乙吡啶醚衍生物及其锌配合物的合成、晶体结构与非线性光学性质研究
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摘要
非线性光学材料在当今高速发展的信息产业中具有广泛的应用,在光频率转换、激光调制、激光偏转、Q开关材料等方面有着十分广阔的应用前景,因此,研究此类材料对于光信号处理、光转换技术等领域具有重要的学术意义。本学位论文根据有机分子结构丰富多变的特点,利用结构-性能关系对非线性光学材料的结构要求,选择4-硝基-2-吡啶甲酸-1-氧(POA)为母体,进行改组设计,通过溶液法生长晶体,培养了6种晶体;并利用元素分析、X-射线单晶衍射、傅立叶变换红外光谱、差热与热重分析、紫外-可见光谱、荧光分析、倍频效应分析等手段对晶体材料的组成、结构和性质进行相关研究。
6种晶体分为三类:
1、乙吡啶醚衍生物3种: PEHA(1)(4-乙氧基-2-吡啶羟肟酸)、PEHZ(2)(4-乙氧基-2-吡啶甲酰肼)、PPEHZ(3)(4-乙氧基-N-丙酰-2-吡啶甲酰肼);
2、配位化合物2种: [ZnCl(APEHZ)(H2O)]?0.5H2O(4)(APEHZ为4-乙氧基-N-乙酰-2-吡啶甲酰肼)、[ZnCl(PPEHZ)] n(5);
3、吡啶二羧酸1种: DPOA(6)(2,4-二吡啶甲酸-1-氧);
X-射线单晶衍射结果表明:晶体1、2、6和配合物4为平面形结构;晶体1和2结构类似,具有非心结构;配位化合物4和配位聚合物5为5配位的配合物;晶体2通过分子间氢键形成二维结构,晶体1、3、6通过分子间氢键形成一维链状结构,配位聚合物5以羧基氧为桥和分子内氢键聚合成一维链状结构。
红外光谱分析测试表明:配位化合物4和配位聚合物5中一个N-H的伸缩振动峰和弯曲振动峰消失;配位化合物4和配位聚合物5中烷酰基部分C=O的伸缩振动峰发生红移;配位聚合物5酰肼基部分C=O的伸缩振动峰也发生红移。
紫外-可见光谱测试表明:晶体1、2、3的紫外吸收峰位置类似;晶体6的吸收峰位置与晶体1、2、3相比较均发生了红移,并且透光波段变窄。
差热与热重分析测试表明:晶体6的热稳定性高于POA,分解温度提高了近30℃;晶体1、2、3的热稳定性与POA相比稍差;配位聚合物5骨架分子的分解温度比配位化合物4的高。
荧光测试结果说明:晶体6的发射波长与POA相比较发生了蓝移;晶体1、2、3的激发光谱和发射光谱基本一致;配位化合物4的发射光谱与其配体的发射光谱相比较发生了红移。
非线性光学性质测试表明,晶体1的1.06μm激光二倍频光强度是KDP的2倍;晶体2的1.06μm激光二倍频光强度较弱。
Nonlinear Optical (NLO) materials have extensive applications in the high-speed developing information industry, and they play a more and more important part in the application areas of frequency-changing, laser modulation and deflexion, and Q switch and so on. So it is very important for the light-signal processing, transferring and operation and so on to research NLO materials. Based on the flexibility of organic molecule structure, we picked 4-Nitro-1-Oxide-Pyridine-2-Carboxylic Acid(POA) as a mother reagent to prepare and synthesized 6 crystal materials through solution growth technique, in fitting of the requirements for NLO materials from the relationship between molecular structure and material function. The grown 6 crystals were characterized using Element analysis, Single-crystal X-ray diffraction, FTIR, UV-visible, DSC-TGA, Fluorescence, SHG studies.
Crystal 1, 2 and 3 are Ethylpyridl ether derivatives, and crystal 4 and 5 are complexes, and crystal 6 belongs to pyridine dicarboxylic acid. Single-crystal X-ray analysis shows, crystal 1, 2, 6 and complex 4 have plane-structure, and crystal 1 and 2 have the similar noncentrosymmetrical structure, and complex 4 and 5 have five-coordination structure, and the packing arrangement with intermolecular hydrogen bonds of crystal 2 is two-dimensional structure but one-dimensional structure in crystal 2, 3 and 6 is formed through the intermolecular hydrogen bonds, and there is a one-dimensional structure in complex 5 through an atom of O in carboxyl and an intramolecular hydrogen bond. FTIR analysis shows that the stretching and bending peaks of N-H and the stretching peaks of C=O in complex 4 and 5 disappear. UV-visible analysis shows that absorbing peaks of crystal 6 have red-shift phenomenon compare to that of crystal 1, 2 and 3 with the similar absorbing peaks and that there is a higher cutoff ultraviolet-visible absorption of crystal 6 than that of crystal 1, 2 and 3. DSC-TGA analysis shows that the stability of crystal 6 is 30℃higher than that of POA but the stability of crystal 1, 2 and 3 is lower than that of POA and that the decomposition temperature of framework molecular of complex 5 is higher than that of complex 4. Fluorescence analysis shows that emission peak of crystal 6 has blue-shift phenomenon compare to that of POA and crystal 1, 2 and 3 have the similar excitation and emission peaks, and that emission peak of complex 4 has red-shift phenomenon compare to organic ligand. SHG studies shows that SHG efficiency of crystal 1 is about 2 times as large as that of KDP and that crystal 2 has weak SHG efficiency.
6种晶体分为三类:
1、乙吡啶醚衍生物3种: PEHA(1)(4-乙氧基-2-吡啶羟肟酸)、PEHZ(2)(4-乙氧基-2-吡啶甲酰肼)、PPEHZ(3)(4-乙氧基-N-丙酰-2-吡啶甲酰肼);
2、配位化合物2种: [ZnCl(APEHZ)(H2O)]?0.5H2O(4)(APEHZ为4-乙氧基-N-乙酰-2-吡啶甲酰肼)、[ZnCl(PPEHZ)] n(5);
3、吡啶二羧酸1种: DPOA(6)(2,4-二吡啶甲酸-1-氧);
X-射线单晶衍射结果表明:晶体1、2、6和配合物4为平面形结构;晶体1和2结构类似,具有非心结构;配位化合物4和配位聚合物5为5配位的配合物;晶体2通过分子间氢键形成二维结构,晶体1、3、6通过分子间氢键形成一维链状结构,配位聚合物5以羧基氧为桥和分子内氢键聚合成一维链状结构。
红外光谱分析测试表明:配位化合物4和配位聚合物5中一个N-H的伸缩振动峰和弯曲振动峰消失;配位化合物4和配位聚合物5中烷酰基部分C=O的伸缩振动峰发生红移;配位聚合物5酰肼基部分C=O的伸缩振动峰也发生红移。
紫外-可见光谱测试表明:晶体1、2、3的紫外吸收峰位置类似;晶体6的吸收峰位置与晶体1、2、3相比较均发生了红移,并且透光波段变窄。
差热与热重分析测试表明:晶体6的热稳定性高于POA,分解温度提高了近30℃;晶体1、2、3的热稳定性与POA相比稍差;配位聚合物5骨架分子的分解温度比配位化合物4的高。
荧光测试结果说明:晶体6的发射波长与POA相比较发生了蓝移;晶体1、2、3的激发光谱和发射光谱基本一致;配位化合物4的发射光谱与其配体的发射光谱相比较发生了红移。
非线性光学性质测试表明,晶体1的1.06μm激光二倍频光强度是KDP的2倍;晶体2的1.06μm激光二倍频光强度较弱。
Nonlinear Optical (NLO) materials have extensive applications in the high-speed developing information industry, and they play a more and more important part in the application areas of frequency-changing, laser modulation and deflexion, and Q switch and so on. So it is very important for the light-signal processing, transferring and operation and so on to research NLO materials. Based on the flexibility of organic molecule structure, we picked 4-Nitro-1-Oxide-Pyridine-2-Carboxylic Acid(POA) as a mother reagent to prepare and synthesized 6 crystal materials through solution growth technique, in fitting of the requirements for NLO materials from the relationship between molecular structure and material function. The grown 6 crystals were characterized using Element analysis, Single-crystal X-ray diffraction, FTIR, UV-visible, DSC-TGA, Fluorescence, SHG studies.
