质子交换膜燃料电池冷启动性能影响因素分析
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摘要
质子交换膜燃料电池(PEMFC)的冷启动性能与初始水含量、启动模式、启动温度等密切相关。从电池内部水结冰/解冻过程,电池的不同启动模式,电池内水的结冰位置等方面较详细地阐述了它们对电池性能的影响,对学者们的研究成果进行了总结归纳,就电池冷启动后续研究方向提出了建议。
The cold start performance of proton exchange membrane fuel cell(PEMFC) is closely related to initial water content, start-up mode and start-up temperature. Some influence factors with respect to fuel cell performance were described, including water freezing or thawing process within the fuel cell stack, different battery start-up mode,battery water ice location, etc. The author summarized the research results of the previous scholars, and pointed out the research focus of the battery cold start in the future.
The cold start performance of proton exchange membrane fuel cell(PEMFC) is closely related to initial water content, start-up mode and start-up temperature. Some influence factors with respect to fuel cell performance were described, including water freezing or thawing process within the fuel cell stack, different battery start-up mode,battery water ice location, etc. The author summarized the research results of the previous scholars, and pointed out the research focus of the battery cold start in the future.
引文
[1]崔胜民.新能源汽车技术[M].北京:北京工业大学出版社,2014.
[2]李超,贾秋红,常英杰.基于两相混合流理论PEMFC含水量特性分析[J].电源技术,2016,40(9):1775-1778.
[3]HISHINUMA Y,CHIKAHISA T,KAGAMI F,et al.The design and performance of a PEFC at a temperature below freezing[J].JSME International Journal,2004,47(2):235-241.
[4]MALDONADO L,PERRIN J C,DILLET J,et al.Characterization of polymer electrolyte Nafion membranes:Influence of temperature,heat treatment and drying protocol on sorption and transport properties[J].Journal of Membrane Science,2012,389(11):43-56.
[5]TAJIRI K,TABUCHI Y,KAGAMI F.Effects of operating and design parameters on PEFC cold start[J].Journal of Power Sources,2007,165(1):279-286.
[6]LUO Y,JIAO K,JIA B.Elucidating the constant power,current and voltage cold start modes of proton exchange membrane fuel cell[J].International Journal of Heat&Mass Transfer,2014,77(4):489-500.
[7]黄成勇.质子交换膜燃料电池CCM冰点以下低温特性的研究[D].武汉:武汉理工大学,2007:37-39.
[8]孙树成,俞红梅,侯俊波,等.PEMFC在0℃以下环境启动的研究[J].电源技术,2007,31(8):626-629.
[9]RUI L,WENG Y,YI L,et al.Internal behavior of segmented fuel cell during cold start[J].International Journal of Hydrogen Energy,2014,39(28):16025-16035.
[10]KNIGHTS S D,COLBOW K M,ST-PIERRE J,et al.Aging mechanisms and lifetime of PEFC and DMFC[J].Journal of Power Sources,2004,127(1/2):127-134.
[11]HOU J B,YU H M,ZHANG S S,et al.Analysis of PEMFC freeze degradation at-20℃after gas purging s[J].Journal of Power Sources,2006,162(1):513-520.
[12]CHO E A,KO J J,HA H Y,et al.Effects of water removal on the performance degradation of PEMFCs repetitively brought to<0℃[J].Journal of the Electrochemical Society,2004,151(5):A661-A665.
[13]郑浩,李义,许思传.基于恒电压模式PEMFC冷起动性能研究[J].电源技术,2014,38(2):259-261.
[14]TABE Y,SAITO M,FUKUI K,et al.Cold start characteristics and freezing mechanism dependence on start-up temperature in a polymer electrolyte membrane fuel cell[J].Journal of Power Sources,2012,208(2):366-373.
[15]XIE G,OKADA T.The state of water in Nafion 117 of various cation forms[J].Electrochemistry,1996,64(6):718-726.
[16]黄永.质子交换膜燃料电池冷启动研究[D].武汉:武汉理工大学,2008.
[17]詹志刚,吕志勇,黄永,等.质子交换膜燃料电池冷启动及性能衰减研究[J].武汉理工大学学报,2011(1):151-155.
[18]SANTAMARIA A D,BACHMAN J,PARK J W.Cold-start of parallel and interdigitated flow-field polymer electrolyte membrane fuel cell[J].Electrochimica Acta,2013,107(10):327-338.
