石墨烯量子点制备方法研究进展
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摘要
石墨烯量子点由于良好的发光性、低毒性、溶解性、化学惰性等特殊性质,使其在医学领域、环境领域、电子领域拥有巨大的潜在应用,也引起了众多研究者的关注。从自上而下制备法、自下而上制备法以及表面化学掺杂反应三方面综述了制备石墨烯量子点的方法以及相关领域的研究进展,提出了目前制备石墨烯量子点的困境,并对其未来发展进行了展望。
Graphene quantum dots have great potential applications in medical, environmental and electronic fields due to their good luminescent property,low toxicity,solubility,chemical inertness and have attracted the attention of many researchers. The methods of preparing graphene quantum dots and the research progress in related fields were reviewed from the top-down preparation method,the bottom-up preparation method and the surface chemical doping reaction. Finally,the predicament of preparing graphene quantum dots was proposed.
Graphene quantum dots have great potential applications in medical, environmental and electronic fields due to their good luminescent property,low toxicity,solubility,chemical inertness and have attracted the attention of many researchers. The methods of preparing graphene quantum dots and the research progress in related fields were reviewed from the top-down preparation method,the bottom-up preparation method and the surface chemical doping reaction. Finally,the predicament of preparing graphene quantum dots was proposed.
引文
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[2] RITTER K A,LYDING J W. The influence of edge structure on the electronic properties of graphene quantum dots and nanoribbons[J]. Nature Materials,2009,8(3):235-242.
[3] LIU C,ZHANG P,TIAN F,et al. One-step synthesis of surface passivated carbon nanodots by microwave assisted pyrolysis for enhanced multicolor photoluminescence and bioimaging[J]. Journal of Materials Chemistry,2011,21(35):13163.
[4] LI F,LIU C,YANG J,et al. Mg/N double doping strategy to fabricate extremely high luminescent carbon dots for bioimaging[J]. RSC Adv,2014,4(7):3201-3205.
[5] SHI W,ZHANG X,BRILLET J,et al. Significant enhancement of the photoelectrochemical activity of WO 3nanoflakes by carbon quantum dots decoration[J]. Carbon,2016,105:387-393.
[6] ZHANG Z Z,CHANG K,PEETERS F M. Tuning of energy levels and optical properties of graphene quantum dots[J]. Physical Review B,2008,77(23):
[7] LIU R,WU D,LIU S,et al. An Aqueous Route to Multicolor Photoluminescent Carbon Dots Using Silica Spheres as Carriers[J]. Angewandte Chemie International Edition,2009,48(25):4598-4601.
[8] SALINAS-CASTILLO A,ARIZA-AVIDAD M,PRITZ C,et al. Carbon dots for copper detection with down and upconversion fluorescent properties as excitation sources[J]. Chemical Communications,2013,49(11):1103.
[9] WANG J,GAO M,HO G W. Bidentate-complex-derived Ti O2/carbon dot photocatalysts:in situ synthesis,versatile heterostructures,and enhanced H2 evolution[J]. Journal of Materials Chemistry A, 2014, 2(16):5703.
[10] WU Y,WEI P,PENGPUMKIAT S,et al. Development of a Carbon Dot(C-Dot)-Linked Immunosorbent Assay for the Detection of Humanα-Fetoprotein[J].Analytical Chemistry,2015,87(16):8510-8516.
[11] HUANG S,WANG L,ZHU F,et al. A ratiometric nanosensor based on fluorescent carbon dots for labelfree and highly selective recognition of DNA[J]. RSC Advances,2015,5(55):44587-44597.
[12] PONOMARENKO L A,SCHEDIN F,KATSNELSON M I,et al. Chaotic Dirac Billiard in Graphene Quantum Dots[J]. Science,2008,320(5874):356-358.
[13] SHEN J,ZHU Y,YANG X,et al. Graphene quantum dots:emergent nanolights for bioimaging,sensors,catalysis and photovoltaic devices[J]. Chemical Communications,2012,48(31):3686-3699.
[14] PENG J,GAO W,GUPTA B K,et al. Graphene Quantum Dots Derived from Carbon Fibers[J]. Nano Letters,2012,12(2):844-849.
[15] XU Y,JIA X-H,YIN X-B,et al. Carbon Quantum Dot Stabilized Gadolinium Nanoprobe Prepared via a One-Pot Hydrothermal Approach for Magnetic Resonance and Fluorescence Dual-Modality Bioimaging[J]. Analytical Chemistry,2014,86(24):12122-12129.
