含氮、氧、硫配体构筑的配位聚合物的合成与结构
|
摘要
本文以设计合成配位聚合物为目标,选用羧酸(1,3,4-噻二唑-2,5-二硫代乙酸(H2btc)、2,2’-联毗啶-3,3’-二甲酸-1,1’-氮氧化物(H2bpdado)和5-硝基间苯二甲酸(O2N-bdc))为构筑单元,通过辅助配体(1,1’-(1,4-丁烷)二(咪唑)(bbi))的调节,与稀土、过渡金属离子反应。采用溶剂热法和水热法合成了4个具有二维、三维结构的配合物,测定其单晶结构并对其进行红外光谱分析、X-射线单晶衍射和差热-热重分析表征。配合物的分子式如下：
{Zn(bpdado)(bbi)·H2O}n 1
{Ni2(O2N-bdc)2(bbi)3(H2O)2·2H2O}n 2
{[Ni2(O2N-bdc)2(bbi)2H2O]·4H2O}n 3
[Nd2(btc)3(H2O)5]n 4
配合物1是由2,2’-联吡啶-3,3’-二甲酸-1,1’-氮氧化物和1,1’-(1,4-丁烷)二(咪唑)配体合成的具有8.995×13.502 A2孔洞的二维层状配位聚合物。配合物2和3均为5-硝基间苯二甲酸和1,1’-(1,4-丁烷)二(咪唑)配体合成的三维配位聚合物。配合物4是由柔性配体1,3,4-噻二唑-2,5-二硫代乙酸合成的具有三维结构的配位聚合物。配合物4中存在S…S弱作用归因于1,3,4-噻二唑-2,5-二硫代乙酸配体的柔性。
拓扑分析表明,配合物1具有4-连接的(4,4)拓扑结构,配合物2和3具有5-连接的(44,66)拓扑结构,配合物4具有6,8-连接的(37·47·5)(38·48·55·67)拓扑结构。
Four novel metal-organic coordination polymers have been synthesized by empolying 1,3,4-thiadiazole-2,5-diyldithio)diacetic acid (H2btc),2,2'-bipyridine-3,3'-dicarboxylate-1,1'-dioxide (H2bpdado) and 5-Nitro-1,3-benzene dicarboxylic acid (O2N-bdc) and associated ligand 1,1'-(1,4-butanediyl)bis (imidazole) (bbi) as building block, combining with rare metal and transition metal ions through hydrothermal and solvothermal synthesis method. The crystal structures are determined by X-ray single diffraction and characterized by IR, TGA. The formulas of the complexs are as follows:
{Zn(bpdado)(bbi)·H2O}n 1
{Ni2(O2N-bdc)2(bbi)3(H2O)2·2H2O}n 2
{[Ni2(O2N-bdc)2(bbi)2H2O]·4H2O}n 3
[Nd2(btc)3(H2O)5]n 4
Complex 1 is built up by two ligands 2,2'-bipyridine-3,3'-dicarboxy late-1,1'-dioxide and 1,1'-(1,4-butanediyl)bis(imidazole).The structure of complex 1 has 2D layers with 8.995×13.502A2 micropores. Complex 2 and 3 show 3D open framework by two ligands 5-Nitro-1,3-benzene dicarboxylic acid and 1,1'-(1,4-butanediyl) bis (imidazole). Complex 4 consist of flexible ligand (1,3,4-thia diazole-2,5-di yldithio)diacetic acid with 3D open framework. Complex 4 exists S S weak interaction due to (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid being flexible ligand.
Topological analysis shows that complex 1 with 4-connected (4,4) topology, complex 2 and 3 with 5-connected (44,66) topology, complex 4 with 6,8-connected (37·47·5)(38·48·55·67) topology.
{Zn(bpdado)(bbi)·H2O}n 1
{Ni2(O2N-bdc)2(bbi)3(H2O)2·2H2O}n 2
{[Ni2(O2N-bdc)2(bbi)2H2O]·4H2O}n 3
[Nd2(btc)3(H2O)5]n 4
配合物1是由2,2’-联吡啶-3,3’-二甲酸-1,1’-氮氧化物和1,1’-(1,4-丁烷)二(咪唑)配体合成的具有8.995×13.502 A2孔洞的二维层状配位聚合物。配合物2和3均为5-硝基间苯二甲酸和1,1’-(1,4-丁烷)二(咪唑)配体合成的三维配位聚合物。配合物4是由柔性配体1,3,4-噻二唑-2,5-二硫代乙酸合成的具有三维结构的配位聚合物。配合物4中存在S…S弱作用归因于1,3,4-噻二唑-2,5-二硫代乙酸配体的柔性。
拓扑分析表明,配合物1具有4-连接的(4,4)拓扑结构,配合物2和3具有5-连接的(44,66)拓扑结构,配合物4具有6,8-连接的(37·47·5)(38·48·55·67)拓扑结构。
Four novel metal-organic coordination polymers have been synthesized by empolying 1,3,4-thiadiazole-2,5-diyldithio)diacetic acid (H2btc),2,2'-bipyridine-3,3'-dicarboxylate-1,1'-dioxide (H2bpdado) and 5-Nitro-1,3-benzene dicarboxylic acid (O2N-bdc) and associated ligand 1,1'-(1,4-butanediyl)bis (imidazole) (bbi) as building block, combining with rare metal and transition metal ions through hydrothermal and solvothermal synthesis method. The crystal structures are determined by X-ray single diffraction and characterized by IR, TGA. The formulas of the complexs are as follows:
{Zn(bpdado)(bbi)·H2O}n 1
{Ni2(O2N-bdc)2(bbi)3(H2O)2·2H2O}n 2
{[Ni2(O2N-bdc)2(bbi)2H2O]·4H2O}n 3
[Nd2(btc)3(H2O)5]n 4
Complex 1 is built up by two ligands 2,2'-bipyridine-3,3'-dicarboxy late-1,1'-dioxide and 1,1'-(1,4-butanediyl)bis(imidazole).The structure of complex 1 has 2D layers with 8.995×13.502A2 micropores. Complex 2 and 3 show 3D open framework by two ligands 5-Nitro-1,3-benzene dicarboxylic acid and 1,1'-(1,4-butanediyl) bis (imidazole). Complex 4 consist of flexible ligand (1,3,4-thia diazole-2,5-di yldithio)diacetic acid with 3D open framework. Complex 4 exists S S weak interaction due to (1,3,4-thiadiazole-2,5-diyldithio)diacetic acid being flexible ligand.
Topological analysis shows that complex 1 with 4-connected (4,4) topology, complex 2 and 3 with 5-connected (44,66) topology, complex 4 with 6,8-connected (37·47·5)(38·48·55·67) topology.
引文
[1]宋银柱,王耕霖,等译.配位化学[M].北京大学出版社,1982.
[2]Abrahams B F,Haywood M QRobson R etc.New Tricks for an Old Dog:The Carbonate Ion as a Building Block for Networks Including Examples of Composition[Cu6(CO3)12{C(NH2)3}8]4-with the Sodalite Topology[J].Angew.Chem.Int.Ed.2003,42:1112-1115.
[3]Eddaoudi M, Moler D B, Li H L etc.Modular Chemistry:Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks [J]. Acc. Chem. Res.2001, 34(4):319-330.
[4]Stein A,Keller S W,Mallouk T E.Turning Down the Heat:Design and Mechanism in Solid-State Synthesis[J].Science.1993,259:1558-1564.
[5]Olenyuk B,Fechtenkotter A,Stang P J.Molecular architecture of cyclic nanostructures:use of co-ordination chemistry in the building of supermolecules with predefined geometric shapes[J]. J. Chem. Soc.Dalton Trans. 1998:1707-1728.
[6]Stumpf H O,Ouahab L,Pei Y, etc. A Molecular-Based Magnet with a Fully Interlocked Three-Di mensional Structure [J]. Science.1993,261:447-449.
[7]Ohba M,Maruono N,Okawa H etc. A New Bimetallic Ferromagnet, [Ni(en)2]3[Fe(CN)6]2·2H2O, with a Rare Rope-Ladder Chain Structure [J]. J. Am. Chem. Soc.1994,116:11566-11567.
[8]Ohba M, Fukita N, Okawa H.Magnetic characteristics of bimetallic assemblies, [Ni(en)2]3[M(CN)6]2·2H2O (en=H2NCH2CH2NH2;M=Fe, Mn, Cr or Co), with a one-dimensional rope-ladder chain structure [J]. J. Chem. Soc. Dalton Trans.1997:1733-1738.
[9]Ohba M,Okawa H,Ito T, etc. A two-dimensional bimetallic assembly, [Ni(pn)2]2[Fe(CN)6]ClO4·2H2O, with a square structure[J]. J. Chem. Soc. Chem. Commun.1995:1545-1546.
[10]Graddon D P. An Introduction to Coordination Chemistry [M]. Pergamon Press.1997:4127.
[11]Bruser H J, Schwarzenbach D, etc. The crystal structure of Prussian Blue:Fe4[Fe(CN)6]3xH2O[J]. Inorg. Chem.1977,16:2704-2710.
[12]Iwamoto T. Comprehensive Supramolecular Chemistry [M]. Oxford,1996,6:643.
[13]胡亚微.由柔性双功能配体构筑的配位聚合物[D].长春：吉林大学化学学院,2008.
[14]Hoskins B F,Robson R.Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments[J].J.Am.Chem.Soc.1989,111:5962-5964.
[15]Munakata M, Wu L P, Kuroda-Sowa T. Advances in Inorganic Chemistry:Including Bioinorganic Chemistry, Sykes A G, Ed [M]. Academic Press:San Diego. CA.1999,46:175.
[16]Yaghi O M, Davis C E, Li G M etc. Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(Ⅱ)-Benzenetricarboxylate Network [J]. J. Am. Chem. Soc.1997,119:2861-2867.
[17]Kerpet C J, Prior T J, Rosseinsky M J.A Versatile Family of Interconvertible Microporous Chiral Molecular Frameworks:The First Example of Ligand Control of Network Chirality [J]. J. Am. Chem. Soc.2000,122:5158-5168.
[18]Carlucci L,Ciani G,Proserpio D M A etc.1-,2-, and 3-Dimensional Polymeric Frames in the Coordination Chemistry of AgBF4 with Pyrazine. The First Example of Three Interpenetrating 3-Dimensional Triconnected Nets [J]. J. Am. Chem. Soc.1995,117:4562-4569.
[19]Yaghi O M, Li H L.T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4'-bpy)·NO3 [J]. J. Am. Chem. Soc.1996,118:295-296.
[20]Gardner G B D, Verkataraman J S, Moore S etc. Spontaneous assembly of a hinged coordination network [J]. Nature.1995,374:792-795.
[21]Yaghi O M, Li H L, Groy L T.Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid [J]. J. Am. Chem. Soc.1996,118:9096-9101.
[22]Hoskins B F,Robson R,Slizys D A.The Structure of [Zn(bix)2(NO3)2]·4.5H2O (bix=1,4-Bis (imidazol-1-ylmethyl)benzene):A New Type of Two-Dimensional Polyrotaxane [J]. Angew. Chem. Int. Ed. 1997,36:2336-2338.
[23]Chen B L,Eddaoudi M,Hyde S T etc. Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores [J]. Science.2001,291:1021-1023.
[24]Eddaoudi M,Kim J.O'Keeffe M etc. Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:A Framework Deliberately Designed To Have the NbO Structure Type [J]. J. Am. Chem. Soc.2002,124:376-377.
[25]Vossmeyer T,Reck G, Katsikas L etc.A Double-Diamond Superlattice Built Up of Cd17S4(SCH2CH2OH)26 Clusters [J]. Science.1995,267:1476-1479.
[26]Evans O R, Xiong R G, Wang Z Y etc.Crystal Engineering of Acentric Diamondoid Metal-Organic Coordination Networks[J]. Angew.Chem. Int. Ed.1999,38:536.
[27]Abrahams B F,Hoskins B F,Michaili D M etc.Assembly of porphyrin building blocks into network structures with large channels [J]. Nature.1994,369:727-729.
[28]CHen B L, Eddaoudi M, Reineke T M etc.Cu2(ATC)·6H2O:Design of Open Metal Sites in Porous Metal-Organic Crystals (ATC:1,3,5,7-Adamantane Tetracarboxylate) [J]. J. Am. Chem. Soc.2000,122: 11559-11560.
[29]Kim J, Chen B L, Reineke T M etc.Assembly of Metal-Organic Frameworks from Large Organic and Inorganic Secondary Building Units:New Examples and Simplifying Principles for Complex Structures [J]. J. Am. Chem. Soc.2001,123:8239-8247.
[30]Soma T,Iwamoto T.Supramolecular Structures in Solid State AgCN-Cd(CN)2-(4-Picoline) Complexes.An Interwoven Double Network of [Cd{Ag(CN)2}2]-in [traps-Cd(4-Mepy)2{Ag(CN)2}2]} (4-Mepy) and a Linear Chain of [-Cd-NC-Ag(CN)Ag-CN-]" in [Cd(4-Mepy)4{Ag2(CN)3}][Ag(CN)2][J]. Chem. Lett.1994: 821-824.
[31]Li H L, Thomas C E D, Groy L etc.Establishing Microporosity in Open Metal-Organic Frameworks:Gas Sorption Isotherms for Zn(BDC) (BDC=1,4-Benzenedicarboxylate) [J]. J. Am. Chem. Soc.1998,120: 8571-8572.
[32]Li H L, Eddaoudi M, O'Keeffe M etc. Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J]. Nature.1999,402:276-279.
[33]Hoskins B F, Robson R, Silzys D A. A Hexaimidazole Ligand Binding Six Octahedral Metal Ions to Give an Infinite 3D a-Po-Like Network Through Which Two Independent 2D Hydrogen-Bonded Networks Interweave [J]. Angew. Chem. Int. Ed.1997,36:2752-2755.
[34]Reinked T M, Eddaoudi M, Moler B etc. Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO][J]. J. Am. Chem. Soc.2000,122:4843-4844.
