几种典型稀土氧化物荧光粉的制备及其紫外—真空紫外光致发光性能研究
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摘要
针对目前照明和信息显示器件用新型荧光粉的发展需要,本论文选取了几种典型的含氧酸盐作为基质材料,制备了以Eu2+、Tm3+、Ce3+、Tb3+、Dy3+等作为激活离子的一种典型磷酸盐、三种硅酸盐和一种锆酸盐荧光粉,并探讨了它们在白光LED以及PDP显示器领域的潜在应用。这一系列研究成果对于探索新型氧化物发光材料的发光性能、推动其在照明和显示器领域的应用具有重要的基础意义和实用价值。
第一,在具有典型磷钠钙石结构的β-NaCaPO4基质中掺入蓝光激活离子Tm3+,并通过对其UV-Vis吸收光谱、UV和VUV激发和发射光谱的研究,首次对β-NaCaPO4:Tm3+的UV-VUV发光性质进行了探讨,同时对各个光谱的峰位进行了归属。结果发现,β-NaCaPO4:Tm3+在UV和VUV激发下具有色纯度较好的蓝光发射,样品的热稳定性能明显优于商用蓝粉,是一种潜在的新型PDP用蓝色荧光粉。
第二,通过调节和控制起始原料中的Al/Si比例,成功制备得到了具有BaAl2O6衍生结构的Ba13Al22Si10O66的单相样品。首次在无还原气氛的制备条件下得到了具有Eu2+特征发光的Ba13Al22Si10O66：Eu2+白色发光材料,并发现其具有蓝白色余辉,该材料不仅可以作为白光LED用发光材料,而且是一种新型长余辉材料。另外Ba13Al22Si10O66：Ce3+和Ba13Al22Si10O66：Tb3+可以在UV激发下产生良好的发光。然而在VUV区域,Ba13Al22Si10O66：Eu2+,Ce3+,Tb3+的发光很弱,没有作为PDP发光材料的潜质。
第三,在硅酸盐基质Li4SrCa(Si04)2掺入了几种典型稀土离子：Eu2+、Tm3+、Ce3+、Dy3+,并首次探索了它们各自的UV-VUV发光性质。Li4SrCa(SiO4)2:Eu2+在UV激发下可以产生良好的蓝紫色发射,是一种有潜力的白光LED用蓝色发光材料；Li4SrCa(Si04)2:Tm3+在UV和VUV激发下都可以产生Tm3+的特征发射,表现为色纯度较好的蓝色发光,同时其VUV最强激发峰与Xe气体放电的激发波长匹配较好,具有作为PDP发光材料的潜力；Li4SrCa(Si04)2:Ce3+在UV和VUV激发下都可以呈现出Ce3+的5d-4f特征蓝色发射,但就色纯度而言,UV激发下的样品更适合被白光LED采用；Li4SrCa(Si04)2:Dy3+在UV和VUV下的发光都为Dy3+的特征f-f发射,其发光颜色偏黄,需要进一步改善。
第四,对稀土焦硅酸盐β-Y2Si2O7尝试单掺Ce3+、Tb3+以及共掺Ce3+和Tb3+,在研究了它们各自的UV-VUV发光性质的基础上,首次探索了两离子在VUV区域的能量传递过程,考察了共掺样品在PDP领域的潜在利用价值。
第五,对双钙钛矿结构的锆酸盐CaZrO3进行了Dy3+、Tm3+的单掺杂以及Dy3+、Tm3+的共掺杂,同时考察了共掺样品在UV区域内的Tm3+和Dy3+的能量传递过程,探索了其在白光LED领域的潜在应用。
Aiming at the demand for the novel phosphors utilized in illumination and display, by selecting several typical oxysalts as host materials, a phosphate, three silicates and a zirconate activated by Eu2+, Tm3+, Ce3+, Tb3+, Dy3+ ions et al. were synthesized, and their potential possibility as novel UV-LED and PDP phosphors were first explored and discussed in this paper. From the angle of basic theory and practical value, the results abovementioned would significantly contribute to the exploration of the photoluminescent properties for the new kinds of oxysalt phosphors and the promotion of the application in illumination and display fields.
First, merrillite structuredβ-NaCaPO4 host was doped by blue-emitting ion Tm3+. The UV-VUV photoluminescent properties ofβ-NaCaPO4:Tm3+ was first investigated by UV-Vis absorption spectra, excitation and emission spectra in UV and VUV region, and all the peaks in the curves were attributed. The results indicated thatβ-NaCaPO4:Tm3+ could generate blue light with good color purity by UV and VUV excitation, the thermal stability of which was evidently better than the commercial blue phosphor. The phosphor could be a new potential blue phosphor for PDP.
Second, single phase of Ba13Al22Si10O66 with the derivative of BaAl2O6 structure was successfully prepared by adjusting and controlling the ratio of Al/Si in raw materials, and the photoluminescent properties of the host activated by Eu2+, Ce3+ and Tb3+ in UV-VUV region was explored. White-emitting phosphor Ba13Al22Si10O66:Eu2+ with the characteristic luminescence of Eu2+ was first obtained without reducing atmosphere and was proved to have bluish white long afterglow. This phosphor could be adopted by white LED and was a new potential long afterglow phosphor. Furthermore, Ba13Al22Si10O66: Ce3+ and Ba13Al22Si10O66: Tb3+ could generated intense luminescence by UV excitation. However, the three phosphors Ba13Al22Si10O66: Eu2+, Ce3+, Tb3+ hardly emitted light in VUV region, which were not proper to serve as PDP phosphor.
Third, several representative rare-earth ions (Eu2+, Tm3+, Ce3+, Dy3+) were introduced in the silicates host Li4SrCa(SiO4)2, and their photoluminescent properties were first discussed in UV-VUV region. Li4SrCa(SiO4)2: Eu2+ could generate bluish purple emission by UV excitation, which was a potential blue-emitting phosphor utilized by white LED. Li4SrCa(Si04)2:Tm3+ emitted the characteristic emission of Tm3+ by UV and VUV irradiation, which was blue light with good color purity. The strongest VUV excitation peak of the sample matched well with the wavelength that the Xe gas discharged; hence it could be suitable serve as PDP phosphors. By UV and VUV excitation, Li4SrCa(SiO4)2:Ce3+ could produce 5d-4f characteristic emission of Ce3+ by both UV and VUV excitation, however, apropos to the color purity, the sample under UV excitation was proper to be adopted by white LED. The luminescence of Li4SrCa(SiO4)2: Dy3+ generated the characteristic f-f emission of Dy3+ by UV and VUV excitation, which was yellowish and needed to be improved.
Fourth, the UV-VUV photoluminescent properties of rare-earth focal silicateβ-Y2Si2O7 doped with Ce3+, Tb3+ or Ce3++Tb3+ were studied, and the energy transfer process of the two ions in VUV region were first explored. Hence the potential possibility for it to serve as PDP phosphor was valued.
Fifth, double-perovskite-structured CaZrO3 was doped with Dy3+, Tm3+ and Dy3++Tm3+. The energy transfer process of Dy3+ and Tm3+ in co-doped samples was investigated, and the co-doped samples were potentially utilized in white LED.
第一,在具有典型磷钠钙石结构的β-NaCaPO4基质中掺入蓝光激活离子Tm3+,并通过对其UV-Vis吸收光谱、UV和VUV激发和发射光谱的研究,首次对β-NaCaPO4:Tm3+的UV-VUV发光性质进行了探讨,同时对各个光谱的峰位进行了归属。结果发现,β-NaCaPO4:Tm3+在UV和VUV激发下具有色纯度较好的蓝光发射,样品的热稳定性能明显优于商用蓝粉,是一种潜在的新型PDP用蓝色荧光粉。
第二,通过调节和控制起始原料中的Al/Si比例,成功制备得到了具有BaAl2O6衍生结构的Ba13Al22Si10O66的单相样品。首次在无还原气氛的制备条件下得到了具有Eu2+特征发光的Ba13Al22Si10O66：Eu2+白色发光材料,并发现其具有蓝白色余辉,该材料不仅可以作为白光LED用发光材料,而且是一种新型长余辉材料。另外Ba13Al22Si10O66：Ce3+和Ba13Al22Si10O66：Tb3+可以在UV激发下产生良好的发光。然而在VUV区域,Ba13Al22Si10O66：Eu2+,Ce3+,Tb3+的发光很弱,没有作为PDP发光材料的潜质。
第三,在硅酸盐基质Li4SrCa(Si04)2掺入了几种典型稀土离子：Eu2+、Tm3+、Ce3+、Dy3+,并首次探索了它们各自的UV-VUV发光性质。Li4SrCa(SiO4)2:Eu2+在UV激发下可以产生良好的蓝紫色发射,是一种有潜力的白光LED用蓝色发光材料；Li4SrCa(Si04)2:Tm3+在UV和VUV激发下都可以产生Tm3+的特征发射,表现为色纯度较好的蓝色发光,同时其VUV最强激发峰与Xe气体放电的激发波长匹配较好,具有作为PDP发光材料的潜力；Li4SrCa(Si04)2:Ce3+在UV和VUV激发下都可以呈现出Ce3+的5d-4f特征蓝色发射,但就色纯度而言,UV激发下的样品更适合被白光LED采用；Li4SrCa(Si04)2:Dy3+在UV和VUV下的发光都为Dy3+的特征f-f发射,其发光颜色偏黄,需要进一步改善。
第四,对稀土焦硅酸盐β-Y2Si2O7尝试单掺Ce3+、Tb3+以及共掺Ce3+和Tb3+,在研究了它们各自的UV-VUV发光性质的基础上,首次探索了两离子在VUV区域的能量传递过程,考察了共掺样品在PDP领域的潜在利用价值。
第五,对双钙钛矿结构的锆酸盐CaZrO3进行了Dy3+、Tm3+的单掺杂以及Dy3+、Tm3+的共掺杂,同时考察了共掺样品在UV区域内的Tm3+和Dy3+的能量传递过程,探索了其在白光LED领域的潜在应用。
Aiming at the demand for the novel phosphors utilized in illumination and display, by selecting several typical oxysalts as host materials, a phosphate, three silicates and a zirconate activated by Eu2+, Tm3+, Ce3+, Tb3+, Dy3+ ions et al. were synthesized, and their potential possibility as novel UV-LED and PDP phosphors were first explored and discussed in this paper. From the angle of basic theory and practical value, the results abovementioned would significantly contribute to the exploration of the photoluminescent properties for the new kinds of oxysalt phosphors and the promotion of the application in illumination and display fields.
First, merrillite structuredβ-NaCaPO4 host was doped by blue-emitting ion Tm3+. The UV-VUV photoluminescent properties ofβ-NaCaPO4:Tm3+ was first investigated by UV-Vis absorption spectra, excitation and emission spectra in UV and VUV region, and all the peaks in the curves were attributed. The results indicated thatβ-NaCaPO4:Tm3+ could generate blue light with good color purity by UV and VUV excitation, the thermal stability of which was evidently better than the commercial blue phosphor. The phosphor could be a new potential blue phosphor for PDP.
Second, single phase of Ba13Al22Si10O66 with the derivative of BaAl2O6 structure was successfully prepared by adjusting and controlling the ratio of Al/Si in raw materials, and the photoluminescent properties of the host activated by Eu2+, Ce3+ and Tb3+ in UV-VUV region was explored. White-emitting phosphor Ba13Al22Si10O66:Eu2+ with the characteristic luminescence of Eu2+ was first obtained without reducing atmosphere and was proved to have bluish white long afterglow. This phosphor could be adopted by white LED and was a new potential long afterglow phosphor. Furthermore, Ba13Al22Si10O66: Ce3+ and Ba13Al22Si10O66: Tb3+ could generated intense luminescence by UV excitation. However, the three phosphors Ba13Al22Si10O66: Eu2+, Ce3+, Tb3+ hardly emitted light in VUV region, which were not proper to serve as PDP phosphor.
Third, several representative rare-earth ions (Eu2+, Tm3+, Ce3+, Dy3+) were introduced in the silicates host Li4SrCa(SiO4)2, and their photoluminescent properties were first discussed in UV-VUV region. Li4SrCa(SiO4)2: Eu2+ could generate bluish purple emission by UV excitation, which was a potential blue-emitting phosphor utilized by white LED. Li4SrCa(Si04)2:Tm3+ emitted the characteristic emission of Tm3+ by UV and VUV irradiation, which was blue light with good color purity. The strongest VUV excitation peak of the sample matched well with the wavelength that the Xe gas discharged; hence it could be suitable serve as PDP phosphors. By UV and VUV excitation, Li4SrCa(SiO4)2:Ce3+ could produce 5d-4f characteristic emission of Ce3+ by both UV and VUV excitation, however, apropos to the color purity, the sample under UV excitation was proper to be adopted by white LED. The luminescence of Li4SrCa(SiO4)2: Dy3+ generated the characteristic f-f emission of Dy3+ by UV and VUV excitation, which was yellowish and needed to be improved.
Fourth, the UV-VUV photoluminescent properties of rare-earth focal silicateβ-Y2Si2O7 doped with Ce3+, Tb3+ or Ce3++Tb3+ were studied, and the energy transfer process of the two ions in VUV region were first explored. Hence the potential possibility for it to serve as PDP phosphor was valued.
Fifth, double-perovskite-structured CaZrO3 was doped with Dy3+, Tm3+ and Dy3++Tm3+. The energy transfer process of Dy3+ and Tm3+ in co-doped samples was investigated, and the co-doped samples were potentially utilized in white LED.
引文
[1]徐叙熔,苏勉曾。发光学与发光材料[M]。化学工业出版社：2004.
[2]Toda, K. Recent research and development of VUV phosphors for a mercury-free lamp[J]. Journal of Alloys and Compounds.2006,408:665-668.
[3]Park, H. B., Lee, S. E., Kim, G. Y., Lee, Y. D., Choi, K. C. Effect of dual coplanar electrodes on Mercury-free flat fluorescent lamps for liquid crystal display[J]. Display Technology, Journal of.2006,2:60-67.
[4]Cheng-Jun, D., Wei-Feng, L., Hao-Hong, C., Xin-Xin, Y., Jing-Tai, Z., Yi-Bing, F., Guo-Bin, Z., Ze-Ming, Q., Zhao-Shu, S. Luminescence Properties of Ca4GdO(BO3)3:RE (RE= Eu3+, Tb3+) under VUV Excitation[J]. Chinese Physics Letters.2005,22:711.
[5]Bergh, A. A., Dean, P. Light-emitting diodes[J]. Proceedings of the IEEE.2005,60:156-223.
[6]Wierer, J., Steigerwald, D., Krames, M., Oshea, J., Ludowise, M., Christenson, G., Shen, Y. C., Lowery, C., Martin, P., Subramanya, S. High-power AlGaInN flip-chip light-emitting diodes[J]. Applied Physics Letters.2001,78:3379.
[7]Koike, M., Shibata, N., Kato, H., Takahashi, Y. Development of high efficiency GaN-based multiquantum-well light-emitting diodes and their applications[J]. Selected Topics in Quantum Electronics, IEEE Journal of.2002,8:271-277.
[8]Elger, G., Hutter, M., Oppermann, H., Aschenbrenner, R., Reichl, H., J ger, E. Development of an assembly process and reliability investigations for flip-chip LEDs using the AuSn soldering[J]. Microsystem Technologies.2002,7:239-243.
[9]Kovac, J., Peternai, L., Lengyel, O. Advanced light emitting diodes structures for optoelectronic applications[J]. Thin Solid Films.2003,433:22-26.
[10]Meunier, J., Belenguer, P., Boeuf, J. Numerical model of an ac plasma display panel cell in neon-xenon mixtures[J]. Journal of Applied Physics.2009,78:731-745.
[11]Kawai, T.3D displays and applications[J]. Displays.2002,23:49-56.
[12]Grebenyuk, K., Petrov, V. Methods, formats, and technologies for the reproduction of stereoscopic video images[J]. Journal of Optical Technology.2007,74:330-337.
[13]琰,印.,杨宝东,朱月华,王海波.白光LED用荧光粉的发展现状[J].中国照明电器.2009.6-10.
[14]Rohwer, L., Srivastava, A. Development of Phosphors for LEDs[J]. Electrochemical Society Interface.2003,36-39.
[15]慈志鹏.几种LED用氧化物基荧光粉的制备和发光性能研究.兰州大学博士学位论文.
[16]Hu, Y., Zhuang, W., Ye, H., Wang, D., Zhang, S., Huang, X. A novel red phosphor for white light emitting diodes[J]. Journal of Alloys and Compounds.2005,390:226-229.
[17]Yang, Z. P., Wang, S. L., Yang, G. W. Luminescent Properties of Sr2SiO4:Sm3+ Red Phosphor [J]. Journal of The Chinese Ceramic Society.2007,35 (12):1587-1589.
[18]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L., Kim, G. C., Kim, T. W. White-light generation through ultraviolet-emitting diode and white-emitting phosphor[J]. Applied Physics Letters.2009,85:3696-3698.
[19]Lei, F., Yan, B. Hydrothermal synthesis and luminescence of CaMO4: RE3+(M= W, Mo; RE= Eu, Tb) submicro-phosphors[J]. Journal of Solid State Chemistry.2008,181:855-862.
[20]Tian, Y., Qi, X., Wu, X., Hua, R., Chen, B. Luminescent Properties of Y2(MoO4)3:Eu3+ Red Phosphors with Flowerlike Shape Prepared via Coprecipitation Method[J]. The Journal of Physical Chemistry C.2009,113:10767-10772.
[21]Lei, F., Yan, B., Chen, H. H. Solid-state synthesis, characterization and luminescent properties of Eu3+-doped gadolinium tungstate and molybdate phosphors:Gd(2-x)MO6: Eux3+ (M= W, Mo)[J]. Journal of Solid State Chemistry.2008,181:2845-2851.
[22]张国有,赵晓霞,孟庆裕.白光LED用红色荧光粉Gd2Mo3O9：Eu3+的制备及表征[J].发光学报.2007,28：57-61.
[23]Zhao, X., Wang, X., Chen, B., Meng, Q., Yan, B., Di, W. Luminescent properties of Eu3+ doped a-Gd2(MoO4)3 phosphor for white light emitting diodes[J]. Optical Materials.2007, 29:1680-1684.
[24]Wang, Z., Liang, H., Zhou, L., Wu, H., Gong, M., Su, Q. Luminescence of (Li0.333Nao.334Ko.333)Eu(MoO4)2 and its application in near UV InGaN-based light-emitting diode[J]. Chemical Physics Letters.2005,412:313-316.
[25]Wang, Z., Liang, H., Gong, M., Su, Q. A potential red-emitting phosphor for LED solid-state lighting[J]. Electrochemical and Solid-State Letters.2005,8:H33.
[26]Wang, Z., Liang, H., Wang, J., Gong, M., Su, Q. A novel red phosphor for near UV InGaN light-emitting diode and its luminescent properties[J]. Materials Research Bulletin.2008, 43:907-911.
[27]Wang, Z., Liang, H., Gong, M., Su, Q. Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure[J]. Journal of Alloys and Compounds.2007, 432:308-312.
[28]Neeraj, S., Kijima, N., Cheetham, A. Novel red phosphors for solid-state lighting: the system NaM(WO4)2-x (MoO4)x:Eu3+(M= Gd, Y, Bi)[J]. Chemical Physics Letters.2004,387:2-6.
[29]Chiu, C. H., Wang, M. F., Lee, C. S., Chen, T. M. Structural, spectroscopic and photoluminescence studies of LiEu (WO4)2-x(MoO4)x as a near-UV convertible phosphor[J]. Journal of Solid State Chemistry.2007,180:619-627.
[30]Lei, F., Yan, B. Morphology-Controlled Synthesis, Physical Characterization, and Photoluminescence of Novel Self-Assembled Pomponlike White Light Phosphor:Eu3+-Doped Sodium Gadolinium Tungstate[J]. The Journal of Physical Chemistry C.2008, 113:1074-1082.
[31]Wang, Y., Sun, Y., Zhang, J., Ci, Z., Zhang, Z., Wang, L. New red Y0.85Bi0.1Eu0.05V1-yMyO4 (M= Nb, P) phosphors for light-emitting diodes[J]. Physica B:Condensed Matter.2008, 403:2071-2075.
[32]Gundiah, G., Shimomura, Y., Kijima, N., Cheetham, A. K. Novel red phosphors based on vanadate garnets for solid state lighting applications[J]. Chemical Physics Letters.2008, 455:279-283.
[33]Sohn, K. S., Park, D. H., Cho, S. H., Kwak, J. S., Kim, J. S. Computational evolutionary optimization of red phosphor for use in tricolor white LEDs[J]. Chem. Mater.2006, 18:1768-1772.
[34]Shionoya, S., Yen, W. M., Hase, T. Phosphor handbook[M]CRC press Boca Raton, FL,1999.
[35]Singh, V., Gundu Rao, T., Zhu, J. J. Synthesis, photoluminescence, thermoluminescence and electron spin resonance investigations of CaAl12O19:Eu phosphor[J]. Journal of luminescence. 2007,126:1-6.
[36]Ozawa, T. C., Fukuda, K., Akatsuka, K., Ebina, Y., Sasaki, T., Kurashima, K., Kosuda, K. (K1.5Eu0.5)Ta3O10:A Far-Red Luminescent Nanosheet Phosphor with the Double Perovskite Structure[J]. The Journal of Physical Chemistry C.2008,112:17115-17120.
[37]CI, Z., WANG, Y. Preparation, Electronic Structure, and Photoluminescence Properties of Eu2+-Activated Carbonate Sr1-xBaxCO3 for White Light-Emitting Diodes[J]. Journal of the Electrochemical Society.2009,156.
[38]Liu, X., Li, C., Quan, Z., Cheng, Z., Lin, J. Tunable Luminescence properties of CaIn2O4: Eu3+ Phosphors[J]. J. Phys. Chem. C.2007,111:16601-16607.
