基于氰根和Schiff碱构筑的配合物的合成与结构
|
摘要
本文包括两部分内容,第一部分以三种过渡金属的氰根配合物K3[Fe(CN)6]、K4[Mo(CN)8]和K4[Fe(CN)6]作为配位前驱体,与过渡金属离子和稀土金属离子通过自组装得到七种配合物。以[Fe(CN)6]3-为前驱体得到配合物1,以[Mo(CN)8]4-作为构筑单元得到配合物2和3,以[Fe(CN)6]4-为配位前体与稀土离子(Ce3+, La3+, Nd3+, Gd3+)反应得到一系列配合物4、4a、4b和4c。第二部分,以水杨醛缩2-氨基-2-甲基-1,3-丙二醇Schiff碱(H3L)及4,4-联吡啶氮氧化物(bpdo)为配体,得到了两个锰的配合物5,6。
九种配合物化学式为：
(1)[CuⅡ(Hydeten)2]2[FeⅡ(CN)6]·2H2O
(2)[CeⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(3)[LaⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(4) NaLnⅢ[FeⅡ(CN)6]·3H2O (Ln=Ce, La, Nd, Gd)
(5) [MnⅣ(HL)2]·CH3CN
(6) [MnⅡ(bpdo)6](ClO4)2
对合成的配合物进行了红外光谱和ICP表征,并用X-ray单晶衍射法测定了配合物1,2,4,5和6的结构,结构测定表明配合物1由构筑单元[Fe(CN)6]4-和[Cu(Hydeten)2]2+组成,该配合物属于P21空间群,为手性分子；由配体亚氨基二乙酸(IDA)和稀土离子形成的配合物2为二维层状结构,抗衡离子模板[Mo(CN)8]4-嵌在二维层内；配合物4为三维网状结构,Na+填充在三维结构的空穴内；配合物5由单核锰构成,通过分子间氢键作用形成一维超分子链；配合物6是由Mn(Ⅱ)和4,4-联吡啶氮氧化物(bpdo)形成的单核配合物,ClO4-作为配阴离子平衡电荷。根据R光谱及ICP表征,推测配合物3与配合物2结构类似,为二维层状。
The thesis includes two parts. In part 1, the assembly of three building blocks, K3[Fe(CN)6], K4[Mo(CN)8] and K4[Fe(CN)6] with transition metal and lanthanide ions, respectively, leads to the formation of seven compounds. Compound 1 is based on [Fe(CN)6]3-, compound 2 and compound 3 consists of [Mo(CN)8]4- and lanthanide ions (Ln=Ce, La). The reactions between [Fe(CN)6]4- and Ln(Ⅲ) ions, where Ln=Ce(4), La(4a), Nd(4b), Gd(4c), form a series of compounds. In part 2, compound 5 and compound 6 were obtained by the reaction of bivalent manganese ions with Schiff base (H3L) and 4,4'-bipyridine-N,N'-dioxide (bpdo).
The formulae of nine compounds are as follows:
(1)[CuⅡ(Hydeten)2]2[FeⅡ(CN)6]·2H2O
(2)[CeⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(3)[LaⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(4)NaLnⅢ[FeⅡ(CN)6]·3H2O (Ln= Ce, La, Nd, Gd)
(5)[MnⅣ(HL)2]·CH3CN
(6)[MnⅡ(bpdo)6](ClO4)2
All the compounds were characterized by IR and ICP, and the structures of 1, 2,4,5 and 6 were determined by X-ray single crystal diffractometry. The results indicate that the structure of compound 1 consists of trinuclear molecules formed by [Fe(CN)6]4- and [Cu(Hydeten)2]2+ building blocks, which crystallizes in the chiral space group P21. Compound 2 exhibits a two-dimensional layer-like structure extended by IDA ligands and lanthanide ions, while the counter anion, [Mo(CN)8]4- as template, is situated within the two-dimensional layers. The structure of compound 4 shows a 3D network. Na+ is located in the cavity of the network. Compound 5 consists of mononuclear manganese(Ⅳ) structure, which is linked by intermolecular hydrogen bonds to form supramolecular one-dimensional chain-like structure. Compound 6 is comprised of Mn(Ⅱ) and bpdo ligands, which is a mononuclear molecule. The two ClO4- ions act as counter anions to balance charge. The results of IR spectrum and ICP analysis suggest that compound 3 has a two-dimensional layer-like structure similar to compound 2.
九种配合物化学式为：
(1)[CuⅡ(Hydeten)2]2[FeⅡ(CN)6]·2H2O
(2)[CeⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(3)[LaⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(4) NaLnⅢ[FeⅡ(CN)6]·3H2O (Ln=Ce, La, Nd, Gd)
(5) [MnⅣ(HL)2]·CH3CN
(6) [MnⅡ(bpdo)6](ClO4)2
对合成的配合物进行了红外光谱和ICP表征,并用X-ray单晶衍射法测定了配合物1,2,4,5和6的结构,结构测定表明配合物1由构筑单元[Fe(CN)6]4-和[Cu(Hydeten)2]2+组成,该配合物属于P21空间群,为手性分子；由配体亚氨基二乙酸(IDA)和稀土离子形成的配合物2为二维层状结构,抗衡离子模板[Mo(CN)8]4-嵌在二维层内；配合物4为三维网状结构,Na+填充在三维结构的空穴内；配合物5由单核锰构成,通过分子间氢键作用形成一维超分子链；配合物6是由Mn(Ⅱ)和4,4-联吡啶氮氧化物(bpdo)形成的单核配合物,ClO4-作为配阴离子平衡电荷。根据R光谱及ICP表征,推测配合物3与配合物2结构类似,为二维层状。
The thesis includes two parts. In part 1, the assembly of three building blocks, K3[Fe(CN)6], K4[Mo(CN)8] and K4[Fe(CN)6] with transition metal and lanthanide ions, respectively, leads to the formation of seven compounds. Compound 1 is based on [Fe(CN)6]3-, compound 2 and compound 3 consists of [Mo(CN)8]4- and lanthanide ions (Ln=Ce, La). The reactions between [Fe(CN)6]4- and Ln(Ⅲ) ions, where Ln=Ce(4), La(4a), Nd(4b), Gd(4c), form a series of compounds. In part 2, compound 5 and compound 6 were obtained by the reaction of bivalent manganese ions with Schiff base (H3L) and 4,4'-bipyridine-N,N'-dioxide (bpdo).
The formulae of nine compounds are as follows:
(1)[CuⅡ(Hydeten)2]2[FeⅡ(CN)6]·2H2O
(2)[CeⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(3)[LaⅢ2(ida)2(H2O)8][MoⅣ(CN)8]·H2O
(4)NaLnⅢ[FeⅡ(CN)6]·3H2O (Ln= Ce, La, Nd, Gd)
(5)[MnⅣ(HL)2]·CH3CN
(6)[MnⅡ(bpdo)6](ClO4)2
All the compounds were characterized by IR and ICP, and the structures of 1, 2,4,5 and 6 were determined by X-ray single crystal diffractometry. The results indicate that the structure of compound 1 consists of trinuclear molecules formed by [Fe(CN)6]4- and [Cu(Hydeten)2]2+ building blocks, which crystallizes in the chiral space group P21. Compound 2 exhibits a two-dimensional layer-like structure extended by IDA ligands and lanthanide ions, while the counter anion, [Mo(CN)8]4- as template, is situated within the two-dimensional layers. The structure of compound 4 shows a 3D network. Na+ is located in the cavity of the network. Compound 5 consists of mononuclear manganese(Ⅳ) structure, which is linked by intermolecular hydrogen bonds to form supramolecular one-dimensional chain-like structure. Compound 6 is comprised of Mn(Ⅱ) and bpdo ligands, which is a mononuclear molecule. The two ClO4- ions act as counter anions to balance charge. The results of IR spectrum and ICP analysis suggest that compound 3 has a two-dimensional layer-like structure similar to compound 2.
引文
[1]游效曾,孟庆金,韩万书.配位化学进展.[M].北京：高等教育出版社,2000.
[2]游效曾,分子材料—光电功能化合物.[M].上海科学技术出版社,2001.
[3]张岐,功能配合物研究进展.[M].原子能出版社,2007.
[4]Xie P H, HouY J, Zhnag B W, etc. Spectroscopic and Electrochemical Properties of Ruthenium(Ⅱ) polypyridyl complexes. [J], JChem Soc Dalton Trans,1999, (23):4217-4221.
[5]杨怀霞,苯并咪唑基、二茂铁基功能配合物的合成及性能研究[D],郑州大学硕士学位论文,2007.
[6]Zhang, H. Wang X, Zhang, K, etc. Molecular and crystal engineering of a new class of inorganic cadmium-thiocyanate polymers with host-guest complexes as organic spacers, controllers, and templates, [J],Chem. Rev.,1999,183:157-195.
[7]Hou H W, Wei Y L., Two novel two-dimensional double-sheet layered manganese(Ⅱ) coordination polymers synthesis, crystal structures and third-order nonlinear optical properties[J]. J Mater-Chem,2002, 12(4):838-843.
[8]Elena Chelebaeva, Joulia Larionova, Luis D. Carlos, etc. Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d-4f Ions:Toward Multifunctional Materials. [J],Inorganic Chemistry, 2009,48(13):5983-5995.
[9]Fujita M, Yu S Y, KusukawaT, etc. Self-assembly of nanometer-sized macrotrceyclic complexes from ten small component molecules. [J],Angew Chem Int Ed,1998,37(15):2082-208.5
[10]徐伟平,李光宪.分子自组装研究进展.[J].化学通报,1999,(2).
[11]陈小明,蔡继文.单晶结构分析原理与实践.[M].北京：科学出版社2003.
[12]Stefania Tanase, Jan Reedijk., Chemistry and magnetism of cyanido-bridged d-f assemblies,[J],Coordination Chemistry Reviews 250 (2006) 2501-2510.
[13]Korzeniak, T, Podgajny R, Alcock N W,etc. A new family of magnetic 2D coordination polymers based on [MⅤ(CN)8]3-(M= Mo, W) and pre-programmed Cu2+ centres.[J],Polyhedron,2003,22 (14-17),2183-2190.
[14]Z.Y.Sun, R.Yuan, Y.Q.Chai, etal. Study of a bisfuraldehyde Schiff base copper(Ⅱ) complex as carrier for preparation of highly selective thiocyanate electrodes, [J],Anal Bioanal Chem,2004,378:490-494.
[15]闫小宁,Schiff碱过渡金属配合物的合成、表征及催化性能的研究[D],陕西师范大学硕士学位论文,2006.
[16]王寿武,李宝龙,朱霞,氰根桥联超分子配位化学研究进展.[J].化学世界,2004,(3),154-156.
[17]Michel Verdaguer, A. Bleuzen, V. Marvaud,etc. Molecules to build solids:high Tc molecule-based magnets by design and recent revival of cyano complexes chemistry. [J],Coordination Chemistry Reviews,190-192 (1999) 1023-1047.
[18]韩薇,普鲁士蓝类分子磁体的磁性及穆斯堡尔谱学研究[D],南京航空航天大学硕士论文,2007.
[19]司书峰,廖代正.普鲁士蓝类分子磁体研究的新进展.[J].结构化学.2001,20(3)：233-240.
[20]Ksenofontov V, Georgiy L, Sergey R., etc. Pressure-induced electron transfer in ferromagnetic Prussian blue analogs.[J], Phys, Rev. B,2003,68:024415.1-024415.5.
[21]刘本纬,氰根桥联配合物及甲酸根配合物的合成与结构[D],内蒙古大学硕士学位论文,2006.
[22]寇会忠,廖代正.一种设计实用分子铁磁体的有效构件——普鲁士蓝类配合物[J],无机化学学报,1999年3月,第二期.
[23]Holmes S M, Girolami G S. Sol-Gel. Synthesis of KVⅡ[CrⅢ(CN)6]·2H2O:A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 ℃, [J],J. Am. Chem. Soc,1999,121:5593-5594.
[24]Hatlevik, Buschmann W E., Zhang J, etc. Enhancement of the magnetic ordering temperature and air stability of a mixed valent vanadium hexacyanochromate (Ⅲ) magnet to 99℃ (372 K)[J],Adv. Mater,1999,11 (11):914-918.
[25]Tomohiro Nuida, Toshiya Hozumi, Wataru Kosaka, etc. Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities, [J], Polyhedron 2005 (24):901-2905.
[26]Ferlay S, Mallah T., Ouahes R., etc.A room-temperature organometallic magnet based on Prussian blue, [J],Nature,1995,378 (14):701-703.
[27]Djuardin E., Ferlay S., Phan X., etc. Synthesis and magnetization of new room-temperature molecule based magnet:effect of stoichimetry on local magnetic structure by X-ray magnetic circular dichroism, [J],J. Am. Chem. Soc,1998,120:11347-11352.
[28]Mallah T., Thiebaut S., Verdaguer M., etc. High-Tc Molecular-Based Magnets:Ferrimagnetic Mixed-Valence Chromium(Ⅲ)-Chromium(Ⅱ)Cyanides with Tc at 240 and 190 Kelvin, [J], Science,1993,262: 1554-1557.
[29]Entley, William R.; Girolami, Gregory S. High-temperature molecular magnets based on cyanovanadate building blocks:Spontaneous magnetization at 230 K, [J], Science,1995,268:397.
[30]Mallah, T.; Thiebaut, S.; Verdaguer, M.; Veillet, P. High-T_c Molecular-Based Magnets:Ferrimagnetic Mixed-Valence Chromium(Ⅲ)-Chromium(Ⅱ) Cyanides with Tc at 240 and 190 Kelvin,[J],Science, 993,262,1554.
[31]Gadet V, Mallah T., Castro L, etc.High-Tc Molecular-Based Magnets:A Ferromagnetic Bimetallic Chromium(Ⅲ)-Nickel(Ⅱ) Cyanide with Tc=90K, [J], J. Am.Chem. Soc.1992,114:9213-9214.
[32]Entley W. R., Treadway C. R., Girolami G S., etc. Molecular Magnets Construct ed from Cyanometalate Building Blocks, Mol. [J],Cryst. Liq. Cryst.1995,273:153 -158.
[33]Buschmann W. E., Miller J. S., Magnetic Ordering and Spin-Glass Behavior in First-Row Transition Metal Hexacyomanganate (Ⅳ) Prussian Blue Analogues, [J],Inorg. Chem.2000,39(11):2411-2421.
[34]W.R.Entley, G.S.Girolami. New Three-Dimensional Ferrimagnetic Materials:KMn[Mn(CN)6], Mn3[Mn(CN)6]2·12H2O, and CsMn[Mn(CN)6]·1/2H2O [J], Inorg Chem,1994,33,5165-5166.
[35]Hashimoto K., Ohkoshi S. L, Design of novel magnets using Prussian blue analogues, [J],The Royal Society,1999,357:2977-3003.
[36]Hashimoto K,Ohkoshi S. I, Abe Y., Fujishima A, etc. Design and preparation of a novel magnet exhibiting two compensation temperature based on molecular field theory, [J],Pys. Rev. Lett.1999,82 (6): 1285-1288.
[37](a)Michel Verdaguer,Bleuzen A., Lomenech C., Escax V, etc. Photodinduced ferromagnetic systems in Prussian blue analogues CⅠCo4[Fe(CN)6]y (CⅠ=-Alkali Cation)1. conditions to observe the phenomenon, [J], J. Am. Chem. Soc.,2002,122:6648-6652.;(b) Remy Le Bris, Jean-Daniel Cafun, Optical and magnetic properties of the photo-induced state in the coordination network Na2Co4[Fe(CN)6]3.3·14H2O [J], New J. Chem., 2009,33,1255-1261.
[38]Cao Minhua, Wu Xinglong, He Xiaoyan, etc. Shape-controlled synthesis of Prussian blue analogue Co3[Co(CN)6]2 nanocrystals, [J],Chem.Comm.,2005:2241-2243.
[39]Diana Visinescu, Luminita M. Toma, Miguel Julve, etc. New 3d-4f supramolecular systems constructed by [Fe(bipy)(CN)4],and partially blocked lanthanide cations, [J], Polyhedron 2009 (28):851-859.
[40]F. Hulliger, M. Landolt, H. Vetsch, Rare-earth ferricyanides and chromicyanides LnM(CN)6·nH2O, [J], J. Solid State Chem.,1976,18,283.
[41]Bao-Qing Ma, Song Gao, Gang Su, Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two- Dimensional Topological Architecture and Unusual Magnetic Behavior. [J], Angew.Chem. Int. Ed.2001, 40(2).
