Fenton试剂高级氧化法处理丙二醇废水的研究
|
摘要
论文首先采用均相Fenton试剂对丙二醇(PG)废水进行处理。H202和FeSO4采用滴加的方式加入反应器,分别考察H202与PG摩尔比、Fe2+与PG摩尔比、H202和FeSO4的滴加时间、温度、pH、滴加后的反应时间等因素对PG降解速率、PG去除率和COD去除率的影响。建立了拟一级动力学模型,计算得到Fenton反应条件下的拟一级动力学速率常数和本征反应速率常数。
然后采用活性炭吸附法对不同浓度的PG废水进行处理。实验中用到的活性炭为MCC2004和MCC2005,分别考察温度、PG初始浓度、活性炭加入量三个因素对PG的吸附性能的影响,建立其动力学、热力学模型,并进行其吸附机理分析。
选取不同的改性剂对活性炭进行改性处理。利用Beohm滴定法测定改性前后活性炭表面官能团的含量,采用N2物理吸附法测定改性前后活性炭的结构特性,考察改性前后活性炭对PG吸附性能的影响,并分析PG的性质、活性炭的结构特性、活性炭吸附能力三者之间的联系。
最后利用Fe/C-Fenton试剂法对PG废水进行处理,H2O2采用滴加的方式加入到反应器中,分别考察Fe/C催化剂浓度、H202加入量、滴加时间、温度四个因素对PG处理效果的影响。
In this paper, propylene glycol (PG) was treated by continuously adding two solutions of ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2). The effect of different operational variables, such as the molar ratio of H2O2 to PG, the molar ratio of Fe2+ to PG, the dropping time of H2O2 and Fe2+, reaction time after dropping, temperature, and initial pH were investigated, respectively. In this study, HO·concentration was assumed to remain constant in the procedure and pseudo-first-order model was established which involved the concentration of Fe2+, H2O2 and PG. The apparent rate constant kap and the intrinsic reaction rate constant of HO·with PG under optimal conditions were calcaulated, respectively.
Then the adsorption capacities of MCC2004 and MCC2005 for PG wastewater were evaluated, respectively. The effect of different operational variables, such as initial PG concentration, temperarure, and activated carbon concentration were investigated, respectively. The adsorption data were processed to study the adsorption isotherms, kinetics, thermodynamics, and mechanism of PG onto the MCC2004 and MCC2005, respectively.
We investigated the influence of activated carbon modified by HNO3, H2O2, NaOH, and NH3·H2O on the adsorption of PG onto MCC2004 and MCC2005, respectively. The physical characteristics of original and modified carbons were determined by nitrogen adsorption isotherms, respectively. The Boehm Method was applied in order to estimate the content of surface functional groups. The relationship among the properties of PG, structural characteristics of activated carbon, and adsorption capacity were analyzed for PG adsorption.
At last, PG wastewater was treated by heterogeneous Fenton reaction using 5%Fe/C catalyst. The effect of different operational variables, such as the molar ratio of H2O2 to PG, the concentration of Fe/C catalyst, the dropping time of H2O2, and temperature were investigated, respectively.
然后采用活性炭吸附法对不同浓度的PG废水进行处理。实验中用到的活性炭为MCC2004和MCC2005,分别考察温度、PG初始浓度、活性炭加入量三个因素对PG的吸附性能的影响,建立其动力学、热力学模型,并进行其吸附机理分析。
选取不同的改性剂对活性炭进行改性处理。利用Beohm滴定法测定改性前后活性炭表面官能团的含量,采用N2物理吸附法测定改性前后活性炭的结构特性,考察改性前后活性炭对PG吸附性能的影响,并分析PG的性质、活性炭的结构特性、活性炭吸附能力三者之间的联系。
最后利用Fe/C-Fenton试剂法对PG废水进行处理,H2O2采用滴加的方式加入到反应器中,分别考察Fe/C催化剂浓度、H202加入量、滴加时间、温度四个因素对PG处理效果的影响。
In this paper, propylene glycol (PG) was treated by continuously adding two solutions of ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2). The effect of different operational variables, such as the molar ratio of H2O2 to PG, the molar ratio of Fe2+ to PG, the dropping time of H2O2 and Fe2+, reaction time after dropping, temperature, and initial pH were investigated, respectively. In this study, HO·concentration was assumed to remain constant in the procedure and pseudo-first-order model was established which involved the concentration of Fe2+, H2O2 and PG. The apparent rate constant kap and the intrinsic reaction rate constant of HO·with PG under optimal conditions were calcaulated, respectively.
Then the adsorption capacities of MCC2004 and MCC2005 for PG wastewater were evaluated, respectively. The effect of different operational variables, such as initial PG concentration, temperarure, and activated carbon concentration were investigated, respectively. The adsorption data were processed to study the adsorption isotherms, kinetics, thermodynamics, and mechanism of PG onto the MCC2004 and MCC2005, respectively.
We investigated the influence of activated carbon modified by HNO3, H2O2, NaOH, and NH3·H2O on the adsorption of PG onto MCC2004 and MCC2005, respectively. The physical characteristics of original and modified carbons were determined by nitrogen adsorption isotherms, respectively. The Boehm Method was applied in order to estimate the content of surface functional groups. The relationship among the properties of PG, structural characteristics of activated carbon, and adsorption capacity were analyzed for PG adsorption.
At last, PG wastewater was treated by heterogeneous Fenton reaction using 5%Fe/C catalyst. The effect of different operational variables, such as the molar ratio of H2O2 to PG, the concentration of Fe/C catalyst, the dropping time of H2O2, and temperature were investigated, respectively.
引文
[1]雷川华,吴运卿.我国水资源现状,问题与对策研究.节水灌溉[J].2007,(4)：41-43.
[2]Jank, B. E., Guo, H. M., Cairns, V. W. Activated sludge treatment of airport wastewater containing aircraft de-icing fluids. Water Research[J].1974,8 (11):875-880.
[3]Veltman, S., Schoenberg, T., Switzenbaum, M. S. Alcohol and acid formation during the anaerobic decomposition of propylene glycol under methanogenic conditions. Biodegradation[J].1998,9 (2):113-118.
[4]Bielefeldt, A. R., Illangasekare, T., Uttecht, M., LaPlante, R. Biodegradation of propylene glycol and associated hydrodynamic effects in sand. Water Research[J].2002,36 (7):1707-1714.
