La-Ni-Cu三元系合金相图673K等温截面
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摘要
本文主要采用X射线粉末衍射法，同时结合差热分析等方法对La-Ni-Cu三元系合金相图673K等温截面进行了研究。结果表明：该等温截面由13个单相区，23个两相区和11个三相区组成。
在673K下，Cu在La_2Ni_7，LaNi_3，La_7Ni_(16)，La_2Ni_3和LaNi中的最大固溶度分别约为2，2，3，3和5at．％；Ni在LaCu_2和LaCu中的最大固溶度分别约为15at％和4at％；Cu和Ni可以无限固溶，LaCu_5和LaNi_5也是无限固溶，它们分别形成连续固溶体；Cu在La_7Ni_3以及Ni在LaCu_6在中的固溶度很小，在本实验条件下未能观察到。
本系统发现一个新相La_(10)Cu_(85)Ni_5，它属于面心立方晶系，点阵常数a=1.158nm。
The isothermal section of the phase diagram of the ternary system La-Ni-Cu has been investigated by X-ray diffraction, differential thermal analysis, optical microscopy and electron microscopy techniques. It consists of 13 single-phase regions, 23 two-phase regions and 11 three-phase regions. At 673 K, the maximum solid solubility of Cu in La2Ni7, LaNi3, La7Ni16, La2Ni3 and LaNi is about 2,2, 3, 3 and 5at.%Cu, respectively. The solid solubility of Cu in La7Ni3 and Ni in LaCu6 is too small to observe. Cu and Ni can replace each other in LaNis and LaCu5, the LaNis and LaCu5 form a continuous solid solution; Cu and Ni form a continuous solid solution too. The maximum solid solubility of Ni in LaCu2 and LaCu is about 15 and 4at%Ni, respectively. A new ternary compound La10Cu85Ni5 has been observed in the La-Ni-Cu ternary system. It belongs to a face-centered cubic lattice. Its lattice constant a is about equal to 1.158nm.
在673K下，Cu在La_2Ni_7，LaNi_3，La_7Ni_(16)，La_2Ni_3和LaNi中的最大固溶度分别约为2，2，3，3和5at．％；Ni在LaCu_2和LaCu中的最大固溶度分别约为15at％和4at％；Cu和Ni可以无限固溶，LaCu_5和LaNi_5也是无限固溶，它们分别形成连续固溶体；Cu在La_7Ni_3以及Ni在LaCu_6在中的固溶度很小，在本实验条件下未能观察到。
本系统发现一个新相La_(10)Cu_(85)Ni_5，它属于面心立方晶系，点阵常数a=1.158nm。
The isothermal section of the phase diagram of the ternary system La-Ni-Cu has been investigated by X-ray diffraction, differential thermal analysis, optical microscopy and electron microscopy techniques. It consists of 13 single-phase regions, 23 two-phase regions and 11 three-phase regions. At 673 K, the maximum solid solubility of Cu in La2Ni7, LaNi3, La7Ni16, La2Ni3 and LaNi is about 2,2, 3, 3 and 5at.%Cu, respectively. The solid solubility of Cu in La7Ni3 and Ni in LaCu6 is too small to observe. Cu and Ni can replace each other in LaNis and LaCu5, the LaNis and LaCu5 form a continuous solid solution; Cu and Ni form a continuous solid solution too. The maximum solid solubility of Ni in LaCu2 and LaCu is about 15 and 4at%Ni, respectively. A new ternary compound La10Cu85Ni5 has been observed in the La-Ni-Cu ternary system. It belongs to a face-centered cubic lattice. Its lattice constant a is about equal to 1.158nm.
引文
[1]刘光华，稀土固体材料学，机械工业出版社，1997
[2]徐光宪，稀土，冶金工业出版社，1995
[3]胡子龙，储氢材料，化学工业出版社，2002
[4]Sumita Srivastava,O.N.Srivastava,Journal of Alloy and Compounds 282(1999)197-205.
