燃气热脱附技术修复有机污染场地研究与应用进展
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摘要
原位燃气热脱附是目前修复有机污染土壤最具潜力的技术之一。在查阅文献的基础上,结合国内外实际案例,系统梳理了有机污染土壤原位燃气热脱附修复技术的原理、适用范围、优缺点以及工艺施工流程,对国内外燃气热脱附技术的研究现状和工程应用情况进行了对比分析,并对该技术的发展趋势和应用前景进行了展望,以期为我国有机污染土壤原位热修复技术的推广和应用提供参考。
In situ gas thermal desorption(GTD) is one of the most promising technologies for the remediation of organic contaminated soil. Based on extensive literature review and worldwide practical cases analysis, this paper systematically reviewed the fundamental principle, application scope, advantages and disadvantages, and construction procedures of the GTD technology, and systematically compared and analyzed the current status of research and engineering application cases of GTD technology at home and abroad. Then the development trend and application prospect of this technology in China were also proposed. It is expected to provide beneficial information for in situ thermal treatment of organic contaminated soil in China.
In situ gas thermal desorption(GTD) is one of the most promising technologies for the remediation of organic contaminated soil. Based on extensive literature review and worldwide practical cases analysis, this paper systematically reviewed the fundamental principle, application scope, advantages and disadvantages, and construction procedures of the GTD technology, and systematically compared and analyzed the current status of research and engineering application cases of GTD technology at home and abroad. Then the development trend and application prospect of this technology in China were also proposed. It is expected to provide beneficial information for in situ thermal treatment of organic contaminated soil in China.
引文
[1]缪周伟,吕树光,邱兆富,等.原位热处理技术修复重质非水相液体污染场地研究进展[J].环境污染与防治,2012,34(8):63-68.
[2]杨勇,黄海,陈美平,等.异位热解吸技术在有机污染土壤修复中的应用和发展[J].环境工程技术学报,2016,6(6):559-570.
[3]HAN L,QIAN L B,YAN J C,et al.A comparison of risk modeling tools and a case study for human health risk assessment of volatile organic compounds in contaminated groundwater[J].Environmental Science and Pollution Research,2016,23(2):1234-1245.
[4]KINGSTON J L T,DAHLEN P R,JOHNSON P C.State-of-the-practice review of in situ thermal technologies[J].Groundwater Monitoring&Remediation,2010,30(4):64-72.
[5]YANG W R,WANG R S,ZHOU C B,et al.Distribution and health risk assessment of organochlorine pesticides(OCPs)in industrial site soils:A case study of urban renewal in Beijing,China[J].Journal of Environmental Sciences,2009,21(3):366-372.
[6]吴嘉茵,方战强,薛成杰,等.我国有机物污染场地土壤修复技术的专利计量分析[J].环境工程学报,2019,13(8):2015-2024.
[7]康绍果,李书鹏,范云.污染地块原位加热处理技术研究现状与发展趋势[J].化工进展,2017,36(7):2621-2631.
[8]张学良,廖朋辉,李群,等.复杂有机物污染地块原位热脱附修复技术的研究[J].土壤通报,2018,49(4):993-1000.
[9]刘伟,汪华安,尚浩冉,等.有机污染场地原位电法热脱附修复技术综述[J].环境工程,2018,36(增刊):739-743.
[10]HEGELE P R,MUMFORD K G.Gas production and transport during bench-scale electrical resistance heating of water and trichloroethene[J].Journal of Contaminant Hydrology,2014,165:24-36.
[11]HIESTER U,MULLER M,KOSCHITZKY H,et al.In situ thermal treatment(ISTT)for source zone remediation of soil and groundwater[J].British Medical Journal,2013,31:482-484.
[12]BASTON D P,KUEPER B H.Thermal conductive heating in fractured bedrock:Screening calculations to assess the effect of groundwater influx[J].Advances in Water Resources,2009,32(2):231-238.
