钙钛矿太阳能电池的研究进展
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摘要
介绍了钙钛矿材料的结构和光电性质,综述了钙钛矿太阳能电池结构和工作原理,特别是钙钛矿太阳电池电子传输层、钙钛矿吸收层及有机空穴传输层三个重要组成部分的材料和性质,总结出该型电池急需要改进的问题,并对钙钛矿太阳能电池的发展趋势做了展望。
The structure and optoelectronic properties of perovskite materials are described. The structure and working principle of perovskite solar cells is reviewed. The material and properties of the three important components of perovskite solar cells such as perovskite electron transport layer,perovskite-absorbing layer and the organic hole transport layer,are highlighted. The urgent needs to improve this type of battery problems are summarized. The development trend of perovskite solar cells in the future is also prospected.
The structure and optoelectronic properties of perovskite materials are described. The structure and working principle of perovskite solar cells is reviewed. The material and properties of the three important components of perovskite solar cells such as perovskite electron transport layer,perovskite-absorbing layer and the organic hole transport layer,are highlighted. The urgent needs to improve this type of battery problems are summarized. The development trend of perovskite solar cells in the future is also prospected.
引文
[1]Akihiro Kojima,Kenjiro Teshima,Yasuo Shirai,et al.Organometal halide perovskites as visible-Light sensitizers for photovoltaic Cells[J].J Am Chem Soc,2009,131(17):6050-6051.
[2]Zhou Huanping,Chen Qi,Yang Yang,et al.Interface engineering of highly efficient perovskite solar cells[J].Science,2014,345(6196):542-546.
[3]Michael Grtzel.The light and shade of perovskite solar cells[J].Nat Mater,2014,13:838-842.
[4]Samuel D Stranks,Giles E Eperon,Giulia Grancini,et al.ElectronHole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J].Science,2013,342(6156):341-344.
[5]Hui-Seon Kim,Jin-Wook Lee,Michael Grtzel,et al.High efficiency solid-state sensitized solar cell-based on submicrometer rutile Ti O2nanorod and CH3NH3Pb I3perovskite sensitizer[J].Nano Lett,2013,13:2412-2417.
[6]Wang Jacob Tse-Wei,James M Ball,Henry J Snaith,et al.LowTemperature processed electron collection layers of Graphene/Ti O2nanocomposites in thin film perovskite solar Cells[J].Nano Lett,2014,14(2):724-730.
[7]Motonari Adachi,Yusuke Murata,Jun Takao,et al.Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like Ti O2nanowires made by the“Oriented Attachment”mechanism[J].J Am Chem Soc,2004,126:14943-14949.
[8]Lioz Etgar,Peng Gao,Michael Grtzel,et al.Mesoscopic CH3NH3Pb I3/Ti O2heterojunction solar cells[J].J Am Chem Soc,2012,134(42):17396-17399.
[9]Hui-Seon Kim,Chang-Ryul Lee,Michael Grtzel,et al.Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Sci Rep,2012,2:591.
[10]Saito Y,Fukuri N,Senadeera R,et al.Solid state dye sensitized solar cells using in situ polymerized PEDOTs as hole conductor[J].Electrochem Commun,2004,6:71-74.
[11]Qiu J,Qiu Y,Yan K,et al.All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional Ti O2nanowire arrays[J].Nanoscale,2013,5:3245-3248.
[12]Jun Hong Noh,Sang Hyuk Im,Jin Hyuck Heo,et al.Chemical management for colorful,efficient,and stable inorganic-organic hybrid nanostructured solar cells[J].Nano Lett,2013,13:1764-1769.
[13]Hui-Seon Kim,Ivan Mora-Sero,Victoria Gonzalez-Pedro,et al.Mechanism of carrier accumulation in perovskite thin-absorber solar cells[J].Nat Commun,2013,4:2242-2248.
[14]Aswani Yella,Leo-Philipp Heiniger,Michael Grtzel,et al.Nanocrystalline rutile electron extraction layer enables Low-Temperature solution processed perovskite photovoltaics with 13.7%efficiency[J].Nano Lett,2014,14(5):2591-2596.
[15]Mulmudi Hemant Kumar,Michael Graetzel,Subodh Mhaisalkar,et al.Flexible,low-temperature,solution processed Zn O-based perovskite solid state solar cells[J].Chem Commun,2013,49:11089-11091.
[16]Michael M Lee,Jol Teuscher,Henry J Snaith,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643-647.
