IPDC裂解过程分析方法的探索
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摘要
主要讨论应用带紫外检测器的液相色谱~([1]),采用化学衍生手段,利用反相C18液相色谱柱分离~([2-4]),对IPDC裂解过程中多组分的分析测试方法进行广泛探索研究。最后得到的方法精密度好、准确度高、操作性强,有很大的推广价值。
This article focused on the application liquid chromatography with UV detector,with C18 Column ~([1]), derived by chemical means, using C18 liquid chromatography~([2-4]), carried out extensive exploration and research methods of testing the pyrolysis of IPDC in multicomponent analysis test method. Finally, the method has been to explore has good precision, high accuracy, easy to operate, there are a lot of promotional value.
This article focused on the application liquid chromatography with UV detector,with C18 Column ~([1]), derived by chemical means, using C18 liquid chromatography~([2-4]), carried out extensive exploration and research methods of testing the pyrolysis of IPDC in multicomponent analysis test method. Finally, the method has been to explore has good precision, high accuracy, easy to operate, there are a lot of promotional value.
引文
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[2] 邢其毅,等.基础有机化学[M].北京:高等教育出版社,1989,970-977.
[3] 时钧,等.化学工程手册,第二版[M].北京:化学工业出版社,1996,25:85-118.
[4] 袁一,等.化学工程师手册[M].北京:机械工业出版社,2003,81-390.
[5] 宋春梅,王得宁.异佛尔酮二异氰酸酯三聚体的合成[J].合成橡胶工业,2002(11):12-15.
[6] 周益明,包建春,等.异氰酸酯的反应[J].有机化学,1997(2):180-182.
[7] 欧育湘,王秀菊.聚氨酯及其原材料分析[M].北京:兵器工业部出版社,1991.
[8] 高喜平,王勃,曹光宇,等.异佛尔酮二异氰酸酯分子中异氰酸酯基团活活性比较[J].河南科技大学学报·自然科学版,2009,101-104.
[9] 刘秀玲,曾宪海,黄长荣,等.液相色谱-质谱法对氨基甲酸酯反应产物中残留的异佛尔酮二异氰酸酯含量的测定[J].分析测试学报,2008,(27):256-257.
[10] 张华.现代有机波谱分析[M].北京:化学工业出版社,2005.
[11] 宋春梅,薛海丽,庄小璐,等.异佛尔酮二异氰酸酯自聚产物的13C-NMR研究[J].高分子学报,2006(5):660-665.
[12] 汪雷敏,潘铁英,等.IPDI的NMR数据分析[J].波谱学杂志,2005(22):79-84.
[13] Gregory R.Fulmer,Alexander J.M.Miller,Nathaniel H.Sherden,Hugo E.Gottlieb,Abraham Nudelman,Brian M.Stoltz,John E.Bercaw,and Karen I.Goldberg。NMR Chemical Shifts of Trace Impurities:Common Laboratory Solvents,Organics,and Gases in Deuterated Solvents Relevant to the Organometallic Chemist[J].Organometallics,2010,A-D.
[14] Hugo E.Gottlieb,Vadim Kotlyar,and Abraham Nudelman.NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities[J].Org.Chem,1997,(62):7512-7515.