[42]寇会忠,周北川.氰根桥联配合物的结构与磁性研究.[J],无机化学学报2004,20(5),497-508.
[43]袁爱华,周虎,沈小平.氰基桥联配合物的研究进展.[J],化学研究与应用2005,5：582-587.
[44]刘敏,杂化氰根桥联配合物的磁性研究[D],广西师范大学硕士论文,2008.
[45]M. Ohba, N. Maruono, H. Okawa, etc. A New Bimetallic Ferromagnet, [Ni(en)2]3[Fe(CN)6]2·2H2O, with a Rare Rope-Ladder Chain Structure, [J], J.Am.Chem.Soc,1994,116,11566.
[46](a) Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Act,2004 (357):3271-3278; (b) Rodriguez-Dieguez, A; Colacio, E,Crystal structure and magnetic properties of [{Cu(cyclam)}3{Fe(CN)6}2]·6H2O, a cyano-bridged assembly with a rope-ladder chain structure[J], Polyhedron,2007,26:2859-2863; (c) Travnicek, Z; Smekal, Z; Escuer, A, etc. Synthesis, structure and magnetic behaviour of a two-dimensional cyano-bridged complex [{Cu(ept)}3Fe(CN)6] (ClO4)(2)·5H2O [ept= N-(2-aminoethyl)-1,3-diaminopropane] [J], New Journal of chemstry,2001,25(4):655-658;(d) Yuan AH, Shen XP, Zhou H. Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL]2+ and [Fe(CN)6]3- precursors.[J], Transition Metal Chemistry,2008,33(1):133-136.
[47](a)Yi-Zhi Lia, Ai-Hua Yuanb, Zheng Xu, etc.A novel three-dimensional mixed bridging-ligand complex with an unexpected 1,3-diaminopropane bridge,[J], Journal of Molecular Structure 2005 (754):106-110;(b) Zhan SZ, Yu KB, Liu J, [Ni(Ⅱ)(tn)2]5[Fe(Ⅲ)(CN)6]2[Fe(Ⅱ)(CN)6]·10H2O:A 3-dimensional dimetallic polymer exhibiting ferromagnetic interaction[J], Inorganic Chemistry Communication 2006,9 (10):1007-1010.
[48]Masaaki Ohba, Naoki Usuki, Nobuo Fukita, Three-Dimensional Dimetallic Ferrimagnet (Tc=69 K) with a Defective Cubane Unit[J], Angew. Chem. Int. Ed,1999,38:1795.
[49]Inoue K, Imai H, Ghalsasi P.S, etc. A Three-Dimensional Ferrimagnet with a High Magnetic Transition Temperature (Tc) of 53 K Based on a Chiral Molecule, [J], Angew. Chem. Int.Ed,2001,40:4242.
[50]J.A.Smith, J-R.Galan-Mascaros, R.Clerac, etc.{Mn(OH2)2[Mn(bpym)(OH2)]2[Fe(CN)6]2}n:a two-dimensional ferrimagnet with a partial cubane motif, [J],Chem.Commun,2000,1077-1078.
[51]M.Ohba, H.Okawa. Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies [J],Coord.Chem.Rev,2000,198:313.
[52]H-Z Kou, S Gao, B-Q Ma, etc.. A cyano-bridged molecular magnet with a novel two-dimensional brick wall structure, [J],Chem.Commun,2000,1309-1310.
[53]M.S.El Fallah, E.Rentschler, A.Caneschi, etc. A Three-Dimensional Molecular Ferrimagnet Based on Ferricyanide and [Ni(tren)]2+ Building Blocks, [J],Angew.Chem.Int.Ed,1996,35,1947.
[54](a) Kou, HZ, Tang, JK, etc.Crystal structures and magnetic properties of new cyano-bridged two-dimensional grid-like bimetallic assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH·H2O and [Ni(tn)2]2[Co(CN)6] NO3·2H2O (tn=1,3-propanediamine)[J], Inorganic Chemistry,2001,40 (19):4839-4844; (b)Kou, HZ;Gao, S; etc. Magnetic characteristics of new cyano-bridged two-dimensional honeycomb-like bimetallic assemblies containing Ni(Ⅱ)-N equivalent to C-Cr(Ⅲ) or Ni(Ⅱ)-N equivalent to C-Cr(Ⅰ) linkages.[J], Inorganic Chemistry 2001,40 (24):6287-6294; (c)Yusuke Yoshida, Katsuya Inoue, Mohamedally Kurmoo, etc.On the Nature of the Reversibility of HydrationsDehydration on the Crystal Structure and Magnetism of the Ferrimagnet [MnⅡ(enH)(H2O)][CrⅢ(CN)6]·H2O, [J], Inorganic Chemistry,2009,48(1):267.
[55]Shen, XP; Li, BL; Zou, JZ, etc. The first cyano-bridged heptanuclear MnⅢ,FeⅢ cluster:crystal structure and magnetic properties of [{Mn(salen)centerd·H2O6Fe(CN)6][Fe(CN)6]·6H2O, [J], Journal of Molecular Structure,2003,657(1-3):325-331.
[56]Marilena Ferbinteanu, Hitoshi Miyasaka, Wolfgang Wernsdorfer, Single-Chain Magnet (NEt4)[Mn2(5- MeOsalen)2Fe(CN)6] Made of MnⅢ-FeⅢ-MnⅢ Trinuclear Single-Molecule Magnet with an ST= 9/2 Spin Ground State, [J], J. Am. Chem. Soc.,2005,127 (9):3090-3099.
[57]Flavio L. Beneditoc, Fabio S. Nunes, A new pentanuclear cyano-bridged complex [{FeⅡ(tetraaza macrocycle)}3{μ-NC-FeⅢ(CN)5}2]:Synthesis, spectroscopic and magnetic characterization, Spectrochimica Acta PartA:[J], Molecular and Biomolecular Spectroscopy,2008,70(5):1029-1033.
[58](a) Diana Visinescu,Luminita Marilena Toma, Francesc Lloret, etc. Unprecedented coexistence of cyano-bridged Mn4ⅢCrⅢ1 and Mn2ⅢCrⅢ heterobimetallic complexes in one single crystal, [J],Dalton Trans., 2009,37-40; (b) Mondal, N; Dey, DK; Mitra, S, etc.Synthesis and characterization of cyano-bridged polynuclear [Cu(dmpn)2]3[Co(CN)6]2·12H2O and trinuclear [Cu(dmpn)2]2[Co(CN)6]·ClO4·3H2O complexes, [J],Polyhedron,vol:20,issue:7-8,pp:607-613,2001;(c) Zhan, SZ; Sun, DS; Wang, JG, etc. Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)4]2-and [Co(Ⅲ)(CN)6]3-[J], Journal of Coordination Chemistry,2008,61(4):550-562;(d) Nayak M, Majumder S, Lemoine P, etc. Synthesis, Characterization, and Structure of a Cyano-bridged Two-dimensional (CuCo(Ⅲ)-Co(Ⅱ) Coordination Polymer Derived from Trans-1,2-diaminocyclohexane as Blocking Ligand[J], Journal Chemical Crystallography,2008,38(12):937-942; (e) Li BL, Shen XP, etc. Synthesis, structure and characterization of the cyano-bridged heteropolymer poly{[bis(trimethylene-diamine) copper(Ⅱ)] [hexacyanocobalt(Ⅲ)]} perchlorate dihydrate with a two-dimensional framework[J], Journal of Coordination Chemistry,2002,55(10):1191-1198.
[59](a).Yan B, Chen Z. D,Wang S. X etc. A novel cyano-bridged heteronuclear complex [Sm(DMF)4 (H2O)2Mn(CN)6·H2O]n has been synthesized based on the reaction of K3Mn(CN)6, Sm(NO3)3·6H2O and N,N-dimethylformamide (DMF). [J],Chem. Lett.,2001,350; (b) Kou.H. Z, Gao S, Sun BW, etc.A Novel One-Dimensional Chain Cyano-Bridged Complex [Sm(DMF)4 (H2O)2Mn(CN)6·H2O]n:Long-Range Magnetic Ordering, Tc= 18 K and Coercive Force He= 600 Oe, [J],Chem. Mater.,2001,13:1431;(c). Ma B. c, Gao S, Sn G. etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavio [J],Angew. Chem. Int. Ed,2001,40:434.
[60](a) Albert Figuerola, Joan Ribas, Xavier Solans,etc.One Dimensional 3d-4f Heterometallic Compounds: Synthesis, Structure and Magnetic Properties,[J], J. Inorg. Chem.2006,1846-1852; (b) Albert Figuerola, Joan Ribas, Miquel Llunell, etc. Magnetic Properties of Cyano-Bridged Ln3+-M3+ Complexes. Part I:Trinuclear Complexes (Ln3+) La, Ce, Pr, Nd, Sm; M3+ =FeLS, Co) with bpy as Blocking Ligand [J],Inorganic Chemistry, 2005,44,(20):6939.
[61]Bao-Qing Ma, Song Gao, Gang Su, etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavior,[J]Angew. Chem. Int. Ed.2001, 40, (2).
[62]Albert Figuerol, Carmen Diaz, Joan Ribas, etc. Structure and magnetism of the first cyano-bridged hetero-one-dimensional GdⅢ-CrⅢ complexes, [J],Chem. Commun.,2001,1204-1205.
[63]Bing Yan, Zhi-da Chen, The magnetochemistry of novel cyano-bridged complexes Ln(DMF)4 (H2O)2Mn(CN)6·H2O (Ln= Tb, Dy, Er), [J],Transition Metal Chemistry,2001,26:287-289.
[64](a) You Song, Xiao-Zeng You, Kazuhito Hashimoto,etc. Syntheses, Structures, and Properties of Two Three-Dimensional Octacyanometalate-Based Polymers:Cs2Cu3[W(CN)8]2·4NH3·4H2O and Cu2[Mo (CN)8]·8NH3, [J], Crystal Growth &Design,vol:2457-2462,2006; (b)常菲,Ⅰ.氰根桥联的双金属配合物的结构及磁性质,Ⅱ.氮杂环双羧酸氮氧化物的金属配位聚合物.[D],[博士学位论文],北京大学,2002.
[65]Catalin Maxim, Corine Mathoniere, Marius Andruh, etc.New photomagnetic cyanido-bridged CuⅡ-MoⅣ oligonuclear complexes:slight modification of the blocking ligands induces different structures,[J],Dalton Trans.,2009,7805-7810.
[66]Zhuang Jin Zhong, Hidetake Seino, Yasushi Mizobe,etc. A High-Spin Cyanide-Bridged Mn9W6 Cluster (S = 39/2) with a Full-Capped Cubane Structure, [J], J. Am. Chem. Soc.2000, (122):2952.
[67]Chang, F; Sun, HL; Kou, HZ, etc. Structures and magnetism of bimetallic octacyanometallates: honeycomb-like[Mo(CN)8Ni2(pn)4]n·4nH2O and binuclear [Mo(CN)8Ni(en)2(H2O)][Ni(en)3]·2H2O (pn=1,3-diaminopropane, en=1,2-diaminoethane) [J],Inorganic Chemistry Communication,vol:5,issue:9,660-663, 2002.
[68]Zhan, SZ; Wang, JG; Long, B, etc.The assembly, synthesis and properties of a trinuclear cyano-bridged Cu-Ⅱ-Mo-Ⅳ-Cu-Ⅱ complex,[J], Journal of Coordination Chemistry, vol:61, issu:9,pp:1399-1405,2008.
[69]Kania, R; Lewinski, K; Sieklucka, B, etc. Self-assembly of tetranuclear{[Co(trien)]2[W(CN)8]2}2- or {[Co(tren)]2[W(CN)8]2}2-squares with alternating aliphatic tetramine Co(Ⅲ) and octacyanotungstate(Ⅳ) corners,[J], Dalton Trans, vol.5,PP:1033-1040,2003.
[70]Venkatakrishnan, TS; Rajamani, R; Ramasesha, S, etc. Synthesis, crystal structure, and magnetic properties of hexanuclear [{MnL2}4{Nb(CN)8}2] and nonanuclear [{MnL2}6{Nb(CN)8}3] heterometallic clusters (L= bpy, phen), [J], Inorganic Chemistry,46 9569-9574,2007.
[71]Y. Song, P. Zhang, X.-M. Ren, etc. Octacyanometallate-Based Single-Molecule Magnets:CoⅡ9MⅤ6 (M= W, Mo), [J],J.Am. Chem. Soc.2005,127:3708.
[72]G. Rombaut, S. Golhen, L. Ouahab, etc. Structural and photomagnetic studies of a 1-D bimetallic chain [MnⅡ2(L)2(H2O)][MoⅣ(CN)8]·5H2O (L=macrocycle):analogy with the photo-oxidation of K4[MoⅣ (CN)8]·2H2O, [J],J.Chem. Soc., Dalton Trans.2000:3609.
[73]D. Li, S. Gao, L. Zheng, etc. A cyano-bridged MnⅡMoⅤ bimetallic ferrimagnet with a novel moniliform structure, [J],Dalton Trans.2002:2805.
[74]D.-F. Li, L.-M. Zheng, Y.-Z. Zhang, etc. Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers, [J],Inorg. Chem.2003,42:6123.
[75]P. Przychodzen', Wasiutyn'ski, C. Guyard-Duhayon, etc. Crystal Structures and Magnetic Properties of Two Low-Dimensional Materials Constructed from [MnⅢ(salen)H2O]+ and [M(CN)8]3-/4-(M= Mo or W) Precursors, [J], Inorg. Chem.43(2004) 2967.
[76]Y.S. You, D. Kim, Y. Do, etc. One-Dimensional Octacyanomolybdate-Based Cu(Ⅱ)-Mo(Ⅴ) Bimetallic Assembly with a Novel Rope-Ladder Chain Structure, [J],Inorg. Chem.43 (2004)6899.
[77]S. Ikeda, T. Hozumi, K. Hashimoto, etc.Cyano-bridged gadolinium(Ⅲ)-tungstate(Ⅴ) bimetallic assembly with a one-dimensional chain structure, [J], Dalton Trans. (2005) 2120.
[78]R. Podgajny, T. Korzeniak, M. Balanda, T. Wasiutynski,2-D soft ferromagnet based on [WⅤ(CN)8]3- and CuⅡ with a Tc of 34 K, [J],Chem. Comm.(2002) 1138.
[79]S. Ohkoshi, Y. Arimoto, H. Seino, etc. Two-dimensional metamagnet composed of cyano-bridged CuⅡ-WⅤ bimetallic assembly, [J],Chem.Commun.2003:2772.
[80]Y. Arimoto, S. Ohkoshi, Z.J. Zhong, etc.Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate, [J],J. Am. Chem. Soc.2003,1259240.
[81]T. Hozumi, S. Ohkoshi, Y. Arimoto, etc.Cooling-rate Dependent Ferromagnetism in a Two-dimensional Cyano-bridged Sm(Ⅲ)-W(Ⅴ) Complex, [J], J. Phys.Chem. B.2003,107:1571.
[82]H.-Z. Kou, Z.-H. Ni, B.C. Zhou, etc. A cyano-bridged molecule-based magnet containing manganese(Ⅲ) Schiff base and octacyanotungstate(V) building blocks, [J],Inorg. Chem.Commun.2004,7:1150.
[83]T. Korzeniak, K. Stadnicka, M. Rams, etc. Grid-Type Two-Dimensional Magnetic Multinuclear Metal Complex:Strands of{[CuⅡ(μ-4,4'-bpy)]2+}n Cross-Linked by Octacyanotungstate(Ⅴ) Ions, [J],Inorg. Chem. 2004,43:4811.
[84]T. Korzeniak, K. Stadnicka, R. Pelka, etc. An unprecedented copper(Ⅰ,Ⅱ)-octacyanotungstate(Ⅴ) 2-D network:crystal structure and magnetism of [CuⅡ(tren)]{CuⅠ[Wv(CN)g]}·1.5H2O, [J], Chem. Commun.2005: 2939.
[85]J.R. Withers, D. Li, J. Triplet, etc.A Two-Dimensional Octacyanomolybdate(V)-Based Ferrimagnet: {[MnⅡ(DMF)4]3[MoⅤ(CN)8]2}n, [J],Inorg. Chem.2006,45:4307.
[86]J.H. Lim, J.S. Kang, H.C. Kim, etc. Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Honeycomblike Layers MⅤ-CuⅡ (M= Mo, W) Chelated by a Macrocyclic Ligand, [J],Inorg. Chem.2006,45:7821.