[35]Sun J Y, L Wei,G H Y, Zhou M etc.QMOF-1 and QMOF-2:Three-Dimensional Metal-Organic Open Frameworks with a Quartz like Topology [J]. Angew. Chem. Int. Ed.2002,41:4471-4473.
[36]Hoskins B F,Robson R N,Scarlett V Y.Six Interpenetrating Quartz-Like Nets in the Structure of ZnAu2(CN)4 [J]. Angew. Chem. Int. Ed.1995,34:1203-1204.
[37]Chui S S Y, Lo S M F, Charmant J P H etc. A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n [J]. Science.1999,283:1148-1150.
[38]Abrahams B F,Haywood M G,Robson R etc.New Tricks for an Old Dog:The Carbonate Ion as a Building Block for Networks Including Examples of Composition [Cu6(CO3)12{C(NH2)3}g]4- with the Sodalite Topology [J]. Angew. Chem. Int. Ed.2003,42:1112-1115.
[39]Fujita M.,Kwon Y J.,Washizu S. etc.Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(Ⅱ) and 4,4'-Bipyridine[J]. J. Am. Chem. Soc. 1994,116:1151-1152.
[40]Gardner G.B,Venkaraman N.D,Moore J S etc.Spontaneous assembly of a hinged coordination network [J]. Nature.1995,374:792-794.
[41]S.S.-Y.Chui,S.M.-F.Lo,J.P.H.Charmant etc.A Chemically Functionalizable Nanoporous Material [Cu3 (TMA)2(H2O)3]n[J].Science.1999,283:1148-1150.
[42]Yaghi O.M, Li G.M, Li H.L.Selective binding and removal of guests in a microporous metal-organic framework [J]. Nature.1995,378:703-706
[43]Li H, Eddaoudi M, O'Keeffe M etc. Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].Nature.1999,402:276-279.
[44]M. Eddaoudi,M. O'Keeffe,O. M Yaghi etc.Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage [J].Science.2002,295:469.
[45]H.K.Chae,M.O'Keeffe,O.M.Yaghi etc.A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature.2004,427:523-527.
[46]A.C.Sudik, M.O'Keeffe,O.M.Yaghi etc. A Metal-Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks[J].Angew.Chem.Int.Ed.2006,45:2528.
[47]G.Ferey,S.Surble,I.Margiolaki etc.A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area[J]. Science.2005,309:2040.
[48]Batten S R, Robson R.Interpenetrating Nets:Ordered, Periodic Entanglement [J]. Angew. Chem. Int. Ed. 1998,37:1460-1494.
[49]Robin A Y,K M Fromm. Coordination polymer networks with O-and N-donors:What they are, why and how they are made [J].Coord. Chem. Rev.2006,250:2127-2157.
[50](a)邓前军.若干含氮竣酸配体功能配位聚合物的水热合成、晶体结构及性质研究[D].长沙：中南大学博士论文,2007；(b)叶俊伟.5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究[D].吉林：吉林大学,2007.
[51]H.Cui,Z.M.Wang,K.Takahashi etc.Ferroelectric Porous Molecular Crystal, [Mn3(HCOO)6](C2H5OH), Exhibiting Ferrimagnetic Transition[J]. J.Am.Chem.Soc.2006,128:15074.
[52]P.M.Forster,A.K.Cheetha.Open-Framework Nickel Succinate, [Ni7(C4H4O4)6(OH)2(H2O)2]·2 H2O:A New Hybrid Material with Three-Dimensional Ni-O-Ni Connectivity[J].Angew.Chem.Int.Ed.2002,41:457.
[53]V.Kiritsis,A.Michaelides,S.Skoulika etc.Assembly of a Porous Three-Dimensional Coordination Polymer:Crystal Structure of{[La2(adipate)3(H2O)4]6H2O}n[J].Inorg.Chem.1998,37:3407.
[54]N.Guillou,C.Livage,W.Beek etc."A Layered Nickel Succinate with Unprecedented Hexanickel Units:Structure Elucidation from Powder-Diffraction Data, and Magnetic and Sorption Properties" [J].Angew.Chem.Int.Ed.2003,42:643-647.
[55]N.Guillou,C.Livage,M.Drillon etc."The Chirality,Porosity,and Ferromagnetism of a 3D Nickel Glutarate with Intersecting 20-Membered Ring Channels"[J]. Angew.Chem.Int.Ed.2003,42:5314-5317.
[56]F.Abrahams,M.Moylan,S.D.Orchard etc.,"Excess electron transport through DNA:A single electron repairs more than one UV-induced lesion"[J]. Angew.Chem.Int.Ed.,2003,42:1848-1851.
[57]Xing-Jing Zhang,Yong-Heng Xing, Jing Han etc.A Series of Novel Ln-Succinate-Oxalate Coordination Polymers:Synthesis, Structure, Thermal Stability, and Fluorescent Properties[J].Crystal Growth & Design.Vol.8, No.10,2008:3680-3688.
[58]N.Hao,E.Shen,Y.Li etc."A novel metal-organic supramolecular framework constructed by benzene-1,2,4-tricarboxylate:{[Fe(phen)(btc)(H2O)]2·CH3CH2OH}n(btc=benzene-1,2,4-tricarboxylate)".[J].In org.Chem.Commun.2004,7:131-135.
[59]X.Y.Wang, S.C.Sevov."Synthesis,Structures,and Magnetic Properties of Metal-Coordination Polymers with Benzenepentacarboxylate Linkers"[J].Inorg.Chem.2008,47:1037-1043.
[60]Y.Yan,C.Wu,C.Lu."Hydrothermal Synthesis of Two New Transition Metal Coordination Polymers with Mixed Ligands"[J].Z.Anorg.Allg.Chem.2003,629:1991-1995.
[61]P.Zheng,L.Long,R.Huang,L.Zheng."Crystallographic report:A three-dimensional coordination polymer: [Zn6(btc)4(4,4-bipy)5]n (btc= 1,2,4-benzenetricarboxylate; 4,4-bipy=4,4-bipy ridine)"[J].Appl.Organometal. Chem.2003,17:739-740.
[62]C.Qin,X.Wang,E.Wang,C.Hu,L.Xu."Synthesis and characterization of a novel three-dimensional photoluminescent coordination polymer generated from unsymmetrically bridging ligand"[J].Inorg Chim Acta.2004,357:3683-3688.
[63]C.Qin,X.Wang,E.Wang,C.Hu,L.Xu."[Cu2(HBTC)2(H2O)2(μ2-H2O)]·2H2O:a new arm-shaped two-di mensional copper coordination polymer having both rhombic cavities and helical-like channels"[J]. Inorg.Chem.Comm.2004,7:788-197.
[64]L.Wang,Z.Shi,G.Li,Y.Fan,W.Fu,S.Feng."Solvothermal synthesis and structural characterization of a three-dimensional metal-organic polymer [NaZn(1,2,4-BTC)] (1,2,4-BTC=1,2,4-benzenetricarboxy late)"[J]. Solid State Sci.2004,6:85-90.
[65]Bai HY, Ma JF, Yang J etc. Effect of Anions on the Self-Assembly of Cd(II)-Containing Coordination Polymers Based on a Novel Flexible Tetrakis(imidazole) Ligand. CRYSTAL GROWTH & DESIGN.Vol.10, No.2,2010:995-1015.
[66]X.Zhang,S.S.Y.Chui,I.D.Williams."Cooperative magnetic behavior in the coordination polymers [Cu3(TMA)2L3](L=H2O,pyridine)"[J].J.Appl.Phys.2000,87:007-6009.
[67]Eddaoudi,M.O'Keeffe,O.M.Yaghi etc."Porous Metal-Organic Polyhedra:25A Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks" [J].J.Am.Chem.Soc.2001,123:4368-4369.
[68]Eddaoudi,H.Li,O.M.Yaghi."Highly Porous and Stable Metal-Organic Frameworks:Structure Design and Sorption Properties" [J].J.Am. Chem.Soc.2000,122:1391-1397.
[69]Li,M.Eddaoudi,T.L.Groy,O.M.Yaghi."Establishing Microporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC=1,4-Benzenedicarboxylate)"[J].J.Am.Chem.Soc.1998, 120:8571-8572.
[70]Mahata,S.Natarajan,"A New Series of Three-Dimensional Metal-Organic Framework, [M2(H2O)] [C5N1H3(COO)2]3-2H2O,M=La, Pr, and Nd:Synthesis,Structure,and Properties"[J].Inorg.Chem.2007,46: 1250-1258.
[71]Y.G.Huang,B.L.Wu,D.GYuan,Y.Q.Xu etc. "New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln-O-Ln Framework and(3,4)-Connected Net"[J].Inorg.Chem.2007,46:1171-1176.
[72]Y.Q.Sun,J.Zhang,GY.Yang."A series of luminescent lanthanide-cadmium-organic frameworks with helical channels and tubes"[J].Chem.Commun.2006:4700-4702.
[73]Fang Q.-R.,Zhu G-S.,Xue M. etc.Microporous Metal-Organic Framework Constructed from Hepta nuclear Zinc Carboxylate Secondary Building Units[J].Chem.Eur.J.2006,12:3754.
[74]Kyoungmoo Koh,Antek G. Wong-Foy,Adam J. Matzger.A Crystalline Mesoporous Coordination Copolymer with High Microporosity [J].Angew. Chem. Int. Ed.2008,47:677.
[75]Ming Xue, Enhua Kang, and Shilun Qiu etc.Structure, Hydrogen Storage, and Luminescence Properties of Three 3D Metal-Organic Frameworks with NbO and PtS Topologies[J].Crystal Growth & Design. Vol.8, No.7,2008:2478-2483.
[76](a)周瑞莎.含羧基配体的稀土配位聚合物的合成、结构及性能研究[D].吉林：吉林大学博士论文,2008；(b)赵斌.d-f混合金属配位聚合物的合成和性质研究[D].天津：南开大学博士论文,2004.
[77]Zhao B.,Cheng P.,Dai,Y. etc.A Nanotubular 3D Coordination Polymer Based on a 3d-4f Heterometallic Assembly[J].Angew.Chem.Int.Ed.2003,42:934.
[78]Zhao B.,Cheng P.,Chen,X. etc.Design and Synthesis of 3d-4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated "Water"Pipe[J].J.Am.Chem.Soc.2004,126:3012.
[79]Zhao B.,Chen X.Y.,Cheng,P. etc. Coordination Polymers Containing 1D Channels as Selective Luminescent Probes[J].J.Am.Chem.Soc.2004,126,15394.
[80]Kate L. Ziegelgruber, Karah E. Knope, Mark Frisch etc.Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates:New framework compounds and in situ ligand syntheses[J].Journal of Solid State Chemistry.181 (2008):373-381.
[81]K. L. Gurunatha, Kazuhiro Uemura, and Tapas Kumar Maji. Temperature-and Stoichiometry-Controlled Dimensionality in a Magnesium 4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces [J].Inorganic Chemistry. Vol.47, No.15,2008:6578-6580.
[82]X.M. Chen, M.L. Tong, Z.N. Chen, etc.Inclusion of 4,4-Bipyridine(bpy) in its Copper(II) Aqua Perchlorato Complex. Crystal Structure of [Cu(bpy)(H20)2(C104)2]n·(bpy)n,[J]. Aust. J. Chem.1996,49:835.
[83]O.M. Yaghi and H. Li. T-shaped Molecular Building Units in the Porous Structure of Ag(4,4'-bpy)·NO3[J].J. Am. Chem. Soc.1996,118:295-296.
[84]M.L. Tong, B.H. Ye, X.M. Chen, etc.Clathration of two-dimensional coordination polymers:synthesis and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2·(2,4'-bpy)2-H2O and [Cu(4,4'-bpy)2(H2O)2]-(ClO4)2·(4,4'-H2bpy) (M=Cd(Ⅱ), Zn(Ⅱ) and bpy=bipyridine).[J]. Inorg. Chem.1998,37:2645-2647.
[85]K.B. Yu., Sturcture of catena-poly{bis(1,1,1,-trifluoro-2,4-penta-nedionato-κ2O,O')copper-μ-[(4,4'-bi pyridine)-κN:κN']}[J]. Acta Crystallogr, Sect.C.1991,47(12):2653-2655.
[86]J. Lu, T. Paliwala, A.J. Jaeobson, etc.Coordination Polymers of Co(NO3) with Pyrazine and 4,4'-bipyridine:syntheses and struetures[J].Inorg. Chem.1997,36:923-926.
[87]H.J. Chen, W.J. Yu, X.M. Chen,etc.Poly[cadmium(Ⅱ)-μ-4,4'-oxydianiline-N:N-μ-thiocyanato-N:S][J]. Acta Crystallogr, Sect.C.2001,57(6):1285-1287.
[88]M.J. Plater, W.R.St.J. Foreman, M.B. Hursthouse, etc.Synthesis and charaeterization of infinite coordination networks from flexible dipyridyl ligands and cadmium salts[J]. J. Chem. Soc. Dalton Trans. 2000:3065-3072.
[89]L.Carlrcci, G. Ciani, S. Rizzato, etc.Chiral Packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co(bpe)9(H2O)8(SO4)4](SO4)·14H2O [bpe=1,2-bis(4-pyridyl)ethane][J]. Chem. Commun.2000:1319-1320.
[90]G.D. Munno, D. Armentano, M. Jutve. A real novel sheet-like manganese(II) network synthesis and structure of [Mn(bpe)(NCS)2(CH3OH)2] and [Mn(bpe)(NCS)2(CH3OH)2]·bpe [bpe=trans-1,2-bis(4-pyridyl) ethene][J]. J. Chem. Soc. Dalton Trans.1999:1813-1820.
[91]L.Carlcrei, G. Cinai and D.M. Proseprio.New type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4) [bpethy=1,2-bis(4-pyridyl)ethyne][J]. Chem. Commun.1999, 449-451.
[92]J. Chesnut, A. Kusnetzow, J. Zubieta, etc.Solid state coordination chemistry of the copper halide-and pseudo-halide-orgnaoamine system, Cu-X-[bis-2,3-(2-pyridyl)pyrazine)] (X=Cl, Br, CN):hydorthemral synthesis and structural characterization[J]. Inorg. Chem.1999,38:2663-2668.