Crystal 1, 2 and 3 are Ethylpyridl ether derivatives, and crystal 4 and 5 are complexes, and crystal 6 belongs to pyridine dicarboxylic acid. Single-crystal X-ray analysis shows, crystal 1, 2, 6 and complex 4 have plane-structure, and crystal 1 and 2 have the similar noncentrosymmetrical structure, and complex 4 and 5 have five-coordination structure, and the packing arrangement with intermolecular hydrogen bonds of crystal 2 is two-dimensional structure but one-dimensional structure in crystal 2, 3 and 6 is formed through the intermolecular hydrogen bonds, and there is a one-dimensional structure in complex 5 through an atom of O in carboxyl and an intramolecular hydrogen bond. FTIR analysis shows that the stretching and bending peaks of N-H and the stretching peaks of C=O in complex 4 and 5 disappear. UV-visible analysis shows that absorbing peaks of crystal 6 have red-shift phenomenon compare to that of crystal 1, 2 and 3 with the similar absorbing peaks and that there is a higher cutoff ultraviolet-visible absorption of crystal 6 than that of crystal 1, 2 and 3. DSC-TGA analysis shows that the stability of crystal 6 is 30℃higher than that of POA but the stability of crystal 1, 2 and 3 is lower than that of POA and that the decomposition temperature of framework molecular of complex 5 is higher than that of complex 4. Fluorescence analysis shows that emission peak of crystal 6 has blue-shift phenomenon compare to that of POA and crystal 1, 2 and 3 have the similar excitation and emission peaks, and that emission peak of complex 4 has red-shift phenomenon compare to organic ligand. SHG studies shows that SHG efficiency of crystal 1 is about 2 times as large as that of KDP and that crystal 2 has weak SHG efficiency.
引文
[1]石顺祥,陈国夫,赵卫,刘继芳.非线性光学(第一版) [M].西安电子科技大学出版社, 2003, pp: 1 ~ 2.
[2] Karakas A, Elmali A, Unver H, Svoboda I. Nonlinear optical properties, synthesis, structures and spectroscopic studies of N-(4-nitrobenzylidene)-o-fluoroamine and N-(3-nitrobenzylidene)-p-fluoroamine [J]. Spectro. Acta Part A, 2005, 61(13-14): 2979 ~ 2987.
[3] Benjamin J. C. Switchable nonlinear optical metallochromophores with pyridinium electron acceptor groups [J]. Acc. Chem. Res., 2006, 245: 386 ~ 389.
[4] Rajarajan K, Selvakumar S, Joseph G P, Potheher I V, Mohamed M G, Sagayaraj P. Growth, dielectric and photoconducting studies of tetrathiourea mercury(II) tetrathiocyanato zinc(II) NLO single crystals [J]. J. Crystal Growth, 2006, 286(2): 470 ~ 475.
[5] Oertel U, Dudkina M M, Komber H, Pilch B, Tenkovtsev A V, Bohme F. A spectroscopic study on the dissociation behavior of 4-hydroxybenzylideneacetone type NLO chromophores in the presence of sodium hydroxide [J]. Optical Mater., 2005: 1 ~ 9.
[6] de Silva I C, de Silva R M, de Silva K M N. Investigations of nonlinear optical (NLO) properties of Fe, Ru and Os organometallic complexes using high accuracy density functional theory (DFT) calculations [J]. J. Mole. Struct.: THEOCHEM, 2005, 728(1-3): 141 ~ 145.
[7] Cifuentes M P, Humphrey M G. Alkynyl compounds and nonlinear optics [J]. J. Organ. Chem., 2004, 689: 3968 ~ 3981.
[8] Zyss J , Ledoux I. Through2space charge transfer and non-linear optical properties of substituted paracyclophane [J]. J Am Chem Soc, 2000, 122(48): 11956 ~ 11962.
[9] Denning R G. New optics ( new materials) [J]. J Mater Chem, 2001, 11:19 ~ 28.
[10] Delaire J A , Keitaro Nakatani. Linear and nonlinear optical properties of photochromicmolecules and materials [J]. Chem Rev, 2000, 100: 1817 ~ 1845.
[11] Burland D M. Optical nonlinearities in chemistry Introduction [J]. Chem Rev, 1994, 94: 1 ~ 2.
[12] Taki M, Wolford J L. Emission ratiometric imaging of intracellular zinc , Design of abenzoxazole fluorescent sensor and its application in two2photon microscopy [J]. J Am Chem Soc, 2004, 126(3): 712 ~ 713.
[13] Stricker J H, Webb W W. Three-dimensional optical data storage in refractive media by two photon point excitation [J]. Opt Commun, 1991, 16: 1780 ~ 1784.
[14] Fisher A M R, Murphree A L, Gomer C J, et al. Clinical and preclinical photodynamic therapy [J]. 1995, Laser Surg Med, 17: 2 ~ 7.
[15] Belfield KD , Ren X. Near2IR two2photon photoinitiated polymerization using a fluorone/amine initiating system [J]. J Am Chem Soc, 2000, 122(6): 1217 ~ 1218.
[16] Perry J W, Mansour K, Lee I Y S, et al . Organic optical limiter with a st rong nonlinear absorptive response [J] . Science, 1998, 273: 1533 ~ 1536.
[17] Seth R. Marder, Organic nonlinear optical materials: where we have been and where we are going [J], Chem. Commun., 2006, 131–134.
[18]张克从,王希敏.非线性光学晶体材料科学(第一版) [M].北京:科学出版社, 1996, pp. 54 ~ 84.
[19]常新安,陈丹,臧和贵,张玮.非线性光学晶体的研究进展[J],人工晶体学报, 2007, 36(1): 327 ~ 333.
[20] Kurtz S K, Pery T T, A Powder Technique For The Evaluation Of Nonlinear Optical Materials [J], J Appl Phys, 1968, 39: 3798.
[21] Jiang H, Kakkar A K. An alternative route based on acid-base hydrolytic chemistry to NLO active organic-inorganic hybrid materials for second-order nonlinear optics [J]. J. Am. Chem. Soc., 1999, 121(15): 3657 ~ 3665.
[22]高允贵.用于深紫外光源的非线性光学材料[J].光电子技术与信息, 1999, 12(1): 23 ~ 26.
[23]崔元靖.无机-有机杂化二阶韭线性光学材料的设计、合成与性能研究[D],浙江大学博士学位论文, 2005, pp: 4 ~ 33.
[24]王传明.有机非线性光学材料的分子设计[D].南京理工大学硕士学位论文, 2004, pp: 10.
[25] Carlo D C, Alessandro F M, Massimiliano L, Paolo C B, Luisa P, Franco B, Luisa S, Adele M, Mauro C, Felice S, Alessia Q. Preparation and characterization of thiophene copolymers with second order non-linear optical properties [J]. J. European Polymer, 2005, 41(10): 2360 ~ 2369.
[26] Ishow E, Bellaiche C, Bouteiller L, Nakatani K, Delaire J A. Versatile synthesis of small NLO-active molecules forming amorphous materials with spontaneous second-orderNLO response [J]. J. Am. Chem. Soc., 2003, 125(51): 15744 ~ 15745.
[27] Selvakumar S, Rajasekar S A, Thamizharasan K, Sivanesan S, Ramanand A, Sagayaraj P. Thermal, dielectric and photoconductivity studies on pure, Mg2+ and Zn2+ doped BTCC single crystals [J]. Mater. Chem. Phys., 2005, 93(2-3): 356 ~ 360.
