稻壳生物质资源利用技术研究进展
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  • 英文篇名:Research progress of rice husk utilization technologies
  • 作者:何文修 ; 张智亮 ; 计建炳
  • 英文作者:HE Wenxiu;ZHANG Zhiliang;JI Jianbing;College of Chemical Engineering,Zhejiang University of Technology;
  • 关键词:生物质 ; 生物能源 ; 吸附剂 ; 催化剂载体
  • 英文关键词:biomass;;bioenergy;;adsorbents;;catalyst support
  • 中文刊名:HGJZ
  • 英文刊名:Chemical Industry and Engineering Progress
  • 机构:浙江工业大学化学工程学院;
  • 出版日期:2016-05-05
  • 出版单位:化工进展
  • 年:2016
  • 期:v.35;No.296
  • 基金:国家自然科学基金(21406198);; 浙江省自然科学基金(LQ14B060003)项目
  • 语种:中文;
  • 页:HGJZ201605018
  • 页数:11
  • CN:05
  • ISSN:11-1954/TQ
  • 分类号:109-119
摘要
稻壳是一种产量巨大的农业废弃物,直接丢弃或掩埋不但会造成资源浪费更会引起环境污染。稻壳中含有丰富的Si O_2、纤维素、半纤维素和木质素等。资源化利用是稻壳有效利用的发展方向和趋势。本文综述了近年来国内外稻壳资源化利用的研究进展。根据稻壳的特性,将资源化利用方式分为能源化利用、工业化利用及农业化利用,并对其研究现状进行了介绍。重点阐述了稻壳在气化制备可燃气、热裂解制备生物油、改性制备吸附剂、合成分子筛、制备催化剂载体、生产白炭黑与活性炭、水解制备糠醛、木聚糖、低聚木糖及发酵制备饲料等方面的研究进展,同时对其发展方向和趋势进行了展望,指出最大限度控制成本将成为稻壳资源化利用实现工业化的重要因素。
        Rice husk,is abundantly available in rice-producing countries as an agricultural residue. If rick husk is improperly handled,it will cause environment pollution as well as waste of resources. The main components of rice husk are silica,cellulose,hemicellulose and lignin. The utilization of rick husk as a renewable resource for the production of various products has been a meaningful research topic for decades. Based on the characteristics of rice husk,the utilization methods can be divided into energy,industrial and agricultural utilization. This paper reviews the current research progress of rice husk utilization technologies. From rice husk,a large variety of high value products can be produced,such as bio-gas,bio-oil,adsorbents,catalyst supports,silica,activated carbon,furfural,xylan,xylo-oligosaccharides and animal feeds. The future prospects related to the utilization of rice husk are addressed. The main challenge for rice husk utilization is to reduce the manufacturing cost.
引文
[1]董丽辉.稻壳中生物质及二氧化硅的提取工艺研究[D]:哈尔滨:东北农业大学,2011.
    [2]马晓宇.生物质基二氧化硅的提取及在聚酯中的应用[D].长春:吉林大学,2012.
    [3]王惠玲,张洪起,张永欣,等.利用稻壳制取白炭黑的工艺研究[J].无机盐工业,2008,40(9):45-47.
    [4]潘贤齐,苏德仁,周肇秋,等.生物质流化床气化中试实验研究[J].农业机械学报,2014,45(10):175-179,287.
    [5]王立群,陈兆生.煤与生物质流化床水蒸气共气化[J].中南大学学报(自然科学版).2014,45(5):1692-1698.
    [6]贤建伟,范晓旭,韩中合,等.床料对生物质流化床气化影响的初步试验研究[J].可再生能源,2011,29(1):45-48.
    [7]MAKWANA J P,JOSHI A K,ATHAWALE G,et al.Air gasification of rice husk in bubbling fluidized bed reactor with bed heating by conventional charcoal[J].Bioresource Technology,2015,178:45-52.
    [8]GE H J,GUO W J,SHEN L H,et al.Experimental investigation on biomass gasification using chemical looping in a batch reactor and a continuous dual reactor[J].Chemical Engineering Journal,2016,286:689-700.
