新型碳材料在催化领域中的应用及进展
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摘要
碳材料以其优异的性能和独特的结构,已成为国内外研究的热点,在催化领域中常被用作催化剂和催化剂载体,有效提高了贵金属的利用效率.同时,新型碳材料的兴起也不断吸引着人们的目光.我们综述了普通活性炭、富勒烯、碳纳米管和石墨烯在工业催化反应中的一些应用情况,综述了它们作为催化剂和载体在催化反应中的实际应用和研究进展,最后展望了碳材料在催化领域中的未来发展前景.
The carbon material with its excellent performance and unique structure,has become a hot research t opic international. Its high specific surface and uniform pore size distribution can effectively improve the u tilization efficiency of precious metals. At the same time,the rise of new carbon materials also attracted people's attention.Some applications of the general activated carbon,fullerene,carbon nanotubes and graphene in the i ndustrial catalytic reactions are introduced in this paper. It reviewed the carbon material as a catalyst and support practical applications and research progress in catalysis. Finally,we comment the future advances of carbon material in c atalysis.
The carbon material with its excellent performance and unique structure,has become a hot research t opic international. Its high specific surface and uniform pore size distribution can effectively improve the u tilization efficiency of precious metals. At the same time,the rise of new carbon materials also attracted people's attention.Some applications of the general activated carbon,fullerene,carbon nanotubes and graphene in the i ndustrial catalytic reactions are introduced in this paper. It reviewed the carbon material as a catalyst and support practical applications and research progress in catalysis. Finally,we comment the future advances of carbon material in c atalysis.
引文
[1]Zhou J L,Sui Z J,Zhu J,et al.Characterization of surface oxygen complexes on carbon nanofibers by TPD,XPS and FT-IR[J].Carbon,2007,45(4):785-796.
[2]Rodriguez-Reinoso F.The role of carbon materials in heterogeneous catalysis[J].Carbon,1998,36(3):159-175.
[3]Han Xu(韩旭),Li Shu-fen(李疏芬).Advances in catalytic function of fullerene materials(富勒烯材料的催化作用研究进展)[J].Pro Chem(化学进展),2006,18(6):715-720.
[4]Wang Xin(汪信),Xu Chao(徐超).Graphene--a new carbon material(石墨烯—一种新型碳材料)[J].Science(科学),2010,62(3):25-27.
[5]a.Yin Bo(因博),Long Dong-hui(龙东辉),Xu Wei(徐伟),et al.Preparation of Ti O2/platelet carbon nanofiber nanocomposites and their photocatalytic performance for degradation of methyl orange(板式纳米碳纤维负载二氧化钛光催化复合材料的制备及降解甲基橙的研究)[J].J Mol Catal(China)(分子催化),2012,26(5):442-448.b.Ma Lin(马琳),Kang Xiao-xue(康晓雪),Hu Shaozheng(胡绍争),et al.Preparation of Fe-P Co-doped graphitic carbon nitride with enhanced isible-light photocatalytic activity(Fe-P共掺杂石墨相氮化碳催化剂可见光下催化性能研究)[J].J Mol Catal(China)(分子催化),2015,29(4):359-368.c.Zhang Rong(张蓉),Liu Lu(柳璐),Ma Fei(马飞),et al.Preparation and electrocatalytic activity of transition metal/nitrogendoped carboncatalysts for oxygen reduction reaction(过渡金属/氮掺杂石墨催化剂的制备及电催化氧还原)[J].J Mol Catal(China)(分子催化),2014,28(6):553-563.
[6]a.Wang Qing(汪青),Shang Jing(尚静),Zhao Fengwei(赵凤伟),et al.Visible light photocatalytic degradation of rhodamine B over MWCNTs-Ti O2composite device(多壁碳纳米管负载Ti O2复合器件可见光光催化降解Rh B)[J].J Mol Catal(China)(分子催化),2010,24(6):537-541.b.Yang Qin(杨琴),Zhou Juan(周娟),Yin Mengyun(尹梦云),et al.Lysine-graphene oxide as a heterogeneous ligand applied in Cu I-catalyzed C—N coupling reaction(赖氨酸修饰氧化石墨烯固体配体在C—N偶联中的应用研究)[J].J Mol Catal(China)(分子催化),2016,30(2):99-104.c.Wang Qing-yun(王清云),Tong Yong-chun(佟永纯),Xu Xin-jian(徐新建),et al.The influence of the stone-wales defectin graphene on the platinum catalyzed dissociation of oxygen(石墨烯中的Stone-wales缺陷对铂原子催化解离氧分子的影响)[J].J Mol Catal(China)(分子催化),2016,30(1):80-87.
[7]Zhou Wei(周薇),Hu Xiao-long(胡晓龙),Zhao Xiaorong(赵小蓉),et al.Preparation of graphene-Bi OBr composite and the enhanced photocatalytic activity under visible-light irradiation(石墨烯-溴氧化铋复合物的制备及可见光光催化性能研究)[J].J Mol Catal(China)(分子催化),2014,28(4):367-375.
[8]Liu Juan,Liu Yang,Liu Nai-yun,et al.Chem Inform abstract:Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway[J].Science,2015,347(6225):970-974.
[9]Zhao Shun-yan,Li Chuan-xi,Wang Li-ping,et al.Carbon quantum dots modified Mo S2with visible-light-induced high hydrogen evolution catalytic ability[J].Carbon,2015,99:599-606.
[10]Santos A,Yustos P,Rodriguez S,et al.Wet oxidation of phenol,cresols and nitrophenols catalyzed by activated carbon in acid and basic media[J].Appl Catal B,2006,65(3/4):269-281.
