缓释药剂技术在水处理中的应用
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摘要
介绍了包覆型和负载型缓释水处理药剂的制备方法:微胶囊技术、熔化冷凝技术、流变相技术、St-BER技术、浸渍法、碾磨法以及液相分离技术等,并在此基础上分析了几种制备缓释剂技术的特点,进一步探讨了缓释型水处理药剂的研究方向与应用前景。
Discussed the preparation method of sustained release pharmaceutical with coated type and supported type including Microcapsule technology,MSC method,Rheological Method,St-BER Method,impregnation,grinding method and liquid phase separation technique,etc.Further,we analysed the characteristic of several sustained release pharmaceutical techniques and discussed their research directions and application prospect.
Discussed the preparation method of sustained release pharmaceutical with coated type and supported type including Microcapsule technology,MSC method,Rheological Method,St-BER Method,impregnation,grinding method and liquid phase separation technique,etc.Further,we analysed the characteristic of several sustained release pharmaceutical techniques and discussed their research directions and application prospect.
引文
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[9]VALIYAVEETTIL S,Setyono D.Use of Porous Cellulose Microcapsules for Water Treatment[J].Rsc Advances,2015,5(101):83286-83294.
[10]王艳龙.高锰酸钾缓释剂处理地下水中苯酚的研究[D].吉林:吉林大学,2014.
[11]CRIMI M,QUICKEL M,KO S.Enhanced permanganate in situ chemical oxidation through MnO2 particle stabilization:evaluation in 1-D transport systems[J].Journal of Contaminant Hydrology,2009,105(1-2):69.
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[16]徐璇,陶萍,魏威,等.缓释型高铁酸钾水处理剂的制备方法,中国,CN201310364211.9[P].2013-11-27
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[18]LI X Q,ELLIOTT D,ZHANG W X.Zero-Valent Iron Nanoparticles for Abatement of Environmental Pollutants:Materials and Engineering Aspects[J].Critical Reviews in Solid State & Materials Sciences,2006,31(4):111-122.
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[21]张威,韩占涛,许广明.纳米零价铁用于地下水污染修复时存在的问题与对策[J].南水北调与水利科技,2012,(04):34-38.
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[23]张瑛洁,刘强.硅藻土负载型与改性纳米TiO2的研究进展[J].硅酸盐通报,2015,34(3):744-748.
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[26]WANG L H,CHE X,HUI X,et al.A novel strategy to design sustained-release poorly water-soluble drug mesoporous silica microparticles based on super critical fluid technique[J].International Journal of Pharmaceutics,2013,454(1):135-142.
[27]孙霞.介孔孔道限域纳米零价铁的制备及在地下水污染修复中的应用[D].南京:南京理工大学,2014.
[28]许书刚.蒙脱石负载高锰酸钾对地下水中氯代烃的降解实验研究[D].武汉:中国地质大学,2012.
[29]高玉梅,宋慧君,王非,等.复合高铁酸盐片剂的制备及对印染废水的处理研究[J].郑州大学学报:理学版,2012,44(1):107-110.
[30]杨国华,徐国强,汪祖模.水处理片剂的研制[J].化学世界.1989,(4),174-176.
[31]BELLIER N,CHAZARENC F,COMEAU Y.Phosphorus removal from waste water by mineral apatite[J].Water Research,2006,40(15):0-2971.
[32]朱慧杰,贾永锋,姚淑华,等.负载型纳米铁吸附剂去除饮用水中As(Ⅴ)的研究[J].环境科学,2009,30(12):1644-1648.
[33]黎淑贞.蒙脱石负载纳米铁颗粒去除水中硝基苯和六价铬的研究[D].广州:华南理工大学,2011.
[34]HOCH L B,MACK E J,HYDUTSKY B W,et al.Carbothermal Synthesis of Carbon-supported Nanoscale Zero-valent Iron Particles for the Remediation of Hexavalent Chromium[J].Environmental Science & Technology,2008,42(7):2600-2605.
[35]SMULEAC V,BACHAS L,BHATTACHARYYA D.Aqueous-Phase Synthesis of PAA in PVDF Membrane Pores for Nanoparticle Synthesis and Dichlorobiphenyl Degradation[J].Journal of Membrane Science,2010,346(2):310-317.
[36]ZHENG T,ZHAN J,HE J,et al.Reactivity characteristics of nanoscale zerovalent iron--silica composites for trichloroethylene remediation[J].Environmental Science & Technology,2008,42(12):4494-4499.
[37]LI A,TAI C,ZHAO Z,et al.Debromination of decabrominateddiphenyl ether by resin-bound iron nanoparticles[J].Environmental Science & Technology,2007,41(19):6841-6846.
[38]胡六江,李益民.有机膨润土负载纳米铁去除废水中硝基苯[J].环境科学学报,2008,28(6):1107-1112.
[39]LV X,XU J,JIANG G,et al.Removal of chromium(VI) from wastewater by nanoscale zero-valent iron particles supported on multiwalled carbon nanotubes[J].Chemosphere,2011,85(7):1204-1209.