[93]M.Fujita, Y.J. Kwon, K. Ougra, etc. Inteprenetrating molecular ladders and brick. [J]. J. Am. Chem. Soc. 1995,117:7287-7292.
[94]L.R. Macgillivaray, S. Subramnaian and M.J. Zaworotko. Interwoven two-and three-dimensional coordination polymers through self assembly of Cu'cations with linear bidentate ligands[J]. Chem. commun.1994:1325-1328.
[95]L. Carlreei, G. Ciani and D.M. Porseprio. Self-assembly of novel coordination polymers containing polycatenated molecular ladders and intertwined two-dimensional tailings[J].J. Chem. Soc. Dalton Trans. 1999:1799-1805.
[96]S. Ni and J.J. Vittal.Inteprenetrating versus noninterpenetrating (4,4) nets:influence of the size of the metal and counter ions[J]. Cryst. Growth Des.2001,1:195-199.
[97]B. EAbrahams, S.R. Batten, R. Robson, etc. Ni(tpt)(NO3)2-A three-dimensional network with the exceptional (12,3) topology:A self-entangled single net[J].Angew. Chem. Int. Ed.1999,38:1475-1477.
[98]Hye Jin Choi, Mircea Dinca,and Jeffrey R. Long.Broadly Hysteretic H2 Adsorption in the Microporous Metal-Organic Framework Co(1,4-benzenedipyrazolate)[J].J.Am.Chem.Soc.2008,130:7848-7850.
[99]J. R. Li,Y. Tao,Q. Yu, S. Kitagawa. Selective Gas Adsorption and Unique Structural Topology of a Highly Stable Guest-Free Zeolite-Type MOF Material with N-rich Chiral Open Channels[J]. Chem. Eur. J.2008, 14:2771-2776.
[100]M.Ali,A.Ray,W.s.Sheldrick,H.Mayer-figge etc.Synthesis,crystal structure,EPR and magnetic properyies of a cyano-bridged CuⅡ-NiⅡ heterobimetallic comples:an unusual structure with long-rangeferromagnetic
exchange through hydrogen bonding[J].New J.Chem.2004,28:412-417.
[101]P.Y.Shek,W.-T.Wong,S.Gao etc.A novel one-dimensional Ni(Ⅱ)-Fe(Ⅱ) polymer containing μ3-cyanides: [Ni(cyclen)]2[Fe(CN)6]·8H2O. [J].New J.Chem.2002,26:1099-1101.
[102]张丽娟.多羧酸-过渡金属配位聚合物的合成、结构与性能的研究.吉林：吉林大学博士学位论文D],2003.(a)Li-Juan Zhang,Xiao-Li Zhao,Peng Cheng etc."A unique two-dimensional terephthalate-bridged structure with alternate tetra-and penta-coordinate cobalt(Ⅱ)sites.Synthesis,crystal structure and magnetic properties of [{Co-μ3-(tP)2(OH)2(phen)2}n]"[J]. Bulletin of the Chemical Society of Japan.2002, 76:1179-1184;(b)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Hydrothermal synthesis,structures and properties of coordination polymers based on mu(4)-bridging benzene-1,2,4,5-tetra carboxylate:[Co(Him)2(μ4-bta)1/2]n and{[Cu(phen)(μ4--bta)1/2]·H2O}n(bta=benzene-1,2,4,5-tetracarboxylate,Him=imidazole,phen=1,10-phen anthroline)"[J].Journal of Solid State Chemistry.2003,173:32-39;(c)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Hydrothermal synthesis and characterization of the first oxalate-bta mixed-ligand three-dimensional frameworks:{[M2(μ8--bta)(μ2-C2O4)]·(H3O)2(H2O)2}n(M=CoⅡ,FeII;bta=benzene-1,2,4,5-tetracarboxylate)"[J]. Dalton Transtration.2003:1148-1152; (d)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Synthesis and structural characterization of{[Fe(OH)(H2bta)](H2O)}n (3-D)(Hnbta=benzenetetracarboxylic acid)"[J]. Chemistry Letters.2002,10:1052-1053.
[103]M. Smith, J.T. Culp, E. Bittner etc.Kinetics of desorption of hexane from the microporous metal organic framework RPM-1[J].Microporous and Mesoporous Materials.106 (2007):115-121.
[104]Daisuke Tanaka, Keiji Nakagawa, Susumu Kitagawa etc.Kinetic Gate-Opening Process in a Flexible Porous Coordination Polymer [J].Angew. Chem. Int. Ed.2008,47:3914-3918.
[105]Kahn,Molecular Magnetism,New York:VCH,1993.
[106]Z.Kou,D.Z.Liao,P.Cheng. "Reactions of [S2M(μ-S)2FeCl2]2(M=Mo or W) with arenethiolate ions:influence of neighbouring metal sites on the rates and mechanisms of substitution at iron"[J]. J.Chem.Soc.Dalton Trans.1997:1507-1514.
[107]M.Monfort,J.ribas,X.Solan. "New unexpected coordination mode of azide acting as a bridging ligand between nickel(II)ions.Synthesis,crystal structure and magnetic properties of [Ni(N3)2(2,2-dimethylpropane-1,3-diarnme)]n, and infinite bidimensional polymer"[J].J.Chem.Soc.Chem. Commun.1993:350-351.
[108]M.A.S.Goher,Q.C.Yang,T.C.W.Mak. "Synthesis,structural and spectroscopic study of polymeric copper(I)thiocyanato complexes [Cu(NCS)L]n (L=methyl nicotinate and ethyl nicotinate) and[HL][Cu(NCS)2] (HL=H-ethyl isonicotinate)"[J]. Polyhendron.2000,19:615.
[109]L.Li,Z.Liu,S.S.Turner etc.The first one-dimensional copper(II)-radical system with alternating double end-on and end-to-end azido bridges[J].New J.Chem.2003,27:752-755.
[110]M.Ali,A.Ray,W.s.Sheldrick,H.Mayer-figge etc. Synthesis,crystal structure,EPR and magnetic properyies of a cyano-bridged CuⅡ-NiⅡ heterobimetallic comples:an unusual structure with long-range ferromagnetic exchange through hydrogen bonding[J].New J.Chem.2004,28:412-417.
[111]P.Y.Shek,W.-T.Wong,S.Gao etc.A novel one-dimensional Ni(II)-Fe(II) polymer containingμ3-cyanides: [Ni(cyclen)]2[Fe(CN)6]·8H2O[J].New J.Chem.2002,26:1099-1101.
[112]S. Noro,R. Kitaura,M. Kondo etc.Framework Engineering by Anions and Porous Functionalities of Cu(II)/4,4'-bpy Coordination Polymers[J].J. Am. Chem. Soc.2002,124:2568.
[113]G Ferey,C. Serre,Ⅰ. Margiolkai etc.A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction[J].Angew. Chem. Int. Ed.2004,43:6296.
[114]J. L. C. Rowsell,K. S. Park,O. M. Yaghi etc. Hydrogen Sorption in Functionalized Metal-Organic Frameworks[J]. J. Am. Chem. Soc.2004,126:5666.
[115]S. Hu, J. C. Chen, M. L. Chang, Cu2+-Mediated Dehydrogenative Coupling and Hydroxylation of an N-Heterocyclic Ligand:From Generation of a New Tetratopic Ligand to the Designed Assembly of Three-Dimensional Copper(Ⅰ) Coordination Polymers[J].Angew. Chem. Int. Ed.,2005,44:5471.
[116]O. Ohnlori, M. Kawnao, M. Fujita, A Two-in-One Crystal:Uptake of Two Different Guests into Two Distinct Channels of a Biporous Coordination Network[J].Angew. Chem. Int. Ed.,2005,44:1962.
[117]J. L. C. Rowsell, O. M. Yaghi, Strategies for Hydrogen Storage in Metal-Organic Frameworks [J]. Angew. Chem. Int.Ed.2005,44:4670.
[118]Batten S R,Robson R. Interpenetrating Nets:Ordered, Periodic Entanglement[J].Angew Chem.Int Ed.1998,37(11):1460-1494.
[119]K.T.Holman,H.H.Hammud,S.Isber etc.One-dimensional coordination polymer [Co(H2O)4(pyz)] (NO3)2·2H2O(pyz=pyrazine) with intra-and inter-chain H-bonds:structure, electronic spectral studies and magnetic properties[J].Polyhedron.2005,24:221.
[120]H.J.Choi,M.P.Suh.Synthesis,Crystal Structure, and Properties of a 3-D Network Assembled by Nickel(Ⅱ) Macrocyclic Complex and Terephthalato Bridge[J].Inorg.Chem.1999,38:6309.
[121]C.Chen,D.Xu,R.Ling etc.Structure of catena-poly[{(2,2'-bipyridyl)(diperchlorato)copper(Ⅱ)}-μ-4,4'-bipyridyl][J].Acta Cryst.1992,48:1231.
[122]H.K.Fun,S.S.S.Raj,R.GXiong etc.The first structurally characterized 3,4'-bipyridine copper(Ⅰ) coordination polymer with an approximately rectangular molecular box[J].J.Chem.Soc.Dalton Trans.1999: 1711.
[123]S.D.Huang, R.G.Xiong.Molecular recognition of organic chromosphores by coordination polymers: design and construction of nonlinear optical supramolecular assemblies[J]. Polyhedron.1997,16:3929.
[124]L.Carlucci,G.Ciani,D.M.Proserpio.A new type of supramolecular entanglement in the silver(Ⅰ) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy=1,2-bis(4-pyridyl)ethyne][J].Chem.Commun.1999:449.
[125]M.L.Tong,H.J.Chen,X.M.Chen.Molecular Ladders with Multiple Interpenetration of the Lateral Arms into the Squares of Adjacent Ladders Observed for [M2(4,4'-bpy)3(H2O)2(phba)2](NO3)2·4H2O (M=Cu2+ or Co2+; 4,4'-bpy=4,4'-Bipyridine; phba=4-Hydroxybenzoate)[J].Inorg.Chem.2000,39:2235.
[126]E.-Q.Gao,Y.-X.Xu,C.-H.Yan.Two square grid coordination polymers with manganese(Ⅱ) and 1,4-bis (imidazole-1-ylmethyl)benzene[J].CrystEngCommun.2004,6:298.
[127]M.Kondo, M.Shimamura, S.Kitagawa etc.Microporous Materials Constructed from the Interpenetrated Coordination Networks. Structures and Methane Adsorption Properties [J].Chem.Mater.2000,12:1288.
[128]L.R.MacGillivray.Interwoven two-and three-dimensional coordination polymers through self-assembly of CuⅠ cations with linear bidentate ligands [J]. Chem.Commun.1994:1325.
[129]M.Fujita, O.Sasaki, K.Ogura etc.Interpenetrating Molecular Ladders and Bricks[J].J.Am.Chem.Soc. 1995,117:7287.
[130]M.Kondo, T.Yoshitomi,S.Kitagawa etc.Three-Dimensional Framework with Channeling Cavities for Small Molecules:{[M2(4,4'-bpy)3(NO3)4]·xH2O}n (M=Co, Ni, Zn)[J].Angew.Chem.Int.Ed.1997,36:1725.
[131]Di Sun, Geng-Geng Luo, Na Zhang etc. Syntheses, structures, photoluminescences of silver(I) coordination polymers with 2-aminopyrazine and varied dicarboxylate ligands[J].Polyhedron.29(2010): 1243-1250.
[132]Shui-Sheng Chen, Jian Fan,Taka-aki Okamura etc.Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(Ⅱ) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands[J].Crystal Growth & Design.Vol.10, No.2,2010:812-822.
[133]M.Du, X.J.Zhao.{[Cu(bipy)2.5(H2O)](ClO4)2·(H2O)· (CH3OH)1.5}n (bipy=4,4'-bipyridine):organic template effect in formation of a novel bilayer coordination polymer with large chiral channels [J]. Inorg.Chem.Commun.2004:1056.
[134]GB.Gardner,D.Venkataraman,J.S.Moore etc.Spontaneous assembly of a hinged coordination network [J].Nature.1995,374:792.
[135]K.N.Power,T.L.Hennigar,M.J.Zaworotko.X-Ray crystal structure of{Cu[1,2-bis(4-pyridyl)ethane]2 (NO3)2}n:the first example of a coordination polymer that exhibits the NbO 3D network architecture[J]. Chem.Commun.1998:595.
[136]L.Carlucci,N.Cozzi,G.Ciani etc.A three-dimensional nanoporous flexible network of'square-planar' copper(II) centres with an unusual topology [J].Chem.Commun.2002:1354.
[137]B.Rather,B.Moulton,R.D.B.Walsh etc.A new supramolecular isomer of [Zn(nicotinate)2]n:a novel 42.84 network that is the result of self-assembly of 4-connected nodes[J].Chem.Commun.,2002:694.
[138]H.Gudbjartson,K.Biradha,K.M.Poirier etc.Novel Nanoporous Coordination Polymer Sustained by Self-Assembly of T-Shaped Moieties [J].J.Am.Chem.Soc.1999,121:2599.
[139]Shui-Sheng Chen, Jian Fan,Taka-aki Okamura etc.Synthesis, Crystal Structure, and Photoluminescence of a Series ofZinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands[J].Crystal Growth & Design.Vol.10, No.2,2010:812-822.
[140]S.R.Batten. "Topology of interpenetration"[J].CrystEngComm.2001,18:1-7.
[141]T.Ayyappan,O.R.Evans,and W.B.Lin. "A Novel Coordination Polymer Containing Both Interdigitated ID Chains and Interpenetrated 2D Grids"[J].Inorg. Chem.2002,41:3328-3330.
[142]H.Y.Wang,S.Gao,L.H.Huo etc."Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal"[J].Cryst.Growth Des.2008,8:665-670.