[11]Suarez-Ojeda M E,Stüber F,Fortuny A,et al.Catalytic wet air oxidation of substituted phenols using activated carbon as catalyst[J].Appl Catal B,2005,58(1/2):105-114.
[12]Cordero T,Rodríguez-Mirasol J,Bedia J,et al.Activated carbon as catalyst in wet oxidation of phenol:Effect of the oxidation reaction on the catalyst properties and stability[J].Appl Catal B,2008,81(1/2):122-131.
[13]Adapa S,Gaur V,Verma N.Catalytic oxidation of NO by activated carbon fiber(ACF)[J].Chem Eng J,2006,116(1):25-37.
[14]Qi J,Benipal N,Chadderdon D J,et al.Carbon nanotubes as catalysts for direct carbohydrazide fuel cells[J].Carbon,2015,89:142-147.
[15]Tang P,Gao Y J,Yang J H,et al.Growth mechanism of N-doped graphene materials and their catalytic behavior in the selective oxidation of ethylbenzene[J].Chin J Catal,2014,(6):922-928.
[16]Alkhazov T G,Lisovskii A E,Gulakhmedova T K.Oxidative dehydrogenation of ethylbenzene over a charcoal catalyst[J].Rea Kinet Catal L,1979,12(2):189-193.
[17]Cadus L E,Gorriz O F,Rivarola J B.Nature of active coke in the oxydehydrogenation of ethylbenzene to styrene[J].Ind Eng Chem Res,1990,29(7):1143-1146.
[18]Kane M S,Kao L C,Mariwala R K,et al.Effect of porosity of carbogenic molecular sieve catalysts on ethylbenzene oxidative dehydrogenation[J].Ind Eng Chem Res,1996,35(10):3319-3331.
[19]Pereira M F R,rfo J J M,Figueiredo J L.Oxidative dehydrogenation of ethylbenzene on activated carbon catalysts.I.Influence of surface chemical groups[J].Appl Catal A,1999,184(1):153-160.
[20]De Jesús Díaz Velásquez J,Suárez L M C,Figueiredo J L.Oxidative dehydrogenation of isobutane over activated carbon catalysts[J].Appl Catal A,2006,311:51-57.
[21]Carrasco-Marín F,Mueden A,Moreno-Castilla C.Surface-treated activated carbons as catalysts for the dehydration and dehydrogenation reactions of ethanol[J].J Phys Chem B,1998,102(46):9239-9244.
[22]Liu X J,Zhou Y C,Zhou W J,et al.Biomass-derived nitrogen self-doped porous carbon as effective metal-free catalysts for oxygen reduction reaction[J].Nanoscale,2015,7(14):6136-6142.
[23]Watson V J,Nieto Delgado C,Logan B E.Improvement of activated carbons as oxygen reduction catalysts in neutral solutions by ammonia gas treatment and their performance in microbial fuel cells[J].J Pow Sour,2013,242:756-761.
[24]Li W Q,Yang D G,Chen H B,et al.Sulfur-doped carbon nanotubes as catalysts for the oxygen reduction reaction in alkaline medium[J].Electrochim Acta,2015,165:191-197.
[25]Chen Z,Higgins D,Tao H S,et al.Highly active nitrogen-doped carbon nanotubes for oxygen reduction reaction in fuel cell applications[J].J Phys Chem C,2009,113(49):21008-21013.
[26]Jafri R I,Rajalakshmi N,Ramaprabhu S.Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell[J].J Mater Chem,2010,20(34):7114-7117.
[27]Subrahmanyam K S,Panchakarla L S,Govindaraj A,et al.Simple method of preparing graphene flakes by an arc-discharge method[J].J Phys Chem C,2009,113:4257-4259.
[28]Peng San(彭三),Guo Hui-lin(郭慧林),Kang Xiaofeng(亢晓峰),et al.Preparation of nitrogen-doped graphene and its eiectrocatalytic activity for oxygen reduction reaction(氮掺杂石墨烯的制备及其对氧还原反应的电催化性能)[J].Acta Phys-Chim Sin(物理化学学报),2014,30(9):1778-1786.
[29]Fang Peng-fei(方鹏飞),Wu Jing(吴静),Xiong Ming(熊鸣),et al.Preparation and study on the catalytic activity of fullerene-amine metal complexes(富勒烯胺金属配合物的制备及其催化性能研究)[J].J Wuhan Univ(武汉大学学报),2003,49(2):175-178.
[30]Rechnia P,Malaika A,Kozowski M.Synthesis of tertamyl methyl ether(TAME)over modified activated carbon catalysts[J].Fuel,2015,154:338-345.
[31]Lin G-D,Liang X-L,Liu L-M,et al.Multi-walled carbon nanotubes as novel promoter of catalysts for certain hydrogenation and dehydrogenation reactions[J].Sci Chin Chem,2015,58(1):47-59.
[32]Gao Wei-jie(高伟洁),Guo Shu-jing(郭淑静),Zhang Hong-bo(张洪波),et al.Enhanced ammonia synthesis activity of Ru supported on nitrogen-doped carbon nanotubes(氮掺杂碳纳米管对其负载的Ru催化剂上合成氨的促进作用)[J].Chin J Catal(催化学报),2011,32(8):1418-1423.
[33]Wei G,Wang L H,Lin Y J,et a1.Novel ruthenium catalyst(K-Ru/C60/70)for ammonia synthesis[J].Chin Chem Lett,1999,10(5):433-434.
[34]Yun C,Jing D-L,Hong B-C,et al.Novel Ru-K/carbon nanotubes catalyst for ammonia synthesis[J].Chin Chem Lett,2000,11(4):373-374.
[35]Shukla P R,Wang Shao-bin,Sun Hong-qi,et al.Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution[J].Appl Catal B,2010,100(3/4):529-534.
