石墨烯制备方法及在纺织品中的应用
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摘要
总结典型的石墨烯制备方法和近年来石墨烯与纺织品的复合与应用,制备方法包括机械法、氧化-还原法、取向附生法、气相沉积法、溶剂热法、淬火法、插层法,并探讨在纺织领域包括在纤维方面、织物方面、可穿戴方面的应用。指出目前石墨烯在制备成纤过程中存在的困难,与纺织品结合后使用过程中对环境耐受性的试验研究方向,以及在应用方面向健康监测与提高纺织品质量方向的发展。最后展望未来可穿戴纺织品的发展前景。
In this paper, the typical graphene preparation methods of graphene and the compounding and application of graphene and textiles in recent years were summarized. The preparation methods include mechanical method,oxidation-reduction method, orientation epigenetic method, vapor deposition method, solvothermal method, quenching method and intercalation method. The applications of graphene in textile industry include applications in fibre,fabric and wearability. And the difficulties in the preparation of graphene fibers, the research direction of environmental tolerance in the process of using graphene in combination with textiles and the developing direction of health monitoring and textile quality improving in application were put forward. Finally, the development prospects of wearable textiles in the future were prospected.
In this paper, the typical graphene preparation methods of graphene and the compounding and application of graphene and textiles in recent years were summarized. The preparation methods include mechanical method,oxidation-reduction method, orientation epigenetic method, vapor deposition method, solvothermal method, quenching method and intercalation method. The applications of graphene in textile industry include applications in fibre,fabric and wearability. And the difficulties in the preparation of graphene fibers, the research direction of environmental tolerance in the process of using graphene in combination with textiles and the developing direction of health monitoring and textile quality improving in application were put forward. Finally, the development prospects of wearable textiles in the future were prospected.
引文
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[33]亚洲纺织联盟.石墨烯提升跑鞋的性能[J].中国纤检,2018(3):129.
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[35]TAO L Q,ZHANG K N,TIAN H,et al.Graphene-paper pressure sensor for detecting human motions[J].ACSNano,2017,11(9):8790-8795.
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[37]凌良仲.石墨烯/PET复合导电纤维的制备与性能研究[D].天津:天津工业大学,2017.
[38]方舟.石墨烯的制备、功能化及其在纤维增强复合材料中的应用研究进展[J].天津纺织科技,2016(2):1-2,5.
[2]曹宇臣,郭鸣明.石墨烯材料及其应用[J].石油化工,2016,45(10):1149-1159.
[3]GEIM A K,KIM P.Carbon wonderland[J].Scientific American,2008,298(4):90-97.
[4]翟瑞瑞.基于石墨烯及其复合材料电化学传感研究[D].北京:北京化工大学,2011.
[5]DUBAS S T,KUMLANGDUDSANAP,POTIYARAJ P.Layer-by-layer deposition of antimicrobial silvernanoparti cles on textile fibers[J].Colloids and Surfaces A:Physicochemical and Engi neering Aspects,2006,289(1):105-109
[6]匡达,胡文彬.石墨烯复合材料的研究进展[J].无机材料学报,2013,28(3):235-246.
[7]何新民,张婷,陈飞,等.石墨烯在复合热电材料中的应用[J].化学进展,2018,30(4):439-447.
[8]马圣乾,裴立振,康英杰.石墨烯研究进展[J].现代物理知识,2009,21(4):44-47.
[9]张永.功能化部分还原氧化石墨烯的制备及电化学性能研究[D].哈尔滨:哈尔滨工业大学,2017.
[10]杨珊珊,孙怡,耿瑶瑶,等.还原氧化石墨烯制备方法研究进展[J].化学工程师,2016(10):37-40.
[11]刘霞.石墨烯及其复合材料的制备与性能研究[D].上海:东华大学,2016.
[12]韩林芷,赵占霞,马忠权.化学气相沉积法制备大尺寸单晶石墨烯的工艺参数研究[J].物理学报,2014,63(24):356-366.