[39]Setlur, A. A., Heward, W. J., Gao, Y., Srivastava, A. M., Chandran, R. G., Shankar, M. V. Crystal chemistry and luminescence of Ce3+-doped Lu2CaMg2(Si,Ge)3O12 and it use in LED based lighting[J]. Chem. Mater.2006,18:3314-3322.
[40]Zhang, M, Wang, J., Zhang, Q., Ding, W., Su, Q. Optical properties of Ba2SiO4:Eu2+ phosphor for green light-emitting diode (LED)[J]. Materials Research Bulletin.2007, 42:33-39.
[41]Liu, H., He, D., Shen, F. Luminescence Properties of Green-Emitting Phosphor (Ba1-x,Srx)2SiO4:Eu2+ for White LEDS[J]. Journal of Rare Earths.2006,24:121-124.
[42]Kang, H. S., Kang, Y. C., Jung, K. Y., Park, S. B. Eu-doped barium strontium silicate phosphor particles prepared from spray solution containing NH4C1 flux by spray pyrolysis[J]. Materials Science and Engineering B.2005,121:81-85.
[43]Kang, H. S., Hong, S. K., Kang, Y. C., Jung, K. Y., Shul, Y. G., Park, S. B. The enhancement of photoluminescence characteristics of Eu-doped barium strontium silicate phosphor particles by co-doping materials[J]. Journal of Alloys and Compounds.2005,402:246-250.
[44]Kim, J. S., Park, Y. H., Kim, S. M., Choi, J. C., Park, H. L. Temperature-dependent emission spectra of M2Si04:Eu2+(M= Ca, Sr, Ba) phosphors for green and greenish white LEDs[J]. Solid State Communications.2005,133:445-448.
[45]Jung, K. Y., Lee, H. W., Jung, H. K. Luminescent properties of (Sr, Zn)Al2O4:Eu2+, B3+ particles as a potential green phosphor for UV LEDs[J]. Chem. Mater.2006,18:2249-2255.
[46]杨志平,王少丽,杨广伟.绿色荧光粉NaCaPO4:B4+, Tb3+的制备与发光特性[[J].发光学报.2008,29：81-84.
[47]Yang, Z., Yang, G., Wang, S., Tian, J., Li, X., Guo, Q., Fu, G. A novel green-emitting phosphor NaCaPO4:Eu2+ for white LEDs[J]. Materials Letters.2008,62:1884-1886.
[48]P.Yang, Lin, J. H., G.Q.Yao. Luminescence and preparation of LED phosphor Ca8Mg(Si04)4Cl2:Eu2+[J]. J Rare Earth.2005,23(5):633-635.
[49]Ding, W., Wang, J., Zhang, M., Zhang, Q., Su, Q. Luminescence properties of new Ca10(Si207) 3Cl2:Eu2+ phosphor[J]. Chemical physics letters.2007,435:301-305.
[50]Yang, P., Yao, G. Q., Lin, J. H. Energy transfer and photoluminescence of BaMgAl10O17 co-doped with Eu2+ and Mn2+[J]. Optical Materials.2004,26:327-331.
[51]蒋大鹏,赵成久.用荧光粉转换方法制备纯绿色LED[J].发光学报.2002,23：311-313.
[52]张中太,张俊英无机光致发光材料及应用[M]北京：化学工业出版社,2005：166.
[53]Kang, Y., Sohn, J., Yoon, H., Jung, K., Park, H. Improved Photoluminescence of Sr5(PO4)3Cl: Eu2+Phosphor Particles Prepared by Flame Spray Pyrolysis[J]. J. Electrochem. Soc.2003, 150:H38-H42.
[54]N tzold, D., Wulff, H., Herzog, G. Structural and Optical Properties of the System (Ca,Sr,Eu)5(PO4)3CI[J]. physica status solidi (b).1995,191:21-30.
[55]Kottaisamy, M., Jagannathan, R., Jeyagopal, P., Rao, R., Narayanan, R. Eu2+ luminescence in M5(PO4)3X apatites, where M is Ca2+, Sr2+ and Ba2+, and X is F-, Cl-, Br- and OH-[J]. Journal of Physics D:Applied Physics.1994,27:2210.
[56]Park, J., Choi, K., Kim, C., Park, H., Kim, H. Luminescence characteristics of Sr3MgSi2O8: Eu blue phosphor for light-emitting diodes[J]. Electrochemical and Solid-State Letters.2004, 7:H42-H43.
[57]Lakshminarasimhan, N., Varadaraju, U. White-light generation in Sr2Si04, Sr2SiO4:Eu2+, Ce3+under near-UV excitation a novel phosphor for solid-state lighting[J]. Journal of the Electrochemical Society.2005,152:H152-H156.
[58]Saha, S., Chowdhury, P. S., Patra, A. Luminescence of Ce3+ in Y2SiO5 nanocrystals: Role of crystal structure and crystal size[J]. J. Phys. Chem. B.2005,109:2699-2702.
[59]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[60]杨云霞,陈仙玲,袁双龙.白光LED灯用蓝光荧光粉的发光性能和结构[J].硅酸盐学报.2006,34：671-674.
[61]Zeng, Q., Tanno, H., Egoshi, K., Tanamachi, N., Zhang, S. BaSiO4Cl2:Eu:An intense blue emission phosphor under vacuum ultraviolet and near-ultraviolet excitation[J]. Applied Physics Letters.2006,88:051906.
[62]杨志平,刘玉峰,李雪清.用于白光LED的高亮度蓝白色荧光Ca2SiO3Cl2：Eu2+的发光性质[J].发光学报.2006,27：629-632.
[63]杨志平,王少丽,杨广伟. Ca2B5O9Cl:Eu2+蓝色荧光粉的发光特性[J].硅酸盐学报.2008,36(2)：180-181.
[64]孙晓园,张家骅,张霞.新一代白光LED照明用一种适用于近紫外光激发的单一白光荧光粉[J]. Chinese Journal of Luminescence.2005,26:404-406.
[65]Kim, J., Jeon, P., Choi, J., Parka, H., Mho, S., Kim, G. Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor[J]. Applied Physics Letters.2004,84:15.
[66]Kim, J. S., Lim, K. T., Jeong, Y. S., Jeon, P. E., Choi, J. C., Park, H. L. Full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphors for white-light-emitting diodes[J]. Solid State Communications. 2005,135:21-24.
[67]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L. Color tunability and stability of silicate phosphor for UV-pumped white LEDs[J]. Journal of the Electrochemical Society. 2005,152:H29.
[68]Yang, W. J., Luo, L., Chen, T. M., Wang, N. S. Luminescence and energy transfer of Eu-and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED[J]. Chem. Mater. 2005,17:3883-3888.
[69]Liu, B., Kong, L., Shi, C. White-light long-lasting phosphor Sr2MgSi207:Dy3+[J]. Journal of Luminescence.2007,122:121-124.
[70]李盼来,杨志平,王志军.Sr2SiO4：Dy3+材料制备及发光特性[J].高等学校化学学报.2008,29：457-460.
[71]Jiao, H., Wang, Y. CaAlSiO4:Ce, Tb:A White-Light Phosphor Suitable for White-Light-Emitting Diodes[J]. Journal of the Electrochemical Society.2009,156:J117.
[72]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn2(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied Physics Letters.2006,88:1903.
[73]Shuanglong, Y., Xianlin, C., Chaofeng, Z., Yunxia, Y., Guorong, C. Eu2+, Mn2+ Co-doped (Sr, Ba)6BP5O20-A novel phosphor for white-LED[J]. Optical Materials.2007,30:192-194.
[74]杨志平,刘玉峰,王利伟.用于白光LED的单一基质白光荧光粉Ca2SiO3Cl2：Eu2+,Mn2+的发光性质[J].物理学报.2007,56：546-550.
[75]Gou, J., Wang, Y., Guo, H.; IOP Publishing:2009; Vol.152, p 012081.
[76]Dutta, D. P., Ghildiyal, R., Tyagi, A. K. Luminescent Properties of Doped Zinc Aluminate and Zinc Gallate White Light Emitting Nanophosphors Prepared via Sonochemical Method[J]. The Journal of Physical Chemistry C.2009,113:16954-16961.
[77]Jiang, Z., Wang, Y. Near-UV Excitable White SrAlGeO:Ce, Tb Phosphor for Light Emitting Diodes[J]. Electrochemical and Solid-State Letters.2010,13:J68.
[78]Tamura, T., Setomoto, T., Taguchi, T. Illumination characteristics of lighting array using 10 candela-class white LEDs under AC 100 V operation[J]. Journal of luminescence.2000, 87:1180-1182.
[79]张凯,刘河洲,胡文彬.白光LED用荧光粉的研究进展[J].材料导报.2005,19：50-53.
[80]刘行仁.白光LED固态照明光转换荧光体[J].发光学报.2007,28：291-301.
[81]王涛,井艳军,朱月华.白光LED用钨钼酸盐红色荧光粉的研究进展[J].中国照明电器.2010,24：54-57.
[82]Kitai, A. Luminescent materials and applications[M]Wiley,2008.
[83]Kim, C. H., Kwon, I. E., Park, C. H., Hwang, Y. J., Bae, H. S., Yu, B. Y., Pyun, C. H., Hong, G. Y. Phosphors for plasma display panels[J]. Journal of Alloys and Compounds.2000, 311:33-39.
[84]Jiang, X. C., Yan, C. H., Sun, L. D., Wei, Z. G., Liao, C. S. Hydrothermal homogeneous urea precipitation of hexagonal YBO3:Eu3+ nanocrystals with improved luminescent properties[J]. Journal of Solid State Chemistry.2003,175:245-251.
[85]Gupta, S. K., Agrawal, D. C., Mohapatra, Y. N. Photoluminescence and Morphological Studies of (YGd)BO3:Eu Phosphor Powders Prepared by the Urea Hydrolysis Route[J]. Journal of the Electrochemical Society.2004,151:H239.
[86]Lee, K. G., Yu, B. Y., Pyun, C. H., Mho, S. I. Vacuum ultraviolet excitation and photoluminescence characteristics of (Y,Gd)Al3(BO3)4:Eu3+[J]. Solid state communications. 2002,122:485-488.
[87]Chakradhar, R. P. S., Nagabhushana, B., Chandrappa, G., Ramesh, K., Rao, J. Solution combustion derived nanocrystalline ZnSiO4:Mn phosphors:A spectroscopic view[J]. The Journal of chemical physics.2004,121:10250.
[88]Taghavinia, N., Lerondel, G., Makino, H., Parisini, A., Yamamoto, A., Yao, T., Kawazoe, Y., Goto, T. Structural and Optical Properties of Oxidized Porous Silicon Layers Activated by ZnSiO4:Mn[J]. Journal of the Electrochemical Society.2002,149:G251.
[89]Hong, G. Y., Jeoung, B. W., Jeon, B. S., Yoo, J. S., Ha, C. H., Whang, K. W. Improvement of Discharge Characteristics of the ZnSiO4:Mn Phosphor Layer in Plasma Display Panels[J]. Journal of the Electrochemical Society.2004,151:H205.
[90]Sohn, K. S., Kim, S. S., Park, H. D. Luminescence quenching in thermally-treated barium magnesium aluminate phosphor[J]. Applied physics letters.2002,81:1759.
[91]Dawson, B., Ferguson, M., Marking, G., Diaz, A. Mechanisms of VUV Damage in BaMgAl10O17:Eu2+[J]. Chem. Mater.2004,16:5311-5317.
[92]Yokota, K., Zhang, S. X., Kimura, K., Sakamoto, A. Eu2+-activated barium magnesium aluminate phosphor for plasma displays-Phase relation and mechanism of thermal degradation[J]. Journal of luminescence.2001,92:223-227.
[93]Hamada, K., Yamamoto, T., Kurida, T., Takano, Y., Yuyama, I., Murakami, H. Analysis and improvement of crosstalk impairment on a field-sequential stereoscopic display system with DC-type PDP[J]. J. Inst. Television Engng Jpn.2001,55 (12):439.
[94]Okazaki, C., Shiiki, M., Suzuki, T., Suzuki, K. Luminance saturation properties of PDP phosphors[J]. Journal of luminescence.2000,87:1280-1282.
[95]Rao, R. Tb Activated Green Phosphors for Plasma Display Panel Applications[J]. Journal of the Electrochemical Society.2003,150:H165.
[96]Guo, X., Wang, Y., Zhang, J. Synthesis multifarious morphologies and sizes of YBO3:Eu3+ phosphors, and clarification of the crystal structure of YBO3[J]. Journal of Crystal Growth. 2009,311:2409-2417.
[97]Park, K., Nam, S. Enhanced photoluminescence of spray pyrolysis processed YBO3:Eu3+ for PDP application[J]. Materials Chemistry and Physics.2010,123:360-362.
[98]Wang, Y., Hao, Y., Yuwen, L. Synthesis process dependent photoluminescent properties of Zn2Si04:Mn2+upon VUV region[J]. Journal of alloys and compounds.2006,425:339-342.
[99]Kim, Y., Kang, S. Multi-functional colored coating of BaMgAl10O17:Eu phosphors with cobalt-doped Al2O3 thin films[J]. Applied physics. A, Materials science & processing.2010, 98:245-248.
[100]Wang, Y. F., Xu, X., Yin, L. J., Hao, L. Y. High Thermal Stability and Photoluminescence of Si"CN(?)\Codoped BaMgAl10O17:Eu2+ Phosphors[J]. Journal of the American Ceramic Society.2010,93:1534-1536.
[101]Liu, B., Wang, Y., Zhang, F., Wen, Y., Dong, Q., Wang, Z. Thermal stability and photoluminescence of S-doped BaMgAl10O17:Eu2+ phosphors for plasma display panels[J]. Optics Letters.2010,35:3072-3074.
[102]Liu, J., Wang, Y., Yu, X., Li, J. Enhanced photoluminescence properties of Zn2Si04: Mn2+ co-activated with Y3+/Li+ under VUV excitation[J]. Journal of luminescence.2010, 130:2171-2174.
[103]Balakrishnaiah, R., Yi, S. S., Jang, K., Lee, H. S., Moon, B. K., Jeong, J. H. Enhanced luminescence properties of YBO3:Eu3+ phosphors by Li-doping[J]. Materials Research Bulletin.2011,46:621-626.
[104]Kuo, T. W., Chung, H. P., Chen, T. M. Deep Red Emission of Ca19Ce(PO4)14:Mn2+ Phosphor for Fluorescent Lamp and PDP Applications[J]. Chemistry Letters.2010, 39:200-201.
[105]Yadav, R., Khan, A. F., Yadav, A., Chander, H., Haranath, D., Gupta, B. K., Shanker, V., Chawla, S. Intense red-emitting Y4Al2O9:Eu3+ phosphor with short decay time and high color purity for advanced plasma display panel[J]. Optics express.2009,17:22023.
[106]Zhou, L. Y., Gong, F. Z., Shi, J. X., Gong, M. L., Liang, H. B. A novel red phosphor Na2Ca4Mg2Si4O15:Eu3+ for plasma display panels[J]. Materials Research Bulletin.2008, 43:2295-2299.
[107]XIE, M., LIANG, H., SU, Q., HUANG, Y., GAO, Z., TAO, Y. Red Emission of Ca6Gd1.97Euo.o3Na2(P04)6F2 with Suitable Chromaticity Coordinates under VUV Excitation[J]. Electrochemical and Solid-State Letters.2010,13:J140-J142.
[108]Gao, X., Wang, Y., Wang, D., Liu, B. Luminescent properties of KGd1-x (WO4)2:Eux3+and KGd1-x (WO4) 2-y (MoO4)y:Eux3+ phosphors in UV-VUV regions[J]. Journal of luminescence. 2009,129:840-843.
[109]HE, L., WANG, Y., SUN, W. Luminescence properties of BaB8O13:Eu under UV and VUV excitation[J]. Journal of Rare Earths.2009,27:385-389.
[110]Wang, D., Wang, Y., Shi, Y. Photoluminescence properties of Eu3+ in Y(PO3) 3 under VUV excitation[J]. Journal of luminescence.2011,131:1154-1157.
[111]Liang, H., Lin, H., Zhang, G., Dorenbos, P., Su, Q. Luminescence of Ce3+ and Pr3+ doped Sr2Mg(BO3)2 under VUV-UV and X-ray excitation[J]. Journal of luminescence.2010, 131:194-198.
[112]Li, X. X., Wang, Y. H., Chen, Z. Photoluminescence properties of GdBa3B9O18:Ln3+(Ln= Eu, Tb) under UV and VUV excitation[J]. Journal of alloys and compounds.2008, 453:392-394.
[113]Zhang, J., Wang, Y., Zhang, Z., Peng, X., Jiang, Y., Li, H. Vacuum ultraviolet excited photoluminescence properties of novel Na3Y9O3(BO3)8:Eu3+ phosphor[J]. Materials Research Bulletin.2009,44:953-955.
[114]Wang, Z., Wang, Y., Zhang, J., Lu, Y. The photoluminescence properties of Eu3+, Bi3+ co-doped yttrium oxysulfide phosphor under vacuum ultraviolet excitation[J]. Materials Research Bulletin.2009,44:1183-1187.
[115]Wojtowicz, A. J. VUV spectroscopy of BaF2:Er[J]. Optical Materials.2009,31:474-478.
[116]Yuan, J. L., Wang, J., Zhang, Z. J., Zhao, J. T., Zhang, G. B. Synthesis and luminescent properties of AGd1-xLnxP2O7 (A= Rb, Cs; Ln= Ce, Eu, Tb) under VUV and X-ray excitations[J]. Optical Materials.2008,30:1327-1334.
[117]Zhang, F., Wang, Y., Wen, Y., Wang, D., Tao, Y. Photoluminescence properties of RE3+-activated Na3GdP2O8 (RE3+= Tb3+, Dy3+, Eu3+, Sm3+) under VUV excitation[J]. Optical Materials.2010,33:475-479.
[118]Atkins, R., Diaz, A. L. Investigation of host-to-activator energy transfer and surface losses in SrY2O4:Eu3+ under VUV excitation[J]. Journal of luminescence.2008,128:1463-1470.
[119]Zhang, Z., Wang, Y., Zhang, J., Hao, Y. Luminescent properties of Na3YSi309 doped with Eu3+ under UV-VUV excitation[J]. Materials Research Bulletin.2008,43:926-931.
[120]Han, B., Liang, H., Ni, H., Su, Q., Yang, G., Shi, J., Zhang, G. Intense red light emission of Eu3+-doped LiGd(PO3)4 for mercury-free lamps and plasma display panels application[J]. Optics express.2009,17:7138.
[121]Sivakumar, V., Hong, G. Y., Kim, J. S., Jeon, D. Novel blue-emitting phosphor Sr2.979Euo.o2iAl10-xBxSiO2o (x=0,0.25,0.5,0.75 and 1) for PDP applications[J]. Journal of luminescence.2009,129:1632-1636.
[122]Kim, S. B., Kum, B. G., Jang, H. M., Lakshmanan, A. Luminescence efficiencies of self-and Tm3+ activated CaWO4 under vacuum ultraviolet radiation excitation[J]. Journal of luminescence.2011,131:1625-1628.
[123]Im, W. B., Yoo, H. S., Vaidyanathan, S., Kwon, K. H., Park, H. J., Kim, Y. I., Jeon, D. Y. A novel blue-emitting silica-coated KBaPO4:Eu2+ phosphor under vacuum ultraviolet and ultraviolet excitation[J]. Materials Chemistry and Physics.2009,115:161-164.
[124]Li, Y. Z., Wang, Y. H., Zhang, Z. H., Liu, W. J. Precipitation Synthesis of Sr2MgSi07:Eu Phosphor and Its Luminescent Properties under Vacuum Ultraviolet Excitation[J]. Electrochemical and Solid-State Letters.2006,9:J37.
[125]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of luminescence.2005,113:271-278.
[126]Zhang, Z., Wang, Y., Zhang, J. A novel green-emitting VUV phosphor Na3YSi309:Tb3+[J]. Materials Letters.2008,62:846-848.
[127]Zhou, L., Choy, W. C. H., Shi, J., Gong, M., Liang, H. Synthesis and luminescent properties of GdSrAl3O7:Tb3+ phosphor under VUV/UV excitation[J]. Journal of alloys and compounds. 2008,463:302-305.
[128]Yang, H. M., Shi, J., Gong, M. L., Liang, H. The UV and VUV luminescence properties of the phosphor Mg2GeO4:Tb3+[J]. Materials Letters.2010,64:1034-1036.
[129]Yoo, H. S., Im, W. B., Kang, J. H., Jeon, D. Y. Preparation and photoluminescence properties of YAl3(BO3)4: Tb3+, Bi3+ phosphor under VUV/UV excitation[J]. Optical Materials.2008,31:131-135.
[130]LI, X., WANG, Y. VUV-excited luminescence properties of Tb3+ activated BaGdB9O16[J]. Journal of Rare Earths.2010,28:361-364.
[131]WANG, Z., WANG, Y., ZHANG, J. Vacuum ultraviolet excited photoluminescence properties of Gd2O2CO3:Eu3+ phosphor[J]. Journal of Rare Earths.2008,26:425-427.
[132]Zhou, L. Y., Wei, J. S., Shi, J. X., Gong, M. L., Liang, H. B. A novel green phosphor GdCaAlO4:Tb3+ for PDP application[J]. Journal of luminescence.2008,128:1262-1266.
[133]Zhang, H., Wang, Y., Xie, L. Luminescent properties of Tb3+ activated GdTaO4 with M and M' type structure under UV-VUV excitation[J]. Journal of luminescence.2010, 130:2089-2092.
[134]Zhong, J., Liang, H., Han, B., Su, Q., Tao, Y. NaGd(PO3)4:Tb3+-A new promising green phosphor for PDPs application[J]. Chemical physics letters.2008,453:192-196.
[135]Yang, H. M., Gong, M. L., Liang, H. Fine particle Sr2Si04:Tb phosphor for the plasma display panel prepared by a combined approach[J]. Materials Research Bulletin.2010, 45:805-808.