[40]高华生.磷酸盐控制释放玻璃的特性及其在水处理中的应用[D].浙江:浙江大学出版社,2001.
[41]ZHANG Q L,LIN Y C,CHEN X,et al.A method for preparing ferric activated carbon composites adsorbents to remove arsenic from drinking water[J].Journal of Hazardous Materials,2007,148(3):671-678.
[42]HANS Vogel.Method of Eoming a Phosphate Glass to lnoculate Water.U.S.A,372050[P],1973.
[43]西北轻工学院主编.玻璃工艺学[M].北京:中国建筑工业出版社,1982.
[44]张宁,甘复兴.一种新型缓释型水处理剂的性能研究[J].材料保护,2003,36(8):49-51.
[45]陈才丽,向仁军,许友泽,等.载银硅酸盐玻璃缓蚀阻垢剂的研究进展[J].湖南有色金属,2017,33(4):50-53.
[46]汪山,程继建.磷酸盐玻璃缓释材料应用进展[J].玻璃与搪瓷,1999,27(3):53-71.
[47]BARRIOS C A,XU Q,CUTRIGHT T,et al.Incorporating zosteric acid into silicone coatings to achieve its slow release while reducing fresh water bacterial attachment[J].Colloids & Surfaces B Biointerfaces,2005,41(2):83-93.
[48]许春莲,王文君,胡学东,等.缓释型除磷药剂在小型污水处理装置中的应用[J].环境工程技术学报,2013,3(6):527-531.
[49]赵雯,张秋禹,王结良,等.缓释技术及应用[J].河南化工,2004(7):1-3.
[2]王艳龙,吴嫚,史若馨,等.KMnO4缓释剂的释放性能及其在垃圾渗滤液处理中的应用[J].环境工程学报,2013,7(8):2867-2872.
[3]LEE E S,SCHWARTZ F W.Characteristics and applications of controlled-release KMnO4 for groundwater remediation[J].Chemosphere,2007,66(11):2058-2066.
[4]遇静,赵朝成,李超,等.缓释技术的研究现状与展望[J].广州化工,2014(5):18-19.
[5]赵进沛,任庆余,李秀芹,等.缓控释制剂技术的发展及其在饮水消毒中的应用[J].现代预防医学,2005,32(12):1658-1659.
[6]兰华春.包覆型高铁酸钾的制备及其应用研究[D].福州:福州大学,2006.
[7]徐炽焕.微胶囊制备及其应用[J].化工新型材料,2005,33(11):75～78.
[8]YUAN B,CHEN Y,FU M L.Degradation efficiencies and mechanisms of trichloroethylene(TCE) by controlled-release permanganate(CRP) oxidation[J].Chemical Engineering Journal,2012,192(none):276-283.
[9]VALIYAVEETTIL S,Setyono D.Use of Porous Cellulose Microcapsules for Water Treatment[J].Rsc Advances,2015,5(101):83286-83294.
[10]王艳龙.高锰酸钾缓释剂处理地下水中苯酚的研究[D].吉林:吉林大学,2014.
[11]CRIMI M,QUICKEL M,KO S.Enhanced permanganate in situ chemical oxidation through MnO2 particle stabilization:evaluation in 1-D transport systems[J].Journal of Contaminant Hydrology,2009,105(1-2):69.
[12]FREEDMAN D L,MURDOCH L C,SIEGRIST R L,et al.Characteristics of Potassium Permanganate Encapsulated in Polymer[J].Journal of Environmental Engineering,2005,131(8):1203-1211.
[13]章秋菊.包覆型稳定性高铁酸钾的制备及其性能研究[D].南京:南京理工大学,2016.
[14]叶谋仁,苑宝玲,兰华春,等.包覆型高铁酸钾缓释剂的制备及性能表征[J].高技术通讯,200,18(2):201-205.
[15]ADDITION I,Fe(III).Preparation and Application of Sustained-Release Potassium Ferrate(VI)[J].Journal of Chemistry,2014,2014(12):1-7.
[16]徐璇,陶萍,魏威,等.缓释型高铁酸钾水处理剂的制备方法,中国,CN201310364211.9[P].2013-11-27
[17]付真金,廖其龙,卢忠远,等.流变相-前驱物法制备纳米镍铁氧体粉末[J].精细化工,2007,(03):217-220.
[18]LI X Q,ELLIOTT D,ZHANG W X.Zero-Valent Iron Nanoparticles for Abatement of Environmental Pollutants:Materials and Engineering Aspects[J].Critical Reviews in Solid State & Materials Sciences,2006,31(4):111-122.
[19]焦创.流变相法制备包裹型纳米零价铁及处理重金属废水的研究[D].景德镇:景德镇陶瓷学院,2013.
[20]LI Y,JIN Z,LI T,et al.One-step synthesis and characterization of core-shell Fe@SiO2 nanocomposite for Cr(VI) reduction[J].Science of the Total Environment,2012,421-422:260-266.
[21]张威,韩占涛,许广明.纳米零价铁用于地下水污染修复时存在的问题与对策[J].南水北调与水利科技,2012,(04):34-38.