[13]MUNHOLLAND J L,MUMFORD K G,KUEPER B H.Factors affecting gas migration and contaminant redistribution in heterogeneous porous media subject to electrical resistance heating[J].Journal of Contaminant Hydrology,2016,184:14-24.
[14]ZHAO C,MUMFORD K G,KUPPER B H.Laboratory study of non-aqueous phase liquid and water co-boiling during thermal treatment[J].Journal of Contaminant Hydrology,2014,164:49-58.
[15]KROUZEK J,DURDAK V,HENDRYCH J,et al.Pilot scale applications of microwave heating for soil remediation[J].Chemical Engineering and Processing Process Intensification,2018,130:53-60.
[16]北京市质量技术监督局.场地土壤环境风险评价筛选值:DB 11/T 811-2011[S].北京,2011.
[17]生态环境部,国家市场监督管理总局.土壤环境质量建设用地土壤污染风险管控标准:GB 36600-2018[S].北京,2018.
[18]刘志阳.一种原位燃气热脱附土壤修复装置:ZL 201820382578.1.X[P].2018-12-11.
[19]牛晓阳,石德升,赵颖,等.污染土壤燃气原位热脱附修复系统:ZL 201811448227.7.X[P].2018-11-30.
[20]张峰,凃辉,王琛,等.一种用于污染场地的集中燃烧式原位热脱附修复装置:ZL 201710879465.2.X[P].2018-02-13.
[21]KINGSTON J,JOHNSON P,KUEPER B,et al.In situ thermal treatment of chlorinated solvent source zones[M]//BERNARDH K,HANS F S,CATHERINE M V,et al.Chlorinated Solvent Source Zone Remediation.New York:Springer,2014:509-557.
[22]EPA.In situ thermal treatment technologies:Lessons learned[R].Washington,D C:U.S.EPA Enginerring,2013.
[23]HILL S L.Engineering and design:In situ thermal remediation[R].Washington,D C:U.S.Army Corps of Engineers,2009.
[24]刘凯,张瑞环,王世杰.污染地块修复原位热脱附技术的研究及应用进展[J].中国氯碱,2017(12):31-37.
[25]刘伟,范爱武,黄晓明.多孔介质传热传质理论与应用[M].北京:科学出版社,2006.
[26]王华军,齐承英.土壤高温储热热湿迁移过程的初步研究[J].太阳能学报,2009,30(12):1683-1687.
[27]高霏,刘菲,陈鸿汉.三氯乙烯污染土壤和地下水污染源区的修复研究进展[J].地球科学进展,2008,23(8):821-829.
[28]POLING B E,PRAUSNITZ J M,CONNELL J P O.The Properties of Liquids and Gases[M].New York:McGraw-Hill Inc.,1987.
[29]HERON G,VAN ZUTPHEN M,CHRISTENSEN T H,et al.Soil heating for enhanced remediation of chlorinated solvents:Alaboratory study on resistive heating and vapor extraction in a silty,low-permeable soil contaminated with trichloroethylene[J].Environmental Science and Technology,1998,32(10):1474-1481.
[30]HERON G,CARROLL S,NIELSEN S G.Full-scale removal of DNAPL constituents using steam-enhanced extraction and electrical resistance heating[J].Ground Water Monitoring and Remediation,2005,25(4):92-107.
[31]ABRIOLA L M,RATHFELDER K.Mass balance errors in modeling two-phase immiscible flows:Causes and remedies[J].Advances in Water Resources,1993,16(4):223-239.
[32]KARKARE M C,FORT T.Water movement in“unsaturated”porous media due to pore size and surface tension induced capillary pressure gradients[J].Langmuir,1993,9(9):2398-2403.
[33]QUINTARD M,WHITAKER S.Convection,dispersion,and interfacial transport of contaminants:Homogeneous porous media[J].Advances in Water Resources,1994,17(4):221-239.