[5]Haines, J. R., Alexander, M. Microbial degradation of polyethylene glycols. Applied and Environmental Microbiology [J].1975,29 (5):621-625.
[6]高德霖.活性炭的孔隙结构与吸附性能.化学工业与工程[J].1990,7(003)：48-54.
[7]范拴喜,江元汝.Fenton法的研究现状与进展.现代化工[J].2007,27(z1)：104-107.
[8]Chen, F., Li, Y., Guo, L., Zhang, J. Strategies comparison of eliminating the passivation of non-aromatic intermediates in degradation of Orange Ⅱ by Fe3+/H2O2. Journal of Hazardous materials[J].2009,169 (1-3):711-718.
[9]孙根行,刘梅.非均相Fenton反应处理染料废水.印染[J].2008,34(015)：44-46.
[10]Ramirez, J. H., Duarte, F. M., Martins, F. G., Costa, C. A., Madeira, L. M. Modelling of the synthetic dye Orange Ⅱ degradation using Fenton's reagent:From batch to continuous reactor operation. Chemical Engineering Journal[J].2009,148 (2-3):394-404.
[11]Lee, J.-W., Choi, S.-P., Thiruvenkatachari, R., Shim, W.-G., Moon, H. Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes. Water Research[J].2006,40 (3): 435-444.
[12]王秀芳.高比表面积活性炭的制备、表征及应用[D]：[硕士学位论文].广州：华南理工大学,2006.
[13]解强,胡维淳,张玉柱,许红球.对我国活性炭工业发展的思考与建议.煤炭加工与综合利用[J].2003,(005)：36-39.
[14]魏娜,赵乃勤,贾威.活性炭的制备及应用新进展.材料科学与工程学报[J].2003,21(005)：777-780.
[15]范延臻,王宝贞.活性炭表面化学.煤炭转化[J].2000,23(4)：26-30.
[16]黄伟,贾艳秋,孙盛凯.活性炭及其改性研究进展.气体净化[J].2006,6(006)：24-29.
[17]韩严和,全燮,薛大明,赵雅之,陈硕.活性炭改性研究进展.环境污染治理技术与设备[J].2003,4(001)：33-37.
[18]Pereira, M. F. R., Soares, S. F.,orf o, J. J. M., Figueiredo, J. L. Adsorption of dyes on activated carbons:influence of surface chemical groups. Carbon[J].2003,41 (4):811-821.
[19]胡巧开,杜冬云.含铁废水的吸附处理研究.煤炭科学技术[J].2004,32(012)：55-57.
[20]刘月蓉.氢氧化钾法制备竹活性炭.生物质化学工程[J].2006,40(004)：38-40.
[21]刘慧英,冯霞.以果物核壳为原料制备活性炭及其改性研究.宁夏大学学报：自然科学版[J].1996,17(002)：32-35.
[22]高尚愚,安部郁夫.表面改性活性炭对苯醛及苯磺酸吸附的研究.林产化学与工业[J].1994,14(003)：29-34.
[23]荣海琴,郑经堂.改性PAN-ACFs对甲醛吸附性能的初步研究.新型炭材料[J].2001,16(001)：44-48.
[24]Mangun, C. L., Benak, K. R., Economy, J., Foster, K. L. Surface chemistry, pore sizes and adsorption properties of activated carbon fibers and precursors treated with ammonia. Carbon[J].2001,39 (12):1809-1820.
[25]Figueiredo, J. L., Pereira, M. F. R., Freitas, M. M. A., Orfao, J. J. M. Modification of the surface chemistry of activated carbons. Carbon[J].1999,37 (9):1379-1389.
[26]王宝贞,范延臻,孙治荣.改性GAC及ACF去除水中有机污染物的静态研究.哈尔滨建筑大学学报[J].2000,33(004)：46-49.
[27]冯平,彭华平,孙振兴,蔡忠,张战利,周会勇,李文军,周少奇.高效微生物-A/O工艺处理化工综合废水.中国给水排水[J].2010,26(18)：102-105.
[28]朱文芳,李伟光,吕炳南,何华.微生物固定化处理低浓度甲醇废水试验研究.哈尔滨工业大学学报[J].2004,36(008)：1008-1010.
[29]李亚峰,苏永彬.混凝沉淀法处理煤泥水的试验研究.安全与环境学报[J].2002,2(001)：11-13.
[30]杨联京.碱渣中和法在灰水回用中的应用.中国给水排水[J].1995,11(004)：8-11.
[31]陈秀芳.离子交换法在废水处理中的应用.科技情报开发与经济[J].2004,14(007)：148-149.
[32]de Souza, D. R., Duarte, E. T. F. M., de Souza Girardi, G., Velani, V., da Hora Machado, A. E., Sattler, C., de Oliveira, L., de Miranda, J. A. Study of kinetic parameters related to the degradation of an industrial effluent using Fenton-like reactions. Journal of Photochemistry and Photobiology A:Chemistry[J].2006,179 (3):269-275.
[33]Rosenfeldt, E. J., Linden, K. G., Canonica, S., von Gunten, U. Comparison of the efficiency of OH radical formation during ozonation and the advanced oxidation processes O3/H2O2 and UV/H2O2. Water Research[J].2006,40 (20):3695-3704.
[34]Kolaczkowski, S. T., Plucinski, P., Beltran, F. J., Rivas, F. J., McLurgh, D. B. Wet air oxidation:a review of process technologies and aspects in reactor design. Chemical Engineering Journal[J].1999,73 (2):143-160.
[35]Lee, J.-C., Kim, M.-S., Kim, B.-W. Removal of paraquat dissolved in a photoreactor with TiO2 immobilized on the glass-tubes of UV lamps. Water Research[J].2002,36 (7): 1776-1782.
[36]Ruppert, G, Bauer, R., Heisler, G. UV-03, UV-H2O2, UV-TiO2 and the photo-Fenton reaction-comparison of advanced oxidation processes for wastewater treatment. Chemosphere[J].1994,28(8):1447-1454.
[37]Zhu, W., Bin, Y., Li, Z., Jiang, Z., Yin, T. Application of catalytic wet air oxidation for the treatment of H-acid manufacturing process wastewater. Water Research[J].2002,36 (8): 1947-1954.
[38]C zares, P., Hern dez-Ortega, M., Rodrigo, M. A., Barrera-Dz, C. E., Roa-Morales, G, Sz, C. A comparison between Conductive-Diamond Electrochemical Oxidation and other Advanced Oxidation Processes for the treatment of synthetic melanoidins. Journal of Hazardous materials[J].2009,164 (1):120-125.