[16] ZHU X,ZUO X,HU R,et al. Hydrothermal synthesis of two photoluminescent nitrogen-doped graphene quantum dots emitted green and khaki luminescence[J]. Materials Chemistry and Physics,2014,147(3):963-967.
[17] ZHU S,ZHANG J,LIU X,et al. Graphene quantum dots with controllable surface oxidation,tunable fluorescence and up-conversion emission[J]. RSC Advances,2012,2(7):2717.
[18] ANANTHANARAYANAN A,WANG X,ROUTH P,et al. Facile Synthesis of Graphene Quantum Dots from 3D Graphene and their Application for Fe3+Sensing[J].Advanced Functional Materials,2014,24(20):3021
[19] LIU M,XU Y,NIU F,et al. Carbon quantum dots directly generated from electrochemical oxidation of graphite electrodes in alkaline alcohols and the applications for specific ferric ion detection and cell imaging[J]. Analyst,2016,141(9):2657-2664.
[20]刘振宇,刘瑾.石墨烯量子点制备技术及创新资源现状[J].中国科技信息,2018,(1):59-61.
[21] ZHANG Z,ZHANG J,CHEN N,et al. Graphene quantum dots:an emerging material for energy-related applications and beyond[J]. Energy&Environmental Science,2012,5(10):8869.
[22] XU C,YANG S,TIAN L,et al. Fabrication of centimeter-scale light-emitting diode with improved performance based on graphene quantum dots[J]. Applied Physics Express,2017,10(3):032102.
[23] YAN X,CUI X,LI L-S. Synthesis of Large,Stable Colloidal Graphene Quantum Dots with Tunable Size[J]. Journal of the American Chemical Society,2010,132(17):5944-5945.
[24] FENG Y,ZHONG D,MIAO H,et al. Carbon dots derived from rose flowers for tetracycline sensing[J]. Talanta,2015,140:128-133.
[25] WU X,TIAN F,WANG W,et al. Fabrication of highly fluorescent graphene quantum dots using l-glutamic acid for in vitro/in vivo imaging and sensing[J]. Journal of Materials Chemistry C,2013,1(31):4676.
[26] CHUA C K,SOFER Z,IMEK P,et al. Synthesis of Strongly Fluorescent Graphene Quantum Dots by CageOpening Buckminsterfullerene[J]. ACS Nano,2015,9(3):2548-2555.
[27]曲丹.掺杂型石墨烯量子点的制备及其应用研究[D].长春:中国科学院长春光学精密机械与物理研究所,2017.
[28] CHEN H,XIE Y,KIRILLOV A M,et al. A ratiometric fluorescent nanoprobe based on terbium functionalized carbon dots for highly sensitive detection of an anthrax biomarker[J]. Chemical Communications,2015,51(24):5036-5039.
[29] DING H,YU S-B,WEI J-S,et al. Full-Color LightEmitting Carbon Dots with a Surface-State-Controlled Luminescence Mechanism[J]. ACS Nano,2015,10(1):484-491.
[30] DU F,ZHANG M,JU H,et al. Engineering iodinedoped carbon dots as dual-modal probes for fluorescence and X-ray CT imaging[J]. International Journal of Nanomedicine,2015,6943.
[31] HU S,TIAN R,DONG Y,et al. Modulation and effects of surface groups on photoluminescence and photocatalytic activity of carbon dots[J]. Nanoscale,2013,5(23):11665.
[32] YIN J-Y,LIU H-J,JIANG S,et al. Hyperbranched Polymer Functionalized Carbon Dots with MultistimuliResponsive Property[J]. ACS Macro Letters,2013,2(11):1033-1037.
[33] SUN Y-P,ZHOU B,LIN Y,et al. Quantum-Sized Carbon Dots for Bright and Colorful Photoluminescence[J]. Journal of the American Chemical Society,2006,128(24):7756-7757.
[34] HU S,LIU J,YANG J,et al. Laser synthesis and size tailor of carbon quantum dots[J]. Journal of Nanoparticle Research,2011,13(12):7247-7252.
[35] YU H,LI X,ZENG X,et al. Preparation of carbon dots by non-focusing pulsed laser irradiation in toluene[J].Chemical Communications,2016,52(4):819-822.
[36] PAN D,ZHANG J,LI Z,et al. Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots[J]. Advanced Materials,2010,22(6):734-738.
[37] ZHU X,XIAO X,ZUO X,et al. Hydrothermal Preparation of Photoluminescent Graphene Quantum Dots Characterized Excitation-Independent Emission and its Application as a Bioimaging Reagent[J]. Particle&Particle Systems Characterization,2014,31(7):801-809.