[34]BAHAR T,GOLFIER F,OLTEAN C,et al.Comparison of theory and experiment for NAPL dissolution in porous media[J].Journal of Contaminant Hydrology,2018,211:49-64.
[35]KORDKANDI S A,FOROUZESH M.Application of full factorial design for methylene blue dye removal using heat-activated persulfate oxidation[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(5):2597-2604.
[36]NIE M H,YANG Y,ZHANG Z J,et al.Degradation of chloramphenicol by thermally activated persulfate in aqueous solution[J].Chemical Engineering Journal,2014,246:373-382.
[37]徐开泰,林匡飞,陆强,等.热活化过硫酸钠降解土壤体系中的菲[J].环境工程,2018,36(1):188-194.
[38]杜玉吉,刘文杰,王海刚,等.一种利用分布式能源的污染土壤原位热修复系统及方法:ZL 201810918945.X[P].2018-11-30.
[39]程功弼,梁广秋,徐金旺.一种异位燃气加热抽提一体式热脱附装置:ZL201711462559.6.X[P].2018-05-01.
[40]HERON G,LACHANCE J,BAKER R.Removal of PCE DNAPL from tight clays using in situ thermal desorption[J].Ground Water Monitoring&Remediation,2013,33(4):31-43.
[41]HERON G,PARKER K,FOURNIER S,et al.World’s largest in situ thermal desorption project:Challenges and solutions[J].Ground Water Monitoring&Remediation,2015,35(3):89-100.
[42]HERON G,PARKER K,GALLIGAN J,et al.Thermal treatment of eight CVOC source areas to near nondetect concentrations[J].Ground Water Monitoring&Remediation,2009,29(3):56-65.
[43]梅志华,刘志阳,王从利,等.燃气热脱附技术在某有机污染场地的中试应用[J].资源节约与环保,2015(1):34-35.
[44]徐建,林玉锁,李群,等.GTR技术对土壤加热效果及对污染物的去除效果[C]//中国环境科学学会.2016中国环境科学学会学术年会论文集.海口,2016:3672-3681.
[45]张学良,李群,周艳,等.某退役溶剂厂有机物污染场地燃气热脱附原位修复效果试验[J].环境科学学报,2018,38(7):2868-2875.
[46]BELGIU M.Haemers technology references[EB/OL].[2019-01-01].https://haemers-technologies.com/references/,2019.
[47]王锦淮.原位热脱附技术在某有机污染场地修复中试应用[J].化学世界,2018,59(3):182-186.
[48]UDELL K.Heat and mass transfer in clean-up of underground toxic wastes[J].Annual Reviews of Heat Transfer,1996,7:333-405.
[49]籍龙杰,刘鹏,韦云霄,等.单根加热管原位加热土壤过程中温度变化规律[J].环境工程,2019,37(2):165-169.
[2]杨勇,黄海,陈美平,等.异位热解吸技术在有机污染土壤修复中的应用和发展[J].环境工程技术学报,2016,6(6):559-570.
[3]HAN L,QIAN L B,YAN J C,et al.A comparison of risk modeling tools and a case study for human health risk assessment of volatile organic compounds in contaminated groundwater[J].Environmental Science and Pollution Research,2016,23(2):1234-1245.
[4]KINGSTON J L T,DAHLEN P R,JOHNSON P C.State-of-the-practice review of in situ thermal technologies[J].Groundwater Monitoring&Remediation,2010,30(4):64-72.
[5]YANG W R,WANG R S,ZHOU C B,et al.Distribution and health risk assessment of organochlorine pesticides(OCPs)in industrial site soils:A case study of urban renewal in Beijing,China[J].Journal of Environmental Sciences,2009,21(3):366-372.
[6]吴嘉茵,方战强,薛成杰,等.我国有机物污染场地土壤修复技术的专利计量分析[J].环境工程学报,2019,13(8):2015-2024.