[28] Zhang F, Prosenc M H, Heck J. Synthesis and characterization of dinuclear monohydro sesquifulvalene complexes with potential NLO properties [J]. J. Organ. Chem., 2006, 691(3): 455 ~ 462.
[29] Anand D P, Mohamed M G, Pajasekar S A, Selvakumar S, Pragasam A J A, Sagayaraj P. Growth and characterization of pure, benzophenone and iodine doped benzoyl glycine single crystals [J]. Mater. Chem. Phys., 2006, 97(2-3): 501 ~ 505.
[30]祁楠,陈兴,程侣伯.有机非线性光学材料的进展[J].精细化工, 1994, (11): 20 ~ 28.
[31]蔺彬彬,仇永清,苏忠民,孙世玲,封继康.水杨醛缩苯胺类席夫碱构象异构体的稳定及其非线性光学性质的理论研究[J].高等学校化学学报, 2001, 22(9): 1551 ~ 1554.
[32]姜有昌,刘景芳,颜力揩,兰亚乾,赵雅辉.二联吡啶及其二氮取代衍生物电子性质和非线性光学性质的理论研究[J].分子科学学报, 2004, 20(1): 12 ~ 15.
[33]袁跃华,田茂忠,郭永,孟双明.二阶非线性光学聚酰亚胺材料的研究进展[J].雁北师范学院学报, 2004, 20(5): 23 ~ 25.
[34] Zhe xiong Tang , Malkiat S. Johal, Paul Scudder, Ni?a Caculitan, Rudolph J. Magyar, Sergei Tretiak, Hsing-Lin Wang. Study of the non-covalent interactions in Langmuir-lodgett films: An interplay betweenπ?πand dipole-ipole interactions[J]. Thin Solid Films, 2007, 516: 58 ~ 66.
[35]王晓鸥,李俊庆,郑仰东,辛丽,李淳飞.手性分子介质非线性光学研究新进展[J].物理, 2004, 33(8): 574 ~ 578.
[36] Anne M K, Weinan L, Mireille B D. Resonance hyper-raman scattering from conjugated organic donor-acceptor“push-pull”chromophores with large first hyperpolarizabilities [J]. J. Am. Chem. Soc., 2003, 125: 10520 ~ 10521.
[37] Annoni E, Pizzotti M, Ugo R, Quici S, Morotti T, Casati N, Macchi P. The effect on E-silbazoles second order NLO response by axial interaction with M(II) 5,10,15,20-tetraphenyl porphyrinates (M=Zn, Ru, Os); a new crystalline packing with very large holes [J]. Inorg. Chim. Acta, 2006, 359(9): 3029 ~ 3041.
[38] Manuela M, Raposo M A, Sousa M R C, Kirsch G, Ferreira F, Belsley M, de Matos G E,Mauricio A, Fonseca C. Synthesis of tricyanovinyl-subsitituted thienylpyrroles and characterization of the solvatochromic, electrochemical and non-linear optical properties [J]. Tetrahedron, 2005, 61(50): 11991 ~ 11998.
[39] Cariati E, Pizzotti M, Roberto D, Tessore F, Ugo R. Coordination and organometallic compounds and inorganic-organic hybrid crystalline materials for second-order non-linear optics [J]. Coordi. Chem. Rev., 2005, 1 ~ 24.
[40]李辉,徐伯华,谢军揩,毕剑.系列推拉取代基1, 3, 5-己三烯的非线性光学性质的理论研究[J].四川师范大学学报(自然科学版), 2002, 25(1): 56 ~ 58.
[41]向继明,谢周,英柏宁. 5-芳胺-6-氯-2, 3-二氰吡嗪[J].有机化学, 1997, 10(5): 427 ~ 431.
[42]赵雷,常俊丽,王世敏.有机二阶非线性光学分子设计和合成研究进展[J].湖北大学学报(自然科学版), 1999, 21(2): 197 ~ 204.
[43] Marder S R, Goman C B. Stronger acceptors can diminish nonlinear optical response in simple Donor-Acceptor Polyense [J]. J. Am. Chem. Soc., 1993, 115: 3006 ~ 3007.
[44]阚玉和.二氰基三维苯多烯共轭化合物电子光谱及非线性光学性质的INDO/SOS研究[J].东北师大学报自然科学版, 2004, 36(3): 61 ~ 65.
[45]刘永军,刘英,赵显,刘成卜.氮杂联苯乙烯系列衍生物的二阶非线性光学性质的理论研究[J].高等学校化学学报, 2001, 22(6): 1016 ~ 1018.
[46]刘英,刘永军.氮杂联苯乙烯系列衍生物的二阶非线性光学性质的理论研究[J].曲阜师范大学学报, 2001, 27(2): 71 ~ 74.
[47]杨彦杰,苏忠民.硝基取代亚酞菁衍生物的电子光谱和非线性光学性质的理论研究[J].高等学校化学学报, 2005, 26(3): 467 ~ 470.
[48] Pushkara R V, Alex K Y J, Chandrasekhar J, Namboothiri I N N, Rathna A. The important role of heteroaromatics in the design of efficient second-order nonlinear optical molecules: theoretical investigation on push-pull heteroaromatic stilbenes [J]. J. Am. Chem. Soc., 1996, 118: 12443 ~ 12448.
[49] Tian X H, Ru W, Zhong J H, Lin J P, Li Ch Y, Luo X L. Structures and calculated NLO properties of (acenaphthylene) and (acenaphthene)Cr(CO)3 [J]. Chem. Phys., 2006, 324(2-3): 667 ~ 673.
[50]王文军,张山彪,李淑红,刘云龙,王立英,王恭明,王文澄.中心对称萘酞菁分子二次谐波产生的实验研究[J].光子学报, 2004, 33(4): 489 ~ 493.
[51]赵成大,固体量子化学[M],高等教育出版社, 1997,pp: 327 ~ 328.
[52] Albert I D L, Marks T J , M. A. Ratner, Large Molecular Hyperpolarizabilities. Quantitative Analysis of Aromaticity and Auxiliary Donor-Acceptor Effects,J.Am.Chem.Soc., 1997, 119: 6575 ~ 6582。
[53]王大文,叶成,赵建良,白春礼.有机非线性光学晶体NPP的AFM研究[J].物理化学学报, 1994, 10(2): 172 ~ 174.
[54]吴芸,赵波,吴迪,周志华.盐酸氨基脲的二阶非线性光学性质研究[J].化学研究与应用, 2004, 16(1): 111 ~ 112.
[55]赵波,周志华. 2H-苯并吡喃-2-酮类化合物分子二阶非线性光学性质的理论研究[J].南京晓庄学院学报, 2004, 20(4): 28 ~ 32.
[56] Ihara R, Honma T, Benino Y, Fujiwara T, Komatsu T. Second-order optical nonlinearities of metastable BiBO3 phases in crystallized glasses [J]. Optic. Mater., 2004, 27(3): 403 ~ 408.
[57] Marks T J, Ratner M A. Design, synthesis, and properties of molecule-based assemblies with large 2nd-order optical nonlinearities [J]. Angew. Chem. Int. Edit., 1995, 34(2): 155 ~ 173.
[58] Verbiest T, Houbrechts S, Kanranen M. Second-order nonlinear materials:recen advances in chromophore design [J]. J. Mater. Chem., 1997, 7(11): 2175 ~ 2189.
[59] Dewar M J S, Zoebisch E G, Healy E F. AM1: a new general purpose quantum mechanical molecular model [J]. J. Am. Chem. Soc., 1985, 107(13): 3902 ~ 3909.
[60]花建丽,李俊,罗敬东,秦金贵.兼具大的二阶非线性与良好透明性的有机生死团的分子设计进展[J].有机化学, 2003, 23(1): 44 ~ 53.