[136]Wang, D., Wang, Y. Optical properties of (Y, Tb)PO4 under VUV excitation[J]. Materials Chemistry and Physics.2009,115:699-702.
[137]Zhang, F., Wang, Y., Liu, B., Wen, Y., Tao, Y. Investigation of Na3GdP2O8:Tb3+ as a potential green-emitting phosphor for plasma display panels[J]. Materials Research Bulletin. 2011,46:722-725.
[138]Zhang, Z., Zhang, Y., Li, X., Xu, J., Huang, Y. VUV-UV luminescence of magnetoplumbite:(Sr0.96-xBa0.04)Al12-yMgyO19:Tbx[J]. Journal of luminescence.2008, 128:476-480.
[139]Zhang, F., Wang, Y., Liu, J. Vacuum ultraviolet spectroscopic properties of KSrPO4:Tb3+[J]. Journal of alloys and compounds.2011,509:3852-3854.
[140]Tian, Z., Liang, H., Chen, W., Su, Q., Zhang, G., Yang, G. Efficient emission-tunable VUV phosphors Na2GdF2PO4:Tb3+[J]. Optics express.2009,17:956.
[141]Xie, M., Liang, H., Han, B., Chen, W., Su, Q., Huang, Y., Gao, Z., Tao, Y. Ca6Gdi.5Tb0.5Na2(P04)6F2—an intense green-emitting phosphor under vacuum ultraviolet and low-voltage cathode ray excitation[J]. Optics Letters.2009,34:3466.
[142]刘行仁,王晓君.全色等离子体平板显示器用发光材料[J].发光快报.1995,9-13.
[143]Wang, Z., Xu, M., Zhang, W., Yin, M. Synthesis and luminescent properties of nano-scale LuAG:RE3+(Ce, Eu) phosphors prepared by co-precipitation method[J]. Journal of luminescence.2007,122:437-439.
[144]肖志国半导体照明发光材料及应用[M]化学工业出版社,2008.
[145]Blasse, G., Grabmaier, B. C. Luminescent materials[M]Springer-Verlag Berlin,1994.
[146]Cheetham, A. K., Day, P. Solid state chemistry:techniques[M]. Oxford University Press, USA,1990.
[147]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of luminescence. 2008,128:1348-1352.
[148]Zhang, H., Fu, X., Niu, S., Xin, Q. Synthesis and photoluminescence properties of Eu3+-doped AZrO3 (A= Ca, Sr, Ba) perovskite[J]. Journal of alloys and compounds.2008, 459:103-106.
[149]Liu, Z., Liu, Y., Zhang, J., Rong, J., Huang, L., Yuan, D. Long afterglow in Pr3+ and Li+ co-doped CaZrO3[J]. Optics communications.2005,251:388-392.
[150]Shimizu, Y., Sakagami, S., Goto, K., Nakachi, Y., Ueda, K. Tricolor luminescence in rare earth doped CaZrO3 perovskite oxides[J]. Materials Science and Engineering:B.2009, 161:100-103.
[151]Gon alves, M., Cavalcante, L., Sczancoski, J., Espinosa, J., Pizani, P., Longo, E., Rosa, I. (Sr, Tm) ZrO3 powders prepared by the polymeric precursor method:Synthesis, optical properties and morphological characteristics[J]. Optical Materials.2009,31:1134-1143.
[1]余泉茂等,无机发光材料研究及应用新进展
[2]Werner, P. E., Eriksson, L. and Westdahl, Mtreor. A semi-exhausting trial and errorpowder indexing program for all symmetries. Journal of Applied Crystal,1985,18(5):367.
[1]Zhang, H., Fu, X., Niu, S., Sun, G., Xin, Q. Photoluminescence of nanocrystalline YVO4: TmxDy1-x prepared by a modified Pechini method[J]. Materials Letters.2007,61:308-311.
[2]Macalik, L., Hanuza, J., Jaque, D., Garc Sol, J. Spectroscopic characterisation of the Tm3+ doped KLa (WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[3]True, M., Chen, Y, Kirm, M., Vielhauer, S., Zimmerer, G. VUV spectroscopy of pure and Tm3+-doped LiCaAlF6 crystals[J]. Journal of Luminescence.2007,124:279-285.
[4]Yan, B., Su, X.-Q. In situ co-precipitation synthesis and photoluminescence of YxGd1-xVO4:Tm3+ microcrystalline phosphors by hybrid precursors[J]. Optical Materials. 2007,29:1866-1870.
[5]Khaidukov, N. M., Kirikova, N. Y, Kirm, M., Krupa, J. C., Makhov, V. N., Negodin, E., Zimmerer, G.2002; Vol.4766, p 154.
[6]Chapman, A., Thirlwell, L. Spectra of phosphorus compounds:the infrared spectra of orthophosphates[J]. Spectrochimica Acta.1964,20:937-947.
[7]Zhang, Z., Yuan, J., Duan, C., Xiong, D., Chen, H., Zhao, J., Zhang, G, Shi, C. Vacuum ultraviolet spectroscopic properties of rare earth (RE= Ce, Tb, Eu, Tm, Sm)-doped hexagonal KCaGd (PO4)2 phosphate[J]. Journal of Applied Physics.2007,102:093514.
[8]Hu, X., Yan, S., Ma, L., Wan, G, Hu, J. Preparation of LaPO4:Ce,Tb phosphor with different morphologies and their fluorescence properties[J]. Powder Technology.2009,192:27-32.
[9]Huang, Y, Jiang, C., Cao, Y, Shi, L., Seo, H. J. Luminescence and microstructures of Eu3+-doped in triple phosphate Ca8MgR(PO4)7 (R=La, Gd, Y) with whitlockite structure[J]. Materials Research Bulletin.2009,44:793-798.
[10]Eberlein, K., Kattner, G. Automatic method for the determination of ortho-phosphate and total dissolved phosphorus in the marine environment[J]. Fresenius' Journal of Analytical Chemistry.1987,326:354-357.
[11]吴春芳.Eu3+,Tb3+离子掺杂的多种磷酸盐的合成及其发光性能的研究.兰州大学博士学位论文.
[12]Nakazawa, E., Shiga, F. Vacuum ultraviolet luminescence-excitation spectra of RPO4:Eu3+ (R=Y, La, Gd and Lu)[J]. Journal of Luminescence.1977,15:255-259.
[13]Di, W., Wang, X., Chen, B., Lai, H., Zhao, X. Preparation, characterization and VUV luminescence property of YPO4:Tb phosphor for a PDP[J]. Optical Materials.2005, 27:1386-1390.
[14]Wang, D., Wang, Y. Spectroscope properties of KCaY(PO4)2:Eu3+ in vacuum ultraviolet region[J]. Materials Science and Engineering:B.2006,133:218-221.
[15]Wu, C., Wang, Y, Jie, W. Hydrothermal synthesis and luminescent properties of LnPO4:Tb (Ln= La, Gd) phosphors under VUV excitation[J]. Journal of Alloys and Compounds.2007, 436:383-386.
[16]Wanmaker, W., Spier, H. Luminescence of Copper-Activated Orthophosphates of the Type ABPO (A= Ca, Sr, or Ba and B= Li, Na, or K)[J]. Journal of The Electrochemical Society. 1962,109:109.
[17]Wanmaker, W., Bril, A., ter Vrugt, J. Sensitization of Tb3+ luminescence by Sn2+ and Cu2+ in alkaline earth phosphates[J]. Appl. Phys. Lett.1966,8:260.
[18]Paques-Ledent, M.-T. Vibrational spectra and structure of LiB2+PO4 compounds with B=Sr, Ba, Pb[J]. Journal of Solid State Chemistry.1978,23:147-154.
[19]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[20]Wu, Z., Liu, J., Guo, Q., Gong, M. A Novel Blue-green-emitting Phosphor LiBaPO4:Eu2+ for White Light-emitting Diodes[J]. Chemistry Letters.2008,37:190-191.
[21]Liu, J., Wu, Z., Gong, M. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes[J]. Applied Physics B:Lasers and Optics.2008,93:583-587.
[22]Wu, Z., Liu, J., Gong, M., Su, Q. Optimization and Temperature-Dependent Luminescence of LiBaPO4:Eu Phosphor for Near-UV Light-Emitting Diodes[J]. Journal of The Electrochemical Society.2009,156:H153.
[23]More, S., Meshram, M., Wankhede, S., Muthal, P., Dhopte, S., Moharil, S. Luminescence in LiCaPO4[J]. Physica B:Condensed Matter.2011.
[24]Liang, C. S., Eckert, H., Gier, T. E., Stucky, G. D. Compositionally induced phase transitions and nonlinear optic response in ABCO4 crystal solution phases ALiPO4 (A= Sr, Ba, Pb)[J]. Chemistry of Materials.1993,5:597-603.
[25]Patil, R., Moharil, S. Cu+ Luminescence in New Hosts[J]. physica status solidi (a).2001, 187:557-562.
[26]Wu, Z., Shi, J., Gong, M., Wang, J., Su, Q. Nanosized LiSrPO4:Eu2+ phosphor with blue-emission synthesized by the sol-gel method[J]. Materials Chemistry and Physics.2007, 103:415-418.
[27]Patil, R., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Thermoluminescence in some copper-doped compounds[J]. physica status solidi (a).2003,199:527-532.
[28]Im, W. B., Yoo, H. S., Vaidyanathan, S., Kwon, K. H., Park, H. J., Kim, Y. I., Jeon, D. Y. A novel blue-emitting silica-coated KBaPO4:Eu2+ phosphor under vacuum ultraviolet and ultraviolet excitation[J]. Materials Chemistry and Physics.2009,115:161-164.
[29]Yang, Z., Yang, G., Wang, S., Tian, J., Li, X., Guo, Q., Fu, G. A novel green-emitting phosphor NaCaPO4:Eu2+ for white LEDs[J]. Materials Letters.2008,62:1884-1886.
[30]Amara, B., Vlasse, M., Le Flem, G., Hagenmuller, P. Structure of the low-temperature variety of calcium sodium orthophosphate, NaCaPO4[J]. Acta Crystallographica Section C:Crystal Structure Communications.1983,39:1483-1485.
[31]Qin, C., Huang, Y, Shi, L., Chen, G., Qiao, X., Seo, H. J. Thermal stability of luminescence of NaCaPO4:Eu2+ phosphor for white-light-emitting diodes[J]. Journal of Physics D: Applied Physics.2009,42:185105.
[32]Saito, S., Wada, K., Onaka, R. Vacuum ultraviolet reflection spectra of KDP and ADP[J]. Journal of the Physical Society of Japan.1974,37:711.
[33]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[34]Peng, M., Pei, Z., Hong, G., Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[35]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[36]潘金生,健.,田民波.材料科学基础[M].清华大学出版社.1998.
[37]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration. I. Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[38]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[39]Yamamoto, H., Mikami, M., Shimomura, Y., Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000, 87-89:1079-1082.
[40]Lu, Y, Dai, Y, Yang, Y, Wang, J., Dong, A., Sun, B. Anisotropy of thermal and spectral characteristics in Tm:YAP laser crystals[J]. Journal of Alloys and Compounds.2008, 453:482-486.
[41]Macalik, L., Hanuza, J., Jaque, D., Garcia Sole, J. Spectroscopic characterisation of the Tm3+ doped KLa(WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[42]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+ (Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B Phys Rev B.2009,80:085103.
[43]Dexter, D., Schulman, J. Theory of concentration quenching in inorganic phosphors[J]. The Journal of Chemical Physics.1954,22:1063.
[44]Liu, Y, Shi, C. Luminescent Centers of Eu2+ in BaMgAl10O17 Phosphor[J]. Materials Research Bulletin.2001,36:109-115.
[45]Blasse, G, Grabmaier, B.; Springer-Verlag, Berlin.
[46]Dexter, D. A theory of sensitized luminescence in solids[J]. The Journal of Chemical Physics. 1953,21:836.
[47]Blasse, G. Energy transfer in oxidic phosphors[J]. Physics Letters A.1968,28:444-445.
[48]Fukuzawa, T., Tanimizu, S. Flourescence decay characteristics of Tb3+-activated phosphates under H2-VUV laser excitation[J]. Journal of Luminescence.1978,16:447-456.
[49]Liang, H., Tao, Y, Xu, J., He, H., Wu, H., Chen, W., Wang, S., Su, Q. Photoluminescence of Ce3+, Pr3+ and Tb3+ activated Sr3Ln (PO4)3 under VUV-UV excitation[J]. Journal of Solid State Chemistry.2004,177:901-908.
[50]Wu, X., You, H., Cui, H., Zeng, X., Hong, G., Kim, C. H., Pyun, C. H., Yu, B. Y, Park, C. H. Vacuum ultraviolet optical properties of (La, Gd) PO4:RE3+(RE= Eu, Tb)[J]. Materials Research Bulletin.2002,37:1531-1538.
[51]Zeng, Q., Liang, H., Zhang, G., Birowosuto, M. D., Tian, Z., Lin, H., Fu, Y, Dorenbos, P., Su, Q. Luminescence of Ce3+ activated fluoro-apatites M5(PO4)3F (M= Ca, Sr, Ba) under VUV-UV and x-ray excitation[J]. Journal of Physics:Condensed Matter.2006,18:9549.
[52]Liang, H., Tao, Y., Su, Q. The luminescent properties of Ba3Gd1-xLnx(PO4)3 under synchrotron radiation VUV excitation[J]. Materials Science and Engineering B.2005, 119:152-158.
[53]Zhang, Z. J., Yuan, J. L., Wang, X. J., Xiong, D. B., Chen, H. H., Zhao, J. T., Fu, Y. B., Qi, Z. M., Zhang, G. B., Shi, C. S. Luminescence properties of CaZr (PO4)2:RE (RE= Eu3+, Tb3+, Tm3+) under x-ray and VUV-UV excitation[J]. Journal of Physics D:Applied Physics.2007, 40:1910.
[54]Zhang, Z. J., Chen, H. H., Yang, X. X., Zhao, J. T., Zhang, G. B., Shi, C. S. VUV spectroscopic properties of rare-earth (RE3+= Eu, Tb, Tm)-doped AZr2(PO4)3 (A+= Li, Na, K) type phosphate[J]. Journal of Physics D:Applied Physics.2008,41:105503.
[55]Struck, C., Fonger, W. Role of the charge-transfer states in feeding and thermally emptying the 5D states of Eu3+ in yttrium and lanthanum oxysulfides[J]. Journal of Luminescence.1970, 1:456-469.
[56]Fonger, W., Struck, C. Energy Loss and Energy Storage from the Eu Charge-Transfer States in Y and La Oxysulfides[J]. Journal of The Electrochemical Society.1971,118:273.
[57]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[58]苏锵.稀土化学[M].1993.
[59]Dorenbos, P. The 5d level positions of the trivalent lanthanides in inorganic compounds[J]. Journal of Luminescence.2000,91:155-176.
[60]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of Luminescence. 2005,113:271-278.
[1]Wachtel, A. Eu Activated Aluminosilicate Phosphors[J]. Journal of the Electrochemical Society. 1969,116:61.
[2]Qiu, J., Kawasaki, M., Tanaka, K., Shimizugawa, Y., Hirao, K. Phenomenon and mechanism of long-lasting phosphorescence in Eu2+-doped aluminosilicate glasses[J]. Journal of Physics and Chemistry of Solids.1998,59:1521-1525.
[3]Kuang, J., Liu, Y., Zhang, J., Huang, L., Rong, J., Yuan, D. Blue-emitting long-lasting phosphor, Sr3AlioSiO2o:Eu2+, Ho3+[J]. Solid State Communications.2005,136:6-10.
[4]Yang, W. J., Luo, L., Chen, T. M., Wang, N. S. Luminescence and energy transfer of Eu-and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED[J]. Chem. Mater. 2005,17:3883-3888.
[5]Ju, H., Su, X., Xu, S., Zhang, Y., Deng, D., Zhao, S., Wang, H., Wang, B., Sun, L. Luminescence properties of Eu2+-activated Ca12Al10.6Si3.4O32Cl5.4:A promising phosphor for solid state lighting[J]. Materials Letters.2009,63:1275-1277.
[6]Lin, Z., Zeng, H., Yang, Y., Liang, X., Chen, G., Sun, L. The Effect of Fluorine Anions on the Luminescent Properties of Eu-Doped Oxyfluoride Aluminosilicate Glasses[J]. Journal of the American Ceramic Society.2010,93:3095-3098.
[7]Clabau, F., Garcia, A., Bonville, P., Gonbeau, D., Le Mercier, T., Deniard, P., Jobic, S. Fluorescence and phosphorescence properties of the low temperature forms of the MAl2Si2O8: Eu2+(M= Ca, Sr, Ba) compounds[J]. Journal of Solid State Chemistry.2008,181:1456-1461.
[8]Li, Y., With, G, Hintzen, H. Luminescence Properties of Eu2+ -Doped MAl2-xSixO4-xNx (M= Ca, Sr, Ba) Conversion Phosphor for White LED Applications[J]. Journal of the Electrochemical Society.2006,153:278.
[9]Gebert, W. Z. Kristallogr.1972,135:437.
[10]Oehlschlegel, V. G, Kockel, A., Biedl, A. Glastech. Ber.1974,47:31-41.
[11]Denis, G, Deniard, P., Gautron, E., Clabau, F., Garcia, A., Jobic, S. Structure and White Luminescence of Eu-Activated (Ba, Sr)13-xAl22-2xSi10+2x066 Materials[J]. Inorganic chemistry. 2008,47:4226-4235.
[12]Clabau, F., Rocquefelte, X., Jobic, S., Deniard, P., Whangbo, M. H., Garcia, A., Le Mercier, T. Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+-doped SrAl2O4 with codopants Dy3+ and B3+[J]. Chem. Mater.2005,17:3904-3912.
[13]Shannon, R. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallographica Section A:Crystal Physics, Diffraction, Theoretical and General Crystallography.1976,32:751-767.
[14]Xie, R. J., Hirosaki, N., Sakuma, K., Yamamoto, Y., Mitomo, M. Eu-doped Ca-a-SiAlON:A yellow phosphor for white light-emitting diodes[J]. Applied Physics Letters.2004,84:5404.
[15]Hirosaki, N., Xie, R. J., Kimoto, K., Sekiguchi, T., Yamamoto, Y., Suehiro, T., Mitomo, M. Characterization and properties of green-emitting a-SiAlON:Eu powder phosphors for white light-emitting diodes[J]. Applied Physics Letters.2005,86:211905.
[16]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied Physics Letters.2006,88:101903.
[17]Piao, X., Horikawa, T., Hanzawa, H., Machida, K. Characterization and luminescence properties of SrSiN:Eu phosphor for white light-emitting-diode illumination[J]. Applied Physics Letters.2006,88:161908.
[18]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[19]Biswas, A., Friend, C, Prasad, P. Spontaneous reduction of Eu3+ ion in Al co-doped sol-gel silica matrix during densification[J]. Materials Letters.1999,39:227-231.
[20]Niida, H., Takahashi, M., Uchino, T., Yoko, T. Spontaneous reduction of europium ions below 250 C in organic Cinorganic hybrid low-melting phosphite glasses[J]. J. Mater. Res.2003, 18:2.
[21]Pei, Z., Zeng, Q., Su, Q. The application and a substitution defect model for Eu3+-→Eu2+ reduction in non-reducing atmospheres in borates containing BO4 anion groups[J]. Journal of Physics and Chemistry of Solids.2000,61:9-12.
[22]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[23]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[24]Pei, Z., Zeng, Q., Su, Q. A Study on the Mechanism of the Abnormal Reduction of Eu3+→ Eu2+ in Sr2B5O9Cl Prepared in Air at High Temperature[J]. Journal of Solid State Chemistry. 1999,145:212-215.
[25]Su, Q., Liang, H., Hu, T., Tao, Y., Liu, T. Preparation of divalent rare earth ions in air by aliovalent substitution and spectroscopic properties of Ln2+[J]. Journal of Alloys and Compounds.2002,344:132-136.
[26]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[27]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration. I. Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[28]Poort, S., Blokpoel, W., Blasse, G. Luminescence of Eu2+ in barium and strontium aluminate and gallate[J]. Chemistry of Materials.1995,7:1547-1551.
[29]H ppe, H., Lutz, H., Morys, P., Schnick, W., Seilmeier, A. Luminescence in Eu2+-doped Ba2Si5N8:fluorescence, thermoluminescence, and upconversion[J]. Journal of Physics and Chemistry of Solids.2000,61:2001-2006.
[30]Poort, S., Reijnhoudt, H., Van der Kuip, H., Blasse, G. Luminescence of Eu2+ in silicate host lattices with alkaline earth ions in a row[J]. Journal of Alloys and Compounds.1996, 241:75-81.
[31]Meijerink, A., Blasse, G. Luminescence properties of Eu2+-activated alkaline earth haloborates[J]. Journal of Luminescence.1989,43:283-289.
[32]H Is, J., Jungner, H., Lastusaari, M., Niittykoski, J. Persistent luminescence of Eu2+ doped alkaline earth aluminates, MAl2O4:Eu2+[J]. Journal of Alloys and Compounds.2001, 323:326-330.
[33]Lin, Y., Tang, Z., Zhang, Z. Preparation of long-afterglow Sr4Al14O25-based luminescent material and its optical properties[J]. Materials Letters.2001,51:14-18.
[34]Lin, Y., Tang, Z., Zhang, Z., Wang, X., Zhang, J. Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor[J]. Journal of Materials Science Letters.2001,20:1505-1506.
[35]Liu, B., Shi, C., Yin, M., Dong, L., Xiao, Z. The trap states in the Sr2MgSi207 and (Sr, Ca) MgSi2O7 long afterglow phosphor activated by Eu2+ and Dy3+[J]. Journal of Alloys and Compounds.2005,387:65-69.
[36]Lin, Y, Zhang, Z., Zhang, F., Tang, Z., Chen, Q. Preparation of the ultrafine SrAl2O4:Eu, Dy needle-like phosphor and its optical properties[J]. Materials Chemistry and Physics.2000, 65:103-106.
