Y_2O_3：Eu~(3+)和Y_2O_2S：Eu(3+),Mg(2+),Ti(4+) 红色发光材料的制备与性能研究
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摘要
自二十世纪中期以来,稀土发光材料迅速在照明显示、装饰信号、安全运输等领域得到广泛的应用。作为红色发光材料的Y2O3:Eu3+和Y2O2S:Eu3+由于其发光色度纯、化学性质稳定备受国内外研究者的关注。
本文在表面活性剂辅助下合成了性能稳定、发光性能优良的Y2O3:Eu3+和Y2O2S:EuJ3+,Mg2+,Ti4+红色发光材料。通过改变合成条件和原料配比,详细讨论了离子交换、烧结温度、升温速率、PH值、反应时间、SDS浓度对Y2O3:Eu3+形貌和发光性能的影响,并获得了最佳的工艺参数。同时研究了微观形貌变化对产物发光性能的影响,讨论了发光机理。
讨论了在表面活性剂辅助下合成的Y2O2S:Eu3+,Mg2+,Ti4+与传统高温固相法合成的Y2O2S:Eu3+,Mg2+,Ti4+在形貌和发光性能上的区别,利用XRD、 SEM PL、 TL对样品进行了表征。结果表明：在表面活性剂辅助下合成的样品与传统高温固相法合成的样品相比,最佳合成温度降低了200～300℃；表面活性剂的添加影响了样品的表面形貌,而样品的发光性能基本一致；同时对Y2O2S:Eu3+,Ng2+,Ti4+的发光机理进行了讨论。
Since the middle of20th century, rare-earth luminescent materials have been widely applied in the fields of lighting display, adornment signal, safe transportation, etc. The red luminescent materials Y2O3:Eu3+and Y2O2S:Eu3+have been paid much attention for the high brightness and good chemical stability.
In this paper, Y2O3:Eu3+and Y2O2S:Eu3+,Mg2+,Ti4+was synthesized via surfactant assisted, and the red luminescent materials with excellent stability and luminescent property were prepared. Effects of ion exchange, sintering temperature, heating rate, PH value, reaction time, concentration of SDS on the morphology and luminescent property of Y2O3:Eu3+were investigated by changing the synthesis conditions and the ratio of raw materials. After a series of experiments, the optimal reaction conditions were obtained. Influence of microstructure on luminescent property of the samples was studied, and the luminescent mechanism was also discussed.
The difference of the surfactant-assisted method and conventional high temperature solid-phase reaction method on the morphology and luminescent property of Y2O2S:Eu3+,Mg2+,Ti4+was discussed in detail. The luminescent materials were characterized by means of XRD, SEM, PL, and TL. The results indicated that compared with the samples obtained by the conventional high temperature solid-state method, the optimum synthesis temperature of the samples prepared by the surfactant-assisted method decreased by200～300℃. The luminescent properties of the samples prepared by the two methods were similar. Morphology of the samples was affected by introduction of surfactant SDS. The luminescent mechanism of the samples was also discussed.
本文在表面活性剂辅助下合成了性能稳定、发光性能优良的Y2O3:Eu3+和Y2O2S:EuJ3+,Mg2+,Ti4+红色发光材料。通过改变合成条件和原料配比,详细讨论了离子交换、烧结温度、升温速率、PH值、反应时间、SDS浓度对Y2O3:Eu3+形貌和发光性能的影响,并获得了最佳的工艺参数。同时研究了微观形貌变化对产物发光性能的影响,讨论了发光机理。
讨论了在表面活性剂辅助下合成的Y2O2S:Eu3+,Mg2+,Ti4+与传统高温固相法合成的Y2O2S:Eu3+,Mg2+,Ti4+在形貌和发光性能上的区别,利用XRD、 SEM PL、 TL对样品进行了表征。结果表明：在表面活性剂辅助下合成的样品与传统高温固相法合成的样品相比,最佳合成温度降低了200～300℃；表面活性剂的添加影响了样品的表面形貌,而样品的发光性能基本一致；同时对Y2O2S:Eu3+,Ng2+,Ti4+的发光机理进行了讨论。
Since the middle of20th century, rare-earth luminescent materials have been widely applied in the fields of lighting display, adornment signal, safe transportation, etc. The red luminescent materials Y2O3:Eu3+and Y2O2S:Eu3+have been paid much attention for the high brightness and good chemical stability.
In this paper, Y2O3:Eu3+and Y2O2S:Eu3+,Mg2+,Ti4+was synthesized via surfactant assisted, and the red luminescent materials with excellent stability and luminescent property were prepared. Effects of ion exchange, sintering temperature, heating rate, PH value, reaction time, concentration of SDS on the morphology and luminescent property of Y2O3:Eu3+were investigated by changing the synthesis conditions and the ratio of raw materials. After a series of experiments, the optimal reaction conditions were obtained. Influence of microstructure on luminescent property of the samples was studied, and the luminescent mechanism was also discussed.
The difference of the surfactant-assisted method and conventional high temperature solid-phase reaction method on the morphology and luminescent property of Y2O2S:Eu3+,Mg2+,Ti4+was discussed in detail. The luminescent materials were characterized by means of XRD, SEM, PL, and TL. The results indicated that compared with the samples obtained by the conventional high temperature solid-state method, the optimum synthesis temperature of the samples prepared by the surfactant-assisted method decreased by200～300℃. The luminescent properties of the samples prepared by the two methods were similar. Morphology of the samples was affected by introduction of surfactant SDS. The luminescent mechanism of the samples was also discussed.
引文
[1]李兴民.共沉淀法合成长余辉材料及其特性研究[D].石家庄：河北大学,2006.
[2]戴俊.稀土掺杂发光材料溶胶-凝胶法制备与发光性能研究[D].杭州：浙江大学,2011.
[3]刘应亮,雷炳富,邝金勇等.长余辉发光材料研究进展[J].无机化学学报,2009,25(8)：1323-1329.
