过氧化氢提纯净化技术研究进展
|
摘要
简要介绍了过氧化氢的应用及生产工艺。重点介绍了包括蒸馏法、吸附法、离子交换树脂法、膜分离法、结晶法、超临界流体萃取法等几种过氧化氢提纯净化技术的优劣。指出在中国电子工业飞速发展的大背景下,高纯过氧化氢的需求进一步扩大;过氧化氢的提纯净化技术要求向大型化、规模化的方向发展;近些年开发出的以离子交换树脂为核心的多单元集成纯化方法,通过对纯化技术的整合,既保证了高品质的质量要求,又兼顾了经济性、安全环保性。
The application and production technology of hydrogen peroxide were briefly introduced.The advantages and disadvantages of several purification technologies for hydrogen peroxide,including distillation,adsorption,ion exchange resin,membrane separation,crystallization and supercritical fluid extraction,were analyzed and introduced.It was pointed out that under the background of the rapid development of China′s electronics industry,the demand for high-purity hydrogen peroxide was further expanded,and the purification technology of hydrogen peroxide was required to be developed in the direction of large-scale and large-scale.The multi-unit integrated purification method based on ion exchange resin developed in recent years not only ensured high quality requirements,but also took into account economic,safety and environmental protectionthrough the integration of purification technology.
The application and production technology of hydrogen peroxide were briefly introduced.The advantages and disadvantages of several purification technologies for hydrogen peroxide,including distillation,adsorption,ion exchange resin,membrane separation,crystallization and supercritical fluid extraction,were analyzed and introduced.It was pointed out that under the background of the rapid development of China′s electronics industry,the demand for high-purity hydrogen peroxide was further expanded,and the purification technology of hydrogen peroxide was required to be developed in the direction of large-scale and large-scale.The multi-unit integrated purification method based on ion exchange resin developed in recent years not only ensured high quality requirements,but also took into account economic,safety and environmental protectionthrough the integration of purification technology.
引文
[1]Tang X.Recent advance in green catalytic oxidation of alcohols to aldehydes and ketones with hydrogen peroxide as oxidant[J].Advanced Materials Research,2014,3593(1049):158-166.
[2]Schumb W C,Setterfield C N,Wentworth R L.Hydrogen peroxide[M].New York:Reinhold Publishing Co,1995.
[3]杨洪彩,傅虹,艾山江·哈德尔.过氧化氢溶液在医药卫生方面研究与应用进展[J].中国卫生标准管理,2012,3(4):55-60.
[4]Stapelmann K.A combined low-pressure hydrogen peroxide evaporation plus hydrogen plasma treatment method for sterilization-Part 1:Characterization of the condensation process and proof-of-concept[J].Plasma Processes and Polymers,2017,14(8):1600198.
[5]Lackmann J W.A combined low-pressure hydrogen peroxide evaporation plus hydrogen plasma treatment method for sterilization-Part2:An intercomparison study of different biological systems[J].Plasma Processes and Polymers,2017,14(8):201600199.
[6]Kang X B,Pang G C,Liang X Y,et al.Study on a hydrogen peroxide biosensor based on horseradish peroxidase/GNPs-thionine/chitosan[J].Electrochimica Acta,2012,62:327-334.
[7]Lai H X,Huang L Q,Gan C H,et al.Enhanced acid leaching of metallurgical grade silicon in hydrofluoric acid containing hydrogen peroxide as oxidizing agent[J].Hydrometallurgy,2016,164:103-110.
[8]Oh T H.Design specifications of direct borohydride-hydrogen peroxide fuel cell system for space missions[J].Aerospace Science and Technology,2016,58:511-517.
[9]Wang Z K,Guo S,Ye C L.Leaching of copper from metal powders mechanically separated from waste printed circuit boards in chloride media using hydrogen peroxide as oxidant[J].Procedia Environmental Sciences,2016,31:917-924.
