锂离子电池隔膜改性研究现状
|
摘要
针对现有的锂离子电池隔膜在吸液率、强度和安全性等方面存在的不足,提出了其改性的必要性;综述了锂离子电池隔膜接枝改性、复合改性、共混和填充改性等改性方法,并对各种改性方法进行了分析;指出在改性研究的同时,应开发新的电池隔膜制备方法,如静电纺丝技术等;建议开发新的电池隔膜材料,以提高电池隔膜性能,制备具有特殊性能的锂离子电池隔膜。
The modification necessity of separators for lithium-ion batteries was put forward to improve the electrolyte uptake,strength and safety. The modification techniques for battery separators were reviewed and analyzed,including graft modification,composite modification,blending modification and filling modification. It was pointed out that the modification techniques and the production technologies,such as electrospinning process,should be simultaneously developed. It was also suggested that novel materials for battery separator should be developed to improve the properties of battery separator and contribute special properties to the lithium-ion battery separator.
The modification necessity of separators for lithium-ion batteries was put forward to improve the electrolyte uptake,strength and safety. The modification techniques for battery separators were reviewed and analyzed,including graft modification,composite modification,blending modification and filling modification. It was pointed out that the modification techniques and the production technologies,such as electrospinning process,should be simultaneously developed. It was also suggested that novel materials for battery separator should be developed to improve the properties of battery separator and contribute special properties to the lithium-ion battery separator.
引文
[1]梁银峥.基于静电纺纤维的先进锂离子电池隔膜材料的研究[D].上海:东华大学,2011.
[2]黄友桥,管道安.锂离子电池隔膜材料的研究进展[J].船电技术,2011,31(1):26-29.
[3]张传文,严玉蓉,区炜锋,等.静电纺丝法制备锂离子电池隔膜的研究进展[J].产业用纺织品,2009,14(1):1-6.
[4]Lee J Y,Lee Y M,Bhattacharya B,et al.Separator grafted with siloxane by electron beam irradiation for lithium secondary batteries[J].Electrochim Acta,2009,54(18):4312-4315.
[5]张志强,李华,吕晓渊,等.紫外光辐照接枝MMA改性锂离子电池PE隔膜[J].功能高分子学报,2011,24(4):398-403.
[6]吕晓渊,李华,张志强,等.锂离子电池隔膜的紫外辐照接枝改性[J].功能材料,2012,43(1):112-115.
[7]Song M K,Kim Y T,Cho J Y,et al.Composite polymer electrolytes reinforced by non-woven fabrics[J].J Power Sources,2004,125(1):10-16.
[8]苑洪铭,李吉豪,于洋,等.PVDF粉体预辐照接枝甲基丙烯酸缩水甘油酯制备锂离子二次电池隔膜研究[J].辐射研究与辐射工艺学报,2011,29(5):266-270.
[9]Choi S S,Lee Y S,Joo C W,et al.Electrospun PVDF nanofiber web as polymer electrolyte or separator[J].Electrochim Acta,2004,50(2/3):339-343.
[10]宋兆爽,邱景义,马建伟,等.锂离子电池用无纺布支撑聚合物复合膜的制备[J].北京大学学报:自然科学版,2006,42(12):44-47.
[11]唐定国,刘建红,其鲁,等.无纺布支撑聚合物凝胶电解质锂离子电池[J].科学通报,2004,49(22):2290-2293.
[12]程琥,杜洪彦,杨勇.新型锂电池用复合隔膜的制备及其电化学性能表征[J].电化学,2004,10(3):303-306.
[13]刘立健.锂离子电池涂膜隔膜的机理分析[J].山东化工,2012,41(4):69-72.
[14]Kim J Y,Kim S K,Lee S J,et al.Preparation of micro-porous gel polymer for lithium ion polymer battery[J].Electrochim Acta,2004,50(2/3):363-366.
[15]Sannier L,Bouchet R,Grugeon S,et al.Room temperature lithium metal batteries based on a new gel polymer Electrolyte membrane[J].J Power Sources,2005,144(1):231-237.
[16]Huang Xiaosong.Development and characterization of a bilayer separator for lithium ion batteries[J].J Power Sources,2011,196(19):8125-8128.
[17]Zhang H P,Zhang P,Li Z H,et al.A novel sandwiched membrane as polymer electrolyte for lithium ion battery[J].Electrochem Commun,2007,9(7):1700-1703.
[18]Gopalan A I,Santhosh P,Manesh K M,et al.Development of electrospun PVDF-PAN membrane-based polymer electrolytes for lithium batteries[J].J Membr Sci,2008,325(2):683-690.