    [9]卢红伟,刘耀鑫.稻壳热解气化特性的试验研究[J].可再生能源,2009,27(2):52-54.
    [10]SHEN Y F,ZHAO P T,SHAO Q F,et al.In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier[J].Applied Energy,2015,160:808-819.
    [11]LI J,LIU J,LIAO S,et al.Hydrogen-rich gas production by air–steam gasification of rice husk using supported nano-Ni O/γ-Al2O3catalyst[J].International Journal of Hydrogen Energy,2010,35(14):7399-7404.
    [12]CHEN Z M,ZHANG L.Catalyst and process parameters for the gasification of rice husk with pure CO2 to produce CO[J].Fuel Processing Technology,2015,133:227-231.
    [13]ZHOU L Y,YANG H M,WU H,et al.Catalytic pyrolysis of rice husk by mixing with zinc oxide:characterization of bio-oil and its rheological behavior[J].Fuel Processing Technology,2013,106:385-391.
    [14]MEESUK S,CAO J P,SATO K,et al.The effects of temperature on product yields and composition of bio-oils in hydropyrolysis of rice husk using nickel-loaded brown coal char catalyst[J].Journal of Analytical and Applied Pyrolysis,2012,94:238-245.
    [15]NAQVI S R,UEMURA Y,YUSUP S B.Catalytic pyrolysis of paddy husk in a drop type pyrolyzer for bio-oil production:the role of temperature and catalyst[J].Journal of Analytical and Applied Pyrolysis,2014,106:57-62.
    [16]ABU BAKAR M S,TITILOYE J O.Catalytic pyrolysis of rice husk for bio-oil production[J].Journal of Analytical and Applied Pyrolysis,2013,103:362-368.
    [17]ISA K M,DAUD S,HAMIDIN N,et al.Thermogravimetric analysis and the optimisation of bio-oil yield from fixed-bed pyrolysis of rice husk using response surface methodology(RSM)[J].Industrial Crops and Products,2011,33(2):481-487.
    [18]傅旭峰,司顺勇,刘张鹏.生物质流化床热裂解参数对产物分布的影响研究[J].能源工程,2014(1):42-46.
    [19]ALVAREZ J,LOPEZ G,AMUTIO M,et al.Bio-oil production from rice husk fast pyrolysis in a conical spouted bed reactor[J].Fuel,2014,128:162-169.
    [20]HUANG H J,YUAN X Z,ZENG G M,et al.Thermochemical liquefaction of rice husk for bio-oil production with sub-and supercritical ethanol as solvent[J].Journal of Analytical and Applied Pyrolysis,2013,102:60-67.
    [21]LIU Y,YUAN X Z,HUANG H J,et al.Thermochemical liquefaction of rice husk for bio-oil production in mixed solvent(ethanol water)[J].Fuel Processing Technology,2013,112:93-99.
    [22]SHI W,JIA J F,GAO Y H,et al.Influence of ultrasonic pretreatment on the yield of bio-oil prepared by thermo-chemical conversion of rice husk in hot-compressed water[J].Bioresour Technol.,2013,146:355-362.
    [23]王质斌,王宇迪,赖志彬,等.磷酸对微波催化裂解稻壳制备生物油性质的影响[J].农产品加工(学刊),2012(8):64-66,75.
    [24]姬登祥,蔡腾跃,艾宁,等.熔盐热裂解生物质制生物油[J].生物工程学报,2011,27(3):475-481.
    [25]XU M Y,YIN P,LIU X G,et al.Utilization of rice husks modified by organomultiphosphonic acids as low cost biosorbents for enhanced adsorption of heavy metal ions[J].Bioresource Technology,2013,149:420-424.
    [26]LEE S M,ONG S T.Oxalic acid modified rice hull as a sorbent for methylene blue removal[J].APCBEE Procedia,2014,9:165-169.
    [27]WONG K K,LEE C K,LOW K S,et al.Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions[J].Chemosphere,2003,50(1):23-28.
    [28]AJMAL M,RAO R A K,ANWAR S,et al.Adsorption studies on rice husk:removal and recovery of Cd(Ⅱ)from wastewater[J].Bioresource Technology,2003,86(2):147-149.