[4]Marcus Alden, Alaa Omrane, Mattias Richter, et al. Thermographic phosphors for thermometry:A survey of combustion applications [J]. Progress in Energy and Combustion Science,2011,37:422-461.
[5]孙继兵,王海容,安雅琴等.长余辉发光材料研究进展[J].稀土金属材料与工程,2008,37(2)：189-194.
[6]郑继明,徐琰,吕峰等.Sr2SiO4:Eu2+-一维纳米棒的合成及性能研究[J].光学学报,2011,31(11)：1116002-1-1116002-4.
[7]孙家跃,夏志国,杜海燕.稀土红色长余辉发光材料研究进展[J].中国稀土学报,2005,23(3)：257-265.
[8]翟永清,游志江,王欣等.电荷补偿剂对Sr2MgSi207:Eu3+红色发光粉机构和性能的影响[J].硅酸盐学报,2011,39(12)：1887-1891.
[9]曲艳东,李晓杰,陈涛等.铝酸盐系长余辉发光材料的研究新进展[J].稀有金属,2006,30(1)：100-106.
[10]阎武钊,林林,陈永虎等.Mn4+掺杂的新型铝酸盐红色长余辉材料[J].发光学报,2008,29(1)：114-118.
[11]王细凤,夏威,肖志国.一种新型红色荧光粉CaAl12O19:Eu,Mn的制备及发光性能[J].发光学报,2009,30(3)：405-408.
[12]尚用甲,郑峰.草酸盐共沉淀法制备CaTiO3:Pr3+长余辉发光材料的性能研究[J].功能材料,2009,40(1)：17-19.
[13]綦艳,孟建新,时朝璞等.纳米长余辉发光材料CaTiO3:Pr的制备及表征[J].光谱学与光谱分析,2007,27(7)：1287-1290.
[14]杨丽丽,邹少瑜,王荣等.乙二醇辅助水热法制备不同形貌的CaTiO3/CaTiO3:Pr 微晶[J].无机化学学报,2010,26(8)：1345-1348.
[15]崔彩娥,田艳红,黄平等.烧结温度对红色长余辉发光材料Cao.8Zno.2TiO3:Pr3+,Na+性能的影响[J].人工晶体学报,2011,40(4)：958-962.
[16]周文,余丽萍,廉世勋等.前驱溶液的PH值对制备Ca2Zn4Ti16038:Pr3+,Na+发光粉物相、形貌和发光性质的影响[J].发光学报,2010,31(5)：712-718.
[17]Liu Guixia, Hong Guangyan, Dong Xiangting, et al. Synthesis of Y2O3:Eu3+Hollow Spheres Using Silica as Templates [J]. Journal of Rare Earths,2007,25:407-411.
[18]Zhang Ming, Li Xinhai, Wang Zhixing, et al. Synthesis of Y2O3:Eu3+ phosphors by surface diffusion and their photoluminescence properties [J]. Transactions of Nonferrous Metals Society of China,2010,20:115-118.
[19]Jung Hyun Jeong, Hyun Kyoung Yang, Byung Kee Moon, et al. Li-doping effect on enhancement of photoluminescence in Gd2O3:Eu3+ films [J]. Optical Materials,2006,28: 693-697.
[20]Li Yanhong, Hong Guangyan. Synthesis and luminescence properties of nanocrystalline Gd2O3:Eu3+ by combustion process [J]. Journal of Luminescence,2007,124:297-301.
[21]Gao Shiyong, Lu Hongliang, Nie Yanguang, et al. Structural transition induced by the release of residual stress in the complex of cubic and monoclinic Gd2O3:Eu nanoparticles [J]. Materials Letters,2007,61:4003-4005.
[22]Zhou Liya, Wang Wei, Huang Junli, et al. Preparation and characterization of Gd2O3:Eu3+ rods by surfactant assemblies-microwave heating [J]. Optik,2010,121: 1516-1519.
[23]翟永清,刘元红,孟媛等.微波法合成红色长余辉发光材料Gd2O2S:Eu,Mg,Ti及其发光特性[J].光谱学与光谱分析,2007,27(4)：634-638.
[24]Zhang Pengyue, Hong Zhanglian, Shen Huaxiang, et al. Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor [J]. Journal of Rare Earths,2006,24: 115-118.
[25]贺干武,刘应亮,张俊文.沉淀法合成纳米晶长余辉材料Y2O2S:Eu3+,Ti [J].无机化学学报,2007,23(2)：315-318.
[26]Yang Zhiping, Li Xingmin, Liu Chong, et al. Co-Precipitation Synthesis and Spectral Characteristics of Long Afterglow Phosphor Y2O2S:Sm3+,Mg2+,Ti4+[J]. Journal of Rare Earths,2007,25:23-26.
[27]Zeng Huihui, Zhou Xinmu, Zhang Li, et al. Synthesis and luminescence properties of a novel red long lasting phosphor Y2O2S:Eu3+,Si4+,Zn2+[J]. Journal of Alloys and Compounds,2008,460:704-707.
[28]Li Wenyu, Liu Yingliang, Ai Pengfei. Synthesis and luminescence properties of red long-lasting phosphor Y2O2S:Eu3+,Mg2+,Ti4+nanoparticles [J]. Materials Chemistry and Physics,2010,119:52-56.
[29]Ji Tongkun, Jiang Hongyi, Chen Fei. Afterglow phosphor materials Y2O2S:Eu,Mg,Ti doped with various Gd concentrations [J]. Journal of Alloys and Compounds,2010,502: 180-183.
[30]Wang Luxiang, Zhang Li, Huang Yudai, et al. Effects of Gd3+ and Lu3+ co-doping on the long afterglow properties of yellowish-orange phosphor Y2O2S:Ti4+,Mg2+[J]. Journal of Luminescence,2009,129:1032-1035.
[31]赵春雷,胡运生,畅永锋等.Y2O2S:Eu,Mg,Ti,Tb红色长时发光材料的研究[J].中国稀土学报,2002,20(6)：593-596.