[17]Edoardo Mosconi,Michael Grtzel,Filippo De Angelis,et al.Firstprinciples modeling of mixed halide organometal perovskites for photovoltaic applications[J].J Phys Chem C,2013,117:13902-13913.
[18]Jeong-Hyeok Im,Jaehoon Chung,Seung-Joo Kim,et al.Synthesis,structure,and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer(CH3CH2NH3)Pb I3[J].Nanoscale Res Lett,2012,7:353.
[19]Giles E Eperon,Samuel D Stranks,Henry J Snaith,et al.Formamidinium lead trihalide:A broadly tunable perovskite for efficient planar heterojunction solar cells[J].Energy Environ Sci,2014,7:982-988.
[20]Pang Shuping,Hu Hao,Zhang Jiliang,et al.NH2CHNH2Pb I3:An alternative organolead iodide perovskite sensitizer for mesoscopic solar cells[J].Chem Mater,2014,26(3):1485-1491.
[21]Burschka Julian,Norman Pellet,Michael Grtzel,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499:316-319.
[22]Liu Mingzhen,Michael B Johnston,Henry J Snaith.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501:395-398.
[23]Docampo Pablo,James M Ball,Henry J Snaith,et al.Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nat Commun,2013,4:2761.
[24]Dianyi Liu,Timothy L Kelly.Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nature Photon,2014,8:133-138.
[25]Guo Yunlong,Liu Chao,Kento Inoue,et al.Enhancement in the efficiency of an organic-inorganic hybrid solar cell with a doped P3HT hole-transporting layer on a void-free perovskite active layer[J].J Mater Chem A,2014,2:13827-13830.
[26]Bing Cai,Yedi Xing,Zhou Yang,et al.High performance hybrid solar cells sensitized by organolead halide perovskites[J].Energy Environ Sci,2013,6:1480-1485.
[27]Jin Hyuck Heo,Yong Hui Lee,Hi-jung Kim,et al.Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nature Photonics,2013,7:486-491.
[28]Olga Malinkiewicz,Aswani Yella,Yong Hui Lee,et al.Perovskite solar cells employing organic charge-transport layers[J].Nature Photonics,2014,8:128-132.
[29]Jeffrey A Christians,Raymond C M Fung,Prashant V Kamat,et al.An inorganic hole conductor for organo-Lead halide perovskite solar cells.Improved hole conductivity with copper iodide[J].J Am Chem Soc,2014,136(2):758-764.
[30]Eran Edri,Saar Kirmayer,David Cahen,et al.High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J].J Phys Chem Lett,2013,4(6):897-902.
[31]Martin A Green,Anita Ho-Baillie,Henry J Snaith.The emergence of perovskite solar cells[J].Nature Photonics,2014,8:506-514.
[2]Zhou Huanping,Chen Qi,Yang Yang,et al.Interface engineering of highly efficient perovskite solar cells[J].Science,2014,345(6196):542-546.
[3]Michael Grtzel.The light and shade of perovskite solar cells[J].Nat Mater,2014,13:838-842.
[4]Samuel D Stranks,Giles E Eperon,Giulia Grancini,et al.ElectronHole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J].Science,2013,342(6156):341-344.
[5]Hui-Seon Kim,Jin-Wook Lee,Michael Grtzel,et al.High efficiency solid-state sensitized solar cell-based on submicrometer rutile Ti O2nanorod and CH3NH3Pb I3perovskite sensitizer[J].Nano Lett,2013,13:2412-2417.
[6]Wang Jacob Tse-Wei,James M Ball,Henry J Snaith,et al.LowTemperature processed electron collection layers of Graphene/Ti O2nanocomposites in thin film perovskite solar Cells[J].Nano Lett,2014,14(2):724-730.
[7]Motonari Adachi,Yusuke Murata,Jun Takao,et al.Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like Ti O2nanowires made by the“Oriented Attachment”mechanism[J].J Am Chem Soc,2004,126:14943-14949.
[8]Lioz Etgar,Peng Gao,Michael Grtzel,et al.Mesoscopic CH3NH3Pb I3/Ti O2heterojunction solar cells[J].J Am Chem Soc,2012,134(42):17396-17399.
[9]Hui-Seon Kim,Chang-Ryul Lee,Michael Grtzel,et al.Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%[J].Sci Rep,2012,2:591.
[10]Saito Y,Fukuri N,Senadeera R,et al.Solid state dye sensitized solar cells using in situ polymerized PEDOTs as hole conductor[J].Electrochem Commun,2004,6:71-74.