[61] Alain V, Redoglia S, Blandchard D M, Lebus S, Lukaszuk K, Wortmann R, Gubler U, Bosshard C, Gunter P. Elongated push–pull diphenylpolyenes for nonlinear optics: molecular engineering of quadratic and cubic optical nonlinearities via tuning of intramolecular charge transfer [J]. Chem. Phys. 1999, 245(1-3): 51 ~ 57.
[62]赵波,仇立干,费正皓. 4-溴查耳酮的二阶非线性光学性质研究[J].南京师大学报(自然科学版), 2000, 23: 67 ~ 70.
[63]吴迪,赵波,周志华. 1-(4-溴苯基)-5-苯基-2,4-戊二烯-1-酮的二阶非线性光学性质研究[J].南京师大学报(自然科学版), 2004, 27: 55 ~ 60.
[64] Wang S M, Zhao L, Xu Z X, Wu C H, Chen S Y. Novel nonlinearity-transparency-thermal stability trade-off of imidazole chromophores for nonlinear optical application [J]. Mater. Letters, 2002, 56: 1035 ~ 1038.
[65] Gilmour S, Montgomery R A, Marder S R, Cheng L T, Jen A K Y, Cai Y-M, Perry J W, Dalton L R. Synthesis of diarylthiobarbituric acid chromophores with enhanced second-order optical nonlinearities and thermal stabilities [J]. Chem. Mater., 1994, 6: 1603 ~ 1604.
[66] Chen C T, Marder S R, Cheng L T. Syntheses and linear and nonlinear optical properties of unsymmetrical squaraines with extended conjugation [J]. J. Am. Chem. Soc., 1994, 116: 3117 ~ 3118.
[67] Yang M L, Sun Z M, Yan G S. An Ab initio study on nonlinear optical properties of squarates [J]. Acta Chin. Sinica, 1999, 57(7): 754 ~ 759.
[68]孙世玲,苏忠民,阚玉和,陈丽华,朱玉兰,任爱民,封继康.含1,3-方酸苯螺旋共轭分子的设计及其电子光谱和非线性光学性质的理论研究[J].高等学校化学学报, 2002, 23(1): 105 ~ 108.
[69] Lee J Y, Bang H B, Baek C S. Synthesis and nonlinear optical properties of novel T-type polyurethanes with high thermal stability of second harmonic generation [J]. Synthetic Metals, 2005, 148: 161 ~ 168.
[70]赵波,卢文庆,吴芸.一种激光倍频新材料-间羟基苯甲酸的初步研究[J].高等学校化学学报, 2000, 21(4): 620 ~ 622.
[71]钱鹰,肖国民,林保平,薛静,袁春伟.双羟乙氨基-硝基型偶氮[J].精细化工, 2005, 22(11): 823 ~ 826.
[72] Qian Y, Lin B P, Xiao G M, Li H H, Yuan C W. Chromophores exhibiting nonlinearity-transparency-thermal stability trade-off: synthesis and nonlinear optical properties of two-dimensinal chromophores containing nitro acceptors [J]. Optical Mater., 2004, 27(1): 125 ~ 130.
[73]祝阳,杨芳,杨济活.酞菁氧钛/咔唑化合物的合成与其二阶非线性光学性能的研究[J].精细化工, 2004, 21(12): 890 ~ 893.
[74]谭克.甲氧基苯基偶氮衍生物电子结构与二阶NLO性质的HF/FF方法研究[J].分子科学学报, 2005, 21(2): 21 ~ 25.
[75]谭克,杨国春,杨贵福,李波.螺旋双芴体系二阶非线性光学性质的ZINDO-SOS理论研究[J].分子科学学报, 2005, 21(2): 17 ~ 20.
[76] Frazier C C, Harvey M A, Cockerham M P, Hand H M, Chauchard E A, Lee Chi H. Second-harmonic generation in transition-metal-organic compounds [J]. J. Phys. Chem., 1986, 90(22): 5703 ~ 5706.
[77] Santo D B, Ignazio F. Two-dimensional characteristics of the second-order nonlinear optical response in dipolar donor–acceptor coordination complexes [J]. New J. Chem., 2002, 26: 285 ~ 290.
[78] Qin J G, Liu D Y, Dai C Y, Chen C C, Wu B C, Yang C L, Zhan C M. Influence of the molecular configuration on second-order nonlinear optical properties of coordination compounds [J]. Coord. Chem. Rev., 1999, 188(1): 23 ~ 34.
[79] Tam W., Calavrese, J.C. Oxidative addition of Pd(0) and Pt(0) with aromatic halides: Material for second-harmonic generation [J]. Chem. Phys. Lett., 1988, 144(1): 79 ~ 82.
[80] Norman P, Cronstrand P, Ericsson J. Theoretical study of linear and nonlinear absorption in platinum-organic compounds [J]. Chem. Phys., 2002, 285(2-3): 207 ~ 220.
[81]洪涛,吴克琛,莽朝永,林晨升,张明昕,韦永勤,刘彩萍,周张锋,庄伯涛.含Pt配合物电子结构和非线性光学性质TDDTFT研究[J].结构化学, 2004, 23(7): 788 ~ 792.
[82] Nalwa S H. Third-order nonlinear optical properties of pyridine- and ferrocene-containing polyazines [J]. Mater. Lett., 1997, 33(1-2): 23 ~ 26.
[83]蒋伟春,浦鸿汀,李新碗,陈建平.二阶非线性光学聚合物材料的最新研究进展[J].高分子通报, 2004, (5): 28 ~ 38.
[84] Williams D J. Organic polymeric and non-polymeric materials with large optical nonlinearities [J]. Angew. Chem. Int. Ed. Engl., 1984, 23(9): 690 ~ 703.
[85] Zhu X-L, You X-Z, Zhang Y. A novel approach to calculation of the second-order nonlinear optical susceptibilities of organic crystals based on energy-band theory [J]. Chem. Phys., 2000, 254(2-3): 287 ~ 296.
[86]苏忠民,封继康,张锁秦,任爱民,孙家钟.吡啶及其-NH2, -NO2单双取代衍生物的非线性光学性质的理论研究[J].分子科学学报, 1999, 15(4): 232 ~ 237.
[87]苏忠民,封继康,任爱民,张锁秦,孙家锺.用有限场和耦合微扰方法N-氧化吡啶及其-NH2, -NO2单双取代衍生物非线性光学性质的研究[J].高等学校化学学报, 2000, 21(4): 590 ~ 595.
[88] Zyss J, Chemla D S. Demonstration of efficient nonlinear optical crystals with vanishing molecular dipole moment: Second-harmoin generation in 3-methyl-4-nitropyridine-1-oxide [J]. J. Chem. Phys., 1981, 74(9): 4800 ~ 4811.
[89] Li S X, Liu S X, Wu W S. Sythesis, structure and some physical properties of 2-methyl-4- nitropyridine-1-oxide [J]. J. Struct. Chem., 1987, 6(1): 20 ~ 25.
[90] Boomadevi S, Mittal H P, Dhansekaran R. Synthesis, crystal growth andcharacterization of 3-methyl-4-nitropyridine-1-oxide(POM) single crystals [J]. J. Crystal Growth, 2004, 261: 55 ~ 62.
[91] Maxime G, Edith B, Benoi C. Theoretical investigation of the linear and second-order nonlinear susceptibilities of the 3-methyl-4-nitropyridine-1-oxyde(POM) crystal [J]. J. chem. Phys., 2004, 121(15): 7390 ~ 7400.
[92]陈静. POA相关化合物的合成、结构与非线性光学性质研究[D].华侨大学硕士学位论文, 2006, pp: 30 ~ 60.
[93] Jean Pierre Costes, Ghenadie Novitchi, Sergiu Shova, Francüoise Dahan, Bruno Donnadieu, and Jean-Pierre Tuchagues. Synthesis, Structure, and Magnetic Properties of Heterometallic Dicyanamide-Bridged Cu-Na and Cu-Gd One-Dimensional Polymers [J]. Inorg. Chem., 2004, 43(24): 7792 ~ 7799.
