LB膜的制备及表征研究进展
|
摘要
LB膜技术是基于分子水平制备精确有序、厚度可控的超薄膜的先进技术,广泛应用于组装纳米功能材料和分子器件。介绍了LB膜技术的研究发展历程,综述了LB膜的制备方法、制备过程和表征手段,对LB膜技术未来发展趋势进行了展望。
LB film technology is a kind of advanced technology based on molecular level to prepare ultrathin film with controlled thickness,which is widely applied to assembly nano-functional materials and molecular devices.The development process of LB film was introduced,as well as the preparation method,structure type and characterization were summarized.Furthermore,the development trend of LB film technology in the future was also discussed.
LB film technology is a kind of advanced technology based on molecular level to prepare ultrathin film with controlled thickness,which is widely applied to assembly nano-functional materials and molecular devices.The development process of LB film was introduced,as well as the preparation method,structure type and characterization were summarized.Furthermore,the development trend of LB film technology in the future was also discussed.
引文
[1]Liaw Der-Jang,Wang Kungli,Huang Yingchi.Advanced polyimide materials:syntheses,physical properties and applications[J].Progress in Polymer Science,2012,37(7):907-974.
[2]Sharpe W N,Yuan B,Edwards R L.A new technique for measuring the mechanical properties of thin films[J].J Microelectromechanical Systems,1997,6(3):193-199.
[3]Piosik Emilia,Synak Anna,Martynski Tomasz.Influence of chlorine atoms in bay positions of perylene-tetracarboxylic acids on their spectral properties in Langmuir-Blodgett films[J].Spectrochim Acta A,2018(189):374-380.
[4]Langmuir.Constitution and fundamental properties of solids and liquids.Ⅱ.Liquids[J].J Am Chem Soc,1917,39:1848-1906.
[5]Blodgett K B.Films built by depositing successive monomolecular layer on a solide surface[J].J Am Chem Soc,1935,57(6):1007-1022.
[6]Ulman A.Formation and structure of self-assembled monolayers[J].Chem Rev,1996,96:1533-1554.
[7]Matsui J,Mitusishi M,Miyashita T.Characterization of the molecular enviroment of polymer Langmuir-Blodgett films using apyrene fluorescent probe[J].Macromolecules,1999(32):381-385.
[8]欧阳健明.LB膜原理与应用[M].广州:暨南大学出版社,1999:1-4.
[9]Niehaus J C,Hirtz M,Brinks M K.Patterning of functional compounds by multicomponent Langmuir-Blodgett transfer and subsequent chemical modification[J].Langmuir,2010,26(19):15388-15393.
[10]Ulman A.An introduction to ultrathin organic films[M].Boston:Academic Press,1991:22-25.
[11]Saha Mitu,Shil Ashis,Hussain S A,et al.Clay induced changes in the aggregation pattern of safranine-O in hybrid Langmuir-Blogdgett(LB)films[J].J Photoch Photobio A,2017,348:199-208.
[12]Kursunlu Ahmed Nuri,Acikbas Yaser,Ozmen Mustafa,et al.Preparation of pillar 5ene-quinoline Langmuir-Blodgett thin films for detection of volatile organic compounds with hostguest principles[J].Analyst,2017,142(19):3689-3698.
[13]Schoeler U,Tews K H,Kuhn H.Potential model of dye molecule from measurements of the photocurrent in monolayer assemblies[J].J Chem Phys,1974,61:5009-5016.
[14]Tian C Y,Fendler J H.Langmuir-Blodgett film formation from fluorescence-activated,surfactant-capped,size-selected CdS nano-particles spread on water surfaces[J].Chem Mater,1996,8(6):969-974.
[15]Miyashita T.Recent studies on functional ultrathin polymer films prepared by the Langmuir-Blodgett technique[J].Prog Polym Sic,1993(18):263-272.
[16]Bubeck C.Preparation and characterization of mono-and multilayers[J].Polym J,1991,23(5):603-606.
[17]Myagkov I V,Mazurina E A.The role of the electrostatic energy of molecular dipoles in the formation of polar LB films[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2002,198-200:89-99.
