BaBPO_5和(H_3O)Zn(H_2O)_2BP_2O_8·H_2O的低温溶剂热合成及表征
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摘要
以乙醇为溶剂,在低温条件下合成出了两种手性硼磷酸盐化合物BaBPO_5(1)(T=120℃,t=5 d)和(H_3O)Zn(H_2O)_2BP_2O_8·H_2O (2)(T=80℃,t=5 d)。XRD单晶衍射仪测定了化合物的结构,结果表明:(1)属三方晶系,P3221空间群,a=b=7. 1162(3)?,c=6. 9979 (6)?,Z=3,该晶体含有一维线性链状阴离子结构;(2)属六方晶系,P6122空间群,a=b=9. 513(2)?,c=15. 906(8)?,Z=6。该晶体具有三维骨架结构。实验结果表明使用乙醇作溶剂可以极大降低硼磷酸盐的合成温度,进而有助于获得手性硼磷酸盐化合物,这为手性硼磷酸盐的合成提供了一种新思路。
Ethanol was used as solvent to successfully synthesize two chiral borophosphate compounds BaBPO_5( 1)( T =120 ℃,t = 5 d) and( H_3 O) Zn( H_2 O)_2 BP_2 O_8·H_2 O( 2)( T = 80 ℃,t = 5 d) under low temperature conditions. The crystal structures of the two compounds were measured by X-ray single crystal diffractometer. The results indicate that: the compound( 1) crystallizes in trigonal space group P3221,a = b = 7. 1162( 3) ?,c = 6. 9979( 6) ?,Z = 3. The crystal contains one-dimensional linear chain anionic structure. The compound( 2) crystallizes in hexagonal space group P6122,a =b = 9. 513( 2) ?,c = 15. 906( 8) ?,Z = 6. The crystal has a three-dimensional framework structure. The experimental results show that the synthesis temperature of borophosphates can be greatly reduced by using ethanol as the solvent,which is helpful for the synthesis of chiral borophosphates.
Ethanol was used as solvent to successfully synthesize two chiral borophosphate compounds BaBPO_5( 1)( T =120 ℃,t = 5 d) and( H_3 O) Zn( H_2 O)_2 BP_2 O_8·H_2 O( 2)( T = 80 ℃,t = 5 d) under low temperature conditions. The crystal structures of the two compounds were measured by X-ray single crystal diffractometer. The results indicate that: the compound( 1) crystallizes in trigonal space group P3221,a = b = 7. 1162( 3) ?,c = 6. 9979( 6) ?,Z = 3. The crystal contains one-dimensional linear chain anionic structure. The compound( 2) crystallizes in hexagonal space group P6122,a =b = 9. 513( 2) ?,c = 15. 906( 8) ?,Z = 6. The crystal has a three-dimensional framework structure. The experimental results show that the synthesis temperature of borophosphates can be greatly reduced by using ethanol as the solvent,which is helpful for the synthesis of chiral borophosphates.
引文
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[27] Duan C J,Li W F,Wu X Y,et al. Syntheses and X-ray Excited Luminescence Properties of Ba3BP3O12,BaBPO5and Ba3BPO7[J]. Journal of Luminescence,2006,117(1):83-89.
[28] Pushcharovsky D Y,Gobetchia E R,Pasero M,et al. Hydrothermal Synthesis and Crystal Structures of Li,Ba-nanoborate,Li BaB9O15and Baborophosphate,BaBPO5[J]. Journal of Alloys and Compounds,2002,339(1):70-75.
[29]潘世烈,吴以成,傅佩珍,等. BaBPO5晶体的生长研究[J].人工晶体学报,2002,31(1):1-4.
[30] Shi H Z,Shan Y K,He Y M,et al. Synthesis and Structure of the First Protonated Zincoborophosphate:(H3O)Zn(H2O)2BP2O8·H2O[J].Chinese Journal of Chemistry,2003,21(9):1170-1173.
[2] Wang X A,Fu P Z,Pan S L,et al. Dertermination of the Nonlinear Optical Coefficients of the Borophosphate Crystal BaBPO5[J]. Journal of Synthetic Crystals,2001,36(5):985-990.
[3] Wei Z R,Lu Y,Li X,et al. Preparaton,Structure and Luminescent Propertes of Eu3+Doped MBPO5(M=Ca,Sr,Ba)Red Phosphor for White LED[J]. Journal of Applied Biomaterials&Functional Materials,2016,14,(Suppl. 1):S83-S88.
[4] Ben Ali A,Antic-Fidancev E,Viana B,et al. Crystal Structure of ABPO5and Optical Study of Pr3+Embedded in These Compounds[J]. Journal of Physics Condensed Matter,2001,13(42):9663-9671.
[5] Huang Y X,Ewald B,Schnelle W,et al. Chirality and Magnetism in a Novel Series of Isotypic Borophosphates:MII[BPO4(OH)2](MII)Mn,Fe,Co)[J]. Inorganic Chemistry,2006,45(19):7578-7580.
[6] Zhang W L,He Z Z,Xia T L,et al. Syntheses and Magnetic Properties Study of Isostructural BiM2BP2O10(M=Co,Ni)Containing a Quasi-1D Linear Chain Structure[J]. Inorganic Chemistry,2012,51(16):8842-8847.
[7] Li M,Verena-Mudring A. New Developments in the Synthesis,Structure,and Applications of Borophosphates and Metalloborophosphates[J].Crystal Growth&Design,2016,16(4):2441-2458.
[8] Cheetham A K,Ferey G,Loiseau T. Open-Framework Inorganic Materials[J]. Angewandte Chemie International Edition,1999,38:3268-3292.