[10]Zhang X J,Guan J,Guo Y G,et al.Effective dismantling of waste printed circuit board assembly with methanesulfonic acid containing hydrogen peroxide[J].Environmental Progress&Sustainable Energy,2017,36(3):873-878.
[11]Kim K J,Luo N,Cui J.Electrolytic synthesis of hydrogen peroxide directly from water and application thereof:US,2012048744[P].2012-03-01.
[12]Guo Z T,Feng J T,Feng Y J,et al.In situ synthesis of solid base catalysts for the regeneration of degradation products formed during the anthraquinone process for the manufacture of hydrogen peroxide[J].Applied Catalysis A:General,2011,401(1):163-169.
[13]Shang H.Study on the new hydrogenation catalyst and processes for hydrogen peroxide through anthraquinone route[J].Journal of Industrial and Engineering Chemistry,2012,18:1851-1857.
[14]Ding D,Xu X,Tian P,et al.Promotional effects of Sb on Pd-based catalysts for the direct synthesis of hydrogen peroxide at ambient pressure[J].Chinese Journal of Catalysis,2018,39(4):673-681.
[15]Tian P,Xu X,Ao C,et al.Direct and selective synthesis of hydrogen peroxide over palladium-tellurium catalysts at ambient pressure[J].ChemSusChem,2017,10(17):3342-3346.
[16]Lari G M.Puértolas B,Shahrokhi M,et al.Hybrid palladium nanoparticles for direct hydrogen peroxide synthesis:The key role of the ligand[J].Angewandte Chemie,2017,129(7):1801-1805.
[17]GB/T 1616-2014工业过氧化氢[S].
[18]GB/T 6684-2002化学试剂:30%过氧化氢[S].
[19]GB 26371-2010过氧化物类消毒剂卫生标准[S].
[20]GB 22216-2008食品添加剂:过氧化氢[S].
[21]SEMI C30-1101过氧化氢规范说明指南[S].
[22]QJ 20050-2011航天用过氧化氢使用安全规定[S].
[23]Johnsson P.Process for preparing a substantially pure aqueous solution of hydrogen peroxide:US,5705040[P].1998-01-06.
[24]Signorini L,Glinos K.Process for obtaining purified aqueous hydrogen peroxide solutions:US,5296104[P].1994-03-22.
[25]Honig h,Geigel S.Method for purifying hydrogen peroxide for microelectronics uses:US,5232680[P].1993-08-03.
[26]Havlicek M D,Hoffman J G,Yuan W.Integrated method of preconditioning a resin for hydrogen peroxide purification and purifying hydrogen peroxide:US,6537516[P].2003-03-25.
[27]Inaba Y,Ueno Y,Tsujino T,et al.Process for purifying hydrogen peroxide aqueous solution:US,5624655[P].1997-04-29.
[28]下野次男.過酸化水素水精製法:JP,1995115848B2[P].1995-12-13.
[29]Manganano J L,Gibilisco D,Reed J R,et al.Process for removing iron from hydrogen peroxide:US,5266298[P].1993-11-30.
[30]Togo S.Method of removing organic impurities from aqueous solution of hydrogen peroxide:US,4792403[P].1988-12-20.
[31]木暮直毅,吉田寛史.精製過酸化水素水溶液の製造方法:JP,1999035305A[P].1999-02-09.
[32]Luan G Y,Gao W P,Yao P J.Study on experiments of anion exchange resin column for purification of hydrogen peroxide[J].Advanced Materials Research,2014(884/885):140-143.
[33]Oeter D,Dusemund C,Neumann E,et al.Method for the purification of hydrogen peroxide solutions:US,6939527[P].2005-09-06.
[34]Devos C,Demay D,Dulphy H.Process for the purification of aqueous hydrogen peroxide solutions:US,6540921[P].2003-04-01.
[35]Tanaka F.Apparatus for producing purified aqueous hydrogen peroxide solution:US,7368088[P].2008-05-06.