[18]许文俭,李铁生,任方方,等.利用Langmuir技术构筑的光抗蚀剂聚合物纳米薄膜的表面微观结构及在光刻蚀方面的应用(Ⅰ):气液界面上聚合物单分子膜表面行为的研究[J].中州大学学报,2009,26(2):103-107.
[19]Debnath Pintu,Chakraborty Santanu,Deb Subrata,et al.Effect of nanoclay Laponite on stability of SHG active Jaggregate of a thiacyanine dye onto LB films[J].Applied Clay Science,2017,147:105-116.
[20]Modlinska Anna,Filipowicz Marek,Martynski Tomasz.Bulk organisation and alignment in Langmuir and LangmuirBlodgett films of tetrachloroperylene tetracarboxylic acid esters[J].J Mol Struct,2016,1125(5):680-687.
[21]谢丹,蒋亚东,李丹,等.聚苯胺基LB膜的制备及气敏特性的研究[J].高分子学报,2001(2):224-227.
[22]Laschewsky A,Ringsdorf H.Polymerization of amphiphilic dienes in Langmuir-Blodgett multilayers[J].Macromolecules,1988,21(7):1936-1941.
[23]Li T S,Mitsubishi M,Tokuji M.Ultrathin polymer LangmuirBlodgett films for microlithography[J].Thin Solid Films,2004,446(1):138-142.
[24]范迎菊,陈艳丽,王雪莹,等.稀土三酞菁夹心化合物混合LB膜的研究[J].无机化学学报,2004,20(10):1197-1202.
[25]许文俭,李铁生,曾国良,等.含萘基的光抗蚀剂超薄膜的显影和光分解性质的研究[C].第六届中国功能材料及其应用学术会议论文集,2007:253-256.
[26]Li J Y,Luo Y,Bai M J,et al.Nanomesa and nanowell formation in Langmuir-Blodgett polyvinylidene fluoride trifluoroethylene copolymer films[J].Appl Phys Lett,2005,87(21):213116.
[27]Guo X,Zhang L,Lu G Y,et al.Interfacial behaviors of azocalixarene derivatives at the air/water interface and photochromism in the Langmuir-Blodgett films[J].Chinese Chem Lett,2005,16(11):1543-1546.
[28]张兆慧,韩奎,曹娟,等.有机分子超薄膜的结构对摩擦的影响[J].物理学报,2002,61(2):28701-28707.
[29]Fukuda K,Nakahara H.Formation of molecular structures by the buildup of films and the function of these structures[J].Kagaku Sosetsu,1983,40:82-104.
[30]Batirov T M,Verkhovskaya K A,Vizdrik G V,et al.Photoconductor ferroelectric structure of ultrathin Langmuir Blodgett films[J].Ferroelectrics Letters,2002,29(1):1-4.
[31]张晓静,贾天刚,韩志超,等.一种含苯并菲侧基的“毛-棒”状梯形聚倍半硅氧烷LB膜研究[J].高分子学报,2009(6):506-512.
[32]王文军,吴成,高学喜,等.NMOB分子LB膜的光谱及其非线性光学特性研究[J].中国激光,2005,32(8):1123-1126.
[33]马世红,陆兴泽,王恭明,等.半花菁/氮冠(醚)交替LB多层膜的二阶光学非线性性质[J].光学学报,1997,17(9):153-1158.
[34]李铁生,尚巍,毛陆原,等.新型两亲性铕配合物LB膜的性质研究[C].第六届中国功能材料及其应用学术会议论文集,2007:2354-2355.
[35]王筠,杨志广,杨欢欢,等.单组分化学增幅型光致抗蚀剂LB膜的制备及光刻应用[J].化工新型材料,2015,43(8):228-230.
[36]Pablop J,Schaapia T,Schmidt C F.Observation of micmtubules with scanning force microscopy in liquid[J].Nanotechnology,2003,14(2):143-146.
[37]何平笙,李春娥.Langmuir-Blodgett膜的低角X射线衍射分析[J].功能材料,2001,32(2):220-222.
[38]Ohkita M,Higuchi M,Kawaguchi M.AFM studies on LBfilms of poly(n-hexyl isocyanate),poly(vinyl acetate),and their binary mixtures[J].J Colliod Interf Sci,2005,292(1):300-303.