[37]Jia, D., Wang, X., Van der Kolk, E., Yen, W. Site dependent thermoluminescence of long persistent phosphorescence of BaAl2O4:Ce3+[J]. Optics Communications.2002,204:247-251.
[38]Li, Y, Wang, Y, Xu, X., Gong, Y Effects of non-stoichiometry on crystallinity, photoluminescence and afterglow properties of Sr2MgSi2O7:Eu2+, Dy3+ phosphors[J]. Journal of Luminescence.2009,129:1230-1234.
[39]Zhi-ping, Y, Wen-jie, W., Zhi, G., Sheng-chao, Z. Study on Two Kinds of Electron Trapped of Red Long-afterglow Phosphors CaTiO3: Pr3+[J]. Journal of Optoelectronics, laser.2004.
[40]Aitasalo, T., Deren, P., Holsa, J., Jungner, H., Krupa, J. C., Lastusaari, M., Legendziewicz, J., Niittykoski, J., Strek, W. Persistent luminescence phenomena in materials doped with rare earth ions[J]. Journal of Solid State Chemistry.171:114-122.
[41]Yamaga, M., Tanii, Y, Kodama, N., Takahashi, T., Honda, M. Mechanism of long-lasting phosphorescence process of Ce3+-doped Ca2Al2SiO7 melilite crystals[J]. Physical review B. Condensed matter and materials physics.2002,65:235108-235101.
[42]Yamaga, M., Masui, Y, Sakuta, S., Kodama, N., Kaminaga, K. Radiative and nonradiative decay processes responsible for long-lasting phosphorescence of Eu2+-doped barium silicates[J]. Physical Review B.2005,71:205102.
[43]Stevels, A. Ce Luminescence in Hexagonal Aluminates Containing Large Divalent or Trivalent Cations[J]. Journal of the Electrochemical Society.1978,125:588.
[44]Combes, C., Dorenbos, P., Van Eijk, C., Pedrini, C., Den Hartog, H., Gesland, J., Rodnyi, P. Optical and scintillation properties of Ce3+ doped LiYF4 and LiLuF4 crystals[J]. Journal of Luminescence.1997,71:65-70.
[45]Zhou, Y, Lin, J., Yu, M., Wang, S., Zhang, H. Synthesis-dependent luminescence properties of Y3A15O12:Re3+(Re= Ce, Sm, Tb) phosphors[J]. Materials Letters.2002,56:628-636.
[46]Zych, E., Brecher, C., Wojtowicz, A., Lingertat, H. Luminescence properties of Ce-activated YAG optical ceramic scintillator materials[J]. Journal of Luminescence.1997,75:193-203.
[47]Lammers, M., Blasse, G. Luminescence of Tb-and Ce-Activated Rare Earth Silicates[J]. Journal of the Electrochemical Society.1987,134:2068.
[48]Meyssamy, H., Riwotzki, K., Kornowski, A., Naused, S., Haase, M. Wet-chemical synthesis of doped colloidal nanomaterials:particles and fibers of LaPO4:Eu, LaPO4:Ce, and LaPO4: Ce,Tb[J]. Advanced Materials.1999,11:840-844.
[49]Xie, R. J., Mitomo, M., Uheda, K., Xu, F. F., Akimune, Y. Preparation and luminescence spectra of calcium-and rare-earth (R= Eu, Tb, and Pr)-codoped a-SiAlON ceramics[J]. Journal of the American Ceramic Society.2002,85:1229-1234.
[50]Reisfeld, R., Greenberg, E., Velapoldi, R., Barnett, B. Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them[J]. The Journal of Chemical Physics.1972,56:1698.
[51]Seo, S. Y., Shin, J. H. Enhancement of the green, visible Tb luminescence from Tb-doped silicon-rich silicon oxide by C co-doping[J]. Applied Physics Letters.2004,84:4379.
[52]Kang, Y. C., Lenggoro, I. W., Okuyama, K., Park, S. B. Luminescence characteristics of Y2 SiO5:Tb phosphor particles directly prepared by the spray pyrolysis method[J]. Journal of the Electrochemical Society.1999,146:1227-1230.
[53]Quici, S., Cavazzini, M., Marzanni, G., Accorsi, G., Armaroli, N., Ventura, B., Barigelletti, F. Visible and near-infrared intense luminescence from water-soluble lanthanide [Tb, Eu, Sm, Dy, Pr, Ho, Yb, Nd, Er] complexes[J]. Inorg. Chem.2005,44:529-537.
[1]Garlick, G., Gibson, A. The electron trap mechanism of luminescence in sulphide and silicate phosphors[J]. Proceedings of the Physical Society.1948,60:574.
[2]Morimo, R., Mochinaga, R., Nakamura, K. Preparation and characterization of a manganese activated zinc silicate phosphor by fume pyrolysis of an alkoxide solution [Zn2Si04:Mn][J]. Materials Research Bulletin.1994,29:751-757.
[3]Kang, H. S., Hong, S. K., Kang, Y. C., Jung, K. Y., Shul, Y. G., Park, S. B. The enhancement of photoluminescence characteristics of Eu-doped barium strontium silicate phosphor particles by co-doping materials[J]. Journal of Alloys and Compounds.2005,402:246-250.
[4]Akella, A., Keszler, D. A. Sr2LiSi04F:Synthesis, structure, and Eu2+ luminescence[J]. Chemistry of Materials.1995,7:1299-1302.
[5]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L. Color tunability and stability of silicate phosphor for UV-pumped white LEDs[J]. Journal of the Electrochemical Society. 2005,152:H29.
[6]Akella, A., Keszler, D. A. The new orthosilicate Li4SrCa(Si04)2:structure and Eu2+ luminescence[J]. Inorganic Chemistry.1995,34:1308-1310.
[7]Denton, A., Ashcroft, N. Vegard's law[J]. Physical Review A.1991,43:3161-3164.
[8]Yashima, M., Ishizawa, N., Yoshimura, M. Application of an Ion-Packing Model Based on Defect Clusters to Zirconia Solid Solutions:II, Applicability of Vegard's Law[J]. Journal of the American Ceramic Society.1992,75:1550-1557.
[9]Bis, R., Dixon, J. Applicability of Vegard's Law to the PbSnTe Alloy System[J]. Journal of Applied Physics.1969,40:1918.
[10]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[11]Diaz, A., Keszler, D. A. Red, green, and blue Eu2+ luminescence in solid-state borates:A structure-property relationship[J]. Materials Research Bulletin.1996,31:147-151.
[12]Karthikeyani, A., Jagannathan, R. Eu2+ luminescence in stillwellite-type SrBPO5-a new potential X-ray storage phosphor[J]. Journal of Luminescence.2000,86:79-85.
[13]Lucas, F., Jaulmes, S., Quarton, M., Le Mercier, T., Guillen, F., Fouassier, C. Crystal Structure of SrAl2B2O7 and Eu2+ Luminescence[J]. Journal of Solid State Chemistry.2000, 150:404-409.
[14]Tang, Y. S., Hu, S. F., Lin, C. C., Bagkar, N. C., Liu, R. S. Thermally stable luminescence of KSrPO4:Eu phosphor for white light UV light-emitting diodes[J]. Applied Physics Letters. 2007,90:151108.
[15]Iwaya, M., Terao, S., Sano, T., Ukai, T., Nakamura, R., Kamiyama, S., Amano, H., Akasaki, I. Suppression of phase separation of AlGaN during lateral growth and fabrication of high-efficiency UV-LED on optimized AlGaN[J]. Journal of Crystal Growth.2002, 237:951-955.
[16]Diaz, A., Keszler, D. A. Eu2+ Luminescence in the Borates X2Z(BO3)2 (X= Ba, Sr; Z= Mg, Ca)[J]. Chem. Mater.1997,9:2071-2077.
[17]Akella, A., Keszler, D. A. Structure and Eu2+ luminescence of dibarium magnesium orthoborate[J]. Materials Research Bulletin.1995,30:105-111.
[18]Dexter, D., Schulman, J. H. Theory of concentration quenching in inorganic phosphors[J]. The Journal of Chemical Physics.1954,22:1063.
[19]Kim, Y. H., Shin, D. C., Kim, S. H., Ko, C. H., Yu, H. S., Chae, Y. S., Kwon, S. K. Novel blue emitting material with high color purity[J]. Advanced Materials.2001,13:1690-1693.
[20]Komeno, A., Uematsu, K., Toda, K., Sato, M. VUV properties of Eu-doped alkaline earth magnesium silicate[J]. Journal of Alloys and Compounds.2006,408:871-874.
[21]Zhang, Z., Wang, Y., Zhang, J., Hao, Y. Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation[J]. Materials Research Bulletin.2008,43:926-931.
[22]Zhang, Z., Wang, Y. UV-VUV Excitation Luminescence Properties of Eu-doped BaMSiO4 (M= Mg, Zn)[J]. Journal of the Electrochemical Society.2007,154:J62.
[23]Zhang, G., Qi, Z., Zhou, H., Fu, Y, Huo, T., Luo, X., Shi, C. Photoluminescence of (Eu2+ Dy3+) co-doped silicate long lasting phosphors[J]. Journal of Electron Spectroscopy and Related Phenomena.2005,144:861-863.
[24]Yamamoto, H., Mikami, M., Shimomura, Y, Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000,87:1079-1082.
[25]Vila, L. D., Gomes, L., Eyzaguirre, C., Rodriguez, E., Cesar, C., Barbosa, L. Time resolved luminescence in (Tm:Ho) doped tellurite glass[J]. Optical Materials.2005,27:1333-1339.
[26]Scholl, M. S., Trimmier, J. R. Luminescence of YAG:Tm, Tb[J]. Journal of the Electrochemical Society.1986,133:643.
[27]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[28]Tsang, W., Yu, W., Mak, C., Tsui, W., Wong, K., Hui, H. Evidence of the influence of phonon density on Tm upconversion luminescence in tellurite and germanate glasses[J]. Journal of Applied Physics.2002,91:1871.
[29]Macalik, L., Hanuza, J., Jaque, D., Garca Sol, J. Spectroscopic characterisation of the Tm3+ doped KLa (WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[30]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+(Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B 2009,80:085103.
[31]Dorenbos, P., Bos, A., Poolton, N. Carrier recombination processes and divalent lanthanide spectroscopy in YPO4:Ce3+; Ln3+(Ln= Sm, Dy, Tm)[J]. Physical Review B.2010,82:195127.
[32]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[33]苏锵.稀土化学[M].1993.
[34]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of Luminescence.2005,113:271-278.
[35]Bachmann, V., Ronda, C., Meijerink, A. Temperature quenching of yellow Ce3+ luminescence in YAG:Ce[J]. Chemistry of Materials.2009,21:2077-2084.
[36]Zych, E., Brecher, C., Glodo, J. Kinetics of cerium emission in a YAG:Ce single crystal:the role of traps[J]. Journal of Physics:Condensed Matter.2000,12:1947.
[37]Chang, C. K., Chen, T. M. Sr3B2O6:Ce3+, Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes[J]. Appl. Phys. Lett.2007,91:081902.
[38]Van Krevel, J., Hintzen, H., Metselaar, R., Meijerink, A. Long wavelength Ce3+ emission in Y-Si-ON materials[J]. Journal of Alloys and Compounds.1998,268:272-277.
[39]Yang, C., Pan, Y, Zhang, Q. Enhanced white light emission from Dy3+/Ce3+ codoped GdAl3 (BO3)4 phosphors by combustion synthesis[J]. Materials Science and Engineering:B.2007, 137:195-199.
[40]Gedam, S., Dhoble, S., Moharil, S. Eu2+ and Ce3+ emission in sulphate based phosphors[J]. Journal of Luminescence.2008,128:1-6.
[41]Liang, H., Shi, J., Su, Q., Zhang, S., Tao, Y. Spectroscopic properties of Ce3+ doped MBPO5 (M= Ca, Sr, Ba) under VUV excitation[J]. Materials Chemistry and Physics.2005, 92:180-184.
[42]Pidol, L., Kahn-Harari, A., Viana, B., Ferrand, B., Dorenbos, P., Haas, J. T. M., Eijk, C. W. E., Virey, E. Scintillation properties of Lu2Si2O7:Ce3+, a fast and efficient scintillator crystal[J]. Journal of Physics:Condensed Matter.2003,15:2091.
[43]李小侠.Eu3+，Tb3+离子在三种硼酸盐中的VUV-Vis范围的发光性质研究[兰州大学]2007.
[44]Lai, H., Bao, A., Yang, Y, Xu, W., Tao, Y, Yang, H. Preparation and luminescence property of Dy3+-doped YPO4 phosphors[J]. Journal of Luminescence.2008,128:521-524.
[45]Bhaskar Kumar, G., Buddhudu, S. Emission spectra of LiYNbO3:RE3+(=Sm3+or Dy3+) ceramic powders[J]. Physica B:Condensed Matter.2008,403:4164-4170.
[46]Xiu, Z., Yang, Z., Li, M., Liu, S., Zhang, H., Zhou, G. Synthesis, structural and luminescence properties of Dy3+-doped YPO4 nanocrystals[J]. Optical Materials.2006,29:431-434.
[47]Atone, M., Dhoble, S., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Sensitization of luminescence of CaSO4:Dy[J]. physica status solidi (a).1993,135:299-305.
[48]Shi, F., Meng, J., Ren, Y, Su, Q. Structure, luminescence and magnetic properties of AgLnW2O8 (Ln= Eu, Gd, Tb and Dy) compounds[J]. Journal of Physics and Chemistry of Solids.1998,59:105-110.
[49]Kuang, J., Liu, Y, Zhang, J. White-light-emitting long-lasting phosphorescence in Dy3+-doped SrSiO3[J]. Journal of Solid State Chemistry.2006,179:266-269.
[50]Ortega, F., Molina, P., Santiago, M., Spano, F., Lester, M., Caselli, E. Analysis of the glow curve of SrB4O7:Dy compounds employing the GOT model[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms.2006, 243:417-422.
[1]Lu, S., Zhang, J. The Luminescence of Nanoscale Y2Si2O7:Eu3+ Materials[J]. Journal of Nanoscience and Nanotechnology.2010,10:2152-2155.
[2]Marciniak, L., Hreniak, D., Dobrowolska, A., Zych, E. Size-dependent luminescence in Y2Si2O7 nanoparticles doped with Ce3+ ions[J]. Applied Physics A:Materials Science & Processing.2010,1:108.
[3]Li, Y., You, B., Zhao, W., Zhang, W., Yin, M. Synthesis and Luminescent Properties of Nano-scale Y2Si2O7:Re3+(Re= Eu, Tb) Phosphors via Sol-Gel Method[J]. Chinese Journal of Chemical Physics.2008,21:376.
[4]Saeki, S., Kaneko, J. H., Higuchi, M., Kawamura, S., Haruna, J., Fujita, F., Homma, A., Nishiyama, S., Ueda, S., Kurashige, K.; IEEE:2008; Vol.2, p 1426-1428.
[5]Li, Y, Wang, C. N., Wei, X. T., Zhao, J. B., Zhang, W. P., Yin, M. Synthesis and Luminescent Properties of Nanoscale Gd2Si2O7:Eu3+ Phosphors[J]. Journal of Nanoscience and Nanotechnology.2010,10:2219-2222.
[6]Yu, M., Lin, J., Fang, J. Silica Spheres Coated with YVO4:Eu3+ Layers via Sol-Gel Process:A Simple Method To Obtain Spherical Core-Shell Phosphors[J]. Chem. Mater.2005, 17:1783-1791.
[7]Meng, Q., Lin, J., Fu, L., Zhang, H., Wang, S., Zhou, Y. Sol-gel deposition of calcium silicate red-emitting luminescent films doped with Eu3+[J]. Journal of Materials Chemistry.2001, 11:3382-3386.
[8]Zhou, Y, Lin, J., Yu, M., Wang, S., Zhang, H. Synthesis-dependent luminescence properties of Y3Al5O12:Re3+(Re= Ce, Sm, Tb) phosphors[J]. Materials Letters.2002,56:628-636.
[9]Oshio, S., Matsuoka, T., Tanaka, S., Kobayashi, H. Mechanism of particle growth of a BaMgAl10O17:Eu2+ phosphor by firing with AlF3[J]. Journal of The Electrochemical Society. 1998,145.
[10]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[11]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14025:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[12]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[13]Combes, C., Dorenbos, P., Van Eijk, C., Pedrini, C., Den Hartog, H., Gesland, J., Rodnyi, P. Optical and scintillation properties of Ce3+ doped LiYF4 and LiLuF4 crystals[J]. Journal of Luminescence.1997,71:65-70.
[14]Zych, E., Brecher, C., Wojtowicz, A., Lingertat, H. Luminescence properties of Ce-activated YAG optical ceramic scintillator materials[J]. Journal of Luminescence.1997,75:193-203.
[15]Visser, R., Dorenbos, P., Eijk, C., Meijerink, A., Blasse, G., Hartog, H. Energy transfer processes involving different luminescence centres in BaF2:Ce[J]. Journal of Physics: Condensed Matter.1993,5:1659.
[16]Meyssamy, H., Riwotzki, K., Kornowski, A., Naused, S., Haase, M. Wet-chemical synthesis of doped colloidal nanomaterials:particles and fibers of LaPO4:Eu, LaPO4:Ce, and LaPO4: Ce,Tb[J]. Advanced Materials.1999,11:840-844.
[17]Plewa, J., Juestel, T.; Trans Tech Publ:2010; Vol.636, p 344-347.
[18]Shionoya, S., Yen, W. M. Phosphor handbook[M]CRC press New York,1999.
[19]Yamashita, T., Ohishi, Y. Cooperative energy transfer between Tb3+ and Yb3+ ions co-doped in borosilicate glass[J]. Journal of Non-Crystalline Solids.2008,354:1883-1890.
[20]Liao, J., Qiu, B., Wen, H., You, W. Photoluminescence green in microspheres of CaWO4: Tb3+processed in conventional hydrothermal[J]. Optical Materials.2009,31:1513-1516.
[21]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[22]苏锵.稀土化学[M].1993.
[23]Wang, D., Kodama, N. Visible quantum cutting through downconversion in GdPO4:Tb3+ and Sr3Gd (PO4)3:Tb3+[J]. Journal of Solid State Chemistry.2009,182:2219-2224.
[24]Robbins, D., Cockayne, B., Lent, B., Glasper, J. The mechanism of 5D3-5D4 cross-relaxation in Y3A15O12:Tb3+[J]. Solid State Communications.1976,20:673-676.
[25]Ostermayer Jr, F., Van Uitert, L. Cooperative Energy Transfer from Yb3+ to Tb3+ in YF3[J]. Physical Review B.1970,1:4208-4212.
[26]Zhang, J., Ning, J., Liu, X., Pan, Y, Huang, L. A novel synthesis of phase-pure ultrafine YAG: Tb phosphor with different Tb concentration[J]. Materials Letters.2003,57:3077-3081.
[27]Blasse, G. Energy Transfer Phenomena in the System (Y, Ce, Gd, Tb)F3[J]. physica status solidi(a).1982,73:205-208.
[28]Su, Y, Li, G. Generation of tunable wavelength lights in core-shell CaWO4 microspheres via co-doping with Na+ and Ln3+(Ln= Tb, Sm, Dy, Eu)[J]. Journal of Materials Chemistry.2009, 19:2316-2322.
[1]Atone, M., Dhoble, S., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Sensitization of luminescence of CaSO4:Dy[J]. physica status solidi (a).1993,135:299-305.
[2]Liu, B., Shi, C., Qi, Z. Potential white-light long-lasting phosphor:Dy-doped aluminate[J]. Applied physics letters.2005,86:191111.
[3]Liu, Y., Lei, B., Shi, C. Luminescent Properties of a White Afterglow Phosphor CdSiO3: Dy3+[J]. Chem. Mater.2005,17:2108-2113.
[4]Kuang, J., Liu, Y. White-emitting Long-lasting Phosphor Sr2SiO4: Dy3+[J]. Chemistry Letters. 2005,34:598-599.
[5]Jayasimhadri, M., Ratnam, B., Jang, K., Lee, H. S., Chen, B., Yi, S. S., Jeong, J. H., Moorthy, L. R. Greenish-Yellow Emission from Dy3+ Doped Y2O3 Nanophosphors[J]. Journal of the American Ceramic Society.2010,93:494-499.
[6]Maruyama, N., Honma, T., Komatsu, T. Enhanced quantum yield of yellow photoluminescence of Dy3+ ions in nonlinear optical Ba2TiSi208 nanocrystals formed in glass[J]. Journal of Solid State Chemistry.2009,182:246-252.
[7]Lakshminarayana, G, Yang, H., Qiu, J. White light emission from Tm3+/Dy3+ co-doped oxyfluoride germanate glasses under UV light excitation[J]. Journal of Solid State Chemistry. 2009,182:669-676.
[8]Zhang, H., Fu, X., Niu, S., Sun, G., Xin, Q. Photoluminescence of nanocrystalline YVO4:TmxDy1-x prepared by a modified Pechini method[J]. Materials Letters.2007, 61:308-311.
[9]Liu, S., Zhao, G., Lin, X., Ying, H., Liu, J., Wang, J., Han, G. White luminescence of Tm-Dy ions co-doped aluminoborosilicate glasses under UV light excitation[J]. Journal of Solid State Chemistry.2008,181:2725-2730.
[10]Iwahara, H., Asakura, Y, Katahira, K., Tanaka, M. Prospect of hydrogen technology using proton-conducting ceramics[J]. Solid State Ionics.2004,168:299-310.
[11]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[12]Zhang, H., Fu, X., Niu, S., Xin, Q. Synthesis and photoluminescence properties of Eu3+-doped AZrO3 (A=Ca, Sr, Ba) perovskite[J]. Journal of Alloys and Compounds.2008, 459:103-106.
[13]Liu, Z., Liu, Y, Zhang, J., Rong, J., Huang, L., Yuan, D. Long afterglow in Pr3+ and Li+ co-doped CaZrO3[J]. Optics Communications.2005,251:388-392.