[36]Yokoi I.Aqueous hydrogen peroxide purification method and purification device:WO,2018074126[P].2018-04-26.
[37]Owen R,Bosse J,Sell M.Process for the purification of aqueous peroxygen solutions,solutions obtainable thereby and their use:WO,2005033005[P].2005-04-14.
[38]Abejón R,Garea A,Irabien A.Ultrapurification of hydrogen peroxide solution from ionic metals impurities to semiconductor grade by reverse osmosis[J].Separation and Purification Technology,2010,76(1):44-51.
[39]Wagner R.Crystallization process for producing highly concentrated hydrogen peroxide:US,6780206[P].2004-08-24.
[40]Turunen I.Method for purifying hydrogen peroxide:US,5605670[P].1997-02-25.
[41]Pennetreau P,Vandenbussche A.Process for manufacturing an aqueous hydrogen peroxide solution:US,6224845[P].2001-05-01.
[42]Bianchi U P.Process for the industrial production of high purity hydrogen peroxide:US,6333018[P].2001-12-25.
[2]Schumb W C,Setterfield C N,Wentworth R L.Hydrogen peroxide[M].New York:Reinhold Publishing Co,1995.
[3]杨洪彩,傅虹,艾山江·哈德尔.过氧化氢溶液在医药卫生方面研究与应用进展[J].中国卫生标准管理,2012,3(4):55-60.
[4]Stapelmann K.A combined low-pressure hydrogen peroxide evaporation plus hydrogen plasma treatment method for sterilization-Part 1:Characterization of the condensation process and proof-of-concept[J].Plasma Processes and Polymers,2017,14(8):1600198.
[5]Lackmann J W.A combined low-pressure hydrogen peroxide evaporation plus hydrogen plasma treatment method for sterilization-Part2:An intercomparison study of different biological systems[J].Plasma Processes and Polymers,2017,14(8):201600199.
[6]Kang X B,Pang G C,Liang X Y,et al.Study on a hydrogen peroxide biosensor based on horseradish peroxidase/GNPs-thionine/chitosan[J].Electrochimica Acta,2012,62:327-334.
[7]Lai H X,Huang L Q,Gan C H,et al.Enhanced acid leaching of metallurgical grade silicon in hydrofluoric acid containing hydrogen peroxide as oxidizing agent[J].Hydrometallurgy,2016,164:103-110.
[8]Oh T H.Design specifications of direct borohydride-hydrogen peroxide fuel cell system for space missions[J].Aerospace Science and Technology,2016,58:511-517.
[9]Wang Z K,Guo S,Ye C L.Leaching of copper from metal powders mechanically separated from waste printed circuit boards in chloride media using hydrogen peroxide as oxidant[J].Procedia Environmental Sciences,2016,31:917-924.
[10]Zhang X J,Guan J,Guo Y G,et al.Effective dismantling of waste printed circuit board assembly with methanesulfonic acid containing hydrogen peroxide[J].Environmental Progress&Sustainable Energy,2017,36(3):873-878.
[11]Kim K J,Luo N,Cui J.Electrolytic synthesis of hydrogen peroxide directly from water and application thereof:US,2012048744[P].2012-03-01.
[12]Guo Z T,Feng J T,Feng Y J,et al.In situ synthesis of solid base catalysts for the regeneration of degradation products formed during the anthraquinone process for the manufacture of hydrogen peroxide[J].Applied Catalysis A:General,2011,401(1):163-169.
[13]Shang H.Study on the new hydrogenation catalyst and processes for hydrogen peroxide through anthraquinone route[J].Journal of Industrial and Engineering Chemistry,2012,18:1851-1857.
[14]Ding D,Xu X,Tian P,et al.Promotional effects of Sb on Pd-based catalysts for the direct synthesis of hydrogen peroxide at ambient pressure[J].Chinese Journal of Catalysis,2018,39(4):673-681.