[143]Hong-YeBai,Jian-FangMa, JinYang etc.Eight Two-Dimensional and Three-Dimensional Metal-Organic Frameworks Based on a Flexible Tetrakis(imidazole) Ligand:Synthesis, Topological Structures, and Photoluminescent Properties[J].Crystal Growth & Design.Vol.10, No.4,2010:1946-1959.
[1]S.O.H.Gutschke,D.J.Price,A.K.Powell etc. Hydrothermal Synthesis, Structure, and Magnetism of [Co2(OH) {1,2,3-(O2C)3C6H3}(H2O)]·H2O and [Co2(OH){1,2,3-(O2C)3C6H3}]:Magnetic △-Chains with Mixed Cobalt Geometries[J]. Angew.Chem.2001,113:1974.
[2]R.E.Melendez,C.V.K.Sharma,M.J.Zaworkotko etc.Toward the Design of Porous Organic Solids:Modular Honeycomb Grids Sustained by Anions of Trimesic Acid[J]. Angew.Chem.Int.Ed.1996,35:2213.
[3]R.Murugavel,D.Krishnamurthy,M.Sathiyendiran. Anionic metal-organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4}·{C4H12N2}·4H2O]n (M=Co, Ni, and Zn; BTEC =1,2,4,5-benzenetetracarboxylate)[J].J.Chem.Soc.DaltonTrans.2002:34-39.
[4]S.O.H.Gutschke,D.J.Price,A.K.Powell etc.Rational Design of Open-Framework Coordination Solids-Synthesis and Structure of [Co5(OH)2{1,2,4,5-(O2C)4C6H2}2(H2O)4]·xH2O[J].Eur.J.Inorg.Chem.2001:2739.
[5]D.F.Sun,R.Cao,Y.C.Liang etc. Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures[J].J.Chem.Soc.DaltonTrans.,2001:2335.
[6]R.Cao,D.Sun,U.Liang etc.Syntheses and Characterizations of Three-Dimensional Channel-like Polymeric Lanthanide Complexes Constructed by 1,2,4,5-Benzenetetracarboxylic Acid[J].Inorg.Chem.2002,41:2087.
[7]Y.C.Liang,R.Cao,W.P.Su etc.Syntheses, Structures, and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(II) Coordination Polymers by a Hydrothermal Reaction[J].Angew.Chem.Int.Ed.2000,39:3304.
[8]L.A.Gerrard,P.T.Wood. Hydrothermal crystal engineering using hard and soft acids and bases:synthesis and X-ray crystal structures of the metal hydroxide-based phases M3M'2(OH)2[NC5H3(CO2)2-2,4]4(H2O)4(M =Co, Ni, Zn; M'= Pd, Pt)[J]. Chem.Commun.2000,2107.
[9]H.Abourahma,B.Moulton,V. Kravtsov etc.Supramolecular Isomerism in Coordination Compounds: Nanoscale Molecular Hexagons and Chains[J].J.Am.Chem.Soc.2002,124:9990.
[10]J. H. Luo, M. C. Hong, R. H. Wang etc. Novel Bilayer Cobalt(II)-Organic Framework with Nanoscale Channels Accommodating Large Organic Molecules[J].Inorg. Chem.2003,42:4486.
[11]J. W. Ye, J. Wang,J. Y. Zhang etc.Construction of 2-D lanthanide coordination frameworks:syntheses, structures and luminescent property[J]. CrystEngComm.2007,9:515.
[12]C.Kaes,A.Katz,M.W.Hosseini. Bipyridine:The Most Wide Used Ligand.A Review of Molecules Comprising at Least Two 2,2'-Bipyridine Units[J]. Chem. Rev.2000,100:3553
[13]M.D.Ward,J.A.McCleverty,J.C.Jeery.Coordination and Supramolecular Chemistry of Multinucleating Ligands Containing Two or More Pyrazolyl-Pyridine'Arms'[J].Coord.Chem.Rev.2001,222:251.
[14]V.Balzani,A.Juris,Photochemistry and Photophysics of Ru(II)-Polypyridine Complexes in the Bologna Group. From Early Studis to Recent Developments[J].Coord. Chem. Rev.200,211:97.
[15]De-Liang Long,Alexander J.Blake,Neil R.Champness,etc.Unprecedented Seven-and Eight-Connected Lanthanide Coordination Networks[J].Angew. Chem. Int.Ed.2001,40:2443-2447.
[16]Sun H.-L.,Wang Z.-M.,Gao S.Synthesis, Crystal Structures, and Magnetism of Cobalt Coordination Polymers Based on Dicyanamide and Pyrazine-dioxide Derivatives[J].Inorg. Chem.2005,44:2169-2176
[17]Sun H.-L.,Ma B.-Q.Gao, S.etc.A Novel Acentric Three-Dimensional Network with Complicated Topology[J].Cryst. Growth Des.2006,6(6):1261-1263.
[18]Zheng He, En-Qing Gao, Zhe-Ming Wang etc.Coordination Polymers Based on Inorganic Lanthanide(III) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector:Segregation into Three Structural Types by the Lanthanide Contraction Effect[J].Inorg. Chem.2005.44:862-874.
[19]Li-Li Wen,Dong-Bin Dang,Chun-Ying Duan,etc.1D Helix,2D Brick-Wall and Herringbone, and 3D Interpenetration d10 Metal-Organic Framework Structures Assembled from Pyridine-2,6-dicarboxylic Acid N-Oxide[J].Inorg. Chem.2005,44:7161-7170.
[20]Fei Chang,Song Gao,Ge-Hui Wen etc.Xi-Xiang Zhang,{[Cu2(bpdado)2(H2O)2]ⅩH2O}n:A 1D nanotubular coordination Polymer with wall made of edge-sharing hexagons, where bpdado=2,2'-bipyridine-3,3'-dicarboxy late-1,1'-dioxide[J].Dalton Trans.2005:2976-2978.
[21]Zhi Tang,Xi-Sen Wang,Ting Zhou etc.A Novel 2D Manganese(II) Coordination Polymer Exhibiting Ferromagnetic Interaction[J].Crystal Growth & Design.2006,6:11-13.
[22]Zheng He,Zhe-Ming Wang,Song Gao,etc.Coordination Polymers with End-On Azido and Pyridine Carboxylate N-Oxide Bridges Displaying Long-Range Magnetic Ordering with Low Dimensional Character[J]. Inorg. Chem.2006,45:6694-6705.
[23]X. R.Meng,Y.L.Song, H.W. Hou etc.31P NMR Spectroscopy as a Powerful Tool for the Determination of Enantiomeric Excess and Absolute Configurations of a-Amino Acids[J].Inorg. Chem.2003,42:1306.
[24]J. Fan and B. E. Hanson, Novel Zinc Phosphate Topologies Defined by Organic Ligands[J]. Inorg.Chem. 2005,44:6998.
[25]L.K.Li,Y.L.Song, H.W.Hou etc. Syntheses, Structures, and Optical Properties of β-Ferrocenylacrylate Metal Polymers[J]. Eur.J.Inorg.Chem.2005:3238.
[26]Q. Chang,X. R. Meng,Y. L. Song etc. Effect of substituent dtp to optical properties of heterobimetallic M/Ag/S nest-shaped clusters (M=Mo, W) [J].Inorg.Chim. Acta.2005,358:2117.
[27]Vojtisek, P.,Cisarova,I. Podalaha,etc.J.Z.Kristallogr.1997,212:226.
[28]Jian-Fang Ma,Jin Yang, Guo-Li Zheng etc.A Porous Supramolecular Architecture from a Copper(Ⅱ) Coordination Polymer with a 3D Four-Connected 86 Net[J].Inorganic Chemistry.Vol.42, No.23,2003: 7531-7534.
[29]Sanjay Sarkhel and Gautam R. Desiraju. N-H...O, O-H...O, and C-H...O Hydrogen Bonds in Protein-Ligand Complexes:Strong and Weak Interactions in Molecular Recognition[J].PROTEINS:Structure, Function, and Bioinformatics.54:247-259 (2004).
[30]刘孟军.含氮、氧配体构筑的超分子金属配合物的合成与结构[D].内蒙古：内蒙古大学,2009.
[31]Xiaoju Li, Rong Cao, Wenhua Bi etc. A New Family of Cadmium(Ⅱ) Coordination Polymers from Coligands:Effect of the Coexistent Groups (R) H,-NO2,-OH) on Crystal Structures and Properties[J]. Crystal Growth & Design, Vol.5, No.4,2005:1651-1656.
[32](a)Dong-E Wang,Ke-Jian Deng,Kang-Le Lv etc.Structures, photoluminescence and photocatalytic properties of three new metal-organic frameworks based on non-rigid long bridges[J].CrystEngComm,2009, 11:1442-1450;(b)Qin Hou,Jie-Hui Yu, Ji-Qing Xu etc.A new 3-D two-fold interpenetrated framework with sqp net based on Cu6I6 and Cu8I8 cluster nodes[J].CrystEngComm.2009,11:2452-2455.
[33]Ya-Qian Lan, Shun-Li Li, Kui-Zhan Shao etc. Construction of different dimensional inorganic-organic hybrid materials based on polyoxometalates and metal-organic units via changing metal ions:from non-covalent interactions to covalent connections[J].Dalton Trans.2008:3824-3835
[34]Jian-Yong Zhang,Qi Yue, Qin-Xiang Jia etc. Syntheses, structures and luminescence properties of cadmium(II) coordination polymers with in situ formed oxalate and bis(chelating) bridging ligands[J]. CrystEngComm.2008,10:1443-1449.
[1]M. Eddaoudi, M. O'keeffe,O. M. Yaghi. etc. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage[J].Science.2002,295:469-172.
[2]X. H. Bu,S. Kitagawa, S. R. Batter. etc. A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network[J].Angew Chem. Int. Ed.2004,43:192-195.
[3]S.S.Y.Chui,S. M. F. Lo,I.D.Williams,etc.A chemically functionalizable nanoporous material [Cu3(TMA)2 (H2O)3]n[J].Science.1999,283:1148-1150.
[4]S. J. Lee, A. Hu, W. Lin. The first chiral organometallic triangle for asymmetric catalysis[J]. J. Am.Chem. Soc.2002,124:12948-12949.
[5]C. J. Kepert, T. J. Prior, M. J. Rosseinsky. A versatile family of interconvertible microporous chiral molecular frameworks:the first example of ligand control of network chirality[J].J. Am. Chem. Soc.2000, 122:5158-5168.
[6](a)H.-F.Zhu,J. Fan,T.-A.Okamura,Z.-H. Zhang etc. Metal-Organic Architectures of Silver(I),Cadmium(II), and Copper(II) with a Flexible Tricarboxylate Ligand[J].Inorg. Chem.45 (2006):3941; (b) S.-N. Wang, J.-F. Bai,H. Xing,Y.-Z. Li,Y. Song etc.Novel Alternating Ferro-Ferromagnetic Two-Di mensional (4,4) and Photoluminescent Three-Dimensional Interpenetrating PtS-Type Coordination Networks Constructed from a New Flexible Tripodal Ligand as a Four-Connected Node[J].Cryst.Growth Des.7 (2007):747;(c) R. Sun, Y.-Z.Li,J.-F.Bai,Y.Pan.Synthesis,Structure,Water-Induced Reversible Crystal-to-Amorphous Transformation, and Luminescence Properties of Novel Cationic Spacer-Filled 3D Transition Metal Supramolecular Frameworks from N,N',N"-Tris(carboxymethyl)-1,3,5-benzene tricarboxamide[J].Cryst. Growth Des.7 (2007):890;(d)S.-N. Wang, H. Xing, Y.-Z. Li, J.-F. Bai etc.2D and 3D Cadmium(II) Coordination Polymers from a Flexible Tripodal Ligand of 1,3,5-Tris(carboxymethoxy) benzene and Bidentate Pyridyl-Containing Ligands with Three-, Eight-and Ten-Connected Topologies[J].Eur. J. Inorg. Chem.2006 (2006):3041.
[7]B. Rather, M. J. Zaworotko. A 3D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal to single-crystal dehydration and rehydration[J].Chem. Commun.2003, (7):830-831.
[8]P.M.Forster,A.K.Cheetham.Open-framework nickel succinate, [Ni7(C4H4O4)6(OH)(H2O)2]·2H2O: a new hybrid material with three-dimensional Ni-O-Ni connectivity[J].Angew Chem. Int. Ed.2002,41: 457159.
[9]L. Carlucci, Cx Ciani, D. M. Proserpio etc. Supramolecular isomers in the same crystal:a new case involving two different types of layers polycatenated in the 3D architecture of [Cu(bix)2(SO4)]·7.5H2O [bix=1,4-bis(imidazol-1-ylmethyl)benzene] [J].CrystEngComm.2004, (6):96-101.
[10]JB.Moulton, M. J. Zaworotko. From molecules to crystal engineering. Supramolecular isomerism and polymorphism in network solids[J].Chem. Rev.2001,101:1629-1658.
[11]K.Kasai,M.Aoyagi,M.Fujita. Flexible coordination networks with fluorinated backbones Remarkable ability for induced-fit enclathration of organic molecules[J].J. Am. Chem. Soc.2000,122:2140-2141.
[12]F. M. Tabellion, S. R. Seidel, A. M. Arif etc.A novel, tunable manganese coordination system based on a flexible "spacer" unit:noncovalent temptation effects[J].J. Am. Chem. Soc.2001,123:11982-11990.
[13]D. B. Cordes, A. S. Bailey, P. L. Caradoc-Davies etc.Flexible ligands and structural diversity:isomerism in Cd(NO3)2 coordination polymers[J]. Inorg. Chem.2005,44:2544-2552.
[14]田歌.新型金属-多羧酸配位聚合物的合成、结构与性能的研究.吉林：吉林大学博士学位论文[D].2006：59.
[15]B, De Groot, H. A. Jerkins, S. J. Loeb. Exodentate versus endodentate coordination of a crown thioether ligand in silver(Ⅰ) complexes of 2,5,8-trithia[9]-o-benzenophane (TT[9]OB). Structures of [Ag(TT[9)OB)2][X] (X=C104, BPh4, CF3SO3) [J]. Inorg. Chem.1992,31:203-208.