[39]郭楠,李玉平.湿式空气氧化法处理DNT生产废水的影响因素及反应机理.火炸药学报[J]33(3)：25-29.
[40]李红亚.湿式空气氧化法处理模拟染料废水的研究[D]：[硕士学位论文].西安：西北大学,2008.
[41]崔艳萍,杨昌柱.电化学氧化法在难降解有机废水处理中的应用.工业安全与环保[J].2004,30(006)：12-14.
[42]Shaw, R. W., Dahmen, N. Destruction of toxic organic materials using supercritical water oxidation:current state of the technology. NATO ASI SERIES E APPLIED SCIENCES[J]. 2000,36(6):425-438.
[43]Erkonak, H., S, O., Akg, M. Treatment of olive mill wastewater by supercritical water oxidation. The Journal of Supercritical Fluids[J].2008,46 (2):142-148.
[44]高铁,钱朝勇.Ti02光催化氧化水中有机污染物进展.工业水处理[J].2000,20(004)：10-13.
[45]Xu, H., Zhang, D., Xu, W. Monitoring of decolorization kinetics of Reactive Brilliant Blue X-BR by online spectrophotometric method in Fenton oxidation process. Journal of Hazardous materials[J].2008,158 (2-3):445-453.
[46]Kang, N., Lee, D. S., Yoon, J. Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere[J].2002,47 (9):915-924.
[47]Burbano, A. A., Dionysiou, D. D., Suidan, M. T., Richardson, T. L. Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Research[J].2005, 39(1):107-118.
[48]Gallard, H., De Laat, J. Kinetic modelling of Fe (III)/H2O2 oxidation reactions in dilute aqueous solution using atrazine as a model organic compound. Water Research[J].2000,34 (12):3107-3116.
[49]Haag, W. R., Yao, C. C. D. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants. Environmental Science & Technology [J].1992,26 (5): 1005-1013.
[50]Lucas, M. S., Peres, J. A. Removal of COD from olive mill wastewater by Fenton's reagent:Kinetic study. Journal of Hazardous materials[J].2009,1253-1259.
[51]Kang, S. F., Liao, C. H., Chen, M. C. Pre-oxidation and coagulation of textile wastewater by the Fenton process. Chemosphere[J].2002,46 (6):923-928.
[52]Guedes, A., Madeira, L. M. P., Boaventura, R. A. R., Costa, C. A. V. Fenton oxidation of cork cooking wastewater-overall kinetic analysis. Water Research[J].2003,37 (13): 3061-3069.
[53]Meri, S., Kaptan, D., mez, T. Color and COD removal from wastewater containing Reactive Black 5 using Fenton's oxidation process. Chemosphere[J].2004,54 (3):435-441.
[54]Deng, Y. Physical and oxidative removal of organics during Fenton treatment of mature municipal landfill leachate. Journal of Hazardous materials[J].2007,146 (1-2):334-340.
[55]Primo, O., Rivero, M. J., Ortiz, I. Photo-Fenton process as an efficient alternative to the treatment of landfill leachates. Journal of Hazardous materials[J].2008,153 (1-2):834-842.
[56]Zhang, H., Choi, H. J., Canazo, P., Huang, C.-P. Multivariate approach to the Fenton process for the treatment of landfill leachate. Journal of Hazardous materials[J].2009,161 (2-3):1306-1312.
[57]Zhu, S. G, Zhang, N., Chen, X., Cao, G P., Yuan, W. K. The mechanism and kinetics for the selective oxidation of glyoxal to produce glyoxalic acid by Fenton's reagent. Reaction Kinetics, Mechanisms and Catalysis[J].99 (2):325-333.
[58]Walling, C., Amarnath, K. Oxidation of mandelic acid by Fenton's reagent. Journal of the American Chemical Society[J].1982,104 (5):1185-1189.
[59]Grasselli, R. K., Oyama, S. T., Gaffney, A. M., Lyons, J. E.; Elsevier Science:1997, p 527.
[60]Hermosilla, D., Cortijo, M., Huang, C. P. Optimizing the treatment of landfill leachate by conventional Fenton and photo-Fenton processes. Science of the Total Environment[J].2009, 407 (11):3473-3481.
[61]Ramirez, J. H., Duarte, F. M., Martins, F. G., Costa, C. A., Madeira, L. M. Modelling of the synthetic dye Orange II degradation using Fenton's reagent:From batch to continuous reactor operation. Chemical Engineering Journal.[J].2009,148 (2-3):394-404.
[62]包木太,王娜,陈庆国,郭省学,李希明.Fenton法的氧化机理及在废水处理中的应 用进展.CHEMICAL INDUSTRY AND ENGINEERING PROGRESS[J].2008,27 (5): 660-665.
[63]Quici, N., Morgada, M. E., Gettar, R. T., Bolte, M., Litter, M. I. Photocatalytic degradation of citric acid under different conditions:TiO2 heterogeneous photocatalysis against homogeneous photolytic processes promoted by Fe (III) and H2O2. Applied Catalysis B:Environmental[J].2007,71 (3-4):117-124.
[64]Badawy, M. I., Ghaly, M. Y., Gad-Allah, T. A. Advanced oxidation processes for the removal of organophosphorus pesticides from wastewater. Desalination[J].2006,194 (1-3): 166-175.
[65]De Laat, J., Gallard, H., Ancelin, S., Legube, B. Comparative study of the oxidation of atrazine and acetone by H2O2/UV, Fe (III)/UV, Fe (III)/H2O2/UV and Fe (II) or Fe (III)/H2O2. Chemosphere[J].1999,39 (15):2693-2706.
[66]刘杨先,张军,盛昌栋,张永春,赵亮.非均相Photo-Fenton反应中负载型光催化剂研究进展.现代化工[J].2010,(004)：26-30.
[67]Liou, R. M., Chen, S. H., Hung, M. Y, Hsu, C. S., Lai, J. Y. Fe (III) supported on resin as effective catalyst for the heterogeneous oxidation of phenol in aqueous solution. Chemosphere[J].2005,59 (1):117-125.
[68]Kusic, H., Koprivanac, N., Bozic, A. L., Selanec, I. Photo-assisted Fenton type processes for the degradation of phenol:a kinetic study. Journal of Hazardous materials[J].2006,136 (3):632-644.