[32]周新木,曾慧慧.红色长余辉材料Y2O2S:Eu,Si,M(M=Mg,Ca,Sr,Ba)的制备及发光性能[J].发光学报,2010,31(1)：59-63.
[33]Guo Chongfeng, Huang Dexiu, SuQiang. Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED [J]. Materials Science and Engineering B,2006,130:189-193.
[34]Yoshiyuki Kojima, Kenichi Aoyagi, Tamotsu Yasue. Afterglow mechanism and thermoluminescence of red-emitting CaS:Eu2+,Pr3+ phosphor with incorporated Li+ ion upon visible light irradiation [J]. Journal of Luminescence,2007,126:319-322.
[35]Lu Liping, Zhang Xiyan, Bai Zhaohui, et al. Synthesis and characterization of IR up-conversion material CaS:Eu,Sm by low-temperature combustion synthesis method [J]. Materials Research Bulletin,2009,44:207-210.
[36]Song Enhai, Zhao Weiren, Zhou Guoxiong, et al. Luminescence properties of red phosphors Ca10Li(P04)7:Eu3+[J]. Journal of Rare Earths,2011,29(5):440-443.
[37]Yang Baozhu, Yang Zhiping, Liu Yufeng, et al. Synthesis and photoluminescence properties the high-brightness Eu3+-doped Sr3Y(PO4)3 red phosphors [J]. Ceramics International,2012,02,080.
[38]I.M.Nagpure, S.J.Dhoble, Manoj Mohapatraa, et al. Dependence of Eu3+Luminescence dynamics on the structure of the combustion synthesized Srs(PO4)3F host [J]. Journal of Alloys and Compounds,2011,509:2544-2551.
[39]杨继兰,王卓,刘慧等.用燃烧法和沉淀法制备橙红色Sr5(PO4)3X:Eu3+,Na+(X=F,Cl)荧光粉[J].硅酸盐学报,2011,39(6)：913-917.
[40]Yang Lan, Zhou Liqun, Huang Ying, et al. Ag-catalyzed synthesis of europium borate Eu(BO2)3 nanowires, growth mechanism and luminescent properties [J]. Materials Research Bulletin,2011,46:239-243.
[41]Meng Fangui, Zhang Xinmin, Li Wenlan, et al. Luminescence and time-resolved spectroscopy properties of (Gd1-xEux)(BO2)3 multicrystals [J]. Journal of Physics and Chemistry of Solids,2012,73:564-567.
[42]王静,苏锵,王淑彬.杂质离子对Y2O3:Eu3+发光性能的影响[J].功能材料,2002,33(5)：558-560.
[43]杨志平,郭智,朱胜超等.Eu3+摩尔浓度对Y2O2S:Eu3+,Mg2+,Ti4+红色长余辉材料光谱的影响[J].光谱学与光谱分析,2004,24(12)：1506-1510.
[44]Jorma Holsa, Taneli Laamanen, Mika Lastusaari, et al. Effect of Mg2+ and TiⅣ doping on the luminescence of Y2O2S:Eu3+[J]. Optical Materials,2009,31:1791-1793.
[45]董岩,蒋建清,刘刚等.烧结工艺对Y2O3:Eu3+荧光粉颗粒形貌的影响[J].功能材料,2004，35(3)：352-356.
[46]周东方,施朝淑,戚泽明等Y2O2S:Eu,Ti,Mg红色长余辉的温度依赖[J].中国稀土学报,2006,24(1)：18-21.
[47]Wang Yuha, Wang Zhilong. Characterization of Y2O2S:Eu3+,Mg2+,Ti4+ Long-Lasting Phosphor Synthesized by Flux Method [J]. Journal of Rare Earths,2006,24:25-28.
[48]Zhang Junying, Zhang Zhongtai, Tang Zilong, et al. A new method to synthesize long afterglow red phosphor [J]. Ceramics International,2004,30:225-228.
[49]罗昔贤,曹望和.纳米Y2O2S:Eu的燃烧法合成和Eu3+离子荧光探针物相分析[J].功能材料,2007,38(12)：2064-2070.
[50]孟庆裕,陈宝玖,许武等.立方相Y2O3:Eu纳米晶中C2格位Eu3+的5Do能级量子效率[J].光谱学与光谱分析,2006,26(8)：1377-1381.
[51]刘晃清,王玲玲,李宏健等.氧化物纳米材料Y2O3:(Yb3+,Er3+)上转换发光性质的研究[J].光谱学与光谱学分析,2006,26(8)：1396-1399.
[52]王超男,王志芳,张慰萍等.前驱溶液的PH值对Y2O2S:Eu3+荧光粉发光性质的 影响[J].原子与分子物理学报,2008,25(4)：760-766.
[53]翟永清,杨国忠,刘宇等.新型红色荧光粉SrO·Y2O3:Eu的合成及其发光性能研究[J].光谱学与光谱学分析,2008,28(3)：522-526.
[54]罗宏雷,黄莉蕾,张伦.纳米晶Y2O2S:Eu3+的反常拉曼散射[J].光散射学报,2007,19(3)：219-224.
[55]廖亮,张玉奇,李治霞等.新型红色长余辉发光材料Y2O3:Eu3+,Ca2+,Ti4+的燃烧合成和性能表征[J].稀土,2006,27(2)：26-29.
[56]李堂刚,刘素文,王恩华等Y2O3:Yb3+,Tm3+纳米材料的可见及紫外上转换发光[J].物理学报,2011,60(7)：073201.
[57]孙彦彬,邱关明,陈永杰等.稀土发光材料的合成方法[J].稀土,2003,24(1)：43-48.
[58]孙阳艺,罗思媛,费慧龙等.铕掺杂无机红色荧光材料的研究进展[J].电子元件与材料,2010,29(5)：75-78.
[59]Qiao Yanmin, Guo Hai. Upconversion properties of Y2O3:Er films prepared by sol-gel method [J]. Journal of Rare Earths,2009,27(3):406-410.