[16]R. Alberto, W. Nef, A. Smith, T. A. Kaden etc.Silver(I) complexes of the derivatized crown thioether ligands 3,6,9,12,15,18-hexathiacyclononadecanol and 3,6,9,13,16,19-hexathiacycloicosanol. Determination of stability constants and the crystal structures-of [Ag(19-aneS6-OH)][CF3SO3] and [Ag(20-aneS6-OH)] [BF4][J].Inorg. Chem.1996,35:3420-3427.
[17]M.Munakata,T.Kuroda-Sowa,S.Kitagawa. etc. Building of 2D sheet of tetrakis(methylthio)tetrathia fulvalenes coordinating to copper(I) halides with zigzag and helical frames and the 3D network through the S...S Contacts[J].Inorg. Chem.1995,34:2705-2710.
[18]Sandstrom J.Cyclization of thicarbohydrazide and its mono-hydrazones Part III reactions with carbon disulphide in pyridine [J].Acta Chim Scand.1961,15:1295-1302.
[19]Lili Wen, Dong'eWang, ChenggangWang etc.A 3D porous zinc MOF constructed from a flexible tripodal ligand:Synthesis, structure, and photoluminescence property [J]. Journal of Solid State Chemistry. 182 (2009):574-579.
[20]Qi Yang, Sanping Chen, Shengli Gao.An unexpected 3D (6,8)-connected metal-organic framework {[Cu5(trz)2(mal)2(fma)(H2O)4]·2H2O}n:Synthesis, structure and catalytic thermodecomposition for ammonium perchlorate[J].Inorganic Chemistry Communications.12 (2009):1224-1226.
[21]Ya-Qian Lan,Xin-Long Wang,Shun-Li Li etc.An unprecedented (6,8)-connected self-penetrating network based on two distinct zinc clusters[J].Chem. Commun.2007:4863-4865.
[22]Dong-Xu Xue, Wei-Xiong Zhang, Xiao-Ming Chen, Synthesis, structures, and physical properties of metal flexible dicarboxylate frameworks with dipyridyl coligand[J].Journal of Molecular Structure.877 (2008):36-43.
[23]王宇婷.柔性含芳环羧酸构筑的配位聚合物的研究.[D].河南：郑州大学博士论文,2007
[2]Abrahams B F,Haywood M QRobson R etc.New Tricks for an Old Dog:The Carbonate Ion as a Building Block for Networks Including Examples of Composition[Cu6(CO3)12{C(NH2)3}8]4-with the Sodalite Topology[J].Angew.Chem.Int.Ed.2003,42:1112-1115.
[3]Eddaoudi M, Moler D B, Li H L etc.Modular Chemistry:Secondary Building Units as a Basis for the Design of Highly Porous and Robust Metal-Organic Carboxylate Frameworks [J]. Acc. Chem. Res.2001, 34(4):319-330.
[4]Stein A,Keller S W,Mallouk T E.Turning Down the Heat:Design and Mechanism in Solid-State Synthesis[J].Science.1993,259:1558-1564.
[5]Olenyuk B,Fechtenkotter A,Stang P J.Molecular architecture of cyclic nanostructures:use of co-ordination chemistry in the building of supermolecules with predefined geometric shapes[J]. J. Chem. Soc.Dalton Trans. 1998:1707-1728.
[6]Stumpf H O,Ouahab L,Pei Y, etc. A Molecular-Based Magnet with a Fully Interlocked Three-Di mensional Structure [J]. Science.1993,261:447-449.
[7]Ohba M,Maruono N,Okawa H etc. A New Bimetallic Ferromagnet, [Ni(en)2]3[Fe(CN)6]2·2H2O, with a Rare Rope-Ladder Chain Structure [J]. J. Am. Chem. Soc.1994,116:11566-11567.
[8]Ohba M, Fukita N, Okawa H.Magnetic characteristics of bimetallic assemblies, [Ni(en)2]3[M(CN)6]2·2H2O (en=H2NCH2CH2NH2;M=Fe, Mn, Cr or Co), with a one-dimensional rope-ladder chain structure [J]. J. Chem. Soc. Dalton Trans.1997:1733-1738.
[9]Ohba M,Okawa H,Ito T, etc. A two-dimensional bimetallic assembly, [Ni(pn)2]2[Fe(CN)6]ClO4·2H2O, with a square structure[J]. J. Chem. Soc. Chem. Commun.1995:1545-1546.
[10]Graddon D P. An Introduction to Coordination Chemistry [M]. Pergamon Press.1997:4127.
[11]Bruser H J, Schwarzenbach D, etc. The crystal structure of Prussian Blue:Fe4[Fe(CN)6]3xH2O[J]. Inorg. Chem.1977,16:2704-2710.
[12]Iwamoto T. Comprehensive Supramolecular Chemistry [M]. Oxford,1996,6:643.
[13]胡亚微.由柔性双功能配体构筑的配位聚合物[D].长春：吉林大学化学学院,2008.
[14]Hoskins B F,Robson R.Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments[J].J.Am.Chem.Soc.1989,111:5962-5964.
[15]Munakata M, Wu L P, Kuroda-Sowa T. Advances in Inorganic Chemistry:Including Bioinorganic Chemistry, Sykes A G, Ed [M]. Academic Press:San Diego. CA.1999,46:175.
[16]Yaghi O M, Davis C E, Li G M etc. Selective Guest Binding by Tailored Channels in a 3-D Porous Zinc(Ⅱ)-Benzenetricarboxylate Network [J]. J. Am. Chem. Soc.1997,119:2861-2867.
[17]Kerpet C J, Prior T J, Rosseinsky M J.A Versatile Family of Interconvertible Microporous Chiral Molecular Frameworks:The First Example of Ligand Control of Network Chirality [J]. J. Am. Chem. Soc.2000,122:5158-5168.
[18]Carlucci L,Ciani G,Proserpio D M A etc.1-,2-, and 3-Dimensional Polymeric Frames in the Coordination Chemistry of AgBF4 with Pyrazine. The First Example of Three Interpenetrating 3-Dimensional Triconnected Nets [J]. J. Am. Chem. Soc.1995,117:4562-4569.
[19]Yaghi O M, Li H L.T-Shaped Molecular Building Units in the Porous Structure of Ag(4,4'-bpy)·NO3 [J]. J. Am. Chem. Soc.1996,118:295-296.
[20]Gardner G B D, Verkataraman J S, Moore S etc. Spontaneous assembly of a hinged coordination network [J]. Nature.1995,374:792-795.
[21]Yaghi O M, Li H L, Groy L T.Construction of Porous Solids from Hydrogen-Bonded Metal Complexes of 1,3,5-Benzenetricarboxylic Acid [J]. J. Am. Chem. Soc.1996,118:9096-9101.
[22]Hoskins B F,Robson R,Slizys D A.The Structure of [Zn(bix)2(NO3)2]·4.5H2O (bix=1,4-Bis (imidazol-1-ylmethyl)benzene):A New Type of Two-Dimensional Polyrotaxane [J]. Angew. Chem. Int. Ed. 1997,36:2336-2338.
[23]Chen B L,Eddaoudi M,Hyde S T etc. Interwoven Metal-Organic Framework on a Periodic Minimal Surface with Extra-Large Pores [J]. Science.2001,291:1021-1023.
[24]Eddaoudi M,Kim J.O'Keeffe M etc. Cu2[o-Br-C6H3(CO2)2]2(H2O)2·(DMF)8(H2O)2:A Framework Deliberately Designed To Have the NbO Structure Type [J]. J. Am. Chem. Soc.2002,124:376-377.
[25]Vossmeyer T,Reck G, Katsikas L etc.A Double-Diamond Superlattice Built Up of Cd17S4(SCH2CH2OH)26 Clusters [J]. Science.1995,267:1476-1479.
[26]Evans O R, Xiong R G, Wang Z Y etc.Crystal Engineering of Acentric Diamondoid Metal-Organic Coordination Networks[J]. Angew.Chem. Int. Ed.1999,38:536.
[27]Abrahams B F,Hoskins B F,Michaili D M etc.Assembly of porphyrin building blocks into network structures with large channels [J]. Nature.1994,369:727-729.
[28]CHen B L, Eddaoudi M, Reineke T M etc.Cu2(ATC)·6H2O:Design of Open Metal Sites in Porous Metal-Organic Crystals (ATC:1,3,5,7-Adamantane Tetracarboxylate) [J]. J. Am. Chem. Soc.2000,122: 11559-11560.
[29]Kim J, Chen B L, Reineke T M etc.Assembly of Metal-Organic Frameworks from Large Organic and Inorganic Secondary Building Units:New Examples and Simplifying Principles for Complex Structures [J]. J. Am. Chem. Soc.2001,123:8239-8247.
[30]Soma T,Iwamoto T.Supramolecular Structures in Solid State AgCN-Cd(CN)2-(4-Picoline) Complexes.An Interwoven Double Network of [Cd{Ag(CN)2}2]-in [traps-Cd(4-Mepy)2{Ag(CN)2}2]} (4-Mepy) and a Linear Chain of [-Cd-NC-Ag(CN)Ag-CN-]" in [Cd(4-Mepy)4{Ag2(CN)3}][Ag(CN)2][J]. Chem. Lett.1994: 821-824.
[31]Li H L, Thomas C E D, Groy L etc.Establishing Microporosity in Open Metal-Organic Frameworks:Gas Sorption Isotherms for Zn(BDC) (BDC=1,4-Benzenedicarboxylate) [J]. J. Am. Chem. Soc.1998,120: 8571-8572.
[32]Li H L, Eddaoudi M, O'Keeffe M etc. Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J]. Nature.1999,402:276-279.
[33]Hoskins B F, Robson R, Silzys D A. A Hexaimidazole Ligand Binding Six Octahedral Metal Ions to Give an Infinite 3D a-Po-Like Network Through Which Two Independent 2D Hydrogen-Bonded Networks Interweave [J]. Angew. Chem. Int. Ed.1997,36:2752-2755.
[34]Reinked T M, Eddaoudi M, Moler B etc. Large Free Volume in Maximally Interpenetrating Networks: The Role of Secondary Building Units Exemplified by Tb2(ADB)3[(CH3)2SO]4·16[(CH3)2SO][J]. J. Am. Chem. Soc.2000,122:4843-4844.
[35]Sun J Y, L Wei,G H Y, Zhou M etc.QMOF-1 and QMOF-2:Three-Dimensional Metal-Organic Open Frameworks with a Quartz like Topology [J]. Angew. Chem. Int. Ed.2002,41:4471-4473.
[36]Hoskins B F,Robson R N,Scarlett V Y.Six Interpenetrating Quartz-Like Nets in the Structure of ZnAu2(CN)4 [J]. Angew. Chem. Int. Ed.1995,34:1203-1204.
[37]Chui S S Y, Lo S M F, Charmant J P H etc. A Chemically Functionalizable Nanoporous Material [Cu3(TMA)2(H2O)3]n [J]. Science.1999,283:1148-1150.
[38]Abrahams B F,Haywood M G,Robson R etc.New Tricks for an Old Dog:The Carbonate Ion as a Building Block for Networks Including Examples of Composition [Cu6(CO3)12{C(NH2)3}g]4- with the Sodalite Topology [J]. Angew. Chem. Int. Ed.2003,42:1112-1115.
[39]Fujita M.,Kwon Y J.,Washizu S. etc.Preparation, Clathration Ability, and Catalysis of a Two-Dimensional Square Network Material Composed of Cadmium(Ⅱ) and 4,4'-Bipyridine[J]. J. Am. Chem. Soc. 1994,116:1151-1152.
[40]Gardner G.B,Venkaraman N.D,Moore J S etc.Spontaneous assembly of a hinged coordination network [J]. Nature.1995,374:792-794.
[41]S.S.-Y.Chui,S.M.-F.Lo,J.P.H.Charmant etc.A Chemically Functionalizable Nanoporous Material [Cu3 (TMA)2(H2O)3]n[J].Science.1999,283:1148-1150.
[42]Yaghi O.M, Li G.M, Li H.L.Selective binding and removal of guests in a microporous metal-organic framework [J]. Nature.1995,378:703-706
[43]Li H, Eddaoudi M, O'Keeffe M etc. Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].Nature.1999,402:276-279.
[44]M. Eddaoudi,M. O'Keeffe,O. M Yaghi etc.Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage [J].Science.2002,295:469.
[45]H.K.Chae,M.O'Keeffe,O.M.Yaghi etc.A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature.2004,427:523-527.
[46]A.C.Sudik, M.O'Keeffe,O.M.Yaghi etc. A Metal-Organic Framework with a Hierarchical System of Pores and Tetrahedral Building Blocks[J].Angew.Chem.Int.Ed.2006,45:2528.
[47]G.Ferey,S.Surble,I.Margiolaki etc.A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area[J]. Science.2005,309:2040.
[48]Batten S R, Robson R.Interpenetrating Nets:Ordered, Periodic Entanglement [J]. Angew. Chem. Int. Ed. 1998,37:1460-1494.
[49]Robin A Y,K M Fromm. Coordination polymer networks with O-and N-donors:What they are, why and how they are made [J].Coord. Chem. Rev.2006,250:2127-2157.
[50](a)邓前军.若干含氮竣酸配体功能配位聚合物的水热合成、晶体结构及性质研究[D].长沙：中南大学博士论文,2007；(b)叶俊伟.5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究[D].吉林：吉林大学,2007.
[51]H.Cui,Z.M.Wang,K.Takahashi etc.Ferroelectric Porous Molecular Crystal, [Mn3(HCOO)6](C2H5OH), Exhibiting Ferrimagnetic Transition[J]. J.Am.Chem.Soc.2006,128:15074.
[52]P.M.Forster,A.K.Cheetha.Open-Framework Nickel Succinate, [Ni7(C4H4O4)6(OH)2(H2O)2]·2 H2O:A New Hybrid Material with Three-Dimensional Ni-O-Ni Connectivity[J].Angew.Chem.Int.Ed.2002,41:457.