[11]Qiu J,Qiu Y,Yan K,et al.All-solid-state hybrid solar cells based on a new organometal halide perovskite sensitizer and one-dimensional Ti O2nanowire arrays[J].Nanoscale,2013,5:3245-3248.
[12]Jun Hong Noh,Sang Hyuk Im,Jin Hyuck Heo,et al.Chemical management for colorful,efficient,and stable inorganic-organic hybrid nanostructured solar cells[J].Nano Lett,2013,13:1764-1769.
[13]Hui-Seon Kim,Ivan Mora-Sero,Victoria Gonzalez-Pedro,et al.Mechanism of carrier accumulation in perovskite thin-absorber solar cells[J].Nat Commun,2013,4:2242-2248.
[14]Aswani Yella,Leo-Philipp Heiniger,Michael Grtzel,et al.Nanocrystalline rutile electron extraction layer enables Low-Temperature solution processed perovskite photovoltaics with 13.7%efficiency[J].Nano Lett,2014,14(5):2591-2596.
[15]Mulmudi Hemant Kumar,Michael Graetzel,Subodh Mhaisalkar,et al.Flexible,low-temperature,solution processed Zn O-based perovskite solid state solar cells[J].Chem Commun,2013,49:11089-11091.
[16]Michael M Lee,Jol Teuscher,Henry J Snaith,et al.Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites[J].Science,2012,338(6107):643-647.
[17]Edoardo Mosconi,Michael Grtzel,Filippo De Angelis,et al.Firstprinciples modeling of mixed halide organometal perovskites for photovoltaic applications[J].J Phys Chem C,2013,117:13902-13913.
[18]Jeong-Hyeok Im,Jaehoon Chung,Seung-Joo Kim,et al.Synthesis,structure,and photovoltaic property of a nanocrystalline 2H perovskite-type novel sensitizer(CH3CH2NH3)Pb I3[J].Nanoscale Res Lett,2012,7:353.
[19]Giles E Eperon,Samuel D Stranks,Henry J Snaith,et al.Formamidinium lead trihalide:A broadly tunable perovskite for efficient planar heterojunction solar cells[J].Energy Environ Sci,2014,7:982-988.
[20]Pang Shuping,Hu Hao,Zhang Jiliang,et al.NH2CHNH2Pb I3:An alternative organolead iodide perovskite sensitizer for mesoscopic solar cells[J].Chem Mater,2014,26(3):1485-1491.
[21]Burschka Julian,Norman Pellet,Michael Grtzel,et al.Sequential deposition as a route to high-performance perovskite-sensitized solar cells[J].Nature,2013,499:316-319.
[22]Liu Mingzhen,Michael B Johnston,Henry J Snaith.Efficient planar heterojunction perovskite solar cells by vapour deposition[J].Nature,2013,501:395-398.
[23]Docampo Pablo,James M Ball,Henry J Snaith,et al.Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates[J].Nat Commun,2013,4:2761.
[24]Dianyi Liu,Timothy L Kelly.Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques[J].Nature Photon,2014,8:133-138.
[25]Guo Yunlong,Liu Chao,Kento Inoue,et al.Enhancement in the efficiency of an organic-inorganic hybrid solar cell with a doped P3HT hole-transporting layer on a void-free perovskite active layer[J].J Mater Chem A,2014,2:13827-13830.
[26]Bing Cai,Yedi Xing,Zhou Yang,et al.High performance hybrid solar cells sensitized by organolead halide perovskites[J].Energy Environ Sci,2013,6:1480-1485.
[27]Jin Hyuck Heo,Yong Hui Lee,Hi-jung Kim,et al.Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors[J].Nature Photonics,2013,7:486-491.
[28]Olga Malinkiewicz,Aswani Yella,Yong Hui Lee,et al.Perovskite solar cells employing organic charge-transport layers[J].Nature Photonics,2014,8:128-132.
[29]Jeffrey A Christians,Raymond C M Fung,Prashant V Kamat,et al.An inorganic hole conductor for organo-Lead halide perovskite solar cells.Improved hole conductivity with copper iodide[J].J Am Chem Soc,2014,136(2):758-764.
[30]Eran Edri,Saar Kirmayer,David Cahen,et al.High open-circuit voltage solar cells based on organic-inorganic lead bromide perovskite[J].J Phys Chem Lett,2013,4(6):897-902.
[31]Martin A Green,Anita Ho-Baillie,Henry J Snaith.The emergence of perovskite solar cells[J].Nature Photonics,2014,8:506-514.