离型剂稳定性及其应用效果的微观因素研究
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摘要
本课题主要研究了影响纳米SiO_2颗粒在离型剂中稳定分散的因素,通过研究表面活性剂-PMMA-纳米SiO_2颗粒三者之间的相互作用,揭示了表面活性剂、固体颗粒这两种微量物质对分散体系应用性能影响的本质。目的是把表面活性剂-PMMA-纳米SiO_2颗粒三者在离型剂中的配比调整到较佳状态,使得离型剂具有较佳的稳定性,即纳米SiO_2颗粒能够较好的在离型剂胶体中分散开,从而提高离型剂的应用性能。
对纳米SiO_2颗粒在离型剂中的稳定性研究,是先在重力场下和离心力场下对离型剂中的表面活性剂-PMMA-纳米SiO_2颗粒三者之间相互作用进行研究,再制定正交试验进行极差分析离型剂各组分对离型剂稳定性影响的大小顺序,从而确定出较佳稳定性的离型剂。最后将所确定的较佳稳定性离型剂的贮存稳定性、涂膜固化性、剥离强度和离型率等应用性能与原有的离型剂进行比较测试,从而得到具有优良离型性能、稳定性和固化性的离型剂较佳配比。
通过对离型剂贮存稳定性和涂膜固化性进行实验,证实了所研制的离性剂具有良好的稳定性和固化性;采用离型层180°剥离法测得离型层的剥离强度小,即离型剂涂膜与PET薄膜间的附着力小;运用Visual C++软件编写离型率的计算程序,证明所制离型剂涂膜的离型率很小,满足热转印离型的要求;用透射电镜揭示离型物质在成膜物质中的分散状态和微观结构,从微观上说明离型剂稳定性的原因;用红外光谱对离型剂中表面活性剂-PMMA-纳米SiO_2颗粒三者之间的结合作用进行分析;最后通过软物质熵理论等理论对表面活性剂-PMMA-纳米SiO_2颗粒三者之间的相互作用进行理论分析说明。
研究成果表明:通过对离型剂中表面活性剂-PMMA-纳米SiO_2颗粒三者之间相互作用的研究,得到了稳定性较好的离型剂,改善了原有离型剂的应用效果。
In this paper, the affect factors on the stability of nano-SiO2 in release agent are mainly studied. By research the interaction of lipid surfactant—PMMA—nano-SiO_2, it reveals the essence effect of lipid surfactant and solid particles to application performance of disperse system. The goal is to adjust the proportion of lipid surfactant—PMMA—nano-SiO_2 in release agent to an optimal state. Then make the release agent has better stability, that means nano-SiO_2 totally dispersed in colloid of release agent, improves the application of release agent.
The study on stability of nano-SiO_2 in release agent through the interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent under gravity field and centrifugal field at first. By making the orthogonal test and range analysis, then discuss size order effect of components of release agent, and obtain a better stability proportion of release agent. At last the stockpile stability of release agent, coating film solidify, peeling intensity and release percentage are discussed between the former release agent and the new. Then a kind of release agent with excellent release capability, stability and solidy is found, and optimal component and proportion of release agent will be confirmed.
The stockpile stability of release agent and coating film solidify are well by experimenting; The peeling intensity of release layer (the cling strength between coating film and PET film)is tested little by using 180°peeling method; Using Visual C++ software to compile program which can account release percentage, and the release percentage is testified very small, this result can satisfy release request in heat transfer process; The result of TEM also show dispersion state and microscopic structure of release matter in coating matter, and explain the stability of release agent by microcosmic technic. With the analysis of infrared spectrum, the combination interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent has been studied. Finally the interaction of lipid surfactant—PMMA—nano-SiO_2 has been theoretical analysed by the theory of soft matter and entropy theory etc.
It indicates: The study on the interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent, obtain a better stability release agent, improve the application effect.
