不同源挥发性有机物生成二次有机气溶胶的研究进展
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摘要
总结了近几年典型VOCs氧化生成二次有机气溶胶(SOA)的影响因子(大气氧化剂、湿度及种子气溶胶等),从生物源和人为源2个方面,总结了单萜烯类、异戊二烯、芳香烃及小分子有机物等转化为SOA的研究进展。最后,对实验室模拟SOA形成机制及化学成分研究的不足提出展望。
The factors affecting the formation of secondary organic aerosol( SOA) by oxidation of typical VOCs in recent years are summarized,including atmospheric oxidant,humidity,seed aerosol,etc.. From aspects of biological and man-made sources,the advances in the conversion of monoterpenes,isoprene,aromatic hydrocarbons and small molecular organic compounds into SOA are reviewed. The shortcomings of the research on the formation mechanism and chemical composition of simulated SOA in laboratory are prospected.
The factors affecting the formation of secondary organic aerosol( SOA) by oxidation of typical VOCs in recent years are summarized,including atmospheric oxidant,humidity,seed aerosol,etc.. From aspects of biological and man-made sources,the advances in the conversion of monoterpenes,isoprene,aromatic hydrocarbons and small molecular organic compounds into SOA are reviewed. The shortcomings of the research on the formation mechanism and chemical composition of simulated SOA in laboratory are prospected.
引文
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[25]Liu S,Jiang X,Narcisse T,et al.Effects of NOx,SO2and RH on the SOA formation from cyclohexene photooxidation[J]. Chemosphere,2019,216:794-804.
[26]Miracolo M A,Presto A A,Lambe A T,et al.Photo-oxidation of lowvolatility organics found in motor vehicle emissions:Production and chemical evolution of organic aerosol mass[J]. Environmental Science&Technology,2010,44(5):1638-1643.
[27]Jathar S H,Miracolo M A,Tkacik D S,et al. Secondary organic aerosol formation from photo-oxidation of unburned fuel:Experimental results and implications for aerosol formation from combustion emissions[J]. Environmental Science&Technology,2013,47(22):12886-12893.
[28]Loza C L,Craven J S,Yee L D,et al. Secondary organic aerosol yields of 12-carbon alkanes[J]. Atmospheric Chemistry&Physics Discussions,2014,13(8):1423-1439.
[29]Lim Y B,Ziemann P J. Effects of molecular structure on aerosol yields from OH radical-initiated reactions of linear,branched,and cyclic alkanes in the presence of NOx[J].Environmental Science&Technology,2009,43(7):2328-2334.
[30]Presto A A,Miracolo M A,Kroll J H,et al.Intermediate-volatility organic compounds:A potential source of ambient oxidized organic aerosol[J]. Environmental Science&Technology,2009,43(13):4744-4749.
[2]Li J,Zhang M,Wu F,et al.Assessment of the impacts of aromatic VOC emissions and yields of SOA on SOA concentrations with the air quality model RAMS-CMAQ[J]. Atmospheric Environment,2017,158:105-115.
[3]Guenther A B,Jiang X,Heald C L,et al.The Model of emissions of gases and aerosols from nature version 2. 1(MEGAN2. 1):An extended and updated framework for modeling biogenic emissions[J].Geoscientific Model Development Discussions,2012,5(2):1503-1560.
[4]Nah T.Photochemical aging ofα-pinene andβ-pinene secondary organic aerosol formed from nitrate radical oxidation:New insights into the formation and fates of highly oxygenated gas-and particlephase organic nitrates[J]. Environmental Science&Technology,2016,50(1):222-231.
[5]Denjean C,Formenti P,Picquet-Varrault B,et al. Relating hygroscopicity and optical properties to chemical composition and structure of secondary organic aerosol particles generated from the ozonolysis ofα-pinene[J]. Atmospheric Chemistry and Physics,2015,15(6):3339-3358.
[6]Liu Y,Huang L,Li S M,et al.OH-initiated heterogeneous oxidation of tris-2-butoxyethyl phosphate:Implications for its fate in the atmosphere[J].Atmospheric Chemistry and Physics,2014,14(22):12195-12207.
[7]Slade J H,Knopf D A.Multiphase OH oxidation kinetics of organic aerosol:The role of particle phase state and relative humidity[J].Geophysical Research Letters,2014,41(14):5297-5306.
[8]Song C,Zaveri R A,Shilling J E,et al.Effect of hydrophilic organic seed aerosols on secondary organic aerosol formation from ozonolysis ofα-Pinene[J]. Environmental Science&Technology,2011,45(17):7323-7329.