[60]Maria de Andrade Gomes, Mario Ernesto Giroldo Valerio, and Zelia Soares Macedo. Particles Size Control of Prepared via a Coconut Water-Assisted Sol-Gel Method [J]. Journal of Nanomaterials,2011.
[61]杨志平,李兴民,杨勇等.共沉淀法制备Y2O2S:Eu3+,Mg2+,Ti4+红色长余辉材料[J].发光学报,2006,27(2)：187-190.
[62]黄燕,胡运生,赵春雷等.共沉淀-熔盐焙烧法制备Y2O3:Eu及其发光性能的研究[J].中国稀土学报,2007,25(2)：157-161.
[63]司伟,高宏,王晶等.纳米晶Y2O3:Eu3+的合成及其热分析动力学[J].无机化学学报,2010,26(8)：1443-1449.
[64]徐国纲,张旭东,何文等.沉淀法制备纳米Eu:Y2O3荧光粉[J].稀有金属材料与工程,2007,36(增刊1)：55-57.
[65]Wu Xiaoyong, Liang Yujun, Liu Rong, et al. The photoluminescence properties of Y2O3:Eu3+ prepared by surfactant assisted co-precipitation-molten salt synthesis [J]. Materials Research Bulletin,2010,45:594-597.
[66]杨利颖,王进贤,董相廷等.微纳米稀土硫氧化物的合成方法研究进展[J].中国稀土学报,2011,29(6)：643-654.
[67]刘桂霞,洪广言,王进贤等.水热法制备具有光滑表面的球形Y2O3:Eu3+发光材料[J].无机化学学报,2006,22(8)：1535-1539.
[68]Ai Pengfei, Li Wenyu, Xiao L.Y., et al. Monodisperse nanospheres of yttrium oxysulfide: Synthesis, characterization, and luminescent properties [J]. Ceramics International,2010, 36:2169-2174.
[69]刘桂霞,王振东,王进贤等.一维Y2O3:Eu3+纳米发光材料的制备与表征[J].无机化学学报,2008,24(1)：149-152.
[70]李文宇,刘应亮,艾鹏飞.水热-微波法合成纳米晶长余辉发光材料Y2O2S:Eu3+,Mg,Ti [].无机化学学报,2008,24(5)：772-776.
[71]Li Wenyu, Liu Yingliang, Ai Pengfei, et al. Synthesis and characterization of Y2O2S:Eu3+,Mg2+,Ti4+ nanorods via a solvothermal routine [J]. Journal of Rare Earths, 2009,27(6):895-899.
[72]艾鹏飞,刘应亮,,李毅东等.纳米晶Y2O2S:Eu3+,Mg2+,Ti4+长余辉发光材料的制备[J].功能材料,2010,41(6)：986-989.
[73]Wu Yanli, Sun Weili, Zhou Xuezhen, et al. Hydrothermal synthesis of Y(OH)3,Y(OH)3:Eu3+ nanotubes and the photoluminescence of Y(OH)3:Eu3+,Y2O3:Eu3+ [J]. Journal of Rare Earths,2009,27(5):767-772.
[74]王艳丽,张明旭,李本侠等.软模板法六边形纳米Pb粒子的超声制备与表征[J].无机化学学报,2011,27(10)：1914-1918.
[75]周波.表面活性剂[M].北京：化学工业出版社,2006：13,16,18.
[76]赵国玺,朱瑶.表面活性剂作用原理[M].北京：中国轻工业出版社,2003：230,240.
[77]张金中,王中林,刘俊等.自组装纳米结构[M].北京：化学工业出版社,2005：14-16.
[78]张立言,王芬,朱建锋等.反向微乳液法合成ZnO纳米棒及其生长机理研究[J].人工晶体学报,2011,40(5)：1224-1228.
[79]J.S.Beck, J.C.Vartuli, W.J.Roth, et al. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates [J]. Journal of America Chemical Society,1992, 114:10834-10843.
[80]Bian Tianbin, Yin Xuefeng, Fan Jie, et al. Study on the effect of surfactants on morphologies of trigonal selenium in microfluidic reactor [J]. Materials Research Bulletin,2010,45:113-117.
[81]Mei Chee Tan, Lara Al-Baroudi, Richard E. Riman. Surfactant effects on efficiency enhancement of Infrared-to-Visible upconversion emissions of NaYF4:Yb-Er [J]. ACS Applied Materials Interfaces,2011,3:3910-3915.
[82]Hisao Sugihara, Kotaro Inoue, Maiko Nakayama, et al. A novel nanotube of composite of calcium carbonate and calcium sulfate [J]. Materials Letters,2009,63:322-324.
[83]T. Jeevananda. Joong Hee Lee, Siddaramaiah. Preparation of polyaniline nanostructrures using sodium dodecylsulphate [J]. Materials Letters,2008,3995-3998.
[84]Zhang Shengyi, Zhang Juan, Liu Yi, et al. Electrochemical synthesis of selenium nanotubes by using CTAB soft-template [J]. Electrochimica Acta,2005,50:4365-4370.
[85]Mitsunori Yada, Masami Mihara, Shingi Mouri, et al. Rare Earth (Er, Tm, Yb, Lu) Oxide Nanotubes Templated by Dodecylsulfate Assemblies [J]. Advanced Materials,2002, 14(4):309-313.
[86]Wu Changfeng, Qin Weiping, Qin Guanshi, et al. Photoluminescence from surfactant-assembled Y2O3:Eu nanotubes [J]. Applied Physics Letters,2003,82(4): 520-522.
[87]Masami Sekita, Kenichi Iwanaga, Tomomi Hamasuna, et al. Strong Eu emission of annealed Y2O3:Eu nanotube and nano-sized crystals [J]. Physica status solidi,2004, 241(13):R71-R74.