[19]Xi Jingyu,Qiu Xinping,Li Jian,et al.PVDF-PEO blends based microporous polymer electrolyte:Effect of PEO on pore configurations and ionic conductivity[J].J Power Sources,2006,157(1):501-506.
[20]Gopalan A I,Lee K P,Manesh K M,et al.Poly(vinylidene fluoride)-polydiphenylamine composite electrospun membrane as high-performance polymer electrolyte for lithium batteries[J].J Membr Sci,2008,318(1/2):422-428.
[21]Ding Yanhuai,Zhang Ping,Long Zhilin,et al.The ionic conductivity and mechanical property of electrospun P(VDFHFP)/PMMA membranes for lithium ion batteries[J].J Membr Sci,2009,329(1/2):56-59.
[22]Li Hao,Ma Xiaoting,Shi Junli,et al.Preparation and properties of poly(ethylene oxide)gel filled polypropylene separators and their corresponding gel polymer electrolytes for Li-ion batteries[J].Electrochim Acta,2011,56(6):2641-2647.
[23]Li Hao,Chen Yueming,Ma Xiaoting,et al.Gel polymer electrolytes based on active PVDF separator for lithium ion battery.I:Preparation and property of PVDF/poly(dimethylsiloxane)blending membrane[J].J Membr Sci,2011,379(1/2):397-402.
[24]Fisher A S,Khalid M B,Widstrom M,et al.Solid polymer electrolytes with sulfur based ionic liquid for lithium batteries[J].J Power Sources,2011,196(22):9767-9773.
[25]Michael M S,Prabaharan S R S.Rechargeable lithium battery employing a new ambient temperature hybrid polymer electrolyte based on PVK+PVdF-HFP(copolymer)[J].J Power Sources,2004,136(2):408-415.
[26]孙涛,周明阳,李新松.PVDF/PANI-TSA复合纤维膜的电纺制备及电性能[J].化工时刊,2007,21(1):9-11.
[27]Cao Jianhua,Zhu Baoku,Xu Youyi.Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes[J].J Membr Sci,2006,281(1/2):446-453.
[28]Mohamed N S,Arof A K.Investigation of electrical and electrochemical properties of PVDF-based polymer electrolytes[J].J Power Sources,2004,132(1/2):229-234.
[29]Subramania A,Kalyana Sundaram N T,Sathiya Priya A R,et al.Preparation of a novel composite micro-porous polymer electrolyte membrane for high performance Li-ion battery[J].J Membr Sci,2007,294(1/2):8-15.
[30]冯华君,陈渊,代克化,等.一种新型锂离子电池用聚合物电解质复合膜的制备和性能表征[J].物理化学学报,2007,23(12):1922-1926.
[31]Deka M,Kumar A.Electrical and electrochemical studies of poly(vinylidene fluoride)-clay nanocomposite gel polymer electrolytes for Li-ion batteries[J].J Power Sources,2011,196(3):1358-1364.
[32]Prosini P P,Villano P,Carewska M.A novel intrinsically porous separator for self-standing lithium-ion batteries[J].Electrochim Acta,2002,48(3):227-233.
[33]Manuel Stephan A,Nahm K S,Prem Kumar T,et al.Nanofiller incorporated poly(vinylidene fluoride-hexafluoropropylene)(PVdF-HFP)composite electrolytes for lithium batteries[J].J Power Sources,2006,159(2):1316-1321.
[34]李立,苑克国,张育川,等.二次锂电池用PVDF-HFP/SiO2复合聚合物隔膜的研究[J].北京化工大学学报:自然科学版,2006,33(2):55-58.
[35]Kim J K,Cheruvally G,Li X,et al.Preparation and electrochemical characterization of electrospun,microporous membrane-based composite polymer electrolytes for lithium batteries[J].J Power Sources,2008,178(2):815-820.
[36]石桥,黄薇,周啸,等.水蒸气沉淀法制备SiO2/偏氟乙烯六氟丙烯共聚物复合微孔型聚合物电解质的研究[J].高分子学报,2004(3):350-354.
[37]白莹,吴川,吴锋,等.纳米SiO2对聚合物隔膜的影响[J].电池,2006,36(3):165-167.
[38]王洪,邓璋琼,陈鸣才.一种用于锂离子电池的无机复合隔膜[J].复合材料学报,2009,26(1):59-64.
[39]Li Zhaohui,Su Guangyao,Wang Xiayu,et al.Micro-porous P(VDF-HFP)-based polymer electrolyte filled with Al2O3nanoparticles[J].Solid State Ionics.2005,176(23/24):1903-1908.
[40]Takemura D,Aihara S,Hamano K,et al.A powder particle size effect on ceramic powder based separator for lithium rechargeable battery[J].J Power Sources,2005,146(1/2):779-783.
