室内甲醛来源及其防治措施
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摘要
室内甲醛是室内污染物的主要组成,甲醛对人体健康有极大的危害。文章主要综述了室内甲醛的主要来源、危害及其防治措施,介绍了甲醛的重要物理化学性质和多种甲醛去除技术,并归纳了甲醛去除最新研究方法,重点就甲醛净化法进行了论述,对比了多种技术处理甲醛的效果。同时,指出目前甲醛净化法存在的主要问题,并进一步提出未来的研究发展方向。
Indoor formaldehyde is the main composition of indoor pollutants,formaldehyde has great harm to human body health. The main source of indoor formaldehyde,and its harm and prevention measures were briefly reviewed,the important physical and chemical properties of formaldehyde and the removal technologies of formaldehyde was introduced,and new formaldehyde removal research achievements were summarized,formaldehyde purifying methods were mainly discussed,and various formaldehyde removal effects were compared. Moreover,the main problem of the formaldehyde purifying methods and the future development direction was pointed out.
Indoor formaldehyde is the main composition of indoor pollutants,formaldehyde has great harm to human body health. The main source of indoor formaldehyde,and its harm and prevention measures were briefly reviewed,the important physical and chemical properties of formaldehyde and the removal technologies of formaldehyde was introduced,and new formaldehyde removal research achievements were summarized,formaldehyde purifying methods were mainly discussed,and various formaldehyde removal effects were compared. Moreover,the main problem of the formaldehyde purifying methods and the future development direction was pointed out.
引文
[1]张会群,涂明扬.室内空气中甲醛的危害及防治[J].广西轻工业,2008,24(2):69-70.
[2]张仙平,郝金鹏,沈恒根.国内居室的甲醛污染及防治措施[J].建筑热能通风空调,2007,26(3):28-31.
[3]宋莉.纳米Ti O2与涂料的复合及其降解室内甲醛的实验研究[D].重庆大学,2011.
[4]李新.建筑材料对室内空气质量的影响及其评价[D].重庆大学,2004.
[5]石碧清,刘湘,闾振华.室内甲醛污染现状及其防治对策[J].环境科学与技术,2007,30(6):49-51,54.
[6]张秀芝,辛雨家,何鑫巍,等.室内甲醛清除的误区和控制[J].山西建筑,2013,39(6):191-192.
[7]叶芳.家用纺织品中的甲醛[J].中国纤检,2014(12):56.
[8]秦卫普,苗晨琳,王晓晗,等.日化产品中甲醛的危害及分析方法研究进展[J].日用化学品科学,2016,39(4):30-33.
[9]翟淑妙,徐晓俨.甲醛的暴露与健康效应[J].环境与健康杂志,1994(5):238-240.
[10]江浩芝,赵婉君.室内甲醛的危害及其污染现状[J].广东化工,2016,43(11):189.
[11]朱玉玲.室内空气中甲醛的去除研究[D].山东大学,2010.
[12]樊冬梅,谢华.甲醛对呼吸系统毒性作用的研究现状[J].广东医学院学报,2009(5):584-586.
[13]王小玲.甲醛对小鼠中枢神经系统毒性的研究[D].山西医科大学,2008.
[14]Kilburn K.Neurobehavioral Impairment and Seizures from Formaldehyde[C].1994:37-44.
[15]杨振洲,蔡同建.室内甲醛的危害及其预防[J].中国公共卫生,2003,19(6):765-768.
[16]周秀华陈伟.儿童推车用纺织物中残留甲醛现状分析[J].中国纤检,2015(8):80-82.
[17]闫杨.甲醛对肝脏mi RNA-21及其下游TIMP-3和RECK蛋白的影响[J].世界华人消化杂志,2016(14):2143-2159.
[18]杨振洲,蔡同建.室内甲醛的危害及其预防[J].中国公共卫生,2003(6):137-140.
[19]牛凤兰,宋德锋,吕喆,等.甲醛的毒性及预防研究进展[J].现代预防医学,2010(12):2220-2222.
[20]Baba K,Yagi T,Niwa S,et al.Measurement of formaldehydespecific Ig E antibodies in adult asthmatics[J].Arerugī=[Allergy],2000,49(5):404-411.