[39]Valli L.Phthalocyanine-based Langmuir-Blodgett films as chemical sensors[J].Adv Colloid Interfac,2005,116(1/2/3):13-44.
[40]Geoffrey J A.Langmuir-Blodgett films:molecular engineer of non-centrosymmetric structures for second-ordernonlinear optical applications[J].J Mater Chem,1999(9):1991-2003.
[41]曾昊,高峰,马世红.新型花菁染料Langmuir-Blodgett膜的椭偏光谱研究[J].物理学报,2008,57(5):3113-3118.
[42]黄春辉.光电功能超薄膜[M].北京:北京大学出版社,2001.
[2]Sharpe W N,Yuan B,Edwards R L.A new technique for measuring the mechanical properties of thin films[J].J Microelectromechanical Systems,1997,6(3):193-199.
[3]Piosik Emilia,Synak Anna,Martynski Tomasz.Influence of chlorine atoms in bay positions of perylene-tetracarboxylic acids on their spectral properties in Langmuir-Blodgett films[J].Spectrochim Acta A,2018(189):374-380.
[4]Langmuir.Constitution and fundamental properties of solids and liquids.Ⅱ.Liquids[J].J Am Chem Soc,1917,39:1848-1906.
[5]Blodgett K B.Films built by depositing successive monomolecular layer on a solide surface[J].J Am Chem Soc,1935,57(6):1007-1022.
[6]Ulman A.Formation and structure of self-assembled monolayers[J].Chem Rev,1996,96:1533-1554.
[7]Matsui J,Mitusishi M,Miyashita T.Characterization of the molecular enviroment of polymer Langmuir-Blodgett films using apyrene fluorescent probe[J].Macromolecules,1999(32):381-385.
[8]欧阳健明.LB膜原理与应用[M].广州:暨南大学出版社,1999:1-4.
[9]Niehaus J C,Hirtz M,Brinks M K.Patterning of functional compounds by multicomponent Langmuir-Blodgett transfer and subsequent chemical modification[J].Langmuir,2010,26(19):15388-15393.
[10]Ulman A.An introduction to ultrathin organic films[M].Boston:Academic Press,1991:22-25.
[11]Saha Mitu,Shil Ashis,Hussain S A,et al.Clay induced changes in the aggregation pattern of safranine-O in hybrid Langmuir-Blogdgett(LB)films[J].J Photoch Photobio A,2017,348:199-208.
[12]Kursunlu Ahmed Nuri,Acikbas Yaser,Ozmen Mustafa,et al.Preparation of pillar 5ene-quinoline Langmuir-Blodgett thin films for detection of volatile organic compounds with hostguest principles[J].Analyst,2017,142(19):3689-3698.
[13]Schoeler U,Tews K H,Kuhn H.Potential model of dye molecule from measurements of the photocurrent in monolayer assemblies[J].J Chem Phys,1974,61:5009-5016.
[14]Tian C Y,Fendler J H.Langmuir-Blodgett film formation from fluorescence-activated,surfactant-capped,size-selected CdS nano-particles spread on water surfaces[J].Chem Mater,1996,8(6):969-974.
[15]Miyashita T.Recent studies on functional ultrathin polymer films prepared by the Langmuir-Blodgett technique[J].Prog Polym Sic,1993(18):263-272.
[16]Bubeck C.Preparation and characterization of mono-and multilayers[J].Polym J,1991,23(5):603-606.
[17]Myagkov I V,Mazurina E A.The role of the electrostatic energy of molecular dipoles in the formation of polar LB films[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2002,198-200:89-99.
[18]许文俭,李铁生,任方方,等.利用Langmuir技术构筑的光抗蚀剂聚合物纳米薄膜的表面微观结构及在光刻蚀方面的应用(Ⅰ):气液界面上聚合物单分子膜表面行为的研究[J].中州大学学报,2009,26(2):103-107.
[19]Debnath Pintu,Chakraborty Santanu,Deb Subrata,et al.Effect of nanoclay Laponite on stability of SHG active Jaggregate of a thiacyanine dye onto LB films[J].Applied Clay Science,2017,147:105-116.
[20]Modlinska Anna,Filipowicz Marek,Martynski Tomasz.Bulk organisation and alignment in Langmuir and LangmuirBlodgett films of tetrachloroperylene tetracarboxylic acid esters[J].J Mol Struct,2016,1125(5):680-687.