[5]金自宜，材料导报，1993．NO．3．P6
[6]刘红，韩莹，程云阶，沈阳航空工业学院学报，2000．3Vol7
[7]高金良，稀土，1995．Vol6
[8]大角泰章，金属氢化物的性能和应用，吴永宽，苗艳秋译，化学工业出版社，1990
[9]陈长聘等，稀土，1981．NO．1．1
[10]仇九等，稀土，1988．NO．4．1
[11]Percheron-Guegan Aetal,Journal of the Less-Commom Metals, 74(1980) 1; 109(1985) 287
[12]李永绣，魏坤，胡平贵，功能材料，23(1992)193
[13]Liang Jingkui, Wang Chaoguo, Phase Equilibrium And Hydrogen Absorption Of LaNi5-LaCu5 System,Acta Metallurgica Sinica,Vol. 18,592-598(1982)
[14]Deyuan Zhang,Jinke Tang and K.A.Gschneider, Jr, Materials Science Forum Vol 70-72 1991
[15]V.Paul-Boncour, M.Diaf, A.Percheron-Guegan and J.C.A.chard, J.Phys. (Paris) Colloq.C8, 47(1986) 1093
[16]V.Paul-Boncour, A.Percheron-Guegan, M.Diaf and J.C.Achard Journal of the Less-Common Metals 131 (1987)201-208
[17]H.Okamoto Joural of Phase Equilibria Vol.12 No5 1991
[18]A.V.Klimyenko,J.Seuntjens,L.L.Miller, B.J.Beaudry, R.A.Jacobson and K.A.Gschenidner, Journal of the Less-Common Metals. 144 (1988) 133-141
[19]朱延果，《广西大学硕士学位论文》，2001
[20]P.Villars Pearson's Handbook of Crystallographic Data Naterials Park,OH 1997
[21]Y.Y.Pan, P.Nash,in: T.B.Massalski, P.R.Subramanian, H.Okamoto, L.Kacprzak (Eds.), Binary Alloy Phase Diagrams,2nd Edition,ASM International,Materials Park, OH, 1991, pp.2406-2408
[22]D.J.Chakrabarti, D.E.Laughlin, S.W.Chen and Y.A.Chang, Binary Alloy Phase Diagrams, ASM International, Materials Park, OH, 1991, pp. 1442-1446.
[23]D.J.Chakrabarti, D.E.Laughlin, Binary Alloy Phase Diagrams, ASM International, Materials Park, OH, 1991, pp. 1428-1430.
[24]F.A.Shunk,Constitution of Binary Alloys,New York 1969
[25]R.P.Elliott,Constitution of Binary Alloys,New York 1965
[26]张圣弼，李道子，相图—原理、计算及在冶金中的应用，冶金工业出版社，1986
[27]李树棠，晶体X射线衍射学基础，冶金工业出版社，1990
[28]陆学善，相图与相变，中国科技大学出版社，1990
[29]梁敬魁，相图与相结构，科学出版社，1983
[30]Jade 5, XRD pattern processing, Materials Data Inc, 1999.
[31]梁敬魁，相图与相结构，科学出版社，1983
[32]梁敬魁，相图与相结构的测定，在全国X—射线衍射学术会议上的报告，1982
[33]顾菡珍，叶于蒲，相平衡和相图基础，北京大学出版社，1991
[34]潘钦科等，金相实验室，冶金工业出版社，1956
[35]韩德伟，金属学实验指导书，中南工业大学出版社，1990
[36]肖特．裴卓，金相浸蚀手册，科学普及出版社，1982
[37]魏全金，金属电子实验技术，冶金工业出版社，1990
[38]任怀亮，金相实验动手术，冶金工业出版社，1986
[39]侯增寿，卢光熙，《金属学原理》，上海科学技术出版社，1990
[40]Huaiying Zhou, Qingrong Yao, Yinghong Zhuang, Phase Relationships in the La-Ni-Si system at 673K,Journal Of Alloys and Compounds, 366(2004) 161-164.
[41]F.Meeyer-Liautaud, C.H.Allibert and J.M.Moreau,New Phase In The System La-Cu, Joumal Of The Less-Common Metals, 110,81-90(1985)
[42]Liang Jingkui, Wang Chaoguo, Phase Equilibrium And Hydrogen Absorption Of LaNi5-LaCu5 System, Acta Metallurgica Sinica,Vol. 18,592-598(1982)
[2]徐光宪，稀土，冶金工业出版社，1995
[3]胡子龙，储氢材料，化学工业出版社，2002
[4]Sumita Srivastava,O.N.Srivastava,Journal of Alloy and Compounds 282(1999)197-205.