[14]Shimizu, Y, Sakagami, S., Goto, K., Nakachi, Y., Ueda, K. Tricolor luminescence in rare earth doped CaZrO3 perovskite oxides[J]. Materials Science and Engineering:B.2009, 161:100-103.
[15]Gon alves, M., Cavalcante, L., Sczancoski, J., Espinosa, J., Pizani, P., Longo, E., Rosa, I. (Sr, Tm) ZrO3 powders prepared by the polymeric precursor method:Synthesis, optical properties and morphological characteristics[J]. Optical Materials.2009,31:1134-1143.
[16]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[17]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[18]Koopmans, H., Van De Velde, G, Gellings, P. Powder neutron diffraction study of the perovskites CaTiO3 and CaZrO3[J]. Acta Crystallographica Section C:Crystal Structure Communications.1983,39:1323-1325.
[19]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[20]Denton, A., Ashcroft, N. Vegard's law[J]. Physical Review A.1991,43:3161-3164.
[21]Kuo, Y. K., Liou, B. T., Yen, S. H., Chu, H. Y. Vegard's law deviation in lattice constant and band gap bowing parameter of zincblende InxGa1-xN[J]. Optics Communications.2004, 237:363-369.
[22]Bis, R., Dixon, J. Applicability of Vegard's Law to the PbSnTe Alloy System[J]. Journal of Applied Physics.1969,40:1918.
[23]Peng, T., Huajun, L., Yang, H., Yan, C. Synthesis of SrAl2O4:Eu, Dy phosphor nanometer powders by sol-gel processes and its optical properties[J]. Materials Chemistry and Physics. 2004,85:68-72.
[24]Srivastava, J., Supe, S. Gamma radiation induced changes in the glow curve of CaSO4:Dy tld phosphor[J]. Radiation Effects and Defects in Solids.1979,45:13-18.
[25]Chandra, B., Bhatt, R. Effect of dysprosium concentration on the TL characteristics of CaSO4: Dy phosphor[J]. Nuclear Instruments and Methods.1979,164:571-577.
[26]Li, J., Hao, J., Zhang, C., Tang, Q., Zhang, Y, Su, Q., Wang, S. Thermoluminescence characteristics of BaB4O7:Dy phosphor[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms.2004,222:577-582.
[27]Nakashima, K., Takami, M., Ohta, M., Yasue, T., Yamauchi, J. Thermoluminescence mechanism of dysprosium-doped β-tricalcium phosphate phosphor[J]. Journal of Luminescence.2005,111:113-120.
[28]Huang, J., Zhou, L., Lan, Y, Gong, F., Li, Q., Sun, J. Synthesis and luminescence properties of the red phosphor CaZrO3:Eu3+ for white light-emitting diode application[J]. Central European Journal of Physics.2010,1-5.
[29]Nazarov, M., Jeon, D., Kang, J., Popovici, E. J., Muresan, L. E., Zamoryanskaya, M., Tsukerblat, B. Luminescence properties of europium-terbium double activated calcium tungstate phosphor[J]. Solid state communications.2004,131:307-311.
[30]Blasse, G., Grabmaier, B. C. Luminescent materials[M]Springer-Verlag Berlin,1994.
[31]Dexter, D. A theory of sensitized luminescence in solids[J]. The Journal of Chemical Physics. 1953,21:836.
[32]Blasse, G. Energy transfer in oxidic phosphors[J]. Physics Letters A.1968,28:444-445.
[33]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M] Springer-Verlag Berlin, 1977.
[34]苏锵.稀土化学[M].1993.
[35]Lu, Y, Dai, Y, Yang, Y, Wang, J., Dong, A., Sun, B. Anisotropy of thermal and spectral characteristics in Tm:YAP laser crystals[J]. Journal of Alloys and Compounds.2008, 453:482-486.
[36]True, M., Chen, Y., Kirm, M., Vielhauer, S., Zimmerer, G. VUV spectroscopy of pure and Tm3+-doped LiCaAlF6 crystals[J]. Journal of Luminescence.2007,124:279-285.
[37]Yan, B., Su, X. Q. In situ co-precipitation synthesis and photoluminescence of YxGd1-xVO4: Tm3+ microcrystalline phosphors by hybrid precursors[J]. Optical Materials.2007, 29:1866-1870.
[38]Macalik, L., Hanuza, J., Jaque, D., Garcia Sole, J. Spectroscopic characterisation of the Tm3+ doped KLa(WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[39]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+(Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B Phys Rev B.2009,80:085103.
[40]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn (PO4):Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied physics letters.2006,88:101903.
[41]Tan, Y, Shi, C. Ce3+→-Eu2+ energy transfer in BaLiF3 phosphor[J]. Journal of Physics and Chemistry of solids.1999,60:1805-1810.
[42]Yamamoto, H., Mikami, M., Shimomura, Y., Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000,87:1079-1082.
[43]Wegh, R. T., Donker, H., Oskam, K. D., Meijerink, A. Visible quantum cutting in LiGdF4: Eu3+ through downconversion[J]. Science.1999,283:663.
[44]Strk, W. Cooperative energy transfer[J]. Physics Letters A.1977,62:315-316.
[45]Martin, I., Yanes, A., Mendez-Ramos, J., Torres, M., Rodriguez, V. Cooperative energy transfer in Yb-Tb codoped silica sol-gel glasses[J]. Journal of Applied Physics.2001,89:2520.
[2]Toda, K. Recent research and development of VUV phosphors for a mercury-free lamp[J]. Journal of Alloys and Compounds.2006,408:665-668.
[3]Park, H. B., Lee, S. E., Kim, G. Y., Lee, Y. D., Choi, K. C. Effect of dual coplanar electrodes on Mercury-free flat fluorescent lamps for liquid crystal display[J]. Display Technology, Journal of.2006,2:60-67.
[4]Cheng-Jun, D., Wei-Feng, L., Hao-Hong, C., Xin-Xin, Y., Jing-Tai, Z., Yi-Bing, F., Guo-Bin, Z., Ze-Ming, Q., Zhao-Shu, S. Luminescence Properties of Ca4GdO(BO3)3:RE (RE= Eu3+, Tb3+) under VUV Excitation[J]. Chinese Physics Letters.2005,22:711.
[5]Bergh, A. A., Dean, P. Light-emitting diodes[J]. Proceedings of the IEEE.2005,60:156-223.
[6]Wierer, J., Steigerwald, D., Krames, M., Oshea, J., Ludowise, M., Christenson, G., Shen, Y. C., Lowery, C., Martin, P., Subramanya, S. High-power AlGaInN flip-chip light-emitting diodes[J]. Applied Physics Letters.2001,78:3379.
[7]Koike, M., Shibata, N., Kato, H., Takahashi, Y. Development of high efficiency GaN-based multiquantum-well light-emitting diodes and their applications[J]. Selected Topics in Quantum Electronics, IEEE Journal of.2002,8:271-277.
[8]Elger, G., Hutter, M., Oppermann, H., Aschenbrenner, R., Reichl, H., J ger, E. Development of an assembly process and reliability investigations for flip-chip LEDs using the AuSn soldering[J]. Microsystem Technologies.2002,7:239-243.
[9]Kovac, J., Peternai, L., Lengyel, O. Advanced light emitting diodes structures for optoelectronic applications[J]. Thin Solid Films.2003,433:22-26.
[10]Meunier, J., Belenguer, P., Boeuf, J. Numerical model of an ac plasma display panel cell in neon-xenon mixtures[J]. Journal of Applied Physics.2009,78:731-745.
[11]Kawai, T.3D displays and applications[J]. Displays.2002,23:49-56.
[12]Grebenyuk, K., Petrov, V. Methods, formats, and technologies for the reproduction of stereoscopic video images[J]. Journal of Optical Technology.2007,74:330-337.
[13]琰,印.,杨宝东,朱月华,王海波.白光LED用荧光粉的发展现状[J].中国照明电器.2009.6-10.
[14]Rohwer, L., Srivastava, A. Development of Phosphors for LEDs[J]. Electrochemical Society Interface.2003,36-39.
[15]慈志鹏.几种LED用氧化物基荧光粉的制备和发光性能研究.兰州大学博士学位论文.
[16]Hu, Y., Zhuang, W., Ye, H., Wang, D., Zhang, S., Huang, X. A novel red phosphor for white light emitting diodes[J]. Journal of Alloys and Compounds.2005,390:226-229.
[17]Yang, Z. P., Wang, S. L., Yang, G. W. Luminescent Properties of Sr2SiO4:Sm3+ Red Phosphor [J]. Journal of The Chinese Ceramic Society.2007,35 (12):1587-1589.
[18]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L., Kim, G. C., Kim, T. W. White-light generation through ultraviolet-emitting diode and white-emitting phosphor[J]. Applied Physics Letters.2009,85:3696-3698.
[19]Lei, F., Yan, B. Hydrothermal synthesis and luminescence of CaMO4: RE3+(M= W, Mo; RE= Eu, Tb) submicro-phosphors[J]. Journal of Solid State Chemistry.2008,181:855-862.
[20]Tian, Y., Qi, X., Wu, X., Hua, R., Chen, B. Luminescent Properties of Y2(MoO4)3:Eu3+ Red Phosphors with Flowerlike Shape Prepared via Coprecipitation Method[J]. The Journal of Physical Chemistry C.2009,113:10767-10772.
[21]Lei, F., Yan, B., Chen, H. H. Solid-state synthesis, characterization and luminescent properties of Eu3+-doped gadolinium tungstate and molybdate phosphors:Gd(2-x)MO6: Eux3+ (M= W, Mo)[J]. Journal of Solid State Chemistry.2008,181:2845-2851.
[22]张国有,赵晓霞,孟庆裕.白光LED用红色荧光粉Gd2Mo3O9：Eu3+的制备及表征[J].发光学报.2007,28：57-61.
[23]Zhao, X., Wang, X., Chen, B., Meng, Q., Yan, B., Di, W. Luminescent properties of Eu3+ doped a-Gd2(MoO4)3 phosphor for white light emitting diodes[J]. Optical Materials.2007, 29:1680-1684.
[24]Wang, Z., Liang, H., Zhou, L., Wu, H., Gong, M., Su, Q. Luminescence of (Li0.333Nao.334Ko.333)Eu(MoO4)2 and its application in near UV InGaN-based light-emitting diode[J]. Chemical Physics Letters.2005,412:313-316.
[25]Wang, Z., Liang, H., Gong, M., Su, Q. A potential red-emitting phosphor for LED solid-state lighting[J]. Electrochemical and Solid-State Letters.2005,8:H33.
[26]Wang, Z., Liang, H., Wang, J., Gong, M., Su, Q. A novel red phosphor for near UV InGaN light-emitting diode and its luminescent properties[J]. Materials Research Bulletin.2008, 43:907-911.
[27]Wang, Z., Liang, H., Gong, M., Su, Q. Luminescence investigation of Eu3+ activated double molybdates red phosphors with scheelite structure[J]. Journal of Alloys and Compounds.2007, 432:308-312.
[28]Neeraj, S., Kijima, N., Cheetham, A. Novel red phosphors for solid-state lighting: the system NaM(WO4)2-x (MoO4)x:Eu3+(M= Gd, Y, Bi)[J]. Chemical Physics Letters.2004,387:2-6.
[29]Chiu, C. H., Wang, M. F., Lee, C. S., Chen, T. M. Structural, spectroscopic and photoluminescence studies of LiEu (WO4)2-x(MoO4)x as a near-UV convertible phosphor[J]. Journal of Solid State Chemistry.2007,180:619-627.
[30]Lei, F., Yan, B. Morphology-Controlled Synthesis, Physical Characterization, and Photoluminescence of Novel Self-Assembled Pomponlike White Light Phosphor:Eu3+-Doped Sodium Gadolinium Tungstate[J]. The Journal of Physical Chemistry C.2008, 113:1074-1082.
[31]Wang, Y., Sun, Y., Zhang, J., Ci, Z., Zhang, Z., Wang, L. New red Y0.85Bi0.1Eu0.05V1-yMyO4 (M= Nb, P) phosphors for light-emitting diodes[J]. Physica B:Condensed Matter.2008, 403:2071-2075.
[32]Gundiah, G., Shimomura, Y., Kijima, N., Cheetham, A. K. Novel red phosphors based on vanadate garnets for solid state lighting applications[J]. Chemical Physics Letters.2008, 455:279-283.
[33]Sohn, K. S., Park, D. H., Cho, S. H., Kwak, J. S., Kim, J. S. Computational evolutionary optimization of red phosphor for use in tricolor white LEDs[J]. Chem. Mater.2006, 18:1768-1772.
[34]Shionoya, S., Yen, W. M., Hase, T. Phosphor handbook[M]CRC press Boca Raton, FL,1999.
[35]Singh, V., Gundu Rao, T., Zhu, J. J. Synthesis, photoluminescence, thermoluminescence and electron spin resonance investigations of CaAl12O19:Eu phosphor[J]. Journal of luminescence. 2007,126:1-6.
[36]Ozawa, T. C., Fukuda, K., Akatsuka, K., Ebina, Y., Sasaki, T., Kurashima, K., Kosuda, K. (K1.5Eu0.5)Ta3O10:A Far-Red Luminescent Nanosheet Phosphor with the Double Perovskite Structure[J]. The Journal of Physical Chemistry C.2008,112:17115-17120.
[37]CI, Z., WANG, Y. Preparation, Electronic Structure, and Photoluminescence Properties of Eu2+-Activated Carbonate Sr1-xBaxCO3 for White Light-Emitting Diodes[J]. Journal of the Electrochemical Society.2009,156.
[38]Liu, X., Li, C., Quan, Z., Cheng, Z., Lin, J. Tunable Luminescence properties of CaIn2O4: Eu3+ Phosphors[J]. J. Phys. Chem. C.2007,111:16601-16607.
[39]Setlur, A. A., Heward, W. J., Gao, Y., Srivastava, A. M., Chandran, R. G., Shankar, M. V. Crystal chemistry and luminescence of Ce3+-doped Lu2CaMg2(Si,Ge)3O12 and it use in LED based lighting[J]. Chem. Mater.2006,18:3314-3322.
[40]Zhang, M, Wang, J., Zhang, Q., Ding, W., Su, Q. Optical properties of Ba2SiO4:Eu2+ phosphor for green light-emitting diode (LED)[J]. Materials Research Bulletin.2007, 42:33-39.
[41]Liu, H., He, D., Shen, F. Luminescence Properties of Green-Emitting Phosphor (Ba1-x,Srx)2SiO4:Eu2+ for White LEDS[J]. Journal of Rare Earths.2006,24:121-124.
[42]Kang, H. S., Kang, Y. C., Jung, K. Y., Park, S. B. Eu-doped barium strontium silicate phosphor particles prepared from spray solution containing NH4C1 flux by spray pyrolysis[J]. Materials Science and Engineering B.2005,121:81-85.
[43]Kang, H. S., Hong, S. K., Kang, Y. C., Jung, K. Y., Shul, Y. G., Park, S. B. The enhancement of photoluminescence characteristics of Eu-doped barium strontium silicate phosphor particles by co-doping materials[J]. Journal of Alloys and Compounds.2005,402:246-250.
[44]Kim, J. S., Park, Y. H., Kim, S. M., Choi, J. C., Park, H. L. Temperature-dependent emission spectra of M2Si04:Eu2+(M= Ca, Sr, Ba) phosphors for green and greenish white LEDs[J]. Solid State Communications.2005,133:445-448.
[45]Jung, K. Y., Lee, H. W., Jung, H. K. Luminescent properties of (Sr, Zn)Al2O4:Eu2+, B3+ particles as a potential green phosphor for UV LEDs[J]. Chem. Mater.2006,18:2249-2255.
[46]杨志平,王少丽,杨广伟.绿色荧光粉NaCaPO4:B4+, Tb3+的制备与发光特性[[J].发光学报.2008,29：81-84.
[47]Yang, Z., Yang, G., Wang, S., Tian, J., Li, X., Guo, Q., Fu, G. A novel green-emitting phosphor NaCaPO4:Eu2+ for white LEDs[J]. Materials Letters.2008,62:1884-1886.
[48]P.Yang, Lin, J. H., G.Q.Yao. Luminescence and preparation of LED phosphor Ca8Mg(Si04)4Cl2:Eu2+[J]. J Rare Earth.2005,23(5):633-635.
[49]Ding, W., Wang, J., Zhang, M., Zhang, Q., Su, Q. Luminescence properties of new Ca10(Si207) 3Cl2:Eu2+ phosphor[J]. Chemical physics letters.2007,435:301-305.
[50]Yang, P., Yao, G. Q., Lin, J. H. Energy transfer and photoluminescence of BaMgAl10O17 co-doped with Eu2+ and Mn2+[J]. Optical Materials.2004,26:327-331.
[51]蒋大鹏,赵成久.用荧光粉转换方法制备纯绿色LED[J].发光学报.2002,23：311-313.
[52]张中太,张俊英无机光致发光材料及应用[M]北京：化学工业出版社,2005：166.
[53]Kang, Y., Sohn, J., Yoon, H., Jung, K., Park, H. Improved Photoluminescence of Sr5(PO4)3Cl: Eu2+Phosphor Particles Prepared by Flame Spray Pyrolysis[J]. J. Electrochem. Soc.2003, 150:H38-H42.
[54]N tzold, D., Wulff, H., Herzog, G. Structural and Optical Properties of the System (Ca,Sr,Eu)5(PO4)3CI[J]. physica status solidi (b).1995,191:21-30.
[55]Kottaisamy, M., Jagannathan, R., Jeyagopal, P., Rao, R., Narayanan, R. Eu2+ luminescence in M5(PO4)3X apatites, where M is Ca2+, Sr2+ and Ba2+, and X is F-, Cl-, Br- and OH-[J]. Journal of Physics D:Applied Physics.1994,27:2210.
[56]Park, J., Choi, K., Kim, C., Park, H., Kim, H. Luminescence characteristics of Sr3MgSi2O8: Eu blue phosphor for light-emitting diodes[J]. Electrochemical and Solid-State Letters.2004, 7:H42-H43.
[57]Lakshminarasimhan, N., Varadaraju, U. White-light generation in Sr2Si04, Sr2SiO4:Eu2+, Ce3+under near-UV excitation a novel phosphor for solid-state lighting[J]. Journal of the Electrochemical Society.2005,152:H152-H156.
[58]Saha, S., Chowdhury, P. S., Patra, A. Luminescence of Ce3+ in Y2SiO5 nanocrystals: Role of crystal structure and crystal size[J]. J. Phys. Chem. B.2005,109:2699-2702.
[59]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[60]杨云霞,陈仙玲,袁双龙.白光LED灯用蓝光荧光粉的发光性能和结构[J].硅酸盐学报.2006,34：671-674.
[61]Zeng, Q., Tanno, H., Egoshi, K., Tanamachi, N., Zhang, S. BaSiO4Cl2:Eu:An intense blue emission phosphor under vacuum ultraviolet and near-ultraviolet excitation[J]. Applied Physics Letters.2006,88:051906.
[62]杨志平,刘玉峰,李雪清.用于白光LED的高亮度蓝白色荧光Ca2SiO3Cl2：Eu2+的发光性质[J].发光学报.2006,27：629-632.
[63]杨志平,王少丽,杨广伟. Ca2B5O9Cl:Eu2+蓝色荧光粉的发光特性[J].硅酸盐学报.2008,36(2)：180-181.
[64]孙晓园,张家骅,张霞.新一代白光LED照明用一种适用于近紫外光激发的单一白光荧光粉[J]. Chinese Journal of Luminescence.2005,26:404-406.
[65]Kim, J., Jeon, P., Choi, J., Parka, H., Mho, S., Kim, G. Warm-white-light emitting diode utilizing a single-phase full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphor[J]. Applied Physics Letters.2004,84:15.
[66]Kim, J. S., Lim, K. T., Jeong, Y. S., Jeon, P. E., Choi, J. C., Park, H. L. Full-color Ba3MgSi2O8:Eu2+, Mn2+ phosphors for white-light-emitting diodes[J]. Solid State Communications. 2005,135:21-24.
[67]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L. Color tunability and stability of silicate phosphor for UV-pumped white LEDs[J]. Journal of the Electrochemical Society. 2005,152:H29.
[68]Yang, W. J., Luo, L., Chen, T. M., Wang, N. S. Luminescence and energy transfer of Eu-and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED[J]. Chem. Mater. 2005,17:3883-3888.
[69]Liu, B., Kong, L., Shi, C. White-light long-lasting phosphor Sr2MgSi207:Dy3+[J]. Journal of Luminescence.2007,122:121-124.
[70]李盼来,杨志平,王志军.Sr2SiO4：Dy3+材料制备及发光特性[J].高等学校化学学报.2008,29：457-460.
[71]Jiao, H., Wang, Y. CaAlSiO4:Ce, Tb:A White-Light Phosphor Suitable for White-Light-Emitting Diodes[J]. Journal of the Electrochemical Society.2009,156:J117.
[72]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn2(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied Physics Letters.2006,88:1903.
[73]Shuanglong, Y., Xianlin, C., Chaofeng, Z., Yunxia, Y., Guorong, C. Eu2+, Mn2+ Co-doped (Sr, Ba)6BP5O20-A novel phosphor for white-LED[J]. Optical Materials.2007,30:192-194.
[74]杨志平,刘玉峰,王利伟.用于白光LED的单一基质白光荧光粉Ca2SiO3Cl2：Eu2+,Mn2+的发光性质[J].物理学报.2007,56：546-550.
[75]Gou, J., Wang, Y., Guo, H.; IOP Publishing:2009; Vol.152, p 012081.
[76]Dutta, D. P., Ghildiyal, R., Tyagi, A. K. Luminescent Properties of Doped Zinc Aluminate and Zinc Gallate White Light Emitting Nanophosphors Prepared via Sonochemical Method[J]. The Journal of Physical Chemistry C.2009,113:16954-16961.
[77]Jiang, Z., Wang, Y. Near-UV Excitable White SrAlGeO:Ce, Tb Phosphor for Light Emitting Diodes[J]. Electrochemical and Solid-State Letters.2010,13:J68.
