磷酸氧钒催化剂制备及其催化氧化性能研究进展
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摘要
综述磷酸氧钒(VPO)催化剂制备方法及其对烷烃类物质催化氧化反应的研究进展,分析催化剂制备过程中载体、助剂、还原剂、分散剂、磷钒原子比以及在醇类溶液中回流时间等对VPO催化剂性能的影响。介绍VPO催化剂对烷烃类物质选择性氧化反应的反应机理,并展望VPO催化剂未来发展方向。
Research progress of preparation methods for vanadium pyrophosphate oxide( VPO) catalysts and their catalytic performance for oxidation of alkanes were reviewed. Effects of carrier,additive,reducing agent,dispersant,atomic ratio of phosphorus and vanadium and the reflux times in alcohol solutions on properties of VPO catalysts had been investigated. The mechanism of selective oxidation of alkanes over VPO catalysts was also introduced,and the future development of VPO catalysts was prospected.
Research progress of preparation methods for vanadium pyrophosphate oxide( VPO) catalysts and their catalytic performance for oxidation of alkanes were reviewed. Effects of carrier,additive,reducing agent,dispersant,atomic ratio of phosphorus and vanadium and the reflux times in alcohol solutions on properties of VPO catalysts had been investigated. The mechanism of selective oxidation of alkanes over VPO catalysts was also introduced,and the future development of VPO catalysts was prospected.
引文
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[18]Wang Aili,Hu Jing,Yin Hengbo,et al.Aldol condensation of acetic acid with formaldehyde to acrylic acid over Cs(Ce,Nd)VPO/Si O2catalyst[J].Rsc Advances,2017,7(76):48475-48485.
[19]王晓晗,卢冠忠,黄仲涛.用醇还原VOPO4·2H2O制备的VOHPO4·0.5H2O的择优取向性能[J].催化学报,2001,22(1):26-30.Wang Xiaolan,Lu Guanzhong,Huang Zhongtao.The optimal orientation performance of VOHPO4·0.5H2O prepared by reducing VOPO4·2H2O with alcohol[J].Journal of Catalysis,2001,22(1):26-30.
[20]Chen Shengli,Shao Hancheng.A new route to prepare VPOcatalyst for the selective oxidation of pentane[J].Chinese Journal of Catalysis,1999,20(5):553-556.
[21]周凌,李剑锋.超临界流体干燥方法在丁烷选择性氧化制顺酐VPO催化剂制备中的应用[J].催化学报,2001,22(5):427-431.Zhou Ling,Li Jianfeng.Application of supercritical fluid drying method in preparation of anhydride VPO catalyst by butane selective oxidation[J].Journal of catalysis,2001,22(5):427-431.
[22]王晓书,聂维艳,季伟捷,等.高比表面积VPO催化剂的制备及其性质研究[J].高等学校化学学报,2002,23(4):620-623.Wang Xiaoshu,Nie Weiyan,Ji Weijie,et al.Preparation and properties of high specific surface area VPO catalyst[J].Journal of Chemistry,2002,23(4):620-623.
[23]Guliants V V,Holmes S A.Probing polyfunctional nature of vanadyl pyrophosphate catalysts:oxidation of 16 C4molecules[J].Journal of Molecular Catalysis A:Chemical,2001,175(1):227-239.
[24]冯景隆,李春福,刘先明,等.正丁烷选择氧化制顺酐钒磷氧化物催化剂的研究进展[J].石油化工,2008,37(9):967-972.Feng Jinglong,Li Chunfu,Liu Xianming,et al.Research progress of n-butane selective oxidation catalyst for anhydride vanadium phosphorus oxide[J].Petrochemical,2008,37(9):967-972.
[2]刘先明,李春福,高浩华,等.正丁烷选择性氧化制顺酐VPO催化剂的研究进展[J].材料导报,2008,22(4):57-61.Liu Xianming,Li Chunfu,Gao Haohua,et al.Research progress on selective oxidation of n-butane catalyst for anhydride VPO[J].Materials Guide,2008,22(4):57-61.
[3]Hutchings G J,Higgins R.Selective oxidation of n-butane to maleic anhydride with vanadium phosphorus catalysts prepared by comminution in the presence of dispersants[J].Applied Catalysis A:General,1997,154(1/2):103-115.
[4]Poli G,Resta I,Ruggeri O,et al.The chemistry of catalysts based on vanadium-phosphorous oxides:NoteⅡ.The role of the method of preparation[J].Applied Catalysis,1981,1(6):395-404.
[5]Lopez-Sanchez J A,Griesel L,Bartley J K,et al.High temperature preparation of vanadium phosphate catalysts using water as solvent[J].Cheminform,2003,34(46):89-105.
[6]Feng Xinzhen,Yao Yao,Su Qin,et al.Vanadium pyrophosphate oxides:the role of preparation chemistry in determining rene wable acrolein production from glycerol dehydration[J].Applied Catalysis B:Environmental,2015,164(164):31-39.
[7]Kalevaru V N,Lücke B,Martin A.Synthesis of 2,6-dichlorobenzonitrile from 2,6-dichlorotoluene by gas phase ammoxidation over VPO catalysts[J].Catalysis Today,2009,142(3/4):158-164.