[53]V.Kiritsis,A.Michaelides,S.Skoulika etc.Assembly of a Porous Three-Dimensional Coordination Polymer:Crystal Structure of{[La2(adipate)3(H2O)4]6H2O}n[J].Inorg.Chem.1998,37:3407.
[54]N.Guillou,C.Livage,W.Beek etc."A Layered Nickel Succinate with Unprecedented Hexanickel Units:Structure Elucidation from Powder-Diffraction Data, and Magnetic and Sorption Properties" [J].Angew.Chem.Int.Ed.2003,42:643-647.
[55]N.Guillou,C.Livage,M.Drillon etc."The Chirality,Porosity,and Ferromagnetism of a 3D Nickel Glutarate with Intersecting 20-Membered Ring Channels"[J]. Angew.Chem.Int.Ed.2003,42:5314-5317.
[56]F.Abrahams,M.Moylan,S.D.Orchard etc.,"Excess electron transport through DNA:A single electron repairs more than one UV-induced lesion"[J]. Angew.Chem.Int.Ed.,2003,42:1848-1851.
[57]Xing-Jing Zhang,Yong-Heng Xing, Jing Han etc.A Series of Novel Ln-Succinate-Oxalate Coordination Polymers:Synthesis, Structure, Thermal Stability, and Fluorescent Properties[J].Crystal Growth & Design.Vol.8, No.10,2008:3680-3688.
[58]N.Hao,E.Shen,Y.Li etc."A novel metal-organic supramolecular framework constructed by benzene-1,2,4-tricarboxylate:{[Fe(phen)(btc)(H2O)]2·CH3CH2OH}n(btc=benzene-1,2,4-tricarboxylate)".[J].In org.Chem.Commun.2004,7:131-135.
[59]X.Y.Wang, S.C.Sevov."Synthesis,Structures,and Magnetic Properties of Metal-Coordination Polymers with Benzenepentacarboxylate Linkers"[J].Inorg.Chem.2008,47:1037-1043.
[60]Y.Yan,C.Wu,C.Lu."Hydrothermal Synthesis of Two New Transition Metal Coordination Polymers with Mixed Ligands"[J].Z.Anorg.Allg.Chem.2003,629:1991-1995.
[61]P.Zheng,L.Long,R.Huang,L.Zheng."Crystallographic report:A three-dimensional coordination polymer: [Zn6(btc)4(4,4-bipy)5]n (btc= 1,2,4-benzenetricarboxylate; 4,4-bipy=4,4-bipy ridine)"[J].Appl.Organometal. Chem.2003,17:739-740.
[62]C.Qin,X.Wang,E.Wang,C.Hu,L.Xu."Synthesis and characterization of a novel three-dimensional photoluminescent coordination polymer generated from unsymmetrically bridging ligand"[J].Inorg Chim Acta.2004,357:3683-3688.
[63]C.Qin,X.Wang,E.Wang,C.Hu,L.Xu."[Cu2(HBTC)2(H2O)2(μ2-H2O)]·2H2O:a new arm-shaped two-di mensional copper coordination polymer having both rhombic cavities and helical-like channels"[J]. Inorg.Chem.Comm.2004,7:788-197.
[64]L.Wang,Z.Shi,G.Li,Y.Fan,W.Fu,S.Feng."Solvothermal synthesis and structural characterization of a three-dimensional metal-organic polymer [NaZn(1,2,4-BTC)] (1,2,4-BTC=1,2,4-benzenetricarboxy late)"[J]. Solid State Sci.2004,6:85-90.
[65]Bai HY, Ma JF, Yang J etc. Effect of Anions on the Self-Assembly of Cd(II)-Containing Coordination Polymers Based on a Novel Flexible Tetrakis(imidazole) Ligand. CRYSTAL GROWTH & DESIGN.Vol.10, No.2,2010:995-1015.
[66]X.Zhang,S.S.Y.Chui,I.D.Williams."Cooperative magnetic behavior in the coordination polymers [Cu3(TMA)2L3](L=H2O,pyridine)"[J].J.Appl.Phys.2000,87:007-6009.
[67]Eddaoudi,M.O'Keeffe,O.M.Yaghi etc."Porous Metal-Organic Polyhedra:25A Cuboctahedron Constructed from 12 Cu2(CO2)4 Paddle-Wheel Building Blocks" [J].J.Am.Chem.Soc.2001,123:4368-4369.
[68]Eddaoudi,H.Li,O.M.Yaghi."Highly Porous and Stable Metal-Organic Frameworks:Structure Design and Sorption Properties" [J].J.Am. Chem.Soc.2000,122:1391-1397.
[69]Li,M.Eddaoudi,T.L.Groy,O.M.Yaghi."Establishing Microporosity in Open Metal-Organic Frameworks: Gas Sorption Isotherms for Zn(BDC) (BDC=1,4-Benzenedicarboxylate)"[J].J.Am.Chem.Soc.1998, 120:8571-8572.
[70]Mahata,S.Natarajan,"A New Series of Three-Dimensional Metal-Organic Framework, [M2(H2O)] [C5N1H3(COO)2]3-2H2O,M=La, Pr, and Nd:Synthesis,Structure,and Properties"[J].Inorg.Chem.2007,46: 1250-1258.
[71]Y.G.Huang,B.L.Wu,D.GYuan,Y.Q.Xu etc. "New Lanthanide Hybrid as Clustered Infinite Nanotunnel with 3D Ln-O-Ln Framework and(3,4)-Connected Net"[J].Inorg.Chem.2007,46:1171-1176.
[72]Y.Q.Sun,J.Zhang,GY.Yang."A series of luminescent lanthanide-cadmium-organic frameworks with helical channels and tubes"[J].Chem.Commun.2006:4700-4702.
[73]Fang Q.-R.,Zhu G-S.,Xue M. etc.Microporous Metal-Organic Framework Constructed from Hepta nuclear Zinc Carboxylate Secondary Building Units[J].Chem.Eur.J.2006,12:3754.
[74]Kyoungmoo Koh,Antek G. Wong-Foy,Adam J. Matzger.A Crystalline Mesoporous Coordination Copolymer with High Microporosity [J].Angew. Chem. Int. Ed.2008,47:677.
[75]Ming Xue, Enhua Kang, and Shilun Qiu etc.Structure, Hydrogen Storage, and Luminescence Properties of Three 3D Metal-Organic Frameworks with NbO and PtS Topologies[J].Crystal Growth & Design. Vol.8, No.7,2008:2478-2483.
[76](a)周瑞莎.含羧基配体的稀土配位聚合物的合成、结构及性能研究[D].吉林：吉林大学博士论文,2008；(b)赵斌.d-f混合金属配位聚合物的合成和性质研究[D].天津：南开大学博士论文,2004.
[77]Zhao B.,Cheng P.,Dai,Y. etc.A Nanotubular 3D Coordination Polymer Based on a 3d-4f Heterometallic Assembly[J].Angew.Chem.Int.Ed.2003,42:934.
[78]Zhao B.,Cheng P.,Chen,X. etc.Design and Synthesis of 3d-4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated "Water"Pipe[J].J.Am.Chem.Soc.2004,126:3012.
[79]Zhao B.,Chen X.Y.,Cheng,P. etc. Coordination Polymers Containing 1D Channels as Selective Luminescent Probes[J].J.Am.Chem.Soc.2004,126,15394.
[80]Kate L. Ziegelgruber, Karah E. Knope, Mark Frisch etc.Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates:New framework compounds and in situ ligand syntheses[J].Journal of Solid State Chemistry.181 (2008):373-381.
[81]K. L. Gurunatha, Kazuhiro Uemura, and Tapas Kumar Maji. Temperature-and Stoichiometry-Controlled Dimensionality in a Magnesium 4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces [J].Inorganic Chemistry. Vol.47, No.15,2008:6578-6580.
[82]X.M. Chen, M.L. Tong, Z.N. Chen, etc.Inclusion of 4,4-Bipyridine(bpy) in its Copper(II) Aqua Perchlorato Complex. Crystal Structure of [Cu(bpy)(H20)2(C104)2]n·(bpy)n,[J]. Aust. J. Chem.1996,49:835.
[83]O.M. Yaghi and H. Li. T-shaped Molecular Building Units in the Porous Structure of Ag(4,4'-bpy)·NO3[J].J. Am. Chem. Soc.1996,118:295-296.
[84]M.L. Tong, B.H. Ye, X.M. Chen, etc.Clathration of two-dimensional coordination polymers:synthesis and structures of [M(4,4'-bpy)2(H2O)2](ClO4)2·(2,4'-bpy)2-H2O and [Cu(4,4'-bpy)2(H2O)2]-(ClO4)2·(4,4'-H2bpy) (M=Cd(Ⅱ), Zn(Ⅱ) and bpy=bipyridine).[J]. Inorg. Chem.1998,37:2645-2647.
[85]K.B. Yu., Sturcture of catena-poly{bis(1,1,1,-trifluoro-2,4-penta-nedionato-κ2O,O')copper-μ-[(4,4'-bi pyridine)-κN:κN']}[J]. Acta Crystallogr, Sect.C.1991,47(12):2653-2655.
[86]J. Lu, T. Paliwala, A.J. Jaeobson, etc.Coordination Polymers of Co(NO3) with Pyrazine and 4,4'-bipyridine:syntheses and struetures[J].Inorg. Chem.1997,36:923-926.
[87]H.J. Chen, W.J. Yu, X.M. Chen,etc.Poly[cadmium(Ⅱ)-μ-4,4'-oxydianiline-N:N-μ-thiocyanato-N:S][J]. Acta Crystallogr, Sect.C.2001,57(6):1285-1287.
[88]M.J. Plater, W.R.St.J. Foreman, M.B. Hursthouse, etc.Synthesis and charaeterization of infinite coordination networks from flexible dipyridyl ligands and cadmium salts[J]. J. Chem. Soc. Dalton Trans. 2000:3065-3072.
[89]L.Carlrcci, G. Ciani, S. Rizzato, etc.Chiral Packing of chiral quintuple layers polycatenated to give a three-dimensional network in the coordination polymer [Co(bpe)9(H2O)8(SO4)4](SO4)·14H2O [bpe=1,2-bis(4-pyridyl)ethane][J]. Chem. Commun.2000:1319-1320.
[90]G.D. Munno, D. Armentano, M. Jutve. A real novel sheet-like manganese(II) network synthesis and structure of [Mn(bpe)(NCS)2(CH3OH)2] and [Mn(bpe)(NCS)2(CH3OH)2]·bpe [bpe=trans-1,2-bis(4-pyridyl) ethene][J]. J. Chem. Soc. Dalton Trans.1999:1813-1820.
[91]L.Carlcrei, G. Cinai and D.M. Proseprio.New type of supramolecular entanglement in the silver(I) coordination polymer [Ag2(bpethy)5](BF4) [bpethy=1,2-bis(4-pyridyl)ethyne][J]. Chem. Commun.1999, 449-451.
[92]J. Chesnut, A. Kusnetzow, J. Zubieta, etc.Solid state coordination chemistry of the copper halide-and pseudo-halide-orgnaoamine system, Cu-X-[bis-2,3-(2-pyridyl)pyrazine)] (X=Cl, Br, CN):hydorthemral synthesis and structural characterization[J]. Inorg. Chem.1999,38:2663-2668.
[93]M.Fujita, Y.J. Kwon, K. Ougra, etc. Inteprenetrating molecular ladders and brick. [J]. J. Am. Chem. Soc. 1995,117:7287-7292.
[94]L.R. Macgillivaray, S. Subramnaian and M.J. Zaworotko. Interwoven two-and three-dimensional coordination polymers through self assembly of Cu'cations with linear bidentate ligands[J]. Chem. commun.1994:1325-1328.
[95]L. Carlreei, G. Ciani and D.M. Porseprio. Self-assembly of novel coordination polymers containing polycatenated molecular ladders and intertwined two-dimensional tailings[J].J. Chem. Soc. Dalton Trans. 1999:1799-1805.
[96]S. Ni and J.J. Vittal.Inteprenetrating versus noninterpenetrating (4,4) nets:influence of the size of the metal and counter ions[J]. Cryst. Growth Des.2001,1:195-199.
[97]B. EAbrahams, S.R. Batten, R. Robson, etc. Ni(tpt)(NO3)2-A three-dimensional network with the exceptional (12,3) topology:A self-entangled single net[J].Angew. Chem. Int. Ed.1999,38:1475-1477.
[98]Hye Jin Choi, Mircea Dinca,and Jeffrey R. Long.Broadly Hysteretic H2 Adsorption in the Microporous Metal-Organic Framework Co(1,4-benzenedipyrazolate)[J].J.Am.Chem.Soc.2008,130:7848-7850.
[99]J. R. Li,Y. Tao,Q. Yu, S. Kitagawa. Selective Gas Adsorption and Unique Structural Topology of a Highly Stable Guest-Free Zeolite-Type MOF Material with N-rich Chiral Open Channels[J]. Chem. Eur. J.2008, 14:2771-2776.
[100]M.Ali,A.Ray,W.s.Sheldrick,H.Mayer-figge etc.Synthesis,crystal structure,EPR and magnetic properyies of a cyano-bridged CuⅡ-NiⅡ heterobimetallic comples:an unusual structure with long-rangeferromagnetic
exchange through hydrogen bonding[J].New J.Chem.2004,28:412-417.
[101]P.Y.Shek,W.-T.Wong,S.Gao etc.A novel one-dimensional Ni(Ⅱ)-Fe(Ⅱ) polymer containing μ3-cyanides: [Ni(cyclen)]2[Fe(CN)6]·8H2O. [J].New J.Chem.2002,26:1099-1101.