[78]Tamura, T., Setomoto, T., Taguchi, T. Illumination characteristics of lighting array using 10 candela-class white LEDs under AC 100 V operation[J]. Journal of luminescence.2000, 87:1180-1182.
[79]张凯,刘河洲,胡文彬.白光LED用荧光粉的研究进展[J].材料导报.2005,19：50-53.
[80]刘行仁.白光LED固态照明光转换荧光体[J].发光学报.2007,28：291-301.
[81]王涛,井艳军,朱月华.白光LED用钨钼酸盐红色荧光粉的研究进展[J].中国照明电器.2010,24：54-57.
[82]Kitai, A. Luminescent materials and applications[M]Wiley,2008.
[83]Kim, C. H., Kwon, I. E., Park, C. H., Hwang, Y. J., Bae, H. S., Yu, B. Y., Pyun, C. H., Hong, G. Y. Phosphors for plasma display panels[J]. Journal of Alloys and Compounds.2000, 311:33-39.
[84]Jiang, X. C., Yan, C. H., Sun, L. D., Wei, Z. G., Liao, C. S. Hydrothermal homogeneous urea precipitation of hexagonal YBO3:Eu3+ nanocrystals with improved luminescent properties[J]. Journal of Solid State Chemistry.2003,175:245-251.
[85]Gupta, S. K., Agrawal, D. C., Mohapatra, Y. N. Photoluminescence and Morphological Studies of (YGd)BO3:Eu Phosphor Powders Prepared by the Urea Hydrolysis Route[J]. Journal of the Electrochemical Society.2004,151:H239.
[86]Lee, K. G., Yu, B. Y., Pyun, C. H., Mho, S. I. Vacuum ultraviolet excitation and photoluminescence characteristics of (Y,Gd)Al3(BO3)4:Eu3+[J]. Solid state communications. 2002,122:485-488.
[87]Chakradhar, R. P. S., Nagabhushana, B., Chandrappa, G., Ramesh, K., Rao, J. Solution combustion derived nanocrystalline ZnSiO4:Mn phosphors:A spectroscopic view[J]. The Journal of chemical physics.2004,121:10250.
[88]Taghavinia, N., Lerondel, G., Makino, H., Parisini, A., Yamamoto, A., Yao, T., Kawazoe, Y., Goto, T. Structural and Optical Properties of Oxidized Porous Silicon Layers Activated by ZnSiO4:Mn[J]. Journal of the Electrochemical Society.2002,149:G251.
[89]Hong, G. Y., Jeoung, B. W., Jeon, B. S., Yoo, J. S., Ha, C. H., Whang, K. W. Improvement of Discharge Characteristics of the ZnSiO4:Mn Phosphor Layer in Plasma Display Panels[J]. Journal of the Electrochemical Society.2004,151:H205.
[90]Sohn, K. S., Kim, S. S., Park, H. D. Luminescence quenching in thermally-treated barium magnesium aluminate phosphor[J]. Applied physics letters.2002,81:1759.
[91]Dawson, B., Ferguson, M., Marking, G., Diaz, A. Mechanisms of VUV Damage in BaMgAl10O17:Eu2+[J]. Chem. Mater.2004,16:5311-5317.
[92]Yokota, K., Zhang, S. X., Kimura, K., Sakamoto, A. Eu2+-activated barium magnesium aluminate phosphor for plasma displays-Phase relation and mechanism of thermal degradation[J]. Journal of luminescence.2001,92:223-227.
[93]Hamada, K., Yamamoto, T., Kurida, T., Takano, Y., Yuyama, I., Murakami, H. Analysis and improvement of crosstalk impairment on a field-sequential stereoscopic display system with DC-type PDP[J]. J. Inst. Television Engng Jpn.2001,55 (12):439.
[94]Okazaki, C., Shiiki, M., Suzuki, T., Suzuki, K. Luminance saturation properties of PDP phosphors[J]. Journal of luminescence.2000,87:1280-1282.
[95]Rao, R. Tb Activated Green Phosphors for Plasma Display Panel Applications[J]. Journal of the Electrochemical Society.2003,150:H165.
[96]Guo, X., Wang, Y., Zhang, J. Synthesis multifarious morphologies and sizes of YBO3:Eu3+ phosphors, and clarification of the crystal structure of YBO3[J]. Journal of Crystal Growth. 2009,311:2409-2417.
[97]Park, K., Nam, S. Enhanced photoluminescence of spray pyrolysis processed YBO3:Eu3+ for PDP application[J]. Materials Chemistry and Physics.2010,123:360-362.
[98]Wang, Y., Hao, Y., Yuwen, L. Synthesis process dependent photoluminescent properties of Zn2Si04:Mn2+upon VUV region[J]. Journal of alloys and compounds.2006,425:339-342.
[99]Kim, Y., Kang, S. Multi-functional colored coating of BaMgAl10O17:Eu phosphors with cobalt-doped Al2O3 thin films[J]. Applied physics. A, Materials science & processing.2010, 98:245-248.
[100]Wang, Y. F., Xu, X., Yin, L. J., Hao, L. Y. High Thermal Stability and Photoluminescence of Si"CN(?)\Codoped BaMgAl10O17:Eu2+ Phosphors[J]. Journal of the American Ceramic Society.2010,93:1534-1536.
[101]Liu, B., Wang, Y., Zhang, F., Wen, Y., Dong, Q., Wang, Z. Thermal stability and photoluminescence of S-doped BaMgAl10O17:Eu2+ phosphors for plasma display panels[J]. Optics Letters.2010,35:3072-3074.
[102]Liu, J., Wang, Y., Yu, X., Li, J. Enhanced photoluminescence properties of Zn2Si04: Mn2+ co-activated with Y3+/Li+ under VUV excitation[J]. Journal of luminescence.2010, 130:2171-2174.
[103]Balakrishnaiah, R., Yi, S. S., Jang, K., Lee, H. S., Moon, B. K., Jeong, J. H. Enhanced luminescence properties of YBO3:Eu3+ phosphors by Li-doping[J]. Materials Research Bulletin.2011,46:621-626.
[104]Kuo, T. W., Chung, H. P., Chen, T. M. Deep Red Emission of Ca19Ce(PO4)14:Mn2+ Phosphor for Fluorescent Lamp and PDP Applications[J]. Chemistry Letters.2010, 39:200-201.
[105]Yadav, R., Khan, A. F., Yadav, A., Chander, H., Haranath, D., Gupta, B. K., Shanker, V., Chawla, S. Intense red-emitting Y4Al2O9:Eu3+ phosphor with short decay time and high color purity for advanced plasma display panel[J]. Optics express.2009,17:22023.
[106]Zhou, L. Y., Gong, F. Z., Shi, J. X., Gong, M. L., Liang, H. B. A novel red phosphor Na2Ca4Mg2Si4O15:Eu3+ for plasma display panels[J]. Materials Research Bulletin.2008, 43:2295-2299.
[107]XIE, M., LIANG, H., SU, Q., HUANG, Y., GAO, Z., TAO, Y. Red Emission of Ca6Gd1.97Euo.o3Na2(P04)6F2 with Suitable Chromaticity Coordinates under VUV Excitation[J]. Electrochemical and Solid-State Letters.2010,13:J140-J142.
[108]Gao, X., Wang, Y., Wang, D., Liu, B. Luminescent properties of KGd1-x (WO4)2:Eux3+and KGd1-x (WO4) 2-y (MoO4)y:Eux3+ phosphors in UV-VUV regions[J]. Journal of luminescence. 2009,129:840-843.
[109]HE, L., WANG, Y., SUN, W. Luminescence properties of BaB8O13:Eu under UV and VUV excitation[J]. Journal of Rare Earths.2009,27:385-389.
[110]Wang, D., Wang, Y., Shi, Y. Photoluminescence properties of Eu3+ in Y(PO3) 3 under VUV excitation[J]. Journal of luminescence.2011,131:1154-1157.
[111]Liang, H., Lin, H., Zhang, G., Dorenbos, P., Su, Q. Luminescence of Ce3+ and Pr3+ doped Sr2Mg(BO3)2 under VUV-UV and X-ray excitation[J]. Journal of luminescence.2010, 131:194-198.
[112]Li, X. X., Wang, Y. H., Chen, Z. Photoluminescence properties of GdBa3B9O18:Ln3+(Ln= Eu, Tb) under UV and VUV excitation[J]. Journal of alloys and compounds.2008, 453:392-394.
[113]Zhang, J., Wang, Y., Zhang, Z., Peng, X., Jiang, Y., Li, H. Vacuum ultraviolet excited photoluminescence properties of novel Na3Y9O3(BO3)8:Eu3+ phosphor[J]. Materials Research Bulletin.2009,44:953-955.
[114]Wang, Z., Wang, Y., Zhang, J., Lu, Y. The photoluminescence properties of Eu3+, Bi3+ co-doped yttrium oxysulfide phosphor under vacuum ultraviolet excitation[J]. Materials Research Bulletin.2009,44:1183-1187.
[115]Wojtowicz, A. J. VUV spectroscopy of BaF2:Er[J]. Optical Materials.2009,31:474-478.
[116]Yuan, J. L., Wang, J., Zhang, Z. J., Zhao, J. T., Zhang, G. B. Synthesis and luminescent properties of AGd1-xLnxP2O7 (A= Rb, Cs; Ln= Ce, Eu, Tb) under VUV and X-ray excitations[J]. Optical Materials.2008,30:1327-1334.
[117]Zhang, F., Wang, Y., Wen, Y., Wang, D., Tao, Y. Photoluminescence properties of RE3+-activated Na3GdP2O8 (RE3+= Tb3+, Dy3+, Eu3+, Sm3+) under VUV excitation[J]. Optical Materials.2010,33:475-479.
[118]Atkins, R., Diaz, A. L. Investigation of host-to-activator energy transfer and surface losses in SrY2O4:Eu3+ under VUV excitation[J]. Journal of luminescence.2008,128:1463-1470.
[119]Zhang, Z., Wang, Y., Zhang, J., Hao, Y. Luminescent properties of Na3YSi309 doped with Eu3+ under UV-VUV excitation[J]. Materials Research Bulletin.2008,43:926-931.
[120]Han, B., Liang, H., Ni, H., Su, Q., Yang, G., Shi, J., Zhang, G. Intense red light emission of Eu3+-doped LiGd(PO3)4 for mercury-free lamps and plasma display panels application[J]. Optics express.2009,17:7138.
[121]Sivakumar, V., Hong, G. Y., Kim, J. S., Jeon, D. Novel blue-emitting phosphor Sr2.979Euo.o2iAl10-xBxSiO2o (x=0,0.25,0.5,0.75 and 1) for PDP applications[J]. Journal of luminescence.2009,129:1632-1636.
[122]Kim, S. B., Kum, B. G., Jang, H. M., Lakshmanan, A. Luminescence efficiencies of self-and Tm3+ activated CaWO4 under vacuum ultraviolet radiation excitation[J]. Journal of luminescence.2011,131:1625-1628.
[123]Im, W. B., Yoo, H. S., Vaidyanathan, S., Kwon, K. H., Park, H. J., Kim, Y. I., Jeon, D. Y. A novel blue-emitting silica-coated KBaPO4:Eu2+ phosphor under vacuum ultraviolet and ultraviolet excitation[J]. Materials Chemistry and Physics.2009,115:161-164.
[124]Li, Y. Z., Wang, Y. H., Zhang, Z. H., Liu, W. J. Precipitation Synthesis of Sr2MgSi07:Eu Phosphor and Its Luminescent Properties under Vacuum Ultraviolet Excitation[J]. Electrochemical and Solid-State Letters.2006,9:J37.
[125]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of luminescence.2005,113:271-278.
[126]Zhang, Z., Wang, Y., Zhang, J. A novel green-emitting VUV phosphor Na3YSi309:Tb3+[J]. Materials Letters.2008,62:846-848.
[127]Zhou, L., Choy, W. C. H., Shi, J., Gong, M., Liang, H. Synthesis and luminescent properties of GdSrAl3O7:Tb3+ phosphor under VUV/UV excitation[J]. Journal of alloys and compounds. 2008,463:302-305.
[128]Yang, H. M., Shi, J., Gong, M. L., Liang, H. The UV and VUV luminescence properties of the phosphor Mg2GeO4:Tb3+[J]. Materials Letters.2010,64:1034-1036.
[129]Yoo, H. S., Im, W. B., Kang, J. H., Jeon, D. Y. Preparation and photoluminescence properties of YAl3(BO3)4: Tb3+, Bi3+ phosphor under VUV/UV excitation[J]. Optical Materials.2008,31:131-135.
[130]LI, X., WANG, Y. VUV-excited luminescence properties of Tb3+ activated BaGdB9O16[J]. Journal of Rare Earths.2010,28:361-364.
[131]WANG, Z., WANG, Y., ZHANG, J. Vacuum ultraviolet excited photoluminescence properties of Gd2O2CO3:Eu3+ phosphor[J]. Journal of Rare Earths.2008,26:425-427.
[132]Zhou, L. Y., Wei, J. S., Shi, J. X., Gong, M. L., Liang, H. B. A novel green phosphor GdCaAlO4:Tb3+ for PDP application[J]. Journal of luminescence.2008,128:1262-1266.
[133]Zhang, H., Wang, Y., Xie, L. Luminescent properties of Tb3+ activated GdTaO4 with M and M' type structure under UV-VUV excitation[J]. Journal of luminescence.2010, 130:2089-2092.
[134]Zhong, J., Liang, H., Han, B., Su, Q., Tao, Y. NaGd(PO3)4:Tb3+-A new promising green phosphor for PDPs application[J]. Chemical physics letters.2008,453:192-196.
[135]Yang, H. M., Gong, M. L., Liang, H. Fine particle Sr2Si04:Tb phosphor for the plasma display panel prepared by a combined approach[J]. Materials Research Bulletin.2010, 45:805-808.
[136]Wang, D., Wang, Y. Optical properties of (Y, Tb)PO4 under VUV excitation[J]. Materials Chemistry and Physics.2009,115:699-702.
[137]Zhang, F., Wang, Y., Liu, B., Wen, Y., Tao, Y. Investigation of Na3GdP2O8:Tb3+ as a potential green-emitting phosphor for plasma display panels[J]. Materials Research Bulletin. 2011,46:722-725.
[138]Zhang, Z., Zhang, Y., Li, X., Xu, J., Huang, Y. VUV-UV luminescence of magnetoplumbite:(Sr0.96-xBa0.04)Al12-yMgyO19:Tbx[J]. Journal of luminescence.2008, 128:476-480.
[139]Zhang, F., Wang, Y., Liu, J. Vacuum ultraviolet spectroscopic properties of KSrPO4:Tb3+[J]. Journal of alloys and compounds.2011,509:3852-3854.
[140]Tian, Z., Liang, H., Chen, W., Su, Q., Zhang, G., Yang, G. Efficient emission-tunable VUV phosphors Na2GdF2PO4:Tb3+[J]. Optics express.2009,17:956.
[141]Xie, M., Liang, H., Han, B., Chen, W., Su, Q., Huang, Y., Gao, Z., Tao, Y. Ca6Gdi.5Tb0.5Na2(P04)6F2—an intense green-emitting phosphor under vacuum ultraviolet and low-voltage cathode ray excitation[J]. Optics Letters.2009,34:3466.
[142]刘行仁,王晓君.全色等离子体平板显示器用发光材料[J].发光快报.1995,9-13.
[143]Wang, Z., Xu, M., Zhang, W., Yin, M. Synthesis and luminescent properties of nano-scale LuAG:RE3+(Ce, Eu) phosphors prepared by co-precipitation method[J]. Journal of luminescence.2007,122:437-439.
[144]肖志国半导体照明发光材料及应用[M]化学工业出版社,2008.
[145]Blasse, G., Grabmaier, B. C. Luminescent materials[M]Springer-Verlag Berlin,1994.
[146]Cheetham, A. K., Day, P. Solid state chemistry:techniques[M]. Oxford University Press, USA,1990.
[147]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of luminescence. 2008,128:1348-1352.
[148]Zhang, H., Fu, X., Niu, S., Xin, Q. Synthesis and photoluminescence properties of Eu3+-doped AZrO3 (A= Ca, Sr, Ba) perovskite[J]. Journal of alloys and compounds.2008, 459:103-106.
[149]Liu, Z., Liu, Y., Zhang, J., Rong, J., Huang, L., Yuan, D. Long afterglow in Pr3+ and Li+ co-doped CaZrO3[J]. Optics communications.2005,251:388-392.
[150]Shimizu, Y., Sakagami, S., Goto, K., Nakachi, Y., Ueda, K. Tricolor luminescence in rare earth doped CaZrO3 perovskite oxides[J]. Materials Science and Engineering:B.2009, 161:100-103.
[151]Gon alves, M., Cavalcante, L., Sczancoski, J., Espinosa, J., Pizani, P., Longo, E., Rosa, I. (Sr, Tm) ZrO3 powders prepared by the polymeric precursor method:Synthesis, optical properties and morphological characteristics[J]. Optical Materials.2009,31:1134-1143.
[1]余泉茂等,无机发光材料研究及应用新进展
[2]Werner, P. E., Eriksson, L. and Westdahl, Mtreor. A semi-exhausting trial and errorpowder indexing program for all symmetries. Journal of Applied Crystal,1985,18(5):367.
[1]Zhang, H., Fu, X., Niu, S., Sun, G., Xin, Q. Photoluminescence of nanocrystalline YVO4: TmxDy1-x prepared by a modified Pechini method[J]. Materials Letters.2007,61:308-311.
[2]Macalik, L., Hanuza, J., Jaque, D., Garc Sol, J. Spectroscopic characterisation of the Tm3+ doped KLa (WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[3]True, M., Chen, Y, Kirm, M., Vielhauer, S., Zimmerer, G. VUV spectroscopy of pure and Tm3+-doped LiCaAlF6 crystals[J]. Journal of Luminescence.2007,124:279-285.
[4]Yan, B., Su, X.-Q. In situ co-precipitation synthesis and photoluminescence of YxGd1-xVO4:Tm3+ microcrystalline phosphors by hybrid precursors[J]. Optical Materials. 2007,29:1866-1870.
[5]Khaidukov, N. M., Kirikova, N. Y, Kirm, M., Krupa, J. C., Makhov, V. N., Negodin, E., Zimmerer, G.2002; Vol.4766, p 154.
[6]Chapman, A., Thirlwell, L. Spectra of phosphorus compounds:the infrared spectra of orthophosphates[J]. Spectrochimica Acta.1964,20:937-947.
[7]Zhang, Z., Yuan, J., Duan, C., Xiong, D., Chen, H., Zhao, J., Zhang, G, Shi, C. Vacuum ultraviolet spectroscopic properties of rare earth (RE= Ce, Tb, Eu, Tm, Sm)-doped hexagonal KCaGd (PO4)2 phosphate[J]. Journal of Applied Physics.2007,102:093514.
[8]Hu, X., Yan, S., Ma, L., Wan, G, Hu, J. Preparation of LaPO4:Ce,Tb phosphor with different morphologies and their fluorescence properties[J]. Powder Technology.2009,192:27-32.
[9]Huang, Y, Jiang, C., Cao, Y, Shi, L., Seo, H. J. Luminescence and microstructures of Eu3+-doped in triple phosphate Ca8MgR(PO4)7 (R=La, Gd, Y) with whitlockite structure[J]. Materials Research Bulletin.2009,44:793-798.
[10]Eberlein, K., Kattner, G. Automatic method for the determination of ortho-phosphate and total dissolved phosphorus in the marine environment[J]. Fresenius' Journal of Analytical Chemistry.1987,326:354-357.
[11]吴春芳.Eu3+,Tb3+离子掺杂的多种磷酸盐的合成及其发光性能的研究.兰州大学博士学位论文.
[12]Nakazawa, E., Shiga, F. Vacuum ultraviolet luminescence-excitation spectra of RPO4:Eu3+ (R=Y, La, Gd and Lu)[J]. Journal of Luminescence.1977,15:255-259.
[13]Di, W., Wang, X., Chen, B., Lai, H., Zhao, X. Preparation, characterization and VUV luminescence property of YPO4:Tb phosphor for a PDP[J]. Optical Materials.2005, 27:1386-1390.
[14]Wang, D., Wang, Y. Spectroscope properties of KCaY(PO4)2:Eu3+ in vacuum ultraviolet region[J]. Materials Science and Engineering:B.2006,133:218-221.
[15]Wu, C., Wang, Y, Jie, W. Hydrothermal synthesis and luminescent properties of LnPO4:Tb (Ln= La, Gd) phosphors under VUV excitation[J]. Journal of Alloys and Compounds.2007, 436:383-386.
[16]Wanmaker, W., Spier, H. Luminescence of Copper-Activated Orthophosphates of the Type ABPO (A= Ca, Sr, or Ba and B= Li, Na, or K)[J]. Journal of The Electrochemical Society. 1962,109:109.
[17]Wanmaker, W., Bril, A., ter Vrugt, J. Sensitization of Tb3+ luminescence by Sn2+ and Cu2+ in alkaline earth phosphates[J]. Appl. Phys. Lett.1966,8:260.
[18]Paques-Ledent, M.-T. Vibrational spectra and structure of LiB2+PO4 compounds with B=Sr, Ba, Pb[J]. Journal of Solid State Chemistry.1978,23:147-154.
[19]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[20]Wu, Z., Liu, J., Guo, Q., Gong, M. A Novel Blue-green-emitting Phosphor LiBaPO4:Eu2+ for White Light-emitting Diodes[J]. Chemistry Letters.2008,37:190-191.
[21]Liu, J., Wu, Z., Gong, M. Thermally stable luminescence of blue LiSrPO4:Eu2+ phosphor for near-UV light-emitting diodes[J]. Applied Physics B:Lasers and Optics.2008,93:583-587.
[22]Wu, Z., Liu, J., Gong, M., Su, Q. Optimization and Temperature-Dependent Luminescence of LiBaPO4:Eu Phosphor for Near-UV Light-Emitting Diodes[J]. Journal of The Electrochemical Society.2009,156:H153.
