饮用水处理厂锰砂滤料对苯酚的吸附性能及影响因素
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摘要
为了解锰砂滤料对苯酚的吸附性能和影响因素,以生物锰砂滤池运行结束后产生的废料为吸附剂,研究了不同初始p H、温度和溶解氧条件下锰砂滤料对苯酚的吸附性能,通过吸附动力学模型和吸附等温线模型研究其吸附规律。结果表明:锰砂滤料对苯酚的吸附过程符合内扩散动力学模型和Temkin吸附等温线模型,每单分子层吸附,吸附效果主要受苯酚扩散速率影响。通过对吸附等温线n值的计算发现,锰砂滤料容易吸附苯酚。p H对锰砂滤料去除苯酚的影响最大,初始p H为3.0时,苯酚可完全去除,随着初始p H的升高,苯酚的去除率逐渐减小。中性条件下,溶解氧浓度对苯酚的吸附作用影响不大,低温时可通过增加锰砂滤料投加量提高苯酚去除率,每增加1.5倍锰砂滤料,苯酚去除率约增加20个百分点。锰砂滤料可应用于地下水中的苯酚去除,达到废料再利用,不产生二次污染。
In order to understand the adsorption performance and influencing factors of manganese sand filter material on phenol, the waste material produced after the operation of biological manganese sand filter was used as adsorbent. The adsorption performance of manganese sand filter material on phenol under different p H, temperature and dissolved oxygen conditions was studied respectively. The adsorption law of manganese sand filter material was studied by adsorption kinetic model and adsorption isotherm model. The results showed that the adsorption process of manganese sand media for phenol was in accordance with the internal diffusion kinetic model and Temkin isothermal adsorption model, being the monolayer adsorption. The adsorption effect was mainly affected by the diffusion rate of phenol. Through the calculation of n value of adsorption isotherm, it is found that manganese sand filter material is easy to adsorb phenol. The p H had the greatest effect on the removal of phenol from manganese sand filter. When p H = 3. 0, phenol could be removed completely. The removal rate of phenol decreased gradually with the increase of p H. The effect of hypoxia on phenol adsorption was not significant under neutral condition. Theremoval rate of phenol was increased by increasing the dosage of manganese sand filter material under low temperature condition. The removal rate of phenol was increased 20 percent for every 1. 5 times of manganese sand filter material. When that manganese sand filter material is applied to remove phenol from the underground water,the method should achieve the good effect of recycling waste and repairing phenol pollute water body, does not generate secondary pollution phenomenon, and has good application prospects.
In order to understand the adsorption performance and influencing factors of manganese sand filter material on phenol, the waste material produced after the operation of biological manganese sand filter was used as adsorbent. The adsorption performance of manganese sand filter material on phenol under different p H, temperature and dissolved oxygen conditions was studied respectively. The adsorption law of manganese sand filter material was studied by adsorption kinetic model and adsorption isotherm model. The results showed that the adsorption process of manganese sand media for phenol was in accordance with the internal diffusion kinetic model and Temkin isothermal adsorption model, being the monolayer adsorption. The adsorption effect was mainly affected by the diffusion rate of phenol. Through the calculation of n value of adsorption isotherm, it is found that manganese sand filter material is easy to adsorb phenol. The p H had the greatest effect on the removal of phenol from manganese sand filter. When p H = 3. 0, phenol could be removed completely. The removal rate of phenol decreased gradually with the increase of p H. The effect of hypoxia on phenol adsorption was not significant under neutral condition. Theremoval rate of phenol was increased by increasing the dosage of manganese sand filter material under low temperature condition. The removal rate of phenol was increased 20 percent for every 1. 5 times of manganese sand filter material. When that manganese sand filter material is applied to remove phenol from the underground water,the method should achieve the good effect of recycling waste and repairing phenol pollute water body, does not generate secondary pollution phenomenon, and has good application prospects.
引文
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[6]NUHOGLU A,YALCIN B.Modelling of phenol removal in a batch reactor[J].Process Biochemistry,2005,40(3/4):1233-1239.
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[12]MA J,LI H,CHI L,et al.Changes in activation energy and kinetics of heat-activated persulfate oxidation of phenol in response to changes in p H and temperature[J].Chemosphere,2017,189:86-93.