[36]Wu Y S,Yu H,Wang H J,et al.Controllable synthesis and catalytic performance of graphene-supported metal oxide nanoparticles[J].Chin J Catal,2014,(6):952-959.
[37]Wang Li(王丽),Ma Jun-hong(马俊红).Synthesis and electrocatalytic properties of Pt nanoparticles on nitrogen-doped reduced graphene oxide for methanol oxidation(氮掺杂还原氧化石墨烯负载铂催化剂的制备及甲醇电氧化性能)[J].Acta Phys-Chim Sin(物理化学学报),2014,(7):1267-1273.
[38]Wang Yuan(王媛),Chen Wei-ming(陈维民),Zhu Zhen-yu(朱振玉),et al.Preparation and performance for ethanol oxidation of nano-Pd/graphene nanoplateletscarbon nanotubes(纳米Pd/石墨烯-碳纳米管的制备及乙醇电氧化性能)[J].Chem Rea Eng Tec(China)化学反应工程与工艺,2015,31(5):430-435.
[39]Mu Y Y,Liang H P,Hu J S,et al.Controllable Pt nanoparticle deposition on carbon nanotubes as an anode catalyst for direct methanol fuel cells[J].J Phys Chem B,2005,109(47):22212-22216.
[40]Li Xiao-yun(李晓芸),Ma Ding(马丁),Bao Xin-he(包信和).Dispersion of Pt catalysts supported on activated carbon and their catalytic performance in methylcyclohexane dehydrogenation(不同活性炭上Pt催化剂的分散性及其在甲基环己烷脱氢反应中的催化性能)[J].Chin J Catal(催化学报),2008,29(3):259-263.
[41]Biniwale R,Kariya N,Ichikawa M.Dehydrogenation of cyclohexane over Ni based catalysts supported on activated carbon using spray-pulsed reactor and enhancement in activity by addition of a small amount of Pt[J].Catal Lett,2005,105(1/2):83-87.
[42]Ding Yan(丁彦),Pan Xia(潘霞),Xue Jin-zhen(薛锦珍),et al.Performance of Cr2O3/γ-Al2O3catalyst for isobutane dehydrogenation to isobutene(异丁烷催化脱氢制异丁烯Cr2O3/Al2O3体系催化剂)[J].J Mol Catal(China)(分子催化),1999,13(5):373-377.
[43]Hu Yun-xia(胡云霞),An Yue(安越),Cao Jing-wei(曹警伟),et al.Catalytic dehydrogenation of cyclohexane over carbon nanombes-supported elecroless nickelplating catalysts(镀镍碳纳米管催化环己烷脱氢反应的研究)[J].J Chem Eng Chin Univer(高校化学工程学报),2010,24(3):429-434.
[44]Du Jian-ping(杜建平),Song Chang(宋昌),Song Jing-ling(宋金玲),et al.Cyclohexane dehydrogenation over the platinum catalysts supported on carbon nanomaterials(纳米碳材料负载铂催化剂在环己烷脱氢反应中的催化性能研究)[J].J Fuel Chem Tech(燃料化学学报),2009,37(4):468-472.
[45]Castegnaro M V,Kilian A S,Baibich I M,et al.On the reactivity of carbon supported Pd nanoparticles during NO reduction:unraveling a metal-support redox interaction[J].Langmuir,2013,29(23):7125-7133.
[46]Li J,Liu C Y,Liu Y.Au/graphene hydrogel:synthesis,characterization and its use for catalytic reduction of4-nitrophenol[J].J Mater Chem,2012,22(17):8426-8430.
[47]Ma Y W,Liu Z R,Wang B L,et al.Preparation of grapheme-supported Pt-Co nanoparticles and their use in oxygen reduction reactions[J].New Carbon Mater,2012,27(4):250-257.
[48]Wu H,Peng T,Kou Z K,et al.Core-shell graphene@amorphous carbon compodites supported platinum catalysts for oxygen reduction reaction[J].Chin J Catal,2015,(4):490-495.
[49]Jiang L L,Wang Y L,Liu X,et al.Alumina-carbon nanotube supports for sulfur-resistant regenerable Ptbased catalysts in NOx reduction[J].Chin J Catal,2013,(12):2271-2276.
[50]Aksoylu A E,Madalena M,Freitas A,et al.The effects of different activated carbon supports and support modifications on the properties of Pt/AC catalysts[J].Carbon,2001,39(2):175-185.
[51]Tu C Y,Cheng S B.Ceria-modified palladium/activated carbon as a high-performance catalyst for crude caprolactam hydrogenation purification[J].ACS Sustain Chem&Eng,2014,2(4):629-636.
[52]Lordi V,Yao Nan,Wei J.Method for supporting platinum on single-walled carbon nanotubes for a selective hydrogenation catalyst[J].Chem Mater,2001,13(3):733-737.
[53]Shi J J,Nie R F,Zhang M Y,et al.Microwave-assisted fast fabrication of a nanosized Pt3Co alloy on reduced graphene oxides[J].Chin J Catal,2014,(12):2029-2037.
[54]Yang Jing-he(杨敬贺),Yu Qing-tao(郁清涛),Mao Li-qun(毛立群),et al.Pd/Graphene catalytic hydrogenation of benzoquinone to hydroquinone(钯/石墨烯催化苯醌加氢制备氢醌)[J].Chem Res(化学研究),2015,(5):460-463.
[55]Fang Yong-bin(房永彬),Yan Xin-huan(严新焕),Sun Jun-qing(孙军庆),et al.Catalytic performance of PtSn-B amorphous catalyst supported on carbon nanotubes for liquid-phase hydrogenation of chloronitrobenzene(碳纳米管负载Pt-Sn-B非晶态催化剂催化氯代硝基苯液相加氢反应的性能)[J].Chin J Catal(催化学报),2005,26(3):233-237.
