石墨烯制备及应用研究进展
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摘要
石墨烯是近几年发展起来的一种非常有潜力的新型碳材料,具有优异的物理和化学性能,在物理、化学、电子器件、能源以及材料等领域具有广泛的应用。综述了目前制备石墨烯的几种方法:机械剥离法、氧化还原法、液相剥离法、电化学剥离法、超临界流体剥离法、化学气相沉积法和外延生长法等,对比了各种制备方法的优缺点,分析了石墨烯制备方法的发展趋势,并对石墨烯行业的应用前景与发展趋势进行了展望。
Graphene is a very promising and new carbon material, which was rapidly developed in recent years. It has excellent physical and chemical properties and is widely used in many fields such as physics, chemistry, electronic devices. Several current methods for the preparation of graphene including mechanical stripping, redox, liquid stripping, electrochemical stripping, supercritical fluid stripping, chemical vapor deposition and epitaxial growth. The advantages and disadvantages of various graphene preparation methods are compared and the developing trends of graphene preparation methods are analyzed. The application prospect and developing trend of graphene industry are also prospected.
Graphene is a very promising and new carbon material, which was rapidly developed in recent years. It has excellent physical and chemical properties and is widely used in many fields such as physics, chemistry, electronic devices. Several current methods for the preparation of graphene including mechanical stripping, redox, liquid stripping, electrochemical stripping, supercritical fluid stripping, chemical vapor deposition and epitaxial growth. The advantages and disadvantages of various graphene preparation methods are compared and the developing trends of graphene preparation methods are analyzed. The application prospect and developing trend of graphene industry are also prospected.
引文
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[15] Cai M Z,Thorpe D,Damson D H,et al.Methods of Graphite Exfoliation [J].J Mater Chem,2012,22(48):24 992-25 002.
[16] Ma L,Chen X X,Mo D C,et al.Preparation,Proper-ties and Mechanism of Graphene Thermal Conductive Polymer Composites [J].J Chem Ind Eng,2017,17(s1):18-25 (in Chinese).(马良,陈楷炫,莫冬传,等.石墨烯导热高分子复合材料的制备、性能与机理[J].化工学报,2017,17(s1):18-25.)
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[18] Yin W H,Han Q,Yang X H.Research Progress of Graphene-based Semiconductor Optoelectronic Devices [J].Acta Phys Sin,2012,61(24):1-12 (in Chinese).(尹伟红,韩勤,杨晓红.基于石墨烯的半导体光电器件研究进展 [J].物理学报,2012,61(24):585-596.)
[19] Yan L Q,Xu T,Song T X.Application Research of Industrial Graphene [J].Adv Mater Ind,2016,10(8):52-57 (in Chinese).(闫立群,徐亭,宋天欣.工业化石墨烯应用研究[J].新材料产业,2016,10(8):52-57.)
[20] Zhang X S,Zhou Q X.Research Progress of Graphene Stripping for Graphene Production [J].Carbon Tech,2017,36(4):7-10 (in Chinese).(张小诗,周秋香.石墨剥离制备石墨烯的研究进展[J].炭素技术,2017,36(4):7-10.)
[21] Xiao S J,Yu S W,Tan X Y.Preparation and Proper-ties of Graphene [J].Chem World,2015,56(6):378-382 (in Chinese).(肖淑娟,于守武,谭小耀.石墨烯的制备方法及其性能研究[J].化学世界,2015,56(6):378-382.)
[22] Chen C.Preparation of Graphene Composites and Their Application in Photoelectric Conversion [D].Shanghai:Shanghai Jiaotong University,2013 (in Chinese).(陈晨.石墨烯复合材料的制备及其在光电转换中的应用[D].上海:上海交通大学,2013.)
[23] Mei X F,Meng X Q,Wu F M,et al.Hydrothermal Method for the Production of Reduced Grapheneoxide [J].Phys E,2015,68(2015):81-86.
[24] Liu X X,Wang X P,Wang L J,et al.Graphene Research Progress [J].Mater Rev A,2011,25(12):92-97 (in Chinese).(刘欣欣,王小平,王丽军,等.石墨烯的研究进展[J].材料导报 A,2011,25(12):92-97).
[25] Chen Y S,Huang Y I,et al.Graphene—A Novel Two-Dimensional Carbon Nanomaterial [M].Beijing:Science and Technology Press,2013 (in Chinese).(陈永胜,黄毅.石墨烯———新型二维碳纳米材料[M].北京:科技出版社,2013.)
[26] Shi M Y,Zhang X F,Wang X Y,et al.Direct Liquid Phase Stripping Method for Preparing Defect-free Graphene [J].J Nanjing Norm Univ (Eng Technol Ed),2014,14(2):1-7 (in Chinese).(石梦燕,张晓凤,王孝英,等 .直接液相剥离法制备无缺陷石墨烯[J].南京师范大学学报(工程技术版),2014,14(2):1-7.)
[27] Coleman J N,Heenandez Y,Nicolosi V,et al.High-yield Production of Graphene by Liquid Phase Exfoliation of Graphite [J].Nat Nanotechnol,2008,3(9):563-568.
[28] Green A A,Hersam M C.Solution Phase Production of Graphene with Controlled Thickness via Density Differentiation [J].Nano Lett,2009,9(12):4 031-4 036.
[29] Qi S,Huang G Q.New Development of Graphene Production by Liquid Stripping [J].Mater Rev,2017,31(17):34-40 (in Chinese).(祁帅,黄国强.液相剥离法制备石墨烯的新进展[J].材料导报,2017,31(17):34-40.)
[30] Liu N,Luo F,Wu H,et al.One-step Ionic-liquid-assisted Electrochemical Synthesis of Ionic-liquid-functionalized Graphene Sheets Directly from Graphi-te [J].Adv Funct Mater,2008,18(10):1 518-1 525.
[31] Ping Y J,Gong Y N,Pan C X.Research Progress of Graphene Production by Electrochemical Stripping and Its Photoelectric Properties [J].Chin J Lasers,2017,44(7):98-113 (in Chinese).(平蕴杰,龚佑宁,潘春旭.电化学剥离制备石墨烯及其光电特性研究进展[J].中国激光,2017,44(7):98-113.)
[32] Sahoo S K,Mallik A.Simple,Fastand Cost-effective Electrochemical Synthesis of Few Layer Graphene Nanosheets [J].Nano,2015,10(2):666-698.
[33] Pu N W,Wang C A,Yu S,et al.Production of Few-layer Graphene by Supercritical CO2 Exfoliation of Graphite [J].Mater Lett,2009,63(23):1 987-1 989.
[34] Wang W,Wang Y,Gao Y,et al.Control of Number of Graphene Layers Using Ultrasound in Supercritical CO2 and Their Application in Lithium-ion Batteries [J].J Supercrit Fluids,2014,85(1):95-101.
[35] Rangappa D,Sone K,Wang M,et al.Rapid and Direct Conversion of Graphite Crystals into High-yielding,Good-quality Graphene by Supercritical Fluid Exfoliation [J].Chem A Eur J,2010,16(22):6 488-6 494.
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