    [29]KUMAR U,BANDYOPADHYAY M.Sorption of cadmium from aqueous solution using pretreated rice husk[J].Bioresource Technology,2006,97(1):104-109.
    [30]夏天明,王营茹,范鹏程.改性稻壳吸附亚甲基蓝模拟废水试验研究[J].工业水处理,2013,33(3):47-50.
    [31]张建柱,商平,刘涛利.改性稻壳去除低浓度氨氮的研究[J].安徽农业科学,2011,39(1):228-230,260.
    [32]龙逸云,李金轩,李小燕.改性稻壳对废水中铀的吸附性能[J].济南大学学报(自然科学版),2013,27(4):386-389.
    [33]张文岺,万昆,余国贤,等.磷酸活化稻壳制备柴油脱硫吸附剂[J].石油学报(石油加工),2010,26(4):588-593.
    [34]刘文杰,杨彤,徐姣,等.凹凸棒石/脱硅稻壳炭复合材料吸附Pb2+、Cu2+、Ni2+的对比研究[J].化工新型材料,2015,43(5):169-173.
    [35]阮长青,张丽萍,鹿保鑫.酸性稻壳炭作为油脂脱色剂的制备及脱色工艺的实验研究[J].牡丹江师范学院学报(自然科学版),2000,4(8):13-16.
    [36]廖景明,肖军,沈来宏,等.生物质活性炭吸附二氧化碳的性能研究[J].太阳能学报,2013,34(3):382-387.
    [37]李楠,单保庆,唐文忠,等.稻壳活性炭制备及其对磷的吸附[J].环境工程学报,2013,7(3):1024-1028.
    [38]SOMASUNDARAM S,SEKAR K,GUPTA V K,et al.Synthesis and characterization of mesoporous activated carbon from rice husk for dsorption of glycine from alcohol-aqueous mixture[J].Journal of Molecular Liquids,2013,177:416-425.
    [39]KALDERIS D,KOUTOULAKIS D,PARASKEVA P,et al.Adsorption of polluting substances on activated carbons prepared from rice husk and sugarcane bagasse[J].Chemical Engineering Journal,2008,144(1):42-50.
    [40]FOO K Y,HAMEED B H.Utilization of rice husks as a feedstock for preparation of activated carbon by microwave induced KOH and K2CO3 activation[J].Bioresource Technology,2011,102(20):9814-9817.
    [41]佘敏,段钰锋,朱纯,等.CO2/H3PO4活化与NH4Br改性稻壳焦的脱汞性能实验研究[J].东南大学学报(自然科学版),2014,44(2):321-327.
    [42]王桐,姚超,刘文杰,等.直接合成法制备载银稻壳活性炭及其对苯并噻吩的吸附[J].应用化工,2014,43(9):1611-1615.
    [43]YANG N,ZHU S M,ZHANG D,et al.Synthesis and properties of magnetic Fe3O4 activated carbon nanocomposite particles for dye removal[J].Materials Letters,2008,62(4):645-647.
    [44]鲁婷婷,王婧雅,叶长城,等.稻壳基活性炭负载纳米Fe3O4对水体中罗丹明B的吸附[J].净水技术,2015,34(2):61-66.
    [45]GUO Y P,ZHANG H,TAO N N,et al.Adsorption of malachite green and iodine on rice husk based porous carbon[J].Materials Chemistry and Physics,2003,82(1):107-115.
    [46]ALI I O,HASSAN A M,SHAABAN S M,et al.Synthesis and characterization of ZSM-5 zeolite from rice husk ash and their adsorption of Pb2+onto unmodified and surfactant-modified zeolite[J].Separation and Purification Technology,2011,83:38-44.
    [47]HEMALATHA P,BHAGIYALAKSHMI M,GANESH M,et al.Role of ceria in CO2 adsorption on Na ZSM-5 synthesized using rice husk ash[J].Journal of Industrial and Engineering Chemistry,2012,18(1):260-265.
    [48]CHENG Y,LU M,LI J S,et al.Synthesis of MCM-22 zeolite using rice husk as a silica source under varying-temperature conditions[J].Journal of Colloid and Interface Science,2012,369(1):388-394.