[56]Díaz E,Casas J A,Mohedano F,et al.Kinetics of 4-chlorophenol hydrodechlorination with alumina and activated carbon-supported Pd and Rh catalysts[J].Ind Eng Chem Res,2009,48(7):3351-3358.
[57]Xu J H,Zhao J,Xu J T,et al.Influence of surface chemistry of activated carbon on the activity of gold/activated carbon catalyst in acetylene hydrochlorination[J].Ind Eng Chem Res,2014,53(37):14272-14281.
[58]lvarez-Montero M A,Gómez-Sainero L M,Mayoral A,et al.Hydrodechlorination of chloromethanes with a highly stable Pt on activated carbon catalyst[J].Chin J Catal,2011,279(2):389-396.
[59]lvarez-Montero M A,Gómez-Sainero L M,MartínMartínez M,et al.Hydrodechlorination of chloromethanes with Pd on activated carbon catalysts for the treatment of residual gas streams[J].Appl Catal B,2010,96(1/2):148-156.
[60]Farag H,Sakanishi K,Mochida I,et al.Kinetic analyses and Inhibition by naphthalene and H2S in hydrodesulfurization of 4,6-dimethyldibenzothiophene(4,6-DMDBT)over Co Mo-based carbon catalyst[J].Energ Fuel,1999,13(2):449-453.
[61]Dong Kun-ming(董昆明),Wu Xiao-man(武小满),Lin Guo-dong(林国栋),et al.Mo-Co catalyst supported on multiwalled carbon nanotubes for hydrodesulf urization of thiophene(碳纳米管负载/促进的Mo-Co加氢脱硫催化剂)[J].Chin J Catal(催化学报),2005,26(7):550-556.
[62]Fukuyama H,Terai S.Preparing and characterizing the active carbon produced by steam and carbon dioxide as a heavy oil hydrocracking catalyst support[J].Catal Today,2008,130(2/4):382-388.
[63]Viet T T,Lee J H,Ma Fan-zhong,et al.Hydrocracking of petroleum vacuum residue with activated carbon and metal additives in a supercritical m-xylene solvent[J].Fuel,2013,103:553-561.
[64]Li Chuan(李传),Shi Bin(石斌),Cui Min(崔敏),et al.Application of Co-Mo/CNT catalyst in hydro-cracking of gudao vacuum residue(碳纳米管负载Co-Mo催化剂在孤岛减压渣油加氢裂化反应中的应用)[J].J Fuel Chem Technol(燃料化学学报),2007,35(4):407-411.
[65]Mondal S,Das T,Ghosh P,et al.Exploring the interior of hollow fluorescent carbon nanoparticles[J].J Phys Chem C,2013,117(8):4260-4262.
[66]Ikezawa S,Homyara H,Kubota R,et al.Applications of Ti O2film for environmental purification deposited by controlled electron beam-excited plasma[J].Thin Sol Films,2001,386(2):173-176.
[67]Liu Rui-hua,Huang Hui,Li Hai-tao,et al.Metal nanoparticle/carbon quantum dot composite as a photocatalyst for high-efficiency cyclohexane oxidation[J].Acs Catal,2013,4(1):328-336.
[68]Liu Juan,Yang Yan-mei,Liu Nai-yun,et al.Total photocatalysis conversion from cyclohexane to cyclohexanone by C3N4/Au nanocomposites[J].Green Chem,2014,16(10):4559-4565.
[69]Li H T,He X D,Kang Z H,et al.Water-soluble fluorescentcarbon quantum dots and photocatalyst design[J].Angew Chem Int Ed,2010,49(26):4430-4434.
[70]Zhang Xiao-yan(张晓艳),Li Hao-peng(李浩鹏),Cui Xiao-li(崔晓莉),et al.Preparation and photocatalytic activity for hydrogen evolution of Ti O2/graphene sheets composite(Ti O2/石墨烯复合材料的合成及光催化分解水产氢活性)[J].Chin J Inorg Chem(无机化学学报),2009,25(11):1903-1907.
[71]Gao P,Sun D D.Hierarchical sulfonated graphene o xide-Ti O2composites for highly efficient hydrogen production with a wide p H range[J].Appl Catal B:Environ,2014,147(7):888-896.
[72]Kumar P,Sain B,Jain S L.Photocatalytic reduction of carbon dioxide to methanol using a ruthenium trinuclear polyazine complex immobilized on graphene oxide under visible light irradiation[J].J Mater Chem A.2014,2(29):11246-11253.
[73]Ong W J,Tan L L,Chai S P,et al.Heterojunction engineering of graphitic carbon nitride(g-C3N4)via Pt loading with improved daylight-induced photocatalytic reduction of carbon dioxide to methane[J].Dalton Trans,2015,44(2):1249-1257.
[74]Deliy I V,Simakova I L,Ravasio N,et al.Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate[J].Appl Catal A,2009,357(2):170-177.
[75]Wei Xia(魏霞),Guo Yun-hong(郭云红),Zhao Quanlin(赵泉林),et al.Catalytic degradation of 17β-estradiol in aqueous solution by magnetic Fe3O4/graphene nanocomposite(磁性Fe3O4/石墨烯纳米复合材料催化降解水中17β-雌二醇)[J].Chin J Environ Engineer(环境工程学报),2015,9(5):2137-2143.
[76]Nie Ren-feng(聂仁峰),Jiang He-zhan(江和展),Lu Xin-huan(鲁新环),et al.Synthesis and application of N-doped reduced graphene oxides supported Pd in Suzuki-Miyaura coupling reaction(氮杂石墨烯负载钯的制备及其在Suzuki偶联反应中的应用)[J].J Hubei Univer(湖北大学学报),2015,37(6):581-584.
