水性塑/塑复合胶粘剂的制备研究
|
摘要
以无机补强剂、复合偶联剂、复合润湿剂、多元共混树脂乳液、增粘树脂乳液、复合消泡剂等为原料制备了水性塑/塑复合胶粘剂。研究了偶联剂、润湿剂、消泡剂等对其复合膜剥离强度的影响,结果表明,偶联剂、润湿剂、消泡剂等通过形成化学键、增加接触面积、减少表面应力破坏等形式可使其剥离强度得到提高,当用量过多时会引起剥离强度下降。
The water-based plastic-plastic laminating adhesive was prepared with the inorganic reinforcing agent, combined coupling agent, combined wetting agent, combined defoaming agent, multicomponent blending resin emulsion and tackifying resin emulsion as the raw materials. The effects of the coupling agent, wetting agent and defoaming agent were studied on the peeling strength. The results show that the peeling strength can be improved by forming chemical bond, increasing the contact area and reducing surface stress failure, but their contents are too much, the peeling strength will decrease.
The water-based plastic-plastic laminating adhesive was prepared with the inorganic reinforcing agent, combined coupling agent, combined wetting agent, combined defoaming agent, multicomponent blending resin emulsion and tackifying resin emulsion as the raw materials. The effects of the coupling agent, wetting agent and defoaming agent were studied on the peeling strength. The results show that the peeling strength can be improved by forming chemical bond, increasing the contact area and reducing surface stress failure, but their contents are too much, the peeling strength will decrease.
引文
[1]陈昌杰.塑料薄膜的印刷与复合[M].北京:化学工业出版社,2013.
[2]李陵岚,叶楚平,张正华.包装用胶黏剂及粘结技术[M].北京:化学工业出版社,2005.
[3]黄玉东.聚合物表面与界面技术[M].北京:化学工业出版社,2003.
[4]阿方萨斯V.波丘斯著,潘顺龙,赵飞,许关利(译).粘接与胶黏剂技术导论[M].北京:化学工业出版社,2005.
[5]王军,杨许召,李刚森.功能性表面活性剂制备与应用[M].北京:化学工业出版社,2009.
[6]王国建,邱军.多组分聚合物结构与性能[M].北京:化学工业出版社,2010.
[7]Yang X,Fleming F F.C-and N-Metalated Nitriles:The Relationship between Structure and Selectivity[J].Accounts of Chemical Research,2017,50(10):2556-2568.
[8]Chakrabarty S,Choudhary S,Doshi A.Catalytic Isonitrile Insertions and Condensations Initiated by RNC-X Complexation[J].Cheminform,2014,45(37):2135-2196.
[9]法西罗夫斯基R T,凯斯特尔曼V N著,王洪祚,刘芝兰,王颖(译).聚合物的粘结作用[M].北京:化学工业出版社,2004.
[10]密特K L,皮兹A著,陈步宁,黎复华(译).粘结表面处理技术[M].北京:化学工业出版社,2004.
[11]Yang X,Nath D,Morse J.Cyclic Alkenenitriles:Copper-Catalyzed Deconjugativeα-Alkylation[J].Journal of Organic Chemistry,2016,81(10):4098-4102.
[12]Yang X,Nath D,Fleming F F.Chemoselective Alkylations with N-and C-Metalated Nitriles[J].Organic letters,2015,17(19):4906-4909.
[13]张招贵,刘峰,余政.有机硅化合物化学[M].北京:化学工业出版社,2010.
[14]蒋庆哲,宋昭峥,赵密福,等.表面活性剂科学与应用[M].北京:中国石化出版社,2006.
[15]Yang X,Nath D,Gau M R,et al.Sulfone-Metal Exchange and Alkylation of Sulfonylnitriles[J].Angewandte Chemie,2017,56(25):7363-7366.
[16]燕永利.泡沫、乳状液的稳定化及其应用[M].北京:化学工业出版社,2013.
[2]李陵岚,叶楚平,张正华.包装用胶黏剂及粘结技术[M].北京:化学工业出版社,2005.
[3]黄玉东.聚合物表面与界面技术[M].北京:化学工业出版社,2003.
[4]阿方萨斯V.波丘斯著,潘顺龙,赵飞,许关利(译).粘接与胶黏剂技术导论[M].北京:化学工业出版社,2005.
[5]王军,杨许召,李刚森.功能性表面活性剂制备与应用[M].北京:化学工业出版社,2009.
[6]王国建,邱军.多组分聚合物结构与性能[M].北京:化学工业出版社,2010.
[7]Yang X,Fleming F F.C-and N-Metalated Nitriles:The Relationship between Structure and Selectivity[J].Accounts of Chemical Research,2017,50(10):2556-2568.
[8]Chakrabarty S,Choudhary S,Doshi A.Catalytic Isonitrile Insertions and Condensations Initiated by RNC-X Complexation[J].Cheminform,2014,45(37):2135-2196.
[9]法西罗夫斯基R T,凯斯特尔曼V N著,王洪祚,刘芝兰,王颖(译).聚合物的粘结作用[M].北京:化学工业出版社,2004.
[10]密特K L,皮兹A著,陈步宁,黎复华(译).粘结表面处理技术[M].北京:化学工业出版社,2004.
[11]Yang X,Nath D,Morse J.Cyclic Alkenenitriles:Copper-Catalyzed Deconjugativeα-Alkylation[J].Journal of Organic Chemistry,2016,81(10):4098-4102.
[12]Yang X,Nath D,Fleming F F.Chemoselective Alkylations with N-and C-Metalated Nitriles[J].Organic letters,2015,17(19):4906-4909.
[13]张招贵,刘峰,余政.有机硅化合物化学[M].北京:化学工业出版社,2010.
[14]蒋庆哲,宋昭峥,赵密福,等.表面活性剂科学与应用[M].北京:中国石化出版社,2006.
[15]Yang X,Nath D,Gau M R,et al.Sulfone-Metal Exchange and Alkylation of Sulfonylnitriles[J].Angewandte Chemie,2017,56(25):7363-7366.
[16]燕永利.泡沫、乳状液的稳定化及其应用[M].北京:化学工业出版社,2013.