异相芬顿反应降解废水中有机污染物的研究进展
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摘要
简述了芬顿反应的机理以及传统芬顿反应的局限性。综述了异相芬顿、光-异相芬顿和电-异相芬顿降解废水中有机污染物的最新研究进展。概述了新型芬顿催化剂在宽泛的pH范围内具有良好效果,以及重复利用率。探讨了未来芬顿反应的研究重点。
The mechanism of the Fenton reaction and the limitations of the traditional Fenton reaction are briefly described.The recent progress in the degradation of organic pollutants in wastewater by heterogeneous Fenton,photo-heterogeneous Fenton and electro-heterogeneous Fenton is reviewed.It is outlined that the novel Fenton catalyst has a good effect in both the broad pH range and the reuse rate.The focus of future Fenton reaction is discussed.
The mechanism of the Fenton reaction and the limitations of the traditional Fenton reaction are briefly described.The recent progress in the degradation of organic pollutants in wastewater by heterogeneous Fenton,photo-heterogeneous Fenton and electro-heterogeneous Fenton is reviewed.It is outlined that the novel Fenton catalyst has a good effect in both the broad pH range and the reuse rate.The focus of future Fenton reaction is discussed.
引文
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[2] Wang Weimin,Song Jia,Xu Han.Schwertmannite as a new Fenton-like catalyst in the oxidation of phenol by H2O2[J].Journal of Hazardous Materials,2013,262(11):412-419.
[3] 吴鹏.芬顿反应处理有机废水探索[J].新疆有色金属,2016(S1):72-73.
[4] Nidheesh P V,Gandhimathi R,Ramesh S T.Degradation of dyes from aqueous solution by Fenton processes:a review[J].Environ Sci Pollut R,2013,20(4):2099-2132.
[5] Luo W,Zhu L,Wang N,et al.Efficient removal of organic pollutants with magnetic nanoscaled BiFeO3 as a reusable heterogeneous Fenton-like catalyst[J].Environ Sci Technol,2010(44):1786-1791.
[6] Neyens E,Baeyens J.A review of classic Fenton’s peroxidation as an advanced oxidation technique[J].Journal of Hazardous Materials,2003,98(1/2/3):33-50.
[7] Bayat M,Sohrabi M,Royaee S J. Degradation of phenol by heterogeneous Fenton reaction using Fe/clinoptilolite[J].Journal of Industrial and Engineering Chemistry,2012,18(3):957-962.
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[9] Joseph J Pignatello,Esther Oliveros,Allison MacKay.Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry[J].Critical Reviews in Environmental Science & Technology,2006,36(1):1-84.
[10] Bokare A D,Choi W Y.Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes[J].Journal of Hazardous Materials,2014,275:121-135.
[11] Alireza K,Peyman G,Behrouz V.Heterogeneous sono-Fenton-like process using nanostructured pyrite prepared by Ar glow discharge plasma for treatment of a textile dye[J].Ultrasonics Sonochemistry,2016,29(6):213-225.
[12] Khataee A,Taseidifar M,Khorram S,et al.Preparation of nanostructured magnetite with plasma for degradation of a cationic textile dye by the heterogeneous Fenton process[J].Journal of the Taiwan Institute of Chemical Engineers,2015,53:132-139.
[13] Ramirez J H,Zea H R,Cramer T.Degradation of Chrysoidin dye by Fenton and photo-Fenton reaction using natural marmatite as catalyst[J].Journal of Advanced Oxidation Technology,2014,17(2):389-396.
[14] Feng J,Hu Xijun,Yue P L.Discoloration and mineralization of Orange II using different heterogeneous catalysts containing Fe:A comparative study[J].Environmental Science & Technology,2004,38(21):5773-5578.
[15] Sánchez-Sánchez C M,Expósito E,Casado J,et al.Goethite as a more effective iron dosage source for mineralization of organic pollutants by electro-Fenton process[J].Electrochemistry Communications,2007,9(1):19-24.
[16] 付益伟,于云江,冯俊生,等.改性Fenton试剂处理模拟苯酚废水研究[J].环境卫生学杂志,2013,3(3):225-228.
