无机钙钛矿CsPbX_3晶体的低温溶液生长及应用研究进展
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摘要
无机钙钛矿材料CsPbX_3(X=Cl,Br,I)具有光吸收系数高、发射谱线宽度窄、发光效率高等优异的光电性能,与目前在光伏领域大放异彩的有机-无机杂化钙钛矿材料相比,其在化学稳定性和热稳定性方面更胜一筹。文章就CsPbBr_3晶体的低温制备方法及其在光电探测器、发光二极管、激光、高能射线探测等领域的应用研究进展进行了分析和总结。
Inorganic lead halide perovskite CsPbX_3(X = Cl,Br,I)has excellent photoelectric properties such as high optical absorption coefficient,narrow emission line width and high luminescence.Compared with the organic-inorganic hybrid halide perovskite commonly used in photovoltaic fields,the chemical and heat stability of CsPbX_3 is much better.In this paper,several preparation methods of CsPbX_3 crystal were analyzed and recent progresses in the fields of photodetector,LED,laser and high energy detector were summarized.
Inorganic lead halide perovskite CsPbX_3(X = Cl,Br,I)has excellent photoelectric properties such as high optical absorption coefficient,narrow emission line width and high luminescence.Compared with the organic-inorganic hybrid halide perovskite commonly used in photovoltaic fields,the chemical and heat stability of CsPbX_3 is much better.In this paper,several preparation methods of CsPbX_3 crystal were analyzed and recent progresses in the fields of photodetector,LED,laser and high energy detector were summarized.
引文
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[2]Tian Wei,Zhou Huanping,Li Liang.Hybrid organicinorganic perovskite photodetectors[J].Small,2017,13(41):1702107.
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[4]Xiao Junyan,Shi Jiangjian,Li Dongmei,et al.Perovskite thin-film solar cell:excitation in photovoltaic science[J].Science China Chemistry,2015,58(2):221-238.
[5]Saliba M,Simon M W,Jay B P,et al.Structured organicinorganic perovskite toward a distributed feedback laser[J].Adv.Mater.,2016,28(5):923-929.
[6]Duan X,Huang Y,Agarwal R,et al.Single-nanowire electrically driven lasers[J].Nature,2003,421(6920):241-245.
[7]Chen Y S,Manser J S,Kamat P V,et al.All solutionprocessed lead halide perovskite-BiVO4tandem assembly for photolytic solar fuels production[J].J.of the American Chemical Society,2015,137(2):974-981.
[8]Shi D,Adinolfi V,Comin R,et al.Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals[J].Science,2015,347:519-522.
[9]Fang Yanjun,Dong Qingfeng,Shao Yuchuan,et al.Highly narrowband perovskite single-crystal photodetectors enabled by surface-charge recombination[J].Nature Photonics,2015,9(10):679-686.
[10]Parthiban R,Da-Hye L,Bumjin K,et al.All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications[J].Chemical Communications,2015,52(10):2067.
[11]Ding Jianxu,Du Songjie,Zou Zhiyuan,et al.High detectivity and rapid response in perovskite CsPbBr3 single crystal photo-detector[J].J.of Physical Chemistry C,2017,121(9):4917-4923.
[12]Ng Y F,Jamaludin N F,Yantara N,et al.Rapid crystallization of all-inorganic CsPbBr3 perovskite for highbrightness light-emitting diodes[J].ACS Omega,2017,2(6):2757-2764.
[13]Fu Y,Zhu H,Stoumpos C C,et al.Broad wavelength tunable robust lasing from single-crystal nanowires of cesium lead halide perovskites(CsPbX3,X=Cl,Br,I)[J].ACSNano,2016,10(8):7963-7972.
[14]Li C,Han C,Zhang Y,et al.Enhanced photoresponse of self-powered perovskite photodetector based on ZnOnanoparticles decorated CsPbBr3 films[J].Solar Energy Materials&Solar Cells,2017,172:341-346.
[15]Yakunin S,Drin D N,Shynkarenko Y,et al.Detection of gamma photons using solution-grown single crystals of hybrid lead halide perovskites[J].Nature Photonics,2016,139:585-589.
[16]Saidaminov M I,Haque M A,Almutlag J,et al.Inorganic lead halide pervoskite single crystals:phase-selective lowtemperature growth,carrier transport properties and selfpowered photodetection[J].Adv.Opt.Mater.,2017,5(2):1600704.
[17]Kim H S,Im S H,Park N G.Organolead halide perovskite:new horizons in solar cell research[J].J.of Physical Chemistry C,2014,118(11):5615-5625.
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[19]Green M A,Baillie A H,Snaith H J,et al.The emergence of perovskite solar cells[J].Nature Photonics,2014,8(7):506-514.
[20]Zhang Hongjian,Liu Xin,Dong Jiangpeng.Centimeter-sized inorganic lead halide perovskite CsPbBr3crystals grown by an improved solution method[J].Crystal Growth&Design,2017,12:6426-6431.
[21]Heidrich K,Kunzel H,Treusch J,et al.Optical properties and electronic structure of CsPbCl3and CsPbBr3[J].Solid State Commun.,1978,25(11):887-889.
[22]Fujii Y,Hoshino S,Yamada Y,et al.Neutron-scattering study on phase transitions of CsPbCl3[J].Phys.Rev.B,1974,9(10):4549-4559.
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[28]Kadro J M,Nonomura K,Gachet D,et al.Facile route to freestanding CH3NH3PbI3 crystals using inverse solubility[J].Scientific Reports,2015,5:11654.
[29]Dong Yuhui,Gu Yu,Zou Yousheng,et al.Improving allinorganic perovskite photodetectors by preferred orientation and plasmonic effect[J].Small,2016,12:5622-5632.
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[34]Fu A,Yang P.Organic-inorganic perovskites:lower threshold for nanowire lasers[J].Nature Materials,2015,14(6):557-558.
[35]Kasap S,Frey J B,Belev G,et al.Amorphous and polycrystalline photoconductors for direct conversion fat panel X-ray image sensors[J].Sensors,2011,11(12):5112-5157.
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[38]He Y,Matei L,Jung H J,et al.High spectral resolution of gamma-rays at room temperature by perovskite CsPbBr3single crystals[J].Nature Commun.,2018,9(1):1609.
[39]Takahashi T,Watanabe S.Recent progress in CdTe and CdZnTe detectors[J].IEEE Trans.on Nuclear Science,2002,48(4):950-959.