[102]张丽娟.多羧酸-过渡金属配位聚合物的合成、结构与性能的研究.吉林：吉林大学博士学位论文D],2003.(a)Li-Juan Zhang,Xiao-Li Zhao,Peng Cheng etc."A unique two-dimensional terephthalate-bridged structure with alternate tetra-and penta-coordinate cobalt(Ⅱ)sites.Synthesis,crystal structure and magnetic properties of [{Co-μ3-(tP)2(OH)2(phen)2}n]"[J]. Bulletin of the Chemical Society of Japan.2002, 76:1179-1184;(b)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Hydrothermal synthesis,structures and properties of coordination polymers based on mu(4)-bridging benzene-1,2,4,5-tetra carboxylate:[Co(Him)2(μ4-bta)1/2]n and{[Cu(phen)(μ4--bta)1/2]·H2O}n(bta=benzene-1,2,4,5-tetracarboxylate,Him=imidazole,phen=1,10-phen anthroline)"[J].Journal of Solid State Chemistry.2003,173:32-39;(c)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Hydrothermal synthesis and characterization of the first oxalate-bta mixed-ligand three-dimensional frameworks:{[M2(μ8--bta)(μ2-C2O4)]·(H3O)2(H2O)2}n(M=CoⅡ,FeII;bta=benzene-1,2,4,5-tetracarboxylate)"[J]. Dalton Transtration.2003:1148-1152; (d)Li-Juan Zhang,Ji-Qing Xu,Zhan Shi etc."Synthesis and structural characterization of{[Fe(OH)(H2bta)](H2O)}n (3-D)(Hnbta=benzenetetracarboxylic acid)"[J]. Chemistry Letters.2002,10:1052-1053.
[103]M. Smith, J.T. Culp, E. Bittner etc.Kinetics of desorption of hexane from the microporous metal organic framework RPM-1[J].Microporous and Mesoporous Materials.106 (2007):115-121.
[104]Daisuke Tanaka, Keiji Nakagawa, Susumu Kitagawa etc.Kinetic Gate-Opening Process in a Flexible Porous Coordination Polymer [J].Angew. Chem. Int. Ed.2008,47:3914-3918.
[105]Kahn,Molecular Magnetism,New York:VCH,1993.
[106]Z.Kou,D.Z.Liao,P.Cheng. "Reactions of [S2M(μ-S)2FeCl2]2(M=Mo or W) with arenethiolate ions:influence of neighbouring metal sites on the rates and mechanisms of substitution at iron"[J]. J.Chem.Soc.Dalton Trans.1997:1507-1514.
[107]M.Monfort,J.ribas,X.Solan. "New unexpected coordination mode of azide acting as a bridging ligand between nickel(II)ions.Synthesis,crystal structure and magnetic properties of [Ni(N3)2(2,2-dimethylpropane-1,3-diarnme)]n, and infinite bidimensional polymer"[J].J.Chem.Soc.Chem. Commun.1993:350-351.
[108]M.A.S.Goher,Q.C.Yang,T.C.W.Mak. "Synthesis,structural and spectroscopic study of polymeric copper(I)thiocyanato complexes [Cu(NCS)L]n (L=methyl nicotinate and ethyl nicotinate) and[HL][Cu(NCS)2] (HL=H-ethyl isonicotinate)"[J]. Polyhendron.2000,19:615.
[109]L.Li,Z.Liu,S.S.Turner etc.The first one-dimensional copper(II)-radical system with alternating double end-on and end-to-end azido bridges[J].New J.Chem.2003,27:752-755.
[110]M.Ali,A.Ray,W.s.Sheldrick,H.Mayer-figge etc. Synthesis,crystal structure,EPR and magnetic properyies of a cyano-bridged CuⅡ-NiⅡ heterobimetallic comples:an unusual structure with long-range ferromagnetic exchange through hydrogen bonding[J].New J.Chem.2004,28:412-417.
[111]P.Y.Shek,W.-T.Wong,S.Gao etc.A novel one-dimensional Ni(II)-Fe(II) polymer containingμ3-cyanides: [Ni(cyclen)]2[Fe(CN)6]·8H2O[J].New J.Chem.2002,26:1099-1101.
[112]S. Noro,R. Kitaura,M. Kondo etc.Framework Engineering by Anions and Porous Functionalities of Cu(II)/4,4'-bpy Coordination Polymers[J].J. Am. Chem. Soc.2002,124:2568.
[113]G Ferey,C. Serre,Ⅰ. Margiolkai etc.A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction[J].Angew. Chem. Int. Ed.2004,43:6296.
[114]J. L. C. Rowsell,K. S. Park,O. M. Yaghi etc. Hydrogen Sorption in Functionalized Metal-Organic Frameworks[J]. J. Am. Chem. Soc.2004,126:5666.
[115]S. Hu, J. C. Chen, M. L. Chang, Cu2+-Mediated Dehydrogenative Coupling and Hydroxylation of an N-Heterocyclic Ligand:From Generation of a New Tetratopic Ligand to the Designed Assembly of Three-Dimensional Copper(Ⅰ) Coordination Polymers[J].Angew. Chem. Int. Ed.,2005,44:5471.
[116]O. Ohnlori, M. Kawnao, M. Fujita, A Two-in-One Crystal:Uptake of Two Different Guests into Two Distinct Channels of a Biporous Coordination Network[J].Angew. Chem. Int. Ed.,2005,44:1962.
[117]J. L. C. Rowsell, O. M. Yaghi, Strategies for Hydrogen Storage in Metal-Organic Frameworks [J]. Angew. Chem. Int.Ed.2005,44:4670.
[118]Batten S R,Robson R. Interpenetrating Nets:Ordered, Periodic Entanglement[J].Angew Chem.Int Ed.1998,37(11):1460-1494.
[119]K.T.Holman,H.H.Hammud,S.Isber etc.One-dimensional coordination polymer [Co(H2O)4(pyz)] (NO3)2·2H2O(pyz=pyrazine) with intra-and inter-chain H-bonds:structure, electronic spectral studies and magnetic properties[J].Polyhedron.2005,24:221.
[120]H.J.Choi,M.P.Suh.Synthesis,Crystal Structure, and Properties of a 3-D Network Assembled by Nickel(Ⅱ) Macrocyclic Complex and Terephthalato Bridge[J].Inorg.Chem.1999,38:6309.
[121]C.Chen,D.Xu,R.Ling etc.Structure of catena-poly[{(2,2'-bipyridyl)(diperchlorato)copper(Ⅱ)}-μ-4,4'-bipyridyl][J].Acta Cryst.1992,48:1231.
[122]H.K.Fun,S.S.S.Raj,R.GXiong etc.The first structurally characterized 3,4'-bipyridine copper(Ⅰ) coordination polymer with an approximately rectangular molecular box[J].J.Chem.Soc.Dalton Trans.1999: 1711.
[123]S.D.Huang, R.G.Xiong.Molecular recognition of organic chromosphores by coordination polymers: design and construction of nonlinear optical supramolecular assemblies[J]. Polyhedron.1997,16:3929.
[124]L.Carlucci,G.Ciani,D.M.Proserpio.A new type of supramolecular entanglement in the silver(Ⅰ) coordination polymer [Ag2(bpethy)5](BF4)2 [bpethy=1,2-bis(4-pyridyl)ethyne][J].Chem.Commun.1999:449.
[125]M.L.Tong,H.J.Chen,X.M.Chen.Molecular Ladders with Multiple Interpenetration of the Lateral Arms into the Squares of Adjacent Ladders Observed for [M2(4,4'-bpy)3(H2O)2(phba)2](NO3)2·4H2O (M=Cu2+ or Co2+; 4,4'-bpy=4,4'-Bipyridine; phba=4-Hydroxybenzoate)[J].Inorg.Chem.2000,39:2235.
[126]E.-Q.Gao,Y.-X.Xu,C.-H.Yan.Two square grid coordination polymers with manganese(Ⅱ) and 1,4-bis (imidazole-1-ylmethyl)benzene[J].CrystEngCommun.2004,6:298.
[127]M.Kondo, M.Shimamura, S.Kitagawa etc.Microporous Materials Constructed from the Interpenetrated Coordination Networks. Structures and Methane Adsorption Properties [J].Chem.Mater.2000,12:1288.
[128]L.R.MacGillivray.Interwoven two-and three-dimensional coordination polymers through self-assembly of CuⅠ cations with linear bidentate ligands [J]. Chem.Commun.1994:1325.
[129]M.Fujita, O.Sasaki, K.Ogura etc.Interpenetrating Molecular Ladders and Bricks[J].J.Am.Chem.Soc. 1995,117:7287.
[130]M.Kondo, T.Yoshitomi,S.Kitagawa etc.Three-Dimensional Framework with Channeling Cavities for Small Molecules:{[M2(4,4'-bpy)3(NO3)4]·xH2O}n (M=Co, Ni, Zn)[J].Angew.Chem.Int.Ed.1997,36:1725.
[131]Di Sun, Geng-Geng Luo, Na Zhang etc. Syntheses, structures, photoluminescences of silver(I) coordination polymers with 2-aminopyrazine and varied dicarboxylate ligands[J].Polyhedron.29(2010): 1243-1250.
[132]Shui-Sheng Chen, Jian Fan,Taka-aki Okamura etc.Synthesis, Crystal Structure, and Photoluminescence of a Series of Zinc(Ⅱ) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands[J].Crystal Growth & Design.Vol.10, No.2,2010:812-822.
[133]M.Du, X.J.Zhao.{[Cu(bipy)2.5(H2O)](ClO4)2·(H2O)· (CH3OH)1.5}n (bipy=4,4'-bipyridine):organic template effect in formation of a novel bilayer coordination polymer with large chiral channels [J]. Inorg.Chem.Commun.2004:1056.
[134]GB.Gardner,D.Venkataraman,J.S.Moore etc.Spontaneous assembly of a hinged coordination network [J].Nature.1995,374:792.
[135]K.N.Power,T.L.Hennigar,M.J.Zaworotko.X-Ray crystal structure of{Cu[1,2-bis(4-pyridyl)ethane]2 (NO3)2}n:the first example of a coordination polymer that exhibits the NbO 3D network architecture[J]. Chem.Commun.1998:595.
[136]L.Carlucci,N.Cozzi,G.Ciani etc.A three-dimensional nanoporous flexible network of'square-planar' copper(II) centres with an unusual topology [J].Chem.Commun.2002:1354.
[137]B.Rather,B.Moulton,R.D.B.Walsh etc.A new supramolecular isomer of [Zn(nicotinate)2]n:a novel 42.84 network that is the result of self-assembly of 4-connected nodes[J].Chem.Commun.,2002:694.
[138]H.Gudbjartson,K.Biradha,K.M.Poirier etc.Novel Nanoporous Coordination Polymer Sustained by Self-Assembly of T-Shaped Moieties [J].J.Am.Chem.Soc.1999,121:2599.
[139]Shui-Sheng Chen, Jian Fan,Taka-aki Okamura etc.Synthesis, Crystal Structure, and Photoluminescence of a Series ofZinc(II) Coordination Polymers with 1,4-Di(1H-imidazol-4-yl)benzene and Varied Carboxylate Ligands[J].Crystal Growth & Design.Vol.10, No.2,2010:812-822.
[140]S.R.Batten. "Topology of interpenetration"[J].CrystEngComm.2001,18:1-7.
[141]T.Ayyappan,O.R.Evans,and W.B.Lin. "A Novel Coordination Polymer Containing Both Interdigitated ID Chains and Interpenetrated 2D Grids"[J].Inorg. Chem.2002,41:3328-3330.
[142]H.Y.Wang,S.Gao,L.H.Huo etc."Three Interpenetrated Frameworks Assembly from a Long Multicarboxylate Ligand and Transition Metal"[J].Cryst.Growth Des.2008,8:665-670.
[143]Hong-YeBai,Jian-FangMa, JinYang etc.Eight Two-Dimensional and Three-Dimensional Metal-Organic Frameworks Based on a Flexible Tetrakis(imidazole) Ligand:Synthesis, Topological Structures, and Photoluminescent Properties[J].Crystal Growth & Design.Vol.10, No.4,2010:1946-1959.
[1]S.O.H.Gutschke,D.J.Price,A.K.Powell etc. Hydrothermal Synthesis, Structure, and Magnetism of [Co2(OH) {1,2,3-(O2C)3C6H3}(H2O)]·H2O and [Co2(OH){1,2,3-(O2C)3C6H3}]:Magnetic △-Chains with Mixed Cobalt Geometries[J]. Angew.Chem.2001,113:1974.
[2]R.E.Melendez,C.V.K.Sharma,M.J.Zaworkotko etc.Toward the Design of Porous Organic Solids:Modular Honeycomb Grids Sustained by Anions of Trimesic Acid[J]. Angew.Chem.Int.Ed.1996,35:2213.
[3]R.Murugavel,D.Krishnamurthy,M.Sathiyendiran. Anionic metal-organic and cationic organic layer alternation in the coordination polymers [{M(BTEC)(OH2)4}·{C4H12N2}·4H2O]n (M=Co, Ni, and Zn; BTEC =1,2,4,5-benzenetetracarboxylate)[J].J.Chem.Soc.DaltonTrans.2002:34-39.
[4]S.O.H.Gutschke,D.J.Price,A.K.Powell etc.Rational Design of Open-Framework Coordination Solids-Synthesis and Structure of [Co5(OH)2{1,2,4,5-(O2C)4C6H2}2(H2O)4]·xH2O[J].Eur.J.Inorg.Chem.2001:2739.
[5]D.F.Sun,R.Cao,Y.C.Liang etc. Hydrothermal syntheses, structures and properties of terephthalate-bridged polymeric complexes with zig-zag chain and channel structures[J].J.Chem.Soc.DaltonTrans.,2001:2335.
[6]R.Cao,D.Sun,U.Liang etc.Syntheses and Characterizations of Three-Dimensional Channel-like Polymeric Lanthanide Complexes Constructed by 1,2,4,5-Benzenetetracarboxylic Acid[J].Inorg.Chem.2002,41:2087.
[7]Y.C.Liang,R.Cao,W.P.Su etc.Syntheses, Structures, and Magnetic Properties of Two Gadolinium(Ⅲ)-Copper(II) Coordination Polymers by a Hydrothermal Reaction[J].Angew.Chem.Int.Ed.2000,39:3304.