[77]Deng Cao-lin(邓曹林),Wang Jing-gang(王京刚),Wang Ying(王颖),et al.Fenton catalytic degradation of phenol by using iron-loaded graphene modified mesoporous Al-MCM-41 catalyst(石墨烯改性Al-MCM-41介孔分子筛负载铁芬顿催化剂降解苯酚)[J].Environ Chem(环境化学),2015,(6):1185-1192.
[78]Hareesh H N,Minchitha K U,Nagaraju N,et al.Catalytic role of Cu(I)species in Cu2O/Cu I supported on MWCNTs in the oxidative amidation of aryl aldehydes with 2-aminopyridines[J].Chin J Catal,2015,(11):1825-1836.
[2]Rodriguez-Reinoso F.The role of carbon materials in heterogeneous catalysis[J].Carbon,1998,36(3):159-175.
[3]Han Xu(韩旭),Li Shu-fen(李疏芬).Advances in catalytic function of fullerene materials(富勒烯材料的催化作用研究进展)[J].Pro Chem(化学进展),2006,18(6):715-720.
[4]Wang Xin(汪信),Xu Chao(徐超).Graphene--a new carbon material(石墨烯—一种新型碳材料)[J].Science(科学),2010,62(3):25-27.
[5]a.Yin Bo(因博),Long Dong-hui(龙东辉),Xu Wei(徐伟),et al.Preparation of Ti O2/platelet carbon nanofiber nanocomposites and their photocatalytic performance for degradation of methyl orange(板式纳米碳纤维负载二氧化钛光催化复合材料的制备及降解甲基橙的研究)[J].J Mol Catal(China)(分子催化),2012,26(5):442-448.b.Ma Lin(马琳),Kang Xiao-xue(康晓雪),Hu Shaozheng(胡绍争),et al.Preparation of Fe-P Co-doped graphitic carbon nitride with enhanced isible-light photocatalytic activity(Fe-P共掺杂石墨相氮化碳催化剂可见光下催化性能研究)[J].J Mol Catal(China)(分子催化),2015,29(4):359-368.c.Zhang Rong(张蓉),Liu Lu(柳璐),Ma Fei(马飞),et al.Preparation and electrocatalytic activity of transition metal/nitrogendoped carboncatalysts for oxygen reduction reaction(过渡金属/氮掺杂石墨催化剂的制备及电催化氧还原)[J].J Mol Catal(China)(分子催化),2014,28(6):553-563.
[6]a.Wang Qing(汪青),Shang Jing(尚静),Zhao Fengwei(赵凤伟),et al.Visible light photocatalytic degradation of rhodamine B over MWCNTs-Ti O2composite device(多壁碳纳米管负载Ti O2复合器件可见光光催化降解Rh B)[J].J Mol Catal(China)(分子催化),2010,24(6):537-541.b.Yang Qin(杨琴),Zhou Juan(周娟),Yin Mengyun(尹梦云),et al.Lysine-graphene oxide as a heterogeneous ligand applied in Cu I-catalyzed C—N coupling reaction(赖氨酸修饰氧化石墨烯固体配体在C—N偶联中的应用研究)[J].J Mol Catal(China)(分子催化),2016,30(2):99-104.c.Wang Qing-yun(王清云),Tong Yong-chun(佟永纯),Xu Xin-jian(徐新建),et al.The influence of the stone-wales defectin graphene on the platinum catalyzed dissociation of oxygen(石墨烯中的Stone-wales缺陷对铂原子催化解离氧分子的影响)[J].J Mol Catal(China)(分子催化),2016,30(1):80-87.
[7]Zhou Wei(周薇),Hu Xiao-long(胡晓龙),Zhao Xiaorong(赵小蓉),et al.Preparation of graphene-Bi OBr composite and the enhanced photocatalytic activity under visible-light irradiation(石墨烯-溴氧化铋复合物的制备及可见光光催化性能研究)[J].J Mol Catal(China)(分子催化),2014,28(4):367-375.
[8]Liu Juan,Liu Yang,Liu Nai-yun,et al.Chem Inform abstract:Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway[J].Science,2015,347(6225):970-974.
[9]Zhao Shun-yan,Li Chuan-xi,Wang Li-ping,et al.Carbon quantum dots modified Mo S2with visible-light-induced high hydrogen evolution catalytic ability[J].Carbon,2015,99:599-606.
[10]Santos A,Yustos P,Rodriguez S,et al.Wet oxidation of phenol,cresols and nitrophenols catalyzed by activated carbon in acid and basic media[J].Appl Catal B,2006,65(3/4):269-281.
[11]Suarez-Ojeda M E,Stüber F,Fortuny A,et al.Catalytic wet air oxidation of substituted phenols using activated carbon as catalyst[J].Appl Catal B,2005,58(1/2):105-114.
[12]Cordero T,Rodríguez-Mirasol J,Bedia J,et al.Activated carbon as catalyst in wet oxidation of phenol:Effect of the oxidation reaction on the catalyst properties and stability[J].Appl Catal B,2008,81(1/2):122-131.
[13]Adapa S,Gaur V,Verma N.Catalytic oxidation of NO by activated carbon fiber(ACF)[J].Chem Eng J,2006,116(1):25-37.
[14]Qi J,Benipal N,Chadderdon D J,et al.Carbon nanotubes as catalysts for direct carbohydrazide fuel cells[J].Carbon,2015,89:142-147.
[15]Tang P,Gao Y J,Yang J H,et al.Growth mechanism of N-doped graphene materials and their catalytic behavior in the selective oxidation of ethylbenzene[J].Chin J Catal,2014,(6):922-928.