[23]More, S., Meshram, M., Wankhede, S., Muthal, P., Dhopte, S., Moharil, S. Luminescence in LiCaPO4[J]. Physica B:Condensed Matter.2011.
[24]Liang, C. S., Eckert, H., Gier, T. E., Stucky, G. D. Compositionally induced phase transitions and nonlinear optic response in ABCO4 crystal solution phases ALiPO4 (A= Sr, Ba, Pb)[J]. Chemistry of Materials.1993,5:597-603.
[25]Patil, R., Moharil, S. Cu+ Luminescence in New Hosts[J]. physica status solidi (a).2001, 187:557-562.
[26]Wu, Z., Shi, J., Gong, M., Wang, J., Su, Q. Nanosized LiSrPO4:Eu2+ phosphor with blue-emission synthesized by the sol-gel method[J]. Materials Chemistry and Physics.2007, 103:415-418.
[27]Patil, R., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Thermoluminescence in some copper-doped compounds[J]. physica status solidi (a).2003,199:527-532.
[28]Im, W. B., Yoo, H. S., Vaidyanathan, S., Kwon, K. H., Park, H. J., Kim, Y. I., Jeon, D. Y. A novel blue-emitting silica-coated KBaPO4:Eu2+ phosphor under vacuum ultraviolet and ultraviolet excitation[J]. Materials Chemistry and Physics.2009,115:161-164.
[29]Yang, Z., Yang, G., Wang, S., Tian, J., Li, X., Guo, Q., Fu, G. A novel green-emitting phosphor NaCaPO4:Eu2+ for white LEDs[J]. Materials Letters.2008,62:1884-1886.
[30]Amara, B., Vlasse, M., Le Flem, G., Hagenmuller, P. Structure of the low-temperature variety of calcium sodium orthophosphate, NaCaPO4[J]. Acta Crystallographica Section C:Crystal Structure Communications.1983,39:1483-1485.
[31]Qin, C., Huang, Y, Shi, L., Chen, G., Qiao, X., Seo, H. J. Thermal stability of luminescence of NaCaPO4:Eu2+ phosphor for white-light-emitting diodes[J]. Journal of Physics D: Applied Physics.2009,42:185105.
[32]Saito, S., Wada, K., Onaka, R. Vacuum ultraviolet reflection spectra of KDP and ADP[J]. Journal of the Physical Society of Japan.1974,37:711.
[33]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[34]Peng, M., Pei, Z., Hong, G., Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[35]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[36]潘金生,健.,田民波.材料科学基础[M].清华大学出版社.1998.
[37]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration. I. Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[38]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[39]Yamamoto, H., Mikami, M., Shimomura, Y., Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000, 87-89:1079-1082.
[40]Lu, Y, Dai, Y, Yang, Y, Wang, J., Dong, A., Sun, B. Anisotropy of thermal and spectral characteristics in Tm:YAP laser crystals[J]. Journal of Alloys and Compounds.2008, 453:482-486.
[41]Macalik, L., Hanuza, J., Jaque, D., Garcia Sole, J. Spectroscopic characterisation of the Tm3+ doped KLa(WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[42]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+ (Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B Phys Rev B.2009,80:085103.
[43]Dexter, D., Schulman, J. Theory of concentration quenching in inorganic phosphors[J]. The Journal of Chemical Physics.1954,22:1063.
[44]Liu, Y, Shi, C. Luminescent Centers of Eu2+ in BaMgAl10O17 Phosphor[J]. Materials Research Bulletin.2001,36:109-115.
[45]Blasse, G, Grabmaier, B.; Springer-Verlag, Berlin.
[46]Dexter, D. A theory of sensitized luminescence in solids[J]. The Journal of Chemical Physics. 1953,21:836.
[47]Blasse, G. Energy transfer in oxidic phosphors[J]. Physics Letters A.1968,28:444-445.
[48]Fukuzawa, T., Tanimizu, S. Flourescence decay characteristics of Tb3+-activated phosphates under H2-VUV laser excitation[J]. Journal of Luminescence.1978,16:447-456.
[49]Liang, H., Tao, Y, Xu, J., He, H., Wu, H., Chen, W., Wang, S., Su, Q. Photoluminescence of Ce3+, Pr3+ and Tb3+ activated Sr3Ln (PO4)3 under VUV-UV excitation[J]. Journal of Solid State Chemistry.2004,177:901-908.
[50]Wu, X., You, H., Cui, H., Zeng, X., Hong, G., Kim, C. H., Pyun, C. H., Yu, B. Y, Park, C. H. Vacuum ultraviolet optical properties of (La, Gd) PO4:RE3+(RE= Eu, Tb)[J]. Materials Research Bulletin.2002,37:1531-1538.
[51]Zeng, Q., Liang, H., Zhang, G., Birowosuto, M. D., Tian, Z., Lin, H., Fu, Y, Dorenbos, P., Su, Q. Luminescence of Ce3+ activated fluoro-apatites M5(PO4)3F (M= Ca, Sr, Ba) under VUV-UV and x-ray excitation[J]. Journal of Physics:Condensed Matter.2006,18:9549.
[52]Liang, H., Tao, Y., Su, Q. The luminescent properties of Ba3Gd1-xLnx(PO4)3 under synchrotron radiation VUV excitation[J]. Materials Science and Engineering B.2005, 119:152-158.
[53]Zhang, Z. J., Yuan, J. L., Wang, X. J., Xiong, D. B., Chen, H. H., Zhao, J. T., Fu, Y. B., Qi, Z. M., Zhang, G. B., Shi, C. S. Luminescence properties of CaZr (PO4)2:RE (RE= Eu3+, Tb3+, Tm3+) under x-ray and VUV-UV excitation[J]. Journal of Physics D:Applied Physics.2007, 40:1910.
[54]Zhang, Z. J., Chen, H. H., Yang, X. X., Zhao, J. T., Zhang, G. B., Shi, C. S. VUV spectroscopic properties of rare-earth (RE3+= Eu, Tb, Tm)-doped AZr2(PO4)3 (A+= Li, Na, K) type phosphate[J]. Journal of Physics D:Applied Physics.2008,41:105503.
[55]Struck, C., Fonger, W. Role of the charge-transfer states in feeding and thermally emptying the 5D states of Eu3+ in yttrium and lanthanum oxysulfides[J]. Journal of Luminescence.1970, 1:456-469.
[56]Fonger, W., Struck, C. Energy Loss and Energy Storage from the Eu Charge-Transfer States in Y and La Oxysulfides[J]. Journal of The Electrochemical Society.1971,118:273.
[57]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[58]苏锵.稀土化学[M].1993.
[59]Dorenbos, P. The 5d level positions of the trivalent lanthanides in inorganic compounds[J]. Journal of Luminescence.2000,91:155-176.
[60]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of Luminescence. 2005,113:271-278.
[1]Wachtel, A. Eu Activated Aluminosilicate Phosphors[J]. Journal of the Electrochemical Society. 1969,116:61.
[2]Qiu, J., Kawasaki, M., Tanaka, K., Shimizugawa, Y., Hirao, K. Phenomenon and mechanism of long-lasting phosphorescence in Eu2+-doped aluminosilicate glasses[J]. Journal of Physics and Chemistry of Solids.1998,59:1521-1525.
[3]Kuang, J., Liu, Y., Zhang, J., Huang, L., Rong, J., Yuan, D. Blue-emitting long-lasting phosphor, Sr3AlioSiO2o:Eu2+, Ho3+[J]. Solid State Communications.2005,136:6-10.
[4]Yang, W. J., Luo, L., Chen, T. M., Wang, N. S. Luminescence and energy transfer of Eu-and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED[J]. Chem. Mater. 2005,17:3883-3888.
[5]Ju, H., Su, X., Xu, S., Zhang, Y., Deng, D., Zhao, S., Wang, H., Wang, B., Sun, L. Luminescence properties of Eu2+-activated Ca12Al10.6Si3.4O32Cl5.4:A promising phosphor for solid state lighting[J]. Materials Letters.2009,63:1275-1277.
[6]Lin, Z., Zeng, H., Yang, Y., Liang, X., Chen, G., Sun, L. The Effect of Fluorine Anions on the Luminescent Properties of Eu-Doped Oxyfluoride Aluminosilicate Glasses[J]. Journal of the American Ceramic Society.2010,93:3095-3098.
[7]Clabau, F., Garcia, A., Bonville, P., Gonbeau, D., Le Mercier, T., Deniard, P., Jobic, S. Fluorescence and phosphorescence properties of the low temperature forms of the MAl2Si2O8: Eu2+(M= Ca, Sr, Ba) compounds[J]. Journal of Solid State Chemistry.2008,181:1456-1461.
[8]Li, Y., With, G, Hintzen, H. Luminescence Properties of Eu2+ -Doped MAl2-xSixO4-xNx (M= Ca, Sr, Ba) Conversion Phosphor for White LED Applications[J]. Journal of the Electrochemical Society.2006,153:278.
[9]Gebert, W. Z. Kristallogr.1972,135:437.
[10]Oehlschlegel, V. G, Kockel, A., Biedl, A. Glastech. Ber.1974,47:31-41.
[11]Denis, G, Deniard, P., Gautron, E., Clabau, F., Garcia, A., Jobic, S. Structure and White Luminescence of Eu-Activated (Ba, Sr)13-xAl22-2xSi10+2x066 Materials[J]. Inorganic chemistry. 2008,47:4226-4235.
[12]Clabau, F., Rocquefelte, X., Jobic, S., Deniard, P., Whangbo, M. H., Garcia, A., Le Mercier, T. Mechanism of phosphorescence appropriate for the long-lasting phosphors Eu2+-doped SrAl2O4 with codopants Dy3+ and B3+[J]. Chem. Mater.2005,17:3904-3912.
[13]Shannon, R. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallographica Section A:Crystal Physics, Diffraction, Theoretical and General Crystallography.1976,32:751-767.
[14]Xie, R. J., Hirosaki, N., Sakuma, K., Yamamoto, Y., Mitomo, M. Eu-doped Ca-a-SiAlON:A yellow phosphor for white light-emitting diodes[J]. Applied Physics Letters.2004,84:5404.
[15]Hirosaki, N., Xie, R. J., Kimoto, K., Sekiguchi, T., Yamamoto, Y., Suehiro, T., Mitomo, M. Characterization and properties of green-emitting a-SiAlON:Eu powder phosphors for white light-emitting diodes[J]. Applied Physics Letters.2005,86:211905.
[16]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn(PO4)2:Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied Physics Letters.2006,88:101903.
[17]Piao, X., Horikawa, T., Hanzawa, H., Machida, K. Characterization and luminescence properties of SrSiN:Eu phosphor for white light-emitting-diode illumination[J]. Applied Physics Letters.2006,88:161908.
[18]Wu, Z., Shi, J., Wang, J., Gong, M., Su, Q. A novel blue-emitting phosphor LiSrPO4:Eu2+ for white LEDs[J]. Journal of Solid State Chemistry.2006,179:2356-2360.
[19]Biswas, A., Friend, C, Prasad, P. Spontaneous reduction of Eu3+ ion in Al co-doped sol-gel silica matrix during densification[J]. Materials Letters.1999,39:227-231.
[20]Niida, H., Takahashi, M., Uchino, T., Yoko, T. Spontaneous reduction of europium ions below 250 C in organic Cinorganic hybrid low-melting phosphite glasses[J]. J. Mater. Res.2003, 18:2.
[21]Pei, Z., Zeng, Q., Su, Q. The application and a substitution defect model for Eu3+-→Eu2+ reduction in non-reducing atmospheres in borates containing BO4 anion groups[J]. Journal of Physics and Chemistry of Solids.2000,61:9-12.
[22]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[23]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[24]Pei, Z., Zeng, Q., Su, Q. A Study on the Mechanism of the Abnormal Reduction of Eu3+→ Eu2+ in Sr2B5O9Cl Prepared in Air at High Temperature[J]. Journal of Solid State Chemistry. 1999,145:212-215.
[25]Su, Q., Liang, H., Hu, T., Tao, Y., Liu, T. Preparation of divalent rare earth ions in air by aliovalent substitution and spectroscopic properties of Ln2+[J]. Journal of Alloys and Compounds.2002,344:132-136.
[26]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[27]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration. I. Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[28]Poort, S., Blokpoel, W., Blasse, G. Luminescence of Eu2+ in barium and strontium aluminate and gallate[J]. Chemistry of Materials.1995,7:1547-1551.
[29]H ppe, H., Lutz, H., Morys, P., Schnick, W., Seilmeier, A. Luminescence in Eu2+-doped Ba2Si5N8:fluorescence, thermoluminescence, and upconversion[J]. Journal of Physics and Chemistry of Solids.2000,61:2001-2006.
[30]Poort, S., Reijnhoudt, H., Van der Kuip, H., Blasse, G. Luminescence of Eu2+ in silicate host lattices with alkaline earth ions in a row[J]. Journal of Alloys and Compounds.1996, 241:75-81.
[31]Meijerink, A., Blasse, G. Luminescence properties of Eu2+-activated alkaline earth haloborates[J]. Journal of Luminescence.1989,43:283-289.
[32]H Is, J., Jungner, H., Lastusaari, M., Niittykoski, J. Persistent luminescence of Eu2+ doped alkaline earth aluminates, MAl2O4:Eu2+[J]. Journal of Alloys and Compounds.2001, 323:326-330.
[33]Lin, Y., Tang, Z., Zhang, Z. Preparation of long-afterglow Sr4Al14O25-based luminescent material and its optical properties[J]. Materials Letters.2001,51:14-18.
[34]Lin, Y., Tang, Z., Zhang, Z., Wang, X., Zhang, J. Preparation of a new long afterglow blue-emitting Sr2MgSi2O7-based photoluminescent phosphor[J]. Journal of Materials Science Letters.2001,20:1505-1506.
[35]Liu, B., Shi, C., Yin, M., Dong, L., Xiao, Z. The trap states in the Sr2MgSi207 and (Sr, Ca) MgSi2O7 long afterglow phosphor activated by Eu2+ and Dy3+[J]. Journal of Alloys and Compounds.2005,387:65-69.
[36]Lin, Y, Zhang, Z., Zhang, F., Tang, Z., Chen, Q. Preparation of the ultrafine SrAl2O4:Eu, Dy needle-like phosphor and its optical properties[J]. Materials Chemistry and Physics.2000, 65:103-106.
[37]Jia, D., Wang, X., Van der Kolk, E., Yen, W. Site dependent thermoluminescence of long persistent phosphorescence of BaAl2O4:Ce3+[J]. Optics Communications.2002,204:247-251.
[38]Li, Y, Wang, Y, Xu, X., Gong, Y Effects of non-stoichiometry on crystallinity, photoluminescence and afterglow properties of Sr2MgSi2O7:Eu2+, Dy3+ phosphors[J]. Journal of Luminescence.2009,129:1230-1234.
[39]Zhi-ping, Y, Wen-jie, W., Zhi, G., Sheng-chao, Z. Study on Two Kinds of Electron Trapped of Red Long-afterglow Phosphors CaTiO3: Pr3+[J]. Journal of Optoelectronics, laser.2004.
[40]Aitasalo, T., Deren, P., Holsa, J., Jungner, H., Krupa, J. C., Lastusaari, M., Legendziewicz, J., Niittykoski, J., Strek, W. Persistent luminescence phenomena in materials doped with rare earth ions[J]. Journal of Solid State Chemistry.171:114-122.
[41]Yamaga, M., Tanii, Y, Kodama, N., Takahashi, T., Honda, M. Mechanism of long-lasting phosphorescence process of Ce3+-doped Ca2Al2SiO7 melilite crystals[J]. Physical review B. Condensed matter and materials physics.2002,65:235108-235101.
[42]Yamaga, M., Masui, Y, Sakuta, S., Kodama, N., Kaminaga, K. Radiative and nonradiative decay processes responsible for long-lasting phosphorescence of Eu2+-doped barium silicates[J]. Physical Review B.2005,71:205102.
[43]Stevels, A. Ce Luminescence in Hexagonal Aluminates Containing Large Divalent or Trivalent Cations[J]. Journal of the Electrochemical Society.1978,125:588.
[44]Combes, C., Dorenbos, P., Van Eijk, C., Pedrini, C., Den Hartog, H., Gesland, J., Rodnyi, P. Optical and scintillation properties of Ce3+ doped LiYF4 and LiLuF4 crystals[J]. Journal of Luminescence.1997,71:65-70.
[45]Zhou, Y, Lin, J., Yu, M., Wang, S., Zhang, H. Synthesis-dependent luminescence properties of Y3A15O12:Re3+(Re= Ce, Sm, Tb) phosphors[J]. Materials Letters.2002,56:628-636.
[46]Zych, E., Brecher, C., Wojtowicz, A., Lingertat, H. Luminescence properties of Ce-activated YAG optical ceramic scintillator materials[J]. Journal of Luminescence.1997,75:193-203.
[47]Lammers, M., Blasse, G. Luminescence of Tb-and Ce-Activated Rare Earth Silicates[J]. Journal of the Electrochemical Society.1987,134:2068.
[48]Meyssamy, H., Riwotzki, K., Kornowski, A., Naused, S., Haase, M. Wet-chemical synthesis of doped colloidal nanomaterials:particles and fibers of LaPO4:Eu, LaPO4:Ce, and LaPO4: Ce,Tb[J]. Advanced Materials.1999,11:840-844.
[49]Xie, R. J., Mitomo, M., Uheda, K., Xu, F. F., Akimune, Y. Preparation and luminescence spectra of calcium-and rare-earth (R= Eu, Tb, and Pr)-codoped a-SiAlON ceramics[J]. Journal of the American Ceramic Society.2002,85:1229-1234.
[50]Reisfeld, R., Greenberg, E., Velapoldi, R., Barnett, B. Luminescence quantum efficiency of Gd and Tb in borate glasses and the mechanism of energy transfer between them[J]. The Journal of Chemical Physics.1972,56:1698.
[51]Seo, S. Y., Shin, J. H. Enhancement of the green, visible Tb luminescence from Tb-doped silicon-rich silicon oxide by C co-doping[J]. Applied Physics Letters.2004,84:4379.
[52]Kang, Y. C., Lenggoro, I. W., Okuyama, K., Park, S. B. Luminescence characteristics of Y2 SiO5:Tb phosphor particles directly prepared by the spray pyrolysis method[J]. Journal of the Electrochemical Society.1999,146:1227-1230.
[53]Quici, S., Cavazzini, M., Marzanni, G., Accorsi, G., Armaroli, N., Ventura, B., Barigelletti, F. Visible and near-infrared intense luminescence from water-soluble lanthanide [Tb, Eu, Sm, Dy, Pr, Ho, Yb, Nd, Er] complexes[J]. Inorg. Chem.2005,44:529-537.
[1]Garlick, G., Gibson, A. The electron trap mechanism of luminescence in sulphide and silicate phosphors[J]. Proceedings of the Physical Society.1948,60:574.
[2]Morimo, R., Mochinaga, R., Nakamura, K. Preparation and characterization of a manganese activated zinc silicate phosphor by fume pyrolysis of an alkoxide solution [Zn2Si04:Mn][J]. Materials Research Bulletin.1994,29:751-757.
[3]Kang, H. S., Hong, S. K., Kang, Y. C., Jung, K. Y., Shul, Y. G., Park, S. B. The enhancement of photoluminescence characteristics of Eu-doped barium strontium silicate phosphor particles by co-doping materials[J]. Journal of Alloys and Compounds.2005,402:246-250.
[4]Akella, A., Keszler, D. A. Sr2LiSi04F:Synthesis, structure, and Eu2+ luminescence[J]. Chemistry of Materials.1995,7:1299-1302.
[5]Kim, J. S., Jeon, P. E., Park, Y. H., Choi, J. C., Park, H. L. Color tunability and stability of silicate phosphor for UV-pumped white LEDs[J]. Journal of the Electrochemical Society. 2005,152:H29.
[6]Akella, A., Keszler, D. A. The new orthosilicate Li4SrCa(Si04)2:structure and Eu2+ luminescence[J]. Inorganic Chemistry.1995,34:1308-1310.
[7]Denton, A., Ashcroft, N. Vegard's law[J]. Physical Review A.1991,43:3161-3164.
[8]Yashima, M., Ishizawa, N., Yoshimura, M. Application of an Ion-Packing Model Based on Defect Clusters to Zirconia Solid Solutions:II, Applicability of Vegard's Law[J]. Journal of the American Ceramic Society.1992,75:1550-1557.
[9]Bis, R., Dixon, J. Applicability of Vegard's Law to the PbSnTe Alloy System[J]. Journal of Applied Physics.1969,40:1918.
[10]Yamashita, N. Luminescence Centers of Ca (S:Se) Phosphors Activated with Impurity Ions Having s2 Configuration Ca (S:Se):Sb3+ Phosphors[J]. Journal of the Physical Society of Japan.1973,35.
[11]Diaz, A., Keszler, D. A. Red, green, and blue Eu2+ luminescence in solid-state borates:A structure-property relationship[J]. Materials Research Bulletin.1996,31:147-151.
[12]Karthikeyani, A., Jagannathan, R. Eu2+ luminescence in stillwellite-type SrBPO5-a new potential X-ray storage phosphor[J]. Journal of Luminescence.2000,86:79-85.
[13]Lucas, F., Jaulmes, S., Quarton, M., Le Mercier, T., Guillen, F., Fouassier, C. Crystal Structure of SrAl2B2O7 and Eu2+ Luminescence[J]. Journal of Solid State Chemistry.2000, 150:404-409.
[14]Tang, Y. S., Hu, S. F., Lin, C. C., Bagkar, N. C., Liu, R. S. Thermally stable luminescence of KSrPO4:Eu phosphor for white light UV light-emitting diodes[J]. Applied Physics Letters. 2007,90:151108.