[88]冯一飞,魏长平,管宏伟等.掺杂表面活性剂及金属离子对纳米Y2O3:Eu3+粉体的发光性能的影响[J].中国稀土学报,2006,24(增刊)：78-81.
[89]吴长峰,秦伟平,张继森等.表面活性剂组装的Y2O3:Eu3+纳米管及其位置选择光谱[J].中国稀土学报,2003,21(6)：631-634.
[90]李渝,尹剑波,赵晓鹏等.两步法制备单分散的Li掺杂Y2O3:Eu3+微球及其发光性能[J].功能材料,2011,42(2)：336-338.
[91]杨雷,唐元洪,陈江华等Y2O3:Eu3+(?)内米管阵列的荧光和拉曼光谱研究[J].功能材料,2008,39(2)：205-208.
[92]Murazaki Y, Arai K, Ichinomiya K. A new long persistence red phosphor [J]. Japanese Rare Earth,1999,35(1):41-45.
[93]Holsa J, Laamanen T, Lastusaari M, et al. Effect of Mg2+ and Ti doping on the luminescence of Y2O2S:Eu3+[J]. Optical Materials,2009,31:1791-1793.
[94]Zhang Pengyue, Hong Zhanglian, Shen Huaxiang, et al. Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor [J]. Journal Of Rare Earths,2006, 24(12):115-118.
[95]Li Xu. Yang Zhiping, Guan Li, et al. Fabrication and luminescence properties of red emitting phosphor Y2O2S:Sm3+ for white LED by combustion method [J]. Journal of Alloys and Compounds,2008,464:565-568.
[96]赵淑金,林元华,张中太,等.凝胶法制备稀土掺杂的超细SrAl2O4基发光材料及其性能研究[J].硅酸盐学报,2002,30(6)：771-774.
[97]Chen R. Glow Curves with General Order Kinetics [J]. Journal of the Electrochemical Society:Solid State Science,1969,116(9):1254-1257.
[98]Huang Ping, Wu Yaqiao, Cui Cai-e, etc. Enhancement of luminescence and afterglow in Cao.8Zno.2Ti03:Pr3+by Nb5+substitution for Ti4+[J]. Journal of Rare Earths,2012,30(2): 100-104.
[99]Liu Bo, Shi Chaoshu, Qi Zeming. White-light long-lasting phosphorescence from Tb3+-activated Y2O2S phosphor [J]. Journal of Physics and Chemistry of Solids,2006, 67:1674-1677.
[100]林林,尹民,施朝淑,等.红色长余辉材料Mg2Si04:Dy3+,Mn2+的制备及发光特性[J].发光学报,2006,27(3)：331-336.
[101]张希艳,姜薇薇,卢利平,等.SrAl2O4:Eu2+,Dy3+纳米长余辉发光材料的制备与表征[J].无机化学学报,2004,12(12)：1397-1400.
[2]戴俊.稀土掺杂发光材料溶胶-凝胶法制备与发光性能研究[D].杭州：浙江大学,2011.
[3]刘应亮,雷炳富,邝金勇等.长余辉发光材料研究进展[J].无机化学学报,2009,25(8)：1323-1329.
[4]Marcus Alden, Alaa Omrane, Mattias Richter, et al. Thermographic phosphors for thermometry:A survey of combustion applications [J]. Progress in Energy and Combustion Science,2011,37:422-461.
[5]孙继兵,王海容,安雅琴等.长余辉发光材料研究进展[J].稀土金属材料与工程,2008,37(2)：189-194.
[6]郑继明,徐琰,吕峰等.Sr2SiO4:Eu2+-一维纳米棒的合成及性能研究[J].光学学报,2011,31(11)：1116002-1-1116002-4.
[7]孙家跃,夏志国,杜海燕.稀土红色长余辉发光材料研究进展[J].中国稀土学报,2005,23(3)：257-265.
[8]翟永清,游志江,王欣等.电荷补偿剂对Sr2MgSi207:Eu3+红色发光粉机构和性能的影响[J].硅酸盐学报,2011,39(12)：1887-1891.
[9]曲艳东,李晓杰,陈涛等.铝酸盐系长余辉发光材料的研究新进展[J].稀有金属,2006,30(1)：100-106.
[10]阎武钊,林林,陈永虎等.Mn4+掺杂的新型铝酸盐红色长余辉材料[J].发光学报,2008,29(1)：114-118.
[11]王细凤,夏威,肖志国.一种新型红色荧光粉CaAl12O19:Eu,Mn的制备及发光性能[J].发光学报,2009,30(3)：405-408.
[12]尚用甲,郑峰.草酸盐共沉淀法制备CaTiO3:Pr3+长余辉发光材料的性能研究[J].功能材料,2009,40(1)：17-19.
[13]綦艳,孟建新,时朝璞等.纳米长余辉发光材料CaTiO3:Pr的制备及表征[J].光谱学与光谱分析,2007,27(7)：1287-1290.
[14]杨丽丽,邹少瑜,王荣等.乙二醇辅助水热法制备不同形貌的CaTiO3/CaTiO3:Pr 微晶[J].无机化学学报,2010,26(8)：1345-1348.
[15]崔彩娥,田艳红,黄平等.烧结温度对红色长余辉发光材料Cao.8Zno.2TiO3:Pr3+,Na+性能的影响[J].人工晶体学报,2011,40(4)：958-962.
[16]周文,余丽萍,廉世勋等.前驱溶液的PH值对制备Ca2Zn4Ti16038:Pr3+,Na+发光粉物相、形貌和发光性质的影响[J].发光学报,2010,31(5)：712-718.
[17]Liu Guixia, Hong Guangyan, Dong Xiangting, et al. Synthesis of Y2O3:Eu3+Hollow Spheres Using Silica as Templates [J]. Journal of Rare Earths,2007,25:407-411.
[18]Zhang Ming, Li Xinhai, Wang Zhixing, et al. Synthesis of Y2O3:Eu3+ phosphors by surface diffusion and their photoluminescence properties [J]. Transactions of Nonferrous Metals Society of China,2010,20:115-118.