对纳米SiO_2颗粒在离型剂中的稳定性研究,是先在重力场下和离心力场下对离型剂中的表面活性剂-PMMA-纳米SiO_2颗粒三者之间相互作用进行研究,再制定正交试验进行极差分析离型剂各组分对离型剂稳定性影响的大小顺序,从而确定出较佳稳定性的离型剂。最后将所确定的较佳稳定性离型剂的贮存稳定性、涂膜固化性、剥离强度和离型率等应用性能与原有的离型剂进行比较测试,从而得到具有优良离型性能、稳定性和固化性的离型剂较佳配比。
通过对离型剂贮存稳定性和涂膜固化性进行实验,证实了所研制的离性剂具有良好的稳定性和固化性;采用离型层180°剥离法测得离型层的剥离强度小,即离型剂涂膜与PET薄膜间的附着力小;运用Visual C++软件编写离型率的计算程序,证明所制离型剂涂膜的离型率很小,满足热转印离型的要求;用透射电镜揭示离型物质在成膜物质中的分散状态和微观结构,从微观上说明离型剂稳定性的原因;用红外光谱对离型剂中表面活性剂-PMMA-纳米SiO_2颗粒三者之间的结合作用进行分析;最后通过软物质熵理论等理论对表面活性剂-PMMA-纳米SiO_2颗粒三者之间的相互作用进行理论分析说明。
研究成果表明:通过对离型剂中表面活性剂-PMMA-纳米SiO_2颗粒三者之间相互作用的研究,得到了稳定性较好的离型剂,改善了原有离型剂的应用效果。
In this paper, the affect factors on the stability of nano-SiO2 in release agent are mainly studied. By research the interaction of lipid surfactant—PMMA—nano-SiO_2, it reveals the essence effect of lipid surfactant and solid particles to application performance of disperse system. The goal is to adjust the proportion of lipid surfactant—PMMA—nano-SiO_2 in release agent to an optimal state. Then make the release agent has better stability, that means nano-SiO_2 totally dispersed in colloid of release agent, improves the application of release agent.
The study on stability of nano-SiO_2 in release agent through the interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent under gravity field and centrifugal field at first. By making the orthogonal test and range analysis, then discuss size order effect of components of release agent, and obtain a better stability proportion of release agent. At last the stockpile stability of release agent, coating film solidify, peeling intensity and release percentage are discussed between the former release agent and the new. Then a kind of release agent with excellent release capability, stability and solidy is found, and optimal component and proportion of release agent will be confirmed.
The stockpile stability of release agent and coating film solidify are well by experimenting; The peeling intensity of release layer (the cling strength between coating film and PET film)is tested little by using 180°peeling method; Using Visual C++ software to compile program which can account release percentage, and the release percentage is testified very small, this result can satisfy release request in heat transfer process; The result of TEM also show dispersion state and microscopic structure of release matter in coating matter, and explain the stability of release agent by microcosmic technic. With the analysis of infrared spectrum, the combination interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent has been studied. Finally the interaction of lipid surfactant—PMMA—nano-SiO_2 has been theoretical analysed by the theory of soft matter and entropy theory etc.
It indicates: The study on the interaction of lipid surfactant—PMMA—nano-SiO_2 in release agent, obtain a better stability release agent, improve the application effect.