[94] Rajesh Koner, Hsin-Huang Lin, Ho-Hsiang Wei, and Sasankasekhar Mohanta, Syntheses, Structures, and Magnetic Properties of Diphenoxo-Bridged MIILnIII Complexes Derived from N,N’-Ethylenebis(3-ethoxysalicylaldiimine) (M =Cu or Ni; Ln=Ce-Yb): Observation of Surprisingly Strong Exchange Interactions [J], Inorg. Chem., 2005, 44(24): 3524 ~ 3536.
[95] Christian Lorber, Robert Choukroun, and Laure Vendier. A General and Facile One-Step Synthesis of Imido-Titanium(IV) Complexes: Application to the Synthesis of Compounds Containing Functionalized or Chiral Imido Ligands and Bimetallic Diimido Architectures [J], Eur. J. Inorg. Chem. 2006, 4503 ~ 4518.
[96] Ann J. Stemmler, Jeff W. Kampf, Martin L. Kirk, Bassel H. Atasi, and Vincent L. Pecoraro. The Preparation, Characterization, and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes [J], Inorg. Chem. 1999, 38(12), 2807 ~ 2817.
[97]吴文士.含皮考林酰肼和皮考林羟肟酸配合物的结构化学[D].福州大学博士学位论文, 2001, pp: 59 ~ 72.
[98]卢勇.某些大环平面型金属有机配合物的结构化学和非线性光学性质研究[D].华侨大学硕士学位论文, 2006, pp: 43 ~ 49.
[99] Blatt G., Oragnic Syntheses Collective [M], New York: Wiley, 1951, Vol III, pp: 79 ~ 80.
[100]吴文士,程文旦,吴东升,张浩,龚亚京,施立新.一种二阶非线性激光晶体4-硝基-2-吡啶甲酸-1-氧及其制备方法,公开号:CN 1814591A,中华人民共和国知识产权局, 2006-8-25, 22卷(32期).
[101]吴文士,戴劲草,林建明,一种二阶非线性激光晶体4-硝基-N-氧-2-吡啶甲酸二代晶体及其生长方法和用途,申请号: CN 200710008940.5,中华人民共和国知识产权局, 2007-5-9.
[102] Wu W S, W D S, Cheng W D, Zhang H, Dai J C, Syntheses, Crystal Growths, and Nonlinear Optical Properties for 2-Carboxylic acid-4-nitropyridine-1-oxide Crystals with Two Different Arrangements of Chromophores, Crystal Growth and Design, Vol. xxx, No. xx, XXXX, Published on Web 10/18/2007.
[103] Blatt. A. H., Org. Syn. [M], 1943, Vol 10-19, pp: 67 ~ 68.
[104]吴文士,陈静,戴劲草,林建明,兰心仁,黄婷婷. N-皮考林酰肼及其双核钯配合物的晶体结构和荧光性质[J].化学学报, 2005,63(21): 1967 ~ 1973.
[105]吴文士,刘世雄.丙酰皮考林酰肼(C9H11N3O2)的合成和晶体结构[J],结构化学,2003,20(3): 226 ~ 228.
[106]吴文士,刘世雄,黄尊行.含N-乙酰皮考啉肼的锌和钒配合物的晶体结构及其激光倍频性质[J],应用化学, 2003, 20(2): 138 ~ 143.
[107]陈小明,蔡继文.单晶结构分析原理与实践[M],科学出版社,2003,pp: 115.
[108]吴文士,董美斌,李宋贤. ZnCl2和POM的合成和结构[J],华侨大学学报(自然科学版), 1996, 17(2): 136 ~ 139.
[109] Li H P, Wu W S, Yang G D and Liu G X. Pyridine-2,4-dicarboxylic acid-N-oxide [J]. Acta Cryst. 2007, E63, o3950.
[110]于青. N-氧化吡啶类席夫碱配合物的合成、晶体结构及谱学表征[D].广西师范大学硕士学位论文, 2000, pp: 5.
[111]李润卿.有机结构波谱分析[M],天津大学出版社, 2002, pp:5 ~ 134.
[112]谢晶曦,常俊标,王绪明.红外光谱在有机化学和药物化学中的应用(修订版) [M],科学出版社, 2001, pp: 79 ~ 329.
[113]蔡正千.差热分析[M],高等教育出版社, 1993, pp: 34 ~ 131.
[114]李余增.热分析[M],清华大学出版社, 1987, pp: 12 ~ 311.
[115]夏锦尧.实用荧光分析法[M],中国人民公安大学出版社, 1992, pp: 349.
[116] Li S X, Wu W S, et al., Frequency Doubling in some Benzenedirevative Molecular Crystal, Chinese Physics LASERS, a Publication of the America Institute of Physics and the Optical society of America, 1988, 791 ~ 795.
[117]刑其毅,徐瑞秋,周政,裴伟伟.基础有机化学(第二版) [M],高等教育出版社,2003, pp: 900 ~ 901.
[118] J. A.焦耳, K.米尔斯,杂化化学[M],科学出版社,pp: 83.
[119] T.艾歇尔, S.豪普特曼,杂化化学-结构、反应、合成与应用[M],化学工业出版社, pp: 241.
[2] Karakas A, Elmali A, Unver H, Svoboda I. Nonlinear optical properties, synthesis, structures and spectroscopic studies of N-(4-nitrobenzylidene)-o-fluoroamine and N-(3-nitrobenzylidene)-p-fluoroamine [J]. Spectro. Acta Part A, 2005, 61(13-14): 2979 ~ 2987.
[3] Benjamin J. C. Switchable nonlinear optical metallochromophores with pyridinium electron acceptor groups [J]. Acc. Chem. Res., 2006, 245: 386 ~ 389.
[4] Rajarajan K, Selvakumar S, Joseph G P, Potheher I V, Mohamed M G, Sagayaraj P. Growth, dielectric and photoconducting studies of tetrathiourea mercury(II) tetrathiocyanato zinc(II) NLO single crystals [J]. J. Crystal Growth, 2006, 286(2): 470 ~ 475.
[5] Oertel U, Dudkina M M, Komber H, Pilch B, Tenkovtsev A V, Bohme F. A spectroscopic study on the dissociation behavior of 4-hydroxybenzylideneacetone type NLO chromophores in the presence of sodium hydroxide [J]. Optical Mater., 2005: 1 ~ 9.
[6] de Silva I C, de Silva R M, de Silva K M N. Investigations of nonlinear optical (NLO) properties of Fe, Ru and Os organometallic complexes using high accuracy density functional theory (DFT) calculations [J]. J. Mole. Struct.: THEOCHEM, 2005, 728(1-3): 141 ~ 145.
[7] Cifuentes M P, Humphrey M G. Alkynyl compounds and nonlinear optics [J]. J. Organ. Chem., 2004, 689: 3968 ~ 3981.
[8] Zyss J , Ledoux I. Through2space charge transfer and non-linear optical properties of substituted paracyclophane [J]. J Am Chem Soc, 2000, 122(48): 11956 ~ 11962.
[9] Denning R G. New optics ( new materials) [J]. J Mater Chem, 2001, 11:19 ~ 28.
[10] Delaire J A , Keitaro Nakatani. Linear and nonlinear optical properties of photochromicmolecules and materials [J]. Chem Rev, 2000, 100: 1817 ~ 1845.
[11] Burland D M. Optical nonlinearities in chemistry Introduction [J]. Chem Rev, 1994, 94: 1 ~ 2.
[12] Taki M, Wolford J L. Emission ratiometric imaging of intracellular zinc , Design of abenzoxazole fluorescent sensor and its application in two2photon microscopy [J]. J Am Chem Soc, 2004, 126(3): 712 ~ 713.
[13] Stricker J H, Webb W W. Three-dimensional optical data storage in refractive media by two photon point excitation [J]. Opt Commun, 1991, 16: 1780 ~ 1784.
[14] Fisher A M R, Murphree A L, Gomer C J, et al. Clinical and preclinical photodynamic therapy [J]. 1995, Laser Surg Med, 17: 2 ~ 7.