[9] Ewald B,Huang Y X,Kniep R. Structural Chemistry of Borophosphates,Metalloborophosphates,and Related Compounds[J]. Zeitschrift für Anorganische und Allgemeine Chemie,2007,633(10):1517-1540.
[10] Kniep R,Engelhardt,H,Hauf C. A First Approach to Borophosphate Structural Chemistry[J]. Chemistry of Materials,1998,10(10):2930-2934.
[11] Klooster H S. Uber das Verhalten der Metabor-und der Metaphosphorsaure in den Schrnelzen Ihrer Alkalisalze[J]. Zeitschrift für Anorganische und Allgemeine Chemie,1911,69(1):122-134.
[12] Zhao D,Cheng W D,Zhang H,et al. KMBP2O8(M=Sr,Ba):A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework[J]. Inorganic Chemistry,2009,48(14):6623-6629.
[13] Zhang W L,Cheng W D,Zhang H,et al. Syntheses and Characterizations of Cs2Cr3(BP4O14)(P4O13)and CsFe(BP3O11)Compounds with Novel Borophosphate Anionic Partial Structures[J]. Inorganic Chemistry,2010,49(5):2550-2556.
[14] Wang Y,Pan S L,Shi Y J. Further Examples of the P-O-P Connection in Borophosphates:Synthesis and Characterization of Li2Cs2B2P4O15,Li K2BP2O8and Li3M2BP4O14(M=K,Rb)[J]. Chemistry-A European Journal,2012,18(38):12046-12051.
[15] Toru H,Hisanori Y. Synthesis,Crystal Structure and Lithium Ion Conduction of Li3BP2O8[J]. Dalton Transactions,2013,43(5):2294-2300.
[16] Hauf C. Ph. D. Dissertation. Technische Hochschule Darmstadt,1997.
[17] Sevov S. C. Synthesis and Structure of CoB2P3O12(OH)·C2H10N2:The First Metal Borophosphate with an Open Framework Structure[J].Angewandte Chemie International Edition,1996,35(22):2630-2631.
[18] Menezes P W,Hoffmann S,Prots Y,et al. Crystal Sstructure of Hemicalcium Diaquairon(II)Catena-(Monoborodiphosphate)Monohydrate,Ca0. 5Fe(H2O)2[BP2O8]·H2O[J]. Zeitschrift fur Kristallographie-New Crystal Structures,2008,223:9-10.
[19] Menezes P W,Hoffmann S,Prots Y,et al. Synthesis and Crystal Structure of CaCo(H2O)[BP2O8(OH)]·H2O[J]. Zeitschrift für Anorganische und Allgemeine Chemie,2009,635:614-617.
[20] Menezes P W, Hoffmann S, Prots Y, et al. Crystal Structure of Calcium Iron(II)Hydrogenmonophosphate-DihydrogenmonoborateMonophosphate,CaFe[BP2O7(OH)3][J]. Zeitschrift Fur Kristallographie-New Crystal Structures,2008,223:335-336.
[21] Guesmi,A,Driss A. KCo(H2O)2BP2O8·0. 48H2O and K0. 17Ca0. 42Co(H2O)2BP2O8·H2O:Two Cobalt Borophosphates with Helical Ribbons and Disordered(K,Ca)/H2O Schemes[J]. Acta Crystallographica Section C:Crystal Structure Communications,2012,C68:i55-i59.
[22] Yang T,Ju J,Liao F H,et al. Chirality and Ferromagnetism in Ni BPO4(OH)2Containinghelix Edge-Sharing Ni O6Chains[J]. Journal of Solid State Chemistry,2008,181:1110-1115.
[23]石恒真,单永奎,何鸣元,等.具有螺旋结构的新型硼磷酸盐化合物:(NH4)0. 5(H3O)0. 5Mg(H2O)2BP2O8[J].化学学报,2003,61(5):711-714.
[24] Liu W,Zhao J T.(NH4)[B3PO6(OH)3]0. 5H2O[J]. Acta Crystallographica,2007,E63:i185.
[25] Song Y,Ding L,An Q D,et al. Synthesis and Characterization of Zinc Borophosphates with ANA-Zeotype Framework by the Microwave Method[J]. Journal of Solid State Chemistry,2013,202(5):300-304.
[26] Bauer H Z.über Eine Reihe Isotyper Erdalkaliboratphosphate und-arsenate vom Typus 2MeO·X2O5·B2O3. II. Die Verbindungen 2BaO·P2O5·B2O3und 2BaO·As2O5·B2O3[J]. Zeitschrift für Anorganische und Allgemeine Chemie,1966,345(5-6):225-229.
[27] Duan C J,Li W F,Wu X Y,et al. Syntheses and X-ray Excited Luminescence Properties of Ba3BP3O12,BaBPO5and Ba3BPO7[J]. Journal of Luminescence,2006,117(1):83-89.
[28] Pushcharovsky D Y,Gobetchia E R,Pasero M,et al. Hydrothermal Synthesis and Crystal Structures of Li,Ba-nanoborate,Li BaB9O15and Baborophosphate,BaBPO5[J]. Journal of Alloys and Compounds,2002,339(1):70-75.
[29]潘世烈,吴以成,傅佩珍,等. BaBPO5晶体的生长研究[J].人工晶体学报,2002,31(1):1-4.
[30] Shi H Z,Shan Y K,He Y M,et al. Synthesis and Structure of the First Protonated Zincoborophosphate:(H3O)Zn(H2O)2BP2O8·H2O[J].Chinese Journal of Chemistry,2003,21(9):1170-1173.