[7]康绍果,李书鹏,范云.污染地块原位加热处理技术研究现状与发展趋势[J].化工进展,2017,36(7):2621-2631.
[8]张学良,廖朋辉,李群,等.复杂有机物污染地块原位热脱附修复技术的研究[J].土壤通报,2018,49(4):993-1000.
[9]刘伟,汪华安,尚浩冉,等.有机污染场地原位电法热脱附修复技术综述[J].环境工程,2018,36(增刊):739-743.
[10]HEGELE P R,MUMFORD K G.Gas production and transport during bench-scale electrical resistance heating of water and trichloroethene[J].Journal of Contaminant Hydrology,2014,165:24-36.
[11]HIESTER U,MULLER M,KOSCHITZKY H,et al.In situ thermal treatment(ISTT)for source zone remediation of soil and groundwater[J].British Medical Journal,2013,31:482-484.
[12]BASTON D P,KUEPER B H.Thermal conductive heating in fractured bedrock:Screening calculations to assess the effect of groundwater influx[J].Advances in Water Resources,2009,32(2):231-238.
[13]MUNHOLLAND J L,MUMFORD K G,KUEPER B H.Factors affecting gas migration and contaminant redistribution in heterogeneous porous media subject to electrical resistance heating[J].Journal of Contaminant Hydrology,2016,184:14-24.
[14]ZHAO C,MUMFORD K G,KUPPER B H.Laboratory study of non-aqueous phase liquid and water co-boiling during thermal treatment[J].Journal of Contaminant Hydrology,2014,164:49-58.
[15]KROUZEK J,DURDAK V,HENDRYCH J,et al.Pilot scale applications of microwave heating for soil remediation[J].Chemical Engineering and Processing Process Intensification,2018,130:53-60.
[16]北京市质量技术监督局.场地土壤环境风险评价筛选值:DB 11/T 811-2011[S].北京,2011.
[17]生态环境部,国家市场监督管理总局.土壤环境质量建设用地土壤污染风险管控标准:GB 36600-2018[S].北京,2018.
[18]刘志阳.一种原位燃气热脱附土壤修复装置:ZL 201820382578.1.X[P].2018-12-11.
[19]牛晓阳,石德升,赵颖,等.污染土壤燃气原位热脱附修复系统:ZL 201811448227.7.X[P].2018-11-30.
[20]张峰,凃辉,王琛,等.一种用于污染场地的集中燃烧式原位热脱附修复装置:ZL 201710879465.2.X[P].2018-02-13.
[21]KINGSTON J,JOHNSON P,KUEPER B,et al.In situ thermal treatment of chlorinated solvent source zones[M]//BERNARDH K,HANS F S,CATHERINE M V,et al.Chlorinated Solvent Source Zone Remediation.New York:Springer,2014:509-557.
[22]EPA.In situ thermal treatment technologies:Lessons learned[R].Washington,D C:U.S.EPA Enginerring,2013.
[23]HILL S L.Engineering and design:In situ thermal remediation[R].Washington,D C:U.S.Army Corps of Engineers,2009.
[24]刘凯,张瑞环,王世杰.污染地块修复原位热脱附技术的研究及应用进展[J].中国氯碱,2017(12):31-37.
[25]刘伟,范爱武,黄晓明.多孔介质传热传质理论与应用[M].北京:科学出版社,2006.
[26]王华军,齐承英.土壤高温储热热湿迁移过程的初步研究[J].太阳能学报,2009,30(12):1683-1687.
[27]高霏,刘菲,陈鸿汉.三氯乙烯污染土壤和地下水污染源区的修复研究进展[J].地球科学进展,2008,23(8):821-829.
[28]POLING B E,PRAUSNITZ J M,CONNELL J P O.The Properties of Liquids and Gases[M].New York:McGraw-Hill Inc.,1987.