[69]Feng, J., Hu, X., Yue, P. L. Degradation of salicylic acid by photo-assisted Fenton reaction using Fe ions on strongly acidic ion exchange resin as catalyst. Chemical Engineering Journal[J].2004,100 (1-3):159-165.
[70]闵怀,傅亮,陈泽军.Fenton法及其在废水处理中的应用研究.环境污染与防治[J].2004,26(001)：28-30.
[71]陈雨露,黎钢,杨芳,陈艳平,张松梅.电-Fenton法解聚纤维素的研究.化学世界[J].51(006)：337-340.
[72]解清杰,马涛,王琳玲,陆晓华.六氯苯污染沉积物的电Fenton法处理.华中科技大学学报：自然科学版[J].2005,33(003)：122-124.
[73]王奇,黄应平,唐敏,潘家荣,李瑞萍.光／电Fenton催化降解有毒有机污染物.太阳能学报[J].2009,30(003)：361-367.
[74]王春霞,肖书虎,赵旭,刘会娟,曲久辉,常雁红.光电芬顿氧化法深度处理垃圾渗滤液研究.环境工程学报[J].2009,3(001)：11-16.
[75]孙红杰,孙道玮,孙天竹,何婉姝,张思华,杨洁,孙秀娟.超声-Fenton试剂联合降解水中十二烷基苯磺酸钠的研究.大连民族学院学报[J].2005,7(003)：54-57.
[76]徐美娟,王启山,孙晓明.非均相光催化技术处理废纸制浆废水的比较和优化.天 津大学学报[J].2009,42(001)：72-77.
[77]Parra, S., Nadtotechenko, V., Albers, P., Kiwi, J. Discoloration of azo-dyes at biocompatible pH-values through an Fe-histidine complex immobilized on Nafion via fenton-like processes. Journal of Physical Chemistry B[J].2004,108 (14):4439-4448.
[78]尹红霞,康天放,张雁,郝玉翠.电化学催化氧化法降解水中甲基橙的研究.环境科学与技术[J].2008,31(002)：88-91.
[79]陈爱因,马小东,孙红文.Y型分子筛负载铁催化剂对活性艳蓝KN-R脱色的研究[J].环境化学[J].2008,27(1)：23-28.
[80]Sum,O. S. N., Feng, J., Hu, X., Yue, P. L. Pillared laponite clay-based Fe nanocomposites as heterogeneous catalysts for photo-Fenton degradation of acid black 1. Chemical Engineering Science[J].2004,59 (22):5269-5275.
[81]何立平,杨迎春,徐成华,叶芝祥,刘盛余.Fe/活性炭多相类Fenton法湿式氧化罗丹明B废水的研究.环境工程学报[J].2009,3(008)：1433-1437.
[82]严新焕,许丹倩.Fe/活性炭作催化剂湿式氧化降解对氨基苯酚废水.染料工业[J].2002,39(003)：42-43.
[83]Liao, Q., Sun, J., Gao, L. Degradation of phenol by heterogeneous Fenton reaction using multi-walled carbon nanotube supported Fe2O3 catalysts. Colloids and Surfaces A: Physicochemical and Engineering Aspects [J].2009,345 (1-3):95-100.
[84]蔡梅,严菲,蔡关明.气相色谱法测定依托咪酯注射液中PG的含量.药学与临床研究[J].18(002)：191-192.
[85]李忠,杨光宇,黄海涛,施红林,刘巍,蒋次清,注意,邮箱,职业.高效液相色谱法测定烟草料液中的糖,甘油和PG.分析化学(FENXI HUAXUE)[J].2002,30(6): 687-689.
[86]梁振明.PG酯中游离PG含量的直接测定.中国食品添加剂[J].2007,4(4)：160-162.
[87]C.Leibman, K., Ortiz, E. A Colorimetric Method for Determination of Glycols. Analytical Chemistry[J].1968,40 (1):251-252.
[88]孔红星,李利军.高碘酸钠氧化甘油的动力学研究及应用.光谱实验室[J].2003,20(001)：70-73.
[89]张楚富,王泽胜.高碘酸钠氧化法测定肌醇含量.武汉大学学报：自然科学版[J].1996,42(002)：255-257.
[90]Eaton, A. D., Franson, M. A. H. Standard methods for the examination of water and wastewater[M]:Amer Public Health Assn,2005.
[91]Greenberg, A. E., Clesceri, L. S., Eaton, A. D. Standard methods for the examination of water and wastewater. Washington (DC)[J].1992.
[92]张瑛洁,马军,张亮.钛盐分光光度法测定酸性染料体系中的过氧化氢.工业水处理[J].2008,28(11)：72-74.
[93]姜成春,庞素艳,马军,谢炜平,邹原.钛盐光度法测定Fenton氧化中的过氧化氢.中国给水排水[J].2006,22(004)：88-91.
[94]Tamura, H., Goto, K., Yotsuyanagi, T., Nagayama, M. Spectrophotometric determination of iron (II) with 1,10-phenanthroline in the presence of large amounts of iron (III). Talanta[J]. 1974,21 (4):314-318.
[95]Lin, S. H., Lin, C. M., Leu, H. G. Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation. Water Research[J].1999,33 (7): 1735-1741.
[96]Bautista, P., Mohedano, A. F., Gilarranz, M. A., Casas, J. A., Rodriguez, J. J. Application of Fenton oxidation to cosmetic wastewaters treatment. Journal of Hazardous materials[J]. 2007,143 (1-2):128-134.
[97]Lopez, A., Pagano, M., Volpe, A., Claudio Di Pinto, A. Fenton's pre-treatment of mature landfill leachate. Chemosphere[J].2004,54 (7):1005-1010.
[98]Casero, I., Sicilia, D., Rubio, S., Perez-Bendito, D. Chemical degradation of aromatic amines by Fenton's reagent. Water Research[J].1997,31 (8):1985-1995.
[99]Neyens, E., Baeyens, J. A review of classic Fenton's peroxidation as an advanced oxidation technique. Journal of Hazardous materials[J].2003,98 (1-3):33-50.
[100]Walling, C., Kato, S. Oxidation of alcohols by Fenton's reagent. Effect of copper ion. Journal of the American Chemical Society[J].1971,93 (17):4275-4281.
[101]Kang, Y. W., Hwang, K. Y. Effects of reaction conditions on the oxidation efficiency in the Fenton process. Water Research[J].2000,34 (10):2786-2790.
[102]Bigda, R. J. Consider Fenton's chemistry for wastewater treatment. Chemical Engineering Progress [J].1995,91 (12):62-66.