[17] Nie Y,Zhang L,Li Y Y,et al.Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2[J].Journal of Hazardous Materials,2015,294:195-200.
[18] Shi J,Ai Z,Zhang L.Fe@Fe2O3 core-shell nanowires enhanced Fenton oxidation by accelerating the Fe(III)/Fe(II) cycles[J].Water Research,2014,59(4):145-153.
[19] Hu X,Liu B,Deng Y,et al.Adsorption and heterogeneous Fenton degradation of 17α-methyltestosterone on nano Fe3O4/MWCNTs in aqueous solution[J].Applied Catalysis B Environmental,2011,107(3):274-283.
[20] Guo S,Yuan N,Zhang G,et al.Graphene modified iron sludge derived from homogeneous Fenton process as an efficient heterogeneous Fenton catalyst for degradation of organic pollutants[J].Microporous & Mesoporous Materials,2017,238:62-68.
[21] Pataquiva-Mateus A Y,Zea H R,Ramirez J H.Degradation of Orange II by Fenton reaction using ilmenite as catalyst[J].Environmental Science and Pollution Research,2017,24(7):6187-6194.
[22] Ma J,Yang Q,Wen Y,et al.Fe-g-C3N4/graphitized mesoporous carbon composite as an effective Fenton-like catalyst in a wide pH range[J].Applied Catalysis B Environmental,2017,201:232-240.
[23] Khataee A,Gholami P,Sheydaei M.Heterogeneous Fenton process by natural pyrite for removal of a textile dye from water:Effect of parameters and intermediate identification[J].Journal of the Taiwan Institute of Chemical Engineers,2015,58:366-373.
[24] Pignatello J J.Dark and photo-assisted Fe3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide[J].Environ Sci Technol,1992,26:944-951.
[25] Kusic H,Koprivanac N,Horvat S,et al.Modeling dye degradation kinetic using dark- and photo-Fenton type processes[J].Chemical Engineering Journal,2009,155(1):144-154.
[26] RodríGuez S M,Gálvez J B,Rubio M I M,et al.Engineering of solar photocatalytic collectors[J].Solar Energy,2004,77(5):513-524.
[27] Cai C,Zhang Z,Liu J,et al.Visible light-assisted heterogeneous Fenton with ZnFe2O4,for the degradation of Orange II in water[J].Applied Catalysis B Environmental,2016,182:456-468.
[28] Deng Y,Xing M,Zhang J.An advanced TiO2/Fe2TiO5/Fe2O3 triple-heterojunction with enhanced and stable visible-light-driven Fenton reaction for the removal of organic pollutants[J].Applied Catalysis B:Environmental,2017,211:157-166.
[29] Ju Y,Yu Y,Wang X,et al.Environmental application of millimetre-scale sponge iron (s-Fe0) particles (IV):New insights into visible light photo-Fenton-like process with optimum dosage of H2O2 and RhB photosensitizers[J].Journal of Hazardous Materials,2017,323:611-620.
[30] Brillas E,Sirés I,Oturan M A.Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry[J].Chemical Reviews,2009,109(12):6570-6631.
[31] Panizza M,Dirany A,Sirés I,et al.Complete mineralization of the antibiotic amoxicillin by electro-Fenton with a BDD anode[J].Journal of Applied Electrochemistry,2014,44(12):1327-1335.
[32] 邱珊,柴一荻,古振澳,等.电芬顿反应原理研究进展[J].环境科学与管理,2014,39(9):55-58.
[33] Nidheesh P V,Gandhimathi R.Trends in electro-Fenton process for water and wastewater treatment:An overview[J].Desalination,2012,299(4):1-15.
[34] Hou B,Ren B,Deng R,et al.Three-dimensional electro-Fenton oxidation of N-heterocyclic compounds with a novel catalytic particle electrode:high activity,wide pH range and catalytic mechanism[J].RSC Advances,2017,7(25):15455-15462.
[35] Es’haghzade Z,Pajootan E,Bahrami H,et al.Facile synthesis of Fe3O4 nanoparticles via aqueous based electro chemical route for heterogeneous electro-Fenton removal of azo dyes[J].Journal of the Taiwan Institute of Chemical Engineers,2017,71:91-105.