[41]Li Z H,Zhang H P,Zhang P,et al.Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries[J].J Membr Sci,2008,322(2):416-422.
[42]韩领.静电纺丝法制备无机改性锂离子电池隔膜[D].大连:大连理工大学,2012.
[43]Gao Kun,Hu Xinguo,Dai Chongsong,et al.Crystal structures of electrospun PVDF membranes and its separator application for rechargeable lithium metal cells[J].Mater Sci Eng B,2006,131(1/2/3):100-105.
[44]李月姣,胡仁超,吴锋,等.聚氧化乙烯-聚硅氧烷基离子液体复合聚合物电解质的研究[J].功能材料,2012,43(4):525-528.
[2]黄友桥,管道安.锂离子电池隔膜材料的研究进展[J].船电技术,2011,31(1):26-29.
[3]张传文,严玉蓉,区炜锋,等.静电纺丝法制备锂离子电池隔膜的研究进展[J].产业用纺织品,2009,14(1):1-6.
[4]Lee J Y,Lee Y M,Bhattacharya B,et al.Separator grafted with siloxane by electron beam irradiation for lithium secondary batteries[J].Electrochim Acta,2009,54(18):4312-4315.
[5]张志强,李华,吕晓渊,等.紫外光辐照接枝MMA改性锂离子电池PE隔膜[J].功能高分子学报,2011,24(4):398-403.
[6]吕晓渊,李华,张志强,等.锂离子电池隔膜的紫外辐照接枝改性[J].功能材料,2012,43(1):112-115.
[7]Song M K,Kim Y T,Cho J Y,et al.Composite polymer electrolytes reinforced by non-woven fabrics[J].J Power Sources,2004,125(1):10-16.
[8]苑洪铭,李吉豪,于洋,等.PVDF粉体预辐照接枝甲基丙烯酸缩水甘油酯制备锂离子二次电池隔膜研究[J].辐射研究与辐射工艺学报,2011,29(5):266-270.
[9]Choi S S,Lee Y S,Joo C W,et al.Electrospun PVDF nanofiber web as polymer electrolyte or separator[J].Electrochim Acta,2004,50(2/3):339-343.
[10]宋兆爽,邱景义,马建伟,等.锂离子电池用无纺布支撑聚合物复合膜的制备[J].北京大学学报:自然科学版,2006,42(12):44-47.
[11]唐定国,刘建红,其鲁,等.无纺布支撑聚合物凝胶电解质锂离子电池[J].科学通报,2004,49(22):2290-2293.
[12]程琥,杜洪彦,杨勇.新型锂电池用复合隔膜的制备及其电化学性能表征[J].电化学,2004,10(3):303-306.
[13]刘立健.锂离子电池涂膜隔膜的机理分析[J].山东化工,2012,41(4):69-72.
[14]Kim J Y,Kim S K,Lee S J,et al.Preparation of micro-porous gel polymer for lithium ion polymer battery[J].Electrochim Acta,2004,50(2/3):363-366.
[15]Sannier L,Bouchet R,Grugeon S,et al.Room temperature lithium metal batteries based on a new gel polymer Electrolyte membrane[J].J Power Sources,2005,144(1):231-237.
[16]Huang Xiaosong.Development and characterization of a bilayer separator for lithium ion batteries[J].J Power Sources,2011,196(19):8125-8128.
[17]Zhang H P,Zhang P,Li Z H,et al.A novel sandwiched membrane as polymer electrolyte for lithium ion battery[J].Electrochem Commun,2007,9(7):1700-1703.
[18]Gopalan A I,Santhosh P,Manesh K M,et al.Development of electrospun PVDF-PAN membrane-based polymer electrolytes for lithium batteries[J].J Membr Sci,2008,325(2):683-690.
[19]Xi Jingyu,Qiu Xinping,Li Jian,et al.PVDF-PEO blends based microporous polymer electrolyte:Effect of PEO on pore configurations and ionic conductivity[J].J Power Sources,2006,157(1):501-506.
[20]Gopalan A I,Lee K P,Manesh K M,et al.Poly(vinylidene fluoride)-polydiphenylamine composite electrospun membrane as high-performance polymer electrolyte for lithium batteries[J].J Membr Sci,2008,318(1/2):422-428.
[21]Ding Yanhuai,Zhang Ping,Long Zhilin,et al.The ionic conductivity and mechanical property of electrospun P(VDFHFP)/PMMA membranes for lithium ion batteries[J].J Membr Sci,2009,329(1/2):56-59.
[22]Li Hao,Ma Xiaoting,Shi Junli,et al.Preparation and properties of poly(ethylene oxide)gel filled polypropylene separators and their corresponding gel polymer electrolytes for Li-ion batteries[J].Electrochim Acta,2011,56(6):2641-2647.