[13]SARAVANAKUMAR K,MUTHURAJ V.Fabrication of sphere like plasmonic Ag/Sn O2,photocatalyst for the degradation of phenol[J].Optik-International Journal for Light and Electron Optics,2016,131:754-763.
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[19]陈焕利,邢宝林,谌伦建,等.有机膨润土对模拟废水中苯酚的吸附特性[J].化工进展,2017,36(2):735-741.CHEN H L,XING B L,CHAN L J,et al.Adsorption of phenol from simulated wastewater by organic bentonite[J].Chemical Industry and Engineering Progress,2017,36(2):735-741.
[20]MOSHE S B,RYTWO G.Thiamine-based organoclay for phenol removal from water[J].Applied Clay Science,2018,155:50-56.
[21]林森,杨维,施爽,等.OH-Fe-有机柱撑膨润土的制备及其对苯酚的吸附试验研究[J].华中师范大学学报(自科版),2010,44(2):264-268.LIN S,YANG W,SHI S,et al.Research on manufacture of the OH-Fe-organo pillaring bentonite and its absorption properties to phenol[J].Journal of Central China Normal University(Natural Sciences),2010,44(2):264-268.
[22]TOURNASSAT C,CHARLET L,BOSBACH D,et al.Arsenic(Ⅲ)oxidation by birnessite and precipitation of manganese(Ⅱ)arsenate[J].Environmental Science&Technology,2002,36(3):493-500.
[23]BRUINS J H,PETRUSEVSKI B,SLOKAR Y M,et al.Biological and physico-chemical formation of Birnessite during the ripening of manganese removal filters[J].Water Research,2015,69:154.
[24]ASMALY H A,ABUSSAUD B,IHSANULLAH,et al.Evaluation of micro and nano carbon-based adsorbents for the removal of Phenol from aqueous solutions[J].Toxicological&Environmental Chemistry,2015,97(9):1164-1179.
[25]杨柳燕,周治,肖琳,等.HDTMA改性蒙脱土吸附苯酚后的化学和生物再生[C]//南京科技学术年会.南京市科协:南京:南京科学技术协会,2005.
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[27]VRIES D,BERTELKAMP C,SCHOONENBERG K F,et al.Iron and manganese removal:recent advances in modelling treatment efficiency by rapid sand filtration[J].Water Research,2016,109:35-45.
[28]李博瑶,罗彤,李欣.不同锰砂滤料除锰吸附特性研究[J].供水技术,2014,8(3):13-16.LI B Y,LUO T,LI X.Adsorption characteristics of different manganese sand filter media[J].Water Technology,2014,8(3):13-16.
[29]梁冠男,廉新颖,贾永锋,等.化学合成及废物基锰氧化物对不同形态砷的去除转化机制[J].环境科学研究,2017,30(10):1622-1629.LIANG G N,LIAN X Y,JIA Y F,et.al.Removal and species transformation mechanism of arsenic by chemical synthetic and waste-based manganese oxides[J].Research of Environmental Sciences,2017,30(10):1622-1629.
[30]BAI Y,CHANG Y,LIANG J,et al.Treatment of groundwater containing Mn(Ⅱ),Fe(Ⅱ),As(Ⅲ)and Sb(Ⅲ)by bioaugmented quartz-sand filters[J].Water Research,2016,106:126-134.
[31]GRSES A,DOG(AR C,YALIN M,et al.The adsorption kinetics of the cationic dye,methylene blue,onto clay[J].Journal of Hazardous Materials,2006,131(1):217-228.
[32]CHEN M,XU P,ZENG G,et al.Bioremediation of soils contaminated with polycyclic aromatic hydrocarbons,petroleum,pesticides,chlorophenols and heavy metals by composting:applications,microbes and future research needs[J].Biotechnology Advances,2015,33(6):745.
[33]BANERJEE P.Phenol adsorption onto various soil composite membranes:insight into process kinetics,modelling and optimisation using response surface methodolog[J].Astrophysical Journal,2015,207(2):414-424.
[34]ALKARAM U F,MUKHLIS A A,ALDUJAILI A H.The removal of phenol from aqueous solutions by adsorption using surfactantmodified bentonite and kaolinite[J].Journal of Hazardous Materials,2009,169(1/2/3):324.
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