[15]Iwaya, M., Terao, S., Sano, T., Ukai, T., Nakamura, R., Kamiyama, S., Amano, H., Akasaki, I. Suppression of phase separation of AlGaN during lateral growth and fabrication of high-efficiency UV-LED on optimized AlGaN[J]. Journal of Crystal Growth.2002, 237:951-955.
[16]Diaz, A., Keszler, D. A. Eu2+ Luminescence in the Borates X2Z(BO3)2 (X= Ba, Sr; Z= Mg, Ca)[J]. Chem. Mater.1997,9:2071-2077.
[17]Akella, A., Keszler, D. A. Structure and Eu2+ luminescence of dibarium magnesium orthoborate[J]. Materials Research Bulletin.1995,30:105-111.
[18]Dexter, D., Schulman, J. H. Theory of concentration quenching in inorganic phosphors[J]. The Journal of Chemical Physics.1954,22:1063.
[19]Kim, Y. H., Shin, D. C., Kim, S. H., Ko, C. H., Yu, H. S., Chae, Y. S., Kwon, S. K. Novel blue emitting material with high color purity[J]. Advanced Materials.2001,13:1690-1693.
[20]Komeno, A., Uematsu, K., Toda, K., Sato, M. VUV properties of Eu-doped alkaline earth magnesium silicate[J]. Journal of Alloys and Compounds.2006,408:871-874.
[21]Zhang, Z., Wang, Y., Zhang, J., Hao, Y. Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation[J]. Materials Research Bulletin.2008,43:926-931.
[22]Zhang, Z., Wang, Y. UV-VUV Excitation Luminescence Properties of Eu-doped BaMSiO4 (M= Mg, Zn)[J]. Journal of the Electrochemical Society.2007,154:J62.
[23]Zhang, G., Qi, Z., Zhou, H., Fu, Y, Huo, T., Luo, X., Shi, C. Photoluminescence of (Eu2+ Dy3+) co-doped silicate long lasting phosphors[J]. Journal of Electron Spectroscopy and Related Phenomena.2005,144:861-863.
[24]Yamamoto, H., Mikami, M., Shimomura, Y, Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000,87:1079-1082.
[25]Vila, L. D., Gomes, L., Eyzaguirre, C., Rodriguez, E., Cesar, C., Barbosa, L. Time resolved luminescence in (Tm:Ho) doped tellurite glass[J]. Optical Materials.2005,27:1333-1339.
[26]Scholl, M. S., Trimmier, J. R. Luminescence of YAG:Tm, Tb[J]. Journal of the Electrochemical Society.1986,133:643.
[27]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[28]Tsang, W., Yu, W., Mak, C., Tsui, W., Wong, K., Hui, H. Evidence of the influence of phonon density on Tm upconversion luminescence in tellurite and germanate glasses[J]. Journal of Applied Physics.2002,91:1871.
[29]Macalik, L., Hanuza, J., Jaque, D., Garca Sol, J. Spectroscopic characterisation of the Tm3+ doped KLa (WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[30]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+(Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B 2009,80:085103.
[31]Dorenbos, P., Bos, A., Poolton, N. Carrier recombination processes and divalent lanthanide spectroscopy in YPO4:Ce3+; Ln3+(Ln= Sm, Dy, Tm)[J]. Physical Review B.2010,82:195127.
[32]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[33]苏锵.稀土化学[M].1993.
[34]Rao, R. Tm3+ activated lanthanum phosphate:a blue PDP phosphor[J]. Journal of Luminescence.2005,113:271-278.
[35]Bachmann, V., Ronda, C., Meijerink, A. Temperature quenching of yellow Ce3+ luminescence in YAG:Ce[J]. Chemistry of Materials.2009,21:2077-2084.
[36]Zych, E., Brecher, C., Glodo, J. Kinetics of cerium emission in a YAG:Ce single crystal:the role of traps[J]. Journal of Physics:Condensed Matter.2000,12:1947.
[37]Chang, C. K., Chen, T. M. Sr3B2O6:Ce3+, Eu2+:A potential single-phased white-emitting borate phosphor for ultraviolet light-emitting diodes[J]. Appl. Phys. Lett.2007,91:081902.
[38]Van Krevel, J., Hintzen, H., Metselaar, R., Meijerink, A. Long wavelength Ce3+ emission in Y-Si-ON materials[J]. Journal of Alloys and Compounds.1998,268:272-277.
[39]Yang, C., Pan, Y, Zhang, Q. Enhanced white light emission from Dy3+/Ce3+ codoped GdAl3 (BO3)4 phosphors by combustion synthesis[J]. Materials Science and Engineering:B.2007, 137:195-199.
[40]Gedam, S., Dhoble, S., Moharil, S. Eu2+ and Ce3+ emission in sulphate based phosphors[J]. Journal of Luminescence.2008,128:1-6.
[41]Liang, H., Shi, J., Su, Q., Zhang, S., Tao, Y. Spectroscopic properties of Ce3+ doped MBPO5 (M= Ca, Sr, Ba) under VUV excitation[J]. Materials Chemistry and Physics.2005, 92:180-184.
[42]Pidol, L., Kahn-Harari, A., Viana, B., Ferrand, B., Dorenbos, P., Haas, J. T. M., Eijk, C. W. E., Virey, E. Scintillation properties of Lu2Si2O7:Ce3+, a fast and efficient scintillator crystal[J]. Journal of Physics:Condensed Matter.2003,15:2091.
[43]李小侠.Eu3+，Tb3+离子在三种硼酸盐中的VUV-Vis范围的发光性质研究[兰州大学]2007.
[44]Lai, H., Bao, A., Yang, Y, Xu, W., Tao, Y, Yang, H. Preparation and luminescence property of Dy3+-doped YPO4 phosphors[J]. Journal of Luminescence.2008,128:521-524.
[45]Bhaskar Kumar, G., Buddhudu, S. Emission spectra of LiYNbO3:RE3+(=Sm3+or Dy3+) ceramic powders[J]. Physica B:Condensed Matter.2008,403:4164-4170.
[46]Xiu, Z., Yang, Z., Li, M., Liu, S., Zhang, H., Zhou, G. Synthesis, structural and luminescence properties of Dy3+-doped YPO4 nanocrystals[J]. Optical Materials.2006,29:431-434.
[47]Atone, M., Dhoble, S., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Sensitization of luminescence of CaSO4:Dy[J]. physica status solidi (a).1993,135:299-305.
[48]Shi, F., Meng, J., Ren, Y, Su, Q. Structure, luminescence and magnetic properties of AgLnW2O8 (Ln= Eu, Gd, Tb and Dy) compounds[J]. Journal of Physics and Chemistry of Solids.1998,59:105-110.
[49]Kuang, J., Liu, Y, Zhang, J. White-light-emitting long-lasting phosphorescence in Dy3+-doped SrSiO3[J]. Journal of Solid State Chemistry.2006,179:266-269.
[50]Ortega, F., Molina, P., Santiago, M., Spano, F., Lester, M., Caselli, E. Analysis of the glow curve of SrB4O7:Dy compounds employing the GOT model[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms.2006, 243:417-422.
[1]Lu, S., Zhang, J. The Luminescence of Nanoscale Y2Si2O7:Eu3+ Materials[J]. Journal of Nanoscience and Nanotechnology.2010,10:2152-2155.
[2]Marciniak, L., Hreniak, D., Dobrowolska, A., Zych, E. Size-dependent luminescence in Y2Si2O7 nanoparticles doped with Ce3+ ions[J]. Applied Physics A:Materials Science & Processing.2010,1:108.
[3]Li, Y., You, B., Zhao, W., Zhang, W., Yin, M. Synthesis and Luminescent Properties of Nano-scale Y2Si2O7:Re3+(Re= Eu, Tb) Phosphors via Sol-Gel Method[J]. Chinese Journal of Chemical Physics.2008,21:376.
[4]Saeki, S., Kaneko, J. H., Higuchi, M., Kawamura, S., Haruna, J., Fujita, F., Homma, A., Nishiyama, S., Ueda, S., Kurashige, K.; IEEE:2008; Vol.2, p 1426-1428.
[5]Li, Y, Wang, C. N., Wei, X. T., Zhao, J. B., Zhang, W. P., Yin, M. Synthesis and Luminescent Properties of Nanoscale Gd2Si2O7:Eu3+ Phosphors[J]. Journal of Nanoscience and Nanotechnology.2010,10:2219-2222.
[6]Yu, M., Lin, J., Fang, J. Silica Spheres Coated with YVO4:Eu3+ Layers via Sol-Gel Process:A Simple Method To Obtain Spherical Core-Shell Phosphors[J]. Chem. Mater.2005, 17:1783-1791.
[7]Meng, Q., Lin, J., Fu, L., Zhang, H., Wang, S., Zhou, Y. Sol-gel deposition of calcium silicate red-emitting luminescent films doped with Eu3+[J]. Journal of Materials Chemistry.2001, 11:3382-3386.
[8]Zhou, Y, Lin, J., Yu, M., Wang, S., Zhang, H. Synthesis-dependent luminescence properties of Y3Al5O12:Re3+(Re= Ce, Sm, Tb) phosphors[J]. Materials Letters.2002,56:628-636.
[9]Oshio, S., Matsuoka, T., Tanaka, S., Kobayashi, H. Mechanism of particle growth of a BaMgAl10O17:Eu2+ phosphor by firing with AlF3[J]. Journal of The Electrochemical Society. 1998,145.
[10]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[11]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14025:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[12]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[13]Combes, C., Dorenbos, P., Van Eijk, C., Pedrini, C., Den Hartog, H., Gesland, J., Rodnyi, P. Optical and scintillation properties of Ce3+ doped LiYF4 and LiLuF4 crystals[J]. Journal of Luminescence.1997,71:65-70.
[14]Zych, E., Brecher, C., Wojtowicz, A., Lingertat, H. Luminescence properties of Ce-activated YAG optical ceramic scintillator materials[J]. Journal of Luminescence.1997,75:193-203.
[15]Visser, R., Dorenbos, P., Eijk, C., Meijerink, A., Blasse, G., Hartog, H. Energy transfer processes involving different luminescence centres in BaF2:Ce[J]. Journal of Physics: Condensed Matter.1993,5:1659.
[16]Meyssamy, H., Riwotzki, K., Kornowski, A., Naused, S., Haase, M. Wet-chemical synthesis of doped colloidal nanomaterials:particles and fibers of LaPO4:Eu, LaPO4:Ce, and LaPO4: Ce,Tb[J]. Advanced Materials.1999,11:840-844.
[17]Plewa, J., Juestel, T.; Trans Tech Publ:2010; Vol.636, p 344-347.
[18]Shionoya, S., Yen, W. M. Phosphor handbook[M]CRC press New York,1999.
[19]Yamashita, T., Ohishi, Y. Cooperative energy transfer between Tb3+ and Yb3+ ions co-doped in borosilicate glass[J]. Journal of Non-Crystalline Solids.2008,354:1883-1890.
[20]Liao, J., Qiu, B., Wen, H., You, W. Photoluminescence green in microspheres of CaWO4: Tb3+processed in conventional hydrothermal[J]. Optical Materials.2009,31:1513-1516.
[21]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M]Springer-Verlag Berlin, 1977.
[22]苏锵.稀土化学[M].1993.
[23]Wang, D., Kodama, N. Visible quantum cutting through downconversion in GdPO4:Tb3+ and Sr3Gd (PO4)3:Tb3+[J]. Journal of Solid State Chemistry.2009,182:2219-2224.
[24]Robbins, D., Cockayne, B., Lent, B., Glasper, J. The mechanism of 5D3-5D4 cross-relaxation in Y3A15O12:Tb3+[J]. Solid State Communications.1976,20:673-676.
[25]Ostermayer Jr, F., Van Uitert, L. Cooperative Energy Transfer from Yb3+ to Tb3+ in YF3[J]. Physical Review B.1970,1:4208-4212.
[26]Zhang, J., Ning, J., Liu, X., Pan, Y, Huang, L. A novel synthesis of phase-pure ultrafine YAG: Tb phosphor with different Tb concentration[J]. Materials Letters.2003,57:3077-3081.
[27]Blasse, G. Energy Transfer Phenomena in the System (Y, Ce, Gd, Tb)F3[J]. physica status solidi(a).1982,73:205-208.
[28]Su, Y, Li, G. Generation of tunable wavelength lights in core-shell CaWO4 microspheres via co-doping with Na+ and Ln3+(Ln= Tb, Sm, Dy, Eu)[J]. Journal of Materials Chemistry.2009, 19:2316-2322.
[1]Atone, M., Dhoble, S., Moharil, S., Dhopte, S., Muthal, P., Kondawar, V. Sensitization of luminescence of CaSO4:Dy[J]. physica status solidi (a).1993,135:299-305.
[2]Liu, B., Shi, C., Qi, Z. Potential white-light long-lasting phosphor:Dy-doped aluminate[J]. Applied physics letters.2005,86:191111.
[3]Liu, Y., Lei, B., Shi, C. Luminescent Properties of a White Afterglow Phosphor CdSiO3: Dy3+[J]. Chem. Mater.2005,17:2108-2113.
[4]Kuang, J., Liu, Y. White-emitting Long-lasting Phosphor Sr2SiO4: Dy3+[J]. Chemistry Letters. 2005,34:598-599.
[5]Jayasimhadri, M., Ratnam, B., Jang, K., Lee, H. S., Chen, B., Yi, S. S., Jeong, J. H., Moorthy, L. R. Greenish-Yellow Emission from Dy3+ Doped Y2O3 Nanophosphors[J]. Journal of the American Ceramic Society.2010,93:494-499.
[6]Maruyama, N., Honma, T., Komatsu, T. Enhanced quantum yield of yellow photoluminescence of Dy3+ ions in nonlinear optical Ba2TiSi208 nanocrystals formed in glass[J]. Journal of Solid State Chemistry.2009,182:246-252.
[7]Lakshminarayana, G, Yang, H., Qiu, J. White light emission from Tm3+/Dy3+ co-doped oxyfluoride germanate glasses under UV light excitation[J]. Journal of Solid State Chemistry. 2009,182:669-676.
[8]Zhang, H., Fu, X., Niu, S., Sun, G., Xin, Q. Photoluminescence of nanocrystalline YVO4:TmxDy1-x prepared by a modified Pechini method[J]. Materials Letters.2007, 61:308-311.
[9]Liu, S., Zhao, G., Lin, X., Ying, H., Liu, J., Wang, J., Han, G. White luminescence of Tm-Dy ions co-doped aluminoborosilicate glasses under UV light excitation[J]. Journal of Solid State Chemistry.2008,181:2725-2730.
[10]Iwahara, H., Asakura, Y, Katahira, K., Tanaka, M. Prospect of hydrogen technology using proton-conducting ceramics[J]. Solid State Ionics.2004,168:299-310.
[11]Zhang, H., Fu, X., Niu, S., Xin, Q. Blue luminescence of nanocrystalline CaZrO3:Tm phosphors synthesized by a modified Pechini sol-gel method[J]. Journal of Luminescence. 2008,128:1348-1352.
[12]Zhang, H., Fu, X., Niu, S., Xin, Q. Synthesis and photoluminescence properties of Eu3+-doped AZrO3 (A=Ca, Sr, Ba) perovskite[J]. Journal of Alloys and Compounds.2008, 459:103-106.
[13]Liu, Z., Liu, Y, Zhang, J., Rong, J., Huang, L., Yuan, D. Long afterglow in Pr3+ and Li+ co-doped CaZrO3[J]. Optics Communications.2005,251:388-392.
[14]Shimizu, Y, Sakagami, S., Goto, K., Nakachi, Y., Ueda, K. Tricolor luminescence in rare earth doped CaZrO3 perovskite oxides[J]. Materials Science and Engineering:B.2009, 161:100-103.
[15]Gon alves, M., Cavalcante, L., Sczancoski, J., Espinosa, J., Pizani, P., Longo, E., Rosa, I. (Sr, Tm) ZrO3 powders prepared by the polymeric precursor method:Synthesis, optical properties and morphological characteristics[J]. Optical Materials.2009,31:1134-1143.
[16]Peng, M., Pei, Z., Hong, G, Su, Q. Study on the reduction of Eu3+→Eu2+ in Sr4Al14O25:Eu prepared in air atmosphere[J]. Chemical Physics Letters.2003,371:1-6.
[17]Peng, M., Pei, Z., Hong, G., Su, Q. The reduction of Eu3+ to Eu2+ in BaMgSiO4:Eu prepared in air and the luminescence of BaMgSiO4:Eu2+ phosphor[J]. Journal of Materials Chemistry. 2003,13:1202-1205.
[18]Koopmans, H., Van De Velde, G, Gellings, P. Powder neutron diffraction study of the perovskites CaTiO3 and CaZrO3[J]. Acta Crystallographica Section C:Crystal Structure Communications.1983,39:1323-1325.
[19]Etsell, T., Flengas, S. N. Electrical properties of solid oxide electrolytes[J]. Chemical Reviews.1970,70:339-376.
[20]Denton, A., Ashcroft, N. Vegard's law[J]. Physical Review A.1991,43:3161-3164.
[21]Kuo, Y. K., Liou, B. T., Yen, S. H., Chu, H. Y. Vegard's law deviation in lattice constant and band gap bowing parameter of zincblende InxGa1-xN[J]. Optics Communications.2004, 237:363-369.
[22]Bis, R., Dixon, J. Applicability of Vegard's Law to the PbSnTe Alloy System[J]. Journal of Applied Physics.1969,40:1918.
[23]Peng, T., Huajun, L., Yang, H., Yan, C. Synthesis of SrAl2O4:Eu, Dy phosphor nanometer powders by sol-gel processes and its optical properties[J]. Materials Chemistry and Physics. 2004,85:68-72.
[24]Srivastava, J., Supe, S. Gamma radiation induced changes in the glow curve of CaSO4:Dy tld phosphor[J]. Radiation Effects and Defects in Solids.1979,45:13-18.
[25]Chandra, B., Bhatt, R. Effect of dysprosium concentration on the TL characteristics of CaSO4: Dy phosphor[J]. Nuclear Instruments and Methods.1979,164:571-577.
[26]Li, J., Hao, J., Zhang, C., Tang, Q., Zhang, Y, Su, Q., Wang, S. Thermoluminescence characteristics of BaB4O7:Dy phosphor[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms.2004,222:577-582.
[27]Nakashima, K., Takami, M., Ohta, M., Yasue, T., Yamauchi, J. Thermoluminescence mechanism of dysprosium-doped β-tricalcium phosphate phosphor[J]. Journal of Luminescence.2005,111:113-120.
[28]Huang, J., Zhou, L., Lan, Y, Gong, F., Li, Q., Sun, J. Synthesis and luminescence properties of the red phosphor CaZrO3:Eu3+ for white light-emitting diode application[J]. Central European Journal of Physics.2010,1-5.
[29]Nazarov, M., Jeon, D., Kang, J., Popovici, E. J., Muresan, L. E., Zamoryanskaya, M., Tsukerblat, B. Luminescence properties of europium-terbium double activated calcium tungstate phosphor[J]. Solid state communications.2004,131:307-311.
[30]Blasse, G., Grabmaier, B. C. Luminescent materials[M]Springer-Verlag Berlin,1994.
[31]Dexter, D. A theory of sensitized luminescence in solids[J]. The Journal of Chemical Physics. 1953,21:836.
[32]Blasse, G. Energy transfer in oxidic phosphors[J]. Physics Letters A.1968,28:444-445.
[33]Reisfeld, R., J rgensen, C. Lasers and excited states of rare earths[M] Springer-Verlag Berlin, 1977.
[34]苏锵.稀土化学[M].1993.
[35]Lu, Y, Dai, Y, Yang, Y, Wang, J., Dong, A., Sun, B. Anisotropy of thermal and spectral characteristics in Tm:YAP laser crystals[J]. Journal of Alloys and Compounds.2008, 453:482-486.
[36]True, M., Chen, Y., Kirm, M., Vielhauer, S., Zimmerer, G. VUV spectroscopy of pure and Tm3+-doped LiCaAlF6 crystals[J]. Journal of Luminescence.2007,124:279-285.
[37]Yan, B., Su, X. Q. In situ co-precipitation synthesis and photoluminescence of YxGd1-xVO4: Tm3+ microcrystalline phosphors by hybrid precursors[J]. Optical Materials.2007, 29:1866-1870.
[38]Macalik, L., Hanuza, J., Jaque, D., Garcia Sole, J. Spectroscopic characterisation of the Tm3+ doped KLa(WO4)2 single crystals[J]. Optical Materials.2006,28:980-987.
[39]Krumpel, A. H., Bos, A. J. J., Bessire, A., Van der Kolk, E., Dorenbos, P. Controlled electron and hole trapping in YPO4:Ce3+, Ln3+ and LuPO4:Ce3+, Ln3+(Ln= Sm, Dy, Ho, Er, Tm)[J]. Physical Review B Phys Rev B.2009,80:085103.
[40]Yang, W. J., Chen, T. M. White-light generation and energy transfer in SrZn (PO4):Eu, Mn phosphor for ultraviolet light-emitting diodes[J]. Applied physics letters.2006,88:101903.
[41]Tan, Y, Shi, C. Ce3+→-Eu2+ energy transfer in BaLiF3 phosphor[J]. Journal of Physics and Chemistry of solids.1999,60:1805-1810.
[42]Yamamoto, H., Mikami, M., Shimomura, Y., Oguri, Y. Host-to-activator energy transfer in a new blue-emitting phosphor SrHfO3:Tm3+[J]. Journal of Luminescence.2000,87:1079-1082.
[43]Wegh, R. T., Donker, H., Oskam, K. D., Meijerink, A. Visible quantum cutting in LiGdF4: Eu3+ through downconversion[J]. Science.1999,283:663.
[44]Strk, W. Cooperative energy transfer[J]. Physics Letters A.1977,62:315-316.
[45]Martin, I., Yanes, A., Mendez-Ramos, J., Torres, M., Rodriguez, V. Cooperative energy transfer in Yb-Tb codoped silica sol-gel glasses[J]. Journal of Applied Physics.2001,89:2520.