[9]Wang N,Kostenidou E,Donahue N M,et al.Multi-generation chemical aging ofα-pinene ozonolysis products by reactions with OH[J]. Atmospheric Chemistry and Physics,2018,18(5):3589-3601.
[10]Carlton A G,Wiedinmyer C,Kroll J H. A review of secondary organic aerosol(SOA)formation from isoprene[J]. Atmospheric Chemistry and Physics,2009,9(14):4987-5005.
[11]Yin H,Yuan H,Ye Z,et al. Temporal and spatial distribution of VOCs and their OFP in the atmosphere of Chengdu[J].Acta Scientiae Circumstantiae,2015,35(2):386-393.
[12]Kamens R M,Zhang H,Chen E H,et al.Secondary organic aerosol formation from toluene in an atmospheric hydrocarbon mixture:Water and particle seed effects[J]. Atmospheric Environment,2011,45(13):2324-2334.
[13]Beardsley R,Jang M,Ori B,et al.Role of sea salt aerosols in the formation of aromatic secondary organic aerosol:Yields and hygroscopic properties[J].Environmental Chemistry,2013,10(3):167-177.
[14]Jia L,Xu Y. Ozone and secondary organic aerosol formation from ethylene-NOx-Na Cl irradiations under different relative humidity conditions[J]. Journal of Atmospheric Chemistry,2016,73(1):81-100.
[15]George C, Ammann M, D'Anna B, et al. Heterogeneous photochemistry in the atmosphere[J].Chemical Reviews,2015,115(10):4218-4258.
[16]Huang M,Lin Y,Huang X,et al.Experimental study of particulate products for aging of 1,3,5-trimethylbenzene secondary organic aerosol[J]. Atmospheric Pollution Research,2015,6(2):209-219.
[17]Ge S,Xu Y,Jia L.Secondary organic aerosol formation from ethyne in the presence of Na Cl in a smog chamber[J]. Environmental Chemistry,2016,13(4):699-710.
[18]Ge S,Xu Y,Jia L.Secondary organic aerosol formation from propylene irradiations in a chamber study[J].Atmospheric Environment,2017,157:146-155.
[19]何方辉.VOCs向PM2.5转化机理研究[D].石家庄:河北科技大学,2015.
[20]Ge S,Xu Y,Jia L.Effects of inorganic seeds on secondary organic aerosol formation from photochemical oxidation of acetone in a chamber[J].Atmospheric Environment,2017,170:205-215.
[21]田淼.乙酸乙酯-臭氧光氧化向二次有机气溶胶(SOA)转化的研究[D].石家庄:河北科技大学,2016.
[22]王姗姗.挥发性有机物1,3-丁二烯向二次有机气溶胶转化特性研究[D].石家庄:河北科技大学,2016.
[23]Carlsson P T,Dege J E,Keunecke C,et al. Pressure dependent aerosol formation from the cyclohexene gas-phase ozonolysis in the presence and absence of sulfur dioxide:A new perspective on the stabilisation of the initial clusters[J].Physical Chemistry Chemical Physics,2012,14(33):11695-11705.
[24]Liu S,Jia L,Xu Y,et al.Photooxidation of cyclohexene in the presence of SO2:SOA yield and chemical composition[J].Atmospheric Chemistry&Physics,2017,17(21):13329-13343.
[25]Liu S,Jiang X,Narcisse T,et al.Effects of NOx,SO2and RH on the SOA formation from cyclohexene photooxidation[J]. Chemosphere,2019,216:794-804.
[26]Miracolo M A,Presto A A,Lambe A T,et al.Photo-oxidation of lowvolatility organics found in motor vehicle emissions:Production and chemical evolution of organic aerosol mass[J]. Environmental Science&Technology,2010,44(5):1638-1643.
[27]Jathar S H,Miracolo M A,Tkacik D S,et al. Secondary organic aerosol formation from photo-oxidation of unburned fuel:Experimental results and implications for aerosol formation from combustion emissions[J]. Environmental Science&Technology,2013,47(22):12886-12893.
[28]Loza C L,Craven J S,Yee L D,et al. Secondary organic aerosol yields of 12-carbon alkanes[J]. Atmospheric Chemistry&Physics Discussions,2014,13(8):1423-1439.
[29]Lim Y B,Ziemann P J. Effects of molecular structure on aerosol yields from OH radical-initiated reactions of linear,branched,and cyclic alkanes in the presence of NOx[J].Environmental Science&Technology,2009,43(7):2328-2334.
[30]Presto A A,Miracolo M A,Kroll J H,et al.Intermediate-volatility organic compounds:A potential source of ambient oxidized organic aerosol[J]. Environmental Science&Technology,2009,43(13):4744-4749.