引文
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[6]段振云,郑鹏,金嘉琦,n乎咏.PVC材料覆膜原理的研究与设备的研制[J].沈阳工业大学学报,2001,11(23):1-2
[7]钱军浩.新型油墨印刷技术[M].北京:中国轻工业出版社,2002
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[23]黄应钦,成晓玲,白晓军,向雄志,匡同春.表面活性剂在超细粉体植被和分散中的应用[J].日用化学工业,2006,36(1):30-33
[24]杨金龙,吴建镜,黄勇等.陶瓷粉末颗粒尺寸测试、表征及分散[J].硅胶盐通报,1995,3(5):67-77
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[27]冯绪胜,刘洪国,郝京诚.胶体化学[M].化学工业出版社,2005
[28]沈钟,赵振国,王国庭.胶体于表面化学第三版[M].北京:化学工业出版社,2004
[29]李云雁,胡传荣.实验设计与数据处理[M].北京:化学工业出版社,2005
[30]茆诗松,周纪芗,陈颖.实验设计—学习指导与习题[M].北京:中国统计出版社,2005
[31]陈魁.实验设计与分析[M].北京:清华大学出版社,1996
[32]李津,余泳霆,董德祥.生物制药设备和分离纯化技术[M].北京:化学工业出版社,2003
[33]杜会静.纳米材料检测中透射电镜制样品的制备[J].理化检验—物理分册,2005,41(9):463-474
[34]唐雷钧,谢进,陈一,郑国祥,宗祥福.聚焦离子束(FIB)的透射电镜制样[J].电子显微学报,2000,19(4):513-514
[35]周玉,武高辉.材料分析测试技术—材料X射线衍射与电子显微分析[M].哈尔滨:哈尔滨工业大学出版社,1998
[36]钱苗根,姚寿山,张少宗.现代表面技术[M].北京:机械工业出版社,1999
[37]漆睿,戎詠华.X射线衍射与电子显微分析[M].上海:上海交通大学出版社,1992
[38]何斌,马天予等.Visual C++数字图像处理(第二版)[M].北京:人民邮电出版社,2002
[39]苏彦华等.Visual C++数字图像识别技术典型案例[M].北京:人民邮电出版社,2004
[40]虞伟钧,李强等.电镜图像分析法测定纳米碳酸钙的大小及其分布[J].电子显微学报,2006,25(增刊):144-155
[41]谢海安,陈汉全,王振轩,王伟.W/O型微乳法制备纳米SiO_2[J].化学与生物工程,2007,24(1):21-22
[42]Israelachvili J N.Intermolecular and Surface Force[M].New York Academic Press,1992
[43]胡博路,杭瑚.二氧化硅悬浮体的絮凝[J].物理化学学报,1999,15(1):87-90
[44]HENGLEIN AMIM.Colloidal nano-particles of semiconductors and metal:electomic structure and processes[J].Physical Chemistry Chemical Physics,1997,101(11):1562-1572
[45]Vrij A.Pure Appl[J].Chem.,1976,48:471
[46]Gast A P,Russel W B.Physics Today[J],1998,24
[47]Lekkerkerker H N W,et al.Europhys[J].Lett.,1992,20:559
[48]Vanel L,Clement E.Eur.Phys.J.B[J],1999,11:525
[49]Smid J,Novosad J.Inst.Chem.Eng.Symp.Ser.[J],1981,63:D3/V/1
[2]白松芳.烫印纸的结构及生产工艺[J].丝网印刷,2004,(11):29-31
[3]马晓燕,颜红侠.塑料装饰[M].北京:化学工业出版,2004
[4]白松芳,侯文华.非纸张烫印技术面面观[J].广东印刷,2005,(2):46-48
[5]白松芳,侯文华.烫印工艺技术简述[J].丝网印刷,2004,(10):36-41
[6]段振云,郑鹏,金嘉琦,n乎咏.PVC材料覆膜原理的研究与设备的研制[J].沈阳工业大学学报,2001,11(23):1-2
[7]钱军浩.新型油墨印刷技术[M].北京:中国轻工业出版社,2002
[8]L.E.Makela.Manufacture of base paper for silicone release coating applications[M].TAPPI,1978
[9]吴志浩.有机硅离型剂的种类和应用[J].上海造纸,1996,(12):164-166
[10]马文杰.离型剂发展动向[J].合成材料老化与应用,1994,(4):18-20
[11]Lubensky T C.Solid State Commun[J],1997,102:187
[12]de Gennes P G,Badoz J.Fragile Objects:Soft Matter[M],Hard Science,and the Thrill of Discovery,1996(中译本:卢定伟等译,冯端校.软物质与硬科学[M].湖南教育出版社,2000)
