α-烯烃聚合制低黏度聚α-烯烃催化剂的研究进展
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摘要
对近年来聚α-烯烃合成低黏度润滑油基础油催化剂的研究进行了综述。介绍了BF_3体系、AlCl_3体系、齐格勒-纳塔催化剂体系、茂金属催化体系和离子液体催化体系,评价了各催化剂的优缺点,并展望了低黏度催化剂的发展方向。
The research on the catalysts used for synthesizing low viscosity lubricating oil base oil with poly alpha olefin in recent years is summarized,BF_3 catalyst system,AlCl_3 catalyst system,Ziegler-Natta catalyst system,metallocene catalyst system and ionic liquid catalyst system are introduced,the advantages and disadvantages of different catalysts are evaluated,and the development direction of low viscosity catalysts is discussed.
The research on the catalysts used for synthesizing low viscosity lubricating oil base oil with poly alpha olefin in recent years is summarized,BF_3 catalyst system,AlCl_3 catalyst system,Ziegler-Natta catalyst system,metallocene catalyst system and ionic liquid catalyst system are introduced,the advantages and disadvantages of different catalysts are evaluated,and the development direction of low viscosity catalysts is discussed.
引文
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[12]杨晓明,丁洪生,卢富强,等.Al Cl3-正丁醚络合催化剂催化1-癸烯齐聚反应的研究[J].应用化工,2011,40(11):1922-1924.
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[19]申志明,蒋山,郝策,等.(C2H5)2Al Cl/Ti Cl4催化1-癸烯聚合制备高黏度指数润滑油[J].工业催化,2009,17(12):32-36.
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[24]田凡.合成聚α-烯烃离子液体催化剂的研究[J].应用化工,2012,41(3):483-485.
[25]高聪聪,张大伟,王艳,等.烷基咪唑离子液体催化齐聚α-烯烃反应的研究[J].山东大学学报:工学版,2013,43(4):93-98.
[26]张大伟.离子液体催化1-癸烯齐聚物的合成及其应用研究[D].济南:山东大学,2013.
[2]蒋岩,孙恩浩,刘通,等.AlCl3催化剂催化1-癸烯齐聚及其黏温性与低温性的研究[J].精细石油化工进展,2016,17(1):41-44.
[3]李磊.聚α-烯烃润滑油基础油合成工艺研究[D].兰州:兰州大学,2016.
[4]金树余,丁洪生,张冬梅,等.α-烯烃齐聚制PAO催化剂的研究进展[J].应用化工,2011,40(11):2012-2014.
[5]李振华.BF3催化1-癸稀聚α-烯烃合成润滑油研究[J].应用化工,2011,40(3):492-493.
[6]张志峰,丁洪生,权成光,等.癸烯-1聚α-烯烃合成油的合成及性质[J].辽宁石油化工大学学报,2005,25(3):24-27.
[7]王斯晗,曹媛媛,刘通,等.BF3催化1-癸烯制备聚α-烯烃合成润滑油基础油[J].化工进展,2016,35(12):3907-3912.
[8]KRAMER A I,PHIL S,NANDAPURKAR P J,et al.High viscosity polyalphaolefins based on 1-hexene,1-dodecene and1-tetradecene:US,20060388285[P].2009-06-16.
[9]王斯晗,王力搏,刘通,等.BF3催化混合C10和α-烯烃制备聚α-烯烃润滑油基础油[J].化学反应工程与工艺,2016,32(6):528-535.
[10]李登.α-烯烃合成PAO润滑油基础油新技术研究[D].上海:华东理工大学,2014.
[11]王玉龙,高晗,梁宇,等.Al Cl3-H2O催化体系催化1-癸烯齐聚工艺研究[J].精细石油化工进展,2017,18(3):51-54.
[12]杨晓明,丁洪生,卢富强,等.Al Cl3-正丁醚络合催化剂催化1-癸烯齐聚反应的研究[J].应用化工,2011,40(11):1922-1924.
[13]HIROSHI I,TOSHIYUKI U,ANRI T,et al.Method for preparation of olefin oligomer:US,3997622[P].1976-12-14.
[14]HIROSHI M,TOSHIYUKI U,ANRI T,et al.Method for preparation of polyolefin oil:US,40311159[P].1977-06-21.
[15]RYOZO T,HIDEO K,TAKESHI S.Process for preparing catalyst for olefin polymerization:US,4107080[P].1978-08-15.
[16]吕春胜,苏琳.1-C10/1-C14混合烯烃齐聚制备高性能润滑油基础油[J].当代化工,2017,46(4):625-628.
[17]吕春胜,李艺超,杨阳,等.1-C14烯烃齐聚制备高性能润滑油基础油[J].应用化工,2015,44(1):76-80.
[18]卫鹏.负载型催化剂制备低粘度PAO基础油[D].上海:华东理工大学,2012.
[19]申志明,蒋山,郝策,等.(C2H5)2Al Cl/Ti Cl4催化1-癸烯聚合制备高黏度指数润滑油[J].工业催化,2009,17(12):32-36.
[20]GAMBAROVA S A,AKHMEDOV A I.Catalytic systems for oligomerization of higherα-olefins[J].Chemistry and Technology of Fuels and Oils,1997,33(4):212-213.
[21]马跃锋,许健,蒋海珍,等.茂金属催化体系下煤制α-烯烃制备低黏度PAO基础油的工艺研究[J].石油炼制与化工,2016,47(6):32-36.
[22]KISSIN Y V,SCHWAB F C.Post-oligomerization ofα-olefin oligomers:A route to single-component and multicomponent synthetic lubricating oils[J].Journal of Applied Polymer Science,2009,111(1):273-280.
[23]赵智,殷彤蛟,田鹏.离子液体在有机合成中的应用研究[J].山东化工,2017,46(4):65-66.
[24]田凡.合成聚α-烯烃离子液体催化剂的研究[J].应用化工,2012,41(3):483-485.
[25]高聪聪,张大伟,王艳,等.烷基咪唑离子液体催化齐聚α-烯烃反应的研究[J].山东大学学报:工学版,2013,43(4):93-98.
[26]张大伟.离子液体催化1-癸烯齐聚物的合成及其应用研究[D].济南:山东大学,2013.