甲基乙烯基硅橡胶的研究进展
|
摘要
综述了甲基乙烯基硅橡胶(MVQ)的力学性能、电性能、导热性能、耐热性能、阻燃性能、耐辐射性能、压缩永久变形性能等方面主要的研究和改性进展,研究了甲基乙烯基硅橡胶加工改性工艺对材料多项性能的影响变化规律,解决了研发新材料的基本思路与开发新性能等基本问题。
The main research and modification progress of methyl vinyl silicone rubber(MVQ) on mechanical properties,electrical properties,thermal conductivity,heat resistance,flame retardancy,radiation resistance and compression set properties was reviewed. The influence of vinyl silicone rubber processing modification process on the multiple properties of materials has solved the basic problems of developing new materials and new properties.
The main research and modification progress of methyl vinyl silicone rubber(MVQ) on mechanical properties,electrical properties,thermal conductivity,heat resistance,flame retardancy,radiation resistance and compression set properties was reviewed. The influence of vinyl silicone rubber processing modification process on the multiple properties of materials has solved the basic problems of developing new materials and new properties.
引文
[1] 石大立,马炳湘,等.除水工艺疏水改性白炭黑及对硅橡胶力学性能的影响[J].广东化工,2017,44(17):29-31.
[2] 胡文谦,贾晓龙,等.气相白炭黑的比表面积与表面特性对硅橡胶的补强效果的影响[J].弹性体,2011,21(2):57-60.
[3] 李哲,曹留烜,李宁.改性氧化石墨烯/蒙脱土/甲基乙烯基硅橡胶的制备及其阻燃性能研究[J].厦门大学学报:自然科学版,2018,57(04):587-592.
[4] 夏艳平,耿浩然,等.硅橡胶/改性蒙脱土复合材料的制备及其性能研究[J].中国塑料,2017,31(5):26-30.
[5] 王锦成,陈月辉,等. HOMMT/MVQ纳米复合材料的制备与性能研究[J].橡胶工业,2010,57(4):209-214.
[6] 李智敏,吴友平.高抗撕裂硅橡胶复合材料的制备[J].合成橡胶工业,2015,38(2):141-144.
[7] 廖治强,张凯,等. h-BN用量对h-BN/MVQ导热绝缘复合材料性能的影响[J].高分子材料科学与工程,2016,32(2):65-70.
[8] Wang X,Xia Z,Yuan B,et al. Effect of curing temperature on the properties of conductive silicone rubber filled with carbonyl permalloy powder[J]. Materials & Design,2013,51(5):287-292.
[9] 陈建博,孙举涛,等.导热绝缘硅橡胶的研究[J].特种橡胶制品,2017,38(4):29-31.
[10] 王文志,张炜巍,等. SiC/AL2O3/MVQ导热复合材料的制备和性能研究[J].特种橡胶制品,2012,33(3):10-13.
[11] 贾奇博,刘宇,等.甲基乙烯基硅橡胶和氧化铝的干燥温度对其复合材料导热性能的影响[J].合成橡胶工业,2011,34(2):147-151.
[12] 王晓晴,文庆珍,等.可膨胀微球/硅橡胶泡沫隔热保温材料的制备及性能表征[J].功能材料,2018,49(2):02152-02156.
[13] 钱天语,刘春林,等.碳化硅及碳纤维对甲基乙烯基硅橡胶导热复合材料性能的影响[J].橡胶工业,2016,63(4):231-234.
[14] Hu H,Zhao L,Liu J,et al. Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene[J]. Polymer,2012,53(15):3378-3385.
[15] 张玉环.甲基乙烯基硅橡胶耐热改性及应用[D].杭州:浙江大学,2009.
[16] 张树明,周亚斌,等.稀土氧化物对提高甲基乙烯基硅橡胶耐热剂的作用[J].特种橡胶制品,2009,30(9):11-13.
[17] 苏柳梅.黏土/甲基乙烯基硅橡胶可瓷化复合材料的制备及其热稳定性研究[D].湖南:中南大学,2011:15-42.
[18] 郝冬冬,张磊,等.甲基乙烯基硅橡胶的耐热改性研[J].有机硅材料,2017,31(2):89-93.
[19] 孙希路,刘春霞,等.白云母与玻璃粉配合对可瓷化阻燃硅橡泡沫性能的影响[J].有机硅材料,2017,31(4):257-262.
[20] 吕高鹏,王宁,等.高分散型三聚氰胺氰尿酸盐阻燃硅橡胶的研究[J].橡胶工业,2015,62(4):211-215.
[21] 孙名伟,郭平,等.高性能阻燃硅橡胶的研制[J].有机硅材料,2017,31(增刊):72-76.
[22] 王文志,顾军渭.聚磷酸铵/氢氧化镁复配填充阻燃硅橡胶的研究[J].有机硅材料,2012,26(1):30-33.
[23] Chai H,Tang X,Ni M,et al. Preparation and properties of flexible flame-retardant neutron shielding material based on methyl vinyl silicone rubber[J]. Journal of Nuclear Materials,2015,46(4):210-215.
[24] 蒋丹.硅橡胶片材的辐照硫化研究[J].广州化工,2017,45(15):101-104.