[8]L.A.Gerrard,P.T.Wood. Hydrothermal crystal engineering using hard and soft acids and bases:synthesis and X-ray crystal structures of the metal hydroxide-based phases M3M'2(OH)2[NC5H3(CO2)2-2,4]4(H2O)4(M =Co, Ni, Zn; M'= Pd, Pt)[J]. Chem.Commun.2000,2107.
[9]H.Abourahma,B.Moulton,V. Kravtsov etc.Supramolecular Isomerism in Coordination Compounds: Nanoscale Molecular Hexagons and Chains[J].J.Am.Chem.Soc.2002,124:9990.
[10]J. H. Luo, M. C. Hong, R. H. Wang etc. Novel Bilayer Cobalt(II)-Organic Framework with Nanoscale Channels Accommodating Large Organic Molecules[J].Inorg. Chem.2003,42:4486.
[11]J. W. Ye, J. Wang,J. Y. Zhang etc.Construction of 2-D lanthanide coordination frameworks:syntheses, structures and luminescent property[J]. CrystEngComm.2007,9:515.
[12]C.Kaes,A.Katz,M.W.Hosseini. Bipyridine:The Most Wide Used Ligand.A Review of Molecules Comprising at Least Two 2,2'-Bipyridine Units[J]. Chem. Rev.2000,100:3553
[13]M.D.Ward,J.A.McCleverty,J.C.Jeery.Coordination and Supramolecular Chemistry of Multinucleating Ligands Containing Two or More Pyrazolyl-Pyridine'Arms'[J].Coord.Chem.Rev.2001,222:251.
[14]V.Balzani,A.Juris,Photochemistry and Photophysics of Ru(II)-Polypyridine Complexes in the Bologna Group. From Early Studis to Recent Developments[J].Coord. Chem. Rev.200,211:97.
[15]De-Liang Long,Alexander J.Blake,Neil R.Champness,etc.Unprecedented Seven-and Eight-Connected Lanthanide Coordination Networks[J].Angew. Chem. Int.Ed.2001,40:2443-2447.
[16]Sun H.-L.,Wang Z.-M.,Gao S.Synthesis, Crystal Structures, and Magnetism of Cobalt Coordination Polymers Based on Dicyanamide and Pyrazine-dioxide Derivatives[J].Inorg. Chem.2005,44:2169-2176
[17]Sun H.-L.,Ma B.-Q.Gao, S.etc.A Novel Acentric Three-Dimensional Network with Complicated Topology[J].Cryst. Growth Des.2006,6(6):1261-1263.
[18]Zheng He, En-Qing Gao, Zhe-Ming Wang etc.Coordination Polymers Based on Inorganic Lanthanide(III) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector:Segregation into Three Structural Types by the Lanthanide Contraction Effect[J].Inorg. Chem.2005.44:862-874.
[19]Li-Li Wen,Dong-Bin Dang,Chun-Ying Duan,etc.1D Helix,2D Brick-Wall and Herringbone, and 3D Interpenetration d10 Metal-Organic Framework Structures Assembled from Pyridine-2,6-dicarboxylic Acid N-Oxide[J].Inorg. Chem.2005,44:7161-7170.
[20]Fei Chang,Song Gao,Ge-Hui Wen etc.Xi-Xiang Zhang,{[Cu2(bpdado)2(H2O)2]ⅩH2O}n:A 1D nanotubular coordination Polymer with wall made of edge-sharing hexagons, where bpdado=2,2'-bipyridine-3,3'-dicarboxy late-1,1'-dioxide[J].Dalton Trans.2005:2976-2978.
[21]Zhi Tang,Xi-Sen Wang,Ting Zhou etc.A Novel 2D Manganese(II) Coordination Polymer Exhibiting Ferromagnetic Interaction[J].Crystal Growth & Design.2006,6:11-13.
[22]Zheng He,Zhe-Ming Wang,Song Gao,etc.Coordination Polymers with End-On Azido and Pyridine Carboxylate N-Oxide Bridges Displaying Long-Range Magnetic Ordering with Low Dimensional Character[J]. Inorg. Chem.2006,45:6694-6705.
[23]X. R.Meng,Y.L.Song, H.W. Hou etc.31P NMR Spectroscopy as a Powerful Tool for the Determination of Enantiomeric Excess and Absolute Configurations of a-Amino Acids[J].Inorg. Chem.2003,42:1306.
[24]J. Fan and B. E. Hanson, Novel Zinc Phosphate Topologies Defined by Organic Ligands[J]. Inorg.Chem. 2005,44:6998.
[25]L.K.Li,Y.L.Song, H.W.Hou etc. Syntheses, Structures, and Optical Properties of β-Ferrocenylacrylate Metal Polymers[J]. Eur.J.Inorg.Chem.2005:3238.
[26]Q. Chang,X. R. Meng,Y. L. Song etc. Effect of substituent dtp to optical properties of heterobimetallic M/Ag/S nest-shaped clusters (M=Mo, W) [J].Inorg.Chim. Acta.2005,358:2117.
[27]Vojtisek, P.,Cisarova,I. Podalaha,etc.J.Z.Kristallogr.1997,212:226.
[28]Jian-Fang Ma,Jin Yang, Guo-Li Zheng etc.A Porous Supramolecular Architecture from a Copper(Ⅱ) Coordination Polymer with a 3D Four-Connected 86 Net[J].Inorganic Chemistry.Vol.42, No.23,2003: 7531-7534.
[29]Sanjay Sarkhel and Gautam R. Desiraju. N-H...O, O-H...O, and C-H...O Hydrogen Bonds in Protein-Ligand Complexes:Strong and Weak Interactions in Molecular Recognition[J].PROTEINS:Structure, Function, and Bioinformatics.54:247-259 (2004).
[30]刘孟军.含氮、氧配体构筑的超分子金属配合物的合成与结构[D].内蒙古：内蒙古大学,2009.
[31]Xiaoju Li, Rong Cao, Wenhua Bi etc. A New Family of Cadmium(Ⅱ) Coordination Polymers from Coligands:Effect of the Coexistent Groups (R) H,-NO2,-OH) on Crystal Structures and Properties[J]. Crystal Growth & Design, Vol.5, No.4,2005:1651-1656.
[32](a)Dong-E Wang,Ke-Jian Deng,Kang-Le Lv etc.Structures, photoluminescence and photocatalytic properties of three new metal-organic frameworks based on non-rigid long bridges[J].CrystEngComm,2009, 11:1442-1450;(b)Qin Hou,Jie-Hui Yu, Ji-Qing Xu etc.A new 3-D two-fold interpenetrated framework with sqp net based on Cu6I6 and Cu8I8 cluster nodes[J].CrystEngComm.2009,11:2452-2455.
[33]Ya-Qian Lan, Shun-Li Li, Kui-Zhan Shao etc. Construction of different dimensional inorganic-organic hybrid materials based on polyoxometalates and metal-organic units via changing metal ions:from non-covalent interactions to covalent connections[J].Dalton Trans.2008:3824-3835
[34]Jian-Yong Zhang,Qi Yue, Qin-Xiang Jia etc. Syntheses, structures and luminescence properties of cadmium(II) coordination polymers with in situ formed oxalate and bis(chelating) bridging ligands[J]. CrystEngComm.2008,10:1443-1449.
[1]M. Eddaoudi, M. O'keeffe,O. M. Yaghi. etc. Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage[J].Science.2002,295:469-172.
[2]X. H. Bu,S. Kitagawa, S. R. Batter. etc. A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network[J].Angew Chem. Int. Ed.2004,43:192-195.
[3]S.S.Y.Chui,S. M. F. Lo,I.D.Williams,etc.A chemically functionalizable nanoporous material [Cu3(TMA)2 (H2O)3]n[J].Science.1999,283:1148-1150.
[4]S. J. Lee, A. Hu, W. Lin. The first chiral organometallic triangle for asymmetric catalysis[J]. J. Am.Chem. Soc.2002,124:12948-12949.
[5]C. J. Kepert, T. J. Prior, M. J. Rosseinsky. A versatile family of interconvertible microporous chiral molecular frameworks:the first example of ligand control of network chirality[J].J. Am. Chem. Soc.2000, 122:5158-5168.
[6](a)H.-F.Zhu,J. Fan,T.-A.Okamura,Z.-H. Zhang etc. Metal-Organic Architectures of Silver(I),Cadmium(II), and Copper(II) with a Flexible Tricarboxylate Ligand[J].Inorg. Chem.45 (2006):3941; (b) S.-N. Wang, J.-F. Bai,H. Xing,Y.-Z. Li,Y. Song etc.Novel Alternating Ferro-Ferromagnetic Two-Di mensional (4,4) and Photoluminescent Three-Dimensional Interpenetrating PtS-Type Coordination Networks Constructed from a New Flexible Tripodal Ligand as a Four-Connected Node[J].Cryst.Growth Des.7 (2007):747;(c) R. Sun, Y.-Z.Li,J.-F.Bai,Y.Pan.Synthesis,Structure,Water-Induced Reversible Crystal-to-Amorphous Transformation, and Luminescence Properties of Novel Cationic Spacer-Filled 3D Transition Metal Supramolecular Frameworks from N,N',N"-Tris(carboxymethyl)-1,3,5-benzene tricarboxamide[J].Cryst. Growth Des.7 (2007):890;(d)S.-N. Wang, H. Xing, Y.-Z. Li, J.-F. Bai etc.2D and 3D Cadmium(II) Coordination Polymers from a Flexible Tripodal Ligand of 1,3,5-Tris(carboxymethoxy) benzene and Bidentate Pyridyl-Containing Ligands with Three-, Eight-and Ten-Connected Topologies[J].Eur. J. Inorg. Chem.2006 (2006):3041.
[7]B. Rather, M. J. Zaworotko. A 3D metal-organic network, [Cu2(glutarate)2(4,4'-bipyridine)], that exhibits single-crystal to single-crystal dehydration and rehydration[J].Chem. Commun.2003, (7):830-831.
[8]P.M.Forster,A.K.Cheetham.Open-framework nickel succinate, [Ni7(C4H4O4)6(OH)(H2O)2]·2H2O: a new hybrid material with three-dimensional Ni-O-Ni connectivity[J].Angew Chem. Int. Ed.2002,41: 457159.
[9]L. Carlucci, Cx Ciani, D. M. Proserpio etc. Supramolecular isomers in the same crystal:a new case involving two different types of layers polycatenated in the 3D architecture of [Cu(bix)2(SO4)]·7.5H2O [bix=1,4-bis(imidazol-1-ylmethyl)benzene] [J].CrystEngComm.2004, (6):96-101.
[10]JB.Moulton, M. J. Zaworotko. From molecules to crystal engineering. Supramolecular isomerism and polymorphism in network solids[J].Chem. Rev.2001,101:1629-1658.
[11]K.Kasai,M.Aoyagi,M.Fujita. Flexible coordination networks with fluorinated backbones Remarkable ability for induced-fit enclathration of organic molecules[J].J. Am. Chem. Soc.2000,122:2140-2141.
[12]F. M. Tabellion, S. R. Seidel, A. M. Arif etc.A novel, tunable manganese coordination system based on a flexible "spacer" unit:noncovalent temptation effects[J].J. Am. Chem. Soc.2001,123:11982-11990.
[13]D. B. Cordes, A. S. Bailey, P. L. Caradoc-Davies etc.Flexible ligands and structural diversity:isomerism in Cd(NO3)2 coordination polymers[J]. Inorg. Chem.2005,44:2544-2552.
[14]田歌.新型金属-多羧酸配位聚合物的合成、结构与性能的研究.吉林：吉林大学博士学位论文[D].2006：59.
[15]B, De Groot, H. A. Jerkins, S. J. Loeb. Exodentate versus endodentate coordination of a crown thioether ligand in silver(Ⅰ) complexes of 2,5,8-trithia[9]-o-benzenophane (TT[9]OB). Structures of [Ag(TT[9)OB)2][X] (X=C104, BPh4, CF3SO3) [J]. Inorg. Chem.1992,31:203-208.
[16]R. Alberto, W. Nef, A. Smith, T. A. Kaden etc.Silver(I) complexes of the derivatized crown thioether ligands 3,6,9,12,15,18-hexathiacyclononadecanol and 3,6,9,13,16,19-hexathiacycloicosanol. Determination of stability constants and the crystal structures-of [Ag(19-aneS6-OH)][CF3SO3] and [Ag(20-aneS6-OH)] [BF4][J].Inorg. Chem.1996,35:3420-3427.
[17]M.Munakata,T.Kuroda-Sowa,S.Kitagawa. etc. Building of 2D sheet of tetrakis(methylthio)tetrathia fulvalenes coordinating to copper(I) halides with zigzag and helical frames and the 3D network through the S...S Contacts[J].Inorg. Chem.1995,34:2705-2710.
[18]Sandstrom J.Cyclization of thicarbohydrazide and its mono-hydrazones Part III reactions with carbon disulphide in pyridine [J].Acta Chim Scand.1961,15:1295-1302.
[19]Lili Wen, Dong'eWang, ChenggangWang etc.A 3D porous zinc MOF constructed from a flexible tripodal ligand:Synthesis, structure, and photoluminescence property [J]. Journal of Solid State Chemistry. 182 (2009):574-579.
[20]Qi Yang, Sanping Chen, Shengli Gao.An unexpected 3D (6,8)-connected metal-organic framework {[Cu5(trz)2(mal)2(fma)(H2O)4]·2H2O}n:Synthesis, structure and catalytic thermodecomposition for ammonium perchlorate[J].Inorganic Chemistry Communications.12 (2009):1224-1226.
[21]Ya-Qian Lan,Xin-Long Wang,Shun-Li Li etc.An unprecedented (6,8)-connected self-penetrating network based on two distinct zinc clusters[J].Chem. Commun.2007:4863-4865.
[22]Dong-Xu Xue, Wei-Xiong Zhang, Xiao-Ming Chen, Synthesis, structures, and physical properties of metal flexible dicarboxylate frameworks with dipyridyl coligand[J].Journal of Molecular Structure.877 (2008):36-43.
[23]王宇婷.柔性含芳环羧酸构筑的配位聚合物的研究.[D].河南：郑州大学博士论文,2007