[19]SCHIEBWOHL E,UNWERTH T V,SEYFRIED F,et al.Experimental investigation of parameters influencing the freeze start ability of a fuel cell system[J].Journal of Power Sources,2009,193(1):107-115.
[20]DU Q,JIA B,LUO Y,et al.Maximum power cold start mode of proton exchange membrane fuel cell[J].International Journal of Hydrogen Energy,2014,39(16):8390-8400.
[21]LUO Y,JIAO K.Cold start of proton exchange membrane fuel cell[J].Progress in Energy&Combustion Science,2018,64:29-61.
[2]李超,贾秋红,常英杰.基于两相混合流理论PEMFC含水量特性分析[J].电源技术,2016,40(9):1775-1778.
[3]HISHINUMA Y,CHIKAHISA T,KAGAMI F,et al.The design and performance of a PEFC at a temperature below freezing[J].JSME International Journal,2004,47(2):235-241.
[4]MALDONADO L,PERRIN J C,DILLET J,et al.Characterization of polymer electrolyte Nafion membranes:Influence of temperature,heat treatment and drying protocol on sorption and transport properties[J].Journal of Membrane Science,2012,389(11):43-56.
[5]TAJIRI K,TABUCHI Y,KAGAMI F.Effects of operating and design parameters on PEFC cold start[J].Journal of Power Sources,2007,165(1):279-286.
[6]LUO Y,JIAO K,JIA B.Elucidating the constant power,current and voltage cold start modes of proton exchange membrane fuel cell[J].International Journal of Heat&Mass Transfer,2014,77(4):489-500.
[7]黄成勇.质子交换膜燃料电池CCM冰点以下低温特性的研究[D].武汉:武汉理工大学,2007:37-39.
[8]孙树成,俞红梅,侯俊波,等.PEMFC在0℃以下环境启动的研究[J].电源技术,2007,31(8):626-629.
[9]RUI L,WENG Y,YI L,et al.Internal behavior of segmented fuel cell during cold start[J].International Journal of Hydrogen Energy,2014,39(28):16025-16035.
[10]KNIGHTS S D,COLBOW K M,ST-PIERRE J,et al.Aging mechanisms and lifetime of PEFC and DMFC[J].Journal of Power Sources,2004,127(1/2):127-134.
[11]HOU J B,YU H M,ZHANG S S,et al.Analysis of PEMFC freeze degradation at-20℃after gas purging s[J].Journal of Power Sources,2006,162(1):513-520.
[12]CHO E A,KO J J,HA H Y,et al.Effects of water removal on the performance degradation of PEMFCs repetitively brought to<0℃[J].Journal of the Electrochemical Society,2004,151(5):A661-A665.
[13]郑浩,李义,许思传.基于恒电压模式PEMFC冷起动性能研究[J].电源技术,2014,38(2):259-261.
[14]TABE Y,SAITO M,FUKUI K,et al.Cold start characteristics and freezing mechanism dependence on start-up temperature in a polymer electrolyte membrane fuel cell[J].Journal of Power Sources,2012,208(2):366-373.
[15]XIE G,OKADA T.The state of water in Nafion 117 of various cation forms[J].Electrochemistry,1996,64(6):718-726.
[16]黄永.质子交换膜燃料电池冷启动研究[D].武汉:武汉理工大学,2008.
[17]詹志刚,吕志勇,黄永,等.质子交换膜燃料电池冷启动及性能衰减研究[J].武汉理工大学学报,2011(1):151-155.
[18]SANTAMARIA A D,BACHMAN J,PARK J W.Cold-start of parallel and interdigitated flow-field polymer electrolyte membrane fuel cell[J].Electrochimica Acta,2013,107(10):327-338.
[19]SCHIEBWOHL E,UNWERTH T V,SEYFRIED F,et al.Experimental investigation of parameters influencing the freeze start ability of a fuel cell system[J].Journal of Power Sources,2009,193(1):107-115.
[20]DU Q,JIA B,LUO Y,et al.Maximum power cold start mode of proton exchange membrane fuel cell[J].International Journal of Hydrogen Energy,2014,39(16):8390-8400.
[21]LUO Y,JIAO K.Cold start of proton exchange membrane fuel cell[J].Progress in Energy&Combustion Science,2018,64:29-61.