[22]YU J P,GUAN Y X,YAO S J,et al.Preparation of Roxithromycin-Loaded Poly(l-lactic Acid) Films with Super critical Solution Impregnation[J].Industrial & Engineering Chemistry Research,2011,50(24):13813-13818.
[23]张瑛洁,刘强.硅藻土负载型与改性纳米TiO2的研究进展[J].硅酸盐通报,2015,34(3):744-748.
[24]SAND M L.Method for impregnating a thermoplastic polymer; US,4598006[P],1986-07-01.
[25]关怡新,余金鹏,姚善泾,等.超临界溶液浸渍法制备缓释药物[J].化工学报,2010,61(2):269-274.
[26]WANG L H,CHE X,HUI X,et al.A novel strategy to design sustained-release poorly water-soluble drug mesoporous silica microparticles based on super critical fluid technique[J].International Journal of Pharmaceutics,2013,454(1):135-142.
[27]孙霞.介孔孔道限域纳米零价铁的制备及在地下水污染修复中的应用[D].南京:南京理工大学,2014.
[28]许书刚.蒙脱石负载高锰酸钾对地下水中氯代烃的降解实验研究[D].武汉:中国地质大学,2012.
[29]高玉梅,宋慧君,王非,等.复合高铁酸盐片剂的制备及对印染废水的处理研究[J].郑州大学学报:理学版,2012,44(1):107-110.
[30]杨国华,徐国强,汪祖模.水处理片剂的研制[J].化学世界.1989,(4),174-176.
[31]BELLIER N,CHAZARENC F,COMEAU Y.Phosphorus removal from waste water by mineral apatite[J].Water Research,2006,40(15):0-2971.
[32]朱慧杰,贾永锋,姚淑华,等.负载型纳米铁吸附剂去除饮用水中As(Ⅴ)的研究[J].环境科学,2009,30(12):1644-1648.
[33]黎淑贞.蒙脱石负载纳米铁颗粒去除水中硝基苯和六价铬的研究[D].广州:华南理工大学,2011.
[34]HOCH L B,MACK E J,HYDUTSKY B W,et al.Carbothermal Synthesis of Carbon-supported Nanoscale Zero-valent Iron Particles for the Remediation of Hexavalent Chromium[J].Environmental Science & Technology,2008,42(7):2600-2605.
[35]SMULEAC V,BACHAS L,BHATTACHARYYA D.Aqueous-Phase Synthesis of PAA in PVDF Membrane Pores for Nanoparticle Synthesis and Dichlorobiphenyl Degradation[J].Journal of Membrane Science,2010,346(2):310-317.
[36]ZHENG T,ZHAN J,HE J,et al.Reactivity characteristics of nanoscale zerovalent iron--silica composites for trichloroethylene remediation[J].Environmental Science & Technology,2008,42(12):4494-4499.
[37]LI A,TAI C,ZHAO Z,et al.Debromination of decabrominateddiphenyl ether by resin-bound iron nanoparticles[J].Environmental Science & Technology,2007,41(19):6841-6846.
[38]胡六江,李益民.有机膨润土负载纳米铁去除废水中硝基苯[J].环境科学学报,2008,28(6):1107-1112.
[39]LV X,XU J,JIANG G,et al.Removal of chromium(VI) from wastewater by nanoscale zero-valent iron particles supported on multiwalled carbon nanotubes[J].Chemosphere,2011,85(7):1204-1209.
[40]高华生.磷酸盐控制释放玻璃的特性及其在水处理中的应用[D].浙江:浙江大学出版社,2001.
[41]ZHANG Q L,LIN Y C,CHEN X,et al.A method for preparing ferric activated carbon composites adsorbents to remove arsenic from drinking water[J].Journal of Hazardous Materials,2007,148(3):671-678.
[42]HANS Vogel.Method of Eoming a Phosphate Glass to lnoculate Water.U.S.A,372050[P],1973.
[43]西北轻工学院主编.玻璃工艺学[M].北京:中国建筑工业出版社,1982.
[44]张宁,甘复兴.一种新型缓释型水处理剂的性能研究[J].材料保护,2003,36(8):49-51.
[45]陈才丽,向仁军,许友泽,等.载银硅酸盐玻璃缓蚀阻垢剂的研究进展[J].湖南有色金属,2017,33(4):50-53.
[46]汪山,程继建.磷酸盐玻璃缓释材料应用进展[J].玻璃与搪瓷,1999,27(3):53-71.
[47]BARRIOS C A,XU Q,CUTRIGHT T,et al.Incorporating zosteric acid into silicone coatings to achieve its slow release while reducing fresh water bacterial attachment[J].Colloids & Surfaces B Biointerfaces,2005,41(2):83-93.
[48]许春莲,王文君,胡学东,等.缓释型除磷药剂在小型污水处理装置中的应用[J].环境工程技术学报,2013,3(6):527-531.
[49]赵雯,张秋禹,王结良,等.缓释技术及应用[J].河南化工,2004(7):1-3.