[29]HERON G,VAN ZUTPHEN M,CHRISTENSEN T H,et al.Soil heating for enhanced remediation of chlorinated solvents:Alaboratory study on resistive heating and vapor extraction in a silty,low-permeable soil contaminated with trichloroethylene[J].Environmental Science and Technology,1998,32(10):1474-1481.
[30]HERON G,CARROLL S,NIELSEN S G.Full-scale removal of DNAPL constituents using steam-enhanced extraction and electrical resistance heating[J].Ground Water Monitoring and Remediation,2005,25(4):92-107.
[31]ABRIOLA L M,RATHFELDER K.Mass balance errors in modeling two-phase immiscible flows:Causes and remedies[J].Advances in Water Resources,1993,16(4):223-239.
[32]KARKARE M C,FORT T.Water movement in“unsaturated”porous media due to pore size and surface tension induced capillary pressure gradients[J].Langmuir,1993,9(9):2398-2403.
[33]QUINTARD M,WHITAKER S.Convection,dispersion,and interfacial transport of contaminants:Homogeneous porous media[J].Advances in Water Resources,1994,17(4):221-239.
[34]BAHAR T,GOLFIER F,OLTEAN C,et al.Comparison of theory and experiment for NAPL dissolution in porous media[J].Journal of Contaminant Hydrology,2018,211:49-64.
[35]KORDKANDI S A,FOROUZESH M.Application of full factorial design for methylene blue dye removal using heat-activated persulfate oxidation[J].Journal of the Taiwan Institute of Chemical Engineers,2014,45(5):2597-2604.
[36]NIE M H,YANG Y,ZHANG Z J,et al.Degradation of chloramphenicol by thermally activated persulfate in aqueous solution[J].Chemical Engineering Journal,2014,246:373-382.
[37]徐开泰,林匡飞,陆强,等.热活化过硫酸钠降解土壤体系中的菲[J].环境工程,2018,36(1):188-194.
[38]杜玉吉,刘文杰,王海刚,等.一种利用分布式能源的污染土壤原位热修复系统及方法:ZL 201810918945.X[P].2018-11-30.
[39]程功弼,梁广秋,徐金旺.一种异位燃气加热抽提一体式热脱附装置:ZL201711462559.6.X[P].2018-05-01.
[40]HERON G,LACHANCE J,BAKER R.Removal of PCE DNAPL from tight clays using in situ thermal desorption[J].Ground Water Monitoring&Remediation,2013,33(4):31-43.
[41]HERON G,PARKER K,FOURNIER S,et al.World’s largest in situ thermal desorption project:Challenges and solutions[J].Ground Water Monitoring&Remediation,2015,35(3):89-100.
[42]HERON G,PARKER K,GALLIGAN J,et al.Thermal treatment of eight CVOC source areas to near nondetect concentrations[J].Ground Water Monitoring&Remediation,2009,29(3):56-65.
[43]梅志华,刘志阳,王从利,等.燃气热脱附技术在某有机污染场地的中试应用[J].资源节约与环保,2015(1):34-35.
[44]徐建,林玉锁,李群,等.GTR技术对土壤加热效果及对污染物的去除效果[C]//中国环境科学学会.2016中国环境科学学会学术年会论文集.海口,2016:3672-3681.
[45]张学良,李群,周艳,等.某退役溶剂厂有机物污染场地燃气热脱附原位修复效果试验[J].环境科学学报,2018,38(7):2868-2875.
[46]BELGIU M.Haemers technology references[EB/OL].[2019-01-01].https://haemers-technologies.com/references/,2019.
[47]王锦淮.原位热脱附技术在某有机污染场地修复中试应用[J].化学世界,2018,59(3):182-186.
[48]UDELL K.Heat and mass transfer in clean-up of underground toxic wastes[J].Annual Reviews of Heat Transfer,1996,7:333-405.
[49]籍龙杰,刘鹏,韦云霄,等.单根加热管原位加热土壤过程中温度变化规律[J].环境工程,2019,37(2):165-169.