[15] Belfield KD , Ren X. Near2IR two2photon photoinitiated polymerization using a fluorone/amine initiating system [J]. J Am Chem Soc, 2000, 122(6): 1217 ~ 1218.
[16] Perry J W, Mansour K, Lee I Y S, et al . Organic optical limiter with a st rong nonlinear absorptive response [J] . Science, 1998, 273: 1533 ~ 1536.
[17] Seth R. Marder, Organic nonlinear optical materials: where we have been and where we are going [J], Chem. Commun., 2006, 131–134.
[18]张克从,王希敏.非线性光学晶体材料科学(第一版) [M].北京:科学出版社, 1996, pp. 54 ~ 84.
[19]常新安,陈丹,臧和贵,张玮.非线性光学晶体的研究进展[J],人工晶体学报, 2007, 36(1): 327 ~ 333.
[20] Kurtz S K, Pery T T, A Powder Technique For The Evaluation Of Nonlinear Optical Materials [J], J Appl Phys, 1968, 39: 3798.
[21] Jiang H, Kakkar A K. An alternative route based on acid-base hydrolytic chemistry to NLO active organic-inorganic hybrid materials for second-order nonlinear optics [J]. J. Am. Chem. Soc., 1999, 121(15): 3657 ~ 3665.
[22]高允贵.用于深紫外光源的非线性光学材料[J].光电子技术与信息, 1999, 12(1): 23 ~ 26.
[23]崔元靖.无机-有机杂化二阶韭线性光学材料的设计、合成与性能研究[D],浙江大学博士学位论文, 2005, pp: 4 ~ 33.
[24]王传明.有机非线性光学材料的分子设计[D].南京理工大学硕士学位论文, 2004, pp: 10.
[25] Carlo D C, Alessandro F M, Massimiliano L, Paolo C B, Luisa P, Franco B, Luisa S, Adele M, Mauro C, Felice S, Alessia Q. Preparation and characterization of thiophene copolymers with second order non-linear optical properties [J]. J. European Polymer, 2005, 41(10): 2360 ~ 2369.
[26] Ishow E, Bellaiche C, Bouteiller L, Nakatani K, Delaire J A. Versatile synthesis of small NLO-active molecules forming amorphous materials with spontaneous second-orderNLO response [J]. J. Am. Chem. Soc., 2003, 125(51): 15744 ~ 15745.
[27] Selvakumar S, Rajasekar S A, Thamizharasan K, Sivanesan S, Ramanand A, Sagayaraj P. Thermal, dielectric and photoconductivity studies on pure, Mg2+ and Zn2+ doped BTCC single crystals [J]. Mater. Chem. Phys., 2005, 93(2-3): 356 ~ 360.
[28] Zhang F, Prosenc M H, Heck J. Synthesis and characterization of dinuclear monohydro sesquifulvalene complexes with potential NLO properties [J]. J. Organ. Chem., 2006, 691(3): 455 ~ 462.
[29] Anand D P, Mohamed M G, Pajasekar S A, Selvakumar S, Pragasam A J A, Sagayaraj P. Growth and characterization of pure, benzophenone and iodine doped benzoyl glycine single crystals [J]. Mater. Chem. Phys., 2006, 97(2-3): 501 ~ 505.
[30]祁楠,陈兴,程侣伯.有机非线性光学材料的进展[J].精细化工, 1994, (11): 20 ~ 28.
[31]蔺彬彬,仇永清,苏忠民,孙世玲,封继康.水杨醛缩苯胺类席夫碱构象异构体的稳定及其非线性光学性质的理论研究[J].高等学校化学学报, 2001, 22(9): 1551 ~ 1554.
[32]姜有昌,刘景芳,颜力揩,兰亚乾,赵雅辉.二联吡啶及其二氮取代衍生物电子性质和非线性光学性质的理论研究[J].分子科学学报, 2004, 20(1): 12 ~ 15.
[33]袁跃华,田茂忠,郭永,孟双明.二阶非线性光学聚酰亚胺材料的研究进展[J].雁北师范学院学报, 2004, 20(5): 23 ~ 25.
[34] Zhe xiong Tang , Malkiat S. Johal, Paul Scudder, Ni?a Caculitan, Rudolph J. Magyar, Sergei Tretiak, Hsing-Lin Wang. Study of the non-covalent interactions in Langmuir-lodgett films: An interplay betweenπ?πand dipole-ipole interactions[J]. Thin Solid Films, 2007, 516: 58 ~ 66.
[35]王晓鸥,李俊庆,郑仰东,辛丽,李淳飞.手性分子介质非线性光学研究新进展[J].物理, 2004, 33(8): 574 ~ 578.
[36] Anne M K, Weinan L, Mireille B D. Resonance hyper-raman scattering from conjugated organic donor-acceptor“push-pull”chromophores with large first hyperpolarizabilities [J]. J. Am. Chem. Soc., 2003, 125: 10520 ~ 10521.
[37] Annoni E, Pizzotti M, Ugo R, Quici S, Morotti T, Casati N, Macchi P. The effect on E-silbazoles second order NLO response by axial interaction with M(II) 5,10,15,20-tetraphenyl porphyrinates (M=Zn, Ru, Os); a new crystalline packing with very large holes [J]. Inorg. Chim. Acta, 2006, 359(9): 3029 ~ 3041.
[38] Manuela M, Raposo M A, Sousa M R C, Kirsch G, Ferreira F, Belsley M, de Matos G E,Mauricio A, Fonseca C. Synthesis of tricyanovinyl-subsitituted thienylpyrroles and characterization of the solvatochromic, electrochemical and non-linear optical properties [J]. Tetrahedron, 2005, 61(50): 11991 ~ 11998.
[39] Cariati E, Pizzotti M, Roberto D, Tessore F, Ugo R. Coordination and organometallic compounds and inorganic-organic hybrid crystalline materials for second-order non-linear optics [J]. Coordi. Chem. Rev., 2005, 1 ~ 24.
[40]李辉,徐伯华,谢军揩,毕剑.系列推拉取代基1, 3, 5-己三烯的非线性光学性质的理论研究[J].四川师范大学学报(自然科学版), 2002, 25(1): 56 ~ 58.
[41]向继明,谢周,英柏宁. 5-芳胺-6-氯-2, 3-二氰吡嗪[J].有机化学, 1997, 10(5): 427 ~ 431.
[42]赵雷,常俊丽,王世敏.有机二阶非线性光学分子设计和合成研究进展[J].湖北大学学报(自然科学版), 1999, 21(2): 197 ~ 204.
[43] Marder S R, Goman C B. Stronger acceptors can diminish nonlinear optical response in simple Donor-Acceptor Polyense [J]. J. Am. Chem. Soc., 1993, 115: 3006 ~ 3007.
[44]阚玉和.二氰基三维苯多烯共轭化合物电子光谱及非线性光学性质的INDO/SOS研究[J].东北师大学报自然科学版, 2004, 36(3): 61 ~ 65.
[45]刘永军,刘英,赵显,刘成卜.氮杂联苯乙烯系列衍生物的二阶非线性光学性质的理论研究[J].高等学校化学学报, 2001, 22(6): 1016 ~ 1018.
[46]刘英,刘永军.氮杂联苯乙烯系列衍生物的二阶非线性光学性质的理论研究[J].曲阜师范大学学报, 2001, 27(2): 71 ~ 74.
[47]杨彦杰,苏忠民.硝基取代亚酞菁衍生物的电子光谱和非线性光学性质的理论研究[J].高等学校化学学报, 2005, 26(3): 467 ~ 470.
[48] Pushkara R V, Alex K Y J, Chandrasekhar J, Namboothiri I N N, Rathna A. The important role of heteroaromatics in the design of efficient second-order nonlinear optical molecules: theoretical investigation on push-pull heteroaromatic stilbenes [J]. J. Am. Chem. Soc., 1996, 118: 12443 ~ 12448.