[87]M. Atanasov, P. Comba, Y.D. Lampeka,etc. Ation of Cyanometalates by a Tris-macrocyclic Ligand Tricopper(Ⅱ) Complex:Syntheses, Structural Variation, and Magnetic Exchange Coupling Pathways [J],Chem. Eur. J.2006,12:737.
[88]Z.J. Zhong, H. Seino, Y. Mizobe, etc. Crystal Structure and Magnetic Properties of an Octacyano metalate-Based Three-Dimensional Tungstate(Ⅴ)-Manganese(Ⅱ) Bimetallic Assembly, [J], Inorg. Chem.2000, 39:5095.
[89]G. Rombaut, M. Verelst, S. Golhen, etc. Hepta/octa cyanomolybdates with Fe2+:influence of the valence state of Mo on the magnetic behavior, [J], New J. Chem.2000,24:871.
[90]J.M. Herrera, A. Bleuzen, M. Julve, etc. Crystal Structures and Magnetic Properties of Two Octacyano tungstate(Ⅳ) and(Ⅴ)-Cobalt(Ⅱ) Three-Dimensional Bimetallic Frameworks, [J],Inorg.Chem.2003,42:7052.
[91]Y. Song, S. Ohkoshi, Y. Arimoto, etc. Hashimoto, Synthesis, Crystal Structures, and Magnetic Properties of Two Cyano-Bridged Tungstate(Ⅴ)-Manganese(Ⅱ) Bimetallic Magnets, [J], Inorg. Chem.2003,42:1848.
[92]D. Li, L. Zheng, X. Wang, etc. [Cu(tn)]3[W(CN)8]2·3H2O and [Cu(pn)]3 [W(CN)8]2·3H2O:Two Novel Cu(Ⅱ)-W(Ⅴ) Cyano-Bridged Two-Dimensional Coordination Polymers with Metamagnetism, [J],Chem. Mater. 2003,15:2094.
[93]T.Kashiwagi, S.Ohkoshi, H. Seino, etc. Hashimoto, Manganese(Ⅱ) Octacyanotungstate(Ⅴ)-Based Mag-net Containing a Noncoordinated Aromatic Molecule,[J],J.Am. Chem. Soc.2004,126:5024.
[94]T. Hozumi, K. Hashimoto, S. Ohkoshi, etc.Electrochemical Synthesis, Crystal Structure, and Photomagnetic Properties of a Three-Dimensional Cyano-Bridged Copper-Molybdenum Complex, [J], J. Am. Chem. Soc.2005,127:3864.
[95]J.R. Withers, C. Ruschman, S. Parkin, etc. One-and three-dimensional octacyanometalate(IV) networks constructed via a building block approach:{[trans-NiⅡ(tn)2(OH2)][trans-NiⅡ(μ-NC)2(tn)2][(μ-NC)3MⅣ (CN)5]·6H2O} (MⅣ= Mo, W) and Cs4[CuⅡ(OH2)4]2[CuⅡ(NH3)]4[MoⅣ(CN)8]4·2H2O, [J],Polyhedron 2005,24: 1845.
[96]Z.-X. Wang, X.-F. Shen, Y. Song, etc. X.-Z. You, A Sodalite-like Framework Based on Octacyano molybdate and Neodymium with Guest Methanol Molecules and Neodymium Octahydrate Ions, [J],Angew. Chem. Int. Ed.2006,45:3287.
[97]J. Larionova, S. Willemin, B. Donnadieu,.etc. Crystal engineering in two-and three-dimensional systems based on cyanomolybdates:structures, magnetism and intercalation properties [J],J. Phys. Chem. Solids2004, 65:677.
[98]B. Sieklucka, R. Podgajny, P. Przychodzen, etc. Supramolecular networks based on octacyanometallates of Mo and W, [J],CR Chimie 2002,5:639.
[99]Larionova, M. Gross, M. Pilkingto, etc. High-Spin Molecules:A Novel Cyano-Bridged MnⅡ9MoⅤ6 Molecular Cluster with a S=51/2 Ground State and Ferromagnetic Intercluster Ordering at Low Temperatures, [J],Angew. Chem. Int. Ed.2000,39:1605.
[100]Venkatakrishnan, TS; Rajamani, R; Ramasesha, S, etc. Synthesis, crystal structure, and magnetic properties of hexanuclear [{MnL2}{Nb(CN)8}2] and nonanuclear [{MnL2}{Nb(CN)8}3] heterometallic clusters (L= bpy, phen), [J], Inorganic Chemistry, Volume,2007,46,9569-9574.
[101]Satoru Ikeda, Toshiya Hozumi, Kazuhito Hashimoto,etc. Cyano-bridged gadolinium(Ⅲ)-tungstate(V) bimetallic assembly with a one-dimensional chain structure, [J], Dalton Trans,2005,2120-2123.
[102]Jin Huang, Song Gao, Wenxia Tang, etc.Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers, [J],Inorganic Chemistry,2003, 42(19):6123-6129.
[103]Pawel Przychodzen, Robert Pelka, Krzysztof Lewin' ski, etc.Tuning of Magnetic Properties of Polynuclear Lanthanide(Ⅲ)-Octacyanotungstate(V) Systems:Determination of Ligand-Field Parameters and Exchange Interaction, [J], Inorganic Chemistry,2007,46,21.
[104]Almeida Paz,Alexander Trifonov, Christian Gu_erin, etc.Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d-4f Ions:Toward Multifunctional Materials, [J], Inorganic Chemistry, 2009,48,13.
[105]Yuji Miyazakic, Michio Sorai, Tadeusz Wasiuty Nski, etc.Ferromagnetic ordering in new layered copper Octacyanometallates, [J] Journal of Magnetism and Magnetic Materials 2004:1058-1059.
[106]Yoshihide Tsunobuchi, Wataru Kosaka, Shin-ichi Ohkoshi,etc. Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet, [J],Cryst EngComm,2009,11:2051-2053.
[107]Dai-Zheng Liao, Zong-Hui Jiang, Peng Cheng,etc. Two dierent three-dimensional microporous framework structuresin [Mn2(H2O)4{W(CN)8}.4H2O]n and [Mn2(H2O)4{W(CN)8}(OH).2H2O]n, [J], New J. Chem.,2003,27:1760-1764.
[108]Rodrigue Lescouelzec, Jacqueline Vaissermann, Francesc Lloret, etc.Ferromagnetic Coupling between Low-and High-Spin Iron(III) Ions in the Tetranuclear Complex fac-[FeⅢHB(pZ)3(CN)2(μ-CN)]3 FeⅢ(H2O)3·6H2O([HB(pz)3]=Hydrotris (1-pyrazolyl)borate) [J], Inorg. Chem.,2002,41,5943-5945.
[109]Abbati G L, Caneschi A, Cornia A, etc.Towards stepwise cluster assembly:a decacopper(II) complex obtained by controlled expansion of a metallasiloxane cage. [J], Angew.Chem. Int. Ed.2002,41:4517-4520.
[110]Zhong-Hai Ni, Hui-Zhong Kou, Yi-Hua Zhao, etc. [Fe(bpb)(CN)2]-as a Versatile Building Block for the Design of Novel Low-Dimensional Heterobimetallic Systems:Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged FeⅢ-NiⅡ Complexes [(bpb)2-=2-Bis(pyridine-2-carboxamidobenzenate], [J],Inorganic Chemistry,2005,44,6.
[111]Hai-Yan Wei, Hao-Ling Sun, Song Gao,etc. Heterometallic MⅡRuⅢ2 Compounds Constructed from trans-[Ru(Salen)(CN)2]" and trans-[Ru(Acac)2(CN)2]-.Synthesis,Structures, Magnetic Properties, and Density Functional Theoretical Study, [J], Inorganic Chemistry,2005,44(19):6579.
[112]Xiao-Long Feng, Tong-Bu Lu, Song Gao,etc.Synthesis, Structures, and Magnetic Properties of a Series of Cyano-Bridged Fe-Mn Bimetallic Complexes, [J],Inorganic Chemistry,2006,45,13.
[113](a)Xi-Rui Zeng, Hong-Cai Zhou, Xiao-Zeng You,etc. Two-dimensional cyanide-bridged heterobi-metallic complexes based on CpCo(CN)3-:Syntheses, structures and magnetic properties,[J],Inorganica Chimica Acta,2006,359:3790-3794; (b) You Song, Xi-Rui Zeng, Xiao-Zeng Y, etc.Syntheses, Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [Fe(bpca)(CN)3]-, [J],Inorganic Chemistry,2006,45, (2):582-590.
[114]Quan-Xiu Li, Yi-Zhi Li, Xiao-Zeng You, etc. Syntheses, Structures, and Magnetic Properties of Heterobimetallic Clusters with Tricyanometalate and π-Conjugated Ligands Containing 1,3-Dithiol-2-ylidene, [J], Inorg. Chem.2010,49:1905-1912.
[115]陈向军,以[Cr(phen)(CN)4]配离子为组装单元的配合物的合成与表征[D],内蒙古大学硕士学位论文,2007年.
[116]Long Jiang, Xiao-Long Feng, Tong-Bu Lu, etc. Self-Assembly from Discrete Clusters to 2D Network Based on [Fe(phen)(CN)4]- and [Fe(bipy)(CN)4]-:Synthesis, Structures and Magnetic Properties,[J],European Journal of Inorganic Chemistry,2009,14:2074-2082.
[117]Yuan-Zhu Zhang, Song Gao,Hao-Ling Sun, etc. Linking cyano-bridged ladders by azide to form a layered metamagnet, [J],Chem.Commun,2004:1906-1907.
[118]Luminita T, Rodrigue L, Jacqueline V, etc. Nuclearity Controlled Cyanide-Bridged Bimetallic CrⅢ-MnⅡ Compounds:Synthesis, Crystal Structures, Magnetic Properties and Theoretical Calculations, [J],Chem. Eur. J, 2004,10,6130.
[119]Liviu T, Luminita M T., Rodrigue L, etc. Synthesis, crystal structures and magnetic properties of cyanideand phenolate-bridged [MⅢNiⅡ]2 tetranuclear complexes (M= Fe and Cr), [J],Dalton trans,2005: 1357.
[120]Luminita T, Rodrigue L, Jacqueline V, etc. [CrⅢ(L)(CN)4]-:a new building block in designing cyanide-bridged 4,2-ribbon-like chains{[CrⅢ(L)(CN)4]2Mn(H2O)2}nH2O [L=2-aminomethyl pyridine (n= 6) and 1,10-phenanthroline (n= 4)], [J], New J.Chem,2005,29:210.
[121]Shi W, Peter D, Luminita M T, etc. TTF charge transfer salts containing cyanometallate anions [M(phen)(CN)4]-(M= Cr or Fe; phen= 1,10-phenanthroline), [J],Inorg Chim Acta,2006,359:3283.
[122]Yuan-Zhu Zhang, Zhe-Ming Wang, Song Gao, etc. Heterometallic Cr-Mn Complexes Containing Cyanide and Oxalate Bridges, [J], Inorg Chem,2006,45:5447-5454.
[123]Yuan-Zhu Zhang., Song Gao, Zhe-Ming Wang., etc. Rational Synthesis and Magnetic Properties of a Family of Low-Dimensional Heterometallic Cr-Mn Complexes Based on the Versatile Building Block [Cr(2,2'-bipyridine)(CN)4]-, [J],Inorg Chem,2005,44:4534-4545.
[124]Yuan-Zhu Zhang, Zhe-Ming Wang, Song Gao. Three-Dimensional Heterometallic Chiral Cr-Mn Compound Constructed by Cyanide and Dicyanamide Bridges, [J],Inorg Chem,2006,45:10404-10406.
[125]Kou H Z, Gao S, Bai O, etc. Magnetic characteristics of new cyano-bridged two-dimensional honeycomb-like bimetallic assemblies containing NiⅡ-N equivalent to C-CrⅢ or NiⅡ-N equivalent to C-CrⅠ linkages, [J], Inorg Chem,2001,40:6287-6294.
[126]Hui-Zhong Kou, Jin-Kui Tang, Dai-Zheng Liao, etc. Crystal Structures and Magnetic Properties of New Cyano-Bridged Two-Dimensional Grid-Like Bimetallic Assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH·H2O and [Ni(tn)2]2[Co(CN)6]NO3·2H2O (tn=1,3-Propanediamine), [J], Inorg Chem,2001,40:4839-4844.
[127]Shaikh N, Panja A, Goswami S, etc. Synthesis, crystal structure and magnetic properties of cyanide bridged 2D coordination polymers [Mn(salen)]2[Fe(CN)5NO] and [Mn(salen)]2[Ni(CN)4], [J], Indian J Chem Techn,2004,43(7):1403-1408.
[128]Liu CQ,Shi JM, Xu W, etc. Synthesis, crystal structure and magnetic behavior of a one-dimensional chain complex:{[Cu(N-men)2Fe(CN)5(NO)]·H2O}n, [J],Pol J Chem,2003,77 (7):929-933.
[129]Zhong-Hai Ni, Ai-Li Cui, Hui-Zhong Kou, etc. Cyanide-Bridged Mn(Ⅲ)-Fe(Ⅲ) Bimetallic Complexes Based on the Pentacyano(1-methylimidazole)ferrate(Ⅲ) Building Block:Structure and Magnetic Characterizations, [J], Inorganic Chemistry,2007,46,1.
[130]Miyasaka, H.; Matsumoto, N.; Okawa, H. etc. The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6], [J], Angew. Chem., Int. Ed. Engl.1995,34:1446.
[131]MiyasakaH.; Matsumoto, N.; Okawa, H. etc. Floriani, C. Complexes Derived from the Reaction of Manganese(Ⅲ) Schiff Base Complexes and Hexacyanoferrate(Ⅲ):Syntheses, Multidimensional Network Structures, and Magnetic Properties, [J], J. Am.Chem. Soc.1996,118:981.
[132]Miyasaka, H.; Ieda, H.; MatsumotoN.; etc. Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures Using a Desolvation Reaction:Synthesis, Structure, and Magnetic Properties of Manganese(Ⅲ)-Schiff-Base-Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures, [J], Inorg. Chem.1998,37:255.
[133]Miyasaka, H.; Matsumoto, N.; Re, N.; etc. Synthesis, Crystal Structure, and Magnetic Properties of a Ferrimagnetic Layered Compound [NEt4][Mn(5-Cl-salen)]2[Fe(CN)6](NEt4= Tetraethy-lammonium, 5-Cl-salen= N,N'-Ethylenebis((5-chlorosalicylidene)aminato)), [J],InorgChem.1997,36:670.
[134]Ferbinteanu, M.; Miyasaka, H.; WernsdorferW.; etc. Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2 Fe(CN)6] Made of MnⅢ-FeⅢ-MnⅢ Trinuclear Single-Molecule Magnet with an ST= 9/2 Spin Ground State. [J],J. Am. Chem. Soc.2005,127:3090.
[135]Dai-Zheng Liao, Shi-Ping Yan, Guang-Ming Yang,etc. Bimetallic Materials Derived from manganese(Ⅲ) Schiff Base Complexes and Pentacyanidonitrosylferrate(Ⅱ) Precursor:Structures and Magnetic Properties, [J],Inorg. Chem.2010,49,2047-2056.
[136]张引莉,Schiff碱及其配合物应用研究及进展,[J],化工时刊,第22卷第5期,2008年.
[137]Ajay K S,Tomoaki T, Masahiro M.Tri-and tetranuclear copper(Ⅱ)complexes consisting of mononuclear Cu(Ⅱ)chiral building blocks with a sugar-derived Schiff's base ligand. [J], Inorg Chem,2006,45:2083-2092.
[138]Averseng F,Lacroix P G,Malfant I, etc. Enhanced second harmonic generation on passing from a mono-to a dicopper(Ⅱ)bis(salicylaldiminato)Schiff base complex. [J],Inorg Chem,2001,40:3797-3804.
[139](a)Mei Yuan.Azide-Bridged One-Dimensional MnⅢ Polymers:Effects of Side Groupof Schiff Base Ligands on Structure and Magnetism,[J],Inorganic Chemistry.2007,46,11235-11239;(b)Lollita Lecren. One-Dimensional Supramolecular Organization of Single-Molecule Magnets[J], J. Am. Chem. Soc.2007,129, 5045-5051;(c) Jian-Wei Lu. New 1-oxo-bridged tetranuclear Cu(Ⅱ) complex with Schiff-base ligand:Synthesis, crystal structure and magnetic properties [J], Inorg. Chem. Comm.2007,10,1210-1213.