[36] Tian J,Zhao J,Olajuyin A M,et al.Effective degradation of Rhodamine B by electro-Fenton process,using ferromagnetic nanoparticles loaded on modified graphite felt electrode as reusable catalyst:in neutral pH condition and without external aeration[J].Environmental Science and Pollution Research,2016,23(15):15471-15482.
[2] Wang Weimin,Song Jia,Xu Han.Schwertmannite as a new Fenton-like catalyst in the oxidation of phenol by H2O2[J].Journal of Hazardous Materials,2013,262(11):412-419.
[3] 吴鹏.芬顿反应处理有机废水探索[J].新疆有色金属,2016(S1):72-73.
[4] Nidheesh P V,Gandhimathi R,Ramesh S T.Degradation of dyes from aqueous solution by Fenton processes:a review[J].Environ Sci Pollut R,2013,20(4):2099-2132.
[5] Luo W,Zhu L,Wang N,et al.Efficient removal of organic pollutants with magnetic nanoscaled BiFeO3 as a reusable heterogeneous Fenton-like catalyst[J].Environ Sci Technol,2010(44):1786-1791.
[6] Neyens E,Baeyens J.A review of classic Fenton’s peroxidation as an advanced oxidation technique[J].Journal of Hazardous Materials,2003,98(1/2/3):33-50.
[7] Bayat M,Sohrabi M,Royaee S J. Degradation of phenol by heterogeneous Fenton reaction using Fe/clinoptilolite[J].Journal of Industrial and Engineering Chemistry,2012,18(3):957-962.
[8] Bautista P,Mohedano A F,Casas J A,et al.An overview of the application of Fenton oxidation to industrial wastewaters treatment[J].Journal of Chemical Technology and Biotechnology,2008,83(10):1323-1338.
[9] Joseph J Pignatello,Esther Oliveros,Allison MacKay.Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry[J].Critical Reviews in Environmental Science & Technology,2006,36(1):1-84.
[10] Bokare A D,Choi W Y.Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes[J].Journal of Hazardous Materials,2014,275:121-135.
[11] Alireza K,Peyman G,Behrouz V.Heterogeneous sono-Fenton-like process using nanostructured pyrite prepared by Ar glow discharge plasma for treatment of a textile dye[J].Ultrasonics Sonochemistry,2016,29(6):213-225.
[12] Khataee A,Taseidifar M,Khorram S,et al.Preparation of nanostructured magnetite with plasma for degradation of a cationic textile dye by the heterogeneous Fenton process[J].Journal of the Taiwan Institute of Chemical Engineers,2015,53:132-139.
[13] Ramirez J H,Zea H R,Cramer T.Degradation of Chrysoidin dye by Fenton and photo-Fenton reaction using natural marmatite as catalyst[J].Journal of Advanced Oxidation Technology,2014,17(2):389-396.
[14] Feng J,Hu Xijun,Yue P L.Discoloration and mineralization of Orange II using different heterogeneous catalysts containing Fe:A comparative study[J].Environmental Science & Technology,2004,38(21):5773-5578.
[15] Sánchez-Sánchez C M,Expósito E,Casado J,et al.Goethite as a more effective iron dosage source for mineralization of organic pollutants by electro-Fenton process[J].Electrochemistry Communications,2007,9(1):19-24.
[16] 付益伟,于云江,冯俊生,等.改性Fenton试剂处理模拟苯酚废水研究[J].环境卫生学杂志,2013,3(3):225-228.
[17] Nie Y,Zhang L,Li Y Y,et al.Enhanced Fenton-like degradation of refractory organic compounds by surface complex formation of LaFeO3 and H2O2[J].Journal of Hazardous Materials,2015,294:195-200.
[18] Shi J,Ai Z,Zhang L.Fe@Fe2O3 core-shell nanowires enhanced Fenton oxidation by accelerating the Fe(III)/Fe(II) cycles[J].Water Research,2014,59(4):145-153.