[13]RAVANI F,PAPAGELIS K,DRA-COPOULOS V,et al.Graphene production by dissociation of camphor molecules on nickel substrate[J].Thin Solid Films,2013,527(1):31-37.
[14]韦丰.CVD法制备石墨烯材料及其表征[D].西安:长安大学,2016.
[15]袁小亚.石墨烯的制备研究进展[J]无机材料学报,2011,26(6):561-570.
[16]刘霞平,王会才,孙强,等.石墨烯、3D石墨烯及其复合材料的研究进展[J].化工进展,2018,37(1):168-174.
[17]CHOUCAIR M,THORDARSON P,STRIDE J A.Gram-scale production of graphene based on solvothermal synthesis and sonication[J].Nature Nanotechnology,2009,4(1):30-33.
[18]陈莹莹,宓一鸣,阮勤超,等.石墨烯的制备及应用的研究进展[J].硅酸盐通报,2015,34(3):755-763.
[19]蒋保江.石墨烯基复合材料的制备与性能研究[D].哈尔滨:哈尔滨工程大学,2012.
[20]原梅妮,向丰华,郎贤忠,等.石墨烯的制备方法与工艺研究进展[J].兵器材料科学与工程,2015,38(1):125-130.
[21]何大方,吴健,刘战剑,等.面向应用的石墨烯制备研究进展[J].化工学报,2015,66(8):2888-2894.
[22]胡希丽.石墨烯层层自组装功能纺织品制备及其性能研究[D].青岛:青岛大学,2016.
[23]胡希丽,田伟明,朱士凤,等.聚乙烯醇氧化石墨烯导电棉织物的制备[J].棉纺织技术,2016(4):28-32.
[24]赵晓凤.石墨烯/PET复合材料的制备及性能研究[D].杭州:浙江理工大学,2017.
[25]LIU K,CHEN L,CHEN Y,et al Preparation of polyester/reduced graphene oxide composites via in situ melt polycondensation and simultaneous thermo-reduction of graphene oxide[J]Journal of Materials Chemistry,2011,21(24):8612-8617.
[26]ZHU Y,MURALI S,CAI W,et al.Graphene and graphene oxide:synthesis,properties and application[J]Advanced Materials,2010,22(35):3906-3924.
[27]李昌垒,马君志,秦翠梅,等.石墨烯与再生纤维素复合纤维制备及性能研究[J].针织工业,2015(6):6-8.
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[29]LI G,HONG G,DONG D,et al.Multiresponsive graphene-aerogel-directed phase-change smart fibers[J].Advanced Materials,2018,30(30):1801754.
[30]Haydale Ltd.Haydale forms partnerships to accelerate functionalized graphene development[J].Additives for Polymers,2015(10):3-4.
[31]HU G,KANG J,NG L W T,et al.Functional inks and printing of two-dimensional materials[J].Chemical Society Reviews,2018,47(9):3265-3300.
[32]KARIM N,AFROJ S,TAN S,et al.Scalable production of graphene-based wearable e-textiles[J].ACS Nano,2017,11(12):12266-12275.
[33]亚洲纺织联盟.石墨烯提升跑鞋的性能[J].中国纤检,2018(3):129.
[34]佚名.新型柔性锌---空气电池可编织可穿戴[J].仪器仪表用户,2018,25(5):79.
[35]TAO L Q,ZHANG K N,TIAN H,et al.Graphene-paper pressure sensor for detecting human motions[J].ACSNano,2017,11(9):8790-8795.
[36]KABIRI AMERI S,HO R,JANGH,et al.Graphene electronic tattoo sen sors[J].ACS Nano,2017,11(8):7634-7641.
[37]凌良仲.石墨烯/PET复合导电纤维的制备与性能研究[D].天津:天津工业大学,2017.
[38]方舟.石墨烯的制备、功能化及其在纤维增强复合材料中的应用研究进展[J].天津纺织科技,2016(2):1-2,5.