[15]Tian P,Xu X,Ao C,et al.Direct and selective synthesis of hydrogen peroxide over palladium-tellurium catalysts at ambient pressure[J].ChemSusChem,2017,10(17):3342-3346.
[16]Lari G M.Puértolas B,Shahrokhi M,et al.Hybrid palladium nanoparticles for direct hydrogen peroxide synthesis:The key role of the ligand[J].Angewandte Chemie,2017,129(7):1801-1805.
[17]GB/T 1616-2014工业过氧化氢[S].
[18]GB/T 6684-2002化学试剂:30%过氧化氢[S].
[19]GB 26371-2010过氧化物类消毒剂卫生标准[S].
[20]GB 22216-2008食品添加剂:过氧化氢[S].
[21]SEMI C30-1101过氧化氢规范说明指南[S].
[22]QJ 20050-2011航天用过氧化氢使用安全规定[S].
[23]Johnsson P.Process for preparing a substantially pure aqueous solution of hydrogen peroxide:US,5705040[P].1998-01-06.
[24]Signorini L,Glinos K.Process for obtaining purified aqueous hydrogen peroxide solutions:US,5296104[P].1994-03-22.
[25]Honig h,Geigel S.Method for purifying hydrogen peroxide for microelectronics uses:US,5232680[P].1993-08-03.
[26]Havlicek M D,Hoffman J G,Yuan W.Integrated method of preconditioning a resin for hydrogen peroxide purification and purifying hydrogen peroxide:US,6537516[P].2003-03-25.
[27]Inaba Y,Ueno Y,Tsujino T,et al.Process for purifying hydrogen peroxide aqueous solution:US,5624655[P].1997-04-29.
[28]下野次男.過酸化水素水精製法:JP,1995115848B2[P].1995-12-13.
[29]Manganano J L,Gibilisco D,Reed J R,et al.Process for removing iron from hydrogen peroxide:US,5266298[P].1993-11-30.
[30]Togo S.Method of removing organic impurities from aqueous solution of hydrogen peroxide:US,4792403[P].1988-12-20.
[31]木暮直毅,吉田寛史.精製過酸化水素水溶液の製造方法:JP,1999035305A[P].1999-02-09.
[32]Luan G Y,Gao W P,Yao P J.Study on experiments of anion exchange resin column for purification of hydrogen peroxide[J].Advanced Materials Research,2014(884/885):140-143.
[33]Oeter D,Dusemund C,Neumann E,et al.Method for the purification of hydrogen peroxide solutions:US,6939527[P].2005-09-06.
[34]Devos C,Demay D,Dulphy H.Process for the purification of aqueous hydrogen peroxide solutions:US,6540921[P].2003-04-01.
[35]Tanaka F.Apparatus for producing purified aqueous hydrogen peroxide solution:US,7368088[P].2008-05-06.
[36]Yokoi I.Aqueous hydrogen peroxide purification method and purification device:WO,2018074126[P].2018-04-26.
[37]Owen R,Bosse J,Sell M.Process for the purification of aqueous peroxygen solutions,solutions obtainable thereby and their use:WO,2005033005[P].2005-04-14.
[38]Abejón R,Garea A,Irabien A.Ultrapurification of hydrogen peroxide solution from ionic metals impurities to semiconductor grade by reverse osmosis[J].Separation and Purification Technology,2010,76(1):44-51.
[39]Wagner R.Crystallization process for producing highly concentrated hydrogen peroxide:US,6780206[P].2004-08-24.
[40]Turunen I.Method for purifying hydrogen peroxide:US,5605670[P].1997-02-25.
[41]Pennetreau P,Vandenbussche A.Process for manufacturing an aqueous hydrogen peroxide solution:US,6224845[P].2001-05-01.
[42]Bianchi U P.Process for the industrial production of high purity hydrogen peroxide:US,6333018[P].2001-12-25.