[140](a)Chandra S, Sharma AK. Synthesis and spectroscopic characterization of homo binuclear Cr-Ⅲ, Mn-Ⅱ, Co-Ⅱ and Ni-Ⅱ complexes of 1,4-diformylpiperazine derivative[J]. Journal of the Indian Chemical Society, 2009,86(7):690-696; (b) Prakash D; Kumar C; Prakash S, etc. Synthesis, spectral characterization and antimicrobial studies of some new binuclear complexes of Cu-Ⅱ and Ni-Ⅱ Schiff base[J], Journal of the Indian Chemical Society,2009,86(12):1257-1261; (c) Costes JP; Auchel M; Dahan F, etc. Synthesis, structures, and magnetic properties of tetranuclear Cu-Ⅱ-Ln(Ⅲ) complexes[J], Inorgenic Chemistry,2006,45 (5):1924-1934; (d)Mukherjee P, Drew MGB, Tangoulis V, etc. Facile strategies for the synthesis and crystallization of linear trinuclear nickel(Ⅱ)-Schiff base, complexes with carboxylate bridges:Tuning of coordination geometry and magnetic properties[J]. Polyhedron,2009,28(14):2989-2996; (e)Costes, Jean-Pierre, Garcia-Tojal, etc. Structural and Magnetic Study of a Trinuclear Mn-Ⅱ-Gd-Ⅲ-Mn-Ⅱ Complex[J]. European Journal of Inorganic Chemistry,2009,25:3801-3806; (f) Zhang SH, Tang MF, Ge. CM, etc. Microwave Synthesis, Crystal Structure and Magnetic Behavior of a Schiff Base Trinuclear Nickel Cluster[J], Zeitschrift fur anorganische und allgemeine Chemie,2009,635(9-10):1442-1446; (g)Banerjee A, Singh R, Mondal P, etc. Tetranuclear Copper(Ⅱ) Complexes Bearing Cu4O6 and Cu4O4 Cores:Synthesis, Structure, Magnetic Properties, and DFT Study [J]. European Journal of Inorganic Chemistry,2010,5:790-798.
[141]Barra,A. L., Caneschi,A, Cornia,A, etc.Single-Molecule Magnet Behavior of a Tetranuclear Iron(Ⅲ) Complex. The Origin of Slow Magnetic Relaxation in Iron(Ⅲ)Clusters. [J], J. Am. Chem. Soc.1999,121: 5302-5310.
[142]Andreas Sieber. Synthesis and Spectroscopic Characterization of a New Family of-Ni4 Spin clusters, [J],Inorg. Chem,2005,44:4315-4325.
[143]Arindam Mukherjee. Magnetostructural Studies on Ferromagnetically Coupled Copper(ⅱ) Cubanes of Schiff-Base Ligands, [J],Chem. Eur. J.2005,11:3087-3096.
[144]Ayuk M. Ako, Annie K. Powell, Hiroki Oshio,etc. Molecular Magnets Containing Wheel Motifs, [J],Inorganic Chemistry,2009,48(8):33396-3407.
[145]Qiong Wu, Lollita Lecren, Rodolphe Clerac,etc. Synthesis, structure and magnetism of new polynuclear transition metal aggregates assembled with Schiff-base ligand and anionic N-donor ligands, [J], Journal of Molecular Structure 2008:339-345.
[146]Chaitali Biswas, Michael GB. Drew, Ashutosh Ghosh, etc. Magnetic coupling in trinuclear partial cubane copper(II) complexes with a hydroxo bridging core and peripheral phenoxo bridges from NNO donor Schiff base ligands, [J], Inorganica Chimica Acta,2010:846-854.
[147]Jung Oh Huh, Chang Seop Hong, David G. Churchill,etc. Synthesis, Structure, and Magnetic Properties of Closely Related Mono-and Di-Cu(Ⅱ) Schiff Base Complexes:Formation of Water Clusters and Hydrogen-Bonded Networks, [J],Cryst. Growth Des.,2010,10 (1):327-334.
[148]田秀梅,苯甲醛类Schiff碱及其配合物的合成、晶体结构与性能研究[D],新疆大学硕士研究生学位论文,新疆大学,2008.
[1]Rikken, G. L. J. A., Raupach, E. Observation of magneto-chiral dichroism, [J],Nature 1997,390:493-494.
[2]Liu, W. L.; Song, Y.; Li, Y. Z.; etc. Self-assembly of a 1D heterotrimetallic Cu(Ⅱ)-Sr(Ⅱ)-Na(Ⅰ) propeller-like chiral coordination polymer with ferromagnetic interactions, [J], J. Chem. Commun.2004: 2348-2349.
[3]Katsuya Inoue, Hiroyuki Imai, Prasanna S, etc. A Three-Dimensional Ferrimagnet with a High Magnetic Transition Temperature (Tc) of 53 K Based on a Chiral Molecule[J], Angewandte Chemie International Edition, 2001,40(22):4242-4245; (b) Coronado, E.; Go' mez-Garcia, C. J.; Nuez, A.; etc. Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds [J], Inorg. Chem.2002,41(18):4615-4617; (c) Katsuya Inoue, Koichi Kikuchi, Hisashi Okawa, H. etc.Structure and Magnetic Properties of a Chiral Two-Dimensional Ferrimagnet with Tc of 38 K[J], Angewandte Chemie International Edition,2003,42(39), 4810-4813; (d) Imai, H.; Inoue, K.; Kikuchi, K.; etc. Three-Dimensional Chiral Molecule-Based Ferrimagnet with Triple-Helical-Strand Structure [J],Angew. Chem., Int. Ed,.2004,43(42):5618-5621.
[4]Zhao-Xi Wang, Jia Wei, You Song, etc.Two trinuclear copper(Ⅱ)-octacyanometalate(Ⅳ) bimetallic complexes coordinated with chiral ligands.[J], Journal of Molecular Structure,2008,875:198-204.
[5]You Song, Xi-Rui Zeng, Xiao-Zeng You, etc.Syntheses, Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [Fe(bpca)(CN)3], [J],Inorganic Chemistry,2006,45 (2): 52-590.
[6](a)Ahmet Karadag, Yusuf Yerli, Ibrahim Onal,etc. Preparations, IR spectra and crystal structures of cyano-bridged bimetallic complexes of zinc(Ⅱ) and cadmium(Ⅱ) with tetracyanopalladate(Ⅱ), [J], Journal of Coordination Chemistry, Vol.60, No.19,1 October 2007,2035-2044;(b) Ahmet Karadag, Yusuf Yerli Ertanshin,etc.Syntheses, IR spectra, thermal properties and crystal structures of novel cyano-bridged polymeric complexes of zincⅡ and cadmiumll with tetracyanoplatinate, [J], Polyhedron 27 (2008) 223-231;(c) Ahmet Karadag, Yusuf Yerli,Ibrahim Onal,etc. Preparation, structural, magnetic and thermal properties of two heterobimetallic cyano-bridged nickel(Ⅱ)-copper(Ⅱ)/platinum(Ⅱ) coordination polymers, [J], Inorganica Chimica Acta 362 (2009) 2299-2304.
[7](a)Eric A. Maatta,Changmin Kim,Structure of an L-Tyrosyl-L-histidine-Copper Complex Involving an Axial Copper(Ⅱ)-PhenolOH Bonding. Implication for Substrate Binding at the Active Site of Tyrosinase, [J],Inorg. Chem.1989,28,624-625; (b) I. M. Procter, B. J. Hathaway, and P. Nicholls,The Electronic Properties and Stereochemistry of the Copper(ii)Ion.Part I.Bis(ethylenediamine)copper(Ⅱ) Complexes ,[J],J. Chem. SOC. (A),1968,pp:1678; (c)Jun Tao, Yong Zhang, Ming-Liang Tong, etc.A mixed-valence copper coordination polymer generated byhydrothermal metal/ligand redox reactions[J],CHEM COMMUN. 2002,1342-1343.
[8](a) Holden Thorp Bond Valence Sum Analysis of Metal-Ligand Bond Lengths in Metalloenzymes and Model Complexes[J], Inorg. Chem.1992,31:1585-1588; (b) Ruth E, Saari Robert P Hausinger Robert A, X-ray absorption spectroscopic analysis of Fe(Ⅱ) and Cu(Ⅱ) forms of a herbicide-degrading a-ketoglutarate dioxygenase[J], JBIC,1999,4:122-129.
[9](a) Albert Figuerola, Carmen Diaz, Joan Ribas, Synthesis and Characterization of Heterodinuclear Ln3+-Fe3+ and Ln3+-Co3+ Complexes, Bridged by Cyanide Ligand(Ln3+) Lanthanide Ions:Nature of the Magnetic Interaction in the Ln3+-Fe3+ Complexe[J], Inorganic Chemistry,2003,42(2):641; (b)Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Acta,2004 (357):3271-3278; (c) Rodriguez-Dieguez, A; Colacio, E,Crystal structure and magnetic properties of [{Cu(cyclam)}3{Fe(CN)6}2]·6H2O, a cyano-bridged assembly with a rope-ladder chain structure[J], Polyhedron,2007,26:2859-2863.
[10]Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Acta 2004,357:3271-3278.
[11]Juraj Kucha, Francois Varret, and Werner Massa, Polymeric [{Cd(en)}3{Fe(CN)6}2]·4H2O:Preparation, Crystal Structure and Characterization (en=1,2-diaminoethane)[J], Z. Anorg. Allg. Chem.2006,632:495-500
[12]孟令芝,龚淑玲,何永炳,有机波谱分析[M],武汉大学出版社,2004.
[13]Sindhu Menon, M. V. Rajasekharan, J.-P. Tuchagues, Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2-H2O (bp3ca=2,2'-Bipyridine-3,3'-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges, [J],Inorg. Chem.1997,36,4341-4346.
[14]Maxwell A. Braverman, Robert L. LaDuca, Hydrothermal synthesis of divalent metal pyromellitate /dipyridylamine complexes:From an unprecedented supramolecular three-dimensional topology to an anionic coordination polymer framework with large incipient cation-bearing voids, [J],CrystEngComm,2008,10, 117-124.
[15]Maxwell A. Bravermana, Ronald M. Supkowskib, Robert L. LaDucaa, Luminescent zinc and cadmium complexes incorporating 1,3,5-benzenetricarboxylate and a protonated kinked organodiimine:From a hydrogen-bonded layer motif to thermally robust two-dimensional coordination polymers, [J],J. Solid State Chem.,2007,180,1852-186.
[16]Xinjun Luan, Yichun Chu, Yaoyu Wang, etc.Formation of Two-Dimensional Supramolecular Water Layer Containing (H2O)18 Morphology via Dianion Templating, [J],Cryst. Growth Des.,2006,6,812-814.
[17]Qian Chu, Guang-Xiang Liu, Wei-Yin Sun, etc., Syntheses, structures, and optical properties of novel zinc(Ⅱ) complexes with multicarboxylate and N-donor ligands, [J], Dalton Trans.,2007,4302-4311.
[18]Zhong-Ming Sun, Jiang-Gao Mao, Yan-Qiong Sun, etc., Hydrothermal synthesis, characterization and crystal structures of two new layered lead(Ⅱ) diphosphonates, [J], New J. Chem.,2003,27,1326-1330.
[19]Subhashree Mallika Krishnan, Niral M. Patel, Robert L. LaDuca, Oxoanion and cation effects on the structural morphology of coordination polymers incorporating a kinked organodiimine tethering ligand, [J],CrystEngComm,2007,9,503-514.
[20]R.Custelcean,Vincent Sellin and B.A.Moyer, Sulfate separation by selective crystallization of a urea-functionalized metal-organic framework,[J], Chem.Commun.,2007,1541.
[21]Hui-Zhong Kou, Jin-Kui Tang, Dai-Zheng Liao, etc. Crystal Structures and Magnetic Properties of New Cyano-Bridged Two-Dimensional Grid-Like Bimetallic Assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH-H2O and [Ni(tn)2]2[Co(CN)6]NO3-2H2O (tn=1,3-Propanediamine), [J], Inorg Chem,2001,40:4839-4844.
[22]Taka-aki Okamura,Norikazu Ueyamac and Wen-Xia Tang,etc.A novel Cu(Ⅱ)-W(Ⅴ) bimetallic assembly magnet{[Cu(en)2]3[W(CN)8]2·H2O}(en=ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reactiony, [J], New J. Chem.,2002,26,485-489.
[23]刘孟军,含氮、氧配体构筑的超分子金属配合物的合成与结构[D],内蒙古大学,2009；(b)Xiang-Jian Kong, Yan-Ping Ren, Zheng, Gary Nichol, etc. Dual Shell-like Magnetic Clusters Containing Ni(Ⅱ) and Ln(Ⅲ)(Ln= La, Pr, and Nd) Ions[J], Inorg. Chem.,2008,47 (7),2728-2739.
[24]日本化学会编,曹惠民译,无机化合物合成手册(第三卷)[M],北京：化学工业出版,1998,477,379.
[25]Ma B. c, Gao S, Sn G. etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavio, [J],Angew. Chem. Int. Ed,2001,40:434.
[26]Albert Figuerol, Carmen Diaz, Joan Ribas, etc. Structure and magnetism of the first cyano-bridged hetero-one-dimensional Gdm-Crm complexes, [J],Chem. Commun.,2001,1204-1205.
[27](a) G. W. Beall, D. F. Mullica, etc.The crystal structure of LaKFe(CN)6.4H2O,[J], Acta Cryst. (1978). B34, 1446-1449; (b) T. Siegristl, C. Besnard and C. Svensson, Crystal structure of CsLnFe(CN)6·5H2O (Ln=Ce, Pr, Nd), CsCeFe(CN)6·4H2O, and T1TmRu(CN)6·3H2O,[J],Solid State Sciences,2(6),2000,607-614; (c) D. F. Mullica, W. O. Milligan and R. L. Garner,Refined crystal structure of lanthanum hexacyanoferrate(III) tetrahydrate, [J]Acta Cryst. (1980). B36,2561-2564; (d) F. H. Herbstein and R. E. Marsh, Changes in space and Laue groups of some published crystal structures,[J], Acta Cryst. (1982). B38,1051-1055.
[1]Jan Vanoc, Jarom'r Marek, Zdenek Travncek, etc.Synthesis, structural characterization, antiradical and antidiabetic activities of copper(Ⅱ) and zinc(Ⅱ) Schiff base complexes derived from salicylaldehyde and b-alanine[J], Journal of Inorganic Biochemistry,2008,102:595-605.
[2]Mandal S, Rosair G Ribas J, etc. Synthesis, crystal structure and magnetic characterization of a new phenoxo-bridged binuclear manganese(Ⅲ) Schiff base complex exhibiting single-molecule-magnet behavior[J], Inorganica Chimica Acta,2009,362 (7):2200-2204.
[3](a)Mishtu Dey.Chebrolu Pulla Rao,Pauli Saarenketo, etc.Four-, Five-and Six-Coordinated ZnⅡComplexes of OH-Containing Ligands Syntheses, Structure and Reactivity,Eur.[J], J. Inorg. Chem.2002,2207-2215;(b) Mishtu Dey, Chebrolu P. Rao, Pauli K. Saarenketo,etc. Mono-, di-and tri-nuclear Ni(Ⅱ) complexes of N-, O-donor ligands:structural diversity and reactivity[J].Inorganic Chemistry Communications 5 (2002) 924-928; (c) Mishtu Dey, Chebrolu P. Rao, Pauli K. Saarenketo,etc. Synthesis, structural diversity, inter-conversion and reactivity of Cu(Ⅱ) complexes of hydroxy-rich molecules[J], Inorganic Chemistry Communications 5 (2002) 380-383.
[4]Dey,M.; Rao, C. P.; Saarenketo, P. K.; etc. Mn(Ⅳ) and Co(Ⅲ)-complexes of-OH-rich ligands possessing O2N,O3N and O4N cores:syntheses,characterization and crystal structures.[J], Polyhedron 22 (2003) 3515-3521.
[5]Guo-Min Wang, Li-Li Hu, Jun Tao.etc. Synthesis and magnetic properties of a new hexanuclear iron(III) compound[J], Inorganic Chemistry Communications 12 (2009) 622-624.
[6](a)袁瑞娟,阮文娟,朱必学等.手性双核Salen配合物的合成与谱学性质[J],无机化学报,2004,20(4)444-450；(b)中本一雄著,无机和配位化合物的红外和拉曼光谱(第四版),[M],化学工业出版社1991,228-234,304-306.