[103]Ma, X. J., Xia, H. L. Treatment of water-based printing ink wastewater by Fenton process combined with coagulation. Journal of Hazardous materials[J].2009,162 (1): 386-390.
[104]Huling, S. G., Hwang, S. Iron Amendment and Fenton Oxidation of MTBE-Spent Granular Activated Carbon. Water Research[J].2010,44 (8):2663-2671.
[105]Malik, P. K., Saha, S. K. Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst. Separation and Purification Technology[J].2003,31 (3):241-250.
[106]Chen, R., Pignatello, J. J. Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ. Sci. Technol[J].1997, 31 (8):2399-2406.
[107]Gallard, H., De Laat, J. Kinetics of oxidation of chlorobenzenes and phenyl-ureas by Fe (II)/H2O2 and Fe (III)/H2O2. Evidence of reduction and oxidation reactions of intermediates by Fe (II) or Fe (III). Chemosphere[J].2001,42 (4):405-413.
[108]Najm, I. N., Snoeyink, V. L., Richard, Y. Removal of 2,4,6-trichlorophenol and natural organic matter from water supplies using PAC in floc-blanket reactors. Water Research[J]. 1993,27 (4):551-560.
[109]Ayranci, E., Hoda, N. Adsorption kinetics and isotherms of pesticides onto activated carbon-cloth. Chemosphere[J].2005,60 (11):1600-1607.
[110]Kumar, A., Prasad, B., Mishra, I. M. Adsorptive removal of acrylonitrile by commercial grade activated carbon:Kinetics, equilibrium and thermodynamics. Journal of hazardous materials[J].2008,152 (2):589-600.
[111]Shim, J. W., Park, S. J., Ryu, S. K. Effect of modification with HNO3 and NaOH on metal adsorption by pitch-based activated carbon fibers. Carbon[J].2001,39 (11): 1635-1642.
[112]Dhaouadi, A., Monser, L., Adhoum, N. Removal of rotenone insecticide by adsorption onto chemically modified activated carbons. Journal of hazardous materials[J].2010,181: 692-699.
[113]Adam, O., Bitschene, M., Torri, G, De Giorgi, F., Badot, P. M., Crini, G. Studies on adsorption of propiconazole on modified carbons. Separation and purification technology [J]. 2005,46(1-2):11-18.
[114]Ramirez, J. H., Maldonado-Hodar, F. J., Perez-Cadenas, A. F., Moreno-Castilla, C., Costa, C. A., Madeira, L. M. Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalysts. Applied Catalysis B:Environmental [J].2007,75 (3-4): 312-323.
[115]Bach, A., Semiat, R. The role of activated carbon as a catalyst in GAC/iron oxide/H2O2 oxidation process. Desalination[J].2010,20(4):1-7.
[2]Jank, B. E., Guo, H. M., Cairns, V. W. Activated sludge treatment of airport wastewater containing aircraft de-icing fluids. Water Research[J].1974,8 (11):875-880.
[3]Veltman, S., Schoenberg, T., Switzenbaum, M. S. Alcohol and acid formation during the anaerobic decomposition of propylene glycol under methanogenic conditions. Biodegradation[J].1998,9 (2):113-118.
[4]Bielefeldt, A. R., Illangasekare, T., Uttecht, M., LaPlante, R. Biodegradation of propylene glycol and associated hydrodynamic effects in sand. Water Research[J].2002,36 (7):1707-1714.
[5]Haines, J. R., Alexander, M. Microbial degradation of polyethylene glycols. Applied and Environmental Microbiology [J].1975,29 (5):621-625.
[6]高德霖.活性炭的孔隙结构与吸附性能.化学工业与工程[J].1990,7(003)：48-54.
[7]范拴喜,江元汝.Fenton法的研究现状与进展.现代化工[J].2007,27(z1)：104-107.
[8]Chen, F., Li, Y., Guo, L., Zhang, J. Strategies comparison of eliminating the passivation of non-aromatic intermediates in degradation of Orange Ⅱ by Fe3+/H2O2. Journal of Hazardous materials[J].2009,169 (1-3):711-718.
[9]孙根行,刘梅.非均相Fenton反应处理染料废水.印染[J].2008,34(015)：44-46.
[10]Ramirez, J. H., Duarte, F. M., Martins, F. G., Costa, C. A., Madeira, L. M. Modelling of the synthetic dye Orange Ⅱ degradation using Fenton's reagent:From batch to continuous reactor operation. Chemical Engineering Journal[J].2009,148 (2-3):394-404.
[11]Lee, J.-W., Choi, S.-P., Thiruvenkatachari, R., Shim, W.-G., Moon, H. Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes. Water Research[J].2006,40 (3): 435-444.
[12]王秀芳.高比表面积活性炭的制备、表征及应用[D]：[硕士学位论文].广州：华南理工大学,2006.
[13]解强,胡维淳,张玉柱,许红球.对我国活性炭工业发展的思考与建议.煤炭加工与综合利用[J].2003,(005)：36-39.
[14]魏娜,赵乃勤,贾威.活性炭的制备及应用新进展.材料科学与工程学报[J].2003,21(005)：777-780.
[15]范延臻,王宝贞.活性炭表面化学.煤炭转化[J].2000,23(4)：26-30.
[16]黄伟,贾艳秋,孙盛凯.活性炭及其改性研究进展.气体净化[J].2006,6(006)：24-29.
[17]韩严和,全燮,薛大明,赵雅之,陈硕.活性炭改性研究进展.环境污染治理技术与设备[J].2003,4(001)：33-37.
[18]Pereira, M. F. R., Soares, S. F.,orf o, J. J. M., Figueiredo, J. L. Adsorption of dyes on activated carbons:influence of surface chemical groups. Carbon[J].2003,41 (4):811-821.
[19]胡巧开,杜冬云.含铁废水的吸附处理研究.煤炭科学技术[J].2004,32(012)：55-57.
[20]刘月蓉.氢氧化钾法制备竹活性炭.生物质化学工程[J].2006,40(004)：38-40.
[21]刘慧英,冯霞.以果物核壳为原料制备活性炭及其改性研究.宁夏大学学报：自然科学版[J].1996,17(002)：32-35.
[22]高尚愚,安部郁夫.表面改性活性炭对苯醛及苯磺酸吸附的研究.林产化学与工业[J].1994,14(003)：29-34.