[5]金自宜，材料导报，1993．NO．3．P6
[6]刘红，韩莹，程云阶，沈阳航空工业学院学报，2000．3Vol7
[7]高金良，稀土，1995．Vol6
[8]大角泰章，金属氢化物的性能和应用，吴永宽，苗艳秋译，化学工业出版社，1990
[9]陈长聘等，稀土，1981．NO．1．1
[10]仇九等，稀土，1988．NO．4．1
[11]Percheron-Guegan Aetal,Journal of the Less-Commom Metals, 74(1980) 1; 109(1985) 287
[12]李永绣，魏坤，胡平贵，功能材料，23(1992)193
[13]Liang Jingkui, Wang Chaoguo, Phase Equilibrium And Hydrogen Absorption Of LaNi5-LaCu5 System,Acta Metallurgica Sinica,Vol. 18,592-598(1982)
[14]Deyuan Zhang,Jinke Tang and K.A.Gschneider, Jr, Materials Science Forum Vol 70-72 1991
[15]V.Paul-Boncour, M.Diaf, A.Percheron-Guegan and J.C.A.chard, J.Phys. (Paris) Colloq.C8, 47(1986) 1093
[16]V.Paul-Boncour, A.Percheron-Guegan, M.Diaf and J.C.Achard Journal of the Less-Common Metals 131 (1987)201-208
[17]H.Okamoto Joural of Phase Equilibria Vol.12 No5 1991
[18]A.V.Klimyenko,J.Seuntjens,L.L.Miller, B.J.Beaudry, R.A.Jacobson and K.A.Gschenidner, Journal of the Less-Common Metals. 144 (1988) 133-141
[19]朱延果，《广西大学硕士学位论文》，2001
[20]P.Villars Pearson's Handbook of Crystallographic Data Naterials Park,OH 1997
[21]Y.Y.Pan, P.Nash,in: T.B.Massalski, P.R.Subramanian, H.Okamoto, L.Kacprzak (Eds.), Binary Alloy Phase Diagrams,2nd Edition,ASM International,Materials Park, OH, 1991, pp.2406-2408
[22]D.J.Chakrabarti, D.E.Laughlin, S.W.Chen and Y.A.Chang, Binary Alloy Phase Diagrams, ASM International, Materials Park, OH, 1991, pp. 1442-1446.
[23]D.J.Chakrabarti, D.E.Laughlin, Binary Alloy Phase Diagrams, ASM International, Materials Park, OH, 1991, pp. 1428-1430.
[24]F.A.Shunk,Constitution of Binary Alloys,New York 1969
[25]R.P.Elliott,Constitution of Binary Alloys,New York 1965
[26]张圣弼，李道子，相图—原理、计算及在冶金中的应用，冶金工业出版社，1986
[27]李树棠，晶体X射线衍射学基础，冶金工业出版社，1990
[28]陆学善，相图与相变，中国科技大学出版社，1990
[29]梁敬魁，相图与相结构，科学出版社，1983
[30]Jade 5, XRD pattern processing, Materials Data Inc, 1999.
[31]梁敬魁，相图与相结构，科学出版社，1983
[32]梁敬魁，相图与相结构的测定，在全国X—射线衍射学术会议上的报告，1982
[33]顾菡珍，叶于蒲，相平衡和相图基础，北京大学出版社，1991
[34]潘钦科等，金相实验室，冶金工业出版社，1956
[35]韩德伟，金属学实验指导书，中南工业大学出版社，1990
[36]肖特．裴卓，金相浸蚀手册，科学普及出版社，1982
[37]魏全金，金属电子实验技术，冶金工业出版社，1990
[38]任怀亮，金相实验动手术，冶金工业出版社，1986
[39]侯增寿，卢光熙，《金属学原理》，上海科学技术出版社，1990
[40]Huaiying Zhou, Qingrong Yao, Yinghong Zhuang, Phase Relationships in the La-Ni-Si system at 673K,Journal Of Alloys and Compounds, 366(2004) 161-164.
[41]F.Meeyer-Liautaud, C.H.Allibert and J.M.Moreau,New Phase In The System La-Cu, Joumal Of The Less-Common Metals, 110,81-90(1985)
[42]Liang Jingkui, Wang Chaoguo, Phase Equilibrium And Hydrogen Absorption Of LaNi5-LaCu5 System, Acta Metallurgica Sinica,Vol. 18,592-598(1982)