[19]Jung Hyun Jeong, Hyun Kyoung Yang, Byung Kee Moon, et al. Li-doping effect on enhancement of photoluminescence in Gd2O3:Eu3+ films [J]. Optical Materials,2006,28: 693-697.
[20]Li Yanhong, Hong Guangyan. Synthesis and luminescence properties of nanocrystalline Gd2O3:Eu3+ by combustion process [J]. Journal of Luminescence,2007,124:297-301.
[21]Gao Shiyong, Lu Hongliang, Nie Yanguang, et al. Structural transition induced by the release of residual stress in the complex of cubic and monoclinic Gd2O3:Eu nanoparticles [J]. Materials Letters,2007,61:4003-4005.
[22]Zhou Liya, Wang Wei, Huang Junli, et al. Preparation and characterization of Gd2O3:Eu3+ rods by surfactant assemblies-microwave heating [J]. Optik,2010,121: 1516-1519.
[23]翟永清,刘元红,孟媛等.微波法合成红色长余辉发光材料Gd2O2S:Eu,Mg,Ti及其发光特性[J].光谱学与光谱分析,2007,27(4)：634-638.
[24]Zhang Pengyue, Hong Zhanglian, Shen Huaxiang, et al. Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor [J]. Journal of Rare Earths,2006,24: 115-118.
[25]贺干武,刘应亮,张俊文.沉淀法合成纳米晶长余辉材料Y2O2S:Eu3+,Ti [J].无机化学学报,2007,23(2)：315-318.
[26]Yang Zhiping, Li Xingmin, Liu Chong, et al. Co-Precipitation Synthesis and Spectral Characteristics of Long Afterglow Phosphor Y2O2S:Sm3+,Mg2+,Ti4+[J]. Journal of Rare Earths,2007,25:23-26.
[27]Zeng Huihui, Zhou Xinmu, Zhang Li, et al. Synthesis and luminescence properties of a novel red long lasting phosphor Y2O2S:Eu3+,Si4+,Zn2+[J]. Journal of Alloys and Compounds,2008,460:704-707.
[28]Li Wenyu, Liu Yingliang, Ai Pengfei. Synthesis and luminescence properties of red long-lasting phosphor Y2O2S:Eu3+,Mg2+,Ti4+nanoparticles [J]. Materials Chemistry and Physics,2010,119:52-56.
[29]Ji Tongkun, Jiang Hongyi, Chen Fei. Afterglow phosphor materials Y2O2S:Eu,Mg,Ti doped with various Gd concentrations [J]. Journal of Alloys and Compounds,2010,502: 180-183.
[30]Wang Luxiang, Zhang Li, Huang Yudai, et al. Effects of Gd3+ and Lu3+ co-doping on the long afterglow properties of yellowish-orange phosphor Y2O2S:Ti4+,Mg2+[J]. Journal of Luminescence,2009,129:1032-1035.
[31]赵春雷,胡运生,畅永锋等.Y2O2S:Eu,Mg,Ti,Tb红色长时发光材料的研究[J].中国稀土学报,2002,20(6)：593-596.
[32]周新木,曾慧慧.红色长余辉材料Y2O2S:Eu,Si,M(M=Mg,Ca,Sr,Ba)的制备及发光性能[J].发光学报,2010,31(1)：59-63.
[33]Guo Chongfeng, Huang Dexiu, SuQiang. Methods to improve the fluorescence intensity of CaS:Eu2+ red-emitting phosphor for white LED [J]. Materials Science and Engineering B,2006,130:189-193.
[34]Yoshiyuki Kojima, Kenichi Aoyagi, Tamotsu Yasue. Afterglow mechanism and thermoluminescence of red-emitting CaS:Eu2+,Pr3+ phosphor with incorporated Li+ ion upon visible light irradiation [J]. Journal of Luminescence,2007,126:319-322.
[35]Lu Liping, Zhang Xiyan, Bai Zhaohui, et al. Synthesis and characterization of IR up-conversion material CaS:Eu,Sm by low-temperature combustion synthesis method [J]. Materials Research Bulletin,2009,44:207-210.
[36]Song Enhai, Zhao Weiren, Zhou Guoxiong, et al. Luminescence properties of red phosphors Ca10Li(P04)7:Eu3+[J]. Journal of Rare Earths,2011,29(5):440-443.
[37]Yang Baozhu, Yang Zhiping, Liu Yufeng, et al. Synthesis and photoluminescence properties the high-brightness Eu3+-doped Sr3Y(PO4)3 red phosphors [J]. Ceramics International,2012,02,080.
[38]I.M.Nagpure, S.J.Dhoble, Manoj Mohapatraa, et al. Dependence of Eu3+Luminescence dynamics on the structure of the combustion synthesized Srs(PO4)3F host [J]. Journal of Alloys and Compounds,2011,509:2544-2551.
[39]杨继兰,王卓,刘慧等.用燃烧法和沉淀法制备橙红色Sr5(PO4)3X:Eu3+,Na+(X=F,Cl)荧光粉[J].硅酸盐学报,2011,39(6)：913-917.
[40]Yang Lan, Zhou Liqun, Huang Ying, et al. Ag-catalyzed synthesis of europium borate Eu(BO2)3 nanowires, growth mechanism and luminescent properties [J]. Materials Research Bulletin,2011,46:239-243.
[41]Meng Fangui, Zhang Xinmin, Li Wenlan, et al. Luminescence and time-resolved spectroscopy properties of (Gd1-xEux)(BO2)3 multicrystals [J]. Journal of Physics and Chemistry of Solids,2012,73:564-567.
[42]王静,苏锵,王淑彬.杂质离子对Y2O3:Eu3+发光性能的影响[J].功能材料,2002,33(5)：558-560.
[43]杨志平,郭智,朱胜超等.Eu3+摩尔浓度对Y2O2S:Eu3+,Mg2+,Ti4+红色长余辉材料光谱的影响[J].光谱学与光谱分析,2004,24(12)：1506-1510.