[23]荣海琴,郑经堂.改性PAN-ACFs对甲醛吸附性能的初步研究.新型炭材料[J].2001,16(001)：44-48.
[24]Mangun, C. L., Benak, K. R., Economy, J., Foster, K. L. Surface chemistry, pore sizes and adsorption properties of activated carbon fibers and precursors treated with ammonia. Carbon[J].2001,39 (12):1809-1820.
[25]Figueiredo, J. L., Pereira, M. F. R., Freitas, M. M. A., Orfao, J. J. M. Modification of the surface chemistry of activated carbons. Carbon[J].1999,37 (9):1379-1389.
[26]王宝贞,范延臻,孙治荣.改性GAC及ACF去除水中有机污染物的静态研究.哈尔滨建筑大学学报[J].2000,33(004)：46-49.
[27]冯平,彭华平,孙振兴,蔡忠,张战利,周会勇,李文军,周少奇.高效微生物-A/O工艺处理化工综合废水.中国给水排水[J].2010,26(18)：102-105.
[28]朱文芳,李伟光,吕炳南,何华.微生物固定化处理低浓度甲醇废水试验研究.哈尔滨工业大学学报[J].2004,36(008)：1008-1010.
[29]李亚峰,苏永彬.混凝沉淀法处理煤泥水的试验研究.安全与环境学报[J].2002,2(001)：11-13.
[30]杨联京.碱渣中和法在灰水回用中的应用.中国给水排水[J].1995,11(004)：8-11.
[31]陈秀芳.离子交换法在废水处理中的应用.科技情报开发与经济[J].2004,14(007)：148-149.
[32]de Souza, D. R., Duarte, E. T. F. M., de Souza Girardi, G., Velani, V., da Hora Machado, A. E., Sattler, C., de Oliveira, L., de Miranda, J. A. Study of kinetic parameters related to the degradation of an industrial effluent using Fenton-like reactions. Journal of Photochemistry and Photobiology A:Chemistry[J].2006,179 (3):269-275.
[33]Rosenfeldt, E. J., Linden, K. G., Canonica, S., von Gunten, U. Comparison of the efficiency of OH radical formation during ozonation and the advanced oxidation processes O3/H2O2 and UV/H2O2. Water Research[J].2006,40 (20):3695-3704.
[34]Kolaczkowski, S. T., Plucinski, P., Beltran, F. J., Rivas, F. J., McLurgh, D. B. Wet air oxidation:a review of process technologies and aspects in reactor design. Chemical Engineering Journal[J].1999,73 (2):143-160.
[35]Lee, J.-C., Kim, M.-S., Kim, B.-W. Removal of paraquat dissolved in a photoreactor with TiO2 immobilized on the glass-tubes of UV lamps. Water Research[J].2002,36 (7): 1776-1782.
[36]Ruppert, G, Bauer, R., Heisler, G. UV-03, UV-H2O2, UV-TiO2 and the photo-Fenton reaction-comparison of advanced oxidation processes for wastewater treatment. Chemosphere[J].1994,28(8):1447-1454.
[37]Zhu, W., Bin, Y., Li, Z., Jiang, Z., Yin, T. Application of catalytic wet air oxidation for the treatment of H-acid manufacturing process wastewater. Water Research[J].2002,36 (8): 1947-1954.
[38]C zares, P., Hern dez-Ortega, M., Rodrigo, M. A., Barrera-Dz, C. E., Roa-Morales, G, Sz, C. A comparison between Conductive-Diamond Electrochemical Oxidation and other Advanced Oxidation Processes for the treatment of synthetic melanoidins. Journal of Hazardous materials[J].2009,164 (1):120-125.
[39]郭楠,李玉平.湿式空气氧化法处理DNT生产废水的影响因素及反应机理.火炸药学报[J]33(3)：25-29.
[40]李红亚.湿式空气氧化法处理模拟染料废水的研究[D]：[硕士学位论文].西安：西北大学,2008.
[41]崔艳萍,杨昌柱.电化学氧化法在难降解有机废水处理中的应用.工业安全与环保[J].2004,30(006)：12-14.
[42]Shaw, R. W., Dahmen, N. Destruction of toxic organic materials using supercritical water oxidation:current state of the technology. NATO ASI SERIES E APPLIED SCIENCES[J]. 2000,36(6):425-438.
[43]Erkonak, H., S, O., Akg, M. Treatment of olive mill wastewater by supercritical water oxidation. The Journal of Supercritical Fluids[J].2008,46 (2):142-148.
[44]高铁,钱朝勇.Ti02光催化氧化水中有机污染物进展.工业水处理[J].2000,20(004)：10-13.
[45]Xu, H., Zhang, D., Xu, W. Monitoring of decolorization kinetics of Reactive Brilliant Blue X-BR by online spectrophotometric method in Fenton oxidation process. Journal of Hazardous materials[J].2008,158 (2-3):445-453.
[46]Kang, N., Lee, D. S., Yoon, J. Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere[J].2002,47 (9):915-924.
[47]Burbano, A. A., Dionysiou, D. D., Suidan, M. T., Richardson, T. L. Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water Research[J].2005, 39(1):107-118.
[48]Gallard, H., De Laat, J. Kinetic modelling of Fe (III)/H2O2 oxidation reactions in dilute aqueous solution using atrazine as a model organic compound. Water Research[J].2000,34 (12):3107-3116.
[49]Haag, W. R., Yao, C. C. D. Rate constants for reaction of hydroxyl radicals with several drinking water contaminants. Environmental Science & Technology [J].1992,26 (5): 1005-1013.
[50]Lucas, M. S., Peres, J. A. Removal of COD from olive mill wastewater by Fenton's reagent:Kinetic study. Journal of Hazardous materials[J].2009,1253-1259.
[51]Kang, S. F., Liao, C. H., Chen, M. C. Pre-oxidation and coagulation of textile wastewater by the Fenton process. Chemosphere[J].2002,46 (6):923-928.
[52]Guedes, A., Madeira, L. M. P., Boaventura, R. A. R., Costa, C. A. V. Fenton oxidation of cork cooking wastewater-overall kinetic analysis. Water Research[J].2003,37 (13): 3061-3069.
[53]Meri, S., Kaptan, D., mez, T. Color and COD removal from wastewater containing Reactive Black 5 using Fenton's oxidation process. Chemosphere[J].2004,54 (3):435-441.
[54]Deng, Y. Physical and oxidative removal of organics during Fenton treatment of mature municipal landfill leachate. Journal of Hazardous materials[J].2007,146 (1-2):334-340.
