chiral molecules. The asymmetric synthesis is hot spots and cutting-edge in the organic synthesis.
The chiral ligand is the main body of the chiral catalysts, and the basis of the asymmetric catalysis. The design and synthesis of chiral ligands is the eternally topic on the asymmetric catalyze studies. The chiral amine ligands is used widely in the asymmetric catalyze reactions. In this thesis, my study focused on the field of the chiral ligands from theα-phenylethylamine.
Based on our group's research work, my study is carried out in this paper. Takingα-phenylethylamine as the parent body, chiral ketone-imines were synthesized by condensation reaction, and explore the condensation reaction ofα-phenylethylamine and propiophene. Then based on chiral ketone-imine, two azaallyl complexes were synthesized, and do some work in organometallic chemistry; on the basis of azaallyl complexes, we do some work about the unsymmetrical henry reaction in the experimention. At last, the corresponding imine phosphine ligand was synthesized by inserting into diphenylphosphone group.
手性配体是手性催化剂的主体,也是不对称催化化学的基础。它的设计与合成是不对称催化研究中的主题。手性胺类配体在不对称催化反应中的应用较为广泛。本论文在以苯乙胺为原料的手性配体的合成中做了一些工作。
本论文是在本课题组以往亚胺的合成基础上开展的。以α-苯乙胺为起始原料,与脂肪酮进行缩合得到手性酮亚胺,并探索了与苯丙酮缩合的反应。然后以得到的手性酮亚胺为基础,合成了两个氮杂烯丙基配体,并得到了一个与特丁腈配位的晶体结构;同时在实验过程中,以得到的氮杂烯丙基配体为基础,进行了一部分的不对称催化Henry反应。最后,以得到的氮杂烯丙基配体为基础,通过引入二苯基磷基团,合成了相应的亚胺膦配体。
The chirality is a kind of basic characterize of the nature .Many biological phenomenon and basic law in the nature are all created by the chirality. Many biologically active molecules are chiral molecules. The asymmetric synthesis is hot spots and cutting-edge in the organic synthesis.
The chiral ligand is the main body of the chiral catalysts, and the basis of the asymmetric catalysis. The design and synthesis of chiral ligands is the eternally topic on the asymmetric catalyze studies. The chiral amine ligands is used widely in the asymmetric catalyze reactions. In this thesis, my study focused on the field of the chiral ligands from theα-phenylethylamine.
Based on our group's research work, my study is carried out in this paper. Takingα-phenylethylamine as the parent body, chiral ketone-imines were synthesized by condensation reaction, and explore the condensation reaction ofα-phenylethylamine and propiophene. Then based on chiral ketone-imine, two azaallyl complexes were synthesized, and do some work in organometallic chemistry; on the basis of azaallyl complexes, we do some work about the unsymmetrical henry reaction in the experimention. At last, the corresponding imine phosphine ligand was synthesized by inserting into diphenylphosphone group.
引文
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