    [49]YUSOF A M,KEAT L K,IBRAHIM Z,et al.Kinetic and equilibrium studies of the removal of ammonium ions from aqueous solution by rice husk ash-synthesized zeolite Y and powdered and granulated forms of mordenite[J].Journal of Hazardous Materials,2010,174(1/2/3):380-385.
    [50]GRISDANURAK N,CHIARAKORN S,WITTAYAKUN J.Utilization of mesoporous molecular sieves synthesized from natural source rice husk silica to chlorinated volatile organic compounds(CVOCs)adsorption[J].Korean Journal of Chemical Engineering,2003,20(5):950-955.
    [51]任素霞.稻壳资源的综合利用研究[D].长春:吉林大学,2009.
    [52]甘露,刘厚凡,高长华,等.稻壳联产纳米白炭黑与活性炭的研究[J].粮食与饲料工业,2007(11):7-9,12.
    [53]阮长青,马军喜,崔素萍,等.稻壳沉淀法制备白炭黑工艺的研究[J].黑龙江八一农垦大学学报,2005,17(2):63-66.
    [54]AN D,GUO Y,ZOU B,et al.A study on the consecutive preparation of silica powders and active carbon from rice husk ash[J].Biomass and Bioenergy,2011,35:1227-1234.
    [55]丁开宇,张彦军,刘成梅,等.稻壳灰制备高纯度白炭黑联产水玻璃影响因素研究[J].中国粮油学报,2009,24(5):1-6.
    [56]LI M,CHEN D Y,ZHU X F.Preparation of solid acid catalyst from rice husk char and its catalytic performance in esterification[J].Chinese Journal of Catalysis,2013,34(9):1674-1682.
    [57]LU C Y,WEY M Y,CHUANG K H.Catalytic treating of gas pollutants over cobalt catalyst supported on porous carbons derived from rice husk and carbon nanotube[J].Applied Catalysis B:Environmental,2009,90(3):652-661.
    [58]ZHANG X,LI Y X,LI G Y et al.Preparation of Fe/activated carbon directly from rice husk pyrolytic carbon and its application in catalytic hydroxylation of phenol[J].RSC Advances,2015,5(7):4984-4992.
    [59]杨波,王伟,朱凯,等.纳米银复合介孔碳材料制备固定化猪胰脂肪酶[J].生物加工过程,2012,10(3):50-55.
    [60]KENNEDY L J,DAS K M,SEKARAN G.Integrated biological and catalytic oxidation of organics/inorganics in tannery wastewater by rice husk based mesoporous activated carbon——Bacillus sp.[J].Carbon,2004,42(12/13):2399-2407.
    [61]ADAM F,CHEW T S,ANDAS J.Liquid phase oxidation of acetophenone over rice husk silica vanadium catalyst[J].Chinese Journal of Catalysis,2012,33(2/3):518-522.
    [62]HINDRYAWATI N,MANIAM G P,KARIM M R,et al.Transesterification of used cooking oil over alkali metal(Li,Na,K)supported rice husk silica as potential solid base catalyst[J].Engineering Science and Technology,an International Journal,2014,17(2):95-103.
    [63]ARTKLA S,KIM W,CHOI W,et al.Highly enhanced photocatalytic degradation of tetramethylammonium on the hybrid catalyst of titania and MCM-41 obtained from rice husk silica[J].Applied Catalysis B:Environmental,2009,91(1/2):157-164.
    [64]徐莉莉.负载型过渡金属氧化物催化剂催化氧化NO的实验研究[D].哈尔滨:哈尔滨工业大学,2009.
    [65]MANSILLA H D,BAEZA J,URZUA S,et al.Acid-catalysed hydrolysis of rice hull:evaluation of furfural production[J].Bioresource Technology,1998,66(3):189-193.
    [66]SINGH A,DAS K,SHARMA D K.Production of xylose,furfural,fermentable sugars and ethanol from agricultural residues[J].Journal of Chemical Technology and Biotechnology,Chemical Technology,1984,34(2):51-61.