[7]孟令芝,龚淑玲,何永炳.有机波谱分析,[M]武汉大学出版社,2004.
[8]Shyamapada Shit,etc. A rare ferromagnetically coupled asymmetric doubly azido bridged copper(II) dimer with an N, N, O donor Schiff base [J],Polyhedron 2007,46,1357-1363.
[9]Xian-Ming Zhang, Rui-Qin Fang, and Hai-Shun Wu, A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer, [J], J Am Chem. Soc.2005,127,7670-7671.
[10]Gong-Ping Duan,Osamu Satob,Song Gao,etc. Structures and magnetism of cyano-bridged grid-like two-dimensional 4f-3d arrays, [J], J. Mater. Chem.,2006,16,2625-2634.
[11](a) Alexander J. Blake, Neil R. Champness, Peter Hubberstey, etc.Inorganic crystal engineering using self-assembly of tailored building-blocks[J], Coord. Chem. Rev.1999,183:117; (b) Susan A. Bourne,and Lesego J. Moitsheki, Copper(Ⅱ) and lead(Ⅱ) complexes of 4,4-bipyridine-N,N- dioxide,[J], Journal of Chemical Crystallography, Vol.37, No.5,2007 359-367; (c) Susan A. Bourne and Lesego J. Moitsheki, Anion dependent structural diversity in cobalt(Ⅱ) complexes of 4,4'-bipyridine-N,N'-dioxide, [J],CrystEngComm, 2005,7,674-681; (d) Shu-Lan Ma, Wen-Xiang Zhu, Gui-HaiHuang,etc. Novel three-dimensional network of lanthanum(Ⅲ) complex{[La2(BTA)6(4,4'-bpdo)1.5]·1.5H2O}n (BTA= benzoyltrifluoroacetone; 4,4'-bpdo= 4,4'-bipyridine dioxide) [J], Journal of Molecular Structure 646 (2003) 869-94; (e) Shu-Lan Ma, Chuan-Min Qi, Qian-Ling Guo,etc. The novel one-dimensional chain of europium(Ⅲ) complex[Eu2(BTA)6(4,4'-bpdo)]n containing dimers bridged by terminal oxygen atoms of 4,4'-bpdo molecules[J], Journal of Molecular Structure 738 (2005) 99-104; (f) De borah Gonza' lez Mantero, Antonia Neels,etc. Novel 3D,2D, and OD First-Row Coordination Compounds with 4,4'-Bipyridine-N,N'-dioxide Incorporating Sulfur-Containing Anions,[J],Inorganic Chemistry,45,3287.
[12]Peter Hubberstey,Claire Wilson, Martin Schro,etc. Multi-Dimensional Transition-Metal Coordination Polymers of 4,4'-Bipyridine-N,N'-dioxide:1D Chains and 2D Sheets, [J],Inorganic Chemistry,47,,8652-8664.
[13]De-Liang Long, Alexander J. Blake, Neil R. Champness,etc. Can 4,4'-bipyridine N,N'-dioxide play the same important role as 4,4'-bipyridine in the construction of metal coordination networks and crystal engineering [J], Chem. Commun.,2000,2273-2274.
[2]游效曾,分子材料—光电功能化合物.[M].上海科学技术出版社,2001.
[3]张岐,功能配合物研究进展.[M].原子能出版社,2007.
[4]Xie P H, HouY J, Zhnag B W, etc. Spectroscopic and Electrochemical Properties of Ruthenium(Ⅱ) polypyridyl complexes. [J], JChem Soc Dalton Trans,1999, (23):4217-4221.
[5]杨怀霞,苯并咪唑基、二茂铁基功能配合物的合成及性能研究[D],郑州大学硕士学位论文,2007.
[6]Zhang, H. Wang X, Zhang, K, etc. Molecular and crystal engineering of a new class of inorganic cadmium-thiocyanate polymers with host-guest complexes as organic spacers, controllers, and templates, [J],Chem. Rev.,1999,183:157-195.
[7]Hou H W, Wei Y L., Two novel two-dimensional double-sheet layered manganese(Ⅱ) coordination polymers synthesis, crystal structures and third-order nonlinear optical properties[J]. J Mater-Chem,2002, 12(4):838-843.
[8]Elena Chelebaeva, Joulia Larionova, Luis D. Carlos, etc. Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d-4f Ions:Toward Multifunctional Materials. [J],Inorganic Chemistry, 2009,48(13):5983-5995.
[9]Fujita M, Yu S Y, KusukawaT, etc. Self-assembly of nanometer-sized macrotrceyclic complexes from ten small component molecules. [J],Angew Chem Int Ed,1998,37(15):2082-208.5
[10]徐伟平,李光宪.分子自组装研究进展.[J].化学通报,1999,(2).
[11]陈小明,蔡继文.单晶结构分析原理与实践.[M].北京：科学出版社2003.
[12]Stefania Tanase, Jan Reedijk., Chemistry and magnetism of cyanido-bridged d-f assemblies,[J],Coordination Chemistry Reviews 250 (2006) 2501-2510.
[13]Korzeniak, T, Podgajny R, Alcock N W,etc. A new family of magnetic 2D coordination polymers based on [MⅤ(CN)8]3-(M= Mo, W) and pre-programmed Cu2+ centres.[J],Polyhedron,2003,22 (14-17),2183-2190.
[14]Z.Y.Sun, R.Yuan, Y.Q.Chai, etal. Study of a bisfuraldehyde Schiff base copper(Ⅱ) complex as carrier for preparation of highly selective thiocyanate electrodes, [J],Anal Bioanal Chem,2004,378:490-494.
[15]闫小宁,Schiff碱过渡金属配合物的合成、表征及催化性能的研究[D],陕西师范大学硕士学位论文,2006.
[16]王寿武,李宝龙,朱霞,氰根桥联超分子配位化学研究进展.[J].化学世界,2004,(3),154-156.
[17]Michel Verdaguer, A. Bleuzen, V. Marvaud,etc. Molecules to build solids:high Tc molecule-based magnets by design and recent revival of cyano complexes chemistry. [J],Coordination Chemistry Reviews,190-192 (1999) 1023-1047.
[18]韩薇,普鲁士蓝类分子磁体的磁性及穆斯堡尔谱学研究[D],南京航空航天大学硕士论文,2007.
[19]司书峰,廖代正.普鲁士蓝类分子磁体研究的新进展.[J].结构化学.2001,20(3)：233-240.
[20]Ksenofontov V, Georgiy L, Sergey R., etc. Pressure-induced electron transfer in ferromagnetic Prussian blue analogs.[J], Phys, Rev. B,2003,68:024415.1-024415.5.
[21]刘本纬,氰根桥联配合物及甲酸根配合物的合成与结构[D],内蒙古大学硕士学位论文,2006.
[22]寇会忠,廖代正.一种设计实用分子铁磁体的有效构件——普鲁士蓝类配合物[J],无机化学学报,1999年3月,第二期.
[23]Holmes S M, Girolami G S. Sol-Gel. Synthesis of KVⅡ[CrⅢ(CN)6]·2H2O:A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100 ℃, [J],J. Am. Chem. Soc,1999,121:5593-5594.
[24]Hatlevik, Buschmann W E., Zhang J, etc. Enhancement of the magnetic ordering temperature and air stability of a mixed valent vanadium hexacyanochromate (Ⅲ) magnet to 99℃ (372 K)[J],Adv. Mater,1999,11 (11):914-918.
[25]Tomohiro Nuida, Toshiya Hozumi, Wataru Kosaka, etc. Colored magnetic films composed of cyano-bridged metal assemblies and magneto-optical functionalities, [J], Polyhedron 2005 (24):901-2905.
[26]Ferlay S, Mallah T., Ouahes R., etc.A room-temperature organometallic magnet based on Prussian blue, [J],Nature,1995,378 (14):701-703.
[27]Djuardin E., Ferlay S., Phan X., etc. Synthesis and magnetization of new room-temperature molecule based magnet:effect of stoichimetry on local magnetic structure by X-ray magnetic circular dichroism, [J],J. Am. Chem. Soc,1998,120:11347-11352.
[28]Mallah T., Thiebaut S., Verdaguer M., etc. High-Tc Molecular-Based Magnets:Ferrimagnetic Mixed-Valence Chromium(Ⅲ)-Chromium(Ⅱ)Cyanides with Tc at 240 and 190 Kelvin, [J], Science,1993,262: 1554-1557.
[29]Entley, William R.; Girolami, Gregory S. High-temperature molecular magnets based on cyanovanadate building blocks:Spontaneous magnetization at 230 K, [J], Science,1995,268:397.
[30]Mallah, T.; Thiebaut, S.; Verdaguer, M.; Veillet, P. High-T_c Molecular-Based Magnets:Ferrimagnetic Mixed-Valence Chromium(Ⅲ)-Chromium(Ⅱ) Cyanides with Tc at 240 and 190 Kelvin,[J],Science, 993,262,1554.
[31]Gadet V, Mallah T., Castro L, etc.High-Tc Molecular-Based Magnets:A Ferromagnetic Bimetallic Chromium(Ⅲ)-Nickel(Ⅱ) Cyanide with Tc=90K, [J], J. Am.Chem. Soc.1992,114:9213-9214.
[32]Entley W. R., Treadway C. R., Girolami G S., etc. Molecular Magnets Construct ed from Cyanometalate Building Blocks, Mol. [J],Cryst. Liq. Cryst.1995,273:153 -158.
[33]Buschmann W. E., Miller J. S., Magnetic Ordering and Spin-Glass Behavior in First-Row Transition Metal Hexacyomanganate (Ⅳ) Prussian Blue Analogues, [J],Inorg. Chem.2000,39(11):2411-2421.
[34]W.R.Entley, G.S.Girolami. New Three-Dimensional Ferrimagnetic Materials:KMn[Mn(CN)6], Mn3[Mn(CN)6]2·12H2O, and CsMn[Mn(CN)6]·1/2H2O [J], Inorg Chem,1994,33,5165-5166.
[35]Hashimoto K., Ohkoshi S. L, Design of novel magnets using Prussian blue analogues, [J],The Royal Society,1999,357:2977-3003.
[36]Hashimoto K,Ohkoshi S. I, Abe Y., Fujishima A, etc. Design and preparation of a novel magnet exhibiting two compensation temperature based on molecular field theory, [J],Pys. Rev. Lett.1999,82 (6): 1285-1288.
[37](a)Michel Verdaguer,Bleuzen A., Lomenech C., Escax V, etc. Photodinduced ferromagnetic systems in Prussian blue analogues CⅠCo4[Fe(CN)6]y (CⅠ=-Alkali Cation)1. conditions to observe the phenomenon, [J], J. Am. Chem. Soc.,2002,122:6648-6652.;(b) Remy Le Bris, Jean-Daniel Cafun, Optical and magnetic properties of the photo-induced state in the coordination network Na2Co4[Fe(CN)6]3.3·14H2O [J], New J. Chem., 2009,33,1255-1261.
[38]Cao Minhua, Wu Xinglong, He Xiaoyan, etc. Shape-controlled synthesis of Prussian blue analogue Co3[Co(CN)6]2 nanocrystals, [J],Chem.Comm.,2005:2241-2243.
[39]Diana Visinescu, Luminita M. Toma, Miguel Julve, etc. New 3d-4f supramolecular systems constructed by [Fe(bipy)(CN)4],and partially blocked lanthanide cations, [J], Polyhedron 2009 (28):851-859.
[40]F. Hulliger, M. Landolt, H. Vetsch, Rare-earth ferricyanides and chromicyanides LnM(CN)6·nH2O, [J], J. Solid State Chem.,1976,18,283.
[41]Bao-Qing Ma, Song Gao, Gang Su, Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two- Dimensional Topological Architecture and Unusual Magnetic Behavior. [J], Angew.Chem. Int. Ed.2001, 40(2).
[42]寇会忠,周北川.氰根桥联配合物的结构与磁性研究.[J],无机化学学报2004,20(5),497-508.
[43]袁爱华,周虎,沈小平.氰基桥联配合物的研究进展.[J],化学研究与应用2005,5：582-587.
[44]刘敏,杂化氰根桥联配合物的磁性研究[D],广西师范大学硕士论文,2008.
[45]M. Ohba, N. Maruono, H. Okawa, etc. A New Bimetallic Ferromagnet, [Ni(en)2]3[Fe(CN)6]2·2H2O, with a Rare Rope-Ladder Chain Structure, [J], J.Am.Chem.Soc,1994,116,11566.
[46](a) Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Act,2004 (357):3271-3278; (b) Rodriguez-Dieguez, A; Colacio, E,Crystal structure and magnetic properties of [{Cu(cyclam)}3{Fe(CN)6}2]·6H2O, a cyano-bridged assembly with a rope-ladder chain structure[J], Polyhedron,2007,26:2859-2863; (c) Travnicek, Z; Smekal, Z; Escuer, A, etc. Synthesis, structure and magnetic behaviour of a two-dimensional cyano-bridged complex [{Cu(ept)}3Fe(CN)6] (ClO4)(2)·5H2O [ept= N-(2-aminoethyl)-1,3-diaminopropane] [J], New Journal of chemstry,2001,25(4):655-658;(d) Yuan AH, Shen XP, Zhou H. Crystal structure and magnetic properties of a three-dimensional complex constructed from [CuL]2+ and [Fe(CN)6]3- precursors.[J], Transition Metal Chemistry,2008,33(1):133-136.
[47](a)Yi-Zhi Lia, Ai-Hua Yuanb, Zheng Xu, etc.A novel three-dimensional mixed bridging-ligand complex with an unexpected 1,3-diaminopropane bridge,[J], Journal of Molecular Structure 2005 (754):106-110;(b) Zhan SZ, Yu KB, Liu J, [Ni(Ⅱ)(tn)2]5[Fe(Ⅲ)(CN)6]2[Fe(Ⅱ)(CN)6]·10H2O:A 3-dimensional dimetallic polymer exhibiting ferromagnetic interaction[J], Inorganic Chemistry Communication 2006,9 (10):1007-1010.
[48]Masaaki Ohba, Naoki Usuki, Nobuo Fukita, Three-Dimensional Dimetallic Ferrimagnet (Tc=69 K) with a Defective Cubane Unit[J], Angew. Chem. Int. Ed,1999,38:1795.
[49]Inoue K, Imai H, Ghalsasi P.S, etc. A Three-Dimensional Ferrimagnet with a High Magnetic Transition Temperature (Tc) of 53 K Based on a Chiral Molecule, [J], Angew. Chem. Int.Ed,2001,40:4242.
[50]J.A.Smith, J-R.Galan-Mascaros, R.Clerac, etc.{Mn(OH2)2[Mn(bpym)(OH2)]2[Fe(CN)6]2}n:a two-dimensional ferrimagnet with a partial cubane motif, [J],Chem.Commun,2000,1077-1078.
[51]M.Ohba, H.Okawa. Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies [J],Coord.Chem.Rev,2000,198:313.
[52]H-Z Kou, S Gao, B-Q Ma, etc.. A cyano-bridged molecular magnet with a novel two-dimensional brick wall structure, [J],Chem.Commun,2000,1309-1310.
[53]M.S.El Fallah, E.Rentschler, A.Caneschi, etc. A Three-Dimensional Molecular Ferrimagnet Based on Ferricyanide and [Ni(tren)]2+ Building Blocks, [J],Angew.Chem.Int.Ed,1996,35,1947.
[54](a) Kou, HZ, Tang, JK, etc.Crystal structures and magnetic properties of new cyano-bridged two-dimensional grid-like bimetallic assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH·H2O and [Ni(tn)2]2[Co(CN)6] NO3·2H2O (tn=1,3-propanediamine)[J], Inorganic Chemistry,2001,40 (19):4839-4844; (b)Kou, HZ;Gao, S; etc. Magnetic characteristics of new cyano-bridged two-dimensional honeycomb-like bimetallic assemblies containing Ni(Ⅱ)-N equivalent to C-Cr(Ⅲ) or Ni(Ⅱ)-N equivalent to C-Cr(Ⅰ) linkages.[J], Inorganic Chemistry 2001,40 (24):6287-6294; (c)Yusuke Yoshida, Katsuya Inoue, Mohamedally Kurmoo, etc.On the Nature of the Reversibility of HydrationsDehydration on the Crystal Structure and Magnetism of the Ferrimagnet [MnⅡ(enH)(H2O)][CrⅢ(CN)6]·H2O, [J], Inorganic Chemistry,2009,48(1):267.