[8]Hutchings G J,Sananes M T,Sajip S,et al.Improved method of preparation of vanadium phosphate catalysts[J].Catalysis Today,1997,33(1/3):161-171.
[9]Leong L K,Chin K S,Taufiq-Yap Y H,et al.Effect of varying reflux durations on the physico-chemical and catalytic performance of vanadium phosphate catalysts synthesized via vanadyl hydrogen phosphate sesquihydrate[J].Applied Catalysis A:General,2012,415(s 415/416):53-58.
[10]师慧敏,陈雅萍.正丁烷氧化法制顺酐钒磷氧催化剂的研究进展[J].石油化工,2013,42(9):1044-1055.Shi Huimin,Chen Yaping.Research progress on anhydride vanadium phosphorus oxygen catalyst by n-butane oxidation[J].Petrochemical Industry,2013,42(9):1044-1055.
[11]Santra C,Shah S,Mondal A,et al.Synthesis,characterization of VPO catalyst dispersed on mesoporous silica surface and catalytic activity for cyclohexane oxidation reaction[J].Microporous&Mesoporous Materials,2016,223:121-128.
[12]Rezaei M,Chermahini A N,Dabbagh H A.Selective oxidation of toluene to benzaldehyde by H2O2with mesoporous silica KIT-6 supported VOHPO4·0.5H2O catalyst[J].Journal of Environmental Chemical Engineering,2017,5(4):3529-3539.
[13]Wu Huayi,Jin Peng,Sun Yifei,et al.Enhancing catalytic performance of phosphorus-modified ceria supported VPOcatalysts for n-butane oxidation[J].Journal of Molecular Catalysis A:Chemical,2016,414:1-8.
[14]Toosi M R,Peyrovi M H,Hejazian S,et al.Highly selective oxidation of cyclohexane to cyclohexanone using VPO catalysts in a high pressure batch reactor[J].Reaction Kinetics Mechanisms&Catalysis,2014,111(2):569-576.
[15]Guo Xinpeng,Yang Dan,Zuo Cuncun,et al.Catalysts,process optimization and kinetics for the production of methyl acrylate over vanadium phosphorus oxide catalysts[J].Industrial&Engineering Chemistry Research,2017,56(20):5860-5871.
[16]周凌,李然家,李剑锋,等.用于丁烷选择性氧化制顺酐的铈锆复合钒磷氧催化剂的研究[J].催化学报,2002,23(1):72-76.Zhou Ling,Li Ranjia,Li Jianfeng,et al.Study on cerium zirconium composite vanadium phosphorus oxygen catalyst for selective oxidation of butane to anhydride[J].Journal of Catalysis,2002,23(1):72-76.
[17]Ye Daiqi,Fu Mingli,Liang Hong,et al.Influence of additives on various VPO catalysts prepared by coprecipitation process[J].Journal of South China University of Technology,2004,32(1):49-55.
[18]Wang Aili,Hu Jing,Yin Hengbo,et al.Aldol condensation of acetic acid with formaldehyde to acrylic acid over Cs(Ce,Nd)VPO/Si O2catalyst[J].Rsc Advances,2017,7(76):48475-48485.
[19]王晓晗,卢冠忠,黄仲涛.用醇还原VOPO4·2H2O制备的VOHPO4·0.5H2O的择优取向性能[J].催化学报,2001,22(1):26-30.Wang Xiaolan,Lu Guanzhong,Huang Zhongtao.The optimal orientation performance of VOHPO4·0.5H2O prepared by reducing VOPO4·2H2O with alcohol[J].Journal of Catalysis,2001,22(1):26-30.
[20]Chen Shengli,Shao Hancheng.A new route to prepare VPOcatalyst for the selective oxidation of pentane[J].Chinese Journal of Catalysis,1999,20(5):553-556.
[21]周凌,李剑锋.超临界流体干燥方法在丁烷选择性氧化制顺酐VPO催化剂制备中的应用[J].催化学报,2001,22(5):427-431.Zhou Ling,Li Jianfeng.Application of supercritical fluid drying method in preparation of anhydride VPO catalyst by butane selective oxidation[J].Journal of catalysis,2001,22(5):427-431.
[22]王晓书,聂维艳,季伟捷,等.高比表面积VPO催化剂的制备及其性质研究[J].高等学校化学学报,2002,23(4):620-623.Wang Xiaoshu,Nie Weiyan,Ji Weijie,et al.Preparation and properties of high specific surface area VPO catalyst[J].Journal of Chemistry,2002,23(4):620-623.
[23]Guliants V V,Holmes S A.Probing polyfunctional nature of vanadyl pyrophosphate catalysts:oxidation of 16 C4molecules[J].Journal of Molecular Catalysis A:Chemical,2001,175(1):227-239.
[24]冯景隆,李春福,刘先明,等.正丁烷选择氧化制顺酐钒磷氧化物催化剂的研究进展[J].石油化工,2008,37(9):967-972.Feng Jinglong,Li Chunfu,Liu Xianming,et al.Research progress of n-butane selective oxidation catalyst for anhydride vanadium phosphorus oxide[J].Petrochemical,2008,37(9):967-972.