[38] SHEN J,SHANG S,CHEN X,et al. Facile synthesis of fluorescence carbon dots from sweet potato for Fe3+sensing and cell imaging[J]. Materials Science and Engineering:C,2017,76:856-864.
[39]战岩,俎鸿儒,黄棣,等.水热法快速制备荧光氧化石墨烯量子点及其在细胞成像中的应用[J].光谱学与光谱分析,2018,38(5):1458-1462.
[40] XUE W,LIN Z,CHEN H,et al. Enhancement of Ultraweak Chemiluminescence from Reaction of Hydrogen Peroxide and Bisulfite by Water-Soluble Carbon Nanodots[J]. The Journal of Physical Chemistry C,2011,115(44):21707-21714.
[41] LIU Q,GUO B,RAO Z,et al. Strong Two-Photon-Induced Fluorescence from Photostable,Biocompatible Nitrogen-Doped Graphene Quantum Dots for Cellular and Deep-Tissue Imaging[J]. Nano Letters,2013,13(6):2436-2441.
[42] LU J,YANG J-X,WANG J,et al. One-Pot Synthesis of Fluorescent Carbon Nanoribbons,Nanoparticles,and Graphene by the Exfoliation of Graphite in Ionic Liquids[J]. ACS Nano,2009,3(8):2367-2375.
[43] SHINDE D B,PILLAI V K. Electrochemical Preparation of Luminescent Graphene Quantum Dots from Multiwalled Carbon Nanotubes[J]. Chemistry-A European Journal,2012,18(39):12522-12528.
[44] SHEN J,ZHU Y,CHEN C,et al. Facile preparation and upconversion luminescence of graphene quantum dots[J]. Chemical Communications,2011,47(9):2580-2582.
[45] DONG Y,CHEN C,ZHENG X,et al. One-step and high yield simultaneous preparation of single-and multi-layer graphene quantum dots from CX-72 carbon black[J]. Journal of Materials Chemistry, 2012, 22(18):8764.
[46] JI Z,WANG J,HOU D,et al. Effect of microwave irradiation on vacuum membrane distillation[J]. Journal of Membrane Science,2013,429:473-479.
[47] TANG L,JI R,CAO X,et al. Deep Ultraviolet Photoluminescence of Water-Soluble Self-Passivated Graphene Quantum Dots[J]. ACS Nano,2012,6(6):5102-5110.
[48]王珊珊,米渭清,朱红,等.一步微波法合成碳点及其荧光性质研究[J].光谱学与光谱分析,2012,32(10):2710-2713.
[49]林新浩,张雨,王伟军,等.石墨烯量子点的制备与表征[J].化学与黏合,2015,37(1):39-42.
[50] WANG D,ZHU L,MCCLEESE C,et al. Fluorescent carbon dots from milk by microwave cooking[J]. RSC Advances,2016,6(47):41516-41521.
[51] KIANI H,ZHANG Z,DELGADO A,et al. Ultrasound assisted nucleation of some liquid and solid model foods during freezing[J]. Food Research International,2011,44(9):2915-2921.
[52] ZHUO S,SHAO M,LEE S-T. Upconversion and Downconversion Fluorescent Graphene Quantum Dots:Ultrasonic Preparation and Photocatalysis[J]. ACS Nano,2012,6(2):1059-1064.
[53] GOKHALE R,SINGH P. Blue Luminescent Graphene Quantum Dots by Photochemical Stitching of Small Aromatic Molecules:Fluorescent Nanoprobes in Cellular Imaging[J]. Particle&Particle Systems Characterization,2014,31(4):433-438.
[54] ZHU Y, WANG G, JIANG H, et al. One-step ultrasonic synthesis of graphene quantum dots with high quantum yield and their application in sensing alkaline phosphatase[J]. Chemical Communications,2015,51(5):948-951.
[55] ZHAO J,TANG L,XIANG J,et al. Fabrication and properties of a high-performance chlorine doped graphene quantum dot based photovoltaic detector[J].RSC Advances,2015,5(37):29222-29229.
[56] WANG F,PANG S,WANG L,et al. One-Step Synthesis of Highly Luminescent Carbon Dots in Noncoordinating Solvents[J]. Chemistry of Materials,2010,22(16):4528-4530.
[57] ZHOU J,SHENG Z,HAN H,et al. Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon source[J]. Materials Letters,2012,66(1):222-224.
[58] HSU P-C,CHANG H-T. Synthesis of high-quality carbon nanodots from hydrophilic compounds:role of functional groups[J]. Chemical Communications,2012,48(33):3984.
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