固相反应型Al_2O_3-TiB_2复相陶瓷涂层形成机理及力学性能研究
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摘要
以Al-TiO_2-B_2O_3为反应体系,经机械球磨制成超细粉体,混以一定比例的磷酸二氢铝胶粘剂涂覆于Q235钢表面进行热固化,通过粉体颗粒之间的固相反应于700℃原位合成了Al_2O_3-TiB_2复相陶瓷涂层。
用SEM、激光粒度分布仪、XRD、DTA等设备和手段研究了Al-TiO_2-B_2O_3复合粉体的微观形貌、粒度分布、物相组成、晶粒度变化等机械力化学及热化学特征;采用热力学、动力学方法研究了涂层的形成机理,并对涂层的结合强度、耐磨性等力学性能进行了测试。
结果表明,机械力化学作用使Al-TiO_2-B_2O_3体系的热化学反应在670℃就可发生,由此在700℃制备的涂层,其物相组成为Al_2O_3,TiB_2并含少量未发生反应的Al,TiO_2以及辅料反应生成的Cr_2O_3和MgAl_2O_4等。当涂层骨料中Al、TiO_2、B2O_3物质的量比为10:3:3,骨料与粘结剂的质量比为1.5:1时,涂层性能最佳,结合强度可达13.4MP,热震次数可达45次;耐磨性提高为基底的3.21倍。
The Al-TiO2-B2O3 reaction system superfine powder made by mechanical ball milling is mixed with a proportional aluminum phosphate adhesive and deposited on the surface of Q235 and then undergo thermocuring, through the solid-state reaction of which, Al_2O_3-TiB_2 multiphase ceramic coating is in situ synthesized at 700℃.
The mechano-chemical and thermo-chemical characteristics including micro-morphology, particle distribution, phase composition, grain size changes etc. of the Al-TiO_2-B_2O_3 composite powder are studied with SEM, laser fineness gage, XRD, DTA etc..The formation mechanism of coating is investigated with thermodynamics and dynamic method. The mechanical properties such as bond strength, wear resistance etc. is tested.
Results indicate that the mechanochemical force can make the Al-TiO_2-B_2O_3 system react at 670℃. Accordingly, the coating formed at 700℃is composed of Al_2O_3, TiB_2 and a few of Al,TiO_2, Cr_2O_3 and MgAl_2O_4. When the ratio of Al to TiO2 to B_2O_3 is 10:3:3 in amount of substance and of the aggregate to adhesive is 1.5:1 in weight, the coating is the best. Its bonding strength can reach 13.4MP, thermal shock times can reach 45, and wear resistance improves 3.21 times than the base Q235.
用SEM、激光粒度分布仪、XRD、DTA等设备和手段研究了Al-TiO_2-B_2O_3复合粉体的微观形貌、粒度分布、物相组成、晶粒度变化等机械力化学及热化学特征;采用热力学、动力学方法研究了涂层的形成机理,并对涂层的结合强度、耐磨性等力学性能进行了测试。
结果表明,机械力化学作用使Al-TiO_2-B_2O_3体系的热化学反应在670℃就可发生,由此在700℃制备的涂层,其物相组成为Al_2O_3,TiB_2并含少量未发生反应的Al,TiO_2以及辅料反应生成的Cr_2O_3和MgAl_2O_4等。当涂层骨料中Al、TiO_2、B2O_3物质的量比为10:3:3,骨料与粘结剂的质量比为1.5:1时,涂层性能最佳,结合强度可达13.4MP,热震次数可达45次;耐磨性提高为基底的3.21倍。
The Al-TiO2-B2O3 reaction system superfine powder made by mechanical ball milling is mixed with a proportional aluminum phosphate adhesive and deposited on the surface of Q235 and then undergo thermocuring, through the solid-state reaction of which, Al_2O_3-TiB_2 multiphase ceramic coating is in situ synthesized at 700℃.
The mechano-chemical and thermo-chemical characteristics including micro-morphology, particle distribution, phase composition, grain size changes etc. of the Al-TiO_2-B_2O_3 composite powder are studied with SEM, laser fineness gage, XRD, DTA etc..The formation mechanism of coating is investigated with thermodynamics and dynamic method. The mechanical properties such as bond strength, wear resistance etc. is tested.
Results indicate that the mechanochemical force can make the Al-TiO_2-B_2O_3 system react at 670℃. Accordingly, the coating formed at 700℃is composed of Al_2O_3, TiB_2 and a few of Al,TiO_2, Cr_2O_3 and MgAl_2O_4. When the ratio of Al to TiO2 to B_2O_3 is 10:3:3 in amount of substance and of the aggregate to adhesive is 1.5:1 in weight, the coating is the best. Its bonding strength can reach 13.4MP, thermal shock times can reach 45, and wear resistance improves 3.21 times than the base Q235.
引文
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