[21]谢丹,蒋亚东,李丹,等.聚苯胺基LB膜的制备及气敏特性的研究[J].高分子学报,2001(2):224-227.
[22]Laschewsky A,Ringsdorf H.Polymerization of amphiphilic dienes in Langmuir-Blodgett multilayers[J].Macromolecules,1988,21(7):1936-1941.
[23]Li T S,Mitsubishi M,Tokuji M.Ultrathin polymer LangmuirBlodgett films for microlithography[J].Thin Solid Films,2004,446(1):138-142.
[24]范迎菊,陈艳丽,王雪莹,等.稀土三酞菁夹心化合物混合LB膜的研究[J].无机化学学报,2004,20(10):1197-1202.
[25]许文俭,李铁生,曾国良,等.含萘基的光抗蚀剂超薄膜的显影和光分解性质的研究[C].第六届中国功能材料及其应用学术会议论文集,2007:253-256.
[26]Li J Y,Luo Y,Bai M J,et al.Nanomesa and nanowell formation in Langmuir-Blodgett polyvinylidene fluoride trifluoroethylene copolymer films[J].Appl Phys Lett,2005,87(21):213116.
[27]Guo X,Zhang L,Lu G Y,et al.Interfacial behaviors of azocalixarene derivatives at the air/water interface and photochromism in the Langmuir-Blodgett films[J].Chinese Chem Lett,2005,16(11):1543-1546.
[28]张兆慧,韩奎,曹娟,等.有机分子超薄膜的结构对摩擦的影响[J].物理学报,2002,61(2):28701-28707.
[29]Fukuda K,Nakahara H.Formation of molecular structures by the buildup of films and the function of these structures[J].Kagaku Sosetsu,1983,40:82-104.
[30]Batirov T M,Verkhovskaya K A,Vizdrik G V,et al.Photoconductor ferroelectric structure of ultrathin Langmuir Blodgett films[J].Ferroelectrics Letters,2002,29(1):1-4.
[31]张晓静,贾天刚,韩志超,等.一种含苯并菲侧基的“毛-棒”状梯形聚倍半硅氧烷LB膜研究[J].高分子学报,2009(6):506-512.
[32]王文军,吴成,高学喜,等.NMOB分子LB膜的光谱及其非线性光学特性研究[J].中国激光,2005,32(8):1123-1126.
[33]马世红,陆兴泽,王恭明,等.半花菁/氮冠(醚)交替LB多层膜的二阶光学非线性性质[J].光学学报,1997,17(9):153-1158.
[34]李铁生,尚巍,毛陆原,等.新型两亲性铕配合物LB膜的性质研究[C].第六届中国功能材料及其应用学术会议论文集,2007:2354-2355.
[35]王筠,杨志广,杨欢欢,等.单组分化学增幅型光致抗蚀剂LB膜的制备及光刻应用[J].化工新型材料,2015,43(8):228-230.
[36]Pablop J,Schaapia T,Schmidt C F.Observation of micmtubules with scanning force microscopy in liquid[J].Nanotechnology,2003,14(2):143-146.
[37]何平笙,李春娥.Langmuir-Blodgett膜的低角X射线衍射分析[J].功能材料,2001,32(2):220-222.
[38]Ohkita M,Higuchi M,Kawaguchi M.AFM studies on LBfilms of poly(n-hexyl isocyanate),poly(vinyl acetate),and their binary mixtures[J].J Colliod Interf Sci,2005,292(1):300-303.
[39]Valli L.Phthalocyanine-based Langmuir-Blodgett films as chemical sensors[J].Adv Colloid Interfac,2005,116(1/2/3):13-44.
[40]Geoffrey J A.Langmuir-Blodgett films:molecular engineer of non-centrosymmetric structures for second-ordernonlinear optical applications[J].J Mater Chem,1999(9):1991-2003.
[41]曾昊,高峰,马世红.新型花菁染料Langmuir-Blodgett膜的椭偏光谱研究[J].物理学报,2008,57(5):3113-3118.
[42]黄春辉.光电功能超薄膜[M].北京:北京大学出版社,2001.