[55]Primo, O., Rivero, M. J., Ortiz, I. Photo-Fenton process as an efficient alternative to the treatment of landfill leachates. Journal of Hazardous materials[J].2008,153 (1-2):834-842.
[56]Zhang, H., Choi, H. J., Canazo, P., Huang, C.-P. Multivariate approach to the Fenton process for the treatment of landfill leachate. Journal of Hazardous materials[J].2009,161 (2-3):1306-1312.
[57]Zhu, S. G, Zhang, N., Chen, X., Cao, G P., Yuan, W. K. The mechanism and kinetics for the selective oxidation of glyoxal to produce glyoxalic acid by Fenton's reagent. Reaction Kinetics, Mechanisms and Catalysis[J].99 (2):325-333.
[58]Walling, C., Amarnath, K. Oxidation of mandelic acid by Fenton's reagent. Journal of the American Chemical Society[J].1982,104 (5):1185-1189.
[59]Grasselli, R. K., Oyama, S. T., Gaffney, A. M., Lyons, J. E.; Elsevier Science:1997, p 527.
[60]Hermosilla, D., Cortijo, M., Huang, C. P. Optimizing the treatment of landfill leachate by conventional Fenton and photo-Fenton processes. Science of the Total Environment[J].2009, 407 (11):3473-3481.
[61]Ramirez, J. H., Duarte, F. M., Martins, F. G., Costa, C. A., Madeira, L. M. Modelling of the synthetic dye Orange II degradation using Fenton's reagent:From batch to continuous reactor operation. Chemical Engineering Journal.[J].2009,148 (2-3):394-404.
[62]包木太,王娜,陈庆国,郭省学,李希明.Fenton法的氧化机理及在废水处理中的应 用进展.CHEMICAL INDUSTRY AND ENGINEERING PROGRESS[J].2008,27 (5): 660-665.
[63]Quici, N., Morgada, M. E., Gettar, R. T., Bolte, M., Litter, M. I. Photocatalytic degradation of citric acid under different conditions:TiO2 heterogeneous photocatalysis against homogeneous photolytic processes promoted by Fe (III) and H2O2. Applied Catalysis B:Environmental[J].2007,71 (3-4):117-124.
[64]Badawy, M. I., Ghaly, M. Y., Gad-Allah, T. A. Advanced oxidation processes for the removal of organophosphorus pesticides from wastewater. Desalination[J].2006,194 (1-3): 166-175.
[65]De Laat, J., Gallard, H., Ancelin, S., Legube, B. Comparative study of the oxidation of atrazine and acetone by H2O2/UV, Fe (III)/UV, Fe (III)/H2O2/UV and Fe (II) or Fe (III)/H2O2. Chemosphere[J].1999,39 (15):2693-2706.
[66]刘杨先,张军,盛昌栋,张永春,赵亮.非均相Photo-Fenton反应中负载型光催化剂研究进展.现代化工[J].2010,(004)：26-30.
[67]Liou, R. M., Chen, S. H., Hung, M. Y, Hsu, C. S., Lai, J. Y. Fe (III) supported on resin as effective catalyst for the heterogeneous oxidation of phenol in aqueous solution. Chemosphere[J].2005,59 (1):117-125.
[68]Kusic, H., Koprivanac, N., Bozic, A. L., Selanec, I. Photo-assisted Fenton type processes for the degradation of phenol:a kinetic study. Journal of Hazardous materials[J].2006,136 (3):632-644.
[69]Feng, J., Hu, X., Yue, P. L. Degradation of salicylic acid by photo-assisted Fenton reaction using Fe ions on strongly acidic ion exchange resin as catalyst. Chemical Engineering Journal[J].2004,100 (1-3):159-165.
[70]闵怀,傅亮,陈泽军.Fenton法及其在废水处理中的应用研究.环境污染与防治[J].2004,26(001)：28-30.
[71]陈雨露,黎钢,杨芳,陈艳平,张松梅.电-Fenton法解聚纤维素的研究.化学世界[J].51(006)：337-340.
[72]解清杰,马涛,王琳玲,陆晓华.六氯苯污染沉积物的电Fenton法处理.华中科技大学学报：自然科学版[J].2005,33(003)：122-124.
[73]王奇,黄应平,唐敏,潘家荣,李瑞萍.光／电Fenton催化降解有毒有机污染物.太阳能学报[J].2009,30(003)：361-367.
[74]王春霞,肖书虎,赵旭,刘会娟,曲久辉,常雁红.光电芬顿氧化法深度处理垃圾渗滤液研究.环境工程学报[J].2009,3(001)：11-16.
[75]孙红杰,孙道玮,孙天竹,何婉姝,张思华,杨洁,孙秀娟.超声-Fenton试剂联合降解水中十二烷基苯磺酸钠的研究.大连民族学院学报[J].2005,7(003)：54-57.
[76]徐美娟,王启山,孙晓明.非均相光催化技术处理废纸制浆废水的比较和优化.天 津大学学报[J].2009,42(001)：72-77.
[77]Parra, S., Nadtotechenko, V., Albers, P., Kiwi, J. Discoloration of azo-dyes at biocompatible pH-values through an Fe-histidine complex immobilized on Nafion via fenton-like processes. Journal of Physical Chemistry B[J].2004,108 (14):4439-4448.
[78]尹红霞,康天放,张雁,郝玉翠.电化学催化氧化法降解水中甲基橙的研究.环境科学与技术[J].2008,31(002)：88-91.
[79]陈爱因,马小东,孙红文.Y型分子筛负载铁催化剂对活性艳蓝KN-R脱色的研究[J].环境化学[J].2008,27(1)：23-28.
[80]Sum,O. S. N., Feng, J., Hu, X., Yue, P. L. Pillared laponite clay-based Fe nanocomposites as heterogeneous catalysts for photo-Fenton degradation of acid black 1. Chemical Engineering Science[J].2004,59 (22):5269-5275.
[81]何立平,杨迎春,徐成华,叶芝祥,刘盛余.Fe/活性炭多相类Fenton法湿式氧化罗丹明B废水的研究.环境工程学报[J].2009,3(008)：1433-1437.
[82]严新焕,许丹倩.Fe/活性炭作催化剂湿式氧化降解对氨基苯酚废水.染料工业[J].2002,39(003)：42-43.