[49] Tian X H, Ru W, Zhong J H, Lin J P, Li Ch Y, Luo X L. Structures and calculated NLO properties of (acenaphthylene) and (acenaphthene)Cr(CO)3 [J]. Chem. Phys., 2006, 324(2-3): 667 ~ 673.
[50]王文军,张山彪,李淑红,刘云龙,王立英,王恭明,王文澄.中心对称萘酞菁分子二次谐波产生的实验研究[J].光子学报, 2004, 33(4): 489 ~ 493.
[51]赵成大,固体量子化学[M],高等教育出版社, 1997,pp: 327 ~ 328.
[52] Albert I D L, Marks T J , M. A. Ratner, Large Molecular Hyperpolarizabilities. Quantitative Analysis of Aromaticity and Auxiliary Donor-Acceptor Effects,J.Am.Chem.Soc., 1997, 119: 6575 ~ 6582。
[53]王大文,叶成,赵建良,白春礼.有机非线性光学晶体NPP的AFM研究[J].物理化学学报, 1994, 10(2): 172 ~ 174.
[54]吴芸,赵波,吴迪,周志华.盐酸氨基脲的二阶非线性光学性质研究[J].化学研究与应用, 2004, 16(1): 111 ~ 112.
[55]赵波,周志华. 2H-苯并吡喃-2-酮类化合物分子二阶非线性光学性质的理论研究[J].南京晓庄学院学报, 2004, 20(4): 28 ~ 32.
[56] Ihara R, Honma T, Benino Y, Fujiwara T, Komatsu T. Second-order optical nonlinearities of metastable BiBO3 phases in crystallized glasses [J]. Optic. Mater., 2004, 27(3): 403 ~ 408.
[57] Marks T J, Ratner M A. Design, synthesis, and properties of molecule-based assemblies with large 2nd-order optical nonlinearities [J]. Angew. Chem. Int. Edit., 1995, 34(2): 155 ~ 173.
[58] Verbiest T, Houbrechts S, Kanranen M. Second-order nonlinear materials:recen advances in chromophore design [J]. J. Mater. Chem., 1997, 7(11): 2175 ~ 2189.
[59] Dewar M J S, Zoebisch E G, Healy E F. AM1: a new general purpose quantum mechanical molecular model [J]. J. Am. Chem. Soc., 1985, 107(13): 3902 ~ 3909.
[60]花建丽,李俊,罗敬东,秦金贵.兼具大的二阶非线性与良好透明性的有机生死团的分子设计进展[J].有机化学, 2003, 23(1): 44 ~ 53.
[61] Alain V, Redoglia S, Blandchard D M, Lebus S, Lukaszuk K, Wortmann R, Gubler U, Bosshard C, Gunter P. Elongated push–pull diphenylpolyenes for nonlinear optics: molecular engineering of quadratic and cubic optical nonlinearities via tuning of intramolecular charge transfer [J]. Chem. Phys. 1999, 245(1-3): 51 ~ 57.
[62]赵波,仇立干,费正皓. 4-溴查耳酮的二阶非线性光学性质研究[J].南京师大学报(自然科学版), 2000, 23: 67 ~ 70.
[63]吴迪,赵波,周志华. 1-(4-溴苯基)-5-苯基-2,4-戊二烯-1-酮的二阶非线性光学性质研究[J].南京师大学报(自然科学版), 2004, 27: 55 ~ 60.
[64] Wang S M, Zhao L, Xu Z X, Wu C H, Chen S Y. Novel nonlinearity-transparency-thermal stability trade-off of imidazole chromophores for nonlinear optical application [J]. Mater. Letters, 2002, 56: 1035 ~ 1038.
[65] Gilmour S, Montgomery R A, Marder S R, Cheng L T, Jen A K Y, Cai Y-M, Perry J W, Dalton L R. Synthesis of diarylthiobarbituric acid chromophores with enhanced second-order optical nonlinearities and thermal stabilities [J]. Chem. Mater., 1994, 6: 1603 ~ 1604.
[66] Chen C T, Marder S R, Cheng L T. Syntheses and linear and nonlinear optical properties of unsymmetrical squaraines with extended conjugation [J]. J. Am. Chem. Soc., 1994, 116: 3117 ~ 3118.
[67] Yang M L, Sun Z M, Yan G S. An Ab initio study on nonlinear optical properties of squarates [J]. Acta Chin. Sinica, 1999, 57(7): 754 ~ 759.
[68]孙世玲,苏忠民,阚玉和,陈丽华,朱玉兰,任爱民,封继康.含1,3-方酸苯螺旋共轭分子的设计及其电子光谱和非线性光学性质的理论研究[J].高等学校化学学报, 2002, 23(1): 105 ~ 108.
[69] Lee J Y, Bang H B, Baek C S. Synthesis and nonlinear optical properties of novel T-type polyurethanes with high thermal stability of second harmonic generation [J]. Synthetic Metals, 2005, 148: 161 ~ 168.
[70]赵波,卢文庆,吴芸.一种激光倍频新材料-间羟基苯甲酸的初步研究[J].高等学校化学学报, 2000, 21(4): 620 ~ 622.
[71]钱鹰,肖国民,林保平,薛静,袁春伟.双羟乙氨基-硝基型偶氮[J].精细化工, 2005, 22(11): 823 ~ 826.
[72] Qian Y, Lin B P, Xiao G M, Li H H, Yuan C W. Chromophores exhibiting nonlinearity-transparency-thermal stability trade-off: synthesis and nonlinear optical properties of two-dimensinal chromophores containing nitro acceptors [J]. Optical Mater., 2004, 27(1): 125 ~ 130.
[73]祝阳,杨芳,杨济活.酞菁氧钛/咔唑化合物的合成与其二阶非线性光学性能的研究[J].精细化工, 2004, 21(12): 890 ~ 893.
[74]谭克.甲氧基苯基偶氮衍生物电子结构与二阶NLO性质的HF/FF方法研究[J].分子科学学报, 2005, 21(2): 21 ~ 25.
[75]谭克,杨国春,杨贵福,李波.螺旋双芴体系二阶非线性光学性质的ZINDO-SOS理论研究[J].分子科学学报, 2005, 21(2): 17 ~ 20.
[76] Frazier C C, Harvey M A, Cockerham M P, Hand H M, Chauchard E A, Lee Chi H. Second-harmonic generation in transition-metal-organic compounds [J]. J. Phys. Chem., 1986, 90(22): 5703 ~ 5706.
[77] Santo D B, Ignazio F. Two-dimensional characteristics of the second-order nonlinear optical response in dipolar donor–acceptor coordination complexes [J]. New J. Chem., 2002, 26: 285 ~ 290.
[78] Qin J G, Liu D Y, Dai C Y, Chen C C, Wu B C, Yang C L, Zhan C M. Influence of the molecular configuration on second-order nonlinear optical properties of coordination compounds [J]. Coord. Chem. Rev., 1999, 188(1): 23 ~ 34.
[79] Tam W., Calavrese, J.C. Oxidative addition of Pd(0) and Pt(0) with aromatic halides: Material for second-harmonic generation [J]. Chem. Phys. Lett., 1988, 144(1): 79 ~ 82.
[80] Norman P, Cronstrand P, Ericsson J. Theoretical study of linear and nonlinear absorption in platinum-organic compounds [J]. Chem. Phys., 2002, 285(2-3): 207 ~ 220.
[81]洪涛,吴克琛,莽朝永,林晨升,张明昕,韦永勤,刘彩萍,周张锋,庄伯涛.含Pt配合物电子结构和非线性光学性质TDDTFT研究[J].结构化学, 2004, 23(7): 788 ~ 792.
[82] Nalwa S H. Third-order nonlinear optical properties of pyridine- and ferrocene-containing polyazines [J]. Mater. Lett., 1997, 33(1-2): 23 ~ 26.