[44]Jorma Holsa, Taneli Laamanen, Mika Lastusaari, et al. Effect of Mg2+ and TiⅣ doping on the luminescence of Y2O2S:Eu3+[J]. Optical Materials,2009,31:1791-1793.
[45]董岩,蒋建清,刘刚等.烧结工艺对Y2O3:Eu3+荧光粉颗粒形貌的影响[J].功能材料,2004，35(3)：352-356.
[46]周东方,施朝淑,戚泽明等Y2O2S:Eu,Ti,Mg红色长余辉的温度依赖[J].中国稀土学报,2006,24(1)：18-21.
[47]Wang Yuha, Wang Zhilong. Characterization of Y2O2S:Eu3+,Mg2+,Ti4+ Long-Lasting Phosphor Synthesized by Flux Method [J]. Journal of Rare Earths,2006,24:25-28.
[48]Zhang Junying, Zhang Zhongtai, Tang Zilong, et al. A new method to synthesize long afterglow red phosphor [J]. Ceramics International,2004,30:225-228.
[49]罗昔贤,曹望和.纳米Y2O2S:Eu的燃烧法合成和Eu3+离子荧光探针物相分析[J].功能材料,2007,38(12)：2064-2070.
[50]孟庆裕,陈宝玖,许武等.立方相Y2O3:Eu纳米晶中C2格位Eu3+的5Do能级量子效率[J].光谱学与光谱分析,2006,26(8)：1377-1381.
[51]刘晃清,王玲玲,李宏健等.氧化物纳米材料Y2O3:(Yb3+,Er3+)上转换发光性质的研究[J].光谱学与光谱学分析,2006,26(8)：1396-1399.
[52]王超男,王志芳,张慰萍等.前驱溶液的PH值对Y2O2S:Eu3+荧光粉发光性质的 影响[J].原子与分子物理学报,2008,25(4)：760-766.
[53]翟永清,杨国忠,刘宇等.新型红色荧光粉SrO·Y2O3:Eu的合成及其发光性能研究[J].光谱学与光谱学分析,2008,28(3)：522-526.
[54]罗宏雷,黄莉蕾,张伦.纳米晶Y2O2S:Eu3+的反常拉曼散射[J].光散射学报,2007,19(3)：219-224.
[55]廖亮,张玉奇,李治霞等.新型红色长余辉发光材料Y2O3:Eu3+,Ca2+,Ti4+的燃烧合成和性能表征[J].稀土,2006,27(2)：26-29.
[56]李堂刚,刘素文,王恩华等Y2O3:Yb3+,Tm3+纳米材料的可见及紫外上转换发光[J].物理学报,2011,60(7)：073201.
[57]孙彦彬,邱关明,陈永杰等.稀土发光材料的合成方法[J].稀土,2003,24(1)：43-48.
[58]孙阳艺,罗思媛,费慧龙等.铕掺杂无机红色荧光材料的研究进展[J].电子元件与材料,2010,29(5)：75-78.
[59]Qiao Yanmin, Guo Hai. Upconversion properties of Y2O3:Er films prepared by sol-gel method [J]. Journal of Rare Earths,2009,27(3):406-410.
[60]Maria de Andrade Gomes, Mario Ernesto Giroldo Valerio, and Zelia Soares Macedo. Particles Size Control of Prepared via a Coconut Water-Assisted Sol-Gel Method [J]. Journal of Nanomaterials,2011.
[61]杨志平,李兴民,杨勇等.共沉淀法制备Y2O2S:Eu3+,Mg2+,Ti4+红色长余辉材料[J].发光学报,2006,27(2)：187-190.
[62]黄燕,胡运生,赵春雷等.共沉淀-熔盐焙烧法制备Y2O3:Eu及其发光性能的研究[J].中国稀土学报,2007,25(2)：157-161.
[63]司伟,高宏,王晶等.纳米晶Y2O3:Eu3+的合成及其热分析动力学[J].无机化学学报,2010,26(8)：1443-1449.
[64]徐国纲,张旭东,何文等.沉淀法制备纳米Eu:Y2O3荧光粉[J].稀有金属材料与工程,2007,36(增刊1)：55-57.
[65]Wu Xiaoyong, Liang Yujun, Liu Rong, et al. The photoluminescence properties of Y2O3:Eu3+ prepared by surfactant assisted co-precipitation-molten salt synthesis [J]. Materials Research Bulletin,2010,45:594-597.
[66]杨利颖,王进贤,董相廷等.微纳米稀土硫氧化物的合成方法研究进展[J].中国稀土学报,2011,29(6)：643-654.
[67]刘桂霞,洪广言,王进贤等.水热法制备具有光滑表面的球形Y2O3:Eu3+发光材料[J].无机化学学报,2006,22(8)：1535-1539.
[68]Ai Pengfei, Li Wenyu, Xiao L.Y., et al. Monodisperse nanospheres of yttrium oxysulfide: Synthesis, characterization, and luminescent properties [J]. Ceramics International,2010, 36:2169-2174.
[69]刘桂霞,王振东,王进贤等.一维Y2O3:Eu3+纳米发光材料的制备与表征[J].无机化学学报,2008,24(1)：149-152.
[70]李文宇,刘应亮,艾鹏飞.水热-微波法合成纳米晶长余辉发光材料Y2O2S:Eu3+,Mg,Ti [].无机化学学报,2008,24(5)：772-776.
[71]Li Wenyu, Liu Yingliang, Ai Pengfei, et al. Synthesis and characterization of Y2O2S:Eu3+,Mg2+,Ti4+ nanorods via a solvothermal routine [J]. Journal of Rare Earths, 2009,27(6):895-899.
[72]艾鹏飞,刘应亮,,李毅东等.纳米晶Y2O2S:Eu3+,Mg2+,Ti4+长余辉发光材料的制备[J].功能材料,2010,41(6)：986-989.