    [67]张烨,王平,余波,等.用玉米芯、稻壳混合原料生产糠醛的中试工艺研究[J].中南林业科技大学学报,2011,31(7):160-164.
    [68]CHAREONLIMKUN A,CHAMPREDA V,SHOTIPRUK A,et al.Catalytic conversion of sugarcane bagasse,rice husk and corncob in the presence of Ti O2,Zr O2 and mixed-oxide Ti O2-Zr O2 under hot compressed water(HCW)condition[J].Bioresource Technology,2010,101(11):4179-4186.
    [69]REN S X,XU H Y,ZHU J L,et al.Furfural production from rice husk using sulfuric acid and a solid acid catalyst through a two-stage process[J].Carbohydrate Research,2012,359:1-6.
    [70]SANGARUNLERT W,PIUMSOMBOON P,NGAMPRASERTSITH S.Furfural production by acid hydrolysis and supercritical carbon dioxide extraction from rice husk[J].Korean Journal of Chemical Engineering,2007,24(6):936-941.
    [71]阮榕生,姚远,王允圃,等.微波辅助定向裂解稻壳炼制糠醛及乙酸的研究[J].现代化工,2013,33(5):66-68,70.
    [72]刘宝亮.稻壳中木聚糖的提取和生物降解[D].哈尔滨:东北林业大学,2004.
    [73]韩丹妮.稻壳预处理及稻壳中木聚糖的提取工艺研究[D].长沙:长沙理工大学,2012.
    [74]NABARLATZ D,EBRINGEROVA A,MONTANE D.Autohydrolysis of agricultural by-products for the production of xylo-oligosaccharides[J].Carbohydrate Polymers,2007,69(1):20-28.
    [75]PARAJO J C,GARROTE G,CRUZ J M,et al.Production of xylooligosaccharides by autohydrolysis of lignocellulosic materials[J].Trends in Food Science&Technology,2004,15(3/4):115-120.
    [76]GONZALEZ-MUNOZ M J,DOMINGUEZ H,PARAJO J C.Depolymerization of xylan-derived products in an enzymatic membrane reactor[J].Journal of Membrane Science,2008,320(1/2):224-231.
    [77]刘宝亮,方桂珍.从稻壳中提取木聚糖的研究[J].林产化学与工业,2005,25(s1):121-124.
    [78]王风玲,熊素敏,左秀凤.稻壳酶解制备还原糖的研究[J].粮油加工,2007(7):110-112.
    [79]ZHANG H X,ZHAO X,DING X F,et al.A study on the consecutive preparation of d-xylose and pure superfine silica from rice husk[J].Bioresource Technology,2010,101(4):1263-1267.
    [80]LI Y,DING X F,GUO Y P,et al.A new method of comprehensive utilization of rice husk[J].Journal of Hazardous Materials,2011,186(2/3):2151-2156.
    [81]VILA C,CAMPOS A R,CRISTOV?O C,et al.Sustainable biocomposites based on autohydrolysis of lignocellulosic substrates[J].Composites Science and Technology,2008,68(3/4):944-952.
    [82]石荣铭,梁莉丽.常温酸水解法从稻壳中提取木糖的研究[J].食品科技,2007(12):212-214.
    [83]DUTTA N,MUKHOPADHYAY A,DASGUPTA A K,et al.Improved production of reducing sugars from rice husk and rice straw using bacterial cellulase and xylanase activated with hydroxyapatite nanoparticles[J].Bioresource Technology,2014,153:269-277.
    [84]张沛,杨国辉,魏丽娟,等.稻壳粉固态发酵生产蛋白饲料的工艺研究[J].中国饲料,2015(8):25-27,38.
    [85]刘雅琴,刘天霞,夏青柱.混合菌发酵稻壳粉生产饲料蛋白的研究[J].畜牧与饲料科学,2010(9):19-21.
    [86]罗学刚.碳酸盐在稻壳挤压膨化加工中的应用研究[J].农业工程学报,1998,14(3):235-239.
    [87]崔凤珍,崔少东.膨化稻壳可作为蛋鸡饲料添充料[J].饲料与畜牧,1992(2):7-9.

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