[13]Frenkel D.Physica A[J],1999,263:26
[14]Lekkerkerker H N W,Stroobants A.Nature[J],1998,393:305
[15]Zhou H J,Zhang Y,OuOyang Z C.Phys.Rev.Lett.[J],1999,82:4560
[16]Gast A P and Russel W B.Physics Today[J],1998,24
[17]Stutzmann N.Nature[J],2000,407:613
[18]马余强.软物质的自组织[J].物理学进展,2002,22(1):73-98
[19]Irnhof A,Dhont J K G.Experimental phase diagram of a binary colloidal hard2sphere mixture with a large size ratio.Physical Review Letters[J],1995,75(8):166221665
[20]Pusey P N,Megen W.Phase behaviour of concentrated suspendsions of nearly hard colloidal spheres.Nature[J],1986,(320):3402342
[21]Adams M,Dogic Z,Keller S L,et al.Entropically driven microphase transitions in mixtures of colloidal rods and spheres.Nature[J],1998,(393):3492352
[22]S.Asakura and F.Oosawa,J.Chem.phys.22,1255(1954)
[23]黄应钦,成晓玲,白晓军,向雄志,匡同春.表面活性剂在超细粉体植被和分散中的应用[J].日用化学工业,2006,36(1):30-33
[24]杨金龙,吴建镜,黄勇等.陶瓷粉末颗粒尺寸测试、表征及分散[J].硅胶盐通报,1995,3(5):67-77
[25]王兰芬.粉体工程研究中粉体的润湿与分散之间的关系[J].无机盐工业,1990,(6):16-18
[26]陆坤权,刘寄星.软物质物理学导论[M].北京大学出版社,2006
[27]冯绪胜,刘洪国,郝京诚.胶体化学[M].化学工业出版社,2005
[28]沈钟,赵振国,王国庭.胶体于表面化学第三版[M].北京:化学工业出版社,2004
[29]李云雁,胡传荣.实验设计与数据处理[M].北京:化学工业出版社,2005
[30]茆诗松,周纪芗,陈颖.实验设计—学习指导与习题[M].北京:中国统计出版社,2005
[31]陈魁.实验设计与分析[M].北京:清华大学出版社,1996
[32]李津,余泳霆,董德祥.生物制药设备和分离纯化技术[M].北京:化学工业出版社,2003
[33]杜会静.纳米材料检测中透射电镜制样品的制备[J].理化检验—物理分册,2005,41(9):463-474
[34]唐雷钧,谢进,陈一,郑国祥,宗祥福.聚焦离子束(FIB)的透射电镜制样[J].电子显微学报,2000,19(4):513-514
[35]周玉,武高辉.材料分析测试技术—材料X射线衍射与电子显微分析[M].哈尔滨:哈尔滨工业大学出版社,1998
[36]钱苗根,姚寿山,张少宗.现代表面技术[M].北京:机械工业出版社,1999
[37]漆睿,戎詠华.X射线衍射与电子显微分析[M].上海:上海交通大学出版社,1992
[38]何斌,马天予等.Visual C++数字图像处理(第二版)[M].北京:人民邮电出版社,2002
[39]苏彦华等.Visual C++数字图像识别技术典型案例[M].北京:人民邮电出版社,2004
[40]虞伟钧,李强等.电镜图像分析法测定纳米碳酸钙的大小及其分布[J].电子显微学报,2006,25(增刊):144-155
[41]谢海安,陈汉全,王振轩,王伟.W/O型微乳法制备纳米SiO_2[J].化学与生物工程,2007,24(1):21-22
[42]Israelachvili J N.Intermolecular and Surface Force[M].New York Academic Press,1992
[43]胡博路,杭瑚.二氧化硅悬浮体的絮凝[J].物理化学学报,1999,15(1):87-90
[44]HENGLEIN AMIM.Colloidal nano-particles of semiconductors and metal:electomic structure and processes[J].Physical Chemistry Chemical Physics,1997,101(11):1562-1572
[45]Vrij A.Pure Appl[J].Chem.,1976,48:471
[46]Gast A P,Russel W B.Physics Today[J],1998,24
[47]Lekkerkerker H N W,et al.Europhys[J].Lett.,1992,20:559
[48]Vanel L,Clement E.Eur.Phys.J.B[J],1999,11:525
[49]Smid J,Novosad J.Inst.Chem.Eng.Symp.Ser.[J],1981,63:D3/V/1