[73]Wu Yanli, Sun Weili, Zhou Xuezhen, et al. Hydrothermal synthesis of Y(OH)3,Y(OH)3:Eu3+ nanotubes and the photoluminescence of Y(OH)3:Eu3+,Y2O3:Eu3+ [J]. Journal of Rare Earths,2009,27(5):767-772.
[74]王艳丽,张明旭,李本侠等.软模板法六边形纳米Pb粒子的超声制备与表征[J].无机化学学报,2011,27(10)：1914-1918.
[75]周波.表面活性剂[M].北京：化学工业出版社,2006：13,16,18.
[76]赵国玺,朱瑶.表面活性剂作用原理[M].北京：中国轻工业出版社,2003：230,240.
[77]张金中,王中林,刘俊等.自组装纳米结构[M].北京：化学工业出版社,2005：14-16.
[78]张立言,王芬,朱建锋等.反向微乳液法合成ZnO纳米棒及其生长机理研究[J].人工晶体学报,2011,40(5)：1224-1228.
[79]J.S.Beck, J.C.Vartuli, W.J.Roth, et al. A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates [J]. Journal of America Chemical Society,1992, 114:10834-10843.
[80]Bian Tianbin, Yin Xuefeng, Fan Jie, et al. Study on the effect of surfactants on morphologies of trigonal selenium in microfluidic reactor [J]. Materials Research Bulletin,2010,45:113-117.
[81]Mei Chee Tan, Lara Al-Baroudi, Richard E. Riman. Surfactant effects on efficiency enhancement of Infrared-to-Visible upconversion emissions of NaYF4:Yb-Er [J]. ACS Applied Materials Interfaces,2011,3:3910-3915.
[82]Hisao Sugihara, Kotaro Inoue, Maiko Nakayama, et al. A novel nanotube of composite of calcium carbonate and calcium sulfate [J]. Materials Letters,2009,63:322-324.
[83]T. Jeevananda. Joong Hee Lee, Siddaramaiah. Preparation of polyaniline nanostructrures using sodium dodecylsulphate [J]. Materials Letters,2008,3995-3998.
[84]Zhang Shengyi, Zhang Juan, Liu Yi, et al. Electrochemical synthesis of selenium nanotubes by using CTAB soft-template [J]. Electrochimica Acta,2005,50:4365-4370.
[85]Mitsunori Yada, Masami Mihara, Shingi Mouri, et al. Rare Earth (Er, Tm, Yb, Lu) Oxide Nanotubes Templated by Dodecylsulfate Assemblies [J]. Advanced Materials,2002, 14(4):309-313.
[86]Wu Changfeng, Qin Weiping, Qin Guanshi, et al. Photoluminescence from surfactant-assembled Y2O3:Eu nanotubes [J]. Applied Physics Letters,2003,82(4): 520-522.
[87]Masami Sekita, Kenichi Iwanaga, Tomomi Hamasuna, et al. Strong Eu emission of annealed Y2O3:Eu nanotube and nano-sized crystals [J]. Physica status solidi,2004, 241(13):R71-R74.
[88]冯一飞,魏长平,管宏伟等.掺杂表面活性剂及金属离子对纳米Y2O3:Eu3+粉体的发光性能的影响[J].中国稀土学报,2006,24(增刊)：78-81.
[89]吴长峰,秦伟平,张继森等.表面活性剂组装的Y2O3:Eu3+纳米管及其位置选择光谱[J].中国稀土学报,2003,21(6)：631-634.
[90]李渝,尹剑波,赵晓鹏等.两步法制备单分散的Li掺杂Y2O3:Eu3+微球及其发光性能[J].功能材料,2011,42(2)：336-338.
[91]杨雷,唐元洪,陈江华等Y2O3:Eu3+(?)内米管阵列的荧光和拉曼光谱研究[J].功能材料,2008,39(2)：205-208.
[92]Murazaki Y, Arai K, Ichinomiya K. A new long persistence red phosphor [J]. Japanese Rare Earth,1999,35(1):41-45.
[93]Holsa J, Laamanen T, Lastusaari M, et al. Effect of Mg2+ and Ti doping on the luminescence of Y2O2S:Eu3+[J]. Optical Materials,2009,31:1791-1793.
[94]Zhang Pengyue, Hong Zhanglian, Shen Huaxiang, et al. Luminescence Characterization of Mg Doped Y2O2S:Ti Long Afterglow Phosphor [J]. Journal Of Rare Earths,2006, 24(12):115-118.
[95]Li Xu. Yang Zhiping, Guan Li, et al. Fabrication and luminescence properties of red emitting phosphor Y2O2S:Sm3+ for white LED by combustion method [J]. Journal of Alloys and Compounds,2008,464:565-568.
[96]赵淑金,林元华,张中太,等.凝胶法制备稀土掺杂的超细SrAl2O4基发光材料及其性能研究[J].硅酸盐学报,2002,30(6)：771-774.
[97]Chen R. Glow Curves with General Order Kinetics [J]. Journal of the Electrochemical Society:Solid State Science,1969,116(9):1254-1257.
[98]Huang Ping, Wu Yaqiao, Cui Cai-e, etc. Enhancement of luminescence and afterglow in Cao.8Zno.2Ti03:Pr3+by Nb5+substitution for Ti4+[J]. Journal of Rare Earths,2012,30(2): 100-104.
[99]Liu Bo, Shi Chaoshu, Qi Zeming. White-light long-lasting phosphorescence from Tb3+-activated Y2O2S phosphor [J]. Journal of Physics and Chemistry of Solids,2006, 67:1674-1677.
[100]林林,尹民,施朝淑,等.红色长余辉材料Mg2Si04:Dy3+,Mn2+的制备及发光特性[J].发光学报,2006,27(3)：331-336.
[101]张希艳,姜薇薇,卢利平,等.SrAl2O4:Eu2+,Dy3+纳米长余辉发光材料的制备与表征[J].无机化学学报,2004,12(12)：1397-1400.