[83]蒋伟春,浦鸿汀,李新碗,陈建平.二阶非线性光学聚合物材料的最新研究进展[J].高分子通报, 2004, (5): 28 ~ 38.
[84] Williams D J. Organic polymeric and non-polymeric materials with large optical nonlinearities [J]. Angew. Chem. Int. Ed. Engl., 1984, 23(9): 690 ~ 703.
[85] Zhu X-L, You X-Z, Zhang Y. A novel approach to calculation of the second-order nonlinear optical susceptibilities of organic crystals based on energy-band theory [J]. Chem. Phys., 2000, 254(2-3): 287 ~ 296.
[86]苏忠民,封继康,张锁秦,任爱民,孙家钟.吡啶及其-NH2, -NO2单双取代衍生物的非线性光学性质的理论研究[J].分子科学学报, 1999, 15(4): 232 ~ 237.
[87]苏忠民,封继康,任爱民,张锁秦,孙家锺.用有限场和耦合微扰方法N-氧化吡啶及其-NH2, -NO2单双取代衍生物非线性光学性质的研究[J].高等学校化学学报, 2000, 21(4): 590 ~ 595.
[88] Zyss J, Chemla D S. Demonstration of efficient nonlinear optical crystals with vanishing molecular dipole moment: Second-harmoin generation in 3-methyl-4-nitropyridine-1-oxide [J]. J. Chem. Phys., 1981, 74(9): 4800 ~ 4811.
[89] Li S X, Liu S X, Wu W S. Sythesis, structure and some physical properties of 2-methyl-4- nitropyridine-1-oxide [J]. J. Struct. Chem., 1987, 6(1): 20 ~ 25.
[90] Boomadevi S, Mittal H P, Dhansekaran R. Synthesis, crystal growth andcharacterization of 3-methyl-4-nitropyridine-1-oxide(POM) single crystals [J]. J. Crystal Growth, 2004, 261: 55 ~ 62.
[91] Maxime G, Edith B, Benoi C. Theoretical investigation of the linear and second-order nonlinear susceptibilities of the 3-methyl-4-nitropyridine-1-oxyde(POM) crystal [J]. J. chem. Phys., 2004, 121(15): 7390 ~ 7400.
[92]陈静. POA相关化合物的合成、结构与非线性光学性质研究[D].华侨大学硕士学位论文, 2006, pp: 30 ~ 60.
[93] Jean Pierre Costes, Ghenadie Novitchi, Sergiu Shova, Francüoise Dahan, Bruno Donnadieu, and Jean-Pierre Tuchagues. Synthesis, Structure, and Magnetic Properties of Heterometallic Dicyanamide-Bridged Cu-Na and Cu-Gd One-Dimensional Polymers [J]. Inorg. Chem., 2004, 43(24): 7792 ~ 7799.
[94] Rajesh Koner, Hsin-Huang Lin, Ho-Hsiang Wei, and Sasankasekhar Mohanta, Syntheses, Structures, and Magnetic Properties of Diphenoxo-Bridged MIILnIII Complexes Derived from N,N’-Ethylenebis(3-ethoxysalicylaldiimine) (M =Cu or Ni; Ln=Ce-Yb): Observation of Surprisingly Strong Exchange Interactions [J], Inorg. Chem., 2005, 44(24): 3524 ~ 3536.
[95] Christian Lorber, Robert Choukroun, and Laure Vendier. A General and Facile One-Step Synthesis of Imido-Titanium(IV) Complexes: Application to the Synthesis of Compounds Containing Functionalized or Chiral Imido Ligands and Bimetallic Diimido Architectures [J], Eur. J. Inorg. Chem. 2006, 4503 ~ 4518.
[96] Ann J. Stemmler, Jeff W. Kampf, Martin L. Kirk, Bassel H. Atasi, and Vincent L. Pecoraro. The Preparation, Characterization, and Magnetism of Copper 15-Metallacrown-5 Lanthanide Complexes [J], Inorg. Chem. 1999, 38(12), 2807 ~ 2817.
[97]吴文士.含皮考林酰肼和皮考林羟肟酸配合物的结构化学[D].福州大学博士学位论文, 2001, pp: 59 ~ 72.
[98]卢勇.某些大环平面型金属有机配合物的结构化学和非线性光学性质研究[D].华侨大学硕士学位论文, 2006, pp: 43 ~ 49.
[99] Blatt G., Oragnic Syntheses Collective [M], New York: Wiley, 1951, Vol III, pp: 79 ~ 80.
[100]吴文士,程文旦,吴东升,张浩,龚亚京,施立新.一种二阶非线性激光晶体4-硝基-2-吡啶甲酸-1-氧及其制备方法,公开号:CN 1814591A,中华人民共和国知识产权局, 2006-8-25, 22卷(32期).
[101]吴文士,戴劲草,林建明,一种二阶非线性激光晶体4-硝基-N-氧-2-吡啶甲酸二代晶体及其生长方法和用途,申请号: CN 200710008940.5,中华人民共和国知识产权局, 2007-5-9.
[102] Wu W S, W D S, Cheng W D, Zhang H, Dai J C, Syntheses, Crystal Growths, and Nonlinear Optical Properties for 2-Carboxylic acid-4-nitropyridine-1-oxide Crystals with Two Different Arrangements of Chromophores, Crystal Growth and Design, Vol. xxx, No. xx, XXXX, Published on Web 10/18/2007.
[103] Blatt. A. H., Org. Syn. [M], 1943, Vol 10-19, pp: 67 ~ 68.
[104]吴文士,陈静,戴劲草,林建明,兰心仁,黄婷婷. N-皮考林酰肼及其双核钯配合物的晶体结构和荧光性质[J].化学学报, 2005,63(21): 1967 ~ 1973.
[105]吴文士,刘世雄.丙酰皮考林酰肼(C9H11N3O2)的合成和晶体结构[J],结构化学,2003,20(3): 226 ~ 228.
[106]吴文士,刘世雄,黄尊行.含N-乙酰皮考啉肼的锌和钒配合物的晶体结构及其激光倍频性质[J],应用化学, 2003, 20(2): 138 ~ 143.
[107]陈小明,蔡继文.单晶结构分析原理与实践[M],科学出版社,2003,pp: 115.
[108]吴文士,董美斌,李宋贤. ZnCl2和POM的合成和结构[J],华侨大学学报(自然科学版), 1996, 17(2): 136 ~ 139.
[109] Li H P, Wu W S, Yang G D and Liu G X. Pyridine-2,4-dicarboxylic acid-N-oxide [J]. Acta Cryst. 2007, E63, o3950.
[110]于青. N-氧化吡啶类席夫碱配合物的合成、晶体结构及谱学表征[D].广西师范大学硕士学位论文, 2000, pp: 5.
[111]李润卿.有机结构波谱分析[M],天津大学出版社, 2002, pp:5 ~ 134.
[112]谢晶曦,常俊标,王绪明.红外光谱在有机化学和药物化学中的应用(修订版) [M],科学出版社, 2001, pp: 79 ~ 329.
[113]蔡正千.差热分析[M],高等教育出版社, 1993, pp: 34 ~ 131.
[114]李余增.热分析[M],清华大学出版社, 1987, pp: 12 ~ 311.
[115]夏锦尧.实用荧光分析法[M],中国人民公安大学出版社, 1992, pp: 349.
[116] Li S X, Wu W S, et al., Frequency Doubling in some Benzenedirevative Molecular Crystal, Chinese Physics LASERS, a Publication of the America Institute of Physics and the Optical society of America, 1988, 791 ~ 795.
[117]刑其毅,徐瑞秋,周政,裴伟伟.基础有机化学(第二版) [M],高等教育出版社,2003, pp: 900 ~ 901.
[118] J. A.焦耳, K.米尔斯,杂化化学[M],科学出版社,pp: 83.
[119] T.艾歇尔, S.豪普特曼,杂化化学-结构、反应、合成与应用[M],化学工业出版社, pp: 241.