[16]Alkhazov T G,Lisovskii A E,Gulakhmedova T K.Oxidative dehydrogenation of ethylbenzene over a charcoal catalyst[J].Rea Kinet Catal L,1979,12(2):189-193.
[17]Cadus L E,Gorriz O F,Rivarola J B.Nature of active coke in the oxydehydrogenation of ethylbenzene to styrene[J].Ind Eng Chem Res,1990,29(7):1143-1146.
[18]Kane M S,Kao L C,Mariwala R K,et al.Effect of porosity of carbogenic molecular sieve catalysts on ethylbenzene oxidative dehydrogenation[J].Ind Eng Chem Res,1996,35(10):3319-3331.
[19]Pereira M F R,rfo J J M,Figueiredo J L.Oxidative dehydrogenation of ethylbenzene on activated carbon catalysts.I.Influence of surface chemical groups[J].Appl Catal A,1999,184(1):153-160.
[20]De Jesús Díaz Velásquez J,Suárez L M C,Figueiredo J L.Oxidative dehydrogenation of isobutane over activated carbon catalysts[J].Appl Catal A,2006,311:51-57.
[21]Carrasco-Marín F,Mueden A,Moreno-Castilla C.Surface-treated activated carbons as catalysts for the dehydration and dehydrogenation reactions of ethanol[J].J Phys Chem B,1998,102(46):9239-9244.
[22]Liu X J,Zhou Y C,Zhou W J,et al.Biomass-derived nitrogen self-doped porous carbon as effective metal-free catalysts for oxygen reduction reaction[J].Nanoscale,2015,7(14):6136-6142.
[23]Watson V J,Nieto Delgado C,Logan B E.Improvement of activated carbons as oxygen reduction catalysts in neutral solutions by ammonia gas treatment and their performance in microbial fuel cells[J].J Pow Sour,2013,242:756-761.
[24]Li W Q,Yang D G,Chen H B,et al.Sulfur-doped carbon nanotubes as catalysts for the oxygen reduction reaction in alkaline medium[J].Electrochim Acta,2015,165:191-197.
[25]Chen Z,Higgins D,Tao H S,et al.Highly active nitrogen-doped carbon nanotubes for oxygen reduction reaction in fuel cell applications[J].J Phys Chem C,2009,113(49):21008-21013.
[26]Jafri R I,Rajalakshmi N,Ramaprabhu S.Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell[J].J Mater Chem,2010,20(34):7114-7117.
[27]Subrahmanyam K S,Panchakarla L S,Govindaraj A,et al.Simple method of preparing graphene flakes by an arc-discharge method[J].J Phys Chem C,2009,113:4257-4259.
[28]Peng San(彭三),Guo Hui-lin(郭慧林),Kang Xiaofeng(亢晓峰),et al.Preparation of nitrogen-doped graphene and its eiectrocatalytic activity for oxygen reduction reaction(氮掺杂石墨烯的制备及其对氧还原反应的电催化性能)[J].Acta Phys-Chim Sin(物理化学学报),2014,30(9):1778-1786.
[29]Fang Peng-fei(方鹏飞),Wu Jing(吴静),Xiong Ming(熊鸣),et al.Preparation and study on the catalytic activity of fullerene-amine metal complexes(富勒烯胺金属配合物的制备及其催化性能研究)[J].J Wuhan Univ(武汉大学学报),2003,49(2):175-178.
[30]Rechnia P,Malaika A,Kozowski M.Synthesis of tertamyl methyl ether(TAME)over modified activated carbon catalysts[J].Fuel,2015,154:338-345.
[31]Lin G-D,Liang X-L,Liu L-M,et al.Multi-walled carbon nanotubes as novel promoter of catalysts for certain hydrogenation and dehydrogenation reactions[J].Sci Chin Chem,2015,58(1):47-59.
[32]Gao Wei-jie(高伟洁),Guo Shu-jing(郭淑静),Zhang Hong-bo(张洪波),et al.Enhanced ammonia synthesis activity of Ru supported on nitrogen-doped carbon nanotubes(氮掺杂碳纳米管对其负载的Ru催化剂上合成氨的促进作用)[J].Chin J Catal(催化学报),2011,32(8):1418-1423.
[33]Wei G,Wang L H,Lin Y J,et a1.Novel ruthenium catalyst(K-Ru/C60/70)for ammonia synthesis[J].Chin Chem Lett,1999,10(5):433-434.
[34]Yun C,Jing D-L,Hong B-C,et al.Novel Ru-K/carbon nanotubes catalyst for ammonia synthesis[J].Chin Chem Lett,2000,11(4):373-374.
[35]Shukla P R,Wang Shao-bin,Sun Hong-qi,et al.Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution[J].Appl Catal B,2010,100(3/4):529-534.
[36]Wu Y S,Yu H,Wang H J,et al.Controllable synthesis and catalytic performance of graphene-supported metal oxide nanoparticles[J].Chin J Catal,2014,(6):952-959.
[37]Wang Li(王丽),Ma Jun-hong(马俊红).Synthesis and electrocatalytic properties of Pt nanoparticles on nitrogen-doped reduced graphene oxide for methanol oxidation(氮掺杂还原氧化石墨烯负载铂催化剂的制备及甲醇电氧化性能)[J].Acta Phys-Chim Sin(物理化学学报),2014,(7):1267-1273.
[38]Wang Yuan(王媛),Chen Wei-ming(陈维民),Zhu Zhen-yu(朱振玉),et al.Preparation and performance for ethanol oxidation of nano-Pd/graphene nanoplateletscarbon nanotubes(纳米Pd/石墨烯-碳纳米管的制备及乙醇电氧化性能)[J].Chem Rea Eng Tec(China)化学反应工程与工艺,2015,31(5):430-435.