[21]Cole P,Axten C.Formaldehyde and leukemia:an improbable causal relationship[J].Regulatory Toxicology&Pharmacology Rtp.,2004,40(2):107.
[22]李红霞,黄厚今.甲醛的毒性研究进展[J].环境卫生学杂志,2006,33(2):114-117.
[23]Odeigah P G.Sperm head abnormalities and dominant lethal effects of formaldehyde in albino rats[J].Mutation Research,1997,389(2-3):141-148.
[24]易建华,张敬华,高宇香.甲醛对小鼠精子毒作用实验[J].工业卫生与职业病,2000,26(5):263-264.
[25]赵江平,陈盼.通风条件下室内甲醛气体释放规律及其预测模型[J].环境工程,2014,32(2):131-134.
[26]Gilbert N L,Guay M,Gauvin D,et al.Air change rate and concentration of formaldehyde in residential indoor air[J].Atmospheric Environment,2008,42(10):2424-2428.
[27]Sherman M H,Hodgson A T.Formaldehyde as a basis for residential ventilation rates[J].Indoor Air,2004,14(1):2-8.
[28]鲁敏,郭天佑,闫红梅,等.耐阴观叶植物对室内甲醛敏感监测能力研究[J].山东建筑大学学报,2014(6):504-511.
[29]欧佳,薛勇,武海英,等.观赏植物吸收室内甲醛的实验研究[J].资源与人居环境,2008(22):70-72.
[30]敬婧,陈波,卢山.天南星科植物对甲醛净化效果的研究[J].浙江理工大学学报,2015,33(2):276-279.
[31]邓在银.以Co3+/Co2+为媒质原位电化学氧化甲醛[D].大连:大连理工大学,2013.
[32]张兴,朱琨,李丽.室内甲醛检测方法及防治措施研究进展[J].环境与发展,2008,20(6):97-102.
[33]吴自强,刘志宏,许士洪.室内甲醛污染控制技术进展[J].中国建材科技,2002,11(1):55-58.
[34]余阳.新型微孔吸附剂—超细活性碳纤维的制备及其室内甲醛吸附行为研究[D].上海:东华大学,2011.
[35]孙康,蒋剑春,卢辛成,等.表面掺氮活性炭的制备及其甲醛吸附性能研究[J].林产化学与工业,2014,34(4):77-82.
[36]向丰华,原梅妮.石墨烯吸附甲醛分子理论研究[J].测试科学与仪器(英文版),2016,7(1):99-102.
[37]原卫华,毕世华,曹茂盛.石墨烯吸附甲醛的第一性原理研究[J].材料导报,2015,29(18):156-159.
[38]吴利瑞,张蓝心,于飞,等.氨基化碳纳米管/石墨烯气凝胶对甲醛吸附研究[J].中国环境科学,2015,35(11):3251-3256.
[39]邵宇,张子重,王绪绪.室内空气中甲醛的去除[J].暖通空调,2005,35(10):36-39.
[40]Chang M B,Lee C C.Destruction of Formaldehyde with Dielectric Barrier Discharge Plasmas[J].Environmental Science&Technology,1995,29(1):181-186.
[41]Wan Y,Fan X,Zhu T.Removal of low-concentration formaldehyde in air by DC corona discharge plasma[J].Chemical Engineering Journal,2011,171(1):314-319.
[42]Liang W J,Li J,Li J X,et al.Formaldehyde removal from gas streams by means of Na NO2 dielectric barrier discharge plasma[J].Journal of Hazardous Materials,2009,175(1-3):1090-1095.
[43]李坚,李洁,梁文俊,等.高频电晕放电等离子体法处理甲醛的研究[J].环境科学学报,2006,26(6):882-886.
[44]周飞,杨学昌,高得力.等离子体Ti O2催化空气净化试验研究[J].清华大学学报(自然科学版),2007,47(4):462-465.
[45]竹涛,李坚,梁文俊,等.低温等离子体净化甲醛气体的实验研究[J].北京工业大学学报,2008,34(9):971-975.