[25] 宋宏涛,黄玮.密度泛函法研究几种甲基乙烯基硅橡胶初级交联链结构的辐射稳定性[J].计算机与应用化学,2016,33(4):203-506.
[26] 杨勃.氧化石墨烯与苯基对硅橡胶辐射效应影响的对比研究[D].四川:西南科技大学,2017:16-50.
[27] Gong P,Ni M,Chai H,et al. Preparation and characteristics of a flexible neutron and γ-ray shielding and radiation-resistant material reinforced by benzophenone[J]. Nuclear Engineering & Technology,2018:1-8.
[2] 胡文谦,贾晓龙,等.气相白炭黑的比表面积与表面特性对硅橡胶的补强效果的影响[J].弹性体,2011,21(2):57-60.
[3] 李哲,曹留烜,李宁.改性氧化石墨烯/蒙脱土/甲基乙烯基硅橡胶的制备及其阻燃性能研究[J].厦门大学学报:自然科学版,2018,57(04):587-592.
[4] 夏艳平,耿浩然,等.硅橡胶/改性蒙脱土复合材料的制备及其性能研究[J].中国塑料,2017,31(5):26-30.
[5] 王锦成,陈月辉,等. HOMMT/MVQ纳米复合材料的制备与性能研究[J].橡胶工业,2010,57(4):209-214.
[6] 李智敏,吴友平.高抗撕裂硅橡胶复合材料的制备[J].合成橡胶工业,2015,38(2):141-144.
[7] 廖治强,张凯,等. h-BN用量对h-BN/MVQ导热绝缘复合材料性能的影响[J].高分子材料科学与工程,2016,32(2):65-70.
[8] Wang X,Xia Z,Yuan B,et al. Effect of curing temperature on the properties of conductive silicone rubber filled with carbonyl permalloy powder[J]. Materials & Design,2013,51(5):287-292.
[9] 陈建博,孙举涛,等.导热绝缘硅橡胶的研究[J].特种橡胶制品,2017,38(4):29-31.
[10] 王文志,张炜巍,等. SiC/AL2O3/MVQ导热复合材料的制备和性能研究[J].特种橡胶制品,2012,33(3):10-13.
[11] 贾奇博,刘宇,等.甲基乙烯基硅橡胶和氧化铝的干燥温度对其复合材料导热性能的影响[J].合成橡胶工业,2011,34(2):147-151.
[12] 王晓晴,文庆珍,等.可膨胀微球/硅橡胶泡沫隔热保温材料的制备及性能表征[J].功能材料,2018,49(2):02152-02156.
[13] 钱天语,刘春林,等.碳化硅及碳纤维对甲基乙烯基硅橡胶导热复合材料性能的影响[J].橡胶工业,2016,63(4):231-234.
[14] Hu H,Zhao L,Liu J,et al. Enhanced dispersion of carbon nanotube in silicone rubber assisted by graphene[J]. Polymer,2012,53(15):3378-3385.
[15] 张玉环.甲基乙烯基硅橡胶耐热改性及应用[D].杭州:浙江大学,2009.
[16] 张树明,周亚斌,等.稀土氧化物对提高甲基乙烯基硅橡胶耐热剂的作用[J].特种橡胶制品,2009,30(9):11-13.
[17] 苏柳梅.黏土/甲基乙烯基硅橡胶可瓷化复合材料的制备及其热稳定性研究[D].湖南:中南大学,2011:15-42.
[18] 郝冬冬,张磊,等.甲基乙烯基硅橡胶的耐热改性研[J].有机硅材料,2017,31(2):89-93.
[19] 孙希路,刘春霞,等.白云母与玻璃粉配合对可瓷化阻燃硅橡泡沫性能的影响[J].有机硅材料,2017,31(4):257-262.
[20] 吕高鹏,王宁,等.高分散型三聚氰胺氰尿酸盐阻燃硅橡胶的研究[J].橡胶工业,2015,62(4):211-215.
[21] 孙名伟,郭平,等.高性能阻燃硅橡胶的研制[J].有机硅材料,2017,31(增刊):72-76.
[22] 王文志,顾军渭.聚磷酸铵/氢氧化镁复配填充阻燃硅橡胶的研究[J].有机硅材料,2012,26(1):30-33.
[23] Chai H,Tang X,Ni M,et al. Preparation and properties of flexible flame-retardant neutron shielding material based on methyl vinyl silicone rubber[J]. Journal of Nuclear Materials,2015,46(4):210-215.
[24] 蒋丹.硅橡胶片材的辐照硫化研究[J].广州化工,2017,45(15):101-104.
[25] 宋宏涛,黄玮.密度泛函法研究几种甲基乙烯基硅橡胶初级交联链结构的辐射稳定性[J].计算机与应用化学,2016,33(4):203-506.
[26] 杨勃.氧化石墨烯与苯基对硅橡胶辐射效应影响的对比研究[D].四川:西南科技大学,2017:16-50.
[27] Gong P,Ni M,Chai H,et al. Preparation and characteristics of a flexible neutron and γ-ray shielding and radiation-resistant material reinforced by benzophenone[J]. Nuclear Engineering & Technology,2018:1-8.