[39]Mu Y Y,Liang H P,Hu J S,et al.Controllable Pt nanoparticle deposition on carbon nanotubes as an anode catalyst for direct methanol fuel cells[J].J Phys Chem B,2005,109(47):22212-22216.
[40]Li Xiao-yun(李晓芸),Ma Ding(马丁),Bao Xin-he(包信和).Dispersion of Pt catalysts supported on activated carbon and their catalytic performance in methylcyclohexane dehydrogenation(不同活性炭上Pt催化剂的分散性及其在甲基环己烷脱氢反应中的催化性能)[J].Chin J Catal(催化学报),2008,29(3):259-263.
[41]Biniwale R,Kariya N,Ichikawa M.Dehydrogenation of cyclohexane over Ni based catalysts supported on activated carbon using spray-pulsed reactor and enhancement in activity by addition of a small amount of Pt[J].Catal Lett,2005,105(1/2):83-87.
[42]Ding Yan(丁彦),Pan Xia(潘霞),Xue Jin-zhen(薛锦珍),et al.Performance of Cr2O3/γ-Al2O3catalyst for isobutane dehydrogenation to isobutene(异丁烷催化脱氢制异丁烯Cr2O3/Al2O3体系催化剂)[J].J Mol Catal(China)(分子催化),1999,13(5):373-377.
[43]Hu Yun-xia(胡云霞),An Yue(安越),Cao Jing-wei(曹警伟),et al.Catalytic dehydrogenation of cyclohexane over carbon nanombes-supported elecroless nickelplating catalysts(镀镍碳纳米管催化环己烷脱氢反应的研究)[J].J Chem Eng Chin Univer(高校化学工程学报),2010,24(3):429-434.
[44]Du Jian-ping(杜建平),Song Chang(宋昌),Song Jing-ling(宋金玲),et al.Cyclohexane dehydrogenation over the platinum catalysts supported on carbon nanomaterials(纳米碳材料负载铂催化剂在环己烷脱氢反应中的催化性能研究)[J].J Fuel Chem Tech(燃料化学学报),2009,37(4):468-472.
[45]Castegnaro M V,Kilian A S,Baibich I M,et al.On the reactivity of carbon supported Pd nanoparticles during NO reduction:unraveling a metal-support redox interaction[J].Langmuir,2013,29(23):7125-7133.
[46]Li J,Liu C Y,Liu Y.Au/graphene hydrogel:synthesis,characterization and its use for catalytic reduction of4-nitrophenol[J].J Mater Chem,2012,22(17):8426-8430.
[47]Ma Y W,Liu Z R,Wang B L,et al.Preparation of grapheme-supported Pt-Co nanoparticles and their use in oxygen reduction reactions[J].New Carbon Mater,2012,27(4):250-257.
[48]Wu H,Peng T,Kou Z K,et al.Core-shell graphene@amorphous carbon compodites supported platinum catalysts for oxygen reduction reaction[J].Chin J Catal,2015,(4):490-495.
[49]Jiang L L,Wang Y L,Liu X,et al.Alumina-carbon nanotube supports for sulfur-resistant regenerable Ptbased catalysts in NOx reduction[J].Chin J Catal,2013,(12):2271-2276.
[50]Aksoylu A E,Madalena M,Freitas A,et al.The effects of different activated carbon supports and support modifications on the properties of Pt/AC catalysts[J].Carbon,2001,39(2):175-185.
[51]Tu C Y,Cheng S B.Ceria-modified palladium/activated carbon as a high-performance catalyst for crude caprolactam hydrogenation purification[J].ACS Sustain Chem&Eng,2014,2(4):629-636.
[52]Lordi V,Yao Nan,Wei J.Method for supporting platinum on single-walled carbon nanotubes for a selective hydrogenation catalyst[J].Chem Mater,2001,13(3):733-737.
[53]Shi J J,Nie R F,Zhang M Y,et al.Microwave-assisted fast fabrication of a nanosized Pt3Co alloy on reduced graphene oxides[J].Chin J Catal,2014,(12):2029-2037.
[54]Yang Jing-he(杨敬贺),Yu Qing-tao(郁清涛),Mao Li-qun(毛立群),et al.Pd/Graphene catalytic hydrogenation of benzoquinone to hydroquinone(钯/石墨烯催化苯醌加氢制备氢醌)[J].Chem Res(化学研究),2015,(5):460-463.
[55]Fang Yong-bin(房永彬),Yan Xin-huan(严新焕),Sun Jun-qing(孙军庆),et al.Catalytic performance of PtSn-B amorphous catalyst supported on carbon nanotubes for liquid-phase hydrogenation of chloronitrobenzene(碳纳米管负载Pt-Sn-B非晶态催化剂催化氯代硝基苯液相加氢反应的性能)[J].Chin J Catal(催化学报),2005,26(3):233-237.
[56]Díaz E,Casas J A,Mohedano F,et al.Kinetics of 4-chlorophenol hydrodechlorination with alumina and activated carbon-supported Pd and Rh catalysts[J].Ind Eng Chem Res,2009,48(7):3351-3358.
[57]Xu J H,Zhao J,Xu J T,et al.Influence of surface chemistry of activated carbon on the activity of gold/activated carbon catalyst in acetylene hydrochlorination[J].Ind Eng Chem Res,2014,53(37):14272-14281.
[58]lvarez-Montero M A,Gómez-Sainero L M,Mayoral A,et al.Hydrodechlorination of chloromethanes with a highly stable Pt on activated carbon catalyst[J].Chin J Catal,2011,279(2):389-396.