[83]Liao, Q., Sun, J., Gao, L. Degradation of phenol by heterogeneous Fenton reaction using multi-walled carbon nanotube supported Fe2O3 catalysts. Colloids and Surfaces A: Physicochemical and Engineering Aspects [J].2009,345 (1-3):95-100.
[84]蔡梅,严菲,蔡关明.气相色谱法测定依托咪酯注射液中PG的含量.药学与临床研究[J].18(002)：191-192.
[85]李忠,杨光宇,黄海涛,施红林,刘巍,蒋次清,注意,邮箱,职业.高效液相色谱法测定烟草料液中的糖,甘油和PG.分析化学(FENXI HUAXUE)[J].2002,30(6): 687-689.
[86]梁振明.PG酯中游离PG含量的直接测定.中国食品添加剂[J].2007,4(4)：160-162.
[87]C.Leibman, K., Ortiz, E. A Colorimetric Method for Determination of Glycols. Analytical Chemistry[J].1968,40 (1):251-252.
[88]孔红星,李利军.高碘酸钠氧化甘油的动力学研究及应用.光谱实验室[J].2003,20(001)：70-73.
[89]张楚富,王泽胜.高碘酸钠氧化法测定肌醇含量.武汉大学学报：自然科学版[J].1996,42(002)：255-257.
[90]Eaton, A. D., Franson, M. A. H. Standard methods for the examination of water and wastewater[M]:Amer Public Health Assn,2005.
[91]Greenberg, A. E., Clesceri, L. S., Eaton, A. D. Standard methods for the examination of water and wastewater. Washington (DC)[J].1992.
[92]张瑛洁,马军,张亮.钛盐分光光度法测定酸性染料体系中的过氧化氢.工业水处理[J].2008,28(11)：72-74.
[93]姜成春,庞素艳,马军,谢炜平,邹原.钛盐光度法测定Fenton氧化中的过氧化氢.中国给水排水[J].2006,22(004)：88-91.
[94]Tamura, H., Goto, K., Yotsuyanagi, T., Nagayama, M. Spectrophotometric determination of iron (II) with 1,10-phenanthroline in the presence of large amounts of iron (III). Talanta[J]. 1974,21 (4):314-318.
[95]Lin, S. H., Lin, C. M., Leu, H. G. Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation. Water Research[J].1999,33 (7): 1735-1741.
[96]Bautista, P., Mohedano, A. F., Gilarranz, M. A., Casas, J. A., Rodriguez, J. J. Application of Fenton oxidation to cosmetic wastewaters treatment. Journal of Hazardous materials[J]. 2007,143 (1-2):128-134.
[97]Lopez, A., Pagano, M., Volpe, A., Claudio Di Pinto, A. Fenton's pre-treatment of mature landfill leachate. Chemosphere[J].2004,54 (7):1005-1010.
[98]Casero, I., Sicilia, D., Rubio, S., Perez-Bendito, D. Chemical degradation of aromatic amines by Fenton's reagent. Water Research[J].1997,31 (8):1985-1995.
[99]Neyens, E., Baeyens, J. A review of classic Fenton's peroxidation as an advanced oxidation technique. Journal of Hazardous materials[J].2003,98 (1-3):33-50.
[100]Walling, C., Kato, S. Oxidation of alcohols by Fenton's reagent. Effect of copper ion. Journal of the American Chemical Society[J].1971,93 (17):4275-4281.
[101]Kang, Y. W., Hwang, K. Y. Effects of reaction conditions on the oxidation efficiency in the Fenton process. Water Research[J].2000,34 (10):2786-2790.
[102]Bigda, R. J. Consider Fenton's chemistry for wastewater treatment. Chemical Engineering Progress [J].1995,91 (12):62-66.
[103]Ma, X. J., Xia, H. L. Treatment of water-based printing ink wastewater by Fenton process combined with coagulation. Journal of Hazardous materials[J].2009,162 (1): 386-390.
[104]Huling, S. G., Hwang, S. Iron Amendment and Fenton Oxidation of MTBE-Spent Granular Activated Carbon. Water Research[J].2010,44 (8):2663-2671.
[105]Malik, P. K., Saha, S. K. Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst. Separation and Purification Technology[J].2003,31 (3):241-250.
[106]Chen, R., Pignatello, J. J. Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ. Sci. Technol[J].1997, 31 (8):2399-2406.
[107]Gallard, H., De Laat, J. Kinetics of oxidation of chlorobenzenes and phenyl-ureas by Fe (II)/H2O2 and Fe (III)/H2O2. Evidence of reduction and oxidation reactions of intermediates by Fe (II) or Fe (III). Chemosphere[J].2001,42 (4):405-413.
[108]Najm, I. N., Snoeyink, V. L., Richard, Y. Removal of 2,4,6-trichlorophenol and natural organic matter from water supplies using PAC in floc-blanket reactors. Water Research[J]. 1993,27 (4):551-560.
[109]Ayranci, E., Hoda, N. Adsorption kinetics and isotherms of pesticides onto activated carbon-cloth. Chemosphere[J].2005,60 (11):1600-1607.
[110]Kumar, A., Prasad, B., Mishra, I. M. Adsorptive removal of acrylonitrile by commercial grade activated carbon:Kinetics, equilibrium and thermodynamics. Journal of hazardous materials[J].2008,152 (2):589-600.
[111]Shim, J. W., Park, S. J., Ryu, S. K. Effect of modification with HNO3 and NaOH on metal adsorption by pitch-based activated carbon fibers. Carbon[J].2001,39 (11): 1635-1642.
[112]Dhaouadi, A., Monser, L., Adhoum, N. Removal of rotenone insecticide by adsorption onto chemically modified activated carbons. Journal of hazardous materials[J].2010,181: 692-699.
[113]Adam, O., Bitschene, M., Torri, G, De Giorgi, F., Badot, P. M., Crini, G. Studies on adsorption of propiconazole on modified carbons. Separation and purification technology [J]. 2005,46(1-2):11-18.
[114]Ramirez, J. H., Maldonado-Hodar, F. J., Perez-Cadenas, A. F., Moreno-Castilla, C., Costa, C. A., Madeira, L. M. Azo-dye Orange II degradation by heterogeneous Fenton-like reaction using carbon-Fe catalysts. Applied Catalysis B:Environmental [J].2007,75 (3-4): 312-323.
[115]Bach, A., Semiat, R. The role of activated carbon as a catalyst in GAC/iron oxide/H2O2 oxidation process. Desalination[J].2010,20(4):1-7.