Synthesis and Structure of [2]Tetrelocenophanes

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• 作者：André ; Schä ; fer ; Kevin Rohe ; Alexander Grandjean and Volker Huch
• 刊名：European Journal of Inorganic Chemistry
• 出版年：2017
• 出版时间：January 3, 2017
• 年：2017
• 卷：2017
• 期：1
• 页码：35-38
• 全文大小：688K
• ISSN：1099-0682c

文摘

The concept of metallocenophanes has been well established for transition metals for a long time. Expanding this concept to p-block elements, the synthesis of sila[2]tetrelocenophanes, with examples for germanium, tin, and lead as the central atoms, was explored. For the first time, the crystal structures of such compounds were obtained, and they gave intriguing insight into the geometry of this almost unexplored class of low-valent main-group molecules.