[59]lvarez-Montero M A,Gómez-Sainero L M,MartínMartínez M,et al.Hydrodechlorination of chloromethanes with Pd on activated carbon catalysts for the treatment of residual gas streams[J].Appl Catal B,2010,96(1/2):148-156.
[60]Farag H,Sakanishi K,Mochida I,et al.Kinetic analyses and Inhibition by naphthalene and H2S in hydrodesulfurization of 4,6-dimethyldibenzothiophene(4,6-DMDBT)over Co Mo-based carbon catalyst[J].Energ Fuel,1999,13(2):449-453.
[61]Dong Kun-ming(董昆明),Wu Xiao-man(武小满),Lin Guo-dong(林国栋),et al.Mo-Co catalyst supported on multiwalled carbon nanotubes for hydrodesulf urization of thiophene(碳纳米管负载/促进的Mo-Co加氢脱硫催化剂)[J].Chin J Catal(催化学报),2005,26(7):550-556.
[62]Fukuyama H,Terai S.Preparing and characterizing the active carbon produced by steam and carbon dioxide as a heavy oil hydrocracking catalyst support[J].Catal Today,2008,130(2/4):382-388.
[63]Viet T T,Lee J H,Ma Fan-zhong,et al.Hydrocracking of petroleum vacuum residue with activated carbon and metal additives in a supercritical m-xylene solvent[J].Fuel,2013,103:553-561.
[64]Li Chuan(李传),Shi Bin(石斌),Cui Min(崔敏),et al.Application of Co-Mo/CNT catalyst in hydro-cracking of gudao vacuum residue(碳纳米管负载Co-Mo催化剂在孤岛减压渣油加氢裂化反应中的应用)[J].J Fuel Chem Technol(燃料化学学报),2007,35(4):407-411.
[65]Mondal S,Das T,Ghosh P,et al.Exploring the interior of hollow fluorescent carbon nanoparticles[J].J Phys Chem C,2013,117(8):4260-4262.
[66]Ikezawa S,Homyara H,Kubota R,et al.Applications of Ti O2film for environmental purification deposited by controlled electron beam-excited plasma[J].Thin Sol Films,2001,386(2):173-176.
[67]Liu Rui-hua,Huang Hui,Li Hai-tao,et al.Metal nanoparticle/carbon quantum dot composite as a photocatalyst for high-efficiency cyclohexane oxidation[J].Acs Catal,2013,4(1):328-336.
[68]Liu Juan,Yang Yan-mei,Liu Nai-yun,et al.Total photocatalysis conversion from cyclohexane to cyclohexanone by C3N4/Au nanocomposites[J].Green Chem,2014,16(10):4559-4565.
[69]Li H T,He X D,Kang Z H,et al.Water-soluble fluorescentcarbon quantum dots and photocatalyst design[J].Angew Chem Int Ed,2010,49(26):4430-4434.
[70]Zhang Xiao-yan(张晓艳),Li Hao-peng(李浩鹏),Cui Xiao-li(崔晓莉),et al.Preparation and photocatalytic activity for hydrogen evolution of Ti O2/graphene sheets composite(Ti O2/石墨烯复合材料的合成及光催化分解水产氢活性)[J].Chin J Inorg Chem(无机化学学报),2009,25(11):1903-1907.
[71]Gao P,Sun D D.Hierarchical sulfonated graphene o xide-Ti O2composites for highly efficient hydrogen production with a wide p H range[J].Appl Catal B:Environ,2014,147(7):888-896.
[72]Kumar P,Sain B,Jain S L.Photocatalytic reduction of carbon dioxide to methanol using a ruthenium trinuclear polyazine complex immobilized on graphene oxide under visible light irradiation[J].J Mater Chem A.2014,2(29):11246-11253.
[73]Ong W J,Tan L L,Chai S P,et al.Heterojunction engineering of graphitic carbon nitride(g-C3N4)via Pt loading with improved daylight-induced photocatalytic reduction of carbon dioxide to methane[J].Dalton Trans,2015,44(2):1249-1257.
[74]Deliy I V,Simakova I L,Ravasio N,et al.Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate[J].Appl Catal A,2009,357(2):170-177.
[75]Wei Xia(魏霞),Guo Yun-hong(郭云红),Zhao Quanlin(赵泉林),et al.Catalytic degradation of 17β-estradiol in aqueous solution by magnetic Fe3O4/graphene nanocomposite(磁性Fe3O4/石墨烯纳米复合材料催化降解水中17β-雌二醇)[J].Chin J Environ Engineer(环境工程学报),2015,9(5):2137-2143.
[76]Nie Ren-feng(聂仁峰),Jiang He-zhan(江和展),Lu Xin-huan(鲁新环),et al.Synthesis and application of N-doped reduced graphene oxides supported Pd in Suzuki-Miyaura coupling reaction(氮杂石墨烯负载钯的制备及其在Suzuki偶联反应中的应用)[J].J Hubei Univer(湖北大学学报),2015,37(6):581-584.
[77]Deng Cao-lin(邓曹林),Wang Jing-gang(王京刚),Wang Ying(王颖),et al.Fenton catalytic degradation of phenol by using iron-loaded graphene modified mesoporous Al-MCM-41 catalyst(石墨烯改性Al-MCM-41介孔分子筛负载铁芬顿催化剂降解苯酚)[J].Environ Chem(环境化学),2015,(6):1185-1192.
[78]Hareesh H N,Minchitha K U,Nagaraju N,et al.Catalytic role of Cu(I)species in Cu2O/Cu I supported on MWCNTs in the oxidative amidation of aryl aldehydes with 2-aminopyridines[J].Chin J Catal,2015,(11):1825-1836.