[46]韩瑛玉.含载银二氧化锰超细纤维催化降解甲醛的研究[D].天津:天津工业大学,2013.
[47]陈昌兵,陈勇,刘欣伟,等.用于室内甲醛降解的Ti O2光催化材料研究进展[J].自动化与仪器仪表,2016(4):9-11.
[48]齐虹,孙德智,迟国庆.光催化降解甲醛的影响因素及动力学研究[J].哈尔滨工业大学学报,2006,38(7):1051-1054.
[49]张浩,刘秀玉,朱庆明,等.Cu掺杂Ti O2光催化降解室内甲醛气体的实验研究[J].过程工程学报,2012,12(4):160-165.
[50]彭洪根,应家伟,张景岩,等.La掺杂Ti O2负载Pt催化剂制备及其室温氧化低浓度甲醛[J].催化学报,2017,38(1):39-47.
[2]张仙平,郝金鹏,沈恒根.国内居室的甲醛污染及防治措施[J].建筑热能通风空调,2007,26(3):28-31.
[3]宋莉.纳米Ti O2与涂料的复合及其降解室内甲醛的实验研究[D].重庆大学,2011.
[4]李新.建筑材料对室内空气质量的影响及其评价[D].重庆大学,2004.
[5]石碧清,刘湘,闾振华.室内甲醛污染现状及其防治对策[J].环境科学与技术,2007,30(6):49-51,54.
[6]张秀芝,辛雨家,何鑫巍,等.室内甲醛清除的误区和控制[J].山西建筑,2013,39(6):191-192.
[7]叶芳.家用纺织品中的甲醛[J].中国纤检,2014(12):56.
[8]秦卫普,苗晨琳,王晓晗,等.日化产品中甲醛的危害及分析方法研究进展[J].日用化学品科学,2016,39(4):30-33.
[9]翟淑妙,徐晓俨.甲醛的暴露与健康效应[J].环境与健康杂志,1994(5):238-240.
[10]江浩芝,赵婉君.室内甲醛的危害及其污染现状[J].广东化工,2016,43(11):189.
[11]朱玉玲.室内空气中甲醛的去除研究[D].山东大学,2010.
[12]樊冬梅,谢华.甲醛对呼吸系统毒性作用的研究现状[J].广东医学院学报,2009(5):584-586.
[13]王小玲.甲醛对小鼠中枢神经系统毒性的研究[D].山西医科大学,2008.
[14]Kilburn K.Neurobehavioral Impairment and Seizures from Formaldehyde[C].1994:37-44.
[15]杨振洲,蔡同建.室内甲醛的危害及其预防[J].中国公共卫生,2003,19(6):765-768.
[16]周秀华陈伟.儿童推车用纺织物中残留甲醛现状分析[J].中国纤检,2015(8):80-82.
[17]闫杨.甲醛对肝脏mi RNA-21及其下游TIMP-3和RECK蛋白的影响[J].世界华人消化杂志,2016(14):2143-2159.
[18]杨振洲,蔡同建.室内甲醛的危害及其预防[J].中国公共卫生,2003(6):137-140.
[19]牛凤兰,宋德锋,吕喆,等.甲醛的毒性及预防研究进展[J].现代预防医学,2010(12):2220-2222.
[20]Baba K,Yagi T,Niwa S,et al.Measurement of formaldehydespecific Ig E antibodies in adult asthmatics[J].Arerugī=[Allergy],2000,49(5):404-411.
[21]Cole P,Axten C.Formaldehyde and leukemia:an improbable causal relationship[J].Regulatory Toxicology&Pharmacology Rtp.,2004,40(2):107.
[22]李红霞,黄厚今.甲醛的毒性研究进展[J].环境卫生学杂志,2006,33(2):114-117.
[23]Odeigah P G.Sperm head abnormalities and dominant lethal effects of formaldehyde in albino rats[J].Mutation Research,1997,389(2-3):141-148.
[24]易建华,张敬华,高宇香.甲醛对小鼠精子毒作用实验[J].工业卫生与职业病,2000,26(5):263-264.
[25]赵江平,陈盼.通风条件下室内甲醛气体释放规律及其预测模型[J].环境工程,2014,32(2):131-134.