[55]Shen, XP; Li, BL; Zou, JZ, etc. The first cyano-bridged heptanuclear MnⅢ,FeⅢ cluster:crystal structure and magnetic properties of [{Mn(salen)centerd·H2O6Fe(CN)6][Fe(CN)6]·6H2O, [J], Journal of Molecular Structure,2003,657(1-3):325-331.
[56]Marilena Ferbinteanu, Hitoshi Miyasaka, Wolfgang Wernsdorfer, Single-Chain Magnet (NEt4)[Mn2(5- MeOsalen)2Fe(CN)6] Made of MnⅢ-FeⅢ-MnⅢ Trinuclear Single-Molecule Magnet with an ST= 9/2 Spin Ground State, [J], J. Am. Chem. Soc.,2005,127 (9):3090-3099.
[57]Flavio L. Beneditoc, Fabio S. Nunes, A new pentanuclear cyano-bridged complex [{FeⅡ(tetraaza macrocycle)}3{μ-NC-FeⅢ(CN)5}2]:Synthesis, spectroscopic and magnetic characterization, Spectrochimica Acta PartA:[J], Molecular and Biomolecular Spectroscopy,2008,70(5):1029-1033.
[58](a) Diana Visinescu,Luminita Marilena Toma, Francesc Lloret, etc. Unprecedented coexistence of cyano-bridged Mn4ⅢCrⅢ1 and Mn2ⅢCrⅢ heterobimetallic complexes in one single crystal, [J],Dalton Trans., 2009,37-40; (b) Mondal, N; Dey, DK; Mitra, S, etc.Synthesis and characterization of cyano-bridged polynuclear [Cu(dmpn)2]3[Co(CN)6]2·12H2O and trinuclear [Cu(dmpn)2]2[Co(CN)6]·ClO4·3H2O complexes, [J],Polyhedron,vol:20,issue:7-8,pp:607-613,2001;(c) Zhan, SZ; Sun, DS; Wang, JG, etc. Synthesis, crystal structures and magnetic properties of a series of new cyano-bridged complexes derived from templates [Ni(CN)4]2-and [Co(Ⅲ)(CN)6]3-[J], Journal of Coordination Chemistry,2008,61(4):550-562;(d) Nayak M, Majumder S, Lemoine P, etc. Synthesis, Characterization, and Structure of a Cyano-bridged Two-dimensional (CuCo(Ⅲ)-Co(Ⅱ) Coordination Polymer Derived from Trans-1,2-diaminocyclohexane as Blocking Ligand[J], Journal Chemical Crystallography,2008,38(12):937-942; (e) Li BL, Shen XP, etc. Synthesis, structure and characterization of the cyano-bridged heteropolymer poly{[bis(trimethylene-diamine) copper(Ⅱ)] [hexacyanocobalt(Ⅲ)]} perchlorate dihydrate with a two-dimensional framework[J], Journal of Coordination Chemistry,2002,55(10):1191-1198.
[59](a).Yan B, Chen Z. D,Wang S. X etc. A novel cyano-bridged heteronuclear complex [Sm(DMF)4 (H2O)2Mn(CN)6·H2O]n has been synthesized based on the reaction of K3Mn(CN)6, Sm(NO3)3·6H2O and N,N-dimethylformamide (DMF). [J],Chem. Lett.,2001,350; (b) Kou.H. Z, Gao S, Sun BW, etc.A Novel One-Dimensional Chain Cyano-Bridged Complex [Sm(DMF)4 (H2O)2Mn(CN)6·H2O]n:Long-Range Magnetic Ordering, Tc= 18 K and Coercive Force He= 600 Oe, [J],Chem. Mater.,2001,13:1431;(c). Ma B. c, Gao S, Sn G. etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavio [J],Angew. Chem. Int. Ed,2001,40:434.
[60](a) Albert Figuerola, Joan Ribas, Xavier Solans,etc.One Dimensional 3d-4f Heterometallic Compounds: Synthesis, Structure and Magnetic Properties,[J], J. Inorg. Chem.2006,1846-1852; (b) Albert Figuerola, Joan Ribas, Miquel Llunell, etc. Magnetic Properties of Cyano-Bridged Ln3+-M3+ Complexes. Part I:Trinuclear Complexes (Ln3+) La, Ce, Pr, Nd, Sm; M3+ =FeLS, Co) with bpy as Blocking Ligand [J],Inorganic Chemistry, 2005,44,(20):6939.
[61]Bao-Qing Ma, Song Gao, Gang Su, etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavior,[J]Angew. Chem. Int. Ed.2001, 40, (2).
[62]Albert Figuerol, Carmen Diaz, Joan Ribas, etc. Structure and magnetism of the first cyano-bridged hetero-one-dimensional GdⅢ-CrⅢ complexes, [J],Chem. Commun.,2001,1204-1205.
[63]Bing Yan, Zhi-da Chen, The magnetochemistry of novel cyano-bridged complexes Ln(DMF)4 (H2O)2Mn(CN)6·H2O (Ln= Tb, Dy, Er), [J],Transition Metal Chemistry,2001,26:287-289.
[64](a) You Song, Xiao-Zeng You, Kazuhito Hashimoto,etc. Syntheses, Structures, and Properties of Two Three-Dimensional Octacyanometalate-Based Polymers:Cs2Cu3[W(CN)8]2·4NH3·4H2O and Cu2[Mo (CN)8]·8NH3, [J], Crystal Growth &Design,vol:2457-2462,2006; (b)常菲,Ⅰ.氰根桥联的双金属配合物的结构及磁性质,Ⅱ.氮杂环双羧酸氮氧化物的金属配位聚合物.[D],[博士学位论文],北京大学,2002.
[65]Catalin Maxim, Corine Mathoniere, Marius Andruh, etc.New photomagnetic cyanido-bridged CuⅡ-MoⅣ oligonuclear complexes:slight modification of the blocking ligands induces different structures,[J],Dalton Trans.,2009,7805-7810.
[66]Zhuang Jin Zhong, Hidetake Seino, Yasushi Mizobe,etc. A High-Spin Cyanide-Bridged Mn9W6 Cluster (S = 39/2) with a Full-Capped Cubane Structure, [J], J. Am. Chem. Soc.2000, (122):2952.
[67]Chang, F; Sun, HL; Kou, HZ, etc. Structures and magnetism of bimetallic octacyanometallates: honeycomb-like[Mo(CN)8Ni2(pn)4]n·4nH2O and binuclear [Mo(CN)8Ni(en)2(H2O)][Ni(en)3]·2H2O (pn=1,3-diaminopropane, en=1,2-diaminoethane) [J],Inorganic Chemistry Communication,vol:5,issue:9,660-663, 2002.
[68]Zhan, SZ; Wang, JG; Long, B, etc.The assembly, synthesis and properties of a trinuclear cyano-bridged Cu-Ⅱ-Mo-Ⅳ-Cu-Ⅱ complex,[J], Journal of Coordination Chemistry, vol:61, issu:9,pp:1399-1405,2008.
[69]Kania, R; Lewinski, K; Sieklucka, B, etc. Self-assembly of tetranuclear{[Co(trien)]2[W(CN)8]2}2- or {[Co(tren)]2[W(CN)8]2}2-squares with alternating aliphatic tetramine Co(Ⅲ) and octacyanotungstate(Ⅳ) corners,[J], Dalton Trans, vol.5,PP:1033-1040,2003.
[70]Venkatakrishnan, TS; Rajamani, R; Ramasesha, S, etc. Synthesis, crystal structure, and magnetic properties of hexanuclear [{MnL2}4{Nb(CN)8}2] and nonanuclear [{MnL2}6{Nb(CN)8}3] heterometallic clusters (L= bpy, phen), [J], Inorganic Chemistry,46 9569-9574,2007.
[71]Y. Song, P. Zhang, X.-M. Ren, etc. Octacyanometallate-Based Single-Molecule Magnets:CoⅡ9MⅤ6 (M= W, Mo), [J],J.Am. Chem. Soc.2005,127:3708.
[72]G. Rombaut, S. Golhen, L. Ouahab, etc. Structural and photomagnetic studies of a 1-D bimetallic chain [MnⅡ2(L)2(H2O)][MoⅣ(CN)8]·5H2O (L=macrocycle):analogy with the photo-oxidation of K4[MoⅣ (CN)8]·2H2O, [J],J.Chem. Soc., Dalton Trans.2000:3609.
[73]D. Li, S. Gao, L. Zheng, etc. A cyano-bridged MnⅡMoⅤ bimetallic ferrimagnet with a novel moniliform structure, [J],Dalton Trans.2002:2805.
[74]D.-F. Li, L.-M. Zheng, Y.-Z. Zhang, etc. Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers, [J],Inorg. Chem.2003,42:6123.
[75]P. Przychodzen', Wasiutyn'ski, C. Guyard-Duhayon, etc. Crystal Structures and Magnetic Properties of Two Low-Dimensional Materials Constructed from [MnⅢ(salen)H2O]+ and [M(CN)8]3-/4-(M= Mo or W) Precursors, [J], Inorg. Chem.43(2004) 2967.
[76]Y.S. You, D. Kim, Y. Do, etc. One-Dimensional Octacyanomolybdate-Based Cu(Ⅱ)-Mo(Ⅴ) Bimetallic Assembly with a Novel Rope-Ladder Chain Structure, [J],Inorg. Chem.43 (2004)6899.
[77]S. Ikeda, T. Hozumi, K. Hashimoto, etc.Cyano-bridged gadolinium(Ⅲ)-tungstate(Ⅴ) bimetallic assembly with a one-dimensional chain structure, [J], Dalton Trans. (2005) 2120.
[78]R. Podgajny, T. Korzeniak, M. Balanda, T. Wasiutynski,2-D soft ferromagnet based on [WⅤ(CN)8]3- and CuⅡ with a Tc of 34 K, [J],Chem. Comm.(2002) 1138.
[79]S. Ohkoshi, Y. Arimoto, H. Seino, etc. Two-dimensional metamagnet composed of cyano-bridged CuⅡ-WⅤ bimetallic assembly, [J],Chem.Commun.2003:2772.
[80]Y. Arimoto, S. Ohkoshi, Z.J. Zhong, etc.Photoinduced Magnetization in a Two-Dimensional Cobalt Octacyanotungstate, [J],J. Am. Chem. Soc.2003,1259240.
[81]T. Hozumi, S. Ohkoshi, Y. Arimoto, etc.Cooling-rate Dependent Ferromagnetism in a Two-dimensional Cyano-bridged Sm(Ⅲ)-W(Ⅴ) Complex, [J], J. Phys.Chem. B.2003,107:1571.
[82]H.-Z. Kou, Z.-H. Ni, B.C. Zhou, etc. A cyano-bridged molecule-based magnet containing manganese(Ⅲ) Schiff base and octacyanotungstate(V) building blocks, [J],Inorg. Chem.Commun.2004,7:1150.
[83]T. Korzeniak, K. Stadnicka, M. Rams, etc. Grid-Type Two-Dimensional Magnetic Multinuclear Metal Complex:Strands of{[CuⅡ(μ-4,4'-bpy)]2+}n Cross-Linked by Octacyanotungstate(Ⅴ) Ions, [J],Inorg. Chem. 2004,43:4811.
[84]T. Korzeniak, K. Stadnicka, R. Pelka, etc. An unprecedented copper(Ⅰ,Ⅱ)-octacyanotungstate(Ⅴ) 2-D network:crystal structure and magnetism of [CuⅡ(tren)]{CuⅠ[Wv(CN)g]}·1.5H2O, [J], Chem. Commun.2005: 2939.
[85]J.R. Withers, D. Li, J. Triplet, etc.A Two-Dimensional Octacyanomolybdate(V)-Based Ferrimagnet: {[MnⅡ(DMF)4]3[MoⅤ(CN)8]2}n, [J],Inorg. Chem.2006,45:4307.
[86]J.H. Lim, J.S. Kang, H.C. Kim, etc. Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged Honeycomblike Layers MⅤ-CuⅡ (M= Mo, W) Chelated by a Macrocyclic Ligand, [J],Inorg. Chem.2006,45:7821.
[87]M. Atanasov, P. Comba, Y.D. Lampeka,etc. Ation of Cyanometalates by a Tris-macrocyclic Ligand Tricopper(Ⅱ) Complex:Syntheses, Structural Variation, and Magnetic Exchange Coupling Pathways [J],Chem. Eur. J.2006,12:737.
[88]Z.J. Zhong, H. Seino, Y. Mizobe, etc. Crystal Structure and Magnetic Properties of an Octacyano metalate-Based Three-Dimensional Tungstate(Ⅴ)-Manganese(Ⅱ) Bimetallic Assembly, [J], Inorg. Chem.2000, 39:5095.
[89]G. Rombaut, M. Verelst, S. Golhen, etc. Hepta/octa cyanomolybdates with Fe2+:influence of the valence state of Mo on the magnetic behavior, [J], New J. Chem.2000,24:871.
[90]J.M. Herrera, A. Bleuzen, M. Julve, etc. Crystal Structures and Magnetic Properties of Two Octacyano tungstate(Ⅳ) and(Ⅴ)-Cobalt(Ⅱ) Three-Dimensional Bimetallic Frameworks, [J],Inorg.Chem.2003,42:7052.
[91]Y. Song, S. Ohkoshi, Y. Arimoto, etc. Hashimoto, Synthesis, Crystal Structures, and Magnetic Properties of Two Cyano-Bridged Tungstate(Ⅴ)-Manganese(Ⅱ) Bimetallic Magnets, [J], Inorg. Chem.2003,42:1848.
[92]D. Li, L. Zheng, X. Wang, etc. [Cu(tn)]3[W(CN)8]2·3H2O and [Cu(pn)]3 [W(CN)8]2·3H2O:Two Novel Cu(Ⅱ)-W(Ⅴ) Cyano-Bridged Two-Dimensional Coordination Polymers with Metamagnetism, [J],Chem. Mater. 2003,15:2094.
[93]T.Kashiwagi, S.Ohkoshi, H. Seino, etc. Hashimoto, Manganese(Ⅱ) Octacyanotungstate(Ⅴ)-Based Mag-net Containing a Noncoordinated Aromatic Molecule,[J],J.Am. Chem. Soc.2004,126:5024.
[94]T. Hozumi, K. Hashimoto, S. Ohkoshi, etc.Electrochemical Synthesis, Crystal Structure, and Photomagnetic Properties of a Three-Dimensional Cyano-Bridged Copper-Molybdenum Complex, [J], J. Am. Chem. Soc.2005,127:3864.
[95]J.R. Withers, C. Ruschman, S. Parkin, etc. One-and three-dimensional octacyanometalate(IV) networks constructed via a building block approach:{[trans-NiⅡ(tn)2(OH2)][trans-NiⅡ(μ-NC)2(tn)2][(μ-NC)3MⅣ (CN)5]·6H2O} (MⅣ= Mo, W) and Cs4[CuⅡ(OH2)4]2[CuⅡ(NH3)]4[MoⅣ(CN)8]4·2H2O, [J],Polyhedron 2005,24: 1845.
[96]Z.-X. Wang, X.-F. Shen, Y. Song, etc. X.-Z. You, A Sodalite-like Framework Based on Octacyano molybdate and Neodymium with Guest Methanol Molecules and Neodymium Octahydrate Ions, [J],Angew. Chem. Int. Ed.2006,45:3287.
[97]J. Larionova, S. Willemin, B. Donnadieu,.etc. Crystal engineering in two-and three-dimensional systems based on cyanomolybdates:structures, magnetism and intercalation properties [J],J. Phys. Chem. Solids2004, 65:677.
[98]B. Sieklucka, R. Podgajny, P. Przychodzen, etc. Supramolecular networks based on octacyanometallates of Mo and W, [J],CR Chimie 2002,5:639.
[99]Larionova, M. Gross, M. Pilkingto, etc. High-Spin Molecules:A Novel Cyano-Bridged MnⅡ9MoⅤ6 Molecular Cluster with a S=51/2 Ground State and Ferromagnetic Intercluster Ordering at Low Temperatures, [J],Angew. Chem. Int. Ed.2000,39:1605.
[100]Venkatakrishnan, TS; Rajamani, R; Ramasesha, S, etc. Synthesis, crystal structure, and magnetic properties of hexanuclear [{MnL2}{Nb(CN)8}2] and nonanuclear [{MnL2}{Nb(CN)8}3] heterometallic clusters (L= bpy, phen), [J], Inorganic Chemistry, Volume,2007,46,9569-9574.