[23]Li Hao,Chen Yueming,Ma Xiaoting,et al.Gel polymer electrolytes based on active PVDF separator for lithium ion battery.I:Preparation and property of PVDF/poly(dimethylsiloxane)blending membrane[J].J Membr Sci,2011,379(1/2):397-402.
[24]Fisher A S,Khalid M B,Widstrom M,et al.Solid polymer electrolytes with sulfur based ionic liquid for lithium batteries[J].J Power Sources,2011,196(22):9767-9773.
[25]Michael M S,Prabaharan S R S.Rechargeable lithium battery employing a new ambient temperature hybrid polymer electrolyte based on PVK+PVdF-HFP(copolymer)[J].J Power Sources,2004,136(2):408-415.
[26]孙涛,周明阳,李新松.PVDF/PANI-TSA复合纤维膜的电纺制备及电性能[J].化工时刊,2007,21(1):9-11.
[27]Cao Jianhua,Zhu Baoku,Xu Youyi.Structure and ionic conductivity of porous polymer electrolytes based on PVDF-HFP copolymer membranes[J].J Membr Sci,2006,281(1/2):446-453.
[28]Mohamed N S,Arof A K.Investigation of electrical and electrochemical properties of PVDF-based polymer electrolytes[J].J Power Sources,2004,132(1/2):229-234.
[29]Subramania A,Kalyana Sundaram N T,Sathiya Priya A R,et al.Preparation of a novel composite micro-porous polymer electrolyte membrane for high performance Li-ion battery[J].J Membr Sci,2007,294(1/2):8-15.
[30]冯华君,陈渊,代克化,等.一种新型锂离子电池用聚合物电解质复合膜的制备和性能表征[J].物理化学学报,2007,23(12):1922-1926.
[31]Deka M,Kumar A.Electrical and electrochemical studies of poly(vinylidene fluoride)-clay nanocomposite gel polymer electrolytes for Li-ion batteries[J].J Power Sources,2011,196(3):1358-1364.
[32]Prosini P P,Villano P,Carewska M.A novel intrinsically porous separator for self-standing lithium-ion batteries[J].Electrochim Acta,2002,48(3):227-233.
[33]Manuel Stephan A,Nahm K S,Prem Kumar T,et al.Nanofiller incorporated poly(vinylidene fluoride-hexafluoropropylene)(PVdF-HFP)composite electrolytes for lithium batteries[J].J Power Sources,2006,159(2):1316-1321.
[34]李立,苑克国,张育川,等.二次锂电池用PVDF-HFP/SiO2复合聚合物隔膜的研究[J].北京化工大学学报:自然科学版,2006,33(2):55-58.
[35]Kim J K,Cheruvally G,Li X,et al.Preparation and electrochemical characterization of electrospun,microporous membrane-based composite polymer electrolytes for lithium batteries[J].J Power Sources,2008,178(2):815-820.
[36]石桥,黄薇,周啸,等.水蒸气沉淀法制备SiO2/偏氟乙烯六氟丙烯共聚物复合微孔型聚合物电解质的研究[J].高分子学报,2004(3):350-354.
[37]白莹,吴川,吴锋,等.纳米SiO2对聚合物隔膜的影响[J].电池,2006,36(3):165-167.
[38]王洪,邓璋琼,陈鸣才.一种用于锂离子电池的无机复合隔膜[J].复合材料学报,2009,26(1):59-64.
[39]Li Zhaohui,Su Guangyao,Wang Xiayu,et al.Micro-porous P(VDF-HFP)-based polymer electrolyte filled with Al2O3nanoparticles[J].Solid State Ionics.2005,176(23/24):1903-1908.
[40]Takemura D,Aihara S,Hamano K,et al.A powder particle size effect on ceramic powder based separator for lithium rechargeable battery[J].J Power Sources,2005,146(1/2):779-783.
[41]Li Z H,Zhang H P,Zhang P,et al.Effects of the porous structure on conductivity of nanocomposite polymer electrolyte for lithium ion batteries[J].J Membr Sci,2008,322(2):416-422.
[42]韩领.静电纺丝法制备无机改性锂离子电池隔膜[D].大连:大连理工大学,2012.
[43]Gao Kun,Hu Xinguo,Dai Chongsong,et al.Crystal structures of electrospun PVDF membranes and its separator application for rechargeable lithium metal cells[J].Mater Sci Eng B,2006,131(1/2/3):100-105.
[44]李月姣,胡仁超,吴锋,等.聚氧化乙烯-聚硅氧烷基离子液体复合聚合物电解质的研究[J].功能材料,2012,43(4):525-528.