[19] Hu X,Liu B,Deng Y,et al.Adsorption and heterogeneous Fenton degradation of 17α-methyltestosterone on nano Fe3O4/MWCNTs in aqueous solution[J].Applied Catalysis B Environmental,2011,107(3):274-283.
[20] Guo S,Yuan N,Zhang G,et al.Graphene modified iron sludge derived from homogeneous Fenton process as an efficient heterogeneous Fenton catalyst for degradation of organic pollutants[J].Microporous & Mesoporous Materials,2017,238:62-68.
[21] Pataquiva-Mateus A Y,Zea H R,Ramirez J H.Degradation of Orange II by Fenton reaction using ilmenite as catalyst[J].Environmental Science and Pollution Research,2017,24(7):6187-6194.
[22] Ma J,Yang Q,Wen Y,et al.Fe-g-C3N4/graphitized mesoporous carbon composite as an effective Fenton-like catalyst in a wide pH range[J].Applied Catalysis B Environmental,2017,201:232-240.
[23] Khataee A,Gholami P,Sheydaei M.Heterogeneous Fenton process by natural pyrite for removal of a textile dye from water:Effect of parameters and intermediate identification[J].Journal of the Taiwan Institute of Chemical Engineers,2015,58:366-373.
[24] Pignatello J J.Dark and photo-assisted Fe3+-catalyzed degradation of chlorophenoxy herbicides by hydrogen peroxide[J].Environ Sci Technol,1992,26:944-951.
[25] Kusic H,Koprivanac N,Horvat S,et al.Modeling dye degradation kinetic using dark- and photo-Fenton type processes[J].Chemical Engineering Journal,2009,155(1):144-154.
[26] RodríGuez S M,Gálvez J B,Rubio M I M,et al.Engineering of solar photocatalytic collectors[J].Solar Energy,2004,77(5):513-524.
[27] Cai C,Zhang Z,Liu J,et al.Visible light-assisted heterogeneous Fenton with ZnFe2O4,for the degradation of Orange II in water[J].Applied Catalysis B Environmental,2016,182:456-468.
[28] Deng Y,Xing M,Zhang J.An advanced TiO2/Fe2TiO5/Fe2O3 triple-heterojunction with enhanced and stable visible-light-driven Fenton reaction for the removal of organic pollutants[J].Applied Catalysis B:Environmental,2017,211:157-166.
[29] Ju Y,Yu Y,Wang X,et al.Environmental application of millimetre-scale sponge iron (s-Fe0) particles (IV):New insights into visible light photo-Fenton-like process with optimum dosage of H2O2 and RhB photosensitizers[J].Journal of Hazardous Materials,2017,323:611-620.
[30] Brillas E,Sirés I,Oturan M A.Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry[J].Chemical Reviews,2009,109(12):6570-6631.
[31] Panizza M,Dirany A,Sirés I,et al.Complete mineralization of the antibiotic amoxicillin by electro-Fenton with a BDD anode[J].Journal of Applied Electrochemistry,2014,44(12):1327-1335.
[32] 邱珊,柴一荻,古振澳,等.电芬顿反应原理研究进展[J].环境科学与管理,2014,39(9):55-58.
[33] Nidheesh P V,Gandhimathi R.Trends in electro-Fenton process for water and wastewater treatment:An overview[J].Desalination,2012,299(4):1-15.
[34] Hou B,Ren B,Deng R,et al.Three-dimensional electro-Fenton oxidation of N-heterocyclic compounds with a novel catalytic particle electrode:high activity,wide pH range and catalytic mechanism[J].RSC Advances,2017,7(25):15455-15462.
[35] Es’haghzade Z,Pajootan E,Bahrami H,et al.Facile synthesis of Fe3O4 nanoparticles via aqueous based electro chemical route for heterogeneous electro-Fenton removal of azo dyes[J].Journal of the Taiwan Institute of Chemical Engineers,2017,71:91-105.
[36] Tian J,Zhao J,Olajuyin A M,et al.Effective degradation of Rhodamine B by electro-Fenton process,using ferromagnetic nanoparticles loaded on modified graphite felt electrode as reusable catalyst:in neutral pH condition and without external aeration[J].Environmental Science and Pollution Research,2016,23(15):15471-15482.