[26]Gilbert N L,Guay M,Gauvin D,et al.Air change rate and concentration of formaldehyde in residential indoor air[J].Atmospheric Environment,2008,42(10):2424-2428.
[27]Sherman M H,Hodgson A T.Formaldehyde as a basis for residential ventilation rates[J].Indoor Air,2004,14(1):2-8.
[28]鲁敏,郭天佑,闫红梅,等.耐阴观叶植物对室内甲醛敏感监测能力研究[J].山东建筑大学学报,2014(6):504-511.
[29]欧佳,薛勇,武海英,等.观赏植物吸收室内甲醛的实验研究[J].资源与人居环境,2008(22):70-72.
[30]敬婧,陈波,卢山.天南星科植物对甲醛净化效果的研究[J].浙江理工大学学报,2015,33(2):276-279.
[31]邓在银.以Co3+/Co2+为媒质原位电化学氧化甲醛[D].大连:大连理工大学,2013.
[32]张兴,朱琨,李丽.室内甲醛检测方法及防治措施研究进展[J].环境与发展,2008,20(6):97-102.
[33]吴自强,刘志宏,许士洪.室内甲醛污染控制技术进展[J].中国建材科技,2002,11(1):55-58.
[34]余阳.新型微孔吸附剂—超细活性碳纤维的制备及其室内甲醛吸附行为研究[D].上海:东华大学,2011.
[35]孙康,蒋剑春,卢辛成,等.表面掺氮活性炭的制备及其甲醛吸附性能研究[J].林产化学与工业,2014,34(4):77-82.
[36]向丰华,原梅妮.石墨烯吸附甲醛分子理论研究[J].测试科学与仪器(英文版),2016,7(1):99-102.
[37]原卫华,毕世华,曹茂盛.石墨烯吸附甲醛的第一性原理研究[J].材料导报,2015,29(18):156-159.
[38]吴利瑞,张蓝心,于飞,等.氨基化碳纳米管/石墨烯气凝胶对甲醛吸附研究[J].中国环境科学,2015,35(11):3251-3256.
[39]邵宇,张子重,王绪绪.室内空气中甲醛的去除[J].暖通空调,2005,35(10):36-39.
[40]Chang M B,Lee C C.Destruction of Formaldehyde with Dielectric Barrier Discharge Plasmas[J].Environmental Science&Technology,1995,29(1):181-186.
[41]Wan Y,Fan X,Zhu T.Removal of low-concentration formaldehyde in air by DC corona discharge plasma[J].Chemical Engineering Journal,2011,171(1):314-319.
[42]Liang W J,Li J,Li J X,et al.Formaldehyde removal from gas streams by means of Na NO2 dielectric barrier discharge plasma[J].Journal of Hazardous Materials,2009,175(1-3):1090-1095.
[43]李坚,李洁,梁文俊,等.高频电晕放电等离子体法处理甲醛的研究[J].环境科学学报,2006,26(6):882-886.
[44]周飞,杨学昌,高得力.等离子体Ti O2催化空气净化试验研究[J].清华大学学报(自然科学版),2007,47(4):462-465.
[45]竹涛,李坚,梁文俊,等.低温等离子体净化甲醛气体的实验研究[J].北京工业大学学报,2008,34(9):971-975.
[46]韩瑛玉.含载银二氧化锰超细纤维催化降解甲醛的研究[D].天津:天津工业大学,2013.
[47]陈昌兵,陈勇,刘欣伟,等.用于室内甲醛降解的Ti O2光催化材料研究进展[J].自动化与仪器仪表,2016(4):9-11.
[48]齐虹,孙德智,迟国庆.光催化降解甲醛的影响因素及动力学研究[J].哈尔滨工业大学学报,2006,38(7):1051-1054.
[49]张浩,刘秀玉,朱庆明,等.Cu掺杂Ti O2光催化降解室内甲醛气体的实验研究[J].过程工程学报,2012,12(4):160-165.
[50]彭洪根,应家伟,张景岩,等.La掺杂Ti O2负载Pt催化剂制备及其室温氧化低浓度甲醛[J].催化学报,2017,38(1):39-47.