[101]Satoru Ikeda, Toshiya Hozumi, Kazuhito Hashimoto,etc. Cyano-bridged gadolinium(Ⅲ)-tungstate(V) bimetallic assembly with a one-dimensional chain structure, [J], Dalton Trans,2005,2120-2123.
[102]Jin Huang, Song Gao, Wenxia Tang, etc.Coexistence of Long-Range Ferromagnetic Ordering and Glassy Behavior in One-Dimensional Bimetallic Cyano-Bridged Polymers, [J],Inorganic Chemistry,2003, 42(19):6123-6129.
[103]Pawel Przychodzen, Robert Pelka, Krzysztof Lewin' ski, etc.Tuning of Magnetic Properties of Polynuclear Lanthanide(Ⅲ)-Octacyanotungstate(V) Systems:Determination of Ligand-Field Parameters and Exchange Interaction, [J], Inorganic Chemistry,2007,46,21.
[104]Almeida Paz,Alexander Trifonov, Christian Gu_erin, etc.Luminescent and Magnetic Cyano-Bridged Coordination Polymers Containing 4d-4f Ions:Toward Multifunctional Materials, [J], Inorganic Chemistry, 2009,48,13.
[105]Yuji Miyazakic, Michio Sorai, Tadeusz Wasiuty Nski, etc.Ferromagnetic ordering in new layered copper Octacyanometallates, [J] Journal of Magnetism and Magnetic Materials 2004:1058-1059.
[106]Yoshihide Tsunobuchi, Wataru Kosaka, Shin-ichi Ohkoshi,etc. Magnetization-induced second harmonic generation in a three-dimensional manganese octacyanoniobate-based pyroelectric ferrimagnet, [J],Cryst EngComm,2009,11:2051-2053.
[107]Dai-Zheng Liao, Zong-Hui Jiang, Peng Cheng,etc. Two dierent three-dimensional microporous framework structuresin [Mn2(H2O)4{W(CN)8}.4H2O]n and [Mn2(H2O)4{W(CN)8}(OH).2H2O]n, [J], New J. Chem.,2003,27:1760-1764.
[108]Rodrigue Lescouelzec, Jacqueline Vaissermann, Francesc Lloret, etc.Ferromagnetic Coupling between Low-and High-Spin Iron(III) Ions in the Tetranuclear Complex fac-[FeⅢHB(pZ)3(CN)2(μ-CN)]3 FeⅢ(H2O)3·6H2O([HB(pz)3]=Hydrotris (1-pyrazolyl)borate) [J], Inorg. Chem.,2002,41,5943-5945.
[109]Abbati G L, Caneschi A, Cornia A, etc.Towards stepwise cluster assembly:a decacopper(II) complex obtained by controlled expansion of a metallasiloxane cage. [J], Angew.Chem. Int. Ed.2002,41:4517-4520.
[110]Zhong-Hai Ni, Hui-Zhong Kou, Yi-Hua Zhao, etc. [Fe(bpb)(CN)2]-as a Versatile Building Block for the Design of Novel Low-Dimensional Heterobimetallic Systems:Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged FeⅢ-NiⅡ Complexes [(bpb)2-=2-Bis(pyridine-2-carboxamidobenzenate], [J],Inorganic Chemistry,2005,44,6.
[111]Hai-Yan Wei, Hao-Ling Sun, Song Gao,etc. Heterometallic MⅡRuⅢ2 Compounds Constructed from trans-[Ru(Salen)(CN)2]" and trans-[Ru(Acac)2(CN)2]-.Synthesis,Structures, Magnetic Properties, and Density Functional Theoretical Study, [J], Inorganic Chemistry,2005,44(19):6579.
[112]Xiao-Long Feng, Tong-Bu Lu, Song Gao,etc.Synthesis, Structures, and Magnetic Properties of a Series of Cyano-Bridged Fe-Mn Bimetallic Complexes, [J],Inorganic Chemistry,2006,45,13.
[113](a)Xi-Rui Zeng, Hong-Cai Zhou, Xiao-Zeng You,etc. Two-dimensional cyanide-bridged heterobi-metallic complexes based on CpCo(CN)3-:Syntheses, structures and magnetic properties,[J],Inorganica Chimica Acta,2006,359:3790-3794; (b) You Song, Xi-Rui Zeng, Xiao-Zeng Y, etc.Syntheses, Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [Fe(bpca)(CN)3]-, [J],Inorganic Chemistry,2006,45, (2):582-590.
[114]Quan-Xiu Li, Yi-Zhi Li, Xiao-Zeng You, etc. Syntheses, Structures, and Magnetic Properties of Heterobimetallic Clusters with Tricyanometalate and π-Conjugated Ligands Containing 1,3-Dithiol-2-ylidene, [J], Inorg. Chem.2010,49:1905-1912.
[115]陈向军,以[Cr(phen)(CN)4]配离子为组装单元的配合物的合成与表征[D],内蒙古大学硕士学位论文,2007年.
[116]Long Jiang, Xiao-Long Feng, Tong-Bu Lu, etc. Self-Assembly from Discrete Clusters to 2D Network Based on [Fe(phen)(CN)4]- and [Fe(bipy)(CN)4]-:Synthesis, Structures and Magnetic Properties,[J],European Journal of Inorganic Chemistry,2009,14:2074-2082.
[117]Yuan-Zhu Zhang, Song Gao,Hao-Ling Sun, etc. Linking cyano-bridged ladders by azide to form a layered metamagnet, [J],Chem.Commun,2004:1906-1907.
[118]Luminita T, Rodrigue L, Jacqueline V, etc. Nuclearity Controlled Cyanide-Bridged Bimetallic CrⅢ-MnⅡ Compounds:Synthesis, Crystal Structures, Magnetic Properties and Theoretical Calculations, [J],Chem. Eur. J, 2004,10,6130.
[119]Liviu T, Luminita M T., Rodrigue L, etc. Synthesis, crystal structures and magnetic properties of cyanideand phenolate-bridged [MⅢNiⅡ]2 tetranuclear complexes (M= Fe and Cr), [J],Dalton trans,2005: 1357.
[120]Luminita T, Rodrigue L, Jacqueline V, etc. [CrⅢ(L)(CN)4]-:a new building block in designing cyanide-bridged 4,2-ribbon-like chains{[CrⅢ(L)(CN)4]2Mn(H2O)2}nH2O [L=2-aminomethyl pyridine (n= 6) and 1,10-phenanthroline (n= 4)], [J], New J.Chem,2005,29:210.
[121]Shi W, Peter D, Luminita M T, etc. TTF charge transfer salts containing cyanometallate anions [M(phen)(CN)4]-(M= Cr or Fe; phen= 1,10-phenanthroline), [J],Inorg Chim Acta,2006,359:3283.
[122]Yuan-Zhu Zhang, Zhe-Ming Wang, Song Gao, etc. Heterometallic Cr-Mn Complexes Containing Cyanide and Oxalate Bridges, [J], Inorg Chem,2006,45:5447-5454.
[123]Yuan-Zhu Zhang., Song Gao, Zhe-Ming Wang., etc. Rational Synthesis and Magnetic Properties of a Family of Low-Dimensional Heterometallic Cr-Mn Complexes Based on the Versatile Building Block [Cr(2,2'-bipyridine)(CN)4]-, [J],Inorg Chem,2005,44:4534-4545.
[124]Yuan-Zhu Zhang, Zhe-Ming Wang, Song Gao. Three-Dimensional Heterometallic Chiral Cr-Mn Compound Constructed by Cyanide and Dicyanamide Bridges, [J],Inorg Chem,2006,45:10404-10406.
[125]Kou H Z, Gao S, Bai O, etc. Magnetic characteristics of new cyano-bridged two-dimensional honeycomb-like bimetallic assemblies containing NiⅡ-N equivalent to C-CrⅢ or NiⅡ-N equivalent to C-CrⅠ linkages, [J], Inorg Chem,2001,40:6287-6294.
[126]Hui-Zhong Kou, Jin-Kui Tang, Dai-Zheng Liao, etc. Crystal Structures and Magnetic Properties of New Cyano-Bridged Two-Dimensional Grid-Like Bimetallic Assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH·H2O and [Ni(tn)2]2[Co(CN)6]NO3·2H2O (tn=1,3-Propanediamine), [J], Inorg Chem,2001,40:4839-4844.
[127]Shaikh N, Panja A, Goswami S, etc. Synthesis, crystal structure and magnetic properties of cyanide bridged 2D coordination polymers [Mn(salen)]2[Fe(CN)5NO] and [Mn(salen)]2[Ni(CN)4], [J], Indian J Chem Techn,2004,43(7):1403-1408.
[128]Liu CQ,Shi JM, Xu W, etc. Synthesis, crystal structure and magnetic behavior of a one-dimensional chain complex:{[Cu(N-men)2Fe(CN)5(NO)]·H2O}n, [J],Pol J Chem,2003,77 (7):929-933.
[129]Zhong-Hai Ni, Ai-Li Cui, Hui-Zhong Kou, etc. Cyanide-Bridged Mn(Ⅲ)-Fe(Ⅲ) Bimetallic Complexes Based on the Pentacyano(1-methylimidazole)ferrate(Ⅲ) Building Block:Structure and Magnetic Characterizations, [J], Inorganic Chemistry,2007,46,1.
[130]Miyasaka, H.; Matsumoto, N.; Okawa, H. etc. The Two-Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3-MeOsalen)(H2O)]ClO4 and K3[Fe(CN)6], [J], Angew. Chem., Int. Ed. Engl.1995,34:1446.
[131]MiyasakaH.; Matsumoto, N.; Okawa, H. etc. Floriani, C. Complexes Derived from the Reaction of Manganese(Ⅲ) Schiff Base Complexes and Hexacyanoferrate(Ⅲ):Syntheses, Multidimensional Network Structures, and Magnetic Properties, [J], J. Am.Chem. Soc.1996,118:981.
[132]Miyasaka, H.; Ieda, H.; MatsumotoN.; etc. Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures Using a Desolvation Reaction:Synthesis, Structure, and Magnetic Properties of Manganese(Ⅲ)-Schiff-Base-Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures, [J], Inorg. Chem.1998,37:255.
[133]Miyasaka, H.; Matsumoto, N.; Re, N.; etc. Synthesis, Crystal Structure, and Magnetic Properties of a Ferrimagnetic Layered Compound [NEt4][Mn(5-Cl-salen)]2[Fe(CN)6](NEt4= Tetraethy-lammonium, 5-Cl-salen= N,N'-Ethylenebis((5-chlorosalicylidene)aminato)), [J],InorgChem.1997,36:670.
[134]Ferbinteanu, M.; Miyasaka, H.; WernsdorferW.; etc. Single-Chain Magnet (NEt4)[Mn2(5-MeOsalen)2 Fe(CN)6] Made of MnⅢ-FeⅢ-MnⅢ Trinuclear Single-Molecule Magnet with an ST= 9/2 Spin Ground State. [J],J. Am. Chem. Soc.2005,127:3090.
[135]Dai-Zheng Liao, Shi-Ping Yan, Guang-Ming Yang,etc. Bimetallic Materials Derived from manganese(Ⅲ) Schiff Base Complexes and Pentacyanidonitrosylferrate(Ⅱ) Precursor:Structures and Magnetic Properties, [J],Inorg. Chem.2010,49,2047-2056.
[136]张引莉,Schiff碱及其配合物应用研究及进展,[J],化工时刊,第22卷第5期,2008年.
[137]Ajay K S,Tomoaki T, Masahiro M.Tri-and tetranuclear copper(Ⅱ)complexes consisting of mononuclear Cu(Ⅱ)chiral building blocks with a sugar-derived Schiff's base ligand. [J], Inorg Chem,2006,45:2083-2092.
[138]Averseng F,Lacroix P G,Malfant I, etc. Enhanced second harmonic generation on passing from a mono-to a dicopper(Ⅱ)bis(salicylaldiminato)Schiff base complex. [J],Inorg Chem,2001,40:3797-3804.
[139](a)Mei Yuan.Azide-Bridged One-Dimensional MnⅢ Polymers:Effects of Side Groupof Schiff Base Ligands on Structure and Magnetism,[J],Inorganic Chemistry.2007,46,11235-11239;(b)Lollita Lecren. One-Dimensional Supramolecular Organization of Single-Molecule Magnets[J], J. Am. Chem. Soc.2007,129, 5045-5051;(c) Jian-Wei Lu. New 1-oxo-bridged tetranuclear Cu(Ⅱ) complex with Schiff-base ligand:Synthesis, crystal structure and magnetic properties [J], Inorg. Chem. Comm.2007,10,1210-1213.
[140](a)Chandra S, Sharma AK. Synthesis and spectroscopic characterization of homo binuclear Cr-Ⅲ, Mn-Ⅱ, Co-Ⅱ and Ni-Ⅱ complexes of 1,4-diformylpiperazine derivative[J]. Journal of the Indian Chemical Society, 2009,86(7):690-696; (b) Prakash D; Kumar C; Prakash S, etc. Synthesis, spectral characterization and antimicrobial studies of some new binuclear complexes of Cu-Ⅱ and Ni-Ⅱ Schiff base[J], Journal of the Indian Chemical Society,2009,86(12):1257-1261; (c) Costes JP; Auchel M; Dahan F, etc. Synthesis, structures, and magnetic properties of tetranuclear Cu-Ⅱ-Ln(Ⅲ) complexes[J], Inorgenic Chemistry,2006,45 (5):1924-1934; (d)Mukherjee P, Drew MGB, Tangoulis V, etc. Facile strategies for the synthesis and crystallization of linear trinuclear nickel(Ⅱ)-Schiff base, complexes with carboxylate bridges:Tuning of coordination geometry and magnetic properties[J]. Polyhedron,2009,28(14):2989-2996; (e)Costes, Jean-Pierre, Garcia-Tojal, etc. Structural and Magnetic Study of a Trinuclear Mn-Ⅱ-Gd-Ⅲ-Mn-Ⅱ Complex[J]. European Journal of Inorganic Chemistry,2009,25:3801-3806; (f) Zhang SH, Tang MF, Ge. CM, etc. Microwave Synthesis, Crystal Structure and Magnetic Behavior of a Schiff Base Trinuclear Nickel Cluster[J], Zeitschrift fur anorganische und allgemeine Chemie,2009,635(9-10):1442-1446; (g)Banerjee A, Singh R, Mondal P, etc. Tetranuclear Copper(Ⅱ) Complexes Bearing Cu4O6 and Cu4O4 Cores:Synthesis, Structure, Magnetic Properties, and DFT Study [J]. European Journal of Inorganic Chemistry,2010,5:790-798.
[141]Barra,A. L., Caneschi,A, Cornia,A, etc.Single-Molecule Magnet Behavior of a Tetranuclear Iron(Ⅲ) Complex. The Origin of Slow Magnetic Relaxation in Iron(Ⅲ)Clusters. [J], J. Am. Chem. Soc.1999,121: 5302-5310.
[142]Andreas Sieber. Synthesis and Spectroscopic Characterization of a New Family of-Ni4 Spin clusters, [J],Inorg. Chem,2005,44:4315-4325.
[143]Arindam Mukherjee. Magnetostructural Studies on Ferromagnetically Coupled Copper(ⅱ) Cubanes of Schiff-Base Ligands, [J],Chem. Eur. J.2005,11:3087-3096.
[144]Ayuk M. Ako, Annie K. Powell, Hiroki Oshio,etc. Molecular Magnets Containing Wheel Motifs, [J],Inorganic Chemistry,2009,48(8):33396-3407.
[145]Qiong Wu, Lollita Lecren, Rodolphe Clerac,etc. Synthesis, structure and magnetism of new polynuclear transition metal aggregates assembled with Schiff-base ligand and anionic N-donor ligands, [J], Journal of Molecular Structure 2008:339-345.
[146]Chaitali Biswas, Michael GB. Drew, Ashutosh Ghosh, etc. Magnetic coupling in trinuclear partial cubane copper(II) complexes with a hydroxo bridging core and peripheral phenoxo bridges from NNO donor Schiff base ligands, [J], Inorganica Chimica Acta,2010:846-854.
[147]Jung Oh Huh, Chang Seop Hong, David G. Churchill,etc. Synthesis, Structure, and Magnetic Properties of Closely Related Mono-and Di-Cu(Ⅱ) Schiff Base Complexes:Formation of Water Clusters and Hydrogen-Bonded Networks, [J],Cryst. Growth Des.,2010,10 (1):327-334.
[148]田秀梅,苯甲醛类Schiff碱及其配合物的合成、晶体结构与性能研究[D],新疆大学硕士研究生学位论文,新疆大学,2008.
[1]Rikken, G. L. J. A., Raupach, E. Observation of magneto-chiral dichroism, [J],Nature 1997,390:493-494.
[2]Liu, W. L.; Song, Y.; Li, Y. Z.; etc. Self-assembly of a 1D heterotrimetallic Cu(Ⅱ)-Sr(Ⅱ)-Na(Ⅰ) propeller-like chiral coordination polymer with ferromagnetic interactions, [J], J. Chem. Commun.2004: 2348-2349.
[3]Katsuya Inoue, Hiroyuki Imai, Prasanna S, etc. A Three-Dimensional Ferrimagnet with a High Magnetic Transition Temperature (Tc) of 53 K Based on a Chiral Molecule[J], Angewandte Chemie International Edition, 2001,40(22):4242-4245; (b) Coronado, E.; Go' mez-Garcia, C. J.; Nuez, A.; etc. Ferromagnetism and Chirality in Two-Dimensional Cyanide-Bridged Bimetallic Compounds [J], Inorg. Chem.2002,41(18):4615-4617; (c) Katsuya Inoue, Koichi Kikuchi, Hisashi Okawa, H. etc.Structure and Magnetic Properties of a Chiral Two-Dimensional Ferrimagnet with Tc of 38 K[J], Angewandte Chemie International Edition,2003,42(39), 4810-4813; (d) Imai, H.; Inoue, K.; Kikuchi, K.; etc. Three-Dimensional Chiral Molecule-Based Ferrimagnet with Triple-Helical-Strand Structure [J],Angew. Chem., Int. Ed,.2004,43(42):5618-5621.
[4]Zhao-Xi Wang, Jia Wei, You Song, etc.Two trinuclear copper(Ⅱ)-octacyanometalate(Ⅳ) bimetallic complexes coordinated with chiral ligands.[J], Journal of Molecular Structure,2008,875:198-204.
[5]You Song, Xi-Rui Zeng, Xiao-Zeng You, etc.Syntheses, Structures, and Magnetic Properties of Cyano-Bridged Heterobimetallic Complexes Based on [Fe(bpca)(CN)3], [J],Inorganic Chemistry,2006,45 (2): 52-590.
[6](a)Ahmet Karadag, Yusuf Yerli, Ibrahim Onal,etc. Preparations, IR spectra and crystal structures of cyano-bridged bimetallic complexes of zinc(Ⅱ) and cadmium(Ⅱ) with tetracyanopalladate(Ⅱ), [J], Journal of Coordination Chemistry, Vol.60, No.19,1 October 2007,2035-2044;(b) Ahmet Karadag, Yusuf Yerli Ertanshin,etc.Syntheses, IR spectra, thermal properties and crystal structures of novel cyano-bridged polymeric complexes of zincⅡ and cadmiumll with tetracyanoplatinate, [J], Polyhedron 27 (2008) 223-231;(c) Ahmet Karadag, Yusuf Yerli,Ibrahim Onal,etc. Preparation, structural, magnetic and thermal properties of two heterobimetallic cyano-bridged nickel(Ⅱ)-copper(Ⅱ)/platinum(Ⅱ) coordination polymers, [J], Inorganica Chimica Acta 362 (2009) 2299-2304.
[7](a)Eric A. Maatta,Changmin Kim,Structure of an L-Tyrosyl-L-histidine-Copper Complex Involving an Axial Copper(Ⅱ)-PhenolOH Bonding. Implication for Substrate Binding at the Active Site of Tyrosinase, [J],Inorg. Chem.1989,28,624-625; (b) I. M. Procter, B. J. Hathaway, and P. Nicholls,The Electronic Properties and Stereochemistry of the Copper(ii)Ion.Part I.Bis(ethylenediamine)copper(Ⅱ) Complexes ,[J],J. Chem. SOC. (A),1968,pp:1678; (c)Jun Tao, Yong Zhang, Ming-Liang Tong, etc.A mixed-valence copper coordination polymer generated byhydrothermal metal/ligand redox reactions[J],CHEM COMMUN. 2002,1342-1343.
[8](a) Holden Thorp Bond Valence Sum Analysis of Metal-Ligand Bond Lengths in Metalloenzymes and Model Complexes[J], Inorg. Chem.1992,31:1585-1588; (b) Ruth E, Saari Robert P Hausinger Robert A, X-ray absorption spectroscopic analysis of Fe(Ⅱ) and Cu(Ⅱ) forms of a herbicide-degrading a-ketoglutarate dioxygenase[J], JBIC,1999,4:122-129.
[9](a) Albert Figuerola, Carmen Diaz, Joan Ribas, Synthesis and Characterization of Heterodinuclear Ln3+-Fe3+ and Ln3+-Co3+ Complexes, Bridged by Cyanide Ligand(Ln3+) Lanthanide Ions:Nature of the Magnetic Interaction in the Ln3+-Fe3+ Complexe[J], Inorganic Chemistry,2003,42(2):641; (b)Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Acta,2004 (357):3271-3278; (c) Rodriguez-Dieguez, A; Colacio, E,Crystal structure and magnetic properties of [{Cu(cyclam)}3{Fe(CN)6}2]·6H2O, a cyano-bridged assembly with a rope-ladder chain structure[J], Polyhedron,2007,26:2859-2863.
[10]Chang Seop Hong, Young Sin You, Cyano-bridged Fe(Ⅱ)-Cu(Ⅱ) bimetallic assemblies:honeycomb-like and pentanuclear structures[J], Inorganica Chimica Acta 2004,357:3271-3278.
[11]Juraj Kucha, Francois Varret, and Werner Massa, Polymeric [{Cd(en)}3{Fe(CN)6}2]·4H2O:Preparation, Crystal Structure and Characterization (en=1,2-diaminoethane)[J], Z. Anorg. Allg. Chem.2006,632:495-500
[12]孟令芝,龚淑玲,何永炳,有机波谱分析[M],武汉大学出版社,2004.
[13]Sindhu Menon, M. V. Rajasekharan, J.-P. Tuchagues, Synthesis, Crystal Structure, Magnetic Properties, and EPR of Cu(bp3ca)Br2-H2O (bp3ca=2,2'-Bipyridine-3,3'-dicarboxylic Acid). Ferromagnetic Interactions via Unsymmetrical Bromide Bridges, [J],Inorg. Chem.1997,36,4341-4346.
[14]Maxwell A. Braverman, Robert L. LaDuca, Hydrothermal synthesis of divalent metal pyromellitate /dipyridylamine complexes:From an unprecedented supramolecular three-dimensional topology to an anionic coordination polymer framework with large incipient cation-bearing voids, [J],CrystEngComm,2008,10, 117-124.
[15]Maxwell A. Bravermana, Ronald M. Supkowskib, Robert L. LaDucaa, Luminescent zinc and cadmium complexes incorporating 1,3,5-benzenetricarboxylate and a protonated kinked organodiimine:From a hydrogen-bonded layer motif to thermally robust two-dimensional coordination polymers, [J],J. Solid State Chem.,2007,180,1852-186.
[16]Xinjun Luan, Yichun Chu, Yaoyu Wang, etc.Formation of Two-Dimensional Supramolecular Water Layer Containing (H2O)18 Morphology via Dianion Templating, [J],Cryst. Growth Des.,2006,6,812-814.
[17]Qian Chu, Guang-Xiang Liu, Wei-Yin Sun, etc., Syntheses, structures, and optical properties of novel zinc(Ⅱ) complexes with multicarboxylate and N-donor ligands, [J], Dalton Trans.,2007,4302-4311.
[18]Zhong-Ming Sun, Jiang-Gao Mao, Yan-Qiong Sun, etc., Hydrothermal synthesis, characterization and crystal structures of two new layered lead(Ⅱ) diphosphonates, [J], New J. Chem.,2003,27,1326-1330.
[19]Subhashree Mallika Krishnan, Niral M. Patel, Robert L. LaDuca, Oxoanion and cation effects on the structural morphology of coordination polymers incorporating a kinked organodiimine tethering ligand, [J],CrystEngComm,2007,9,503-514.
[20]R.Custelcean,Vincent Sellin and B.A.Moyer, Sulfate separation by selective crystallization of a urea-functionalized metal-organic framework,[J], Chem.Commun.,2007,1541.
[21]Hui-Zhong Kou, Jin-Kui Tang, Dai-Zheng Liao, etc. Crystal Structures and Magnetic Properties of New Cyano-Bridged Two-Dimensional Grid-Like Bimetallic Assemblies [Ni(tn)2]2[Cr(CN)5((NO)]OH-H2O and [Ni(tn)2]2[Co(CN)6]NO3-2H2O (tn=1,3-Propanediamine), [J], Inorg Chem,2001,40:4839-4844.
[22]Taka-aki Okamura,Norikazu Ueyamac and Wen-Xia Tang,etc.A novel Cu(Ⅱ)-W(Ⅴ) bimetallic assembly magnet{[Cu(en)2]3[W(CN)8]2·H2O}(en=ethylenediamine) with cube-like W8Cu12 units from a coordinated anion template self-assembly reactiony, [J], New J. Chem.,2002,26,485-489.
[23]刘孟军,含氮、氧配体构筑的超分子金属配合物的合成与结构[D],内蒙古大学,2009；(b)Xiang-Jian Kong, Yan-Ping Ren, Zheng, Gary Nichol, etc. Dual Shell-like Magnetic Clusters Containing Ni(Ⅱ) and Ln(Ⅲ)(Ln= La, Pr, and Nd) Ions[J], Inorg. Chem.,2008,47 (7),2728-2739.
[24]日本化学会编,曹惠民译,无机化合物合成手册(第三卷)[M],北京：化学工业出版,1998,477,379.
[25]Ma B. c, Gao S, Sn G. etc. Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic Behavio, [J],Angew. Chem. Int. Ed,2001,40:434.
[26]Albert Figuerol, Carmen Diaz, Joan Ribas, etc. Structure and magnetism of the first cyano-bridged hetero-one-dimensional Gdm-Crm complexes, [J],Chem. Commun.,2001,1204-1205.
[27](a) G. W. Beall, D. F. Mullica, etc.The crystal structure of LaKFe(CN)6.4H2O,[J], Acta Cryst. (1978). B34, 1446-1449; (b) T. Siegristl, C. Besnard and C. Svensson, Crystal structure of CsLnFe(CN)6·5H2O (Ln=Ce, Pr, Nd), CsCeFe(CN)6·4H2O, and T1TmRu(CN)6·3H2O,[J],Solid State Sciences,2(6),2000,607-614; (c) D. F. Mullica, W. O. Milligan and R. L. Garner,Refined crystal structure of lanthanum hexacyanoferrate(III) tetrahydrate, [J]Acta Cryst. (1980). B36,2561-2564; (d) F. H. Herbstein and R. E. Marsh, Changes in space and Laue groups of some published crystal structures,[J], Acta Cryst. (1982). B38,1051-1055.
[1]Jan Vanoc, Jarom'r Marek, Zdenek Travncek, etc.Synthesis, structural characterization, antiradical and antidiabetic activities of copper(Ⅱ) and zinc(Ⅱ) Schiff base complexes derived from salicylaldehyde and b-alanine[J], Journal of Inorganic Biochemistry,2008,102:595-605.
[2]Mandal S, Rosair G Ribas J, etc. Synthesis, crystal structure and magnetic characterization of a new phenoxo-bridged binuclear manganese(Ⅲ) Schiff base complex exhibiting single-molecule-magnet behavior[J], Inorganica Chimica Acta,2009,362 (7):2200-2204.
[3](a)Mishtu Dey.Chebrolu Pulla Rao,Pauli Saarenketo, etc.Four-, Five-and Six-Coordinated ZnⅡComplexes of OH-Containing Ligands Syntheses, Structure and Reactivity,Eur.[J], J. Inorg. Chem.2002,2207-2215;(b) Mishtu Dey, Chebrolu P. Rao, Pauli K. Saarenketo,etc. Mono-, di-and tri-nuclear Ni(Ⅱ) complexes of N-, O-donor ligands:structural diversity and reactivity[J].Inorganic Chemistry Communications 5 (2002) 924-928; (c) Mishtu Dey, Chebrolu P. Rao, Pauli K. Saarenketo,etc. Synthesis, structural diversity, inter-conversion and reactivity of Cu(Ⅱ) complexes of hydroxy-rich molecules[J], Inorganic Chemistry Communications 5 (2002) 380-383.
[4]Dey,M.; Rao, C. P.; Saarenketo, P. K.; etc. Mn(Ⅳ) and Co(Ⅲ)-complexes of-OH-rich ligands possessing O2N,O3N and O4N cores:syntheses,characterization and crystal structures.[J], Polyhedron 22 (2003) 3515-3521.
[5]Guo-Min Wang, Li-Li Hu, Jun Tao.etc. Synthesis and magnetic properties of a new hexanuclear iron(III) compound[J], Inorganic Chemistry Communications 12 (2009) 622-624.
[6](a)袁瑞娟,阮文娟,朱必学等.手性双核Salen配合物的合成与谱学性质[J],无机化学报,2004,20(4)444-450；(b)中本一雄著,无机和配位化合物的红外和拉曼光谱(第四版),[M],化学工业出版社1991,228-234,304-306.
[7]孟令芝,龚淑玲,何永炳.有机波谱分析,[M]武汉大学出版社,2004.
[8]Shyamapada Shit,etc. A rare ferromagnetically coupled asymmetric doubly azido bridged copper(II) dimer with an N, N, O donor Schiff base [J],Polyhedron 2007,46,1357-1363.
[9]Xian-Ming Zhang, Rui-Qin Fang, and Hai-Shun Wu, A Twelve-Connected Cu6S4 Cluster-Based Coordination Polymer, [J], J Am Chem. Soc.2005,127,7670-7671.
[10]Gong-Ping Duan,Osamu Satob,Song Gao,etc. Structures and magnetism of cyano-bridged grid-like two-dimensional 4f-3d arrays, [J], J. Mater. Chem.,2006,16,2625-2634.
[11](a) Alexander J. Blake, Neil R. Champness, Peter Hubberstey, etc.Inorganic crystal engineering using self-assembly of tailored building-blocks[J], Coord. Chem. Rev.1999,183:117; (b) Susan A. Bourne,and Lesego J. Moitsheki, Copper(Ⅱ) and lead(Ⅱ) complexes of 4,4-bipyridine-N,N- dioxide,[J], Journal of Chemical Crystallography, Vol.37, No.5,2007 359-367; (c) Susan A. Bourne and Lesego J. Moitsheki, Anion dependent structural diversity in cobalt(Ⅱ) complexes of 4,4'-bipyridine-N,N'-dioxide, [J],CrystEngComm, 2005,7,674-681; (d) Shu-Lan Ma, Wen-Xiang Zhu, Gui-HaiHuang,etc. Novel three-dimensional network of lanthanum(Ⅲ) complex{[La2(BTA)6(4,4'-bpdo)1.5]·1.5H2O}n (BTA= benzoyltrifluoroacetone; 4,4'-bpdo= 4,4'-bipyridine dioxide) [J], Journal of Molecular Structure 646 (2003) 869-94; (e) Shu-Lan Ma, Chuan-Min Qi, Qian-Ling Guo,etc. The novel one-dimensional chain of europium(Ⅲ) complex[Eu2(BTA)6(4,4'-bpdo)]n containing dimers bridged by terminal oxygen atoms of 4,4'-bpdo molecules[J], Journal of Molecular Structure 738 (2005) 99-104; (f) De borah Gonza' lez Mantero, Antonia Neels,etc. Novel 3D,2D, and OD First-Row Coordination Compounds with 4,4'-Bipyridine-N,N'-dioxide Incorporating Sulfur-Containing Anions,[J],Inorganic Chemistry,45,3287.
[12]Peter Hubberstey,Claire Wilson, Martin Schro,etc. Multi-Dimensional Transition-Metal Coordination Polymers of 4,4'-Bipyridine-N,N'-dioxide:1D Chains and 2D Sheets, [J],Inorganic Chemistry,47,,8652-8664.
[13]De-Liang Long, Alexander J. Blake, Neil R. Champness,etc. Can 4,4'-bipyridine N,N'-dioxide play the same important role as 4,4'-bipyridine in the construction of metal coordination networks and crystal engineering [J], Chem. Commun.,2000,2273-2274.